WO2013186094A3 - Anodic oxidation of organic substrates in the presence of nucleophiles - Google Patents

Anodic oxidation of organic substrates in the presence of nucleophiles Download PDF

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Publication number
WO2013186094A3
WO2013186094A3 PCT/EP2013/061555 EP2013061555W WO2013186094A3 WO 2013186094 A3 WO2013186094 A3 WO 2013186094A3 EP 2013061555 W EP2013061555 W EP 2013061555W WO 2013186094 A3 WO2013186094 A3 WO 2013186094A3
Authority
WO
WIPO (PCT)
Prior art keywords
nucleophiles
anodic oxidation
organic substrates
anode
reaction medium
Prior art date
Application number
PCT/EP2013/061555
Other languages
French (fr)
Other versions
WO2013186094A2 (en
Inventor
Nicola Christiane Aust
Itamar Michael Malkowsky
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN201380031601.2A priority Critical patent/CN104379814A/en
Priority to KR20157000674A priority patent/KR20150023709A/en
Priority to EP13729287.6A priority patent/EP2861785A2/en
Priority to JP2015516554A priority patent/JP2015527483A/en
Priority to CA2876566A priority patent/CA2876566A1/en
Publication of WO2013186094A2 publication Critical patent/WO2013186094A2/en
Publication of WO2013186094A3 publication Critical patent/WO2013186094A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

This invention refers to a process of anodic substitution comprising the electrolyzing the liquid reaction medium in an electrochemical cell comprising a cathode and an anode, whereas the liquid reaction medium comprises an organic compound with at least one carbon bound hydrogen atom, a nucleophilic agent, and an ionic liquid in a proportion of at least 10 % by weight, and whereas the said hydrogen atoms are replaced at least partially with the nucleophilic group of said nucleophilic agent. Preferably, a gas diffusion layer electrode is used as anode.
PCT/EP2013/061555 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles WO2013186094A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201380031601.2A CN104379814A (en) 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles
KR20157000674A KR20150023709A (en) 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles
EP13729287.6A EP2861785A2 (en) 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles
JP2015516554A JP2015527483A (en) 2012-06-15 2013-06-05 Anodization of organic substrates in the presence of nucleophiles
CA2876566A CA2876566A1 (en) 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12172250 2012-06-15
EP12172250.8 2012-06-15

Publications (2)

Publication Number Publication Date
WO2013186094A2 WO2013186094A2 (en) 2013-12-19
WO2013186094A3 true WO2013186094A3 (en) 2014-07-24

Family

ID=48628629

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/061555 WO2013186094A2 (en) 2012-06-15 2013-06-05 Anodic oxidation of organic substrates in the presence of nucleophiles

Country Status (7)

Country Link
EP (1) EP2861785A2 (en)
JP (1) JP2015527483A (en)
KR (1) KR20150023709A (en)
CN (1) CN104379814A (en)
CA (1) CA2876566A1 (en)
TW (1) TW201400469A (en)
WO (1) WO2013186094A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3321250A1 (en) * 2016-11-15 2018-05-16 Covestro Deutschland AG Electrochemical method for the production of arylalkylcarbonates and diaryl carbonates
WO2019016903A1 (en) * 2017-07-19 2019-01-24 宇部興産株式会社 Nonaqueous electrolytic solution and electricity storage device using same
CN109321940A (en) * 2018-11-30 2019-02-12 西南大学 A kind of the electrochemical oxidation synthetic method and its application of amide
CN109930171B (en) * 2019-04-12 2020-01-17 天津理工大学 Green and efficient acetal synthesis method
CN111394747B (en) * 2020-04-10 2021-03-30 浙江工业大学 Green electrochemical synthesis method of 2-acyloxy aniline derivatives
CN113046772B (en) * 2021-03-18 2022-03-04 南华大学 Electrochemical synthesis method of 4-selenopyrazole derivative

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US4441970A (en) * 1981-10-28 1984-04-10 Basf Aktiengesellschaft Electrochemical preparation of 2,5-dialkoxy-2,5-dihydrofurans
US5147645A (en) * 1988-06-21 1992-09-15 Basf Aktiengesellschaft Pyrethroids and their use for controlling pests
US5443698A (en) * 1994-05-06 1995-08-22 Huls America Inc. Electrosynthesis of metal carboxylates
US6063256A (en) * 1996-05-10 2000-05-16 Basf Aktiengesellschaft Preparation of phthalides
US20040026263A1 (en) * 2000-11-24 2004-02-12 Hermann Putter Method for producing alcoxylated carbonyl compounds by an anodic oxidation method using a cathodic coupled reaction for organic synthesis
US6764589B1 (en) * 1999-09-20 2004-07-20 Basf Aktiengesellschaft Method for the electrolytic conversion of furan or furan derivatives
WO2011098432A2 (en) * 2010-02-12 2011-08-18 Basf Se Method for producing 4-isopropylcyclohexylmethanol
US20110207968A1 (en) * 2010-02-12 2011-08-25 Basf Se Process for preparing 4-isopropylcyclohexylmethanol
US20120016162A1 (en) * 2009-03-27 2012-01-19 Basf Se Electrochemical method for producing 3-tert-butylbenzaldehyde dimethyl acetal

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DE2848397C2 (en) 1978-11-08 1982-09-23 Basf Ag, 6700 Ludwigshafen Electrochemical production of benzaldehyde dialkyl acetals substituted in the 4-position
EP0241432B1 (en) 1986-03-07 1993-08-11 Tanaka Kikinzoku Kogyo K.K. Gas permeable electrode
US4748095A (en) 1987-03-06 1988-05-31 Nagakazu Furuya Halogen cell
US5618392A (en) 1991-10-31 1997-04-08 Tanaka Kikinzoku Kogyo K.K. Gas diffusion electrode
WO1998000580A1 (en) * 1996-06-28 1998-01-08 E.I. Du Pont De Nemours And Company In-situ halogenation of compounds in an electrochemical cell
US6267865B1 (en) 1997-05-02 2001-07-31 3M Innovative Properties Company Electrochemical fluorination using interrupted current
US6103077A (en) 1998-01-02 2000-08-15 De Nora S.P.A. Structures and methods of manufacture for gas diffusion electrodes and electrode components
DE19962102A1 (en) 1999-12-22 2001-06-28 Basf Ag Process for the electrochemical oxidation of organic compounds
US6824599B2 (en) 2001-10-03 2004-11-30 The University Of Alabama Dissolution and processing of cellulose using ionic liquids
DE102004031025B3 (en) 2004-06-26 2005-12-29 Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. Method and device for the production of shaped articles from cellulose
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CN103119014B (en) * 2010-09-16 2016-01-20 巴斯夫欧洲公司 Produce the method with 2-methyl-3-(4-tert-butyl-phenyl) propionic aldehyde of high contraposition isomeric purities

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405816A (en) * 1980-12-24 1983-09-20 Hoechst Aktiengesellschaft 4,4'-Diphenyl ether-dialdehyde-bis-dimethylacetal
US4441970A (en) * 1981-10-28 1984-04-10 Basf Aktiengesellschaft Electrochemical preparation of 2,5-dialkoxy-2,5-dihydrofurans
US5147645A (en) * 1988-06-21 1992-09-15 Basf Aktiengesellschaft Pyrethroids and their use for controlling pests
US5443698A (en) * 1994-05-06 1995-08-22 Huls America Inc. Electrosynthesis of metal carboxylates
US6063256A (en) * 1996-05-10 2000-05-16 Basf Aktiengesellschaft Preparation of phthalides
US6764589B1 (en) * 1999-09-20 2004-07-20 Basf Aktiengesellschaft Method for the electrolytic conversion of furan or furan derivatives
US20040026263A1 (en) * 2000-11-24 2004-02-12 Hermann Putter Method for producing alcoxylated carbonyl compounds by an anodic oxidation method using a cathodic coupled reaction for organic synthesis
US20120016162A1 (en) * 2009-03-27 2012-01-19 Basf Se Electrochemical method for producing 3-tert-butylbenzaldehyde dimethyl acetal
WO2011098432A2 (en) * 2010-02-12 2011-08-18 Basf Se Method for producing 4-isopropylcyclohexylmethanol
US20110207968A1 (en) * 2010-02-12 2011-08-25 Basf Se Process for preparing 4-isopropylcyclohexylmethanol

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Also Published As

Publication number Publication date
CN104379814A (en) 2015-02-25
WO2013186094A2 (en) 2013-12-19
KR20150023709A (en) 2015-03-05
JP2015527483A (en) 2015-09-17
TW201400469A (en) 2014-01-01
EP2861785A2 (en) 2015-04-22
CA2876566A1 (en) 2013-12-19

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