WO2013093425A1 - Réacteur catalytique et structure catalytique - Google Patents

Réacteur catalytique et structure catalytique Download PDF

Info

Publication number
WO2013093425A1
WO2013093425A1 PCT/GB2012/053098 GB2012053098W WO2013093425A1 WO 2013093425 A1 WO2013093425 A1 WO 2013093425A1 GB 2012053098 W GB2012053098 W GB 2012053098W WO 2013093425 A1 WO2013093425 A1 WO 2013093425A1
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
catalytic
combustion
channels
catalyst
Prior art date
Application number
PCT/GB2012/053098
Other languages
English (en)
Inventor
David James West
Original Assignee
Compactgtl Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compactgtl Limited filed Critical Compactgtl Limited
Publication of WO2013093425A1 publication Critical patent/WO2013093425A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • B01J2219/2464—Independent temperature control in various sections of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2465—Two reactions in indirect heat exchange with each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2479—Catalysts coated on the surface of plates or inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2483—Construction materials of the plates
    • B01J2219/2485—Metals or alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2498—Additional structures inserted in the channels, e.g. plates, catalyst holding meshes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

L'invention concerne un réacteur (10) qui définit des premier et second canaux d'écoulement (16, 17), un insert de catalyseur de combustion amovible (24) étant disposé dans chacun de ces canaux (17) dans lesquels une réaction de combustion doit se produire. L'insert de catalyseur de combustion comprend une première partie (Q2) comprenant une matière catalytique active, une deuxième partie (Q1) ayant une activité catalytique inférieure à 0,2 fois l'activité catalytique de la première partie (Q2), et une troisième partie (P) comprenant une matière catalytique active avec une activité au moins 0,3 fois celle de la première partie (Q2). La première partie (Q2), la deuxième partie (Q1) et la troisième partie (P) sont progressivement plus éloignées à partir de l'entrée ; et elles peuvent être formées d'une seule pièce.
PCT/GB2012/053098 2011-12-22 2012-12-12 Réacteur catalytique et structure catalytique WO2013093425A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1122193.4 2011-12-22
GBGB1122193.4A GB201122193D0 (en) 2011-12-22 2011-12-22 Catalytic reactor and catalyst structure

Publications (1)

Publication Number Publication Date
WO2013093425A1 true WO2013093425A1 (fr) 2013-06-27

Family

ID=45572939

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2012/053098 WO2013093425A1 (fr) 2011-12-22 2012-12-12 Réacteur catalytique et structure catalytique

Country Status (3)

Country Link
GB (1) GB201122193D0 (fr)
TW (1) TW201338860A (fr)
WO (1) WO2013093425A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014096779A1 (fr) * 2012-12-17 2014-06-26 Compactgtl Limited Réacteur chimique multi-canaux

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5281128A (en) * 1990-11-26 1994-01-25 Catalytica, Inc. Multistage process for combusting fuel mixtures
DE19855769A1 (de) * 1998-12-03 2000-06-08 Dbb Fuel Cell Engines Gmbh Katalytisch beheizte Komponente für einen chemischen Reaktor
US6159358A (en) * 1998-09-08 2000-12-12 Uop Llc Process and apparatus using plate arrangement for reactant heating and preheating
US20020054837A1 (en) * 1998-06-29 2002-05-09 Fumio Abe Reformer
DE10110465A1 (de) * 2001-03-05 2002-10-02 Vodafone Pilotentwicklung Gmbh Reaktor
WO2003033131A1 (fr) 2001-10-12 2003-04-24 Gtl Microsystems Ag Reacteur catalytique
US20050235560A1 (en) * 2004-02-14 2005-10-27 Oliver Marquardt Integrated reactor for the thermal coupling of reactions and method for controlling the temperature field in such a reactor
US20060035182A1 (en) 2004-08-13 2006-02-16 Hesse David J Detonation safety in microchannels
US20070258872A1 (en) * 2006-05-08 2007-11-08 Compactgtl Plc Catalytic reactor
US20070258883A1 (en) * 2006-05-08 2007-11-08 Compactgtl Plc Catalyst structure for a rapid reaction
US20080131341A1 (en) * 2000-01-11 2008-06-05 Michael Joseph Bowe Catalytic reactor
WO2010067097A2 (fr) 2008-12-11 2010-06-17 Compactgtl Plc Fonctionnement de réacteur chimique

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5281128A (en) * 1990-11-26 1994-01-25 Catalytica, Inc. Multistage process for combusting fuel mixtures
US20020054837A1 (en) * 1998-06-29 2002-05-09 Fumio Abe Reformer
US6159358A (en) * 1998-09-08 2000-12-12 Uop Llc Process and apparatus using plate arrangement for reactant heating and preheating
DE19855769A1 (de) * 1998-12-03 2000-06-08 Dbb Fuel Cell Engines Gmbh Katalytisch beheizte Komponente für einen chemischen Reaktor
US20080131341A1 (en) * 2000-01-11 2008-06-05 Michael Joseph Bowe Catalytic reactor
DE10110465A1 (de) * 2001-03-05 2002-10-02 Vodafone Pilotentwicklung Gmbh Reaktor
WO2003033131A1 (fr) 2001-10-12 2003-04-24 Gtl Microsystems Ag Reacteur catalytique
US20050235560A1 (en) * 2004-02-14 2005-10-27 Oliver Marquardt Integrated reactor for the thermal coupling of reactions and method for controlling the temperature field in such a reactor
US20060035182A1 (en) 2004-08-13 2006-02-16 Hesse David J Detonation safety in microchannels
US20070258872A1 (en) * 2006-05-08 2007-11-08 Compactgtl Plc Catalytic reactor
US20070258883A1 (en) * 2006-05-08 2007-11-08 Compactgtl Plc Catalyst structure for a rapid reaction
EP2015865B1 (fr) 2006-05-08 2012-01-04 CompactGTL plc Réacteur catalytique comprenant des premiers et des seconds canaux d'écoulement disposés de facon alternée
WO2010067097A2 (fr) 2008-12-11 2010-06-17 Compactgtl Plc Fonctionnement de réacteur chimique

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014096779A1 (fr) * 2012-12-17 2014-06-26 Compactgtl Limited Réacteur chimique multi-canaux

Also Published As

Publication number Publication date
TW201338860A (zh) 2013-10-01
GB201122193D0 (en) 2012-02-01

Similar Documents

Publication Publication Date Title
JP5362553B2 (ja) 交互に配置された第一および第二フローチャネルを備えた触媒作用反応器
EP2015866B1 (fr) Reacteur catalytique comprenant premier et second catalysateur
US20120210995A1 (en) Reactor with Channels
US7235218B2 (en) Catalytic reactors
US20130202498A1 (en) Catalytic Reactor and Catalyst Structure
US20090253814A1 (en) Compact reactor
WO2013093425A1 (fr) Réacteur catalytique et structure catalytique
WO2013093422A1 (fr) Structure de catalyseur et procédé catalytique
WO2013034934A1 (fr) Procédé catalytique utilisant un réacteur de type à plaques
WO2013045921A1 (fr) Réacteur catalytique et structure de catalyseur
OA16579A (en) Catalytic reactor and catalyst structure.

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12810411

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12810411

Country of ref document: EP

Kind code of ref document: A1