WO2013142395A1 - Appareil de brûleur haute efficacité à faible émission de nox - Google Patents

Appareil de brûleur haute efficacité à faible émission de nox Download PDF

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Publication number
WO2013142395A1
WO2013142395A1 PCT/US2013/032742 US2013032742W WO2013142395A1 WO 2013142395 A1 WO2013142395 A1 WO 2013142395A1 US 2013032742 W US2013032742 W US 2013032742W WO 2013142395 A1 WO2013142395 A1 WO 2013142395A1
Authority
WO
WIPO (PCT)
Prior art keywords
waste gas
high efficiency
burner apparatus
chamber
efficiency low
Prior art date
Application number
PCT/US2013/032742
Other languages
English (en)
Inventor
Kurt Kraus
Matthew Martin
Stefano Bietto
Original Assignee
Honeywell International Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell International Inc. filed Critical Honeywell International Inc.
Priority to SG2014009435A priority Critical patent/SG2014009435A/en
Priority to CN201380003234.5A priority patent/CN103842724B/zh
Priority to RU2014112338/06A priority patent/RU2564368C1/ru
Publication of WO2013142395A1 publication Critical patent/WO2013142395A1/fr

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • F23G7/065Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • F23C6/045Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
    • F23C6/047Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure with fuel supply in stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/48Nozzles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00Staged combustion
    • F23C2201/20Burner staging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00Staged combustion
    • F23C2201/30Staged fuel supply
    • F23C2201/301Staged fuel supply with different fuels in stages

Definitions

  • the present invention is directed to a high efficiency low NO x emission burner apparatus and method.
  • the present invention is directed to a thermal oxidizer burner apparatus and method which utilizes waste gas or tail gas from an independent source to achieve high efficiency and low emission of nitrogen oxides. DESCRIPTION OF THE RELATED ART.
  • Oxides of nitrogen form as a result of combustion emitting from burners.
  • Various prior configurations and designs have been utilized in the past to increase the efficiency of thermal oxidizer burners and to reduce nitrogen oxides content of the flue gas effluent.
  • oxides of nitrogen in flue gas effluent such as nitrogen oxide (NO), nitrogen dioxide (N0 2 ) and others which are together generally labeled NO x .
  • a portion of the flue gas, waste or tail gas created by the combustion emitting from the burner is mixed and recirculated with inlet combustion air.
  • European Patent No. 1,203,188 illustrates an example of premixing fuel with internally recirculated waste gases drawn from the furnace chamber and then recirculated.
  • U.S. Patent No. 5,135,387 discloses a flue gas gathering member in a burner which forms a passage so that combustion air and recirculated flue gas are combined.
  • the composition of the waste gas or tail gas will vary but in one non-limiting example would be 98% nitrogen with the balance being combustibles such as methane, carbon monoxide, hydrogen and various sulfur compounds. Because the waste gas or tail gas has little or no oxygen content, the introduction of waste gas or tail gas to the combustion air will influence the oxygen content.
  • the recirculation of a portion of the waste or tail gas is known to decrease and/or control the amount of oxygen content in the combustion air. Decreasing the oxygen content decreases the partial pressure of oxygen, thereby reducing the rate of the reactions forming oxides.
  • thermo oxidizer burner apparatus which utilizes flue gas from an external source separate from the ongoing combustion in the combustion chamber associated with the burner.
  • the present invention is directed to a high efficiency low NO x emission burner apparatus.
  • a plenum chamber includes an inlet for introduction of combustion air which moves into and through the plenum chamber.
  • a combustion chamber is in fluid communication and connected to the plenum chamber.
  • An inlet is in communication with one or more primary waste gas pipes in order to introduce waste gas or tail gas into the combustion chamber through the plenum chamber.
  • the waste gas or tail gas will be delivered from an independent, external source not associated with the combustion herein.
  • the primary waste gas pipe or pipes terminate in a lobed tip nozzle which extends from one end at the waste gas pipe to an opposed end terminating in a plurality of radially extending lobes symmetrically arranged around a center axis.
  • a primary fuel gas line provides a source for fuel to the combustion reaction.
  • the waste gas inlet is also in communication with a secondary waste pipe or pipes for introduction of a portion of the waste gas or tail gas into the combustion chamber so that the introduction of waste gas is staged.
  • a secondary fuel gas line or lines are in communication with the combustion chamber for staged introduction of secondary fuel gas into the combustion chamber.
  • Figure 1 illustrates a simplified schematic diagram of a preferred embodiment of a high efficiency low NO x emission burner apparatus constructed in accordance with the present invention
  • FIG. 2A illustrates a simplified view of the burner apparatus shown in Figure 1 from the combustion chamber into the mixing plenum and Figures 2B and 2C illustrate external views of the burner apparatus;
  • Figures 3, 4 and 5 illustrate alternate views of a lobed tip nozzle of the burner apparatus shown in Figure 1 ;
  • FIG. 6 illustrates an alternate preferred embodiment of the burner apparatus
  • FIG. 7 illustrates a further alternate preferred embodiment of the burner apparatus.
  • Figure 1 illustrates a sectional view of a first preferred embodiment of a high efficiency low NO x emission thermal oxidizer burner apparatus 10 constructed in accordance with the present invention.
  • a substantially tubular or cylindrical plenum chamber 12 is provided although other configurations are possible.
  • the plenum chamber 12 includes an inlet 14 for introduction of combustion air as illustrated by arrow 16.
  • the combustion air may be drawn or forced into the combustion chamber through the plenum chamber 12 in a variety of ways.
  • the combustion air moves into and through the plenum chamber 12 as illustrated by arrow 18.
  • Various fans or other mechanisms along with controls may be used to force or induce combustion air through the plenum chamber 12.
  • a combustion chamber 20 is in fluid communication with and connected to the plenum chamber 12. Thermal oxidation occurs in the combustion chamber.
  • the combustion chamber 20 may be cylindrical or tubular or take other configurations. In a preferred arrangement, the combustion chamber is coaxial with the plenum chamber 12 although other configurations are possible.
  • An inlet 28 is in communication with one or more primary waste gas pipes or tubes 30 in order to introduce waste gas or tail gas into the combustion chamber 20 through the plenum chamber 12 as illustrated by arrow 32.
  • the waste gas or tail gas may be delivered from an independent, external source not associated with the combustion herein.
  • a non- limiting example of a tail gas or waste gas from an independent source would be waste gas or tail gas from a sulfur recovery unit as a part of a petrochemical or natural gas processing plant.
  • At least a portion of the primary waste gas pipe or pipes 30 may be coaxial with the cylindrical plenum chamber 12.
  • the primary waste gas pipe or pipes 30 terminate in a lobed tip nozzle 34, to be described herein in detail, or terminate in an open ended device or other mixing device. Accordingly, primary waste gas is delivered and mixed with the combustion air through the plenum chamber 12.
  • a primary fuel gas line or lines 40 provide a source for fuel to the combustion reaction. Natural gas or various other types of fuel might be employed within the spirit and scope of the invention.
  • the waste gas inlet 28 is in communication with a secondary waste gas pipe or tube 50 for introduction of a portion of waste gas or tail gas into the combustion chamber 20. Accordingly, introduction of the waste gas or tail gas is staged.
  • a secondary fuel gas line or lines 60 are in communication with the combustion chamber 20 for introduction of secondary fuel gas into the combustion chamber 20. Accordingly, introduction of fuel gas is staged. Natural gas or other various types of fuel might be employed within the spirit or scope of the invention.
  • Refractory material or refractory tiles 52 may be used between the fuel gas lines.
  • Figure 2A illustrates an end view taken from the combustion chamber 20 into the plenum chamber 12 of the apparatus 10 shown in Figure 1 while Figures 2B and 2C illustrate external views of the apparatus 10.
  • Figures 3, 4 and 5 illustrate alternate views of the lobed tip nozzle 34 apart from the apparatus 10.
  • the lobed tip nozzle 34 is connected at inlet end 42 to the primary waste gas pipe 30.
  • the lobed tip nozzle 34 extends from the inlet end 42 at the primary waste gas pipe to an opposed outlet end 44 terminating in a plurality of radially extending lobes 36 symmetrically arranged around a center axis.
  • the lobes 36 are rounded protuberances projecting radially outward from the axis.
  • the primary waste gas flows through the nozzle 34 as illustrated by arrows 46.
  • the cross-sectional area of the inlet end 42 of the lobed nozzle 34 is the same as the cross-sectional area of the outlet end 44 of the nozzle whereas the perimeter of the outlet end 44 is greater than the perimeter of the inlet end 42, thereby increasing the surface area of contact of both fluid streams passing through or surrounding the nozzle, in this case waste or tail gas and combustion air respectively, thereby increasing the rate of mixing of the two fluid streams.
  • the secondary fuel gas from secondary fuel gas line or lines 60 mixes with combustion air and the primary fuel gas and waste gas before introduction of secondary waste gas. Accordingly, the arrangement of the present invention causes a thorough mixing of the combustion air, the fuel gas and the waste gas in order to better modulate, control and predict NO x , carbon monoxide and unburned hydrogen emissions from the combustion chamber.
  • the arrangement disclosed in Figures 1 through 5 will tend to minimize carbon monoxide (CO) and unburned hydrocarbon emissions.
  • Figure 6 discloses an alternate preferred embodiment 70 of the burner apparatus 10. The arrangement is similar to that in Figures 1 through 5 with the exception of the introduction of the secondary fuel gas and secondary tail gas or waste gas in conjunction with an alternate arrangement of refractory tile 62.
  • the secondary fuel gas delivered through secondary fuel gas line 60 mixes with the secondary tail gas or waste gas through secondary waste gas pipe or pipes 50 and then simultaneously mixes with the combustion air, primary fuel gas and primary waste gas.
  • Figure 7 illustrates a further, alternate preferred embodiment 80 of the present invention.
  • the alternate embodiment shown in Figure 7 is similar to the arrangement of the foregoing with the exception of the secondary fuel gas and secondary waste gas introduction in conjunction with a further alternate arrangement of refractory tile 72.
  • the secondary tail gas or waste gas delivered through secondary waste pipe 50 fully or partially mixes with the secondary fuel gas delivered through secondary fuel gas line 60 prior to or before mixing with the combustion air, primary fuel gas through primary fuel gas line 40 and primary waste gas from the primary waste gas pipe or pipes 30.
  • the arrangement disclosed in Figure 7 will tend to minimize NO x emissions.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)

Abstract

L'invention concerne un appareil de brûleur haute efficacité à faible émission de NOx à oxydation thermique. L'appareil comprend une chambre de tranquillisation qui présente une entrée pour l'introduction d'air de combustion et une chambre de combustion en communication fluidique avec la chambre de tranquillisation. Une conduite de gaz d'échappement principale se termine en une buse à pointe lobée, à travers la chambre de tranquillisation, destinée à l'introduction des gaz d'échappement dans la chambre de combustion. Une conduite de gaz combustible principale est en communication avec la chambre de tranquillisation pour l'introduction de gaz combustible principal.
PCT/US2013/032742 2012-03-19 2013-03-18 Appareil de brûleur haute efficacité à faible émission de nox WO2013142395A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SG2014009435A SG2014009435A (en) 2012-03-19 2013-03-18 High efficiency low nox emission burner apparatus
CN201380003234.5A CN103842724B (zh) 2012-03-19 2013-03-18 高效低NOx排放的燃烧器装置
RU2014112338/06A RU2564368C1 (ru) 2012-03-19 2013-03-18 Высокоэффективная горелка, обеспечивающая низкий выброс nox и способ высокоэффективного термического окисления

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/423,311 US20130244187A1 (en) 2012-03-19 2012-03-19 HIGH EFFICIENCY LOW NOx EMISSION BURNER APPARATUS
US13/423,311 2012-03-19

Publications (1)

Publication Number Publication Date
WO2013142395A1 true WO2013142395A1 (fr) 2013-09-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/032742 WO2013142395A1 (fr) 2012-03-19 2013-03-18 Appareil de brûleur haute efficacité à faible émission de nox

Country Status (5)

Country Link
US (1) US20130244187A1 (fr)
CN (1) CN103842724B (fr)
RU (1) RU2564368C1 (fr)
SG (1) SG2014009435A (fr)
WO (1) WO2013142395A1 (fr)

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JP6495644B2 (ja) * 2014-12-17 2019-04-03 三菱日立パワーシステムズ株式会社 ガス焚きバーナの運転方法及びガス焚きバーナ
CN104791792B (zh) * 2015-04-30 2017-06-20 上海交通大学 一种低NOx气体燃料燃烧器和燃烧方法
CN107305009B (zh) * 2016-04-20 2020-03-03 赛科有限责任公司 用于使燃料燃烧的方法以及燃烧装置
CN106122943A (zh) * 2016-06-29 2016-11-16 无锡锡能锅炉有限公司 一种燃煤锅炉的零排放燃烧方法
CN106287696B (zh) * 2016-08-31 2018-12-14 王研 低氮燃烧装置以及低氮燃烧方法
CN107131508B (zh) * 2017-07-19 2023-06-02 山东泽轩环保科技有限公司 一种处理VOCs废气的设备及使用方法
FR3079020B1 (fr) * 2018-03-19 2020-08-07 Argumat Bruleur de fumees bleues pour la depollution d'une centrale d'enrobage, centrale d'enrobage et procede de depollution associes
US20210131662A1 (en) * 2019-10-30 2021-05-06 Honeywell International Inc. Recuperative gas burner for industrial applications and method of operating the same
WO2021188790A1 (fr) * 2020-03-18 2021-09-23 Parametric Solutions Inc. Injecteurs pour applications de co2 supercritiques
US11898747B2 (en) 2020-04-30 2024-02-13 Honeywell International Inc. Burner system and process for natural gas production
WO2022061473A1 (fr) * 2020-09-25 2022-03-31 Industrial Ceramics Limited Dispositif pour améliorer la cinétique de réaction d'un procédé d'incinération
CN112628725B (zh) * 2021-01-12 2021-11-12 哈尔滨工业大学 一种径向分级低NOx煤粉燃烧装置
CN113883539A (zh) * 2021-10-20 2022-01-04 洛阳新普石化设备开发有限公司 富氧酸性气焚烧炉燃烧器及其工作方法

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Also Published As

Publication number Publication date
US20130244187A1 (en) 2013-09-19
CN103842724A (zh) 2014-06-04
RU2564368C1 (ru) 2015-09-27
CN103842724B (zh) 2016-03-16
SG2014009435A (en) 2014-04-28

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