WO2013067155A1 - Matériau en tissu - Google Patents

Matériau en tissu Download PDF

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Publication number
WO2013067155A1
WO2013067155A1 PCT/US2012/063023 US2012063023W WO2013067155A1 WO 2013067155 A1 WO2013067155 A1 WO 2013067155A1 US 2012063023 W US2012063023 W US 2012063023W WO 2013067155 A1 WO2013067155 A1 WO 2013067155A1
Authority
WO
WIPO (PCT)
Prior art keywords
strands
filling
fabric material
yarn
filling yarn
Prior art date
Application number
PCT/US2012/063023
Other languages
English (en)
Inventor
David E. Ronner
Paul LYTLE
Original Assignee
Ronner David E
Lytle Paul
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ronner David E, Lytle Paul filed Critical Ronner David E
Priority to CA 2854452 priority Critical patent/CA2854452A1/fr
Publication of WO2013067155A1 publication Critical patent/WO2013067155A1/fr

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C15/00Calendering, pressing, ironing, glossing or glazing textile fabrics
    • D06C15/02Calendering, pressing, ironing, glossing or glazing textile fabrics between co-operating press or calender rolls
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/25Metal
    • D03D15/258Noble metal
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/322Warp differs from weft
    • Y10T442/3228Materials differ
    • Y10T442/3236Including inorganic strand material
    • Y10T442/3244Including natural strand material [e.g., cotton, wool, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/3301Coated, impregnated, or autogenous bonded

Definitions

  • the present invention relates to fabric material, and, more particularly, to fabric material having antimicrobial and healing properties, as well as a low coefficient of friction.
  • Products made from fabric materials are a potential source of bacterial colonization, skin irritation, and migration or worsening of skin infections.
  • Bed sheets and pillow cases often produce irritated areas on a patient's skin as a result of friction caused by motion or lack of motion of the patient relative to the bed sheets and pillow cases. This skin irritation contributes to the formation of pressure ulcers.
  • What is needed is a fabric material having antimicrobial properties, a low coefficient of friction, a "cool to the touch" feel, and moisture-wicking properties.
  • a fabric material including a plurality of strands of a warp yarn positioned in a warp direction; a plurality of strands of a first filling yarn positioned in a filling direction, each of the plurality of strands of the first filling yarn being impregnated by silver ions; and a plurality of strands of a second filling yarn positioned in the filling direction each of the plurality of strands of the second filling yarn being impregnated by copper ions, wherein the plurality of strands of the warp yarn are woven with the plurality of strands of the first filling yarn and the plurality of strands of the second filling yarn to form a face side and a back side opposite the face side, and wherein each of the plurality of stands of the first filling yarn and each of the plurality of strands of the second filling yarn are woven alternately relative to one another with the plurality of strands of the warp yarn in the filling direction.
  • the fabric material includes a five-harness satin weave pattern.
  • the five-harness satin weave pattern is characterized by two of the plurality of strands of the first filling yarn and two of the plurality of strands of the second filling yarn floating over four of the plurality of strands of the warp yarn on the face side.
  • the five-harness satin weave pattern is characterized by four strands of the plurality of strands of the warp yarn underlying two strands of the plurality of strands of the first filling yarn and two strands of the plurality of strands of the second filling yarn on the back side.
  • the coefficient of friction of the face side in the filling direction is less than the coefficient of friction of the back side in the filling direction.
  • the plurality of strands of the warp yarn are made of filament rayon.
  • the plurality of strands of the first filling yarn are made from PLA polymer, and the plurality of strands of the second filling yarn are made from PLA polymer.
  • the fabric material is antimicrobial, cool to the touch, and wickab!e.
  • the plurality of strands of the first filling yarn are made from nylon, and the plurality of strands of the second filling yarn are made from nylon.
  • the plurality of strands of the first filling yarn are made from polyester, and the plurality of strands of the second filling yarn are made from polyester.
  • the fabric material is adapted to be used as a bed sheet.
  • the fabric material includes a plain weave pattern.
  • the plain weave pattern is characterized by five strands of the plurality of strands of the warp yarn in the warp direction, and five alternating strands of the plurality of strands of the first filling yarn and the plurality of strands of the second filling yarn in the filling direction.
  • the coefficient of friction of the face side is approximately equal to the coefficient of friction of the back side.
  • the fabric material is adapted to be used as a pillow case.
  • the fabric material includes a twill pattern.
  • a method for making a fabric materia! includes the steps of weaving a plurality of strands of a warp yarn in a warp direction with a plurality of strands of a first filling yarn impregnated with silver ions in a filling direction and a plurality of strands of a second filling yarn impregnated with copper ions in the filling direction, wherein each of the plurality of stands of the first filling yarn and each of the plurality of strands of the second filling yarn are alternately woven with the plurality of strands of the warp yarn in the filling direction; scouring the fabric material to remove external matter; conditioning the fabric material in order to soften it; drying the fabric material; and calendaring the fabric material to smoothen it.
  • the conditioning step includes wet processing the fabric material using a cationic softener.
  • the silver ion impregnated filling yarn and the copper ion impregnated filling yarn are manufactured separately and inserted alternately in the filling direction of the weave.
  • the silver and copper ions of the filling yarns provide antimicrobial and healing properties which are effective in combating the growth and proliferation of harmful bacteria and fungus. With the silver and copper ions being inherently impregnated, they are resistant to being removed during repeated launderings of the fabric material, which enables the fabric's antimicrobial and healing properties to remain effective.
  • the weave of the fabric material provides a low coefficient of friction on the face-side of the fabric, which inhibits irritation of a user's skin.
  • the rayon used in the warp direction of the weave possesses a low coefficient of friction that reduces the level of friction experienced by a user (such as a patient on a bed sheet) when he/she moves from side-to-side relative to the fabric. The reduced level of friction inhibits the formation of skin abrasions, which is one of the causes of pressure ulcers.
  • the fabric material includes a higher coefficient of friction on the back-side thereof versus the coefficient of friction on the face-side thereof.
  • the higher coefficient on the back-side inhibits movement of the fabric material during movement by the user, when he/she moves from side-to-side thereon, thus reducing formation of wrinkles and creases that causes irregularity in the fabric's surface and creates additional friction points for the user.
  • the fabric material is used for medical bed sheets, pillow cases, and other pressure ulcer related medical products.
  • the fabric material is absorbent and possesses a low coefficient of friction
  • medical bed sheets that are fabricated from the fabric material provide patients comfort and pressure ulcer mitigation. Mitigation of patient pressure ulcers provides a benefit to the overall medical treatment and well being of the patient.
  • the low coefficient of friction on the face-side of the bed sheet greatly enhances rotation of disabled or sedentary patients by hospital staff.
  • the fabric material helps support a significantly enhanced ergonomic process in the hospital environment (e.g., it facilitates patient movement and rotations by hospital care giver staff).
  • the reduction in the required physical demands on care giver staff not only reduces lost time to injuries but also tends to increase the actual number of patient rotations completed by care givers. If patient rotations are easier to accomplish, care givers may be far more physically-able to complete timed rotations of the patients.
  • the fabric can be used in connection with wearing apparel, boots, eibow pads, and other contact point protection shields.
  • FIG. 1 is a diagrammatic plan view of a portion of a fabric material constructed in accordance with an embodiment of the present invention, the fabric material being woven with yarn provided in a warp direction and two different yarns alternately provided in a filling or weft direction;
  • FIG, 2 is a cross-sectional view, taken along the line 2-2 and looking in the direction of the arrows, of the fabric material shown in FIG. 1 ;
  • FIG. 3 is a top perspective view of a fitted bed sheet which is fitted on a mattress, the sheet being made from the fabric material shown in FIGS. 1 and 2;
  • FIG. 4 is a diagrammatic plan view of a fabric material constructed in accordance with another embodiment of the present invention.
  • the present invention can be used in conjunction with a fabric material for use with any type of sleeping or resting facility, it is particularly suitable for bed sheets used in hospitals, medical facilities, and nursing homes. Accordingly, the present invention will be described hereinafter in connection with bed sheets used in hospitals, medical facilities, and nursing homes. It should be understood, however, that the following description is only meant to be illustrative of the present invention and is not meant to limit the scope of the present invention, which also has applicability in other facilities (e.g., hotels, etc.) or for other products, such as pillow cases, wearing apparel and clothing, boots and other footwear, elbow and knee pads, and other fabric protective guards and shields.
  • other facilities e.g., hotels, etc.
  • other products such as pillow cases, wearing apparel and clothing, boots and other footwear, elbow and knee pads, and other fabric protective guards and shields.
  • FIGS. 1 and 2 illustrate a portion of a fabric material 10 constructed in accordance with an embodiment of the present invention.
  • the fabric material 10 is made from a plain weave, a twill weave, or a satin weave.
  • the fabric material 0 includes a face-side 12 and a back-side 14 opposite the face-side 12 (see FIG. 2).
  • the fabric material 10 is woven in a five-harness filling satin weave construction.
  • the face-side 12 of the fabric material 10 which shows one of a repeating pattern of a plurality of strands of warp yarn 16 which are provided in a warp direction, as indicated by arrows W, and one of a repeating pattern of a plurality of alternating strands of filling yarn 8 and filling yarn 20, which are provided in the filling or weft direction, as indicated by arrows F.
  • the repeating pattern of the plurality of strands of the warp yarn 16 is five (5) strands, as shown in FIGS. 1 and 2.
  • the repeating pattern of the plurality of alternating strands of the filling yarns 18, 20 are five (5) strands, as shown in FIG. 1.
  • the warp yarn 16 is made of filament rayon.
  • the filament rayon comprises ENKA® filament rayon.
  • the filament rayon has a low coefficient of friction, absorbency, wicking, and "cool to the touch" properties, and mitigates static electricity.
  • the filament rayon can be made by other manufacturers.
  • the strands of the filling yarn 18 are made from a PLA (polylactic acid) polymer, nylon or a polyester yarn base that is inherently impregnated with silver ions (i.e., impregnated substantially equally throughout the entire yarn), while the strands of filling yarn 20 provided in the filling direction F are made from a PLA polymer, nylon or a polyester yarn base that is inherently impregnated with copper ions.
  • the PLA polymer is manufactured by Radici Fibers. In other embodiments, the PLA polymer can be made by other manufacturers.
  • the strands of the filling yarns 18, 20 are alternately inserted in the filling direction F (i.e., the filling yarn 20 is inserted in one pick, alternating with the filling yarn 18 in the next pick, and so on).
  • the silver and copper ions of the filling yarns 18, 20 include antimicrobial and healing properties which are described hereinbelow.
  • the filling yarn 18 is fabricated from fibers having inherent silver ions added to the base material of the master batch (e.g., PLA polymer, nylon or polyester yarn) of the fiber slurry in a process such as that disclosed in International Patent Publication Number WO 2006/08441 A1 , published on August 17, 2006 (the "'41 1 International Publication), which is incorporated by reference herein in its entirety.
  • the silver ions are inherently part of the fiber.
  • the filling yarn 20 may be fabricated from fibers which have inherent copper ions added to the base material (e.g., PLA polymer, nylon or polyester yarn) of the master batch of the fiber slurry in the process disclosed in the '411 International Publication. Upon extrusion of the fiber, the copper ions are inherently part of the fiber.
  • FIG. 2 illustrates the surface contours of the face-side 12 and the back-side 14 of the five-harness filling satin weave construction of the fabric material 10.
  • an arrow L indicates one of a repeated area of surface contours on the face-side 12, which contributes to a coefficient of friction in the filling direction F that is lower than the coefficient of friction in the filling direction F on the back-side 14 of the fabric material 10.
  • an arrow L indicates one of a repeated area of surface contours in which the two strands of the filling yarn 18 and the two strands of the filling yarn 20 float over (i.e., is not interwoven with) four strands of the warp yarn 16, thereby minimizing the coefficient of friction on the face-side 12 in the filling direction F.
  • the rayon used in the warp direction W also contributes to the low coefficient of friction in the filling direction F.
  • an arrow H indicates one of a repeated area of surface contours in which the four strands of the warp yarn 16 underlie the two strands of the filling yarn 18 and the two strands of the filling yarn 20, thereby maximizing the coefficient of friction on the back-side 14 in the filling direction F.
  • the fabric 10 is woven in specific shapes and sizes to accommodate end use applications.
  • a fitted bed sheet 22 which is made of the fabric material 0 and has fitted bottoms corners C, is shown fitted on a bed mattress 24,
  • a pillow 26 is also shown positioned on the fitted bed sheet 22.
  • the mattress 24 has a length indicated by the arrow L, a breadth indicated by the arrow B, and a thickness indicted by the arrow T.
  • the coefficient of friction in the filling direction F of the fabric material 10 reduces the level of friction that is experienced by a person ⁇ e.g., a patient) when he/she moves from side-to-side or is rotated by care giver staff on the face-side 2 of the fitted bed sheet 22.
  • the reduced level of friction on the face-side 12 of the fabric material 10 inhibits the formation of skin abrasions on the skin of the person resting on the fitted bed sheet 22, which is one of the causes of pressure ulcers,
  • the higher coefficient of friction of the back-side 14 of the fitted bed sheet 22 in the filling direction F serves to inhibit movement of the fitted bed sheet 22 relative to the mattress 24, limiting the formation of 5 wrinkles, creases or other characteristics that cause irritation points.
  • FIG. 4 depicts another embodiment of the present invention. Elements illustrated in FIG. 1 , which correspond, either identically or substantially, to the elements described above with respect to the embodiment illustrated by FIGS. 1 and 2, have been designated by corresponding reference numerals increased by one hundred. Unless i o otherwise stated, the embodiment illustrated by FIG. 4 is constructed and assembled in the same basic manner as the embodiment illustrated by FIG. 4.
  • FIG. 4 illustrates a portion of a fabric material 1 10 constructed in accordance with another embodiment of the present invention.
  • the fabric material 1 10 is woven in a plain weave construction.
  • FIG. 4 illustrates the
  • the strands of the filling yarn 116 provided in the warp W direction are made of filament rayon.
  • the strands of filling yarn 118 are made from a PLA polymer, nylon or a polyester yarn base that are inherently impregnated with silver ions, while the strands of the filling yarn 120 are made from PLA polymer, nylon or polyester yarn base that are inherently impregnated with copper ions and are alternately inserted in the filling direction F (i.e., the filling yarn 120 is inserted in one pick, alternating with the filling yarn 1 18 in the next
  • polyester or nylon yarn may be used as the base in the filling yarns 1 18, 20.
  • the filling yarn 1 18 is fabricated from fibers that have inherent silver ions added to the base material of the master batch (e.g., PLA polymer, nylon or polyester yarn) of the fiber slurry in a process such as that which is disclosed in the '41 1 International Publication. Upon extrusion of the fiber, the silver ions are inherently part of the fiber.
  • the filling yarn 120 may be fabricated from fibers which have inherent copper ions added to the base material (e.g., PLA polymer, nylon or polyester yarn) of the master batch of the fiber slurry in the process disclosed in the '411 International Publication. Upon extrusion of the fiber, the copper ions are inherently part of the fiber.
  • the fabric material 1 10 may be fabricated into pillow cases for covering, for example, the pillow 26 shown in FIG. 3, and a top sheet (not shown) for use with the fitted bed sheet fabric material 10 or 1 10.
  • the plain weave of the fabric material 110 provides the same coefficient of friction on the face- side and the back-side.
  • the silver and copper ions of the filling yarns 118, 120 have antimicrobial and healing properties which are equivalent to those provided by the five-harness filling satin weave of the fabric material 10.
  • the fitted bed sheet 22 mitigates the formation of pressure ulcers and helps to heal existing pressure ulcers. More particularity, the fitted bed sheet 22 has a low coefficient of friction, and has antimicrobial agents that inhibit the development of micro-organisms, and has healing capabilities which are effective in reducing skin-born irritations.
  • the rayon used in the warp direction W possesses a low coefficient of friction and has significant absorption properties.
  • the absorption properties wick- away moisture from the skin of the patient and contributes to the evaporation of moisture, which keeps the skin of the patient dry. This absorption prevents an environment conducive to bacterial growth and wicks odor-causing moisture from patients that are incontinent.
  • the rayon used in the warp yarn 16 in the warp direction W also has a natural cool feeling to the touch. This, in addition to its moisture wicking-action, assists in keeping the overall body temperature of the patient as cool as possible while resting or sleeping on the fitted bed sheet 22.
  • the fitted bed sheet 22 is also breathable and disposable at the end of its useful life. For instance, in an embodiment, if the fitted bed sheet 22 is constructed with rayon in the warp direction W, and PLA polymer, nyion or polyester yarn infused with copper and silver ions in the filling direction F, the material is 100% biodegradable. In another embodiment, if the fitted bed sheet 22 is constructed with rayon in the warp direction W and nylon or polyester infused with copper and silver ions in the filling direction F, it is compostable.
  • silver ions along with PLA polymer, nylon or polyester yarn, have antimicrobial properties which will inhibit the growth of bacteria on the surface of the fitted bed sheet 22 as well as on the skin of the patient, thereby minimizing or eliminating bacterial growth which is a contributing factor to the formation of pressure ulcers.
  • Copper ions are known to be a healing agent. The combination of the silver ions and copper ions in the fitted bed sheet 22 provides both antimicrobial and healing properties.
  • the silver ions are inherently part of the fiber of the filling yarn 8
  • the copper ions are part of the fiber of the filling yam 20 (i.e., not just applied to their exterior surface)
  • the antimicrobial and healing properties provided by the silver and copper ions will not wear away as the fitted bed sheet 22 is used and laundered over its useful life.
  • the weave construction of the fabric material 10 may be provided with a float in the filling direction F which is less than 4 strands of warp yarn 16.
  • the number of strands of the filling yarn 18 in the filling direction F may be greater or less than the number of strands of the filling yarn 20 in the filling direction F.
  • the strands in the filling direction may include only the filling yarn 18.
  • the strands in the filling direction F may include only the filling yarn 20.
  • Examples of other weave construction that may be utilized in the fabric of the present invention are twill weaves and sateen weaves.
  • the fabric materials 10, 110 are scoured to remove any spin finish, oils, or foreign matter.
  • the addition of other conditioning substances, such as wet processing using cationic softeners may also be applied to the fabric materials 10,110.
  • the fabrics 10, 1 10 are dried in a tenter frame and calendared to make the fabric materials 10, 1 10 feel smoother.
  • the fabric materials 10, 1 10 are inspected and rolled for subsequent processing of cutting according to end product specifications or applicable device dimensions.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Woven Fabrics (AREA)
  • Bedding Items (AREA)
  • Invalid Beds And Related Equipment (AREA)

Abstract

La présente invention concerne un matériau en tissu (10) comprenant une pluralité de brins d'un fil de chaîne (16) positionnés dans le sens des fils de chaîne, une pluralité de brins d'un premier fil de trame (18) positionnés dans le sens des fils de trame, imprégnés chacun d'ions argent, et une pluralité de brins d'un second fil de trame (20) positionnés dans le sens des fils de trame, chacun étant imprégné d'ions cuivre. Les brins dudit fil de chaîne (16) sont tissés avec ceux des premiers et seconds fils de trame (18, 20) pour former un verso (12) et un recto (14), et les brins des premiers et seconds fils de trame (18, 20) sont tissés en alternance les uns par rapport aux autres avec les brins dudit fil de chaîne (16) dans ledit sens des fils de trame. Le matériau en tissu (10) peut être du satin, du jersey ou un motif sergé et peut être utilisé comme des draps de lit (22) présentant des propriétés de faible coefficient de friction, de capacité d'absorption, de pouvoir absorbant et de toucher agréable.
PCT/US2012/063023 2011-11-04 2012-11-01 Matériau en tissu WO2013067155A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA 2854452 CA2854452A1 (fr) 2011-11-04 2012-11-01 Materiau en tissu

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161555581P 2011-11-04 2011-11-04
US61/555,581 2011-11-04

Publications (1)

Publication Number Publication Date
WO2013067155A1 true WO2013067155A1 (fr) 2013-05-10

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PCT/US2012/063023 WO2013067155A1 (fr) 2011-11-04 2012-11-01 Matériau en tissu

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US (2) US20130115841A1 (fr)
CA (1) CA2854452A1 (fr)
WO (1) WO2013067155A1 (fr)

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USD876748S1 (en) 2019-06-24 2020-03-03 Hempvana, Llc Glove

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