WO2013116340A1 - Procédé de désulfuration de charges d'alimentation à base de pétrole - Google Patents

Procédé de désulfuration de charges d'alimentation à base de pétrole Download PDF

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Publication number
WO2013116340A1
WO2013116340A1 PCT/US2013/023850 US2013023850W WO2013116340A1 WO 2013116340 A1 WO2013116340 A1 WO 2013116340A1 US 2013023850 W US2013023850 W US 2013023850W WO 2013116340 A1 WO2013116340 A1 WO 2013116340A1
Authority
WO
WIPO (PCT)
Prior art keywords
alkali metal
process according
sulfur
solid materials
anolyte
Prior art date
Application number
PCT/US2013/023850
Other languages
English (en)
Inventor
John Howard Gordon
Javier Alvare
Original Assignee
Ceramatec, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec, Inc. filed Critical Ceramatec, Inc.
Priority to KR1020147024289A priority Critical patent/KR101926905B1/ko
Priority to CA2863357A priority patent/CA2863357C/fr
Priority to EP13744384.2A priority patent/EP2809748B1/fr
Priority to ES13744384.2T priority patent/ES2650952T3/es
Priority to SG11201404513XA priority patent/SG11201404513XA/en
Priority to JP2014555672A priority patent/JP6099676B2/ja
Publication of WO2013116340A1 publication Critical patent/WO2013116340A1/fr
Priority to HK15103142.4A priority patent/HK1202573A1/xx

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/09—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by filtration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content

Abstract

La présente invention concerne un procédé de valorisation d'une charge d'alimentation à base de pétrole (102), le procédé comprenant la réaction de la charge d'alimentation à base de pétrole (102) avec une quantité de métal alcalin (106), la réaction produisant des matières solides et des matières liquides. Les matières solides sont séparées des matières liquides. Les matières solides peuvent être lavées et soumises à un traitement thermique (109) par chauffage à une température supérieure à 400 °C. Le traitement thermique (109) est réalisé sous une atmosphère à faible teneur en oxygène et en eau. Après le traitement thermique (109), les matières solides sont introduites dans une solution contenant un solvant polaire dans lequel les anions de sulfure, de sulfure d'hydrogène ou de polysulfure se dissolvent. La solution contenant le solvant polaire est ensuite introduite dans une cellule électrolytique (120) qui, en fonctionnement, produit un métal alcalin (106) et du soufre (128).
PCT/US2013/023850 2012-02-03 2013-01-30 Procédé de désulfuration de charges d'alimentation à base de pétrole WO2013116340A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1020147024289A KR101926905B1 (ko) 2012-02-03 2013-01-30 석유 공급원료의 탈황화 방법
CA2863357A CA2863357C (fr) 2012-02-03 2013-01-30 Procede de desulfuration de charges d'alimentation a base de petrole
EP13744384.2A EP2809748B1 (fr) 2012-02-03 2013-01-30 Procédé de désulfuration de charges d'alimentation à base de pétrole
ES13744384.2T ES2650952T3 (es) 2012-02-03 2013-01-30 Proceso para desulfurar materias primas de petróleo
SG11201404513XA SG11201404513XA (en) 2012-02-03 2013-01-30 Process for desulfurizing petroleum feedstocks
JP2014555672A JP6099676B2 (ja) 2012-02-03 2013-01-30 石油原料の脱硫プロセス
HK15103142.4A HK1202573A1 (en) 2012-02-03 2015-03-27 Process for desulfurizing petroleum feedstocks

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261594846P 2012-02-03 2012-02-03
US61/594,846 2012-02-03

Publications (1)

Publication Number Publication Date
WO2013116340A1 true WO2013116340A1 (fr) 2013-08-08

Family

ID=48905789

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/023850 WO2013116340A1 (fr) 2012-02-03 2013-01-30 Procédé de désulfuration de charges d'alimentation à base de pétrole

Country Status (8)

Country Link
EP (1) EP2809748B1 (fr)
JP (1) JP6099676B2 (fr)
KR (1) KR101926905B1 (fr)
CA (1) CA2863357C (fr)
ES (1) ES2650952T3 (fr)
HK (1) HK1202573A1 (fr)
SG (1) SG11201404513XA (fr)
WO (1) WO2013116340A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10538847B2 (en) 2015-12-29 2020-01-21 Enlighten Innovations Inc. Method and apparatus for recovering metals and sulfur from feed streams containing metal sulfides and polysulfides
CN111411004B (zh) * 2020-03-31 2021-05-14 广东石油化工学院 一种利用变压吸附原理高效提纯沼气的方法和装置

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1501756A (en) 1922-08-18 1924-07-15 Roessler & Hasslacher Chemical Electrolytic process and cell
US3785965A (en) 1971-10-28 1974-01-15 Exxon Research Engineering Co Process for the desulfurization of petroleum oil fractions
US3787315A (en) 1972-06-01 1974-01-22 Exxon Research Engineering Co Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen
US3788978A (en) 1972-05-24 1974-01-29 Exxon Research Engineering Co Process for the desulfurization of petroleum oil stocks
US4076613A (en) 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US5695632A (en) 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5935421A (en) 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US6368486B1 (en) 2000-03-28 2002-04-09 E. I. Du Pont De Nemours And Company Low temperature alkali metal electrolysis
US6635795B2 (en) * 2001-12-19 2003-10-21 Conocophillips Company Desulfurization with improved sorbent regeneration
US6787019B2 (en) 2001-11-21 2004-09-07 E. I. Du Pont De Nemours And Company Low temperature alkali metal electrolysis
US6852450B2 (en) 2000-07-25 2005-02-08 Samsung Sdi Co., Ltd. Electrolyte for a lithium-sulfur battery and a lithium-sulfur battery using the same
US20060138029A1 (en) * 2004-12-27 2006-06-29 Andrzej Malek Method of removing sulfur from sulfur-containing hydrocarbon streams
US20090134040A1 (en) 2007-11-27 2009-05-28 John Howard Gordon Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US20110100874A1 (en) 2009-11-02 2011-05-05 John Howard Gordon Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1501756A (en) 1922-08-18 1924-07-15 Roessler & Hasslacher Chemical Electrolytic process and cell
US3785965A (en) 1971-10-28 1974-01-15 Exxon Research Engineering Co Process for the desulfurization of petroleum oil fractions
US3788978A (en) 1972-05-24 1974-01-29 Exxon Research Engineering Co Process for the desulfurization of petroleum oil stocks
US3787315A (en) 1972-06-01 1974-01-22 Exxon Research Engineering Co Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen
US4076613A (en) 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US5695632A (en) 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5935421A (en) 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US6368486B1 (en) 2000-03-28 2002-04-09 E. I. Du Pont De Nemours And Company Low temperature alkali metal electrolysis
US6852450B2 (en) 2000-07-25 2005-02-08 Samsung Sdi Co., Ltd. Electrolyte for a lithium-sulfur battery and a lithium-sulfur battery using the same
US6787019B2 (en) 2001-11-21 2004-09-07 E. I. Du Pont De Nemours And Company Low temperature alkali metal electrolysis
US6635795B2 (en) * 2001-12-19 2003-10-21 Conocophillips Company Desulfurization with improved sorbent regeneration
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US20060138029A1 (en) * 2004-12-27 2006-06-29 Andrzej Malek Method of removing sulfur from sulfur-containing hydrocarbon streams
US20090134040A1 (en) 2007-11-27 2009-05-28 John Howard Gordon Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides
US8088270B2 (en) 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
US20110100874A1 (en) 2009-11-02 2011-05-05 John Howard Gordon Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"America's Strategic Unconventional Fuels", RESOURCE AND TECHNOLOGY PROFILES, vol. III, pages 111 - 25
MAY. G. MAY, J. POWER SOURCES, vol. 3, 1978, pages 1

Also Published As

Publication number Publication date
EP2809748B1 (fr) 2017-11-22
EP2809748A1 (fr) 2014-12-10
CA2863357A1 (fr) 2013-08-08
SG11201404513XA (en) 2014-10-30
JP2015511975A (ja) 2015-04-23
HK1202573A1 (en) 2015-10-02
ES2650952T3 (es) 2018-01-23
CA2863357C (fr) 2018-10-16
EP2809748A4 (fr) 2015-12-02
KR101926905B1 (ko) 2018-12-07
KR20140128391A (ko) 2014-11-05
JP6099676B2 (ja) 2017-03-22

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