WO2013143247A1 - 一种铝基铅或铅合金复合阳极及其制备方法 - Google Patents

一种铝基铅或铅合金复合阳极及其制备方法 Download PDF

Info

Publication number
WO2013143247A1
WO2013143247A1 PCT/CN2012/079585 CN2012079585W WO2013143247A1 WO 2013143247 A1 WO2013143247 A1 WO 2013143247A1 CN 2012079585 W CN2012079585 W CN 2012079585W WO 2013143247 A1 WO2013143247 A1 WO 2013143247A1
Authority
WO
WIPO (PCT)
Prior art keywords
lead
aluminum
anode
lead alloy
bar
Prior art date
Application number
PCT/CN2012/079585
Other languages
English (en)
French (fr)
Inventor
郭忠诚
朱盘龙
Original Assignee
昆明理工恒达科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 昆明理工恒达科技有限公司 filed Critical 昆明理工恒达科技有限公司
Publication of WO2013143247A1 publication Critical patent/WO2013143247A1/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/0081—Casting in, on, or around objects which form part of the product pretreatment of the insert, e.g. for enhancing the bonding between insert and surrounding cast metal
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof

Definitions

  • the invention relates to a metal matrix composite material in the fields of non-ferrous metal smelting, storage batteries and the like, in particular to a method for preparing an aluminum-based lead and lead alloy composite anode. Background technique
  • the electrode material for electrolytic production the following basic requirements must be met: (1) good electrical conductivity; (2) strong corrosion resistance; (3) good mechanical strength and processing performance; (4) long service life and low cost; 5) The electrode reaction has good electrocatalytic performance.
  • Metallurgists and researchers have conducted extensive research and development to develop more excellent anode materials. Based on the current research and use at home and abroad, there are four main categories:
  • Lead and lead alloy anodes can basically meet the production needs and are widely used in the industrial production of non-ferrous metals.
  • the anode has the main advantages of good electrical conductivity, low melting point, low hardness, easy casting or calendering, stable in sulfuric acid medium, low manufacturing cost and the like.
  • the disadvantage is that the lead and lead-based alloy anodes have high oxygen evolution potential (close to IV) and the surface passivation film is not dense, and a large amount of non-conductive manganese dioxide is adsorbed during the electrolysis process, resulting in high electrolysis cell voltage (such as zinc electrowinning). 3. 2 ⁇ 3.
  • the current efficiency of the electrowinning process is low (75 ⁇ 90%);
  • the energy consumption is high (such as zinc electrowinning is 3200 ⁇ 3800 kWh/ton);
  • the anode life is short (6 ⁇ 12 months); Corrosion products of anode lead easily enter the cathode product, affecting the quality of the cathode product; low mechanical strength, easy deformation and short circuit.
  • Such anodes are composited on a lead and lead alloy matrix by deposition, coating, inlaying, etc. into a material having good oxygen electrocatalytic activity and high electrochemical stability.
  • the main advantage of this type of electrode compared to the lead-silver anode is that the multi-component lead-based alloy and the composite electrocatalytic lead-based anode improve some of the performance of the anode.
  • the disadvantage is that it does not fundamentally solve its shortcomings, especially the presence of more C1 in the electrolyte. C1—may replace the oxygen ions in the Pb0 2 lattice, causing intergranular damage, causing the lead-based anode to be severely corroded by C1.
  • Such anodes are based on titanium metal (Ti).
  • Ti titanium metal
  • Such anodes include titanium-based manganese dioxide anodes (Ti/Mn0 2 ) and titanium-based lead dioxide anodes (Ti/ Pb0 2 ) and so on.
  • the main advantages of this type of electrode are that the shape and size are very stable, which can eliminate the contamination of the anode lead product, reduce the oxygen evolution overpotential, and have strong corrosion resistance.
  • the disadvantages are high fabrication requirements, short lifetimes of the electrodes in the sulfuric acid medium, and the high cost of such anodes based on titanium.
  • Such a composite electrode material is made of lead alloy, aluminum or stainless steel, and is prepared by a process of: oil removal, zinc immersion (Zn) ⁇ lead plating (Pb) ⁇ electrochemical oxidation ⁇ pulsed electrodeposition of manganese dioxide (Mn0 2 ). take.
  • the main advantage of the electrode is that when the composite electrode material is used to form a dense film layer on the surface of the anode, the anode is in an insoluble state, which can improve the quality of the cathode product and reduce the quality of the cathode product. Slot voltage.
  • This anode material has shortcomings in the production process: the production process is too long and the production energy consumption is high. Dipping, lead plating, rinsing and other processes will produce a large amount of waste liquid, and environmental pollution is more serious. Summary of the invention
  • the object of the present invention is to provide a method for preparing an aluminum-based lead and lead alloy composite anode.
  • the advantages of the present invention are that the production cost can be significantly reduced, the mechanical strength can be improved, and the self-weight can be reduced.
  • the conductive property of the material is obviously improved, the effective conductive area is increased, and the shortcomings of the prior art described above are overcome.
  • An aluminum-based lead and lead alloy composite anode characterized in that: the core of the aluminum-based lead and lead alloy composite anode is an aluminum-based material, and the surface of the core of the core has a plurality of lines along the length direction The dovetail groove, the aluminum-based material is coated with a coating material layer as a composite material, and the outer surface of the composite material is processed by an increase in surface treatment and then processed into an anode plate surface; a conductive beam cast from pure lead and copper row; an anode plate The face and the conductive beam are welded to the anode by an acetylene flame.
  • the outer surface of the aluminum-based lead and lead alloy composite material is processed by an increase in surface treatment and then processed into an anode plate surface, and a conductive beam cast by pure lead and copper row; the anode plate surface and the conductive beam are welded into an anode by an acetylene flame.
  • the casting temperature is 480 ⁇ 500°C, and the copper bar material is T2.
  • the aluminum-based lead and lead alloy composite anode plate surface is an aluminum-based lead alloy composite material: a, bar ( ⁇ 6 ⁇
  • the surface area of the same size of the smooth plate surface area increased by 1 ⁇ 1. 5 times.
  • the aluminum-based lead alloy composite material is an aluminum-based material, and the surface of the core material has a plurality of linear dovetail grooves along the length of the aluminum material, and the aluminum-based material is coated with lead and lead alloy.
  • the coating layer is a composite material, and the outer surface of the composite material is treated with a circular arc convex or concave shape or a zigzag pattern.
  • the aluminum-based material is a rod of ⁇ 3 to ⁇ 20 mm or a thickness of 2 to 5 and a width of 30 to 1000 for the strip, and the material is pure aluminum or aluminum alloy.
  • the coating material is prepared by casting a composition of ⁇ 7 ⁇ 20 mm according to the proportion of each component of the lead alloy, and the thickness of the coating material is 1. 5 ⁇ 5 mm; the material is pure lead or lead alloy.
  • the width of the dovetail slot is 0. 5 ⁇ 3. 0 mm, the width is 0. 75 ⁇ 5.
  • the width of the dovetail slot is 0. 5 ⁇ 3. ⁇ 0 mm, depth 0 ⁇ 5 ⁇ 2 ⁇ 0 mm.
  • the outer surface of the finished composite material is treated as a circular convex or concave shape or a zigzag pattern, and the depth of the pattern is
  • a method for preparing an aluminum-based lead and lead alloy composite anode the process steps are as follows:
  • the aluminum-based material and the lead or lead alloy bar are fed into the coating device to coat the lead or lead alloy coating material layer;
  • the surface of the coating material layer is immediately added to the surface to obtain a circular convex or concave shape or a zigzag pattern; cooling is a composite material;
  • the aluminum-based lead and lead alloy composite material is processed into an anode plate surface by the shape: a.
  • the bar is straightened and bent into ⁇ 6 ⁇ 30 awake specifications; b.
  • the strip is straightened and then assembled into a specification thickness. 6 ⁇ 15 let, width 30 ⁇ 1000 let;
  • the conductive beam is cast with pure lead and copper row, and the casting temperature is 480 ⁇ 500 °C.
  • the anode plate surface and the conductive beam are welded into an anode by an acetylene flame.
  • the invention has the beneficial effects that the aluminum base is coated into the lead and lead alloy electrode materials by physical extrusion, the use amount of lead and lead alloy is reduced, the production cost can be significantly reduced, and the aluminum base has small density and high mechanical strength. At the same time, the advantages of lead and lead alloy electrodes are maintained. Due to the improvement in electrical conductivity and the increase in effective conductive area. It can reduce the material resistance and reduce its own voltage drop to reduce the voltage of the electrolytic cell and reduce the current density of the electrode. In the process of electrowinning, the purpose of improving current efficiency and reducing low energy consumption is achieved. In addition, the heat generated by the electrolytic cell can be reduced, and the cooling process of the liquid after electrolysis can be simplified.
  • Figure 1 Aluminum-based lead and lead alloy composite bar anode
  • Figure 2 Aluminium-based lead and lead alloy composite bar anode plate surface
  • Figure 4 Aluminium-based lead and lead alloy composite strip anode plate surface.
  • the width of the dovetail groove is 0.8 mm, the width is 1 ⁇ 2 mm, and the depth is 0.5 mm.
  • the surface of the aluminum rod of the dovetail groove is processed and roughened, and the length of the bristles is less than 0.3 mm.
  • the processed aluminum rods and lead rods are simultaneously fed into the coating machine for coating on the feeding line of the coating machine, and the layer of pure lead coated is 2 mm thick.
  • the pattern is a circular convex or concave shape or a zigzag pattern
  • the pattern depth is 0. 5 mm
  • the pattern radius is 0. 5 mm
  • the air cooling is obtained to obtain the ⁇ 10 mm aluminum-based lead composite material bar.
  • the ⁇ 10 mm aluminum-based lead composite bar is straightened and bent into a 1000 X 800 X 10 mm anode plate surface. As shown in Fig. 2, the distance between two adjacent bars is 5 mm.
  • the surface of the aluminum rod of the dovetail groove is roughened and roughened, and the length of the bristles is less than 0.5 mm.
  • the processed aluminum rods and lead-silver alloy rods are fed into the coating machine for coating on the feeding line of the coating machine, and the lead-silver alloy layer is 5 mm thick.
  • the table is added, and the pattern is a circular convex or concave shape or a zigzag pattern. 1.5 mm, with a radius of 1 mm, air-cooled to obtain an aluminum-based lead composite.
  • Aluminum-based lead and lead alloy composite bar ( ⁇ 30 ⁇ ) After straightening, it is bent into 1000X800X30 mm anode plate surface. As shown in Fig. 2, the distance between two adjacent bars is 15 mm.
  • lead alloy is cast into ⁇ 10.0 wake bar.
  • the dovetail slot is 1.5 mm wide, 2 mm wide and 0.5 mm deep.
  • the surface of the aluminum strip with the dovetail groove is roughened and roughened, and the length of the bristles is less than 0.5mm.
  • the processed aluminum strip and lead-tin alloy rod are sent to the coating machine for coating on the feeding line of the coating machine, and the thickness of the lead-tin alloy layer is 1.5 awake.
  • the pattern is a circular convex or concave shape or a zigzag pattern
  • the pattern depth is 0.5 mm
  • the pattern radius is 0.5 mm
  • the aluminum-based lead composite material is obtained by air cooling.
  • Aluminum-based lead and lead alloy composite strip (6X49 mm) After straightening and shearing (cutting length is 1000 awake), assembled into 1000X800X6 awake anode surface, as shown in Figure 4, adjacent two strips Wake up to 5 feet.
  • the lead alloy is prepared into a ⁇ 20.0 wake bar according to the ratio of SnO.6%.
  • the dovetail slot is 3 mm wide, 5 mm wide and 1 mm deep.
  • the surface of the aluminum strip with the dovetail groove is roughened and roughened, and the length of the bristles is less than 0.5mm.
  • the processed aluminum strip and lead-tin alloy rod are sent to the coating machine for coating on the feeding line of the coating machine, and the thickness of the lead-tin alloy layer is 5 awake.
  • the pattern is a circular convex or concave shape or a zigzag pattern.
  • the pattern depth is 1.5 mm
  • the pattern radius is 5 mm
  • the aluminum-based lead composite material is obtained by air cooling.
  • Aluminum-based lead and lead alloy composite strip (15X1010 mm) is straightened and sheared (shear length is 1000 awake), assembled into 1000X1010X15 awake anode plate surface, as shown in Figure 4, adjacent two strips Wake up to 15 feet. It is cast into a conductive beam with a pure lead and copper row at a temperature of 480 to 500 °C.
  • the anode plate surface and the conductive beam are welded to the anode by an acetylene flame, as shown in FIG.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

提供了一种铝基铅或铅合金复合阳极及其制备方法。阳极的材芯为铝基材料，材芯表面粗糙带毛刺开有若干条沿铝基材料长度方向的线状燕尾槽，铝基材料外包覆有包覆材料层即为复合材料，复合材料外表面经增表处理再经外形加工成阳极板面，阳极板面和导电梁通过乙炔焰焊接成阳极，导电梁由纯铅与铜排浇铸。制备方法包括：按铅或铅合金各组元比例配制浇铸成铅合金棒材；在铝基材料棒材表面加工若干条沿长度方向的线状燕尾槽；加工好燕尾槽的铝基材料棒材表面拉毛处理；铝基材料和铅或铅合金棒材送入包覆设备进行包覆铅或铅合金包覆材料层；包覆完后在包覆材料层表面立即进行增表处理得到圆弧凸凹状或锯齿状花纹；冷却即为复合材料；复合材料外表面经增表处理再经外形加工成阳极板面，由纯铅与铜排浇铸的导电梁，阳极板面和导电梁通过乙炔焰焊接成阳极。

Description

一种铝基铅或铅合金复合阳极及其制备方法 技术领域
本发明涉及有色金属冶炼、 蓄电池等领域的金属基复合材料， 尤其是一种铝基 铅及铅合金复合阳极制备方法。 背景技术
一般作为电解生产的电极材料必需满足以下基本要求： (1)良好的导电性； （2) 耐腐蚀性强； （3)机械强度和加工性能好； （4)使用寿命长、 费用低； （5)对电极反应 具有良好的电催化性能。 冶金工作者和科研工作者为开发性能更加优越的阳极材料 进行了大量的研究和开发。 综合国内外目前的研究和使用情况， 主要有以下四类：
1、 铅及铅合金阳极
铅和铅合金阳极基本上能满足生产需要， 目前在有色金属工业生产中得到广泛 应用。 该阳极其主要优点在于具有较好的导电性能， 且熔点、 硬度小， 易铸造或压 延成型；在硫酸介质中较稳定； 制造成本低等。其缺点是铅及铅基合金阳极存在析氧 过电位高（接近 IV)和表面钝化膜不致密、 电解过程中吸附大量不导电二氧化锰等， 导致电解槽电压高 （如锌电积为 3. 2〜3. 8V); 电积过程电流效率低 （75〜90%)； 能 耗高 （如锌电积为 3200〜3800千瓦时 /吨）； 阳极寿命短 （6〜12月）； 阳极铅的腐 蚀产物易进入阴极产品， 影响阴极产品质量； 机械强度低，容易变形引起短路等。
2、 复合电催化铅基阳极
此类阳极通过沉积、 涂覆、 镶嵌等方法在铅及铅合金基体上复合入析氧电催化 活性好和高的电化学稳定性的材料。该类电极与铅-银阳极相比，其主要优点在于多 元铅基合金和复合电催化铅基阳极虽然改进了阳极的部分性能。 其缺点是没有从根 本上解决其不足，特别是电解液中存在较多的 C1— 。 C1—可能取代 Pb02 晶格中的氧 离子，引起晶粒间的破坏，造成铅基阳极被 C1—严重腐蚀。
3、 钛基电催化阳极
此类阳极以金属钛（Ti ) 为基体， 主要有 2 种电极:一是薄涂层钛基阳极，其涂 层厚度从几微米到十几微米；二是厚涂层钛基阳极，其涂层厚度在 0. 5mm 以上，甚至 可达 3mm，此类阳极包括钛基二氧化锰阳极（ Ti/ Mn02 ) 、 钛基二氧化铅阳极（ Ti/ Pb02 ) 等。 该类电极与铅-银阳极相比， 其主要优点在于形状尺寸非常稳定，可消除 阳极铅对产品的污染， 降低析氧超电位， 耐腐蚀性强。 其缺点是制作技术要求高， 电极在硫酸介质中使用寿命较短， 而且此类阳极以钛为基体材料成本高。
4、 其它基体复合电催化阳极
此类复合电极材料以铅合金、 铝或不锈钢为基体， 采用： 除油→浸锌 （Zn ) → 镀铅 （Pb ) →电化学氧化→脉冲电沉积二氧化锰 （Mn02 ) 的工艺来制取。 该电极与 铅-银阳极相比，其主要优点在于使用该复合电极材料在电积金属时， 阳极表面形成 一层致密的膜层， 使阳极处于非溶状态， 能提高阴极产品的质量， 降低槽电压。 其 缺点是这种阳极材料在生产过程中存在不足： 生产流程过长， 生产能耗高。 浸锌、 镀铅、 漂洗等工艺， 会产生大量的废液， 环境污染较为严重。 发明内容
本发明的目的是提出一种铝基铅及铅合金复合阳极制备方法， 本发明的优点在 可显著降低生产成本， 提高机械强度， 降低自重。 明显提高材料导电性能， 增大有 效导电面积， 克服上述现有技术存在的不足。
本发明通过以下技术方案来实现
一种铝基铅及铅合金复合阳极， 其特征是： 所述的铝基铅及铅合金复合阳极的 材芯为铝基材料， 材芯表面粗糙带毛剌开有若干条沿长度方向的线状燕尾槽， 铝基 材料外包覆有包覆材料层即为复合材料， 复合材料外表面经增表处理再经外形加工 成阳极板面； 由纯铅与铜排浇铸的导电梁； 阳极板面和导电梁通过乙炔焰焊接成阳 极。
所述的铝基铅及铅合金复合材料外表面经增表处理再经外形加工成阳极板面， 由纯铅与铜排浇铸的导电梁； 阳极板面和导电梁通过乙炔焰焊接成阳极。 浇铸温度 480〜500°C， 铜排材质为 T2。
所述的铝基铅及铅合金复合阳极板面是铝基铅合金复合材料为： a、棒材（ Φ 6〜
Φ 30皿）弯曲后剪切端头成， 棒材弯曲后剪切成， 相邻 2根棒材距离 5〜15皿， 表 面积相对同尺寸光滑板表面积增大 1〜1. 5倍; b、带材（厚度 6〜15mm宽 30〜1000mm) 剪切成， 相邻 2根带材距离 5〜15 mm， 表面积相对同尺寸光滑板表面积增大 1〜1. 5 倍。 所述的铝基铅合金复合材料是材芯为铝基材料， 材芯表面粗糙带毛剌开有若干 条沿铝材长度方向的线状燕尾槽， 铝基材料外包覆有铅及铅合金包覆层即为复合材 料， 复合材料外表面经增表处理有圆弧凸凹状或者锯齿状花纹。
所述的铝基材料为 Φ 3〜Φ 20 mm的棒材或厚度 2〜5讓宽 30〜1000讓带材， 材 质为纯铝或铝合金。
所述的包覆材料为按铅合金各组元比例配制浇铸成 Φ 7〜Φ 20 mm的棒材， 包覆 材料层厚 1. 5〜5 mm; 材质为纯铅或铅合金。
所述的铝基材料表面粗糙带毛剌，毛剌长小于 0. 5 mm，开有若干条线状燕尾槽， 燕尾槽上宽 0. 5〜3. 0 mm， 下宽 0· 75〜5· 0 mm， 深 0· 5〜2· 0 mm。
所述的复合材料成品外表面增表处理为圆弧凸凹状或者锯齿状花纹， 花纹深度
0. 2〜1. 5 mm， 花纹圆弧半径 0. 5〜5 mm。
一种铝基铅及铅合金复合阳极的制备方法， 工艺步骤如下：
1、 按铅或铅合金各组元比例配制浇铸成铅合金棒材；
2、 在铝基材料棒材表面加工若干条沿铝材长度方向的线状燕尾槽；
3、 加工好燕尾槽的铝基材料棒材表面拉毛处理；
4、 铝基材料和铅或铅合金棒材送入包覆设备进行包覆铅或铅合金包覆材料层；
5、包覆完后在包覆材料层表面立即进行增表处理得到圆弧凸凹状或者锯齿状花 纹； 冷却即为复合材料；
6、 铝基铅及铅合金复合材料经外形加工成阳极板面其中： a、 棒材校直后弯曲 成 Φ 6〜Φ 30醒规格； b、带材校直后剪切组装成规格为厚度 6〜15讓、宽 30〜1000讓；
7、 导电梁用纯铅与铜排浇铸而成， 浇铸温度 480〜500°C。
8、 阳极板面和导电梁通过乙炔焰焊接成阳极。
本发明的有益效果是通过物理挤压将铝基包覆入铅及铅合金电极材料中减少了 铅及铅合金使用量可显著降低生产成本， 具备了铝基密度小， 机械强度高的特性， 同时保持了铅及铅合金电极的优点。 由于导电性能的提高和有效导电面积的增大。 可减小材料电阻降低自身电压降达到降低电解槽电压减小电积电流密度， 在电积过 程中达到提高电流效率降低低能耗的目的。此外还可减少电解槽产生的热量，简化电 解后液体的冷却工序。 附图说明
图 1铝基铅及铅合金复合棒材阳极；
图 2 铝基铅及铅合金复合棒材阳极板面；
图 3铝基铅及铅合金复合带材阳极；
图 4 铝基铅及铅合金复合带材阳极板面。
图中： 1、 铜排， 2、 导电梁包铅层， 3、 铝基铅及铅合金板面复合阳极板面。 具体实施方式
实施例 1
1、 浇铸纯铅成 Φ 7. 0 醒棒材。
2、取 Φ 6. 0 mm纯铝棒在表面加工长度方向线状燕尾槽 6条，燕尾槽上宽 0. 8 mm, 下宽 1· 2 mm, 深 0. 5 mm。
3、 加工好燕尾槽的铝棒表面磨粗拉毛处理， 毛剌长小于 0. 3 mm。
4、将加工好的铝棒和铅棒同时送入包覆机在包覆机进料线上进行包覆，包覆的 纯铅层厚 2 mm。
5、 包覆完立即进行增表处理， 花纹为圆弧凸凹状或者锯齿状花纹， 花纹深度 0. 5 mm, 花纹半径 0. 5 mm， 进行风冷获得 Φ 10 mm铝基铅复合材料棒材。
6、将 Φ 10 mm铝基铅复合材料棒材， 校直后弯曲成 1000 X 800 X 10 mm阳极板面， 如图 2所示， 相邻 2根棒材距离 5 mm。
7、 用纯铅与铜排在 480〜500°C温度下浇铸成导电梁。
8、 阳极板面和导电梁通过乙炔焰焊接成如图 1所示的阳极。
实施例 2
1、 按 AgO. 8%比例配制铅合金浇铸成 Φ 9. 5 醒棒材。
2、 取 Φ 20. 0 mm电工铝棒材 （型号 6201 ) 在表面加工长度方向线状燕尾槽 16 条， 燕尾槽上宽 1. 5 醒， 下宽 2 醒， 深 2. 0 醒。
3、 加工好燕尾槽的铝棒表面磨粗拉毛处理， 毛剌长小于 0. 5 mm。
4、将加工好的铝棒和铅银合金棒送入包覆机在包覆机进料线上进行包覆，铅银 合金层厚 5 mm。
5、 包覆完立即进行增表处理， 花纹为圆弧凸凹状或者锯齿状花纹， 花纹深度 1.5 mm, 花纹半径 l mm， 进行风冷获得铝基铅复合材料。
6、 铝基铅及铅合金复合材料棒材 （Φ30 Ι ) 校直后弯曲成 1000X800X30 mm 阳极板面， 如图 2所示， 相邻 2根棒材距离 15 mm。
7、 用纯铅与铜排在 480〜500°C温度下浇铸成导电梁。
8、 阳极板面和导电梁通过乙炔焰焊接成阳极， 如图 1所示。
实施例 3
1、 按 SnO.6%比例配制铅合金浇铸成 Φ 10.0醒棒材。
2、 取 3X46 mm纯铝铝带在表面加工长度方向线状燕尾槽若干条， 燕尾槽上宽 1.5 mm, 下宽 2 mm, 深 0.5 mm。
3、 加工好燕尾槽的铝带表面磨粗拉毛处理， 毛剌长小于 0.5mm。
4、将加工好的铝带、铅锡合金棒送入包覆机在包覆机进料线上进行包覆， 铅锡 合金层厚 1.5醒。
5、 包覆完立即进行增表处理， 花纹为圆弧凸凹状或者锯齿状花纹， 花纹深度 0.5 mm, 花纹半径 0.5mm， 进行风冷获得铝基铅复合材料。
6、 铝基铅及铅合金复合材料带材 （6X49 mm) 校直后剪切 （剪切长度为 1000 醒）， 组装成 1000X800X6醒阳极板面， 如图 4所示， 相邻 2根带材距离 5醒。
7、 用纯铅与铜排在 480〜500°C温度下浇铸成导电梁。
8、 阳极板面和导电梁通过乙炔焰焊接成阳极， 如图 3所示。
实施例 4
1、 按 SnO.6%比例配制铅合金浇铸成 Φ20.0醒棒材。
2、 取 5x1000 mm纯铝铝带在表面加工长度方向线状燕尾槽若干条， 燕尾槽上宽 3 mm, 下宽 5 mm, 深 1· 5 mm。
3、 加工好燕尾槽的铝带表面磨粗拉毛处理， 毛剌长小于 0.5mm。
4、将加工好的铝带、铅锡合金棒送入包覆机在包覆机进料线上进行包覆， 铅锡 合金层厚 5醒。
5、 包覆完立即进行增表处理， 花纹为圆弧凸凹状或者锯齿状花纹， 花纹深度 1.5 mm, 花纹半径 5mm， 进行风冷获得铝基铅复合材料。
6、铝基铅及铅合金复合材料带材（15X1010 mm)校直后剪切（剪切长度为 1000 醒）， 组装成 1000X1010X15醒阳极板面， 如图 4所示， 相邻 2根带材距离 15醒。 、 用纯铅与铜排在 480〜500°C温度下浇铸成导电梁。
、 阳极板面和导电梁通过乙炔焰焊接成阳极， 如图 3所示。

Claims

权利要求书
1、一种铝基铅及铅合金复合阳极， 其特征是： 铝基铅及铅合金复合阳极的材芯为铝基材 料， 材芯表面粗糙带毛剌开有若干条沿铝基材料长度方向的线状燕尾槽， 铝基材料外包覆有 包覆材料层即为复合材料， 复合材料外表面经增表处理再经外形加工成阳极板面， 阳极板面 和导电梁通过乙炔焰焊接成阳极； 所述的导电梁由纯铅与铜排浇铸。
2、根据权利要求 1所述的一种铝基铅及铅合金复合阳极， 其特征是： 所述纯铅与铜排浇 铸成导电梁时， 浇铸温度 480〜500°C， 铜排材质为 T2。
3、根据权利要求 1所述的一种铝基铅及铅合金复合阳极， 其特征是： 所述的铝基材料为 0 3〜0 20 111111的棒材或厚度2〜5111111、 宽 30〜1000mm带材， 材质为纯铝或铝合金。
4、根据权利要求 1所述的一种铝基铅及铅合金复合阳极， 其特征是： 所述的包覆材料层 为按铅合金各组元比例配制浇铸成 Φ 7〜Φ 20 mm的棒材， 包覆材料层厚 1. 5〜5 mm; 材质为纯 铅或铅合金。
5、根据权利要求 1所述的铝基铅及铅合金复合阳极， 其特征是： 所述的阳极板面是铝基 铅合金复合材料， 分为棒材和带材； 其中： a、 棒材规格为 6〜 30 111111， 弯曲后剪切端头而 成， 相邻 2根棒材距离 5〜15 mm， 表面积相对同尺寸光滑板表面积增大 1〜1. 5倍； b、 带材 剪切成规格为厚度 6〜15mm、 宽 30〜1000mm， 相邻 2根带材距离 5〜15 mm， 表面积相对同尺 寸光滑板表面积增大 1〜1. 5倍。
6、根据权利要求 1所述的铝基铅及铅合金复合阳极， 其特征是： 所述的铝基材料表面粗 糙带毛剌，毛剌长小于 0. 5 mm,开有若干条线状燕尾槽，燕尾槽上宽 0. 5〜3. 0 mm,下宽 0. 75〜 5. 0 mm, 深 0. 5〜2. 0 mm。
7、根据权利要求 1所述的铝基铅及铅合金复合阳极， 其特征是： 所述的复合材料成品外 表面增表处理为圆弧凸凹状或者锯齿状花纹， 花纹深度 0. 2〜1. 5 mm， 花纹圆弧半径 0. 5〜5 mm。
8、根据权利要求 1所述的一种铝基铅及铅合金复合阳极的制备方法，其特征是工艺步骤 如下：
( 1 ) 按铅或铅合金各组元比例配制浇铸成铅合金棒材；
( 2 ) 在铝基材料棒材表面加工若干条沿长度方向的线状燕尾槽； (3) 加工好燕尾槽的铝基材料棒材表面拉毛处理；
( 4 ) 铝基材料和铅或铅合金棒材送入包覆设备进行包覆铅或铅合金包覆材料层；
(5)包覆完后在包覆材料层表面立即进行增表处理得到圆弧凸凹状或锯齿状花纹；冷却 即为复合材料；
(6) 铝基铅及铅合金复合材料经外形加工成阳极板面， 阳极板面有棒材和带材； 其中： a、 棒材校直后弯曲成规格为 Φ6〜Φ 30 mm; b、 带材校直后剪切组装成规格为厚度 6〜15mm、 宽 30〜1000mm;
(7) 用纯铅与铜排浇铸导电梁， 浇铸温度 480〜500°C;
(8) 阳极板面和导电梁通过乙炔焰焊接成阳极。
PCT/CN2012/079585 2012-03-27 2012-08-02 一种铝基铅或铅合金复合阳极及其制备方法 WO2013143247A1 (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2012100840895A CN102626776A (zh) 2012-03-27 2012-03-27 一种铝基铅及铅合金复合阳极制备方法
CN201210084089.5 2012-03-27

Publications (1)

Publication Number Publication Date
WO2013143247A1 true WO2013143247A1 (zh) 2013-10-03

Family

ID=46585275

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2012/079585 WO2013143247A1 (zh) 2012-03-27 2012-08-02 一种铝基铅或铅合金复合阳极及其制备方法

Country Status (2)

Country Link
CN (1) CN102626776A (zh)
WO (1) WO2013143247A1 (zh)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102912376B (zh) * 2012-10-10 2015-11-18 云南云铜锌业股份有限公司 一种锌电解铅阳极板及其制作方法
CN103855362A (zh) * 2012-12-02 2014-06-11 天能集团（河南）能源科技有限公司 一种连续生产电动车蓄电池极板的方法
CN103205780B (zh) * 2013-04-15 2017-04-26 昆明理工恒达科技有限公司 有色金属电积用栅栏型钛基PbO2电极及其制备方法
CN103710731A (zh) * 2013-12-10 2014-04-09 中南大学 一种湿法冶金用复合阳极
CN104328459B (zh) * 2014-12-03 2016-08-31 杭州帝洛森科技有限公司 一种压纹矫平增强刚性的电解极板及制备方法
CN105543890B (zh) * 2015-12-10 2017-10-13 沈阳弘圣鑫电解技术研发有限公司 一种内注铜浆型铜、镍电解阴极板导电棒及其制作方法
CN105862076B (zh) * 2016-06-06 2018-09-11 杭州帝洛森科技有限公司 电解锌阴极导电梁及其制备方法
CN106570295B (zh) * 2016-11-15 2019-09-17 首都航天机械公司 一种大厚度铝合金电子束焊接工艺锁底结构设计方法
CN110484733B (zh) * 2019-09-19 2021-03-16 紫金矿业集团股份有限公司 一种高效回收废旧铝基铅合金不溶阳极的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2833499A1 (de) * 1977-08-03 1979-02-15 Ammi Spa Anode fuer elektrolytische zellen
CN201220972Y (zh) * 2008-04-21 2009-04-15 昆明理工大学 有色金属电积用节能惰性阳极板
CN201236219Y (zh) * 2008-03-06 2009-05-13 雍明 一种不溶阳极板
CN102212849A (zh) * 2011-04-22 2011-10-12 昆明理工恒达科技有限公司 一种有色金属电积用新型阳极板制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2835257Y (zh) * 2005-09-26 2006-11-08 胡力星 电解金属锰用阳极板
CN101126166A (zh) * 2007-06-01 2008-02-20 云南冶金集团总公司 铅-铝复合阳极板的制备方法
CN101538724B (zh) * 2009-04-28 2011-03-23 昆明理工恒达科技有限公司 有色金属电积用节能型金属基陶瓷惰性阳极材料的制备方法
CN102161088A (zh) * 2010-12-16 2011-08-24 张纪云 一种改进型铜包铝排及其制备方法
CN202090065U (zh) * 2011-04-07 2011-12-28 湖南瑞源新材料有限公司 电解锰专用阳极板新型导电铜排

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2833499A1 (de) * 1977-08-03 1979-02-15 Ammi Spa Anode fuer elektrolytische zellen
CN201236219Y (zh) * 2008-03-06 2009-05-13 雍明 一种不溶阳极板
CN201220972Y (zh) * 2008-04-21 2009-04-15 昆明理工大学 有色金属电积用节能惰性阳极板
CN102212849A (zh) * 2011-04-22 2011-10-12 昆明理工恒达科技有限公司 一种有色金属电积用新型阳极板制备方法

Also Published As

Publication number Publication date
CN102626776A (zh) 2012-08-08

Similar Documents

Publication Publication Date Title
WO2013143247A1 (zh) 一种铝基铅或铅合金复合阳极及其制备方法
CN101538724B (zh) 有色金属电积用节能型金属基陶瓷惰性阳极材料的制备方法
CN101343758B (zh) 锌电积用惰性阳极材料的制备方法
CN101126166A (zh) 铅-铝复合阳极板的制备方法
CN102888625B (zh) 有色金属电积用栅栏型阳极板
CN104611731B (zh) 一种有色金属电积用栅栏型铝棒铅合金阳极板的制备方法
CN101922024B (zh) 一种有色金属电沉积用轻质复合电催化节能阳极及其制备方法
CN103205780A (zh) 有色金属电积用栅栏型钛基PbO2电极及其制备方法
CN104611609B (zh) 一种有色金属电积用低银铅合金多元阳极材料的制备方法
CN107604388A (zh) 复合阳极材料及其制备方法、阳极板及其制备方法
Karbasi et al. Electrochemical performance of PbCo composite anode during Zinc electrowinning
CN101235521B (zh) 一种有色金属电积用节能阳极
CN201220972Y (zh) 有色金属电积用节能惰性阳极板
CN202830195U (zh) 有色金属电积用栅栏型阳极板
CN106906495B (zh) 铝基的铅银合金复合阳极板及其制备方法
CN102912376B (zh) 一种锌电解铅阳极板及其制作方法
CN207276744U (zh) 复合阳极材料与阳极板
CN102433581B (zh) 一种有色金属电积用新型阳极材料的制备方法
CN106435263B (zh) 一种节能抗腐蚀的Pb-Ag-La合金阳极板的制作方法
WO2013143245A1 (zh) 一种铝基铅或铅合金复合材料及其制备方法
CN103233242B (zh) 一种dsa/铅合金复合电极及其制备方法和应用
CN105132980B (zh) 一种铅银合金阳极表面复合陶瓷膜层成膜方法
CN206502876U (zh) 一种湿法冶金用网栅型铅基多元合金阳极
JP6077884B2 (ja) 非鉄金属の電解採取方法およびそれに用いるアノードの製造方法
Zhang et al. Anodic behavior and microstructure of Al/Pb-Ag-Co anode during zinc electrowinning

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12872711

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12872711

Country of ref document: EP

Kind code of ref document: A1