WO2013107097A1 - High-barrier composite film for vacuum thermal insulation panel and manufacturing method therefor - Google Patents
High-barrier composite film for vacuum thermal insulation panel and manufacturing method therefor Download PDFInfo
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- WO2013107097A1 WO2013107097A1 PCT/CN2012/073395 CN2012073395W WO2013107097A1 WO 2013107097 A1 WO2013107097 A1 WO 2013107097A1 CN 2012073395 W CN2012073395 W CN 2012073395W WO 2013107097 A1 WO2013107097 A1 WO 2013107097A1
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- fiber cloth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
Definitions
- the present invention relates to a cover material for a vacuum insulation board, in particular to a high barrier composite film and a method of manufacturing the same.
- the existing high-barrier film of vacuum insulation board is mainly made of aluminum foil, PET film, nylon film or PP film.
- the disadvantage is that it is afraid of scratching, is afraid of piercing, is not firmly bonded with cement mortar, and is not resistant to aging and intolerance. Alkali and other issues. Once pierced during construction, not only is the insulation performance greatly reduced, but the structure of the entire insulation layer is destroyed.
- the present invention is directed to a high barrier composite film for a vacuum insulation panel and a method of manufacturing the same to solve the existing Vacuum insulation panels are used for a series of problems such as bonding, aging, scratching and piercing of buildings.
- a high barrier composite film for a vacuum insulation panel characterized in that a fiberglass cloth composite film is composited with a binder of a high barrier film on the inner side of the glass fiber cloth; The inside of the glass fiber cloth composite film is composited with the barrier composite film by a binder.
- the binder is a solvent or aqueous glue.
- the high barrier film is aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film, PE film or PP film.
- the composite method of the glass fiber cloth composite film is: applying a binder to the outermost side of the high barrier film by a rubber roller, and adding excess solvent in the binder by electric heating or hot air drying. After the water is drained, the high barrier film and the glass fiber cloth are combined by heating and pressing, and respectively become aluminum foil fiberglass cloth, aluminized glass fiber cloth, PET glass fiber cloth, nylon glass fiber cloth, PVC glass.
- the fiber cloth, the EVOH glass fiber cloth, the PE glass fiber cloth or the PP glass fiber cloth; the composite method of the glass fiber cloth composite film and the above-mentioned barrier composite film is the same as the composite method of the above glass fiber cloth composite film.
- the barrier composite film is compounded by any one or more of aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film or PP film.
- a PE film is provided on the innermost layer of the barrier composite film, and the composite process of each layer film is the same as the composite method of the glass fiber cloth composite film.
- the glass fiber cloth has a specification of 50-500 g/m 2 .
- the utility model has the advantages that: a glass fiber cloth is laminated on the outermost side of the original barrier composite film of the vacuum insulation board, and the high affinity and scratch resistance of the glass fiber cloth and the cement can effectively solve the high barrier of the conventional vacuum insulation board.
- the composite film has the problems of scratching, puncturing, not bonding with cement mortar, and not resisting aging, and solves the problem of the existing vacuum insulation panels used in construction.
- the invention relates to a high barrier composite film for a vacuum insulation panel and a manufacturing method thereof, and a glass fiber cloth is composited with an adhesive on the outermost side of the barrier composite film.
- the binder is a solvent-based or water-based glue (such as 3166 solvent-based glue of Beijing Gaomeng Co., Ltd.). Shanghai Bayer's 7132 water-based adhesive);
- the high barrier film is aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film, PE film or PP film.
- the specific compounding method is: using rubber roller The adhesive is applied on the outer side of the high barrier film, and the excess solvent or water in the adhesive is discharged by electric heating or hot air drying, and the high barrier film and the glass fiber cloth are heated and extruded.
- Glass fiber cloth composite film Composited together, become aluminum foil fiberglass cloth, aluminized glass fiber cloth, PET glass fiber cloth, nylon glass fiber cloth, PVC fiberglass cloth, EVOH glass fiber cloth, PE glass fiber cloth or PP glass fiber cloth, collectively referred to as glass fiber cloth composite film.
- the prepared glass fiber cloth composite film is composited with the barrier composite film when used as a vacuum insulation panel cover material to form the high barrier composite film of the present invention, and the glass fiber cloth is on the outermost side.
- the barrier composite film is formed by a composite of one or more of aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film or PP film by a binder, in a barrier composite There is a PE film on the innermost side of the film.
- the composite process of each layer of the film is the same as that of the above-mentioned glass fiber cloth composite film.
- the glass fiber cloth has a specification of 50-500 g/m 2 .
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- Laminated Bodies (AREA)
Abstract
A high-barrier composite film for a vacuum thermal insulation panel and manufacturing method therefor, characterized in that attached to the outer-most side of the high-barrier film by means of an adhesive agent is a layer of glass fiber cloth. The advantages of the present invention are that: a layer of glass fiber cloth is attached to the outer-most side of the existing high-barrier composite film of the vacuum thermal insulation panel; the glass fiber cloth is scratch resistant and has good affinity with cement, thereby effectively solving the problem of high-barrier films of regular vacuum thermal insulation panels being vulnerable to scratching, stabbing, and aging, and having bad bonding with cement and mortar, and solving the long-standing difficulties of vacuum thermal insulation panels in construction.
Description
技术领域 Technical field
本发明涉及一种用于抽真空的 保温板的封皮料 ,具体是一种高阻隔复合膜及其制造方法。 The present invention relates to a cover material for a vacuum insulation board, in particular to a high barrier composite film and a method of manufacturing the same.
背景技术 Background technique
现有抽真空绝热板高阻隔薄膜主要由铝箔、PET薄膜、尼龙薄膜或PP薄膜制成,其缺点是存在怕划伤,怕刺穿,与水泥砂浆粘结不牢,不抗老化、不耐碱等问题。在施工中一旦被刺穿,则不仅大大降低隔热性能,并使整个保温层的结构受到破坏。
The existing high-barrier film of vacuum insulation board is mainly made of aluminum foil, PET film, nylon film or PP film. The disadvantage is that it is afraid of scratching, is afraid of piercing, is not firmly bonded with cement mortar, and is not resistant to aging and intolerance. Alkali and other issues. Once pierced during construction, not only is the insulation performance greatly reduced, but the structure of the entire insulation layer is destroyed.
发明内容 Summary of the invention
本发明 旨在提供一种用于真空绝热板的高阻隔复合膜及其制造方法,以解决 现有
真空绝热板用于建筑的粘结、老化、划伤、刺穿等一系列问题 。 The present invention is directed to a high barrier composite film for a vacuum insulation panel and a method of manufacturing the same to solve the existing
Vacuum insulation panels are used for a series of problems such as bonding, aging, scratching and piercing of buildings.
本发明
的技术方案是:一种用于真空绝热板的高阻隔复合膜,其特征在于,在玻璃纤维布的内侧与一种高阻隔薄膜用粘结剂复合成一层玻璃纤维布复合膜;然后将该玻璃纤维布复合膜内侧用粘结剂与阻隔复合膜复合。 this invention
The technical proposal is: a high barrier composite film for a vacuum insulation panel, characterized in that a fiberglass cloth composite film is composited with a binder of a high barrier film on the inner side of the glass fiber cloth; The inside of the glass fiber cloth composite film is composited with the barrier composite film by a binder.
所述的粘结剂为溶剂型或水性胶。 The binder is a solvent or aqueous glue.
所述的高阻隔薄膜为铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜、PE薄膜或PP薄膜。 The high barrier film is aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film, PE film or PP film.
所述的玻璃纤维布复合膜的复合方法是:用胶辊将粘结剂涂抹在所述的高阻隔薄膜的最外侧,通过电加热或热风干燥的形式,将粘结剂中多余的溶剂或水份排掉后,用加热挤压的方式将上述高阻隔薄膜与玻璃纤维布复合在一起,分别成为铝箔玻璃纤维布、镀铝玻璃纤维布、PET玻璃纤维布、尼龙玻璃纤维布、PVC玻璃纤维布、EVOH玻璃纤维布、PE玻璃纤维布或PP玻璃纤维布;将该玻璃纤维布复合膜与所述的阻隔复合膜的复合方法与上述的玻璃纤维布复合膜的复合方法相同。
The composite method of the glass fiber cloth composite film is: applying a binder to the outermost side of the high barrier film by a rubber roller, and adding excess solvent in the binder by electric heating or hot air drying. After the water is drained, the high barrier film and the glass fiber cloth are combined by heating and pressing, and respectively become aluminum foil fiberglass cloth, aluminized glass fiber cloth, PET glass fiber cloth, nylon glass fiber cloth, PVC glass. The fiber cloth, the EVOH glass fiber cloth, the PE glass fiber cloth or the PP glass fiber cloth; the composite method of the glass fiber cloth composite film and the above-mentioned barrier composite film is the same as the composite method of the above glass fiber cloth composite film.
所述的阻隔复合膜由铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜或PP薄膜中的一种或一种以上的任意组合复合而成。
The barrier composite film is compounded by any one or more of aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film or PP film.
在所述的阻隔复合膜的最内层设有PE膜,且各层膜的复合工艺与所述的玻璃纤维布复合膜的复合方法相同。 A PE film is provided on the innermost layer of the barrier composite film, and the composite process of each layer film is the same as the composite method of the glass fiber cloth composite film.
所述的玻璃纤维布的规格为50-500g/m2。The glass fiber cloth has a specification of 50-500 g/m 2 .
本发明
的优点是:在真空绝热板的原有阻隔复合膜的最外侧复合一层玻璃纤维布,利用玻璃纤维布与水泥的优良亲和性和抗划伤性能,可以有效解决常规真空绝热板高阻隔复合膜存在的怕划伤、怕刺穿、与水泥砂浆粘结不牢、不抗老化的问题,解决了现有真空绝热板用于建筑上的老大难问题。 this invention
The utility model has the advantages that: a glass fiber cloth is laminated on the outermost side of the original barrier composite film of the vacuum insulation board, and the high affinity and scratch resistance of the glass fiber cloth and the cement can effectively solve the high barrier of the conventional vacuum insulation board. The composite film has the problems of scratching, puncturing, not bonding with cement mortar, and not resisting aging, and solves the problem of the existing vacuum insulation panels used in construction.
具体实施方式 detailed description
本发明是一种用于真空绝热板的高阻隔复合膜及其制造方法,在阻隔复合膜的最外侧用粘结剂复合一层玻璃纤维布。
The invention relates to a high barrier composite film for a vacuum insulation panel and a manufacturing method thereof, and a glass fiber cloth is composited with an adhesive on the outermost side of the barrier composite film.
所述的粘结剂为溶剂型或水性胶(如北京高盟公司的3166溶剂型胶,
上海拜尔的7132水性胶);所述的高阻隔薄膜为铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜、PE薄膜或PP薄膜,具体的复合方法是:用胶辊将粘结剂涂抹在高阻隔薄膜的外侧,通过电加热或热风干燥的形式,将粘结剂中多余的溶剂或水份排掉后,用加热挤压的方式将上述高阻隔薄膜与玻璃纤维布复合在一起,成为铝箔玻璃纤维布、镀铝玻璃纤维布、PET玻璃纤维布、尼龙玻璃纤维布、PVC玻璃纤维布、EVOH玻璃纤维布、
PE玻璃纤维布或PP玻璃纤维布,统称为玻璃纤维布复合膜。 The binder is a solvent-based or water-based glue (such as 3166 solvent-based glue of Beijing Gaomeng Co., Ltd.).
Shanghai Bayer's 7132 water-based adhesive); the high barrier film is aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film, PE film or PP film. The specific compounding method is: using rubber roller The adhesive is applied on the outer side of the high barrier film, and the excess solvent or water in the adhesive is discharged by electric heating or hot air drying, and the high barrier film and the glass fiber cloth are heated and extruded. Composited together, become aluminum foil fiberglass cloth, aluminized glass fiber cloth, PET glass fiber cloth, nylon glass fiber cloth, PVC fiberglass cloth, EVOH glass fiber cloth,
PE glass fiber cloth or PP glass fiber cloth, collectively referred to as glass fiber cloth composite film.
所制得的玻璃纤维布复合膜在用作抽真空绝热板封皮料时再与阻隔复合膜进行复合形成本发明高阻隔复合膜,玻璃纤维布在最外侧。
The prepared glass fiber cloth composite film is composited with the barrier composite film when used as a vacuum insulation panel cover material to form the high barrier composite film of the present invention, and the glass fiber cloth is on the outermost side.
所述的阻隔复合膜为由铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜或PP薄膜中的一种或一种以上的任意组合通过粘结剂复合而成,在阻隔复合膜的最内侧有PE膜。各层薄膜的复合工艺与所述的玻璃纤维布复合膜的复合方法相同。
The barrier composite film is formed by a composite of one or more of aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film or PP film by a binder, in a barrier composite There is a PE film on the innermost side of the film. The composite process of each layer of the film is the same as that of the above-mentioned glass fiber cloth composite film.
所述的玻璃纤维布的规格为50-500g/m2。The glass fiber cloth has a specification of 50-500 g/m 2 .
Claims (7)
- 一种用于真空绝热板的高阻隔复合膜,其特征在于,在玻璃纤维布的内侧与一种高阻隔薄膜用粘结剂复合成一层玻璃纤维布复合膜;然后将该玻璃纤维布复合膜内侧用粘结剂与阻隔复合膜复合。 A high barrier composite film for a vacuum insulation panel, characterized in that a fiberglass cloth composite film is composited with a binder of a high barrier film on the inner side of the glass fiber cloth; and then the glass fiber cloth composite film is laminated The inner adhesive is combined with the barrier composite film.
- 根据权利要求1所述的用于真空绝热板的高阻隔复合膜,其特征在于,所述的粘结剂为溶剂型或水性胶。The high barrier composite film for a vacuum insulation panel according to claim 1, wherein the binder is a solvent type or an aqueous glue.
- 根据权利要求1所述的用于真空绝热板的高阻隔复合膜,其特征在于,所述的高阻隔薄膜为铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜、PE薄膜或PP薄膜。The high barrier composite film for a vacuum insulation panel according to claim 1, wherein the high barrier film is aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film, PE film or PP film.
- 根据权利要求3所述的用于真空绝热板的高阻隔复合膜,其特征在于,所述的玻璃纤维布复合膜的复合方法是:用胶辊将粘结剂涂抹在所述的高阻隔薄膜的最外侧,通过电加热或热风干燥的形式,将粘结剂中多余的溶剂或水份排掉后,用加热挤压的方式将上述高阻隔薄膜与玻璃纤维布复合在一起,分别成为铝箔玻璃纤维布、镀铝玻璃纤维布、PET玻璃纤维布、尼龙玻璃纤维布、PVC玻璃纤维布、EVOH玻璃纤维布、PE玻璃纤维布或PP玻璃纤维布;将该玻璃纤维布复合膜与所述的阻隔复合膜的复合方法与上述的玻璃纤维布复合膜的复合方法相同。The high barrier composite film for a vacuum insulation panel according to claim 3, wherein the composite method of the glass fiber cloth composite film is: applying a binder to the high barrier film by a rubber roller On the outermost side, after the excess solvent or water in the binder is drained by electric heating or hot air drying, the high barrier film and the glass fiber cloth are combined by heating and pressing to form aluminum foil. Glass fiber cloth, aluminized glass fiber cloth, PET glass fiber cloth, nylon glass fiber cloth, PVC glass fiber cloth, EVOH glass fiber cloth, PE glass fiber cloth or PP glass fiber cloth; the glass fiber cloth composite film and the The composite method of the barrier composite film is the same as the composite method of the above-mentioned glass fiber cloth composite film.
- 根据权利要求4所述的用于真空绝热板的高阻隔复合膜,其特征在于,所述的阻隔复合膜由铝箔、镀铝膜、PET薄膜、尼龙薄膜、PVC薄膜、EVOH薄膜或PP薄膜中的一种或一种以上的任意组合复合而成。The high barrier composite film for a vacuum insulation panel according to claim 4, wherein the barrier composite film is made of aluminum foil, aluminized film, PET film, nylon film, PVC film, EVOH film or PP film. One or more of any combination is compounded.
- 根据权利要求5所述的用于真空绝热板的高阻隔复合膜,其特征在于,在所述的阻隔复合膜的最内层设有PE膜,且各层膜的复合工艺与所述的玻璃纤维布复合膜的复合方法相同。The high barrier composite film for a vacuum insulation panel according to claim 5, wherein a PE film is provided in an innermost layer of said barrier composite film, and a composite process of each layer film and said glass The composite method of the fiber cloth composite film is the same.
- 根据权利要求1所述的用于真空绝热板的高阻隔复合膜,其特征在于,所述的玻璃纤维布的规格为50-500g/m2。The high barrier composite film for a vacuum insulation panel according to claim 1, wherein said glass fiber cloth has a specification of 50 to 500 g/m 2 .
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CN103587166A (en) * | 2013-10-20 | 2014-02-19 | 江苏申凯包装高新技术股份有限公司 | Composite packaging film for heat insulation board of refrigerator |
CN115012544A (en) * | 2022-07-15 | 2022-09-06 | 泰山玻璃纤维有限公司 | High-strength wear-resistant puncture-resistant vacuum heat-insulation composite board and production method thereof |
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- 2012-01-17 CN CN201210013288.7A patent/CN102642348B/en active Active
- 2012-03-31 WO PCT/CN2012/073395 patent/WO2013107097A1/en active Application Filing
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CN102642348B (en) | 2014-04-09 |
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