WO2013166780A1 - Wool lubricant for wool textile process - Google Patents

Wool lubricant for wool textile process Download PDF

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Publication number
WO2013166780A1
WO2013166780A1 PCT/CN2012/078795 CN2012078795W WO2013166780A1 WO 2013166780 A1 WO2013166780 A1 WO 2013166780A1 CN 2012078795 W CN2012078795 W CN 2012078795W WO 2013166780 A1 WO2013166780 A1 WO 2013166780A1
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WO
WIPO (PCT)
Prior art keywords
wool
coconut oil
oleate
ester
emulsion
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PCT/CN2012/078795
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French (fr)
Chinese (zh)
Inventor
唐青
孙克全
高桂新
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天津博克尼科技发展有限公司
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Publication of WO2013166780A1 publication Critical patent/WO2013166780A1/en

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters

Definitions

  • the invention relates to a hair styling agent for wool textile process, which is mainly used for wool textile process, and needs to be diluted into an emulsion when used.
  • the non-hair wool textile process has a large adhesiveness, and it is easy to cause wraparound rollers, wrap-around rings, and wrap-around rollers during the spinning process.
  • the poor wool textile process has poor stability and easy delamination, resulting in poor uniform adhesion on the wool fibers, resulting in uneven drafting of the fibers, directly affecting the uniform drafting of the tops and the breakage rate of the spun yarns; Difficult to do, rework, and oil replenishment, affecting production efficiency and yarn quality.
  • Non-woven wool textiles The anti-static properties of the styling oil are generally caused by the phenomenon of flying hair during the spinning process.
  • the object of the present invention is to provide a good wool textile process and a hair oil agent, and the stability of the stock solution and the emulsion is good. It has good antistatic property, good washability, and reduces the problem of wraparound rolls and breakage rate in the coarse and fine yarn process, and improves the feel of the wool fabric.
  • the invention has good antistatic property, washability, good viscosity, good oxidation resistance, good permeability, smoothness and diffusibility to wool. Since the emulsion is a natural emulsification method, the operation is simple and the time is short, so that energy and labor consumption can be saved.
  • the ingredients of the present invention include: mineral oil, methyl oleate, butyl oleate, methyl oleate, coconut oil fatty acid polyethylene glycol (400) ester, coconut oil alkyl alcohol amide, organic amine and hydrophilic lipophilic Balance (HLB) regulators and other chemical products, the weight percentage of each component is: mineral oil 50-70%, oleic acid methanol ester 7 10%, oleic acid butanol 3-6%, coconut oleate 3-6%, coconut oil fatty acid polyethylene glycol (400) ester 8-12%, coconut oil alkyl alcohol amide 8-12%, organic amine 1-3%, hydrophilic lipophilic balance (HLB) regulation 1- 3%.
  • mineral oil 50-70% oleic acid methanol ester 7 10%, oleic acid butanol 3-6%, coconut oleate 3-6%
  • coconut oil fatty acid polyethylene glycol (400) ester 8-12% coconut oil alkyl alcohol amide 8-12%
  • organic amine 1-3%
  • the mineral oil of the invention is an industrial grade mineral oil, which is a base oil produced by hydrocracking as a raw material, deep After dewaxing, chemical refining and other processes are obtained.
  • hydrophilic lipophilic balance (HLB) modifier of the present invention is specifically specified as oleic acid.
  • the manufacturing process of the invention is characterized in that: mineral oil is added to the reaction kettle with heating device, heated to 60 ⁇ 2 ° C, stirred, and then methyl oleate, butyl oleate, methyl oleate, coconut oil
  • the fatty acid polyethylene glycol (400) ester, coconut oil alkyl alcohol amide, triethanolamine is slowly added to the mineral oil. After stirring for 60 minutes, adjust the oleic acid with a hydrophilic-lipophilic balance (HLB) modifier until the blister oil solution is transparent.
  • HLB hydrophilic-lipophilic balance
  • each component of the blended oil is: mineral oil 64%, oleic acid methyl ester 8%, butyl oleate 4%, coconut oleic acid methyl ester 4%, coconut oil fatty acid polyethylene glycol (400) ester 8%, coconut oil alkyl amide 8%, organic amine 2%, hydrophilic lipophilic balance (HLB) regulator about 2%
  • Compounding route Add 64 kg of mineral oil to the reactor with heating device, heat to 60 ⁇ 2 °C, stir, then add 8 kg of methyl oleate, 4 kg of butyl oleate, coconut oil 4 kg of ester, coconut oil fatty acid polyethylene glycol (400) ester 8 kg, coconut oil alkyl alcohol amide 8 kg, triethanolamine 2 kg slowly added to mineral oil. After stirring for 60 minutes, adjust the oleic acid solution to about 2 kg to make the blister oil solution transparent, and finally filter out the product.
  • the weight percentage of each component of the wool oil is: mineral oil 59%, methyl oleate 9%, butyl oleate 5%, coconut oleic acid methyl ester 5%, coconut oil fatty acid polyethylene glycol (400) ester 9%, coconut oil alkyl amide 9%, organic amine 2%, hydrophilic lipophilic balance (HLB) regulator about 2%
  • Compounding route Add 59 kg of mineral oil to the reactor with heating device, heat to 60 ⁇ 2 °C, stir, then add 9 kg of methyl oleate, 5 kg of butyl oleate, coconut oil 5 kg of ester, coconut oil fatty acid polyethylene glycol (400) ester 9 kg, coconut oil alkyl alcohol amide 9 kg, triethanolamine 2 kg slowly added to mineral oil. After stirring for 60 minutes, adjust the oleic acid solution to about 2 kg to make the blister oil solution transparent, and finally filter out the product.
  • the weight percentage of each component of the blended oil is: mineral oil 54%, methyl oleate 10%, butyl oleate 6%, coconut oleic acid methyl ester 6%, coconut oil fatty acid polyethylene glycol (400) ester 10%, coconut oil alkyl alcohol Amide 10%, organic amine 2%, hydrophilic-lipophilic balance (HLB) regulator approximately 2%

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to a wool lubricant for a wool textile process, which is mainly used by a wool textile process, and is required to be diluted into an emulsion for use. The present invention consists of 50-70% of mineral oil, 7-10% of methyl oleate, 3-6% of butyl oleate, 3-6% of coconut oil methyl ester, 8-12% of coconut oil fatty acid polyethylene glycol (400) ester, 8-12% of coconut oil alkanolamide, 1-3% of organic amine, and 1-3% of hydrophilic-lipophilic balance (HLB) modifier. The end product of the wool lubricant of the present invention is bright and transparent, with the pH value being 6-8 and the stability capable of reaching 180 days. The formed emulsion has blue light and the stability capable of reaching more than 48 hours. The present invention has desirable antistatic properties, washability, viscosity, and oxidation resistance, and has desirable performance in penetration, smoothing, and dispersing regarding wool. The emulsion is emulsified naturally, so that the operation is simple, and the time is short, thereby conserving energy and reducing consumption of labors.

Description

说 明 书  Description
一种毛纺织工艺用合毛油剂 Wool coating agent for wool textile process
【技术领域】  [Technical Field]
本发明涉及一种毛纺织工艺用合毛油剂， 主要用于毛纺织工艺用， 使用时需要 稀释成乳化液。  The invention relates to a hair styling agent for wool textile process, which is mainly used for wool textile process, and needs to be diluted into an emulsion when used.
【背景技术】  【Background technique】
不良毛纺织工艺用合毛油剂黏着性较大， 在纺纱过程中容易发生缠皮辊、缠胶 圈、 缠罗拉等现象。 不良毛纺织工艺用合毛油乳液稳定性差、 易分层， 造成在毛纤 维上均匀附着性不好， 使纤维的牵伸力不匀， 直接影响毛条均匀牵伸和细纱的断头 率； 同时生活难做、 有返工、 补油现象， 影响生产效率和纱的质量。 不良毛纺织工 艺用合毛油剂的抗静电性一般， 易造成纺纱过程中出现飞毛现象。  The non-hair wool textile process has a large adhesiveness, and it is easy to cause wraparound rollers, wrap-around rings, and wrap-around rollers during the spinning process. The poor wool textile process has poor stability and easy delamination, resulting in poor uniform adhesion on the wool fibers, resulting in uneven drafting of the fibers, directly affecting the uniform drafting of the tops and the breakage rate of the spun yarns; Difficult to do, rework, and oil replenishment, affecting production efficiency and yarn quality. Non-woven wool textiles The anti-static properties of the styling oil are generally caused by the phenomenon of flying hair during the spinning process.
【发明内容】  [Summary of the Invention]
本发明目的是提供一种良好毛纺织工艺用和毛油剂， 原液和乳液的稳定性好。 具有良好的抗静电性， 具有良好的可洗性， 减少粗、 细纱工序中缠皮辊和断头率的 问题， 提高毛织物的手感。  The object of the present invention is to provide a good wool textile process and a hair oil agent, and the stability of the stock solution and the emulsion is good. It has good antistatic property, good washability, and reduces the problem of wraparound rolls and breakage rate in the coarse and fine yarn process, and improves the feel of the wool fabric.
本发明制造过程中， 无废气、 废水、 固体废弃物， 符合国家环保生产标准。 本发明突出效果是： 和毛油剂成品光亮、 透明， pH值 6-8， 稳定性可达到 180 天。 乳液成型后， 有蓝光， 稳定性可达 48小时以上。  In the manufacturing process of the invention, no waste gas, waste water and solid waste are in compliance with national environmental protection production standards. The outstanding effects of the invention are as follows: The finished product of the oil is bright and transparent, the pH is 6-8, and the stability can reach 180 days. After the emulsion is formed, it has blue light and its stability can reach more than 48 hours.
本发明具有良好抗静电性、 可洗性， 黏度适宜、 抗氧化性好， 对羊毛有很好的 渗透性、 平滑性和扩散性。 因乳液是自然乳化法， 故操作简便、 时间短， 故可以节 约能源和人力消耗。  The invention has good antistatic property, washability, good viscosity, good oxidation resistance, good permeability, smoothness and diffusibility to wool. Since the emulsion is a natural emulsification method, the operation is simple and the time is short, so that energy and labor consumption can be saved.
本发明成分包括： 矿物油、 油酸甲酯、 油酸丁酯、 椰子油酸甲酯、 椰子油脂肪 酸聚乙二醇 （400) 酯、 椰子油烷基醇酰胺、 有机胺和亲水亲油平衡值 （HLB) 调 节剂等化学用品， 各个组分的重量百分比含量为： 矿物油 50-70%、 油酸甲醇酯 7 10%、 油酸丁醇酯 3-6%、 椰子油酸甲酯 3-6%、 椰子油脂肪酸聚乙二醇 （400) 酯 8-12%、 椰子油烷基醇酰胺 8-12%、 有机胺 1-3%、 亲水亲油平衡 （HLB ) 调节 1-3%。  The ingredients of the present invention include: mineral oil, methyl oleate, butyl oleate, methyl oleate, coconut oil fatty acid polyethylene glycol (400) ester, coconut oil alkyl alcohol amide, organic amine and hydrophilic lipophilic Balance (HLB) regulators and other chemical products, the weight percentage of each component is: mineral oil 50-70%, oleic acid methanol ester 7 10%, oleic acid butanol 3-6%, coconut oleate 3-6%, coconut oil fatty acid polyethylene glycol (400) ester 8-12%, coconut oil alkyl alcohol amide 8-12%, organic amine 1-3%, hydrophilic lipophilic balance (HLB) regulation 1- 3%.
本发明矿物油为工业级矿物油， 是由加氢裂化生产的基础油为原料， 经深 度脱蜡、 化学精制等工艺处理后得到。 The mineral oil of the invention is an industrial grade mineral oil, which is a base oil produced by hydrocracking as a raw material, deep After dewaxing, chemical refining and other processes are obtained.
本发明亲水亲油平衡值 （HLB) 调节剂特别规定为油酸。  The hydrophilic lipophilic balance (HLB) modifier of the present invention is specifically specified as oleic acid.
本发明整体配比中可加入适量香精， 以便在使用中可产生愉快香气。 本发明制作工艺特征在于： 在有加热装置的反应釜中加入矿物油， 加热至 60 ± 2 °C， 搅拌， 再依次将油酸甲酯， 油酸丁酯， 椰子油酸甲酯， 椰子油脂肪酸 聚乙二醇（400)酯， 椰子油烷基醇酰胺、 三乙醇胺缓慢加至矿物油中。 搅拌 60分 钟后， 用亲水亲油平衡值（HLB)调节剂油酸调至合毛油溶液透明为止， 最后过滤 An appropriate amount of flavor may be added to the overall ratio of the present invention to produce a pleasant aroma in use. The manufacturing process of the invention is characterized in that: mineral oil is added to the reaction kettle with heating device, heated to 60 ± 2 ° C, stirred, and then methyl oleate, butyl oleate, methyl oleate, coconut oil The fatty acid polyethylene glycol (400) ester, coconut oil alkyl alcohol amide, triethanolamine is slowly added to the mineral oil. After stirring for 60 minutes, adjust the oleic acid with a hydrophilic-lipophilic balance (HLB) modifier until the blister oil solution is transparent.
|_L| 口 |_L| 口
【具体实施方式】 【detailed description】
实施例 1  Example 1
合毛油各个组分的重量百分比含量是： 矿物油 64%、油酸甲酯 8%、油酸丁酯 4%、 椰子油酸甲酯 4%、 椰子油脂肪酸聚乙二醇（400)酯 8%、 椰子油烷基醇酰胺 8%、 有机胺 2%、 亲水亲油平衡 （HLB) 调节剂约为 2%  The weight percentage of each component of the blended oil is: mineral oil 64%, oleic acid methyl ester 8%, butyl oleate 4%, coconut oleic acid methyl ester 4%, coconut oil fatty acid polyethylene glycol (400) ester 8%, coconut oil alkyl amide 8%, organic amine 2%, hydrophilic lipophilic balance (HLB) regulator about 2%
复配工艺路线： 在有加热装置的反应釜中加入矿物油 64公斤， 加热至 60 ± 2 °C，搅拌， 再依次将油酸甲酯 8公斤，油酸丁酯 4公斤，椰子油酸甲酯 4公斤， 椰子油脂肪酸聚乙二醇 （400) 酯 8公斤， 椰子油烷基醇酰胺 8公斤、 三乙醇胺 2 公斤缓慢加至矿物油中。 搅拌 60分钟后， 用调节剂油酸约 2公斤调至合毛油溶液 透明为止， 最后过滤出品。  Compounding route: Add 64 kg of mineral oil to the reactor with heating device, heat to 60 ± 2 °C, stir, then add 8 kg of methyl oleate, 4 kg of butyl oleate, coconut oil 4 kg of ester, coconut oil fatty acid polyethylene glycol (400) ester 8 kg, coconut oil alkyl alcohol amide 8 kg, triethanolamine 2 kg slowly added to mineral oil. After stirring for 60 minutes, adjust the oleic acid solution to about 2 kg to make the blister oil solution transparent, and finally filter out the product.
实施例 2  Example 2
合毛油各个组分的重量百分比含量是： 矿物油 59%、油酸甲酯 9%、油酸丁酯 5%、 椰子油酸甲酯 5%、 椰子油脂肪酸聚乙二醇（400)酯 9%、 椰子油烷基醇酰胺 9%、 有机胺 2%、 亲水亲油平衡 （HLB) 调节剂约为 2%  The weight percentage of each component of the wool oil is: mineral oil 59%, methyl oleate 9%, butyl oleate 5%, coconut oleic acid methyl ester 5%, coconut oil fatty acid polyethylene glycol (400) ester 9%, coconut oil alkyl amide 9%, organic amine 2%, hydrophilic lipophilic balance (HLB) regulator about 2%
复配工艺路线： 在有加热装置的反应釜中加入矿物油 59公斤， 加热至 60 ± 2 °C，搅拌， 再依次将油酸甲酯 9公斤，油酸丁酯 5公斤，椰子油酸甲酯 5公斤， 椰子油脂肪酸聚乙二醇 （400) 酯 9公斤， 椰子油烷基醇酰胺 9公斤、 三乙醇胺 2 公斤缓慢加至矿物油中。 搅拌 60分钟后， 用调节剂油酸约 2公斤调至合毛油溶液 透明为止， 最后过滤出品。  Compounding route: Add 59 kg of mineral oil to the reactor with heating device, heat to 60 ± 2 °C, stir, then add 9 kg of methyl oleate, 5 kg of butyl oleate, coconut oil 5 kg of ester, coconut oil fatty acid polyethylene glycol (400) ester 9 kg, coconut oil alkyl alcohol amide 9 kg, triethanolamine 2 kg slowly added to mineral oil. After stirring for 60 minutes, adjust the oleic acid solution to about 2 kg to make the blister oil solution transparent, and finally filter out the product.
实施例 3  Example 3
合毛油各个组分的重量百分比含量是： 矿物油 54%、 油酸甲酯 10%、 油酸丁 酯 6%、 椰子油酸甲酯 6%、 椰子油脂肪酸聚乙二醇 （400) 酯 10%、 椰子油烷基醇 酰胺 10%、 有机胺 2%、 亲水亲油平衡 （HLB ) 调节剂约为 2% The weight percentage of each component of the blended oil is: mineral oil 54%, methyl oleate 10%, butyl oleate 6%, coconut oleic acid methyl ester 6%, coconut oil fatty acid polyethylene glycol (400) ester 10%, coconut oil alkyl alcohol Amide 10%, organic amine 2%, hydrophilic-lipophilic balance (HLB) regulator approximately 2%
复配工艺路线： 在有加热装置的反应釜中加入矿物油 54公斤， 加热至 60 ± 2 °C， 搅拌， 再依次将油酸甲酯 10公斤， 油酸丁酯 6公斤， 椰子油酸甲酯 6公 斤， 椰子油脂肪酸聚乙二醇 （400) 酯 10公斤， 椰子油烷基醇酰胺 10公斤、 三乙 醇胺 2公斤缓慢加至矿物油中。 搅拌 60分钟后， 用调节剂油酸约 2公斤调至合毛 油溶液透明为止， 最后过滤出品。  Compounding route: Add 54 kg of mineral oil to the reactor with heating device, heat to 60 ± 2 °C, stir, then add 10 kg of methyl oleate, 6 kg of butyl oleate, coconut oleate Ester 6 kg, coconut oil fatty acid polyethylene glycol (400) ester 10 kg, coconut oil alkyl alcohol amide 10 kg, triethanolamine 2 kg slowly added to mineral oil. After stirring for 60 minutes, the mixture was adjusted to about 2 kg of oleic acid until the blister oil solution was transparent, and finally the product was filtered.

Claims

权 j要 求 书 Right j request book
、 本发明涉及一种毛纺织工艺用合毛油剂， 主要用于毛纺织工艺用， 使用时需要 稀释成乳化液。 The invention relates to a hair styling agent for wool textile process, which is mainly used for the wool textile process, and needs to be diluted into an emulsion when used.
、 根据权利要求 1所述， 本发明由矿物油、油酸甲酯、油酸丁酯、椰子油酸甲酯、 椰子油脂肪酸聚乙二醇（400)酯、椰子油垸基醇酰胺、有机胺和亲水亲油平衡According to claim 1, the present invention comprises mineral oil, methyl oleate, butyl oleate, methyl oleate, coconut oil fatty acid polyethylene glycol (400) ester, coconut oil decyl alcohol amide, organic Amine and hydrophilic lipophilic balance
(HLB)调节剂组成。 (HLB) Modulator composition.
、 根据权利要求 1所述， 本发明其特征在于： 矿物油 50-70%、 油酸甲酯 7--10%、 油酸丁酯 3-6%、椰子油酸甲酯 3-6%、椰子油脂肪酸聚乙二醇（400)酯 8-12%、 椰子油垸基醇酰胺 8-12%、 有机胺 1-3%、 亲水亲油平衡（HLB)调节剂 1-3%。 、 根据权利要求 1所述，本发明亲水亲油平衡值（HLB)调节剂特别规定为油酸。 、 根据权利要求 1所述， 本发明制作工艺特征在于： 在有加热装置的反应釜中 加入矿物油， 加热至 60±2°C， 搅拌， 再依次将油酸甲酯， 油酸丁酯， 椰子 油酸甲酯， 椰子油脂肪酸聚乙二醇（400)酯， 椰子油烷基醇酰胺、三乙醇胺缓 慢加至矿物油中。搅拌 60分钟后， 用亲水亲油平衡值（HLB)调节剂油酸调至 合毛油溶液透明为止， 最后过滤出品。 According to claim 1, the invention is characterized in that: mineral oil 50-70%, methyl oleate 7-10%, butyl oleate 3-6%, methyl oleate 3-6%, Coconut oil fatty acid polyethylene glycol (400) ester 8-12%, coconut oil mercapto alcohol amide 8-12%, organic amine 1-3%, hydrophilic lipophilic balance (HLB) regulator 1-3%. According to claim 1, the hydrophilic lipophilic balance (HLB) modifier of the present invention is specifically specified as oleic acid. According to claim 1, the manufacturing process of the present invention is characterized in that: mineral oil is added to a reaction kettle equipped with a heating device, heated to 60 ± 2 ° C, stirred, and then methyl oleate, butyl oleate, Methyl coconut oleate, coconut oil fatty acid polyethylene glycol (400) ester, coconut oil alkyl alcohol amide, triethanolamine slowly added to mineral oil. After stirring for 60 minutes, the oleic acid was adjusted to a clear consistency with a hydrophilic lipophilic balance (HLB) regulator, oleic acid, and finally filtered.
、 根据权利要求 1所述， 本发明合毛油剂成品光亮、透明， pH值 6-8, 稳定性可 达到 180天。 乳液成型后， 有蓝光， 稳定性可达 48小时以上。 According to claim 1, the finished hair oil agent of the invention is bright and transparent, has a pH of 6-8, and has a stability of 180 days. After the emulsion is formed, it has blue light and its stability can reach more than 48 hours.
、 根据权利要求 1所述， 本发明具有良好抗静电性、 可洗性， 黏度适宜、 抗氧化 性好， 对羊毛有很好的渗透性、 平滑性和扩散性。 因乳液是自然乳化法， 故操 作简便、 时间短， 故可以节约能源和人力消耗。 According to claim 1, the invention has good antistatic property, washability, good viscosity, good oxidation resistance, good permeability, smoothness and diffusibility to wool. Since the emulsion is a natural emulsification method, it is easy to operate and short in time, so energy and manpower consumption can be saved.
4 4
替换页 （细则第 26条)  Replacement page (Article 26)
PCT/CN2012/078795 2012-05-11 2012-07-18 Wool lubricant for wool textile process WO2013166780A1 (en)

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