CN111576046A - Oil agent for spinning and stretching one-step method of crude oil oiling and preparation method thereof - Google Patents
Oil agent for spinning and stretching one-step method of crude oil oiling and preparation method thereof Download PDFInfo
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- CN111576046A CN111576046A CN202010327197.5A CN202010327197A CN111576046A CN 111576046 A CN111576046 A CN 111576046A CN 202010327197 A CN202010327197 A CN 202010327197A CN 111576046 A CN111576046 A CN 111576046A
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- agent
- oiling
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an oil agent for a spinning and drawing one-step method for oiling crude oil and a preparation method thereof, wherein the oil agent comprises the following components, namely a smoothing agent consisting of white oil with various viscosities; antistatic agent, one or the combination of fatty alcohol polyoxyethylene ether sylvite and quaternary ammonium salt; a bundling agent, one or the combination of high molecular weight polyoxypropylene ether and polyethylene glycol 400 dioleate; emulsifier, one or more of fatty acid polyoxyethylene ester, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether and sorbitan fatty acid ester. The oil agent for the spinning and stretching one-step method of crude oil oiling is convenient for subsequent use, does not need to be prepared with emulsion, saves the use of distilled water, and saves the labor cost for preparing the emulsion.
Description
The technical field is as follows:
the invention relates to the field of spinning production, in particular to an oiling agent for a spinning and stretching one-step method for oiling crude oil and a preparation method thereof.
Background art:
the FDY oiling agent has the defect of high energy consumption by preparing emulsion oiling at present, because the temperature is as high as 130-; in addition, the moisture evaporation process destroys the oil film, so that the oil film on the surface of the tows is broken more and oiling is not uniform, when the tows are stretched between HR2 and HR3 hot rollers and HR4 and HR5 hot rollers, the surface area is rapidly increased, the condition of non-uniform stretching occurs, and dyeing problems such as uneven evenness of the tows, poor dyeing uniformity, generation of section spots and the like are caused. In addition, if the existing FDY oil agent is directly oiled by crude oil, the crude oil has too high viscosity, and a hot roller is easy to coke, so that the requirement of oiling the crude oil on ibox-FDY equipment cannot be met. In addition, the existing FDY oil agent needs to be prepared with (15-20)% of emulsion for oiling, the emulsion is easy to decay, and finally, the pipeline of the oil agent pump is blocked. Meanwhile, the existing FDY needs to be prepared with emulsion for use, and a certain proportion of preservative needs to be added, so that the FDY volatilizes into the air when passing through a hot roller, has pungent smell, and affects environmental protection and human health.
The invention content is as follows:
the invention aims to solve the technical problem of providing the oiling agent for the spinning and stretching one-step method, which is convenient to use later, does not need to prepare emulsion and is suitable for oiling crude oil used on ibox-FDY equipment.
The technical proposal of the invention is to provide an oil agent for a spinning and drawing one-step method for oiling crude oil, which comprises the following components,
a smoothing agent consisting of white oil of various viscosities;
antistatic agent, one or the combination of fatty alcohol polyoxyethylene ether sylvite and quaternary ammonium salt;
a bundling agent, one or the combination of high molecular weight polyoxypropylene ether and polyethylene glycol 400 dioleate;
emulsifier, one or more of fatty acid polyoxyethylene ester, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether and sorbitan fatty acid ester;
balance regulator, higher fatty alcohol, higher fatty acid, or their combination.
Preferably, it contains the following components in percentage by mass,
preferably, it contains the following components in percentage by mass,
the invention also provides a preparation method of the oil agent for the spinning and stretching one-step method of crude oil oiling, which comprises the following steps of stirring and feeding, and simultaneously using a nitrogen bubbling device to fully and uniformly mix the materials, wherein the feeding sequence is as follows: emulsifier, bundling agent, smoothing agent, antistatic agent and balance regulator.
As preferred, each material preheats and stir evenly with the agitator before the feeding, avoids because of the long-time storage of material causes inhomogeneous phenomenon even layering, influences product stability.
Furthermore, the temperature of the reaction kettle is controlled to be 45 +/-2 ℃, so that the product condensation phenomenon caused by too low temperature and the change of the product performance caused by too high temperature are avoided.
Compared with the prior art, the invention has the following advantages after adopting the scheme: 1. the emulsion is convenient for subsequent use, and the emulsion does not need to be prepared, so that the use of distilled water is saved, and the labor cost for preparing the emulsion is saved; 2. when the hot roller passes through the hot roller, the volatile matter is not easy to volatilize, the coking on the hot roller is less, and the cleaning period of the hot roller can be prolonged; 3. electricity is saved, and heat brought away due to volatilization of emulsion moisture is greatly reduced when the emulsion passes through a hot roller; 4. the crude oil has long storage period and is not easy to decay, and the problem of pipeline blockage of an oil agent pump is solved; 5. dyeing and evenness are uniform, when crude oil is oiled, the phenomenon of oil film breakage caused by water evaporation when strand silk passes through the surface of a hot roller is obviously reduced, the oiling of the strand silk is more sufficient, the stretching is more uniform, and the dyeing performance of the strand silk is better; 6. the friction coefficient between the strand silk and the porcelain piece is effectively reduced, and the generation of broken silk is reduced; crude oil is oiled, the formed oil film is firmer, the surface of the strand silk can not change along with the evaporation of water on the surface of the hot roller, and the oil film is not easy to break under the drawing extrusion and high-temperature heating of the hot roller; 7. the spinning cake has good appearance and forming. Crude oil oiling is adopted to replace emulsion oiling, the appearance of a spinning cake package is produced, the side surface is obviously smoother, and spiral lines are obviously reduced; 8. the main physical indexes of the FDY yarn are normal; the FDY oiling agent is adopted for direct oiling, and a preservative is not needed, so that the defect caused by high-temperature volatilization of the preservative is overcome.
The specific implementation mode is as follows:
the invention is further illustrated with respect to specific embodiments below:
an oil agent for a spinning and drawing one-step method for oiling crude oil, which comprises the following components,
a smoothing agent for smoothing, which consists of white oil with various viscosities;
the antistatic agent plays a role in eliminating static electricity, and is one or the combination of fatty alcohol-polyoxyethylene ether potassium salt and quaternary ammonium salt;
the bundling agent plays a role in cohesion, and one or the combination of high-molecular-weight polyoxypropylene ether and polyethylene glycol 400 dioleate;
the emulsifier plays roles of emulsification, wetting and washing, and is one or a combination of more of fatty acid polyoxyethylene ester, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether and sorbitan fatty acid ester;
balance regulator for regulating emulsification balance, one or combination of higher fatty alcohol and higher fatty acid.
During preparation, the emulsifier, the bundling agent, the smoothing agent, the antistatic agent and the balance regulator are added in sequence.
Example 1
An oil agent for a spinning and stretching one-step method for oiling crude oil comprises the following components in percentage by mass,
the preparation method comprises the following steps of stirring and charging, and simultaneously using a nitrogen bubbling device to fully and uniformly mix the materials, wherein the charging sequence is as follows: emulsifier, bundling agent, smoothing agent, antistatic agent and balance regulator. In addition, each material is preheated before being fed and is uniformly stirred by a stirrer, so that the phenomenon of non-uniformity and even layering caused by long-time storage of the materials is avoided, and the stability of the product is not influenced; the temperature of the reaction kettle is controlled to be 45 +/-2 ℃, so that the product condensation phenomenon caused by too low temperature and the change of the product performance caused by too high temperature are avoided.
Example 2
An oil agent for a spinning and stretching one-step method for oiling crude oil comprises the following components in percentage by mass,
the preparation is as in example 1.
The comparative example was selected from the prior art emulsion products.
The experimental control table is shown in table 1 below:
TABLE 1
Further, the influence on the yarn levelness CV and the dyeing M ratio is shown in Table 2,
TABLE 2
The effect on the rate of decrease in fuzz, as shown in table 3,
TABLE 3
Influence on the main physical index of FDY yarn, as shown in Table 4
TABLE 4
Therefore, the following advantages are provided: 1. the emulsion is convenient for subsequent use, and the emulsion does not need to be prepared, so that the use of distilled water is saved, and the labor cost for preparing the emulsion is saved; 2. when the hot roller passes through the hot roller, the volatile matter is not easy to volatilize, the coking on the hot roller is less, and the cleaning period of the hot roller can be prolonged; 3. electricity is saved, and heat brought away due to volatilization of emulsion moisture is greatly reduced when the emulsion passes through a hot roller; 4. the crude oil has long storage period and is not easy to decay, and the problem of pipeline blockage of an oil agent pump is solved; 5. dyeing and evenness are uniform, when crude oil is oiled, the phenomenon of oil film breakage caused by water evaporation when strand silk passes through the surface of a hot roller is obviously reduced, the oiling of the strand silk is more sufficient, the stretching is more uniform, and the dyeing performance of the strand silk is better (as shown in a table 2); 6. the friction coefficient between the strand silk and the porcelain piece is effectively reduced, and the generation of broken silk is reduced; crude oil is oiled, the formed oil film is firmer, the surface of the strand silk can not change along with the evaporation of water on the surface of the hot roller, the oil film is not easy to break (as shown in table 3)7 under the drawing extrusion and high-temperature heating of the hot roller, and the appearance of the spinning cake is well formed. Crude oil oiling is adopted to replace emulsion oiling, the appearance of a spinning cake package is produced, the side surface is obviously smoother, and spiral lines are obviously reduced; 8. the main physical indexes of the FDY yarn are normal (as shown in Table 4); the FDY oiling agent is adopted for direct oiling, and a preservative is not needed, so that the defect caused by high-temperature volatilization of the preservative is overcome.
The foregoing is illustrative of the preferred embodiments of the present invention only and is not to be construed as limiting the claims. All equivalent process changes made by the present specification are included in the scope of the present invention.
Claims (6)
1. An oiling agent for a spinning and stretching one-step method of crude oil oiling is characterized in that: which comprises the following components in percentage by weight,
a smoothing agent consisting of white oil of various viscosities;
antistatic agent, one or the combination of fatty alcohol polyoxyethylene ether sylvite and quaternary ammonium salt;
a bundling agent, one or the combination of high molecular weight polyoxypropylene ether and polyethylene glycol 400 dioleate;
emulsifier, one or more of fatty acid polyoxyethylene ester, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether and sorbitan fatty acid ester;
balance regulator, higher fatty alcohol, higher fatty acid, or their combination.
2. An oil for a spinning and drawing one-step process on crude oil according to claim 1, characterized in that: the composite material comprises the following components in percentage by mass,
3. an oil for a spinning and drawing one-step process on crude oil according to claim 1, characterized in that: the composite material comprises the following components in percentage by mass,
4. a process for the preparation of a finish for a spin draw one step process for oiling crude oil as defined in any of claims 1 to 3, characterized in that: carry out following operation, adopt the mode of reinforced while stirring to use nitrogen gas bubbling device simultaneously, make each material intensive mixing even, reinforced order is: emulsifier, bundling agent, smoothing agent, antistatic agent and balance regulator.
5. The method for preparing an oiling agent for a spinning and drawing one-step method on crude oil according to claim 4, which is characterized in that: the materials were preheated and stirred well with a stirrer before being fed.
6. The method for preparing an oiling agent for a spinning and drawing one-step method on crude oil according to claim 4, which is characterized in that: the temperature of the reaction kettle is controlled at 45 +/-2 ℃.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010327197.5A CN111576046A (en) | 2020-04-23 | 2020-04-23 | Oil agent for spinning and stretching one-step method of crude oil oiling and preparation method thereof |
| PCT/CN2020/127056 WO2021212808A1 (en) | 2020-04-23 | 2020-11-06 | Oil agent for one-step spinning drawing method with crude oil oiling and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010327197.5A CN111576046A (en) | 2020-04-23 | 2020-04-23 | Oil agent for spinning and stretching one-step method of crude oil oiling and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN111576046A true CN111576046A (en) | 2020-08-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010327197.5A Pending CN111576046A (en) | 2020-04-23 | 2020-04-23 | Oil agent for spinning and stretching one-step method of crude oil oiling and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN111576046A (en) |
| WO (1) | WO2021212808A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021212808A1 (en) * | 2020-04-23 | 2021-10-28 | 桐乡市恒隆化工有限公司 | Oil agent for one-step spinning drawing method with crude oil oiling and preparation method therefor |
| CN113818104A (en) * | 2021-09-27 | 2021-12-21 | 江苏悦孚油品有限公司 | Superfine denier filament spinning oil and preparation method thereof |
| CN113969436A (en) * | 2021-12-10 | 2022-01-25 | 江苏悦孚油品有限公司 | Chinlon spinning oil and preparation method thereof |
| CN115404570A (en) * | 2022-09-22 | 2022-11-29 | 桐乡市恒隆化工有限公司 | FDY oil agent for superfine denier fibers and preparation method thereof |
| CN115897002A (en) * | 2022-11-24 | 2023-04-04 | 桐乡市华家那羊绒服饰有限公司 | Chitosan/cashmere blended yarn roving production process |
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| CN113818104A (en) * | 2021-09-27 | 2021-12-21 | 江苏悦孚油品有限公司 | Superfine denier filament spinning oil and preparation method thereof |
| CN113969436A (en) * | 2021-12-10 | 2022-01-25 | 江苏悦孚油品有限公司 | Chinlon spinning oil and preparation method thereof |
| CN115404570A (en) * | 2022-09-22 | 2022-11-29 | 桐乡市恒隆化工有限公司 | FDY oil agent for superfine denier fibers and preparation method thereof |
| CN115897002A (en) * | 2022-11-24 | 2023-04-04 | 桐乡市华家那羊绒服饰有限公司 | Chitosan/cashmere blended yarn roving production process |
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| WO2021212808A1 (en) | 2021-10-28 |
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Application publication date: 20200825 |
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