WO2014001412A3 - Katalysatorbeschichtung und verfahren für die umwandlung von oxygenaten zu olefinen - Google Patents

Katalysatorbeschichtung und verfahren für die umwandlung von oxygenaten zu olefinen Download PDF

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Publication number
WO2014001412A3
WO2014001412A3 PCT/EP2013/063436 EP2013063436W WO2014001412A3 WO 2014001412 A3 WO2014001412 A3 WO 2014001412A3 EP 2013063436 W EP2013063436 W EP 2013063436W WO 2014001412 A3 WO2014001412 A3 WO 2014001412A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxygenates
olefins
conversion
catalyst
catalyst coating
Prior art date
Application number
PCT/EP2013/063436
Other languages
English (en)
French (fr)
Other versions
WO2014001412A2 (de
Inventor
Kirsten SPANNHOFF
Florina Corina Patcas
Ekkehard Schwab
Alexander Weck
Kerem Bay
Matthias MIELKE
Oliver Seel
Original Assignee
Basf Se
Basf Schweiz Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Basf Schweiz Ag filed Critical Basf Se
Priority to JP2015519079A priority Critical patent/JP6466325B2/ja
Priority to AU2013283349A priority patent/AU2013283349B2/en
Priority to EP13732467.9A priority patent/EP2866934A2/de
Priority to RU2015102718A priority patent/RU2015102718A/ru
Priority to CN201380042077.9A priority patent/CN104582841A/zh
Priority to MX2014015736A priority patent/MX2014015736A/es
Priority to CA2877796A priority patent/CA2877796C/en
Priority to BR112014031094A priority patent/BR112014031094A8/pt
Publication of WO2014001412A2 publication Critical patent/WO2014001412A2/de
Publication of WO2014001412A3 publication Critical patent/WO2014001412A3/de
Priority to ZA2015/00361A priority patent/ZA201500361B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Die vorliegende Erfindung betrifft einen Katalysator für die Umwandlung von Oxygenaten zu Olefinen umfassend - ein Trägersubstrat und - eine auf das Substrat aufgebrachte Schicht, wobei die Schicht ein oder mehrere Zeolithe vom MFI, MEL und/oder vom MWW-Strukturtyp enthält, wobei der eine oder die mehreren Zeolithe ein oder mehrere Erdalkalimetalle enthalten, dessen Herstellung und Verwendung, sowie ein Verfahren zur Umwandlung von Oxygenaten zu Olefinen unter Verwendung des Katalysators.
PCT/EP2013/063436 2012-06-29 2013-06-26 Katalysatorbeschichtung und verfahren für die umwandlung von oxygenaten zu olefinen WO2014001412A2 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP2015519079A JP6466325B2 (ja) 2012-06-29 2013-06-26 オキシジェネートからオレフィンへの転化のための触媒コーティングおよび方法
AU2013283349A AU2013283349B2 (en) 2012-06-29 2013-06-26 Catalyst coating and method for the conversion of oxygenates to olefins
EP13732467.9A EP2866934A2 (de) 2012-06-29 2013-06-26 Katalysatorbeschichtung und verfahren für die umwandlung von oxygenaten zu olefinen
RU2015102718A RU2015102718A (ru) 2012-06-29 2013-06-26 Покрытый катализатор и способ превращения оксигенатов в олефины
CN201380042077.9A CN104582841A (zh) 2012-06-29 2013-06-26 将氧合物转化成烯烃的催化剂涂层和方法
MX2014015736A MX2014015736A (es) 2012-06-29 2013-06-26 Recubrimiento de catalizador y proceso para la conversión de oxigenatos en olefinas.
CA2877796A CA2877796C (en) 2012-06-29 2013-06-26 Catalyst coating and process for the conversion of oxygenates to olefins
BR112014031094A BR112014031094A8 (pt) 2012-06-29 2013-06-26 catalisador para conversão de oxigenados em olefinas, processo para a sua preparação e usos relacionados
ZA2015/00361A ZA201500361B (en) 2012-06-29 2015-01-19 Catalyst coating and method for the conversion of oxygenates to olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12174293.6 2012-06-29
EP12174293 2012-06-29

Publications (2)

Publication Number Publication Date
WO2014001412A2 WO2014001412A2 (de) 2014-01-03
WO2014001412A3 true WO2014001412A3 (de) 2014-02-27

Family

ID=48703493

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/063436 WO2014001412A2 (de) 2012-06-29 2013-06-26 Katalysatorbeschichtung und verfahren für die umwandlung von oxygenaten zu olefinen

Country Status (10)

Country Link
EP (1) EP2866934A2 (de)
JP (1) JP6466325B2 (de)
CN (2) CN109453804A (de)
AU (1) AU2013283349B2 (de)
BR (1) BR112014031094A8 (de)
CA (1) CA2877796C (de)
MX (1) MX2014015736A (de)
RU (1) RU2015102718A (de)
WO (1) WO2014001412A2 (de)
ZA (1) ZA201500361B (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
US9682367B2 (en) 2014-10-22 2017-06-20 King Fahd University Of Petroleum And Minerals Monolith structure loaded with metal promoted nanozeolites for enhanced propylene selectivity in methanol conversion
US9675971B2 (en) 2014-10-22 2017-06-13 King Fahd University Of Petroleum And Minerals Honeycomb monolith structure loaded with nanozeolites for enhanced propylene selectivity in methanol conversion
CN111760589A (zh) * 2020-07-10 2020-10-13 大唐国际化工技术研究院有限公司 分子筛催化剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD238733A1 (de) * 1984-12-29 1986-09-03 Leuna Werke Veb Herstellung selektiver olefinkatalysatoren
US20090048093A1 (en) * 2006-09-19 2009-02-19 Nippon Soken, Inc. Carbon-based material combustion catalyst, manufacturing method of the same, catalyst carrier, and manufacturing method of the same

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
DE2830787B2 (de) 1978-07-13 1981-02-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von stickstoffhaltigen kirstallinen Metallsilikaten mit Zeolithstniktur
DE3006471A1 (de) 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
JPS6251630A (ja) * 1985-08-29 1987-03-06 Agency Of Ind Science & Technol 低級オレフインの製造方法
US4692423A (en) 1985-12-04 1987-09-08 Mobil Oil Corporation Method for preparing structured catalytic solids
DE4009459A1 (de) * 1990-03-23 1991-09-26 Metallgesellschaft Ag Verfahren zur erzeugung von niederen olefinen
ATE339249T1 (de) 1993-04-23 2006-10-15 Exxonmobil Res & Eng Co Molekularsiebschichten und verfahren zu ihrer herstellung
JPH07241471A (ja) * 1994-03-04 1995-09-19 Nissan Motor Co Ltd 排ガス浄化用吸着触媒の製造方法
JP3498410B2 (ja) * 1995-03-07 2004-02-16 日産自動車株式会社 排気ガス浄化用触媒
US5925800A (en) 1996-12-31 1999-07-20 Exxon Chemical Patents Inc. Conversion of oxygenates to hydrocarbons with monolith supported non-zeolitic molecular sieve catalysts
JP2005514319A (ja) * 2002-10-24 2005-05-19 エクソンモービル・ケミカル・パテンツ・インク 酸触媒の安定化
NZ550026A (en) * 2004-03-22 2009-10-30 Celgene Corp Methods of using and compositions comprising immunomodulatory compounds for the treatment and management of skin diseases or disorders
JP2008080301A (ja) * 2006-08-30 2008-04-10 Jgc Corp アルカリ土類金属化合物含有ゼオライト触媒およびその調製方法、並びに、低級炭化水素の製造方法
CN101239875B (zh) * 2007-02-07 2010-11-10 中国石油化工股份有限公司 由甲醇制取丙烯的方法
CN102802792A (zh) * 2009-06-22 2012-11-28 日挥株式会社 低级烯烃制造用催化剂及使用其制造低级烯烃的方法
EP2335810B1 (de) * 2009-12-11 2012-08-01 Umicore AG & Co. KG Selektive katalytische Reduktion von Stickoxiden im Abgas von Dieselmotoren
BR112014031391B1 (pt) * 2012-06-29 2020-12-08 Basf Se processos para a preparação de um catalisador para a conversão de oxigenados em olefinas

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD238733A1 (de) * 1984-12-29 1986-09-03 Leuna Werke Veb Herstellung selektiver olefinkatalysatoren
US20090048093A1 (en) * 2006-09-19 2009-02-19 Nippon Soken, Inc. Carbon-based material combustion catalyst, manufacturing method of the same, catalyst carrier, and manufacturing method of the same

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
ANTIA ET AL., IND. ENG. CHEM. RES., vol. 34, 1995, pages 140 - 147, XP002717446 *
BAIBINGYANG: "Preparation of Modified ZSM-5/Cordierite Monolithic Catalyst and Their Catalytic Performance of Methanol to Olefin", 1 January 2011 (2011-01-01), XP002717228, Retrieved from the Internet <URL:http://www.dissertationtopic.net/doc/180504> [retrieved on 20131204] *
CIAMBELLI ET AL.: "Successful Design of Catalysts", 1988, ELSEVIER SCIENCE PUBLISHERS, article "Acid-base catalysis in the conversion of methanol to olefins over Mg- modified ZSM-5 zeolite", pages: 239 - 246, XP002717443 *
GORYAINOVA ET AL., PETROLEUM CHEMISTRY, vol. 51, no. 3, 2011, pages 169 - 173, XP002717442 *
MCLNTOSH ET AL., APPLIED CATALYSIS, vol. 6, 1983, pages 307 - 314, XP002717445 *
OKADO ET AL., APPLIED CATALYSIS, vol. 41, 1988, pages 121 - 135, XP002717444 *

Also Published As

Publication number Publication date
CA2877796C (en) 2020-06-30
CN109453804A (zh) 2019-03-12
WO2014001412A2 (de) 2014-01-03
MX2014015736A (es) 2015-09-04
CA2877796A1 (en) 2014-01-03
BR112014031094A2 (pt) 2017-06-27
AU2013283349A1 (en) 2015-01-22
JP2015522408A (ja) 2015-08-06
ZA201500361B (en) 2016-03-30
CN104582841A (zh) 2015-04-29
EP2866934A2 (de) 2015-05-06
AU2013283349B2 (en) 2017-05-04
RU2015102718A (ru) 2016-08-20
JP6466325B2 (ja) 2019-02-06
BR112014031094A8 (pt) 2021-01-26

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