WO2013190976A1 - Conveyor belt - Google Patents

Conveyor belt Download PDF

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Publication number
WO2013190976A1
WO2013190976A1 PCT/JP2013/065159 JP2013065159W WO2013190976A1 WO 2013190976 A1 WO2013190976 A1 WO 2013190976A1 JP 2013065159 W JP2013065159 W JP 2013065159W WO 2013190976 A1 WO2013190976 A1 WO 2013190976A1
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WO
WIPO (PCT)
Prior art keywords
rubber
conveyor belt
flame retardant
parts
belt
Prior art date
Application number
PCT/JP2013/065159
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French (fr)
Japanese (ja)
Inventor
寛之 尻池
健 桑鶴
Original Assignee
バンドー化学株式会社
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Filing date
Publication date
Application filed by バンドー化学株式会社 filed Critical バンドー化学株式会社
Priority to JP2014521263A priority Critical patent/JPWO2013190976A1/en
Publication of WO2013190976A1 publication Critical patent/WO2013190976A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G15/00Conveyors having endless load-conveying surfaces, i.e. belts and like continuous members, to which tractive effort is transmitted by means other than endless driving elements of similar configuration
    • B65G15/30Belts or like endless load-carriers
    • B65G15/32Belts or like endless load-carriers made of rubber or plastics
    • B65G15/38Belts or like endless load-carriers made of rubber or plastics with flame-resistant layers, e.g. of asbestos, glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K3/2279Oxides; Hydroxides of metals of antimony
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00Fireproofing materials

Definitions

  • the present invention relates to a conveyor belt that is used for transporting the transported object through a transport path on which a transported object is placed on the surface and surrounded by the periphery.
  • a belt conveyor has been widely used as a conveying device for articles and the like, and various characteristics corresponding to applications are required for a conveyor belt that is a main component of the belt conveyor.
  • a conveyor belt is required to have flame retardancy depending on the application.
  • Patent Document 1 listed below has excellent flame retardancy for a conveyor belt by forming a cover rubber with a flame retardant rubber composition exhibiting a high oxygen index. It is described that it is given.
  • the conveyor belt is also widely used in ore mining sites and the like.
  • the conveyor belt is used to transport coal through a tunnel surrounded by a rock or the like in a coal mine.
  • the said conveyor belt is utilized in the environment where the circumference
  • it is difficult to visually recognize the traveling state of the conveyor belt during the conveyance directly from the outside. Therefore, for example, even if a situation occurs in the middle of the conveyance path that causes the conveyor belt to slidably contact with an inner wall surface of a tunnel or a pipe body or other members constituting the belt conveyor for some reason, It is hard to be found early.
  • the present invention is a conveyor belt that is used to transport a transported object through a transport path in which a transported object is placed on the surface and surrounded by the surface, and the surface side that constitutes the surface
  • At least one of the cover rubber and the back surface side cover rubber constituting the back surface opposite to the front surface is formed of a flame retardant rubber composition
  • the flame retardant rubber composition includes a base rubber, Containing a flame retardant and montmorillonite particles, containing at least one chloroprene rubber as the base rubber, containing aluminum hydroxide, antimony trioxide, and chlorinated paraffin as the flame retardant, the base
  • gum is 3 mass parts or more and 30 mass parts or less
  • the conveyor belt characterized by the above-mentioned is provided.
  • At least one of the front side cover rubber and the back side cover rubber is formed of a flame retardant rubber composition having excellent flame retardancy, and frictional heat is generated in the flame retardant rubber composition. Montmorillonite particles effective for prevention are contained. Therefore, the conveyor belt of the present invention can suppress the generation of frictional heat in the cover rubber, and can suppress the cover rubber from smoking and igniting.
  • FIG. 2 is a cross-sectional view taken along line XX in FIG. 1 showing a schematic cross-sectional structure of a conveyor belt according to an embodiment. Schematic showing the Australian standard test method implemented to rank the heat generation temperature due to friction. The graph showing the test result of the standard.
  • FIG. 1 is a diagram schematically showing a method of using a belt conveyor provided with the conveyor belt of the present embodiment
  • FIG. 2 is a cross-sectional structure taken along the line XX indicated by a broken line in FIG. It is arrow sectional drawing which showed schematically.
  • FIG. 1 shows a state of the belt conveyor 1 in which the conveyor belt 10 of the present embodiment formed in an endless shape is arranged so as to have a constant upward gradient from the right side to the left side when viewed from the front in FIG.
  • symbol 100 and was typically shown from the conveyance direction side is shown.
  • the belt conveyor 1 of the present embodiment includes the conveyor belt 10 and pulleys 20 arranged on one end side (loading side) and the other end side (unloading side) in the longitudinal direction of the transport path (tunnel). .
  • the conveyor belt 10 is provided between the pulley 20 and the belt conveyor 1.
  • the unloading pulley 20 is a driving pulley 21 connected to a driving source.
  • Another pulley 20 arranged on the stacking side is a driven pulley 22 that rotates together with the endless conveyor belt 10 circulated by the drive pulley 21.
  • the belt conveyor 1 further includes support rollers 30 disposed at a plurality of locations between the drive pulley 21 and the driven pulley 22.
  • the belt conveyor 1 includes a plurality of forward path side support rollers 30a that support the conveyor belt 10 from the back surface side in a transport path (forward path) from the loading side to the unloading side.
  • the belt conveyor 1 has its outer peripheral surface in contact with the surface of the conveyor belt 10 that faces downward in a path (return path) from the unloading side to the loading side so that the conveyor belt 10 And a plurality of return-path-side support rollers 30b.
  • the driving pulley 21, the driven pulley 22, and the plurality of forward-side support rollers 30a are arranged at their respective upper ends while their rotational axes are arranged in parallel to each other so as to support the conveyor belt 10 in the outward path with a substantially constant inclination.
  • three outward support rollers 30a are arranged at one support location, the conveyor belt 10 is curved in the width direction, and the conveyor belt 10 is formed in a bowl shape in the entire outward path. It is arranged to run.
  • the three forward path support rollers 30a are arranged side by side with the rotation axis extending in the width direction of the conveyor belt 10, and of the three forward path support rollers 30a, two forward path side support rollers are provided.
  • the rollers 30a are inclined and arranged so as to rise outward in the belt width direction in order to lift both side edges of the conveyor belt 10.
  • the plurality of the return path side support rollers 30b are arranged so that their rotation axes are parallel to each other so that the conveyor belt 10 on the return path can be supported at a substantially constant inclination, and the vertical position of the upper end portion is lowered to the right in FIG. It is provided in the belt conveyor 1 so as to be.
  • the conveyor belt 10 in this embodiment is formed in the shape of a flat belt which is not provided with a horizontal beam crossing in the belt width direction and an ear beam standing along both side edges of the belt.
  • the conveyor belt 10 in this embodiment is a cover rubber 11 which forms the surface side (outer peripheral side) of the conveyor belt 10 in which coal A is mounted, and the surface on the opposite side to the surface in which the said coal A is mounted.
  • a two-layer cover rubber 11 with a cover rubber 11 constituting the back surface is provided.
  • the conveyor belt 10 further includes a canvas layer 12 in which a canvas for imparting tensile strength to the conveyor belt is embedded inside the two layers of cover rubber 11.
  • the conveyor belt 10 of this embodiment is used to transport the coal A through a transport path in which the transported object is coal A as described above and the tunnel 100 is surrounded. Since the dust discharged from the coal A is easily filled in the mine shaft, the support roller 30 may interfere with smooth rotation because the dust enters a bearing or the like. Moreover, the said support roller 30 has a possibility of becoming a state which cannot be rotated with dust depending on the case. And, normally, while the conveyor belt 10 is running, it should generate only a small frictional heat due to rolling friction between the conveyor belt 10 and the support roller 30, but when the support roller 30 stops rotating, Frictional heat due to sliding friction is generated between the conveyor belt 10 and the support roller 30. Usually, the sliding friction coefficient (dynamic friction coefficient) is 2 to 3 digits or more larger than the rolling friction coefficient, so that if the support roller 30 is unable to rotate, there is a risk of generating a great amount of frictional heat.
  • the conveyor belt 10 since the coal A is loaded in the forward path, the conveyor belt 10 is in a state in which a large load is applied between the back surface thereof and the outer peripheral surface of the roller 30, and the support roller 30 becomes unable to rotate.
  • the back surface is heated to a high temperature by frictional heat, and in some cases, there is a risk of smoking or ignition.
  • the conveyor belt 10 includes a front cover rubber 11 (hereinafter also referred to as “front cover rubber 11a”) and a back cover rubber 11 (hereinafter also referred to as “back cover rubber 11b”). It is preferable to form at least the back rubber 11b on the inside in a state excellent in flame retardancy and slipperiness.
  • the back side cover rubber 11b is made of a flame retardant rubber composition containing a flame retardant and a slipperiness imparting agent in addition to the base rubber. What is necessary is just to form.
  • the rubber (base rubber) serving as a base of the flame retardant rubber composition may be one or more types of chloroprene rubber. is important. More specifically, the flame retardant rubber composition of the present embodiment contains a base rubber (A) composed of one or more chloroprene rubbers and a flame retardant (B), and aluminum hydroxide is used as the flame retardant.
  • the flame retardant rubber composition may further contain a general rubber chemical (D) such as a vulcanizing agent.
  • the base rubber constituting the flame retardant rubber composition may be a single type of rubber or a mixed rubber obtained by mixing a plurality of types of rubber, but at least chloroprene rubber should be contained. is important.
  • This chloroprene rubber is excellent in flame retardancy by containing chlorine, which can be expected to have a radical scavenging action, in the molecule.
  • radicals generated by molecular chain scission promote further molecular scission and promote thermal decomposition.
  • chloroprene rubber captures radicals and stabilizes them. Degradation can be made gradual.
  • the chloroprene rubber since the chloroprene rubber generates nonflammable hydrogen chloride as the pyrolysis gas, it has an action of quickly shutting off the supply of oxygen to the conveyor belt that has started combustion with the pyrolysis gas and extinguishing the flame. In this respect, it is important that the flame retardant rubber composition contains chloroprene rubber.
  • the chloroprene rubber is not particularly limited, and examples thereof include those commercially available from Showa Denko Co., Ltd. under the product names “Showrene W”, “Showrene WM1”, “Showrene G”, and “Denka Chloroprene”. PM-40 ",” Denkachloroprene S-41 "and other” Denkachloroprene "series names commercially available from Denki Kagaku Kogyo Co., Ltd. are used alone, or a plurality of these are included in the base rubber. be able to.
  • the base rubber can contain a small amount of rubber other than the chloroprene rubber, for example, chlorinated polyethylene such as chlorinated polyethylene and chlorosulfonated polyethylene that can be expected to have the same function as chloroprene. You may let them.
  • chlorinated polyethylene such as chlorinated polyethylene and chlorosulfonated polyethylene that can be expected to have the same function as chloroprene. You may let them.
  • non-chlorine rubbers such as natural rubber and ethylene / ⁇ -olefin rubber can be contained as a part of the base rubber.
  • the ratio of the non-chlorine rubber to the base rubber is preferably 20% by mass or less.
  • the content is more preferably 10% by mass or less, and particularly preferably 5% by mass or less.
  • the base rubber is most preferably composed of only a chlorinated rubber.
  • the proportion of the other chlorinated rubber in the total of the chloroprene rubber and the other chlorinated rubber is preferably 20% by mass or less. % Or less, more preferably 5% by mass or less.
  • (B) Flame retardant (B1) Aluminum hydroxide
  • the aluminum hydroxide exhibits a dehydration reaction at a temperature lower than the thermal decomposition start temperature (about 300 ° C.) of general polymers such as chloroprene rubber, and the dehydration reaction is endothermic. Because it is a reaction, it has the effect of lowering the temperature of the flame retardant rubber composition during the thermal decomposition of the flame retardant rubber composition, and is an important component for imparting flame resistance to the conveyor belt.
  • Aluminum hydroxide also works effectively to form a heat-insulating coating with char during combustion, for example, when the back cover rubber is heated above the thermal decomposition temperature by frictional heat with the support roller. Then, char can be formed on the surface of the cover rubber to prevent the heat generated on the surface from being transmitted to the inside in the thickness direction.
  • the aluminum hydroxide is not particularly limited, but, for example, those having a relatively small particle diameter and a large specific surface area with a median diameter of about 2 ⁇ m or less have superior mechanical properties as a flame-retardant rubber composition. It is advantageous for exhibiting excellent flame retardancy.
  • Such fine aluminum hydroxide having a particle diameter is commercially available from Showa Denko KK under the series name of “Hijilite” such as “Hijilite H-42” and “Hijilite H-43M”. Things.
  • the aluminum hydroxide is more advantageous in terms of flame retardancy as the content in the flame retardant rubber composition is larger.
  • the mechanical properties of the cover rubber formed by the flame retardant rubber composition are increased. There is a risk of deteriorating the characteristics. Therefore, the flame retardant rubber composition is water-soluble at a ratio of 30 parts by mass or more and 60 parts by mass or less with respect to 100 parts by mass of the base rubber in that the flame retardancy and mechanical properties can be exhibited in a balanced manner. It is preferable to contain aluminum oxide.
  • antimony trioxide exhibits little flame retardancy by itself, and has a function of improving the flame retardant effect of the flame retardant when used in combination with a halogen-based flame retardant such as chlorinated paraffin.
  • antimony trioxide Sb 2 O 3
  • antimony (SbOCl) or antimony trichloride (SbCl 3 ) water vapor is generated and oxygen is blocked.
  • the antimony trioxide is a commercial product marketed by Nippon Seiko Co., Ltd. under the product name “PATOX-M”, “PATOX-K”, etc. It can be a commercial product commercially available from the company.
  • the flame retardant rubber composition usually has an antimony trioxide ratio of 1 to 15 parts by mass, preferably 2 to 10 parts by mass with respect to 100 parts by mass of the base rubber. Can be contained.
  • the chlorinated paraffin is commercially available from Ajinomoto Fine Techno Co., Ltd. under the series name “Empara” such as “Empara 40”, “Empara 70”, “Empara K-45”, etc. And those commercially available from Tosoh Corporation under the “Toyoparax” series name.
  • the flame-retardant rubber composition can usually contain the chlorinated paraffin at a ratio of 10 parts by mass to 30 parts by mass with respect to 100 parts by mass of the base rubber.
  • (M + .M 1/2 2+ ) y nH 2 O (However, y usually represents a value of 0.2 to 0.6, M represents an exchangeable cation and represents Na, K, Ca, Mg, H, etc. n represents interlayer water. A number representing the quantity.) More specifically, montmorillonite having the following chemical formula is known.
  • Na.Ca 0.33
  • Al 1.67 Mg 0.33 Si 4 O 10 (OH) 2 .nH 2 O
  • the montmorillonite particles have an effect of causing delamination on the surface of the cover rubber and exhibiting excellent slipperiness on the conveyor belt.
  • montmorillonite particles those having a particle size of 2 ⁇ m or less when dispersed in the cover rubber are preferable.
  • “Bengel HVP” and other “Bengel” series names are commercially available from Hojun Co. Organic processed products marketed under the series name "can be used.
  • the montmorillonite particles are added in a proportion of 3 to 30 parts by mass with respect to 100 parts by mass of the base rubber. It is important to include in the composition.
  • the flame retardant rubber composition has 5 parts by mass or more and 15 parts by mass of the montmorillonite particles with respect to 100 parts by mass of the base rubber, in order to more effectively exhibit the effects of slipperiness and wear resistance. It is preferable to contain it in the ratio below the part.
  • the rubber chemicals include, for example, vulcanizing agents such as sulfur and organic peroxides; vulcanization accelerators such as sulfenamide compounds and thiazole compounds, fillers, softeners, Examples include aging inhibitors and processability improvers.
  • the flame retardant rubber composition may contain a flame retardant other than the above, if necessary.
  • the flame retardant rubber composition may contain particles made of layered clay minerals such as mica, clay, talc, etc. as a slipperiness imparting agent other than the montmorillonite particles, if necessary.
  • the conveyor belt may be formed of the flame retardant rubber composition so as to impart flame retardancy to both sides, similarly to the back side cover rubber 11b.
  • the flame-retardant rubber composition used for forming the back-side cover rubber 11b and the front-side cover rubber 11a may have the same content or different content.
  • the canvas for forming the canvas layer 12 is not particularly limited, and a canvas used for a general conveyor belt can be used in this embodiment.
  • the manufacturing method of the conveyor belt of this embodiment is not particularly limited, and can be manufactured in the same manner as a general conveyor belt.
  • the conveyor belt is prepared, for example, by kneading a flame retardant rubber composition for a cover rubber using a Banbury mixer, a kneader mixer, a roll or the like, and then making the flame retardant rubber composition into a sheet using a calendar or the like.
  • An unvulcanized sheet for cover rubber can be produced, and the unvulcanized sheet and canvas can be integrated by vulcanization.
  • a rubberized canvas is prepared, and the canvas is further sandwiched from outside by an unvulcanized sheet for cover rubber, and “unvulcanized sheet for cover rubber / canvas / unvulcanized for cover rubber”.
  • a laminated body laminated in the order of “sulfur sheet” is formed, and the laminated body can be produced by vulcanization integration using a hot press.
  • the conveyor belt of the present invention is exemplified. Is effective even in cases where materials other than coal are transported through the inside of a tubular body such as a concrete pipe or an iron pipe. That is, the conveyor belt in such an application is also intended as the conveyor belt of the present invention.
  • the conveyor belt of the present invention is not limited to the one supported and used by the support roller, and the object for imparting flame retardancy and slipperiness is not limited to the back side cover rubber. . That is, a conveyor belt in which the flame retardant rubber composition containing the montmorillonite particles on which the conveyed product is placed is used only for the formation of the surface side cover rubber is also within the range intended as the conveyor belt of the present invention. It is.
  • the conveyor belt of the present invention is not limited to the flat belt illustrated in the present embodiment, but also has a cross rail that traverses in the belt width direction and a belt that has ear rails erected along both side edges. It is the range which is intended as the conveyor belt of this invention.
  • a conveyor belt of the present invention it is a matter of course that the conveyor belt exemplified in the embodiment may be modified in various ways other than the above.
  • Table 1 shows the abbreviations and specific contents of the raw materials used in the evaluation.
  • Samples for evaluation were prepared using a flame retardant rubber composition containing the above raw materials in the blending ratio shown in Table 2, and each evaluation was performed.
  • the evaluation was performed using an apparatus as shown in FIG. 3 defined in the same standard. That is, one end in the longitudinal direction of a belt-shaped sample 10x having a cover rubber formed of the flame-retardant rubber composition shown in Table 2 is fixed to the vertical wall WL, and the belt-shaped sample 10x is moved horizontally away from the fixed position. And a rotary drum TD having a diameter of 212.8 mm disposed so that the rotation axis is orthogonal to the longitudinal direction of the belt-shaped sample 10x at a position away from the vertical wall WL. The belt-shaped sample 10x is extended in the horizontal direction so that the belt-shaped sample 10x is wound around the outer peripheral surface of the rotating drum TD halfway and further approaches the vertical wall WL.
  • the evaluation was performed by generating a tension of 35 kgf from one end in the length direction fixed to the vertical wall WL to the other end where the load was set.
  • the evaluation was performed by rotating the rotating drum TD at a rotation speed of 190.2 rpm using the motor MT in the above-described state. At this time, the rotating drum TD was rotated so that the upper end side thereof moved away from the vertical wall WL. Then, the highest temperature reached by the surface temperature of the belt-like sample 10x (the temperature of the surface in contact with the rotating drum TD) at the position in contact with the rotating drum TD during the test time of about 2 hours was measured.
  • FIGS. 4A to 4D are charts showing how the temperature of the belt-like sample has changed over time, and the friction coefficient (lower chart) calculated based on the temperature (upper chart) is also shown. It is also shown. Also from this chart and the results shown in Table 2, it can be seen that according to the present invention, it is possible to obtain a conveyor belt which is excellent in sliding property and generation of frictional heat is suppressed.
  • the evaluation samples were ranked in wear resistance by the DIN abrasion test of JIS K6264-2 “Vulcanized rubber and thermoplastic rubber—How to obtain abrasion resistance—Part 2: Test method”.
  • the case where the wear amount of DIN wear was less than 200 mm 3 was ranked “A”
  • the case where the wear amount was 250 mm 3 or more and less than 300 mm 3 was ranked “C”
  • Table 2 The results are also shown in Table 2 above. From this result, it can be seen that according to the present invention, a conveyor belt excellent in slipperiness can be obtained.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Belt Conveyors (AREA)
  • Structure Of Belt Conveyors (AREA)

Abstract

The present invention is a conveyor belt to carry transport goods through a transport path, wherein the invention is characterized in that at least one of a front face cover rubber and a back face cover rubber is formed from a flame-resistant rubber composition, and the flame-resistant rubber composition contains no less than 3 parts by weight and no more than 30 parts by weight of montmorillonite particles with respect to 100 parts by weight of a base rubber containing chloroprene. The generation of frictional heat in the conveyor belt can be suppressed by way of this configuration.

Description

コンベヤベルトConveyor belt
 本発明は、表面に搬送物が載置され、周囲が囲われた搬送路を通じて前記搬送物を搬送すべく用いられるコンベヤベルトに関する。 The present invention relates to a conveyor belt that is used for transporting the transported object through a transport path on which a transported object is placed on the surface and surrounded by the periphery.
 ベルトコンベヤは、従来、物品等の搬送装置として広く用いられており、該ベルトコンベヤの主要構成部材であるコンベヤベルトには、用途に応じた種々の特性が求められている。
 例えば、コンベヤベルトは、用途によって難燃性が求められ、下記特許文献1には、高い酸素指数を示す難燃性ゴム組成物でカバーゴムを形成させることでコンベヤベルトに優れた難燃性を付与させることが記載されている。
BACKGROUND ART Conventionally, a belt conveyor has been widely used as a conveying device for articles and the like, and various characteristics corresponding to applications are required for a conveyor belt that is a main component of the belt conveyor.
For example, a conveyor belt is required to have flame retardancy depending on the application. Patent Document 1 listed below has excellent flame retardancy for a conveyor belt by forming a cover rubber with a flame retardant rubber composition exhibiting a high oxygen index. It is described that it is given.
日本国特開2009-249459号公報Japanese Unexamined Patent Publication No. 2009-249459
 前記コンベヤベルトは、鉱石の採掘現場などにおいても広く用いられており、例えば、炭鉱などにおいて岩盤等によって周囲が囲われた坑道を通じて石炭を搬送すべく用いられたりしている。
 また、前記コンベヤベルトは、坑道以外にも、周囲が囲われた環境で利用されており、例えば、管体内に設置されて物品の搬送に利用されたりしている。
 このような場合には、搬送途中におけるコンベヤベルトの走行状況は、外部から直接視認することが難しい。
 そのため、当該コンベヤベルトは、例えば、何等かの原因で坑道や管体の内壁面やベルトコンベヤを構成する他の部材と摺接するような状況が搬送路の途中において生じたとしても、そのことが早期に見出され難い。
The conveyor belt is also widely used in ore mining sites and the like. For example, the conveyor belt is used to transport coal through a tunnel surrounded by a rock or the like in a coal mine.
Moreover, the said conveyor belt is utilized in the environment where the circumference | surroundings were enclosed besides the tunnel, for example, it is installed in the pipe body and is utilized for conveyance of articles | goods.
In such a case, it is difficult to visually recognize the traveling state of the conveyor belt during the conveyance directly from the outside.
Therefore, for example, even if a situation occurs in the middle of the conveyance path that causes the conveyor belt to slidably contact with an inner wall surface of a tunnel or a pipe body or other members constituting the belt conveyor for some reason, It is hard to be found early.
 このような点については、従来、特に重要視がなされてはいなかったが、本発明者は、この点に着目してコンベヤベルトの搬送路における状況を解析した。
 その結果、本発明者は、石炭など粉塵を発生させ易いような物を搬送する場合には、前記粉塵がコンベヤベルトを裏面側から支持するローラーのベアリングに噛み込むなどして該ローラーの回転を不良にさせ易いことを見出した。
 そして、本発明者は、回転不良となったローラーとコンベヤベルトとの間に生じる摩擦熱によってコンベヤベルトに発煙、発火を生じさせるおそれを有することを見出した。
Conventionally, this point has not been particularly important, but the present inventor has analyzed the situation of the conveyor belt in the conveyance path, paying attention to this point.
As a result, the present inventor, when transporting an object that easily generates dust such as coal, rotates the roller by, for example, biting the dust into a roller bearing that supports the conveyor belt from the back side. We found that it was easy to make it defective.
And this inventor discovered that there exists a possibility of producing smoke and a fire on a conveyor belt by the frictional heat which arises between the roller which became poor rotation, and the conveyor belt.
 このような問題に対し、先の特許文献に記載されているようにカバーゴムを難燃化させるという対策は、コンベヤベルトの発煙、発火を防止する上で有効となる。
 本発明者は、発煙、発火の根本原因となる摩擦熱の発生を抑制させることが更に有効な手立てとなり得ることを見出した。
 しかし、従来、上記のような問題に対する十分な認識がなされていなかったためにコンベヤベルトにおける摩擦熱の発生防止方法は十分に検討されてはいない。
For such a problem, as described in the above-mentioned patent document, a measure to make the cover rubber flame-retardant is effective in preventing smoke and fire of the conveyor belt.
The present inventor has found that suppressing the generation of frictional heat, which is the root cause of smoke generation and ignition, can be a more effective measure.
Conventionally, however, the above-mentioned problem has not been sufficiently recognized, and therefore, a method for preventing the generation of frictional heat in the conveyor belt has not been sufficiently studied.
 なお、搬送路における状況把握が難しく、他の部材等との摺接によって発煙、発火を生じさせるおそれを有する点においては、管体などを通じて石炭以外の物を搬送する場合においても共通するものである。
 即ち、上記のような問題は、周囲が囲われた搬送路を通じて搬送物を搬送すべく用いられるコンベヤベルトに共通するものである。
 そして、本発明は、前記搬送路で用いられるコンベヤベルトにおける摩擦熱の発生を抑制させ、ひいてはコンベヤベルトに発煙、発火が生じることを防止することを課題としている。
In addition, in the point that it is difficult to grasp the situation in the conveyance path and that it may cause smoke and ignition by sliding contact with other members, etc., it is common even when things other than coal are conveyed through pipes etc. is there.
That is, the above problems are common to conveyor belts that are used for transporting a transported object through a transport path surrounded by the periphery.
And this invention makes it a subject to suppress generation | occurrence | production of the frictional heat in the conveyor belt used by the said conveyance path, and to prevent that a smoke and a fire arise in a conveyor belt by extension.
 本発明は、上記課題を解決すべく、表面に搬送物が載置され、周囲が囲われた搬送路を通じて前記搬送物を搬送すべく用いられるコンベヤベルトであって、前記表面を構成する表面側カバーゴムと、前記表面とは逆側の裏面を構成する裏面側カバーゴムとの内の少なくとも一方が難燃性ゴム組成物によって形成されており、該難燃性ゴム組成物は、ベースゴム、難燃剤、及び、モンモリロナイト粒子を含有し、前記ベースゴムとしてクロロプレンゴムの1種以上を含有し、前記難燃剤として水酸化アルミニウム、三酸化アンチモン、及び、塩素化パラフィンを含有しており、前記ベースゴム100質量部に対する前記モンモリロナイト粒子の割合が3質量部以上30質量部以下であることを特徴とするコンベヤベルトを提供する。 In order to solve the above-mentioned problems, the present invention is a conveyor belt that is used to transport a transported object through a transport path in which a transported object is placed on the surface and surrounded by the surface, and the surface side that constitutes the surface At least one of the cover rubber and the back surface side cover rubber constituting the back surface opposite to the front surface is formed of a flame retardant rubber composition, the flame retardant rubber composition includes a base rubber, Containing a flame retardant and montmorillonite particles, containing at least one chloroprene rubber as the base rubber, containing aluminum hydroxide, antimony trioxide, and chlorinated paraffin as the flame retardant, the base The ratio of the said montmorillonite particle with respect to 100 mass parts of rubber | gum is 3 mass parts or more and 30 mass parts or less, The conveyor belt characterized by the above-mentioned is provided.
 本発明においては、表面側カバーゴムと裏面側カバーゴムとの内の少なくとも一方が難燃性に優れた難燃性ゴム組成物で形成されるとともにこの難燃性ゴム組成物に摩擦熱の発生防止に有効なモンモリロナイト粒子が含有される。
 従って、本発明のコンベヤベルトは、前記カバーゴムに摩擦熱が発生することを抑制させることができ、該カバーゴムが発煙、発火することを抑制させることができる。
In the present invention, at least one of the front side cover rubber and the back side cover rubber is formed of a flame retardant rubber composition having excellent flame retardancy, and frictional heat is generated in the flame retardant rubber composition. Montmorillonite particles effective for prevention are contained.
Therefore, the conveyor belt of the present invention can suppress the generation of frictional heat in the cover rubber, and can suppress the cover rubber from smoking and igniting.
一実施形態のコンベヤベルトが備えられてなるベルトコンベヤの概略使用状態図。The general use state figure of the belt conveyor provided with the conveyor belt of one Embodiment. 一実施形態のコンベヤベルトの概略的な断面構造を示した図1のX-X線矢視断面図。FIG. 2 is a cross-sectional view taken along line XX in FIG. 1 showing a schematic cross-sectional structure of a conveyor belt according to an embodiment. 摩擦による発熱温度のランク付けをすべく実施した豪州規格の試験方法を表す概略図。Schematic showing the Australian standard test method implemented to rank the heat generation temperature due to friction. 同規格の試験結果を表すグラフ。The graph showing the test result of the standard.
 以下に、本発明の好ましい実施の形態について説明する。
 まず、添付図面に基づき、本実施形態のコンベヤベルトが用いられてなるベルトコンベヤについて、坑道を通じて石炭を搬送すべく用いられる場合を例に説明する。
The preferred embodiments of the present invention will be described below.
First, based on the attached drawings, a belt conveyor using the conveyor belt of the present embodiment will be described by taking as an example a case where it is used to transport coal through a tunnel.
 図1は、本実施形態のコンベヤベルトが備えられてなるベルトコンベヤの使用方法を概略的に示した図であり、図2は図1中に破線で示したX-X線による切断面の構造を概略的に示した矢視断面図である。 FIG. 1 is a diagram schematically showing a method of using a belt conveyor provided with the conveyor belt of the present embodiment, and FIG. 2 is a cross-sectional structure taken along the line XX indicated by a broken line in FIG. It is arrow sectional drawing which showed schematically.
 なお、図1は、無端状に形成された本実施形態のコンベヤベルト10が図1正面視右側から左側に向けて一定の昇り勾配となるように配されたベルトコンベヤ1の様子を表しており、符号100を付して模式的に示した坑道を通じて石炭Aを搬送する様子を搬送方向側方から見た状態を示すものである。
 本実施形態のベルトコンベヤ1は、前記コンベヤベルト10と、搬送路(坑道)の長手方向一端側(積載側)と他端側(荷下ろし側)とに配されたプーリー20とを備えている。
 前記コンベヤベルト10は、前記プーリー20の間に掛け渡されてベルトコンベヤ1に備えられている。
 なお、前記コンベヤベルト10が掛け渡されている一対のプーリー20の内の荷下ろし側のプーリー20は、駆動源に接続された駆動プーリー21である。
 積載側に配されたもう一つのプーリー20は、前記駆動プーリー21によって無端状のコンベヤベルト10が周回されることで共回りする従動プーリー22となっている。
FIG. 1 shows a state of the belt conveyor 1 in which the conveyor belt 10 of the present embodiment formed in an endless shape is arranged so as to have a constant upward gradient from the right side to the left side when viewed from the front in FIG. The state which sees the mode which conveys coal A through the mine shaft which attached | subjected the code | symbol 100 and was typically shown from the conveyance direction side is shown.
The belt conveyor 1 of the present embodiment includes the conveyor belt 10 and pulleys 20 arranged on one end side (loading side) and the other end side (unloading side) in the longitudinal direction of the transport path (tunnel). .
The conveyor belt 10 is provided between the pulley 20 and the belt conveyor 1.
Of the pair of pulleys 20 around which the conveyor belt 10 is stretched, the unloading pulley 20 is a driving pulley 21 connected to a driving source.
Another pulley 20 arranged on the stacking side is a driven pulley 22 that rotates together with the endless conveyor belt 10 circulated by the drive pulley 21.
 本実施形態のベルトコンベヤ1は、この駆動プーリー21と従動プーリー22との間の複数箇所に配された支持ローラー30をさらに備えている。
 具体的には、前記ベルトコンベヤ1は、前記積載側から前記荷下ろし側に掛けての搬送路(往路)においてコンベヤベルト10を裏面側から支持する往路側支持ローラー30aを複数備えている。
 さらに、前記ベルトコンベヤ1は、前記荷下ろし側から前記積載側に戻るまでの経路(復路)において下方に面した状態となるコンベヤベルト10の表面に下方から外周面を当接させてコンベヤベルト10を支持する復路側支持ローラー30bとを複数備えている。
The belt conveyor 1 according to the present embodiment further includes support rollers 30 disposed at a plurality of locations between the drive pulley 21 and the driven pulley 22.
Specifically, the belt conveyor 1 includes a plurality of forward path side support rollers 30a that support the conveyor belt 10 from the back surface side in a transport path (forward path) from the loading side to the unloading side.
Further, the belt conveyor 1 has its outer peripheral surface in contact with the surface of the conveyor belt 10 that faces downward in a path (return path) from the unloading side to the loading side so that the conveyor belt 10 And a plurality of return-path-side support rollers 30b.
 即ち、駆動プーリー21、従動プーリー22および複数の前記往路側支持ローラー30aは、往路におけるコンベヤベルト10を略一定傾斜で支持しうるように、その回転軸を互いに平行に配しつつそれぞれの上端部の垂直位置が図1において左上がりとなるように前記ベルトコンベヤ1に備えられている。
 なお、往路側支持ローラー30aは、図2に示すように一つの支持箇所に3個ずつ配されており、コンベヤベルト10を幅方向において湾曲させた状態にし、往路全体においてコンベヤベルト10を樋状にして走行させるように配されている。
 即ち、3個の往路側支持ローラー30aは、コンベヤベルト10の幅方向に回転軸を延在させて並んで配置されており、3個の往路側支持ローラー30aの内、2個の往路側支持ローラー30aは、コンベヤベルト10の両側縁部を持ち上げるべくベルト幅方向外向きに先上りとなるように傾斜配置されている。
 また、複数の前記復路側支持ローラー30bは、復路におけるコンベヤベルト10を略一定傾斜で支持しうるように、その回転軸を互いに平行に配しつつ上端部の垂直位置が図1において右下がりとなるように前記ベルトコンベヤ1に備えられている。
That is, the driving pulley 21, the driven pulley 22, and the plurality of forward-side support rollers 30a are arranged at their respective upper ends while their rotational axes are arranged in parallel to each other so as to support the conveyor belt 10 in the outward path with a substantially constant inclination. Is provided on the belt conveyor 1 so that the vertical position of FIG.
In addition, as shown in FIG. 2, three outward support rollers 30a are arranged at one support location, the conveyor belt 10 is curved in the width direction, and the conveyor belt 10 is formed in a bowl shape in the entire outward path. It is arranged to run.
In other words, the three forward path support rollers 30a are arranged side by side with the rotation axis extending in the width direction of the conveyor belt 10, and of the three forward path support rollers 30a, two forward path side support rollers are provided. The rollers 30a are inclined and arranged so as to rise outward in the belt width direction in order to lift both side edges of the conveyor belt 10.
Further, the plurality of the return path side support rollers 30b are arranged so that their rotation axes are parallel to each other so that the conveyor belt 10 on the return path can be supported at a substantially constant inclination, and the vertical position of the upper end portion is lowered to the right in FIG. It is provided in the belt conveyor 1 so as to be.
 なお、本実施形態におけるコンベヤベルト10は、ベルト幅方向に横断する横桟やベルト両側縁に沿って立設された耳桟といったものが備えられていない平ベルト状に形成されている。
 そして、本実施形態におけるコンベヤベルト10は、石炭Aが載置されるコンベヤベルト10の表面側(外周側)を形成するカバーゴム11と、前記石炭Aが載置される表面とは逆側の裏面を構成するカバーゴム11との2層のカバーゴム11を備えている。
 また、前記コンベヤベルト10は、この2層のカバーゴム11の内側に当該コンベヤベルトに抗張力を付与するための帆布を埋設させてなる帆布層12をさらに備えている。
In addition, the conveyor belt 10 in this embodiment is formed in the shape of a flat belt which is not provided with a horizontal beam crossing in the belt width direction and an ear beam standing along both side edges of the belt.
And the conveyor belt 10 in this embodiment is a cover rubber 11 which forms the surface side (outer peripheral side) of the conveyor belt 10 in which coal A is mounted, and the surface on the opposite side to the surface in which the said coal A is mounted. A two-layer cover rubber 11 with a cover rubber 11 constituting the back surface is provided.
The conveyor belt 10 further includes a canvas layer 12 in which a canvas for imparting tensile strength to the conveyor belt is embedded inside the two layers of cover rubber 11.
 本実施形態のコンベヤベルト10は、先述のように搬送物が石炭Aであり、坑道100という周囲が囲われた搬送路を通じて前記石炭Aを搬送すべく用いられる。
 前記坑道内には石炭Aから排出される粉塵等が充満されやすいため、前記支持ローラー30は、ベアリングなどに前記粉塵が入り込んでスムーズな回転が阻害されるおそれがある。
 また、前記支持ローラー30は、場合によっては、粉塵によって回転不能な状態となるおそれを有する。
 そして、通常であればコンベヤベルト10の走行中にはコンベヤベルト10と支持ローラー30との間に転がり摩擦による小さな摩擦熱しか発生しないはずが、前記支持ローラー30が回転しなくなった場合には、コンベヤベルト10と支持ローラー30との間にすべり摩擦による摩擦熱を発生させることになる。
 通常、すべり摩擦係数(動摩擦係数)は、転がり摩擦係数に比べて2~3桁以上も値が大きいために前記支持ローラー30が回転不能となると多大な摩擦熱を発生させるおそれを有する。
The conveyor belt 10 of this embodiment is used to transport the coal A through a transport path in which the transported object is coal A as described above and the tunnel 100 is surrounded.
Since the dust discharged from the coal A is easily filled in the mine shaft, the support roller 30 may interfere with smooth rotation because the dust enters a bearing or the like.
Moreover, the said support roller 30 has a possibility of becoming a state which cannot be rotated with dust depending on the case.
And, normally, while the conveyor belt 10 is running, it should generate only a small frictional heat due to rolling friction between the conveyor belt 10 and the support roller 30, but when the support roller 30 stops rotating, Frictional heat due to sliding friction is generated between the conveyor belt 10 and the support roller 30.
Usually, the sliding friction coefficient (dynamic friction coefficient) is 2 to 3 digits or more larger than the rolling friction coefficient, so that if the support roller 30 is unable to rotate, there is a risk of generating a great amount of frictional heat.
 特に往路においては石炭Aを積載しているためにコンベヤベルト10は、その裏面とローラー30の外周面との間に大きな荷重が加わった状態となっており、支持ローラー30が回転不能となると前記裏面が摩擦熱によって高温に加熱され、場合によっては発煙、発火に至るおそれを有する。
 このようなことからコンベヤベルト10は、その表面側のカバーゴム11(以下「表面側カバーゴム11a」ともいう)と裏面側のカバーゴム11(以下「裏面側カバーゴム11b」ともいう)との内の少なくとも裏面側のカバーゴム11bを難燃性及びすべり性に優れた状態に形成させることが好ましい。
In particular, since the coal A is loaded in the forward path, the conveyor belt 10 is in a state in which a large load is applied between the back surface thereof and the outer peripheral surface of the roller 30, and the support roller 30 becomes unable to rotate. The back surface is heated to a high temperature by frictional heat, and in some cases, there is a risk of smoking or ignition.
For this reason, the conveyor belt 10 includes a front cover rubber 11 (hereinafter also referred to as “front cover rubber 11a”) and a back cover rubber 11 (hereinafter also referred to as “back cover rubber 11b”). It is preferable to form at least the back rubber 11b on the inside in a state excellent in flame retardancy and slipperiness.
 前記裏面側カバーゴム11bに難燃性及びすべり性を付与するためには、該裏面側カバーゴム11bをベースゴム以外に難燃剤とすべり性付与剤とを含有させた難燃性ゴム組成物によって形成させればよい。
 なお、この裏面側カバーゴム11bを形成させるための前記難燃性ゴム組成物としては、該難燃性ゴム組成物のベースとなるゴム(ベースゴム)をクロロプレンゴムの1種以上とすることが重要である。
 より具体的には、本実施形態の難燃性ゴム組成物としては、クロロプレンゴムの1種以上からなるベースゴム(A)と難燃剤(B)とを含有し、該難燃剤として水酸化アルミニウム(B1)、三酸化アンチモン(B2)、及び、塩素化パラフィン(B3)が含有されており、さらに前記すべり性付与剤としてモンモリロナイト粒子(C)が含有されているものを用いることが重要である。
 また、難燃性ゴム組成物には、加硫剤等の一般的なゴム薬品(D)をさらに含有させることができる。
 以下に、各成分についてより詳細に説明する。
In order to impart flame retardancy and slipperiness to the back side cover rubber 11b, the back side cover rubber 11b is made of a flame retardant rubber composition containing a flame retardant and a slipperiness imparting agent in addition to the base rubber. What is necessary is just to form.
In addition, as the flame retardant rubber composition for forming the back side cover rubber 11b, the rubber (base rubber) serving as a base of the flame retardant rubber composition may be one or more types of chloroprene rubber. is important.
More specifically, the flame retardant rubber composition of the present embodiment contains a base rubber (A) composed of one or more chloroprene rubbers and a flame retardant (B), and aluminum hydroxide is used as the flame retardant. It is important to use (B1), antimony trioxide (B2), and chlorinated paraffin (B3), and further containing montmorillonite particles (C) as the slipperiness-imparting agent. .
The flame retardant rubber composition may further contain a general rubber chemical (D) such as a vulcanizing agent.
Below, each component is demonstrated in detail.
(A)ベースゴム
 前記難燃性ゴム組成物を構成するベースゴムは、単独種類のゴムであっても複数種類のゴムを混合した混合ゴムであっても良いが、少なくともクロロプレンゴムを含有させることが重要である。
 このクロロプレンゴムは、ラジカル捕捉作用を期待することができる塩素を分子中に含有することで難燃性に優れている。
 即ち、一般にポリマーの熱分解においては、分子鎖切断によって生じるラジカルが更なる分子切断を助長して熱分解を促進させているが、クロロプレンゴムは、塩素がラジカルを捕捉して安定化させるため熱分解を緩やかなものにさせることができる。
 しかも、クロロプレンゴムは、熱分解ガスとして不燃性の塩化水素を発生させるため、燃焼を開始したコンベヤベルトに対する酸素の供給を前記熱分解ガスで素早く遮断して消炎させる作用を有する。
 このような点において前記難燃性ゴム組成物は、クロロプレンゴムを含有することが重要でなる。
(A) Base rubber The base rubber constituting the flame retardant rubber composition may be a single type of rubber or a mixed rubber obtained by mixing a plurality of types of rubber, but at least chloroprene rubber should be contained. is important.
This chloroprene rubber is excellent in flame retardancy by containing chlorine, which can be expected to have a radical scavenging action, in the molecule.
In other words, in general, in the thermal decomposition of polymers, radicals generated by molecular chain scission promote further molecular scission and promote thermal decomposition. However, chloroprene rubber captures radicals and stabilizes them. Degradation can be made gradual.
Moreover, since the chloroprene rubber generates nonflammable hydrogen chloride as the pyrolysis gas, it has an action of quickly shutting off the supply of oxygen to the conveyor belt that has started combustion with the pyrolysis gas and extinguishing the flame.
In this respect, it is important that the flame retardant rubber composition contains chloroprene rubber.
 該クロロプレンゴムとしては、特に限定されず、例えば、商品名「ショウプレンW」、「ショウプレンWM1」、「ショウプレンG」など「ショウプレン」のシリーズ名で昭和電工社より市販されているものや「デンカクロロプレンPM-40」、「デンカクロロプレンS-41」など「デンカクロロプレン」のシリーズ名で電気化学工業社より市販されているものを1種単独、又は、これらの内の複数を前記ベースゴムに含有させることができる。 The chloroprene rubber is not particularly limited, and examples thereof include those commercially available from Showa Denko Co., Ltd. under the product names “Showrene W”, “Showrene WM1”, “Showrene G”, and “Denka Chloroprene”. PM-40 "," Denkachloroprene S-41 "and other" Denkachloroprene "series names commercially available from Denki Kagaku Kogyo Co., Ltd. are used alone, or a plurality of these are included in the base rubber. be able to.
 また、前記ベースゴムには、前記クロロプレンゴム以外のゴムを少量含有させることができ、例えば、クロロプレンと同様の機能を期待することができる塩素化ポリエチレン、クロロスルホン化ポリエチレン等の塩素系ゴムを含有させても良い。
 さらに、要すれば、前記クロロプレンゴムに加えて天然ゴムやエチレン・α-オレフィンゴムといった非塩素系ゴムを前記ベースゴムの一部として含有させることも可能である。
In addition, the base rubber can contain a small amount of rubber other than the chloroprene rubber, for example, chlorinated polyethylene such as chlorinated polyethylene and chlorosulfonated polyethylene that can be expected to have the same function as chloroprene. You may let them.
Furthermore, if necessary, in addition to the chloroprene rubber, non-chlorine rubbers such as natural rubber and ethylene / α-olefin rubber can be contained as a part of the base rubber.
 ただし、非塩素系ゴムは、その含有割合を増大させるほど難燃性ゴム組成物の難燃性を低下させるおそれを有することから、前記ベースゴムに占める割合は20質量%以下とすることが好ましく、10質量%以下とすることがより好ましく、5質量%以下とすることが特に好ましい。
 また、前記ベースゴムは、塩素系ゴムだけで構成することが最も好ましい。
However, since the non-chlorine-based rubber has a risk of reducing the flame retardancy of the flame retardant rubber composition as the content ratio thereof is increased, the ratio of the non-chlorine rubber to the base rubber is preferably 20% by mass or less. The content is more preferably 10% by mass or less, and particularly preferably 5% by mass or less.
The base rubber is most preferably composed of only a chlorinated rubber.
 なお、前記ベースゴムを塩素系ゴムだけで構成する場合においては、クロロプレンゴムとその他の塩素系ゴムとの合計に占めるその他の塩素系ゴムの割合は20質量%以下とすることが好ましく、10質量%以下とすることがより好ましく、5質量%以下とすることが特に好ましい。 In the case where the base rubber is composed of only a chlorinated rubber, the proportion of the other chlorinated rubber in the total of the chloroprene rubber and the other chlorinated rubber is preferably 20% by mass or less. % Or less, more preferably 5% by mass or less.
(B)難燃剤
(B1)水酸化アルミニウム
 前記水酸化アルミニウムは、クロロプレンゴムをはじめとして一般的なポリマーの熱分解開始温度(約300℃)以下において脱水反応を示し、且つ、該脱水反応が吸熱反応であるために、難燃性ゴム組成物の熱分解時において難燃性ゴム組成物の温度を低下させる効果を奏するものでありコンベヤベルトに難燃性を付与するための重要な成分である。
 また、水酸化アルミニウムは、燃焼時等においてチャーによる断熱被膜を形成させるのにも有効に作用し、例えば、裏面側カバーゴムが支持ローラーとの摩擦熱で熱分解温度以上に加熱された場合に、カバーゴム表面にチャーを形成して該表面において発生した熱が厚み方向内部側に伝達することを抑制させうる。
(B) Flame retardant (B1) Aluminum hydroxide The aluminum hydroxide exhibits a dehydration reaction at a temperature lower than the thermal decomposition start temperature (about 300 ° C.) of general polymers such as chloroprene rubber, and the dehydration reaction is endothermic. Because it is a reaction, it has the effect of lowering the temperature of the flame retardant rubber composition during the thermal decomposition of the flame retardant rubber composition, and is an important component for imparting flame resistance to the conveyor belt. .
Aluminum hydroxide also works effectively to form a heat-insulating coating with char during combustion, for example, when the back cover rubber is heated above the thermal decomposition temperature by frictional heat with the support roller. Then, char can be formed on the surface of the cover rubber to prevent the heat generated on the surface from being transmitted to the inside in the thickness direction.
 該水酸化アルミニウムとしては、特に限定されるものではないが、例えば、メジアン径が2μm以下程度の比較的粒子径が細かく比表面積が大きいものの方が難燃性ゴム組成物に優れた機械的特性や優れた難燃性を発揮させる上において有利である。
 このような粒径の細かな水酸化アルミニウムとしては、例えば、商品名「ハイジライトH-42」、「ハイジライトH-43M」など「ハイジライト」のシリーズ名で昭和電工社より市販されているものが挙げられる。
The aluminum hydroxide is not particularly limited, but, for example, those having a relatively small particle diameter and a large specific surface area with a median diameter of about 2 μm or less have superior mechanical properties as a flame-retardant rubber composition. It is advantageous for exhibiting excellent flame retardancy.
Such fine aluminum hydroxide having a particle diameter is commercially available from Showa Denko KK under the series name of “Hijilite” such as “Hijilite H-42” and “Hijilite H-43M”. Things.
 なお、前記水酸化アルミニウムは、難燃性ゴム組成物における含有量が多いほど難燃性において有利となる一方で過度に含有させると当該難燃性ゴム組成物によって形成されるカバーゴムの機械的な特性を低下させるおそれを有する。
 従って、難燃性と機械的特性とをバランス良く発揮させ得る点において前記難燃性ゴム組成物は、前記ベースゴム100質量部に対して、30質量部以上60質量部以下となる割合で水酸化アルミニウムを含有することが好ましい。
The aluminum hydroxide is more advantageous in terms of flame retardancy as the content in the flame retardant rubber composition is larger. On the other hand, if excessively contained, the mechanical properties of the cover rubber formed by the flame retardant rubber composition are increased. There is a risk of deteriorating the characteristics.
Therefore, the flame retardant rubber composition is water-soluble at a ratio of 30 parts by mass or more and 60 parts by mass or less with respect to 100 parts by mass of the base rubber in that the flame retardancy and mechanical properties can be exhibited in a balanced manner. It is preferable to contain aluminum oxide.
(B2)三酸化アンチモン
 前記三酸化アンチモンは、それ単独では難燃性を殆ど発揮せず、塩素化パラフィン等のハロゲン系難燃剤と併用されて該難燃剤の難燃効果を向上させる機能を有するものである。
 より詳しくは、三酸化アンチモン(Sb)は、塩素化パラフィンやクロロプレンなどに含まれている塩素のラジカル捕捉機能を助成するとともにこれらの熱分解によって生じた塩化水素と反応してオキシ塩化アンチモン(SbOCl)や三塩化アンチモン(SbCl)に変化する際に水蒸気を発生させて酸素を遮断する効果を発揮するものである。
(B2) Antimony trioxide The antimony trioxide exhibits little flame retardancy by itself, and has a function of improving the flame retardant effect of the flame retardant when used in combination with a halogen-based flame retardant such as chlorinated paraffin. Is.
More specifically, antimony trioxide (Sb 2 O 3 ) supports the radical scavenging function of chlorine contained in chlorinated paraffin, chloroprene, etc. and reacts with hydrogen chloride generated by these thermal decompositions to react with oxychloride. When changing to antimony (SbOCl) or antimony trichloride (SbCl 3 ), water vapor is generated and oxygen is blocked.
 該三酸化アンチモンは、商品名「PATOX-M」、「PATOX-K」など「PATOX」のシリーズ名で日本精鉱社から市販されている市販品や「ファイアカット」のシリーズ名で鈴裕化学社から市販されている市販品とすることができる。
 なお、前記難燃性ゴム組成物には、通常、前記ベースゴム100質量部に対して、1質量部以上15質量部以下、好ましくは2質量部以上10質量部以下となる割合で三酸化アンチモンを含有させることができる。
The antimony trioxide is a commercial product marketed by Nippon Seiko Co., Ltd. under the product name “PATOX-M”, “PATOX-K”, etc. It can be a commercial product commercially available from the company.
The flame retardant rubber composition usually has an antimony trioxide ratio of 1 to 15 parts by mass, preferably 2 to 10 parts by mass with respect to 100 parts by mass of the base rubber. Can be contained.
(B3)塩素化パラフィン
 前記塩素化パラフィンとしては、例えば、商品名「エンパラ40」、「エンパラ70」、「エンパラK-45」など「エンパラ」のシリーズ名で味の素ファインテクノ社から市販されているもの、「トヨパラックス」のシリーズ名で東ソー社から市販されているものが挙げられる。
 前記難燃性ゴム組成物は、通常、前記ベースゴム100質量部に対して、10質量部以上30質量部以下となる割合で当該塩素化パラフィンを含有させることができる。
(B3) Chlorinated paraffin The chlorinated paraffin is commercially available from Ajinomoto Fine Techno Co., Ltd. under the series name “Empara” such as “Empara 40”, “Empara 70”, “Empara K-45”, etc. And those commercially available from Tosoh Corporation under the “Toyoparax” series name.
The flame-retardant rubber composition can usually contain the chlorinated paraffin at a ratio of 10 parts by mass to 30 parts by mass with respect to 100 parts by mass of the base rubber.
(C)モンモリロナイト粒子
 鉱物としてのモンモリロナイトは、2八面体型含水層状珪酸塩鉱物に分類されており、一般的には以下の化学式で表現されている。
 
(Al2-yMg)Si10(OH)・(M.M1/2 2+・nH
 
(但し、yは、通常、0.2~0.6の値を示し、Mは、交換性陽イオンでNa,K,Ca,Mg,Hなどを表している。また、nは層間水の量を表す数である。)
 
 より具体的には、モンモリロナイトは、以下の化学式のものが知られている。
 
(Na.Ca)0.33(Al1.67Mg0.33)Si10(OH)・nH
(C) Montmorillonite Particles Montmorillonite as a mineral is classified as a dioctahedral water-containing layered silicate mineral and is generally expressed by the following chemical formula.

(Al 2−y Mg y ) Si 4 O 10 (OH) 2. (M + .M 1/2 2+ ) y nH 2 O

(However, y usually represents a value of 0.2 to 0.6, M represents an exchangeable cation and represents Na, K, Ca, Mg, H, etc. n represents interlayer water. A number representing the quantity.)

More specifically, montmorillonite having the following chemical formula is known.

(Na.Ca) 0.33 (Al 1.67 Mg 0.33 ) Si 4 O 10 (OH) 2 .nH 2 O
 前記モンモリロナイト粒子は、カバーゴムの表面において層間剥離を生じコンベヤベルトに優れたすべり性を発揮させる効果を有する。
 該モンモリロナイト粒子としては、カバーゴム中における分散時の粒径が2μm以下となるものが好ましく、例えば、「ベンゲルHVP」など「ベンゲル」のシリーズ名でホージュン社から市販のものや、同社から「エスベン」のシリーズ名で市販されている有機処理品を採用することができる。
The montmorillonite particles have an effect of causing delamination on the surface of the cover rubber and exhibiting excellent slipperiness on the conveyor belt.
As the montmorillonite particles, those having a particle size of 2 μm or less when dispersed in the cover rubber are preferable. For example, “Bengel HVP” and other “Bengel” series names are commercially available from Hojun Co. Organic processed products marketed under the series name "can be used.
 なお、モンモリロナイト粒子が有する効果をコンベヤベルトに確実に発揮させる上においては、カバーゴムを形成させるための前記難燃性ゴム組成物に該モンモリロナイト粒子をある程度以上含有させることが必要になるが、過剰に含有させるとカバーゴムの耐摩耗性を悪化させるおそれを有する。
 従って、カバーゴムに優れたすべり性と耐摩耗性を発揮させる上においては、前記モンモリロナイト粒子を、前記ベースゴム100質量部に対して3質量部以上30質量部以下となる割合で難燃性ゴム組成物に含有させることが重要である。
 具体的には、すべり性と耐摩耗性とにおける効果をより顕著に発揮させる上において前記難燃性ゴム組成物は、前記モンモリロナイト粒子を前記ベースゴム100質量部に対して5質量部以上15質量部以下の割合で含有することが好ましい。
In order to reliably exert the effect of montmorillonite particles on the conveyor belt, it is necessary to contain the montmorillonite particles to a certain extent in the flame-retardant rubber composition for forming the cover rubber. If it is contained in, there is a risk of deteriorating the wear resistance of the cover rubber.
Therefore, in order to make the cover rubber exhibit excellent sliding properties and wear resistance, the montmorillonite particles are added in a proportion of 3 to 30 parts by mass with respect to 100 parts by mass of the base rubber. It is important to include in the composition.
Specifically, the flame retardant rubber composition has 5 parts by mass or more and 15 parts by mass of the montmorillonite particles with respect to 100 parts by mass of the base rubber, in order to more effectively exhibit the effects of slipperiness and wear resistance. It is preferable to contain it in the ratio below the part.
(D)その他のゴム薬品
 前記ゴム薬品としては、例えば、硫黄、有機過酸化物といった加硫剤;スルフェンアミド系化合物、チアゾール系化合物といった加硫促進剤などの他に充填剤、軟化剤、老化防止剤、加工性改良剤が挙げられる。
 また、前記難燃性ゴム組成物は、要すれば上記以外の難燃剤を含有しても良い。
 さらに、前記難燃性ゴム組成物は、要すればマイカ、クレー、タルクなどの層状粘土鉱物からなる粒子を前記モンモリロナイト粒子以外のすべり性付与剤として含有しても良い。
(D) Other rubber chemicals Examples of the rubber chemicals include, for example, vulcanizing agents such as sulfur and organic peroxides; vulcanization accelerators such as sulfenamide compounds and thiazole compounds, fillers, softeners, Examples include aging inhibitors and processability improvers.
Further, the flame retardant rubber composition may contain a flame retardant other than the above, if necessary.
Further, the flame retardant rubber composition may contain particles made of layered clay minerals such as mica, clay, talc, etc. as a slipperiness imparting agent other than the montmorillonite particles, if necessary.
 なお、コンベヤベルトは、前記裏面側カバーゴム11bと同様に前記表面側カバーゴム11aも前記難燃性ゴム組成物で形成させて両面に難燃性を付与させても良い。
 このとき、裏面側カバーゴム11bと表面側カバーゴム11aとの形成に用いる難燃性ゴム組成物は、同じ配合内容のものであっても、異なる配合内容であってもよい。
In addition, the conveyor belt may be formed of the flame retardant rubber composition so as to impart flame retardancy to both sides, similarly to the back side cover rubber 11b.
At this time, the flame-retardant rubber composition used for forming the back-side cover rubber 11b and the front-side cover rubber 11a may have the same content or different content.
 前記帆布層12を形成させるための帆布については特に限定されることなく一般的なコンベヤベルトに用いられているものを本実施形態においても採用することができる。 The canvas for forming the canvas layer 12 is not particularly limited, and a canvas used for a general conveyor belt can be used in this embodiment.
 本実施形態のコンベヤベルトは、その製造方法が特に限定されるものではなく、一般的なコンベヤベルトと同様に製造することができる。
 該コンベヤベルトは、例えば、バンバリーミキサー、ニーダーミキサー、ロール等を用いてカバーゴム用の難燃性ゴム組成物を混練した後、カレンダー等を用いて難燃性ゴム組成物をシート状にさせてカバーゴム用未加硫シートを作製し、該未加硫シートと帆布とを加硫一体化させて製造することができる。
The manufacturing method of the conveyor belt of this embodiment is not particularly limited, and can be manufactured in the same manner as a general conveyor belt.
The conveyor belt is prepared, for example, by kneading a flame retardant rubber composition for a cover rubber using a Banbury mixer, a kneader mixer, a roll or the like, and then making the flame retardant rubber composition into a sheet using a calendar or the like. An unvulcanized sheet for cover rubber can be produced, and the unvulcanized sheet and canvas can be integrated by vulcanization.
 より詳しくは、前記コンベヤベルトは、ゴム引きした帆布を用意し、該帆布をさらに外側からカバーゴム用未加硫シートで挟んで、「カバーゴム用未加硫シート/帆布/カバーゴム用未加硫シート」の順に積層された積層体を形成させ、該積層体を熱プレスを用いて加硫一体化することにより作製することができる。 More specifically, for the conveyor belt, a rubberized canvas is prepared, and the canvas is further sandwiched from outside by an unvulcanized sheet for cover rubber, and “unvulcanized sheet for cover rubber / canvas / unvulcanized for cover rubber”. A laminated body laminated in the order of “sulfur sheet” is formed, and the laminated body can be produced by vulcanization integration using a hot press.
 なお、本実施形態においては、本発明の効果がより顕著に発揮される事例として搬送物が石炭で、坑道を通じた搬送路が設けられている場合を例示しているが、本発明のコンベヤベルトは、コンクリート管や鉄管等の管体内部を通過して石炭以外の物を搬送するような場合においても効果を発揮するものである。
 即ち、このような用途におけるコンベヤベルトも本発明のコンベヤベルトとして意図するものである。
In this embodiment, as an example in which the effect of the present invention is more remarkably exhibited, the case where the conveyed product is coal and a conveyance path through a mine shaft is provided, but the conveyor belt of the present invention is exemplified. Is effective even in cases where materials other than coal are transported through the inside of a tubular body such as a concrete pipe or an iron pipe.
That is, the conveyor belt in such an application is also intended as the conveyor belt of the present invention.
 また、本実施形態においては、摩擦熱の発生原因として支持ローラーの回転が不能となった場合を例示しているが、例えば、搬送路の途中で落下した搬送物とコンベヤベルトが接触するなどして摩擦熱を発生させるようなことも考えられる。
 従って、本発明のコンベヤベルトは、支持ローラーによって支持されて利用されるものに限定されるものではなく、難燃性とすべり性とを付与する対象が裏面側カバーゴムに限定されるものでもない。
 即ち、搬送物が載置されるモンモリロナイト粒子を含んだ前記難燃性ゴム組成物が表面側カバーゴムの形成のみに利用されているようなコンベヤベルトも本発明のコンベヤベルトとして意図する範囲のものである。
 さらに、本発明のコンベヤベルトは、本実施形態に例示のフラットベルトに限定されるものではなくベルト幅方向に横断する横桟付のものや両側縁に沿って立設された耳桟を有するものも本発明のコンベヤベルトとして意図する範囲のものである。
 なお、本発明のコンベヤベルトとして、実施形態に例示のコンベヤベルトに上記以外にも各種変更を加えたものを採用しうることについては説明するまでもなく当然の事柄である。
Further, in the present embodiment, the case where the rotation of the support roller is disabled as a cause of the generation of frictional heat is illustrated, but for example, the conveyed object dropped in the middle of the conveyance path and the conveyor belt come into contact. It is also possible to generate frictional heat.
Therefore, the conveyor belt of the present invention is not limited to the one supported and used by the support roller, and the object for imparting flame retardancy and slipperiness is not limited to the back side cover rubber. .
That is, a conveyor belt in which the flame retardant rubber composition containing the montmorillonite particles on which the conveyed product is placed is used only for the formation of the surface side cover rubber is also within the range intended as the conveyor belt of the present invention. It is.
Furthermore, the conveyor belt of the present invention is not limited to the flat belt illustrated in the present embodiment, but also has a cross rail that traverses in the belt width direction and a belt that has ear rails erected along both side edges. It is the range which is intended as the conveyor belt of this invention.
As a conveyor belt of the present invention, it is a matter of course that the conveyor belt exemplified in the embodiment may be modified in various ways other than the above.
 以下に本発明の実施例を掲げて本発明を更に詳しく説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples of the present invention, but the present invention is not limited thereto.
(使用材料)
 下記表1に、評価に用いた各原料の略称とその具体的な内容とを示す。
Figure JPOXMLDOC01-appb-T000001
(Materials used)
Table 1 below shows the abbreviations and specific contents of the raw materials used in the evaluation.
Figure JPOXMLDOC01-appb-T000001
 上記のような原料を表2に示す配合割合で含有する難燃性ゴム組成物を用いて評価用試料を作製し、各評価を実施した。 Samples for evaluation were prepared using a flame retardant rubber composition containing the above raw materials in the blending ratio shown in Table 2, and each evaluation was performed.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
(評価)
(すべり性の評価)
 各配合によってベルト状試料を作製し、豪州規格(AS1334.11-1988「DETERMINATION OF IGNITABILITY AND MAXIMUM SURFACE TEMPERATURE OF BELTING SUBJECTED TO FRICTION」)に基づく摩擦温度の測定結果についてランク付けを行い、すべり性の評価を実施した。
(Evaluation)
(Evaluation of slipperiness)
A belt-like sample is prepared by each blending, and the friction temperature is evaluated based on the Australian standard (AS1334.111-1988 “DETERMINATION OF IGNITABILITY AND MAXIMUM SURFACE TEMPERATURE OF BELTING SUBRECTED TO FRICTION”). Carried out.
 なお、評価は、同規格に規定されている図3に示すような装置を用いて実施した。
 即ち、表2に示した難燃性ゴム組成物でカバーゴムが形成されたベルト状試料10xの長手方向一端部を垂直壁WLに固定し、この固定位置から水平に遠ざかるようにベルト状試料10xを延在させて前記垂直壁WLから離れた位置において回転軸がベルト状試料10xの長手方向と直交するように配された直径212.8mmの回転ドラムTDをベルト状試料10xの下面側に当接させ、該回転ドラムTDの外周面にベルト状試料10xを半周巻き掛けてさらに前記垂直壁WLに向かって接近するようにベルト状試料10xを水平方向に延在させ、該ベルト状試料10xが垂直壁WLに至る手前において回動自在の補助ロールRLに巻き掛けて残りの部分を下方に垂下させ、該垂下させたベルト状試料10xの下端に35kgの荷重をセットした。
 即ち、評価は、垂直壁WLに固定された長さ方向一端部から荷重がセットされた他端部にかけて35kgfの張力を発生させて実施した。
 また、評価は、上記のような状態でモーターMTを使って前記回転ドラムTDを190.2rpmの回転数で回転させて実施した。
 なお、このとき回転ドラムTDは、その上端側が前記垂直壁WLから遠ざかる方向に移動するように回転させた。
 そして、約2時間の試験時間中に回転ドラムTDと接する箇所におけるベルト状試料10xの表面温度(回転ドラムTDと接している側の表面の温度)が到達した最高到達温度を測定した。
The evaluation was performed using an apparatus as shown in FIG. 3 defined in the same standard.
That is, one end in the longitudinal direction of a belt-shaped sample 10x having a cover rubber formed of the flame-retardant rubber composition shown in Table 2 is fixed to the vertical wall WL, and the belt-shaped sample 10x is moved horizontally away from the fixed position. And a rotary drum TD having a diameter of 212.8 mm disposed so that the rotation axis is orthogonal to the longitudinal direction of the belt-shaped sample 10x at a position away from the vertical wall WL. The belt-shaped sample 10x is extended in the horizontal direction so that the belt-shaped sample 10x is wound around the outer peripheral surface of the rotating drum TD halfway and further approaches the vertical wall WL. Before reaching the vertical wall WL, it is wound around a rotatable auxiliary roll RL and the remaining part is suspended downward, and a load of 35 kg is set on the lower end of the suspended belt-like sample 10x. It was.
That is, the evaluation was performed by generating a tension of 35 kgf from one end in the length direction fixed to the vertical wall WL to the other end where the load was set.
The evaluation was performed by rotating the rotating drum TD at a rotation speed of 190.2 rpm using the motor MT in the above-described state.
At this time, the rotating drum TD was rotated so that the upper end side thereof moved away from the vertical wall WL.
Then, the highest temperature reached by the surface temperature of the belt-like sample 10x (the temperature of the surface in contact with the rotating drum TD) at the position in contact with the rotating drum TD during the test time of about 2 hours was measured.
 その結果、最高到達温度が250℃未満であったものを「A」とランク付けし、最高到達温度が250℃以上300℃未満であった場合を「B」とランク付けした。
 さらに、最高到達温度が300℃以上325℃未満であったものを「C」とランク付けし、最高到達温度が325℃以上であった場合を「D」とランク付けした。
 結果を、先の表2に併せて示す。
 なお、比較例7のベルト状試料は、グローが発生したために途中で評価を打ち切った。
As a result, the case where the maximum attained temperature was less than 250 ° C. was ranked “A”, and the case where the maximum attained temperature was 250 ° C. or more and less than 300 ° C. was ranked “B”.
Furthermore, the case where the maximum temperature reached 300 ° C. or higher and lower than 325 ° C. was ranked “C”, and the case where the maximum temperature reached 325 ° C. or higher was ranked “D”.
The results are also shown in Table 2 above.
Note that the evaluation of the belt-like sample of Comparative Example 7 was terminated in the middle because of the occurrence of glow.
 ここで、比較例7~9、実施例9の試験状況を図4(a)~(d)に示す。
 この図4(a)~(d)は、時間経過とともにベルト状試料の温度がどのように変化したかを示すチャートで、その温度(上チャート)に基づいて算出した摩擦係数(下チャート)も併せて示されている。
 このチャートや表2に示した結果からも、本発明によればすべり性に優れ摩擦熱の発生が抑制されたコンベヤベルトが得られることがわかる。
Here, test conditions of Comparative Examples 7 to 9 and Example 9 are shown in FIGS.
FIGS. 4A to 4D are charts showing how the temperature of the belt-like sample has changed over time, and the friction coefficient (lower chart) calculated based on the temperature (upper chart) is also shown. It is also shown.
Also from this chart and the results shown in Table 2, it can be seen that according to the present invention, it is possible to obtain a conveyor belt which is excellent in sliding property and generation of frictional heat is suppressed.
 また、前記評価試料は、JIS K6264-2「加硫ゴム及び熱可塑性ゴム-耐摩耗性の求め方-第2部:試験方法」のDIN摩耗試験によって耐摩耗性のランク付けを行った。
 このとき、DIN摩耗の摩耗量が200mm未満であったものを「A」とランク付けし、摩耗量が200mm以上250mm未満であった場合を「B」とランク付けした。
 さらに、摩耗量が250mm以上300mm未満であったものを「C」とランク付けし、摩耗量が300mm以上であった場合を「D」とランク付けした。
 結果を、先の表2に併せて示す。
 この結果からも、本発明によればすべり性に優れたコンベヤベルトが得られることがわかる。
The evaluation samples were ranked in wear resistance by the DIN abrasion test of JIS K6264-2 “Vulcanized rubber and thermoplastic rubber—How to obtain abrasion resistance—Part 2: Test method”.
At this time, the case where the wear amount of DIN wear was less than 200 mm 3 was ranked “A”, and the case where the wear amount was 200 mm 3 or more and less than 250 mm 3 was ranked “B”.
Furthermore, the case where the wear amount was 250 mm 3 or more and less than 300 mm 3 was ranked “C”, and the case where the wear amount was 300 mm 3 or more was ranked “D”.
The results are also shown in Table 2 above.
From this result, it can be seen that according to the present invention, a conveyor belt excellent in slipperiness can be obtained.
 1:ベルトコンベヤ、10:コンベヤベルト、11:カバーゴム、12:帆布層、20:プーリー、30:支持ローラー 1: Belt conveyor, 10: Conveyor belt, 11: Cover rubber, 12: Canvas layer, 20: Pulley, 30: Support roller

Claims (4)

  1.  表面に搬送物が載置され、周囲が囲われた搬送路を通じて前記搬送物を搬送すべく用いられるコンベヤベルトであって、
     前記表面を構成する表面側カバーゴムと、前記表面とは逆側の裏面を構成する裏面側カバーゴムとの内の少なくとも一方が難燃性ゴム組成物によって形成されており、該難燃性ゴム組成物は、ベースゴム、難燃剤、及び、モンモリロナイト粒子を含有し、前記ベースゴムとしてクロロプレンゴムの1種以上を含有し、前記難燃剤として水酸化アルミニウム、三酸化アンチモン、及び、塩素化パラフィンを含有しており、前記ベースゴム100質量部に対する前記モンモリロナイト粒子の割合が3質量部以上30質量部以下であることを特徴とするコンベヤベルト。
    It is a conveyor belt that is used for transporting the transported object through a transport path on which a transported object is placed and surrounded by a surface,
    At least one of the surface side cover rubber constituting the surface and the back side cover rubber constituting the back surface opposite to the surface is formed of a flame retardant rubber composition, and the flame retardant rubber The composition contains a base rubber, a flame retardant, and montmorillonite particles, the base rubber contains at least one kind of chloroprene rubber, and the flame retardant contains aluminum hydroxide, antimony trioxide, and chlorinated paraffin. The conveyor belt characterized by containing and the ratio of the said montmorillonite particle with respect to 100 mass parts of said base rubbers being 3 mass parts or more and 30 mass parts or less.
  2.  前記裏面側カバーゴムが前記難燃性ゴム組成物で形成されている請求項1記載のコンベヤベルト。 The conveyor belt according to claim 1, wherein the back side cover rubber is formed of the flame retardant rubber composition.
  3.  前記難燃性ゴム組成物は、前記ベースゴム100質量部に対する前記モンモリロナイト粒子の割合が5質量部以上15質量部以下である請求項1又は2記載のコンベヤベルト。 The conveyor belt according to claim 1 or 2, wherein the flame retardant rubber composition has a ratio of the montmorillonite particles to 5 parts by mass or more and 15 parts by mass or less with respect to 100 parts by mass of the base rubber.
  4.  前記搬送路が炭鉱の坑道であり、前記搬送物が石炭である請求項1乃至3のいずれか1項に記載のコンベヤベルト。
     
     
    The conveyor belt according to any one of claims 1 to 3, wherein the transport path is a mine shaft, and the transported material is coal.

PCT/JP2013/065159 2012-06-22 2013-05-31 Conveyor belt WO2013190976A1 (en)

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