WO2014013136A1 - Procédé de fabrication d'une pellicule adhésive d'étiquette - Google Patents

Procédé de fabrication d'une pellicule adhésive d'étiquette Download PDF

Info

Publication number
WO2014013136A1
WO2014013136A1 PCT/FI2013/050754 FI2013050754W WO2014013136A1 WO 2014013136 A1 WO2014013136 A1 WO 2014013136A1 FI 2013050754 W FI2013050754 W FI 2013050754W WO 2014013136 A1 WO2014013136 A1 WO 2014013136A1
Authority
WO
WIPO (PCT)
Prior art keywords
facestock
skin layer
roll
layer
machine direction
Prior art date
Application number
PCT/FI2013/050754
Other languages
English (en)
Inventor
Tom Saxberg
Noel Mitchell
Matti Manner
Martti Vähälä
Original Assignee
Upm Raflatac Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upm Raflatac Oy filed Critical Upm Raflatac Oy
Publication of WO2014013136A1 publication Critical patent/WO2014013136A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/023—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets using multilayered plates or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
    • B29C55/06—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/0625—LLDPE, i.e. linear low density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/0633—LDPE, i.e. low density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
    • B32B2038/0028—Stretching, elongating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/04—Punching, slitting or perforating
    • B32B2038/045—Slitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/75—Printability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08—Dimensions, e.g. volume
    • B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105—Thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/14—Velocity, e.g. feed speeds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00—Adhesive articles, e.g. adhesive tapes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0004—Cutting, tearing or severing, e.g. bursting; Cutter details

Definitions

  • the present invention relates to labels. More particularly, the invention relates to machine direction oriented multilayer facestock of the label.
  • a method for manufacturing a machine direction oriented facestock comprising at least a core layer having a first surface and second surface, a first skin layer adjoined to a first surface of the core layer and a second skin layer adjoined to the second surface of the core layer.
  • the method comprises:
  • first roll is arranged to be in contact with the first skin layer of the facestock
  • second roll is arranged to be in contact with the second skin layer of the facestock and wherein the longitudinal force is generated by: a first surface friction between the first skin layer and the first roll; and a second surface friction between the second skin layer and the second roll, said first surface friction and second surface friction being balanced by:
  • a machine direction oriented facestock obtained by a specific method is provided.
  • a machine direction oriented facestock for self-adhesive labels.
  • an apparatus comprising a forming unit, a preheating unit and a stretching unit to produce a machine direction oriented facestock is provided.
  • the temperature of the first roll may be lower than the temperature of the second roll, and the difference between the temperature of the first roll and the temperature of the second roll may be smaller than 15°C.
  • the speed of the surface of the second roll may be between 5 and 8 times higher than the speed of the surface of the first roll; and the stretching of the machine direction oriented facestock may generate a first tensile modulus in the machine direction and a second tensile modulus in transversal direction, wherein the tensile modulus ratio of machine direction to transversal direction in the facestock is between 2.0 and 3.8.
  • the forming may be carried out by coextrusion of the core layer and the skin layers.
  • the distance of the gap may be between 1 and 10 mm.
  • the core layer is located between the first skin layer and the second skin layer, and the core layer may comprise: propylene homopolymer, low density polyethylene and linear low density polyethylene.
  • the content of linear low density polyethylene in the core layer may be between 0.1 and 3.0% of the total polymer weight of the layer.
  • the first skin layer may comprise: propylene homopolymer, linear low density polyethylene
  • the second skin layer may comprise: propylene homopolymer, low density polyethylene and linear low density polyethylene.
  • the content of linear low density polyethylene in the first skin layer may be at least 30% of the total polymer weight of the layer and the content of linear low density polyethylene in the second skin layer may be at least 10% of the total polymer weight of the layer.
  • the core layer or the second skin layer may further comprise: hydrocarbon resin, or styrene block copolymer.
  • the content of propylene homopolymer may be at least 40% of the total polymer weight of the core layer, the content of propylene homopolymer may be at least 40% of the total polymer weight of the second skin layer, and the content of propylene homopolymer may be at least 30% of the total polymer weight of the first skin layer.
  • At least one of the skin layers may further comprise an antiblocking agent.
  • the thickness of the first skin layer may be different from the thickness of the second skin layer.
  • the method may further comprise:
  • the apparatus may further comprise a burning unit to produce free radicals, the stretching unit further comprising a first roll and a second roll separated by a gap, the first roll having a first temperature and a first rotation speed, the second roll having a second temperature and a second rotation speed, the first roll arranged to face the first skin layer of the facestock, the second roll arranged to face the second skin layer of the facestock and the first temperature arranged to be lower than the second temperature.
  • a burning unit to produce free radicals the stretching unit further comprising a first roll and a second roll separated by a gap, the first roll having a first temperature and a first rotation speed, the second roll having a second temperature and a second rotation speed, the first roll arranged to face the first skin layer of the facestock, the second roll arranged to face the second skin layer of the facestock and the first temperature arranged to be lower than the second temperature.
  • Figs. 1 a-1f show examples of a surface treatment method
  • Fig. 1 g shows a flow chart illustration of a surface treatment
  • Fig. 3a shows, in a cross-sectional view, a laminated structure for labels
  • Fig. 3b shows, in a cross-sectional view, a laminated structure comprising die-cut labels
  • Fig. 3c shows, in a cross-sectional view, separating a release from a label
  • Fig. 3d shows, in a cross-sectional view, a multilayer facestock structure
  • Figs. 3e-3f show, in a side view, a conformable facestock
  • Fig.3g shows, in a side view, a label attached to a surface of an item
  • Fig. 4a shows a flow chart illustration of an example method providing machine direction oriented facestock
  • Fig 4b shows an example of the processing system for a machine direction oriented facestock
  • a laminate structure 1 for labels also referred to as a label laminate or a labelstock, comprises at least a facestock 100.
  • it may comprise an adhesive layer 1 14.
  • it may include a release liner 1 15.
  • the adhesive layer 1 14 is between the facestock layer 100 and the release liner 1 15.
  • the facestock may also be referred to as a face material layer, a face layer or a face film.
  • the liner is mainly used to protect the adhesive layer. It also allows efficient handling of the label up to the point where the label is dispensed from the liner and adhered to a substrate surface.
  • the liner 1 15 includes a backing material, such as a plastic film or paper substrate, coated with a thin layer of release agent, such as silicone. Therefore, the release liner 1 15 can be easily removed from the adhesive layer of the label prior to labelling, i.e. before adhering the label to a substrate.
  • the plastic backing material of the release liner may be, for example, a polyester film, a biaxially or machine direction oriented polypropylene film.
  • the thickness of the plastic liner is preferably 20 to 30 microns or even less than 20 microns. Paper substrates may have a thickness between 40 and 60 microns. Referring to Fig. 3b, individual labels 3 may be cut from the laminate structure 1 . In particular, the labels 3 may be die-cut from the structure 1 .
  • the labels may be attached to a common liner 1 15 (the liner remains uncut).
  • a plurality of labels may remain attached to a common continuous liner 1 15.
  • the labels 3 may be completely separate (i.e. also the liner 1 15 may be cut).
  • the labels 3 may be separated from the liner 1 15 e.g. by pulling the liner 1 15 in the direction Sz with respect to the label 3.
  • a surface of the adhesive layer 1 14 may be exposed so that said surface can be attached to an item.
  • the adhesive layer 1 14 the label can be affixed to the substrate, i.e. to the surface of an article.
  • the adhesive layer may consist of a pressure sensitive adhesive (PSA).
  • PSA pressure sensitive adhesive
  • the labels consisting of PSA can be adhered to most surfaces through an adhesive layer without the use of a secondary agent, such as a solvent, or heat to strengthen the bond.
  • the PSA forms a bond when pressure is applied onto the label at room temperature, adhering the label to the product to be labelled.
  • the label comprising pressure sensitive adhesive may be referred to as a pressure sensitive adhesive (PSA) label.
  • PSA pressure sensitive adhesive
  • a label is preferably a self-adhesive label, wherein the label may be used in labelling of articles, such as glass or plastic bottles, packages, or other containers. Also paper or metal based articles may be labelled.
  • the label is suitable for labelling of e.g. home and personal care products, industrial chemical products, pharmaceutical and health care products, beverage and wine bottles, tyres etc.
  • Self-adhesive labels are made from a self-adhesive labelstock (self-adhesive label laminate).
  • the self- adhesive label may comprise a facestock and an activatable adhesive layer.
  • the self-adhesive label may comprise a facestock, a pressure sensitive adhesive (PSA) layer and a release liner, which normally includes silicone.
  • PSA pressure sensitive adhesive
  • the release liner is removed from the self-adhesive label prior to labelling.
  • the self-adhesive label may be adhered to the article through an adhesive layer, which adhesive may be either activatable or pressure-sensitive adhesive.
  • the facestock of the self- adhesive label may be laminated with a release liner having a PSA layer in between, or the self-adhesive label may be a linerless facestock including a facestock and an activatable adhesive layer.
  • a facestock for a self- adhesive labelstock use also referred to as a label laminate
  • a facestock for a self-adhesive label use is provided.
  • Graphical patterns may be printed on the facestock layer 100 e.g. in order to provide a visual effect and/or in order to display information. The printing may be performed to a facestock layer 100 prior to lamination of a laminate structure 1 for labels.
  • a facestock 100 of a laminated structure 1 is printed.
  • a laminate or label consisting of a facestock layer and printing layer may be referred to as a printed laminate or printed label.
  • the printing layer 1 12 may be on top of the facestock 100.
  • the laminate may also include a protective layer(s) (overlaminate layer(s)), such as lacquer, 1 18 on top of the printing layer 1 12.
  • the facestock 1 10 layer should have sufficient mechanical properties.
  • the facestock layer should have sufficient modulus and stiffness values in order to provide die-cuttability for the label. From the economical point of view, the smallest possible thickness of the facestock is also preferred.
  • the facestock may have a multilayer structure.
  • asymmetric structure of the facestock layer may be preferred when optimizing facestock parameters suitable for labels.
  • the separate plastic layers in the multilayer facestock structure e.g. a three layer structure, may have different formulations.
  • skin layers may have a different composition when compared to the composition of the core layer.
  • Asymmetry of the multilayer facestock layers may be achieved by using different film compositions of the layers or by varying the thickness of the layers. If the facestock layers have both a different composition and a different thickness, the structure of the multilayer facestock may be called double asymmetric.
  • the facestock layer 100 may have a multilayer plastic film structure including two or more plastic film layers.
  • the multilayer facestock also referred to a multilayer film, may comprise a core layer and at least one skin layer.
  • the facestock has a skin layer on both surfaces of the core layer, i.e. the facestock has a three layer structure.
  • the facestock 100 has a core layer 101 having a first surface and a second surface, wherein the first skin layer 1 10 is provided on the first surface.
  • the second skin layer 105 is on the second surface of the core layer 101 .
  • the first skin layer may also be referred to as the print receiving layer and the second skin layer as the adhesive receiving layer.
  • the adhesive layer is applied directly to the second surface of the core layer opposite to first skin layer.
  • additional skin layers or other layers such as barrier and/or tie layers, in order to improve the label features, such as label functionality, mechanical properties, or the visual appearance.
  • a tie layer may be used in order to provide enhanced adhesion between the core and skin layer(s) and prevent peeling (delamination) of the multilayer structure.
  • Barrier layer(s) may be used in order to prevent, for example, migration of unwanted ingredients.
  • An over-vanish or lacquer layer may be used on top of the print layer to protect the printing layer.
  • Film surfaces may also be treated prior to printing, for example by flame treatment, corona treatment or plasma treatment in order to enhance for example adhesion. Treated surfaces may also be top coated.
  • the thicknesses of separate layers may be different.
  • the core layer may be relatively thick compared to skin layer(s).
  • the thickness of the core layer may be greater than the thickness of the first skin layer and/or the second skin layer.
  • the thicknesses of individual layers may be different from each other.
  • the thickness of the second skin layer is 2 to 30% of the total thickness of the facestock.
  • the thickness of the core layer may be between 60 and 90%, or between 70 and 90%, preferably between 75 and 90% or between 80 and 90% of the total thickness of the facestock layer.
  • the thickness of the first skin layer may be at least 2% or at least 5%, between 2 and 10% or between 5 and 10% of the total thickness of the facestock.
  • the thickness of the second skin layer may be at least 2% or at least 5%, between 2 and 30% or between 5 and 10% of the total thickness of the facestock layer.
  • a thin first skin layer is preferred in order to control the haze of the facestock film.
  • the thin skin layer is advantageous if a transparent facestock should be provided.
  • a MDO multilayer facestock may have a tensile modulus ratio of the machine direction to the transversal direction of the facestock between 2.0 and 3.8.
  • the facestock 1 10 of the label has a total thickness smaller than 100 microns or smaller than 80 microns, preferably smaller than 60 microns.
  • the facestock layer may have a total thickness between 30 and 80 microns, or between 40 and 60 microns, for example 50 microns.
  • the thickness of the first skin layer may be at least 1 ⁇ or at least 2 ⁇ .
  • the thickness of the first skin layer is preferably smaller than 5 ⁇ .
  • the thickness of the first skin layer may be between 1 and 5 microns, preferably between 1 .5 and 3 microns.
  • the core layer may have a thickness of 30 to 50 microns, preferably 35 to 45 microns,, for example, 43 microns.
  • the second skin layer may have a thickness of at least 1 ⁇ or 2 ⁇ .
  • the thickness of the first skin layer is preferably smaller than 10 ⁇ , or smaller than 8 ⁇ .
  • the second skin layer may have a thickness between 1 and 10 microns, preferably between 2 and 6 microns.
  • the haze of the facestock may be between 20 and 35% prior to printing and over-varnishing of the facestock.
  • the haze of the facestock layer is reduced.
  • the haze of the over-vanished facestock may be lower than 10%, or lower than 8%, for example, between 2 and 6% or between 4 and 5%. Thanks to the higher haze values of the facestock the handling of the film before and during printing and subsequent over-vanishing steps may be easier.
  • the haze is tested according to standard ASTM D1003.
  • the facestock may comprise one or more pigments or inorganic fillers as an additive to provide the facestock with a desired colour.
  • Additives may include, for example, titanium dioxide, calcium carbonate and blends thereof. Carbon black may be introduced to provide a black or grey facestock.
  • Opaque facestocks may have an opacity of at least 70%, at least 75%, or at least 80%, for example between 70 and 95% or between 70 and 80%.
  • the pigment may be included in only one layer. The pigment may be included, for example, in the core layer. Alternatively, the pigment may be also in other layers.
  • the compositions of different layers should be at least partially compatible with each other.
  • at least some of the polymer components in the skin layers should be compatible with the polymer(s) of the core layer to provide sufficient adhesion to the core layer without additional intermediate tie layer(s).
  • a blocking tendency of the facestock, when the facestock is rolled on itself may be reduced by using different film compositions in the first and second skin layers of the multilayer structure.
  • an antiblocking agent may be used in a conventional manner in at least one skin layer creating some surface roughness in order to assist the unwinding of the facestock roll.
  • the surface roughness of the skin layer(s) created by using the antiblocking agent may also be advantageous during stretching of the film. Thanks to the surface roughness the surface friction between the skin layer and the drawing roll may be adjusted. Also the blocking tendency of the skin layer(s) onto the drawing rolls may be avoided.
  • the antiblocking agent may be used on at least the adhesive receiving skin layer.
  • thin and low cost films with properties suitable for the labelling applications may be manufactured.
  • MDO films having a double asymmetric structure may allow conformability of the label during the application of the label (labelling).
  • thin labels having adequate and predetermined stiffness during die-cutting and dispensing may be achieved.
  • the films are suitable for printing, recycling and they may be used as a substrate for different types of adhesives.
  • the multilayer structures and layer compositions are presented below.
  • the core layer of the facestock preferably has a plastic structure including a major amount of polymer ingredients (polymer blend). It may also comprise a minor amount of non-polymeric additives. Percentages of separate polymers in the core layer are percentages by weight based on the total polymer weight of the layer.
  • the core layer has a specific polymer blend composition providing sufficient stiffness for the facestock film.
  • the core layer composition also affects the die-cutting performance of the label. In addition, it should enable the conformability of the label.
  • the core layer comprises a polymer blend comprising propylene homopolymer (homo PP), low density polyethylene (LDPE), hydrocarbon resin (HC) and styrene block copolymer. In addition, the core layer may contain minor components.
  • the main polymer in a core layer is preferably a propylene homopolymer.
  • Propylene homopolymers are polymers of propylene only, i.e. all the repeating units along a chain are of the same type.
  • the polypropylene is preferably isotactic, wherein all of the methyl side groups are located on the same side of the polymer chain.
  • PP may have melt flow rates (MFR) from 2 to 40, as determined by specially designed MFR apparatus.
  • Useful propylene homopolymers may also be characterized as having densities in the range of 0.89 to 0.91 kg/m 3 .
  • the propylene homopolymer is preferred in the multilayer film structure due to the specific stiffness needed for the film. For example, copolymers of propylene reduce the stiffness of the film, which is in the case of facestocks a significant drawback.
  • the propylene homopolymer may have a stiffness of 1600 MPa.
  • the content of polypropylene (PP) homopolymer is at least 40%, preferably at least 50%, more preferably at least 60% or at least 70%.
  • the content of homo PP is not more than 95% or not more than 90%.
  • the content of polypropylene may be between 40 and 90% or between 50 and 80%.
  • the core layer may comprise 60%, 65%, 70%, 75% or 80% of propylene homopolymer.
  • Polyethylene which can be utilized in the core layer of the facestock is a low density polyethylene (LDPE).
  • LDPE low density polyethylene
  • Low density polyethylene is a branched, semicrystalline thermoplastic polymer.
  • LDPE may have a density between 0.910 and 0.933 g/cm 3 , preferably between 0.910 and 0.925 g/cm 3 .
  • the content of LDPE is at least 1 % or 2%, preferably at least 3%.
  • the content of LDPE is not more than 20% or 10%, preferably not more than 8%.
  • the LDPE content is between 1 and 20%, preferably between 3 and 10%, or between 3 and 8%.
  • the amount of LDPE may be 3%, 4% 5%, 6%, 7% or 8%.
  • LDPE is used, for example, in order to stabilize the facestock during manufacturing, thus improving the processability of the facestock. It may also be beneficial when improving the adhesion between the layers in multi-layered facestock structure. However, long branches of the LDPE make the orientation more complex and the content of LDPE is preferably less than 10%.
  • hydrocarbon resins are low molecular weight compounds (polymers/oligomers) consisting of only hydrogen and carbon. Hydrocarbon resins may have amorphous structure and they may be derived from synthetic or natural monomers. For example, petroleum based resins may be used. Hydrocarbon resins may be partially or fully hydrogenated. Saturated hydrocarbons are composed entirely of single bonds and are saturated with hydrogen (fully hydrogenated).
  • the hydrocarbon resin may be aromatic, i.e. having at least one aromatic ring. Alternatively it may be an acyclic or cyclic aliphatic resin.
  • the number average molecular weight (Mn) of the HC may be below 2000 g/mol.
  • the Mn may be between 400 and 500 g/mol and the Mw (weight average molecular weight) between 600 and 700 g/mol, when measured via gel permeation chromatography using PS standards.
  • the softening point according to ASTM E 28 may be below 140 °C, preferably between 90 and 140 °C.
  • the content of hydrocarbon resin is at least 1 % or 3%, preferably at least 6 or 9%.
  • the content of HC is at most 18% or 15%, preferably at most 12% or 10%.
  • the HC content of the core layer may be between 5 and 20%, preferably between 8 and 12%.
  • the content of HC may be 5%, 8% 9%, 10% or 12%.
  • the hydrocarbon resin may be added during the manufacturing process of a film as a compound consisting of HC resin and a suitable carrier, such as thermoplastic olefin polymer.
  • the carrier may be for example, propylene homopolymer.
  • the core layer includes styrene block copolymer(s).
  • Styrene block copolymers include, for example, styrene-ethylene-propylene-styrene (SEPS), styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-propylene block copolymer (SEP) and styrene-ethylene-ethylene-propylene- styrene block copolymer (SEEPS).
  • SEPS styrene-ethylene-propylene- styrene
  • SEBS styrene-ethylene-butylene-styrene
  • styrene block copolymers such as mixtures of SEBS and SEPS.
  • the content of styrene block copolymer is at least 1 % or 5%, preferably at least 9%.
  • the core layer contains at most 20% or 17%, preferably at most 15% styrene block copolymer.
  • the content may be between 5 and 20%, preferably between 8 and 15%, for example 5%, 8%, 12% or 15%.
  • styrene block copolymer such as SEPS, is used in order to decrease stiffness and to increase the flexibility of the film thus enhancing the conformability of the film.
  • the label material flexible enough is able to conform with the surface of the item labelled, i.e. the label accommodates with the underlying contour without wrinkles.
  • SEPS may also be advantageous for increasing the tear resistance of the film in machine direction.
  • the core layer may comprise minor components, such as 1 % of an antioxidant for preventing gel formation due to the oxidation during extrusion process of the film.
  • the antioxidant may also be effective in maintaining the mechanical properties of the film.
  • Other minor components include, for example, an antiblocking agent and linear low density polyethylene. Thanks to the LLDPE the adhesion between the core layer and skin layer(s) may be improved.
  • the amount of the antiblocking agent in the core layer may be lower than 1000 ppm, or lower than 500 ppm, preferably lower than 100 ppm, for example, 60 ppm, between 20 and 500 ppm, or between 60 and 100 ppm by weight of the total weight of the layer.
  • the amount of LLDPE may be at most 20%, or at most 10%, for example, between 0.1 and 20% or between 0.1 and 3% by weight based on the total polymer weight of the layer.
  • virgin based raw materials may be used, or the raw materials may comprise recycled raw material.
  • the recycled raw material may be from the facestock manufacturing process, as illustrated in Fig. 4a.
  • the first skin layer of the multilayer facestock structure should be suitable for printing and provide a sufficient printing ink anchorage.
  • flexographic printing may be used.
  • Printing ink may include, for example, UV- curable printing inks. It should also provide good adhesion to the core layer in order to avoid peeling or delamination of the multilayer facestock structure.
  • the first skin layer has a plastic structure including a major amount of polymer ingredients and minor amount of non-polymeric additives.
  • the first skin layer includes propylene homopolymer and linear low density polyethylene (LLDPE). Minor components include, for example, an antiblocking agent (AB), such as synthetic silica.
  • AB antiblocking agent
  • the antiblocking agent may be added during film manufacturing as a compound comprising silica blended with a carrier, such as propylene homopolymer.
  • a carrier such as propylene homopolymer.
  • PE may be used as a carrier.
  • the compound may contain 10% synthetic silica and 90% propylene homopolymer.
  • the content of the antiblocking compound may be for example 1 %, 2% or 3% based on the weight of the first skin layer. In the first skin layer, the content of the antiblocking agent is at least 0.05%, preferably at least 0.1 or 0.2%.
  • the antiblocking agent content is at most 4%, preferably at most 1 or 0.5%. For example, the content is between 0.05 and 0.2%, between 0.2 and 0.5, or between 1 and 4%. Higher contents, e.g.
  • the main polymer of the first skin layer is a propylene homopolymer.
  • the propylene is preferably the same as in the core layer, as presented above.
  • the content of homo PP may be at least 30% or at least 40%, preferably at least 45 or 50% based on the weight of the first skin layer.
  • the content of propylene homopolymer is at most 100%, preferably at most 80 or at most 70%.
  • the skin layer may contain between 30 and 80% or between 40 and 80%, preferably between 50 and 70%, for example 50, 55, 60, 65 or 70% propylene homopolymer.
  • LLDPE linear low density polyethylene
  • LLDPE is a substantially linear polymer with short branches.
  • LLDPE is produced by using a non-metallocene catalyst providing a non-elastomer polyethylene. Thanks to the linear polymer chain structure, the LLDPE is suitable for orientation (stretching).
  • the content of LLDPE may be at least 10% or at least 20%, preferably at least 30%.
  • the maximum LLDPE content may be 60%.
  • the first skin layer may comprise LLDPE between 10 and 60% or between 10 and 50%, preferably between 20 and 45% or between 30 and 45%.
  • the film may comprise 30, 35, 40, 45 or 50% LLDPE.
  • the first skin layer is more suitable for subsequent surface treatment of the film by e.g. corona, plasma or flame treatment.
  • the second skin layer of the multilayer facestock is the adhesive receiving layer.
  • the composition of the layer should provide a surface for an adhesive layer to be joined, said surface being capable of providing good anchorage of an adhesive. It should also provide good adhesion to the core layer in order to avoid peeling or delamination of the multilayer facestock structure.
  • the second skin layer may include all the same polymeric ingredients as the core layer presented above.
  • the second skin layer may include propylene homopolymer, low density polyethylene, hydrocarbon resin and styrene block copolymer.
  • the second skin may comprise an antiblocking agent, such as silica.
  • the content of the antiblocking agent may be e.g. 0.2%.
  • the composition of the second skin is important in view of processability of the facestock.
  • LDPE may also be used as an additive in the second skin layer, providing better adhesion to the core layer.
  • the second skin layer composition may further include linear low density polyethylene.
  • the second skin layer may have a composition comprising propylene homopolymer, linear low density polyethylene, low density polyethylene, hydrocarbon resin and styrene block copolymer. It may further comprise a minor content of antiblocking agent.
  • the content of propylene homopolymer may be at least 20% or 30%, preferably at least 40% based on the weight of the second skin layer.
  • the propylene homopolymer content is at most 80%, preferably at most 60%. For example, between 20 and 80% or between 20 and 60%, preferably between 40 and 50%.
  • the content of linear low density polyethylene may be at most 40% or at most 30%, preferably at most 25%, for example, between 10 and 30%, preferably between 15 and 25%.
  • the content of low density polyethylene (LDPE) is at least 1 % or 2%, preferably at least 3%.
  • the content of LDPE is not higher than 20% or 10%, preferably not higher than 8%.
  • the LDPE content is between 1 and 20%, preferably between 3 and 10%, or between 3 and 8%.
  • the content of LDPE may be 3%, 4% 5%, 6%, 7% or 8%.
  • the content of hydrocarbon resin is at least 1 % or 3%, preferably at least 6 or 9%.
  • the content of HC is at most 18% or 15%, preferably at most 12% or 10%.
  • the HC content of the core layer may be between 5 and 20%, preferably between 8 and 12%.
  • the content of HC may be 5%, 8% 9%, 10% or 12%.
  • the hydrocarbon resin may be added during the manufacturing process of a film as a compound consisting of HC resin and a suitable carrier, such as thermoplastic olefin polymer.
  • the carrier may be for example, propylene homopolymer.
  • the second skin layer includes styrene block copolymer(s).
  • the styrene block copolymer is same as used in the core layer presented above
  • SEPS styrene-ethylene-propylene-styrene
  • SEBS styrene-ethylene-butylene-styrene
  • SEEPS styrene-ethylene-propylene block copolymer
  • SEEPS styrene-ethylene-propylene-styrene block copolymer
  • SEPS styrene-ethylene-propylene-styrene
  • SEBS styrene-ethylene-butylene-styrene
  • the content of styrene block copolymer is at least 1 % or 5%, preferably at least 9%.
  • the core layer contains at most 20% or 17%, preferably at most 15% styrene block copolymer.
  • the content may be between 5 and 20%, preferably between 8 and 15%, for example 5%, 8%, 12% or 15%.
  • the antiblocking agent is preferably the same as used in the first skin layer and presented above.
  • the content of the antiblocking agent is at least 0.05%, preferably at least 0.1 or 0.2%.
  • the AB content is at most 4%, preferably at most 0.5%.
  • the content is between 0.05 and 0.2%, between 0.2 and 0.5, or between 1 and 4%.
  • all polymeric layers in the multilayer structure may further comprise minor components, such as inorganic fillers, pigments, other organic or inorganic additives in order to provide desired properties, such as appearance (opaque or coloured films), durability and processing characteristics.
  • minor components include calcium carbonate, titanium dioxide, antioxidant compounds, optical brighteners, antistatic aids and processing aids.
  • the thickness of the first skin layer may be different from the thickness of the second skin layer.
  • the thickness of the first skin layer is between 10 and 90% of the thickness of the second skin layer.
  • the thickness of the first skin layer is between 20 and 50% of the thickness of the second skin layer.
  • the composition of the first skin layer is different form the composition of the second skin layer.
  • the content of linear low density polyethylene in the second skin layer may be between 0 and 50 % or between 20 and 40% of the content of linear low density polyethylene in the first skin layer.
  • the content of propylene homopolymer in the second skin layer may be at least 50% or at least 75% of the content of PP homopolymer in the first skin layer, preferably at least 80% or at least 90%.
  • the content of PP in the second skin layer may be between 75 and 120% or between 80 and 1 15% of the content of PP in the first skin layer.
  • the second skin may further comprise other components, such as at least one of the following low density polyethylene, hydrocarbon resin or styrene block copolymer, which are not included in the first skin layer composition.
  • a label comprising a facestock may need to be durable and may need to have a good conformability and clarity.
  • the printability to the label surface may need to be good.
  • the stiffness of the facestock in the machine direction may facilitate the labelling, where a label comprising a facestock may need to be detached from a liner.
  • the manufacturing of a facestock may require a chemical composition together with the structure of the facestock to be optimized, as the label may need to be die cut, while the manufacturing method may need to be cost effective and environmentally friendly.
  • the manufacturing method operating parameters may be selected according to the chemical composition and the structure of the layers to produce the facestock.
  • the manufacturing method for the facestock may therefore comprise a combination of operating parameters which, when selected in accordance to the chemical composition and the structure of the layers, may produce a facestock as described above.
  • Tensile modulus may be used to describe the stiffness of the material.
  • the tensile modulus may be directional, where the tensile modulus in a first direction may differ from the tensile modulus in a second direction.
  • the tensile modulus may be referred to as the ratio of stress to elastic strain in tension.
  • a high tensile modulus may mean that the material is rigid, in other words more stress may be required to produce a given amount of strain.
  • the MD tensile modulus may be 1 .7 GPa for multilayer facestock having an orientation ratio of 5:1 , 2.2 GPa for facestock having an orientation ratio of 6:1 , and 2.7 GPa for facestock having an orientation ratio of 7:1 .
  • the TD tensile modulus may be 0.8 GPa.
  • the tensile modulus ratio MD/TD of machine direction oriented multilayer facestock may be between 2.1 to 3.4 based on ISO527 standard for plastic films.
  • high transparency of the labels may be preferred.
  • Transparent (clear) labels are substantially transparent to visible light. Transparent no-label look appearance of the label is advantageous, for example, in applications where the objects beneath the label, i.e. the surface of a bottle, should be visible through the label.
  • the haze level of a facestock layer should be lower than 35%, preferably equal to or lower than 25% or lower than 10%, when tested according to the standard ASTM D1003.
  • the labels are also conformable.
  • the label can conform smoothly and without wrinkles to the contour of the article even when this is curved in two-dimensions.
  • a conformable label 3 attached to the surface of an article 310, such as bottle, is presented.
  • FIGs 3e and 3f present conformability of a multilayer facestock structure.
  • the facestock layers preferably comprise different chemical compositions.
  • an improved tensile modulus may be obtained.
  • an asymmetric facestock structure presented in Fig. 3f may be preferred.
  • the tensile modulus may be improved further by selecting the operating parameter in the processing method when manufacturing the machine direction oriented facestock.
  • the facestock comprises a propylene homopolymer in at least one of the following layers: the core, the first skin layer or the second skin layer.
  • the core or the second skin layer comprises propylene homopolymer.
  • the content of propylene homopolymer is higher than the content of polyethylene.
  • the ratio of propylene homopolymer to polyethylene in the core layer is at least 2:1 , preferably at least 5:1 or at least 10:1 .
  • the ratio of propylene homopolymer to polyethylene may be, for example, at least 2:1 or 3:1 .
  • the propylene homopolymer may also be advantageous in avoiding distortion of the film.
  • the multilayer facestock may be suitable for using with different adhesives. Suitable adhesives include, for example, pressure- sensitive adhesives (PSA), activatable adhesives, hot melt adhesives. Pressure-sensitive adhesives, such as acrylic based adhesives and a natural or synthetic rubber containing elastomers are preferred.
  • PSA pressure- sensitive adhesives
  • the adhesive layer may be directly applied onto the facestock on the surface of the second skin layer opposite the core layer, or the adhesive may be applied onto the second surface of the core layer.
  • the adhesive may be applied onto the release liner and subsequently transferred to the facestock when the liner and facestock are combined.
  • the adhesive remains joined to the facestock and provides an adhesive surface capable of adhering the facestock to the surface of an article during labelling. If the adhesive is activatable, there may be no need for the release liner.
  • the adhesive may be activated by heat or by another energy source, for example UV.
  • the multilayer facestocks can be made by co-extrusion, coating, or any other laminating process.
  • co-extrusion the layers of the multilayer structure are formed simultaneously by using a suitable co-extrusion die.
  • the layers are adhered to each other to provide a unitary co-extrudate.
  • the multilayer films may be co-extruded through blown film extrusion technology. Alternatively, the films may be cast, i.e. produced by cast extrusion technology.
  • the melt flow index values of the separate layer compositions are adjusted. The melt flow index values of the separate layers are also important in providing a multilayer structure in which the separate layers are well adhered together.
  • the extruded multilayer facestock is subsequently machine direction oriented under uniaxial stress in order to provide orientation of the polymer chains in the direction of pull.
  • the machine direction refers to the running direction of the facestock during the manufacturing.
  • the uniaxial stretching of the film in machine direction is so called machine direction orienting (MDO).
  • MDO machine direction orienting
  • the stretching allows, for example, the reduction in total facestock film thickness without losing the mechanical properties required for a facestock of a label.
  • MDO machine direction orienting
  • the film is heated to an orientation temperature.
  • the orientation temperature is above the glass transition temperature T g of the polymer and below the melting temperature of the polymer T m .
  • the orientation temperature may be e.g. between 1 10 and 140 °C.
  • the heating is preferably performed utilizing multiple heating rollers.
  • Heated film is fed into a drawing section, which includes draw rolls with different rolling speeds.
  • the rolling speed is adjusted so that the predetermined draw ratio of the film is achieved.
  • the stretched film enters the annealing section, which allows stress relaxation of the oriented film by keeping the film at an elevated temperature for a period of time. Finally, the film is cooled through a cooling section to ambient temperature.
  • the ratio of total film thickness before and after stretching is called the "draw ratio”.
  • the draw ratio of the MDO facestock film may be between 4:1 and 10:1 , preferably the draw ratio is between 5:1 and 8:1 , for example 7:1 .
  • Fig. 4a shows an example of a process to manufacture a machine direction oriented (MDO) facestock.
  • the layer materials may be mixed in separate mixers, as shown in steps 400, 401 and 402. There may be one or more mixer for each layer material. After the mixing, the material may be conveyed and melted in an extruder, as shown in step 405.
  • the facestock may be formed by extrusion or coextrusion comprising more than one layer. If the layers are extruded separately, they may be attached to each other later, for example by lamination. Coextrusion may be the preferred method.
  • the facestock may be cooled as shown in step 407. Before or after cooling facestock material which may not be suitable for orientation may be recycled back to the manufacturing process, as shown in step 408.
  • Suitable facestock material for orientation may comprise a core layer with a first and a second surface, a first skin layer attached to the first surface of the core layer, and a second skin layer attached to the second surface of the core layer.
  • the chemical composition of the first skin layer may be different from the chemical composition of the second skin layer.
  • the thickness of the first skin layer may be different from the thickness of the second skin layer.
  • the facestock may comprise propylene homopolymer at least 40 percent of the total polymer weight of the core layer.
  • the content of propylene homopolymer may be at least 40 percent of the total polymer weight of the second skin layer, and the content of propylene homopolymer may be at least 30 percent of the total polymer weight of the first skin layer.
  • the content of linear low density polyethylene in the first skin layer may be at least 30 percent of the total polymer weight of the layer, and the content of linear low density polyethylene in the second skin layer may be at least 10 percent of the total polymer weight of the layer.
  • the second skin layer may have a greater thickness than the first skin layer, and the core layer may have a greater thickness than the second skin layer.
  • the chemical composition of the layers may be selected such that the stiffness of the core layer may be increased in the machine direction orientation, for example, by increasing the proportion of propylene homopolymer in the core layer.
  • the facestock may first be heated to improve the uniformity of the temperature of the facestock.
  • the uniformity of the temperature of the facestock may level out the effect of the orientation in machine direction. An even temperature throughout the facestock may further enable a better control of the orientation step to obtain a more equal level of orientation throughout the facestock.
  • the facestock is drawn in the machine direction by a longitudinal force, which causes the facestock material to stretch and the polymer fibers to orientate in the machine direction.
  • the stretching may have an effect on the thickness of the facestock.
  • the thickness of the facestock may diminish in the same ratio as the facestock stretches or elongates.
  • a facestock may have a thickness of 350 micrometers before machine direction orientation (MDO), and is stretched by a draw ratio of 7:1 . After the machine direction orientation the facestock may therefore have a seven fold diminished thickness of 50 micrometers.
  • MDO machine direction orientation
  • the stretching may take place in a stretching unit.
  • the stretching unit may comprise one or more rolls.
  • Advantageously the stretching may be performed by draw rolls, such as a first roll and a second roll.
  • the draw rolls may comprise nip rolls for increasing the surface friction of the facestock to the draw rolls.
  • the rolls may have a rotational speed.
  • the rotational speed of one roll may be different from the rotational speed of another roll.
  • the rotation speed of a roll may be changed or it may be selected according to the required machine direction orientation level or draw ratio.
  • the stretching unit may comprise a first roll and a second roll, which are separated by a gap between the first roll and the second roll.
  • the rolls may rotate in the same direction.
  • the facestock may be arranged to pass through the gap between the first roll and the second roll.
  • the distance of the gap may be between 1 - 10 mm, preferably smaller than 5 mm, for example smaller than 3 mm.
  • the gap may be the site where the stretching of the facestock may be performed between the first roll and the second roll.
  • the first roll may face the first skin layer of the facestock, and the second roll may face the second skin layer of the facestock.
  • the first roll may have a first rotation speed and the second roll may have a second rotation speed. Further, the speed of the surface of the first roll may be different from the speed of the surface of the second roll.
  • the speed of the surface of the second roll may be higher than the speed of the surface of the first roll, which may be used to stretch the facestock.
  • the speed of the surface of the second roll may be, for example, between 5 and 8 times higher than the speed of the surface of the first roll.
  • the first roll may have a first stretching temperature and the second roll may have a second stretching temperature.
  • the first stretching temperature of the first roll may be lower than the second stretching temperature of the second roll.
  • the difference between the first stretching temperature and the second stretching temperature may be used to select the longitudinal force.
  • the first roll may be arranged to face the first skin layer of the facestock and the second roll may be arranged to face the second skin layer of the facestock. In this case, the first stretching temperature at the first roll may be arranged to be lower than the second stretching temperature at the second roll.
  • the use of a temperature gradient when applying a longitudinal force may prevent slipping or breaking of the film.
  • the skin surface in contact with the roll also undergoes a decrease in temperature, which may have an effect on the rheology of the surface. Therefore, the surface friction on the skin layer surface may increase, which may act as a counterforce to the longitudinal force.
  • there may be a first surface friction between the first skin layer and the first roll which may depend on the first stretching temperature of the first roll, the chemical composition and thickness of the first skin layer, and the speed of the surface of the first roll.
  • There may also be a second surface friction between the second skin layer and the second roll which may depend on the second stretching temperature of the second roll, the chemical composition and thickness of the second skin layer, and the speed of the surface of the second roll.
  • the speed of the surface of the second roll may have an effect on the longitudinal force; by increasing the speed of the surface of the second roll the longitudinal force may be increased.
  • the first roll temperature may be decreased to increase the surface friction, which may then counteract the thus increased longitudinal force.
  • the first surface friction and the second surface friction may be balanced by selecting a temperature for the first roll with respect to the chemical composition of the first skin layer and selecting a temperature for the second roll with respect to the chemical composition of the second skin layer.
  • the difference between the temperature of the first roll and the temperature of the second roll may be, for example, between 0°C and 30°C, such as smaller than 15°C.
  • the first roll and the second roll may have the same temperature.
  • the effect may further be controlled by selecting the layer thickness of the first skin layer and the second skin layer such that the applied longitudinal force is evenly balanced and the orientation may proceed in a smooth and controlled manner.
  • the operational parameters such as the layer composition, the layer thickness, the temperature of a roll and the speed of the surface of a roll
  • a machine direction oriented facestock may be obtained which may have a draw ratio in a machine direction between 4:1 and 8:1 , such as greater than or equal to 5:1 and between 5:1 and 8:1 , or between 5:1 and 7:1 .
  • the method may enable the formation of a machine direction oriented facestock with a first tensile modulus in the machine direction and a second tensile modulus in transversal direction, wherein the tensile modulus ratio of machine direction to transversal direction may be improved.
  • the tensile modulus ratio of machine direction to transversal direction in the facestock may be between 2.0 and 3.8.
  • Tensile modulus is measured according to the standard ISO 527.
  • the facestock may be annealed as shown in step 430.
  • the annealing may be used to relax the machine direction oriented facestock and stabilize the effect of the stretching.
  • the facestock may be cooled down as shown in step 450.
  • the thickness of the facestock may not be uniform throughout the facestock width, and edges of the facestock may be thicker than the rest of the facestock.
  • the edges which do not comprise the required thickness may be cut off the facestock after the stretching and may be recycled back to the manufacturing process.
  • the edges may be, for example, used as recycled raw material for the core layer 101 .
  • the material for recycling may be removed before or after the cooling 450, preferably after the annealing 430 and before the cooling 450.
  • adhesive and/or print receiving layer(s) may be surface treated by flame treatment, corona treatment, plasma treatment in order to enhance, for example, adhesion of the print layer.
  • the facestock may be surface treated as shown in step 470.
  • the surface may be apolar and may have a low surface tension.
  • Surface tension in this context is expressed as the amount of a force required for a length of the material with a unit of millinewtons per meter (mlM/m), which may also be in units of dynes per centimetre (dynes/cm).
  • mlM/m millinewtons per meter
  • dynes/cm dynes per centimetre
  • Figs. 1 a-1f show examples of a method for skin layer surface treatment, which may be used to increase the surface tension of the skin layer surface.
  • the surface treatment may improve the printability of the skin layer surface.
  • the surface treatment of the facestock may comprise steps such as shown in Fig. 1 g.
  • the method may comprise other steps in addition to the steps shown in the Fig. 1 g.
  • the facestock may be transferred at a velocity V1 with respect to an apparatus comprising a primer unit 125 located at a distance D1 from the first surface of the skin layer 1 10.
  • the velocity V1 may be selected such that the period of time for which an area a1 of the first surface of the skin layer 1 10 may be exposed to an effect caused by a zone 190 may be sufficient to have a desired effect on the first surface of the skin layer 1 10.
  • the desired effect may depend on the chemical composition or thickness of the facestock layers.
  • the facestock may be stretched uniaxially in the machine direction.
  • some of the polymer molecules in the facestock may be in crystal form while other polymer molecules may be in amorphous form.
  • the stretching may extend the polymer chains in the facestock in the machine direction.
  • the extent of stretching in other words the degree of a longitudinal force in the machine direction, may therefore have an effect on the ratio of the polymer crystals to the amorphous polymer molecules in the facestock.
  • the amorphous form of the oriented polymer molecules may be more extended and may present a larger area exposed to free radicals compared to the polymers in crystal form. After stretching in machine direction and annealing, the crystallization of the polymer molecules may still continue for a while.
  • the surface treatment is applied to the skin layer surface while the number of amorphous polymer molecules is at the greatest. Therefore, exposing the first surface of the skin layer to the free radicals may be done after the stretching of the facestock at a longitudinal force to produce the machine direction oriented facestock, but before winding the machine direction oriented facestock to a roller for storage.
  • the stretching may have an effect in the thickness of the facestock.
  • the thickness of the facestock may diminish in the same ratio as the facestock stretches or elongates.
  • the facestock may have a thickness of 350 micrometers before the machine direction orientation (MDO), and it is stretched by a draw ratio of 7:1 .
  • the facestock may therefore have a seven fold diminished thickness of 50 micrometers.
  • the thickness of the facestock may not be uniform throughout the facestock width, and edges of the facestock may be thicker than the rest of the facestock.
  • the edges which do not comprise the required thickness may be cut off the facestock after the stretching and may be recycled back to the manufacturing process.
  • the edges may be, for example, used as recycled raw material for the core layer.
  • the treatment may be done for the skin layer surface after stretching the facestock.
  • the treatment may comprise an exposure of the skin layer surface to free radicals.
  • the free radicals may be produced by a flame.
  • the free radicals may be produced by a fuel gas.
  • Plasma is a partially ionized gas comprising both physically and chemically reactive species.
  • Plasma treatment includes, for example thermal plasma, but also cold plasma. In thermal plasma all species have approximately same temperature. Cold plasma has a high electron temperature but a low ion or gas temperature. It is also possible to use low pressure or atmospheric pressure during the plasma treatment. Atmospheric pressure may be preferred in in-line surface treatment processes. For surface activation, for example, O2 plasma or N 2 plasma may be used.
  • the apparatus may comprise, for example, a high-frequency power generator, a high-voltage transformer, a stationary electrode, and a treater. Electrical power may be converted into higher frequency electrical power, which may be applied to electrode tips comprising an air gap between the tips. A high voltage difference produced by the high frequency electrical power between the electrode tips may then generate a discharge of plasma.
  • gas molecules in the air may be converted into free radicals, such as ozone (O3), which may act as reactive components in chemical reactions on the facestock surface. The free radicals may participate in breaking the carbon-hydrogen links along the polymer surface.
  • the fuel gas may be a hydrocarbon, for example a Ci - C 4 hydrocarbon.
  • the hydrocarbon may be, for example, methane, propane or butane.
  • the hydrocarbon may also be natural gas.
  • the fuel gas may be mixed with an oxidant and ignited with heat to produce a propagating flame where a combustion reaction may occur.
  • the oxidant may be air.
  • the oxidant may also be oxygen (O2) or a mixture of gaseous components comprising oxygen.
  • the flame may comprise an oxidizing zone with a high temperature, where the combustion reaction between the fuel gas and the oxidant may form free radicals.
  • the temperature of the oxidizing zone may depend of the used fuel gas and the mixture ratio of oxidant and the fuel gas.
  • the temperature of the oxidizing zone may depend on the selected fuel gas and the mixture comprising the fuel gas and the oxidant, which may be set in the step 474.
  • the mixing ratio of the mixture is the amount of the oxidant mixed with the fuel gas, which may have an effect on the level of the combustion reaction.
  • the mixing ratio may be expressed as the molar fraction of fuel gas to the molar fraction of oxidant.
  • a mixture comprising fuel gas and air in at least equimolar amounts may lead to a complete combustion reaction at a higher temperature, whereas a smaller molar fraction oxidant may yield an incomplete reaction at a lower temperature.
  • the temperature of the oxidizing zone in the method may be, for example between 600°C and 2000°C, preferably at least 700°C, more preferably at least 800°C. In the oxidizing zone, the concentration of the fuel gas diminishes rapidly as the combustion reaction and heat release take place.
  • the treatment mixture ratio of oxidant and the fuel gas may be selected such that a dwell time during which the skin layer surface may be exposed to the free radicals is optimized to obtain a desired effect on the surface tension.
  • the facestock may be exposed to the free radicals as shown in step 475.
  • the dwell time may be selected such that the thermal stress of the flame to the skin layer surface is kept at a minimum.
  • the dwell time may be dependent on the velocity Vi of the skin surface.
  • the velocity Vi in this context may be defined with respect to the flame, corona or plasma discharge.
  • the dwell time may also depend on the mixture flow qi, which is the propagation speed of the flame.
  • the propagation speed of the flame correlates with the temperature of the flame, which may define the thickness of the oxidizing zone where free radicals may be formed.
  • the mixture flow may be expressed in normal cubic meters per hour (Nmc/h) of fuel gas burned per burner meter.
  • the distance D1 between the oxidizing zone and the first surface of the skin layer may be thus be selected in respect to the dwell time such that the treatment level produces a desired surface tension level.
  • the distance D1 may advantageously be selected such that the skin layer surface may pass through the oxidizing zone of the flame, which may be the part of the flame with the highest temperature.
  • the temperature in the oxidizing zone may be at least 700°C, preferably at least 800°C.
  • the distance D1 may be smaller than 10 mm, preferably smaller than or equal to 5 mm.
  • the flame may comprise a colour depending on the used mixture ratio.
  • the colour such as violet, green or yellow, may be due to compounds such as excited CH radicals or C2 molecules.
  • the colour of the flame may be used to observe the mixture composition during the flame treatment to optimize the flame conditions.
  • the length of the oxidizing zone may depend on the propagation speed of the flame, which may be called the mixture flow q1 .
  • the oxidation of the hydrocarbon by an oxidant in the flame may, in addition to free radicals, also produce oxygen based groups which may be inserted in the broken carbon-hydrogen links along the polymer chains at the skin layer surface.
  • These oxygen based groups may comprise, for example, oxygen- based OH radicals or a HO2 radical.
  • these reactive groups may increase the surface tension level of the skin layer surface and may participate in prolonging the effect of the surface treatment.
  • the treatment increasing the surface tension may not be permanent, and the level of surface tension may decrease from the obtained treatment level as a function of time.
  • the treatment may later be repeated, as shown in step 476, to restore the level of surface tension obtained in a previous treatment.
  • This step 476 is optional.
  • the restoration may not be complete.
  • the surface tension of the skin layer may be maintained higher than or equal to 38 mlM/m or 44 mlM/m after 50 days, or after 120 days from the treatment. Surface tension is measured according to the standard ISO 8296.
  • An apparatus may be arranged to provide a machine direction oriented facestock and to perform the surface treatment for the facestock.
  • the surface treatment may be a part of the manufacturing process, i.e. the in-line manufacturing process of the facestock may also include surface treatment of the facestock.
  • the surface treatment may alternatively be arranged separately (off-line) and may not be part of the process.
  • the apparatus may comprise a stretching unit 420, a facestock transfer unit 408 and a surface treatment unit (burner unit) 470.
  • the facestock 100 may be transferred by a transfer unit 408 to a pre-heating unit 410, which may be adjoined by a stretching unit 420.
  • the stretching unit may be adjoined to an annealing unit 430, which may be adjoined to a cooling unit 450.
  • the burner unit 470 may be adjoined to the cooling unit.
  • the stretching unit 420, the annealing unit 430 or the cooling unit 450 may comprise the burner unit 470.
  • the pre-heating unit 410, the stretching unit 420, the annealing unit 430, the cooling unit 450 and the burner unit 470 may also be part of the transfer unit 408.
  • Each unit may comprise rolls. There may be more than one roll in each unit and the number of rolls in each unit may vary. The rolls may have a rotational speed. The rotational speed of a roll may be changed or it may be selected according to the required purpose. The rolls may have a temperature.
  • the temperature of a roll may be changed or it may be selected according to the required purpose.
  • the rolls may be used to transfer the facestock.
  • the rolls may generate a velocity V1 at which the facestock may be transferred.
  • the velocity V1 of the facestock may be different in each unit.
  • the preheating unit 420, stretching unit 420, annealing unit 430, cooling unit 450, burning unit 470 or the transfer unit may comprise rolls rotating at different speeds.
  • the velocity V1 of the facestock may therefore be given as the average velocity between two rotating rolls.
  • the rolls may also be used to heat or cool the facestock.
  • the rolls may be used to stretch the facestock in the machine direction by a longitudinal force.
  • the rolls may have a width and a cross-sectional diameter. The width and a cross-sectional diameter of a roll may vary from those of another roll.
  • the burner unit may comprise a primer device 125 and a mixer device 120.
  • the mixer device may be, for example, a burner port.
  • the primer device 125 may comprise the mixer device 120.
  • the mixer device 120 may be optional.
  • the primer device 125 may be used to provide fuel gas.
  • the mixer device 120 may be used for forming a mixture comprising the fuel gas and an oxidant.
  • the mixer device 120 may be used for selecting the mixing ratio of the mixture comprising the fuel gas and the oxidant such that the combustion reaction may produce an oxidizing zone where free radicals may be formed.
  • the surface of the first skin layer 1 10 of the facestock 100 may be facing the primer device.
  • the surface treatment may optionally be performed on the surface of the second skin layer 105, and the facestock may be formed such that the surface of the second skin layer 105 is facing the primer device 125.
  • the facestock may have a thickness D4.
  • the facestock thickness D4 may vary during the manufacturing of the machine direction oriented facestock.
  • the facestock thickness D4 during the flame treatment may be smaller than 60 micrometers, for example 50 micrometers.
  • Fig. 1 b presents an example of an area a1 defined by the first width D2 and the second width D2 of the mixer device 120.
  • the area a1 may be planar, or it may have curvature.
  • An example where the area a1 may have a curvature is presented in Fig. 1f, where the area a1 may be located on the skin layer 1 10 surface above a roll 492, which may be a treater roll.
  • the effect the surface treatment may have on the skin layer 1 10 surface of the facestock 100 may depend on the velocity V1 , the mixture flow q1 , the distance D1 between the skin layer 1 10 surface and the mixer device 120, the temperature of the oxidizing zone and the temperature at the skin layer 1 10 surface.
  • the roll 492 may be used for cooling the facestock 100 during the skin layer 1 10 surface treatment.
  • the roll may have a temperature between 5°C and 30°C, advantageously at least 10°C.
  • the exposure of the skin layer to the free radicals may be determined by the dwell time, which is determined by the velocity V1 of the skin surface.
  • the velocity V1 , the temperature at the skin surface and the mixture flow may be directly correlated to each other.
  • a higher skin surface velocity V1 may require a higher temperature at the skin surface and a higher mixture flow rate q1 .
  • the dwell time may also be selected by setting the oxidizing zone where the flame temperature is to be the highest at the distance D1 from the mixer device 120. The distance D1 may therefore be used to control the flame intensity.
  • the apparatus to perform the surface treatment comprising the primer unit 125 may be located on the same side of the core layer 101 as the skin layer 1 10.
  • An example of the apparatus, which is located in vertical position, is presented in Fig. 1 c.
  • a three dimensional example of the apparatus is presented in Fig.l d, where the width of the facestock 100 is equal to the width D3 of the primer device.
  • Fig. 1 e presents an example where the apparatus may be located at an angle ⁇ from the first surface of the facestock.
  • the facestock 100 may have a velocity Vi with respect to the primer unit 125 which may produce the corona, flame or plasma discharge.
  • the velocity Vi may be parallel to a first direction S x .
  • the facestock 100 may pass through the area a1 specified by the first width D2 and the second width D3 of the mixer device 120.
  • the distance D1 from the mixer device 120 to the surface of the first skin layer 1 10 may be determined by the angle ⁇ from the centre of the first width D2 of the mixer device with respect to the first direction S x .
  • the manufacturing of a facestock for the labels is to be illustrated in the following example. Example 1 .
  • the flame treatment may comprise parameters, as presented in Table 1 below, for a skin layer surface comprising at least 30 percent of propylene homopolymer of the total polymer weight of the layer.
  • the surface treatment of a facestock surface may depend of the composition of the skin layer.
  • polyethylene may be easier to treat, and the increased surface tension level may last longer.
  • the renewal of the surface treatment may also be more efficient.
  • a skin layer comprising at least 30 percent of propylene homopolymer of the total polymer weight of the layer may be difficult to treat. Addition of a linear low density polyethylene or low density polyethylene to the skin layer composition may help to increase the surface tension or the treatment.
  • Flame treatment may be advantageous for a skin layer comprising propylene homopolymer between 30 and 60 percent of propylene homopolymer of the total polymer weight of the layer.
  • a skin layer may endure the flame treatment better due to better physical properties of the polymer, such as a higher melting point.
  • the treatment may be improved by using a facestock, where the core layer comprises at least 50 percent of propylene homopolymer of the total polymer weight of the layer, and the skin layers comprise at least 40 percent of propylene homopolymer of the total polymer weight of the layers. It has also been discovered that by using first a flame to increase the surface tension level of the facestock and later repeating the treatment using corona, the printability of the skin surface may be returned to an excellent level.
  • the facestock comprising a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the composition of the first skin layer is different from the composition of the second skin layer, and wherein the second skin layer is configured to be in contact with the adhesive layer, said second skin layer comprising:
  • the machine direction oriented multilayer facestock according to any of the items 1 .1 to 1 .3, wherein the second skin layer comprises styrene block copolymer between 5 and 20%.
  • a self-adhesive label comprising an adhesive layer and a machine direction oriented multilayer facestock comprising at least a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the composition of the first skin layer is different from the composition of the second skin layer, and wherein the second skin layer is configured to be in contact with the adhesive layer, said second skin layer comprising:
  • a method for manufacturing a machine direction oriented multilayer facestock for labels comprising a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, the method comprising:
  • the chemical composition of the first skin layer is different from the chemical composition of the second skin layer, said second skin layer comprising propylene homopolymer, hydrocarbon resin, styrene block copolymer, and low density polyethylene;
  • a machine direction oriented multilayer facestock for labels comprising a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the first skin layer is configured to be in contact with the print layer and the second skin layer is configured to be in contact with the adhesive layer, and wherein the thickness of the first skin layer is 10 to 90% of the thickness of the second skin layer.
  • a self-adhesive label comprising an adhesive layer and a machine direction oriented multilayer facestock comprising a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the first skin layer is configured to be in contact with the print layer and the second skin layer is configured to be in contact with the adhesive layer, and wherein the thickness of the first skin layer is 10 to 90% of the thickness of the second skin layer.
  • a method for manufacturing a machine direction oriented multilayer facestock for labels comprising a core layer having a first surface and a second surface, a first skin layer adjoined to the first surface of the core layer and a second skin layer adjoined to the second surface of the core layer the method comprising:
  • the thickness of the first skin layer is 10 to 90% of the thickness of the second skin layer
  • a machine direction oriented multilayer facestock for labels comprising a core layer having a first surface and a second surface, and a first skin layer adjoined to the first surface of the core layer, the core layer comprising:
  • styrene block copolymer is at least one of the following styrene-ethylene-propylene-styrene or styrene-ethylene-butylene-styrene.
  • the second skin layer comprises:
  • the second skin layer comprises between 20 and 60% of propylene homopolymer of the weight of the skin layer.
  • a self-adhesive label including an adhesive layer and a machine direction oriented multilayer facestock comprising at least a core layer having a first surface and a second surface and a first skin layer adjoined to the first surface of the core layer, and wherein the adhesive layer is attached to the second surface of the core layer, said core layer comprising:
  • a method for manufacturing a machine direction oriented multilayer facestock for labels comprising:
  • the core layer comprises propylene homopolymer, low density polyethylene, hydrocarbon resin, and styrene block copolymer
  • a machine direction oriented facestock for labels comprising at least a core layer having a first surface and second surface, a first skin layer adjoined to a first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the tensile modulus ratio of the facestock is between 2.0 and 3.8, wherein the tensile modulus ratio is the ratio of the tensile modulus of the machine direction to the tensile modulus of the transversal direction.
  • a method for manufacturing a machine direction oriented facestock for labels comprising at least a core layer having a first surface and second surface, a first skin layer adjoined to a first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, the method comprising:
  • first roll is arranged to be in contact with the first skin layer of the facestock
  • second roll is arranged to be in contact with the second skin layer of the facestock and wherein the longitudinal force is generated by:
  • first surface friction between the first skin layer and the first roll and a second surface friction between the second skin layer and the second roll, said first surface friction and second surface friction balanced by: selecting a temperature for the first roll with respect to the chemical composition of the first skin layer; and
  • the speed of the surface of the second roll is between 5 and 8 times higher than the speed of the surface of the first roll
  • the stretching of the machine direction oriented facestock generates a first tensile modulus in the machine direction and a second tensile modulus in transversal direction, wherein the tensile modulus ratio of machine direction to transversal direction in the facestock is between 2.0 and 3.8.
  • a self-adhesive label including an adhesive layer and a machine direction oriented facestock comprising at least a core layer having a first surface and second surface, a first skin layer adjoined to a first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, wherein the tensile modulus ratio of the facestock in machine direction to transversal direction is between 2.0 and 3.8.
  • a method for manufacturing a machine direction oriented facestock comprising at least a core layer having a first surface and second surface, a first skin layer adjoined to a first surface of the core layer and a second skin layer adjoined to the second surface of the core layer, the method comprising:
  • first roll is arranged to be in contact with the first skin layer of the facestock
  • second roll is arranged to be in contact with the second skin layer of the facestock and wherein the longitudinal force is generated by: a first surface friction between the first skin layer and the first roll; and a second surface friction between the second skin layer and the second roll, said first surface friction and second surface friction being balanced by:
  • the stretching of the machine direction oriented facestock generates a first tensile modulus in the machine direction and a second tensile modulus in transversal direction, wherein the tensile modulus ratio of machine direction to transversal direction in the facestock is between 2.0 and 3.8.
  • the second skin layer comprises:
  • a machine direction oriented facestock obtained by a method according to any of the items 5.1 to 5.14.
  • 5.16. Use of a machine direction oriented facestock according to item 5.15 for self-adhesive labels.
  • An apparatus comprising a forming unit, a preheating unit and a stretching unit to produce a machine direction oriented facestock.
  • the apparatus according to item 5.17 further comprising a burning unit to produce free radicals, the stretching unit further comprising a first roll and a second roll separated by a gap, the first roll having a first temperature and a first rotation speed, the second roll having a second temperature and a second rotation speed, the first roll arranged to face the first skin layer of the facestock, the second roll arranged to face the second skin layer of the facestock and the first temperature arranged to be lower than the second temperature.
  • a method for treating a machine direction oriented facestock comprising a skin layer, said skin layer comprising less than 50% of linear low density polyethylene of the total polymer weight of the layer and more than 50% of propylene homopolymer of the total polymer weight of the layer, said method comprising:
  • the longitudinal force such that the tensile modulus ratio of the facestock is between 2.0 and 3.8, wherein the tensile modulus ratio is the ratio of the tensile modulus of the machine direction to the tensile modulus of the transversal direction generated by the stretching of the facestock.
  • content of propylene homopolymer is between 30 percent and 60 percent of the total polymer weight of the layer;
  • the second skin layer comprises: propylene homopolynner
  • content of propylene homopolymer is between 40 percent and 80 percent of the total polymer weight of the layer.
  • the facestock comprises a core layer between the first skin layer and the second skin layer, said core layer comprising:
  • a machine direction oriented facestock obtained by any of the method according to the items 6.1 to 6.12.
  • An apparatus comprising a stretching unit, a facestock transfer unit and a burner unit for producing free radicals for treating a machine direction oriented facestock. 6.15. The apparatus according to item 6.14, further comprising a first roll and a second roll separated by a gap, the first roll having a first temperature and a first rotation speed, the second roll having a second temperature and a second rotation speed, the first roll being arranged to face the first skin layer of the facestock, the second roll being arranged to face the second skin layer of the facestock and the first temperature being arranged to be lower than the second temperature.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un procédé et un appareil de fabrication d'une pellicule adhésive (100) orientée dans le sens machine qui comprend au moins une couche centrale présentant une première surface et une deuxième surface, une première couche de peau adjacente à une première surface de la couche centrale et une deuxième couche de peau adjacente à la deuxième surface de la couche centrale. L'invention concerne également une pellicule adhésive (100) orientée dans le sens machine et une utilisation de la pellicule adhésive (100) pour des étiquettes autoadhésives.
PCT/FI2013/050754 2012-07-17 2013-07-12 Procédé de fabrication d'une pellicule adhésive d'étiquette WO2014013136A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201261672358P 2012-07-17 2012-07-17
FI20125803 2012-07-17
FI20125803 2012-07-17
US61/672,358 2012-07-17

Publications (1)

Publication Number Publication Date
WO2014013136A1 true WO2014013136A1 (fr) 2014-01-23

Family

ID=49948345

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2013/050754 WO2014013136A1 (fr) 2012-07-17 2013-07-12 Procédé de fabrication d'une pellicule adhésive d'étiquette

Country Status (1)

Country Link
WO (1) WO2014013136A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001017775A1 (fr) * 1999-09-03 2001-03-15 Avery Dennison Corporation Procede permettant d'ameliorer la distribution de constructions d'etiquettes par decollement par plaque
US20040013890A1 (en) * 2002-07-18 2004-01-22 John Kovalchuk Multilayered film
EP1508439A1 (fr) * 2003-08-16 2005-02-23 Renolit AG Film multicouche pour la fabrication d'étiquettes
WO2008011402A1 (fr) * 2006-07-17 2008-01-24 Avery Dennison Corporation Film polymère multicouches asymétrique ainsi que matériau pour étiquettes et étiquettes formés à partir dudit film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001017775A1 (fr) * 1999-09-03 2001-03-15 Avery Dennison Corporation Procede permettant d'ameliorer la distribution de constructions d'etiquettes par decollement par plaque
US20040013890A1 (en) * 2002-07-18 2004-01-22 John Kovalchuk Multilayered film
EP1508439A1 (fr) * 2003-08-16 2005-02-23 Renolit AG Film multicouche pour la fabrication d'étiquettes
WO2008011402A1 (fr) * 2006-07-17 2008-01-24 Avery Dennison Corporation Film polymère multicouches asymétrique ainsi que matériau pour étiquettes et étiquettes formés à partir dudit film

Similar Documents

Publication Publication Date Title
EP2874812B1 (fr) Support d'étiquette
US20150190988A1 (en) Label facestock
US20140134430A1 (en) Label facestock
US8383246B2 (en) Polypropylene-based shrink films
KR102299068B1 (ko) 내스커프성, 투명성 및 순응성이 개선된 필름
US20150279245A1 (en) Part of a package
WO2001038434A1 (fr) Film etire a base de resine et son procede de fabrication
EP2874813B1 (fr) Support d'étiquette
EP2874814B1 (fr) Support d'étiquette
WO2014013136A1 (fr) Procédé de fabrication d'une pellicule adhésive d'étiquette
WO2014013134A1 (fr) Procédé de traitement d'une pellicule adhésive d'étiquette
EP2599628B1 (fr) Films en plastique
US10532533B2 (en) Adhesive label, facestock for an adhesive label and adhesive label laminate
EP3619039B1 (fr) Matériau adhésif multicouche à usage alimentaire
JP2001214013A (ja) 樹脂延伸フィルムおよびその製造方法
JP7213400B1 (ja) 熱収縮性フィルム
WO2023013467A1 (fr) Film thermorétractable
JP2001192470A (ja) 樹脂延伸フィルムおよびその製造方法
WO2015092116A1 (fr) Substrat antiadhésif protecteur, stratifié d'étiquette comprenant un substrat antiadhésif protecteur, et procédé pour produire un stratifié d'étiquette
WO2014053707A1 (fr) Partie d'emballage
WO2014177754A1 (fr) Film pour étiquette, stratifié pour étiquette et procédé de fabrication d'un stratifié pour étiquette
WO2001012704A1 (fr) Film etire a base de resine et procede de fabrication
KR20070104317A (ko) 이축연신 폴리프로필렌 필름

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13747428

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13747428

Country of ref document: EP

Kind code of ref document: A1