WO2013162891A1 - Methods and apparatus for active substrate precession during chemical mechanical polishing - Google Patents

Methods and apparatus for active substrate precession during chemical mechanical polishing Download PDF

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Publication number
WO2013162891A1
WO2013162891A1 PCT/US2013/036034 US2013036034W WO2013162891A1 WO 2013162891 A1 WO2013162891 A1 WO 2013162891A1 US 2013036034 W US2013036034 W US 2013036034W WO 2013162891 A1 WO2013162891 A1 WO 2013162891A1
Authority
WO
WIPO (PCT)
Prior art keywords
polishing
substrate
retaining ring
spindle
during
Prior art date
Application number
PCT/US2013/036034
Other languages
English (en)
French (fr)
Inventor
Hung Chen
Lakshmanan Karuppiah
Original Assignee
Applied Materials, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Applied Materials, Inc. filed Critical Applied Materials, Inc.
Priority to JP2015509005A priority Critical patent/JP2015514599A/ja
Priority to KR20147033300A priority patent/KR20150005672A/ko
Publication of WO2013162891A1 publication Critical patent/WO2013162891A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/27Work carriers
    • B24B37/30Work carriers for single side lapping of plane surfaces
    • B24B37/32Retaining rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B47/00Drives or gearings; Equipment therefor
    • B24B47/10Drives or gearings; Equipment therefor for rotating or reciprocating working-spindles carrying grinding wheels or workpieces

Definitions

  • the present invention relates to semiconductor device processing, and more particularly to active substrate precession during chemical mechanical polishing.
  • a top surface of a substrate may be planarized between processing steps.
  • planarization typically is performed using an etch-back step or chemical mechanical polishing (CMP) .
  • CMP chemical mechanical polishing
  • a substrate is placed face down on a polishing pad and pressed against, and rotated relative to, the polishing pad via a polishing head in the presence of a slurry.
  • the slurry may contain abrasive particles and/or chemicals that assist in material removal from the
  • polishing is continued until enough material is removed to form a planar surface on the substrate. Maintaining uniformity across a substrate during CMP is important to ensure uniform layer thicknesses for devices formed on the substrate. However, maintaining thickness uniformity across the entire surface of a substrate is difficult. This is particularly true for larger diameter substrates. Therefore, a need exists for methods and apparatus for improving uniformity during chemical
  • a chemical mechanical polishing (CMP) apparatus includes a polishing head having (a) a rotatable spindle; (b) a membrane coupled to the rotatable spindle and adapted to press a substrate against a polishing pad during polishing of the substrate; and (c) a retaining ring rotatable coupled to the spindle and adapted to surround a substrate being pressed against a polishing pad during polishing and to limit lateral movement of the substrate relative to the polishing head.
  • the CMP apparatus also includes a drive mechanism coupled to the retaining ring and adapted to drive the retaining ring at a different rate of rotation than the spindle during polishing.
  • a chemical mechanical polishing apparatus includes a polishing head having (a) a rotatable spindle; (b) a membrane coupled to the rotatable spindle and adapted to press a substrate against a polishing pad during polishing of the substrate; (c) a retaining ring coupled to the spindle and adapted to
  • a method of polishing a substrate includes pressing the substrate against a polishing pad using a polishing head having (a) a rotatable spindle; (b) a membrane coupled to the rotatable spindle and adapted to press the substrate against the polishing pad during polishing of the substrate; and (c) a retaining ring rotatable coupled to the spindle and adapted to surround the substrate being pressed against the polishing pad during polishing and to limit lateral movement of the substrate relative to the polishing head.
  • the method includes rotating the spindle and membrane of the polishing head at a first rotation rate during polishing; and rotating the retaining ring of the polishing head at a second rotation rate during polishing so as to cause the substrate to rotate relative to the membrane of the polishing head.
  • a method of polishing a substrate includes pressing the substrate against a polishing pad using a polishing head having (a) a rotatable spindle; (b) a membrane coupled to the rotatable spindle and adapted to press the substrate against the polishing pad during polishing of the substrate; (c) a retaining ring coupled to the spindle and adapted to surround the substrate being pressed against the polishing pad during polishing and to limit lateral movement of the substrate relative to the polishing head; and (d) at least one rotation mechanism coupled to the retaining ring, adapted to contact the substrate during polishing and adapted to allow the
  • the method includes rotating the spindle and membrane of the polishing head at a first rotation rate during polishing; and rotating the at least one rotation mechanism coupled to the retaining ring of the polishing head at a second rotation rate during polishing so as to cause the substrate to rotate relative to the membrane of the polishing head.
  • FIG. 1 is a schematic diagram depicting a side view of an example chemical-mechanical planarization system for polishing substrates according to embodiments.
  • FIGS. 2A-2B are top schematic views of a substrate and retaining ring during polishing in accordance with
  • FIG. 3 is a schematic side view of a first embodiment of an example polishing system provided in accordance with the present invention.
  • FIG. 4A is a schematic side view of a second embodiment of an example polishing system provided in accordance with the present invention.
  • FIGS. 4B-4C are schematic top views of example
  • the present invention provides methods and apparatus for improving uniformity during chemical mechanical
  • polishing of large substrates e.g., semiconductor wafers, glass substrates used for liquid crystal displays (LCDs) or solar cells, or any other similar underlying and/or
  • a substrate is placed face down on a polishing pad and pressed against, and rotated relative to, the polishing pad via a polishing head.
  • a slurry containing abrasive particles and/or chemicals may be supplied to the polishing pad to assist in material removal from the substrate as the substrate is pressed against and rotated relative to the polishing pad. In this manner, the top surface of the substrate may be planarized.
  • FIG. 1 illustrates a side view of an example chemical- mechanical planarization (CMP) system 100 for polishing substrates in accordance with the present invention.
  • the system 100 includes a load cup assembly 102 for receiving a substrate (not shown in FIG. 1) to be polished and for holding the substrate in place for a polishing head 104 to pick up.
  • the polishing head 104 is supported by an arm 106 that is operative to move the head 104 between the load cup assembly 102 and a polishing pad 108 on a rotating platen 110. In operation, the polishing head 104 picks up the substrate from the load cup assembly 102 and carries it to the polishing pad 108.
  • CMP chemical- mechanical planarization
  • the head 104 rotates and pushes the substrate down against the polishing pad 108.
  • an expandable membrane 111 within the polishing head 104 may contact and press the substrate against the polishing pad 108.
  • the diameter of the polishing pad 108 is more than twice that of the substrate.
  • Other platen, polishing pad and/or substrate sizes may be used .
  • the polishing head 104 includes a retaining ring 204 that surrounds the substrate 202 and limits its lateral movement during
  • the substrate 202 has a slightly smaller diameter Di than a diameter D2 of the retaining ring 204 (forming a gap 206 between the substrate 202 and retaining ring 204 which is exaggerated in FIGS. 2A-2B) .
  • the gap 206 may be about 0.01 inches, although other gap sizes may be used.
  • Rotation of the polishing pad 108 during polishing generates a force that presses the substrate 202 against the retaining ring 204 as shown in FIG. 2B (causing the center of rotation of the substrate 202 to no longer align with the center of rotation of the polishing head 104 and retaining ring 204) .
  • the polishing head 104 is rotated during polishing, which causes the retaining ring 204 to similarly rotate.
  • This rotation of the retaining ring 204 causes rotation (precession) of the substrate 202 in a manner similar to a gear wheel due to the misalignment of the centers of rotation of the substrate 202 and retaining ring 204.
  • the membrane 111 of the polishing head 104 used to press the substrate 202 against the polishing pad 108 typically has a low coefficient of friction, allowing the substrate 202 to rotate relative to the
  • the polishing head 104 may generate a non- concentric pressure profile as it presses the substrate 202 against the polishing pad 108.
  • a non-concentric pressure profile may produce a non-concentric and/or
  • the mismatch between the diameter of the substrate 202 and the retaining ring 204 is typically large enough to allow the substrate 202 to precess about 180 degrees or more relative to the polishing head 104 during polishing. This is generally sufficient to reduce and/or mask any asymmetric polishing profile that might otherwise result from a
  • polishing head 's non-concentric pressure profile.
  • any asymmetric polishing profile is undesirable.
  • precession may be insufficient to mask the asymmetric polishing profile resulting from a non-concentric polishing head pressure profile.
  • a polishing head/retaining ring configuration is employed that allows active control over the amount a substrate precesses during polishing.
  • precession allows a substrate to precess sufficiently to reduce and/or minimize the asymmetric polishing profile resulting from a non-concentric polishing head pressure profile. This is beneficial to substrates of any size
  • FIG. 3 is a schematic side view of a first embodiment of an example polishing system 300 provided in accordance with the present invention.
  • the polishing system 300 includes polishing head 104 coupled to a controller 302.
  • the controller 302 may be a computer, a microcontroller, a programmable logic controller or any other suitable controller.
  • Polishing head 104 includes a central spindle 304 rotatably coupled to a retaining ring 204 via one or more bearing assemblies 306.
  • a membrane 308 is coupled to the central spindle 304 and may contact substrate 202, pressing substrate 202 against polishing pad 108.
  • the membrane 308 is adapted to expand to press the substrate 202 against the polishing pad 108.
  • the membrane 308 may be a liquid or gas filled bladder.
  • the portion of the membrane 308 that contacts the substrate 202 may be a low friction material such as
  • PTFE polytetrafluoroethylene
  • Spindle 304 is coupled to a first drive mechanism 310 and retaining ring 204 is coupled to a second drive
  • Controller 302 may include computer program code for directing rotation of spindle 304 and/or retaining ring 204 during polishing as described further below.
  • Bearing assembly 306 keeps retaining ring 204
  • bearing assembly 306 concentric with membrane 308 and may comprise any suitable bearing assembly such as ball bearings, roller bearings, slide bearings, track bearings, non-contact bearings, or the like.
  • the components of the bearing assembly 306, such as the balls and races, may be formed of a material compatible with the chemistry used during chemical mechanical polishing within the polishing system 300 so as not to degrade rapidly or generate particles that could contaminate a substrate being polished.
  • the bearing assembly 306 may be formed of a suitable polymer material.
  • the bearing assembly 306 may be shielded, sealed or otherwise isolated from the polishing chemistry.
  • substrate 202 is placed on the polishing pad 108 and is pressed against the polishing pad 108 by polishing head 104 (via expansion of membrane 308) .
  • Retaining ring 204 surrounds substrate 202 within the polishing head 104, and also contacts polishing pad 108. Note that a suitable abrasive slurry (not shown) may be applied to the polishing pad 108 before and/or during polishing of the substrate 202.
  • Controller 302 causes drive 310 to rotate spindle 304 and membrane 308 as indicated by arrow 314, and drive 312 to rotate retaining ring 204 as indicated by arrow 316.
  • Polishing pad 108 is also rotated using the same or a different drive mechanism under control of controller 302 or another controller (not shown) . As stated, rotation of polishing pad 108 causes substrate 202 to slide into contact with retaining ring 204 as indicated by arrow 318. In some embodiments, retaining ring 204 is rotated at a faster rate than spindle 304. In other embodiments,
  • retaining ring 204 is rotated at a slower rate than spindle 304. In either case, retaining ring 204 and spindle 304 rotate at different rates so that substrate 302 is actively precessed relative to membrane 308 (e.g., so that substrate 202 fully rotates beneath membrane 308 during polishing) .
  • spindle 304 may be rotated at a rate of about 10 to about 150 rotations per minute (RPM) , while retaining ring 204 may be rotated at a rate of about 5 to about 300 RPM.
  • RPM rotations per minute
  • retaining ring 204 may be rotated at about one-half the rotation rate of spindle 304, while in other embodiments, retaining ring 204 may be rotated at about twice the
  • rotation rate of spindle 304 may be used for the spindle 304 and/or retaining ring 204.
  • Retaining ring 204 may be rotated during a portion of or the entire time spindle 304 is rotated, and/or may be maintained stationary one or more times during polishing. Further, in some embodiments, retaining ring 204 may switch direction of rotation during polishing.
  • Polishing of substrate 202 continues until a desired amount of material is removed from the substrate 202.
  • substrate 202 is actively precessed relative to membrane 308 and non-concentric or otherwise asymmetric polishing head pressure profile is averaged out during polishing (e.g., producing a more uniform polish) .
  • This is beneficial to substrates of any size (e.g., 200 mm, 300 mm, 450 mm or other sized semiconductor wafers, or any other substrate type or size) .
  • FIG. 4A is a schematic side view of a second embodiment of an example polishing system 400 provided in accordance with the present invention.
  • the polishing system 400 of FIG. 4A is similar to the polishing system 300 of FIG. 3. However, in the polishing system 400 of FIG. 4A, the
  • FIG. 4B is a schematic top view of the polishing system 400 showing two rollers 404a and 404b. It will be understood that other numbers of rollers may be used (e.g., 3, 4, 5, etc.).
  • Rollers 404a and 404b may be formed from any suitable material such as polyphenylene sulfide (PPS) ,
  • rollers 404a-b may range from about 0.5 to about 2 inches. In some
  • the rollers 404a-b may be spaced apart by about 1 to 5 inches. Other materials, sizes and/or spacings may be used for the rollers.
  • Controller 302 causes drive 310 to rotate spindle 304 and membrane 308 as indicated by arrow 314, and drive 312 to rotate rollers 404a and 404b as indicated by arrow 416.
  • a single drive mechanism may be used to rotate spindle 304, roller 404a and/or roller 404b through use of appropriate belts, gears or the like; or a separate drive mechanism may be used as shown in FIG. 4A.
  • Polishing pad 108 is also rotated using the same or a different drive mechanism under control of controller 302 or another
  • rollers 404a and 404b are rotated at a faster rate than spindle 304. In other embodiments, rollers 404a and 404b are rotated at a slower rate than spindle 304. In either case, rollers 404a-b and spindle 304 rotate at different rates so that substrate 302 is actively precessed relative to membrane 308 (e.g., so that substrate 202 fully rotates beneath membrane 308 during polishing) .
  • spindle 304 may be rotated at a rate of about 10 to about 150 rotations per minute (RPM)
  • rollers 404a-b may be rotated at a rate of about 30 to about 3600 RPM (depending on the diameter of the rollers) .
  • rollers 404a-b may be rotated so that substrate 202 rotates at about one- half the rotation rate of spindle 304, while in other embodiments, rollers 404a-b may be rotated so that substrate 202 rotates at about twice the rotation rate of spindle 304.
  • Other rotation rates may be used for the spindle 304 and/or rollers 404a-b.
  • Rollers 404a-b may be rotated during a portion of or the entire time spindle 304 is rotated, and/or may be maintained stationary one or more times during polishing. Further, in some embodiments, rollers 404a-b may switch direction of rotation during polishing.
  • Polishing of substrate 202 continues until a desired amount of material is removed from the substrate 202.
  • rollers 404a-b rotate at a different rate than spindle 204, substrate 202 is actively precessed relative to membrane 308 and any non-concentric or otherwise asymmetric polishing head pressure profile is averaged out during polishing (e.g., producing a more uniform polish) .
  • This is beneficial to substrates of any size (e.g., 200 mm, 300 mm, 450 mm or other sized semiconductor wafers, or any other substrate type or size) .
  • retaining ring 204 may be formed from any suitable material such as polyphenylene sulfide (PPS) , polyetheretherketone (PEEK) , polyethyleneterephphalate or the like.
  • PPS polyphenylene sulfide
  • PEEK polyetheretherketone
  • the retaining ring 204 may be modified to improve substrate edge polish behavior. For example, features used to allow entry of slurry into the polishing head 104 may be modified depending on the
  • the retaining ring 204 may have different geometries (e.g., widths) along the trailing and leading edges of the retaining ring 204.
  • FIG. 4D illustrates a retaining ring 204 having larger and/or more slurry grooves 420a along a leading edge of the retaining ring 204 than slurry grooves 420b along the trailing edge of the retaining ring 204.
  • FIG. 4E illustrates a retaining ring 204 that is wider along a leading edge of the retaining ring 204 than along a trailing edge of the retaining ring 204. Such an arrangement may be reversed if desired .

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
PCT/US2013/036034 2012-04-27 2013-04-10 Methods and apparatus for active substrate precession during chemical mechanical polishing WO2013162891A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2015509005A JP2015514599A (ja) 2012-04-27 2013-04-10 化学機械研磨中のアクティブ基板歳差運動のための方法および装置
KR20147033300A KR20150005672A (ko) 2012-04-27 2013-04-10 화학적 기계적 폴리싱 동안의 능동적 기판 프리세션을 위한 방법 및 장치

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/459,075 2012-04-27
US13/459,075 US20130288577A1 (en) 2012-04-27 2012-04-27 Methods and apparatus for active substrate precession during chemical mechanical polishing

Publications (1)

Publication Number Publication Date
WO2013162891A1 true WO2013162891A1 (en) 2013-10-31

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PCT/US2013/036034 WO2013162891A1 (en) 2012-04-27 2013-04-10 Methods and apparatus for active substrate precession during chemical mechanical polishing

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US (1) US20130288577A1 (ja)
JP (1) JP2015514599A (ja)
KR (1) KR20150005672A (ja)
TW (1) TW201404535A (ja)
WO (1) WO2013162891A1 (ja)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9050700B2 (en) 2012-01-27 2015-06-09 Applied Materials, Inc. Methods and apparatus for an improved polishing head retaining ring
US20140273756A1 (en) * 2013-03-14 2014-09-18 Chih Hung Chen Substrate precession mechanism for cmp polishing head
DE112015002319T5 (de) 2014-12-31 2017-02-09 Osaka University Planarisierungsbearbeitungsverfahren und Planarisierungsbearbeitungsvorrichtung
JP6187948B1 (ja) * 2016-03-11 2017-08-30 東邦エンジニアリング株式会社 平坦加工装置、その動作方法および加工物の製造方法
CN105881527A (zh) * 2016-05-16 2016-08-24 苏州辰轩光电科技有限公司 全自动垂直机械手
KR102459832B1 (ko) * 2017-11-22 2022-10-28 주식회사 케이씨텍 캐리어

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6012964A (en) * 1997-12-11 2000-01-11 Speedfam Co., Ltd Carrier and CMP apparatus
KR100430581B1 (ko) * 2001-12-11 2004-05-10 동부전자 주식회사 Cmp 장치의 상부링
US20050037694A1 (en) * 2002-07-08 2005-02-17 Taylor Theodore M. Retaining rings, planarizing apparatuses including retaining rings, and methods for planarizing micro-device workpieces
US20060035564A1 (en) * 2003-11-24 2006-02-16 Nikon Corporation Fine force actuator assembly for chemical mechanical polishing apparatuses
US20070054603A1 (en) * 2004-03-05 2007-03-08 Strasbaugh Wafer carrier with pressurized membrane and retaining ring actuator

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6224472B1 (en) * 1999-06-24 2001-05-01 Samsung Austin Semiconductor, L.P. Retaining ring for chemical mechanical polishing
US6540590B1 (en) * 2000-08-31 2003-04-01 Multi-Planar Technologies, Inc. Chemical mechanical polishing apparatus and method having a rotating retaining ring
US6893327B2 (en) * 2001-06-04 2005-05-17 Multi Planar Technologies, Inc. Chemical mechanical polishing apparatus and method having a retaining ring with a contoured surface
CN100400236C (zh) * 2002-09-27 2008-07-09 小松电子金属股份有限公司 一种研磨装置和晶片制造方法
US7029375B2 (en) * 2004-08-31 2006-04-18 Tech Semiconductor Pte. Ltd. Retaining ring structure for edge control during chemical-mechanical polishing

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6012964A (en) * 1997-12-11 2000-01-11 Speedfam Co., Ltd Carrier and CMP apparatus
KR100430581B1 (ko) * 2001-12-11 2004-05-10 동부전자 주식회사 Cmp 장치의 상부링
US20050037694A1 (en) * 2002-07-08 2005-02-17 Taylor Theodore M. Retaining rings, planarizing apparatuses including retaining rings, and methods for planarizing micro-device workpieces
US20060035564A1 (en) * 2003-11-24 2006-02-16 Nikon Corporation Fine force actuator assembly for chemical mechanical polishing apparatuses
US20070054603A1 (en) * 2004-03-05 2007-03-08 Strasbaugh Wafer carrier with pressurized membrane and retaining ring actuator

Also Published As

Publication number Publication date
KR20150005672A (ko) 2015-01-14
TW201404535A (zh) 2014-02-01
US20130288577A1 (en) 2013-10-31
JP2015514599A (ja) 2015-05-21

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