WO2013021751A1 - Drawn reduced-diameter animal fiber manufacturing method, restorable drawn animal fiber spun yarn, restorable drawn composite animal fiber spun yarn, restored animal fiber spun yarn, restored animal fiber cloth, drawn reduced-diameter animal fiber bundle, animal fiber bundle, fixed drawn animal fiber spun yarn, and cloth - Google Patents

Drawn reduced-diameter animal fiber manufacturing method, restorable drawn animal fiber spun yarn, restorable drawn composite animal fiber spun yarn, restored animal fiber spun yarn, restored animal fiber cloth, drawn reduced-diameter animal fiber bundle, animal fiber bundle, fixed drawn animal fiber spun yarn, and cloth Download PDF

Info

Publication number
WO2013021751A1
WO2013021751A1 PCT/JP2012/066901 JP2012066901W WO2013021751A1 WO 2013021751 A1 WO2013021751 A1 WO 2013021751A1 JP 2012066901 W JP2012066901 W JP 2012066901W WO 2013021751 A1 WO2013021751 A1 WO 2013021751A1
Authority
WO
WIPO (PCT)
Prior art keywords
animal hair
roller
hair fiber
fiber bundle
stretched
Prior art date
Application number
PCT/JP2012/066901
Other languages
French (fr)
Japanese (ja)
Inventor
庸治 谷
圭一朗 大庭
孝弘 吉田
さおり 田中
Original Assignee
株式会社アイ.エス.テイ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社アイ.エス.テイ filed Critical 株式会社アイ.エス.テイ
Priority to JP2013527931A priority Critical patent/JP5938619B6/en
Publication of WO2013021751A1 publication Critical patent/WO2013021751A1/en

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01HSPINNING OR TWISTING
    • D01H5/00Drafting machines or arrangements ; Threading of roving into drafting machine
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/84Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres

Definitions

  • the present invention relates to a method for producing an extended stretched animal hair fiber in which animal hair fibers are stretched to increase the length of a single fiber and reduce the fiber diameter.
  • the present invention also relates to a stretch-restored animal hair spun yarn composed of a stretch-expanded diameter animal hair fiber, a stretch-restored composite animal hair spun yarn containing a stretch-stretched-animal hair fiber, a stretch-restored animal hair spun yarn, or a stretch-restored composite animal hair spinning.
  • the present invention relates to an animal hair fiber bundle comprising an animal hair fiber bundle as a main component, a stretched and fixed animal hair fiber spun yarn composed of an extended stretched animal hair fiber bundle or an animal hair fiber bundle, and a fabric comprising a stretched and fixed animal hair fiber spun yarn.
  • clothing for all seasons is required to have not only basic characteristics as clothing such as touch and texture, but also characteristics such as thinness, light weight, heat retention and moisture absorption quick drying.
  • animal hair fibers having a small fiber diameter.
  • those having a fiber diameter of 19.5 ⁇ m to 22 ⁇ m are often used.
  • 18.7 ⁇ m display name SUPER100's
  • 16.0 ⁇ m SUPER150's
  • 13.5 ⁇ m SUPER200's
  • Wool or cashmere fibers with a thinner outer diameter are used.
  • animal hair fiber is a natural product, the amount of hair production below SUPER100's is extremely small, and it becomes a speculative target by increasing or decreasing the amount of hair production. For this reason, animal hair fibers tend to be expensive in price, and supply tends to be unstable. For this reason, in the textile industry, it has been desired to develop a technique capable of producing animal hair fibers having a small fiber diameter and stable quality at low cost.
  • Such fine count animal hair fibers usually have a step of twisting an animal hair fiber bundle, a step of swelling and plasticizing the twisted animal hair fiber bundle, a cross-linkage or a hydrogen bond of the animal hair fiber.
  • a step of twisting an animal hair fiber bundle a step of swelling and plasticizing the twisted animal hair fiber bundle, a cross-linkage or a hydrogen bond of the animal hair fiber.
  • To reduce the animal hair fibers to stretch the swollen plasticized animal hair fiber bundle after the reduction treatment, and to fix the stretched swollen plasticized animal hair fiber bundle in the stretched state. In order to stabilize the process and the immobilization process, it is manufactured through a process of oxidizing the swollen plasticized animal hair fiber bundle.
  • the fiber assembly is treated so that the fiber assembly that runs substantially untwisted is processed to plasticize the fiber so that a substantial draft of the fiber assembly does not occur during stretching.
  • a method of sufficiently twisting and setting the stretching a method is proposed in which the twist applied to the fiber assembly is set as a false twist, the fiber assembly is stretched, and the stretching is applied while being set.
  • '' See, for example, Japanese Patent Publication No. 05-500989.
  • the fiber assembly is stretched in a state where the fiber assembly plasticized in this way is twisted, the contact portions of the fibers twisted by the twist are pressed against each other by the external force during stretching, Uneven marks are formed at the contact area.
  • the fiber having irregularities on the surface of the single fiber is likely to cause glare. Furthermore, since heating, twisting and stretching for stretching the fibers are performed in the same facility, there is a problem that the facility is complicated and large. Further, in this method, in order to set the stretched fiber assembly, it is necessary to maintain the twist by rotating the fiber assembly even when the fiber assembly passes through the steam chamber. For this reason, such a method is complicated.
  • the actual twist plasticized animal hair sliver was nipped by a first nip roller group composed of a top roller and a bottom roller.
  • a first nip roller group composed of a top roller and a bottom roller.
  • the steam treatment machine placed between the "first nip roller group” and the "second nip roller group composed of a top roller and a bottom roller downstream thereof"
  • the stretched real twist plasticized animal hair sliver is sent from the water bath to the oxidation tank, and then in the neutralization tank.
  • Proposed a method of neutralizing the actual twist plasticized animal hair sliver with about 1.01 times tension applied to the actual twist plasticized animal hair sliver and then untwisting the actual twisted animal hair sliver with an untwisting machine Is See JP 2001-003238 A.
  • tension is applied to the animal hair sliver for a very long time from the initial stage of drawing to untwisting with an untwisting machine. Therefore, in this method, the fiber is cut during the mechanical or chemical treatment, and troubles such as short fibers that fall off wind around the drawing roller or float in the treatment tank are likely to occur, resulting in a decrease in productivity.
  • troubles such as short fibers that fall off wind around the drawing roller or float in the treatment tank are likely to occur, resulting in a decrease in productivity.
  • manufacturing equipment becomes heavy and long.
  • An object of the present invention is to provide a method for producing a stretched and contracted diameter animal hair fiber relatively easily while suppressing glare on the surface of the animal hair fiber without complicating or increasing the size of the facility and reducing the productivity. It is in.
  • a method for producing an extended stretchable animal hair fiber according to an aspect of the present invention is performed in an apparatus for producing an extended stretchable animal hair fiber including a swelling plasticizing apparatus and a stretching mechanism having an upstream nip roller pair and a downstream nip roller pair. Is done.
  • the swelling plasticization processing apparatus the animal hair fiber bundle is subjected to the swelling plasticization treatment with the swelling plasticizer to produce the swelling plasticized animal hair fiber bundle.
  • the “swelling plasticizer” herein is an aqueous solution containing, for example, an appropriate mixture, additive, hydrogen bond cleaving agent, cross-linking cleaving agent, hydrophobic bond relaxing agent, etc.
  • the upstream nip roller pair includes a first upstream roller and a second upstream roller.
  • the first upstream roller and the second upstream roller are arranged so as to contact each other, and an upstream nip portion is formed at the contact portion.
  • the downstream nip roller pair includes a first downstream roller and a second downstream roller. Note that the first downstream roller and the second downstream roller are disposed so as to contact each other, and a downstream nip portion is formed at the contact portion.
  • the animal hair fiber bundle is passed through a swelling plasticizing apparatus to produce a swollen plasticized animal hair fiber bundle.
  • the swollen plasticized animal hair fiber bundle is S from the upstream nip portion toward the downstream nip portion between the upstream nip portion and the downstream nip portion.
  • the swollen plasticized animal hair fiber bundle is drawn in a state of flowing in a letter shape or an inverted S shape.
  • the swollen plasticized animal hair fiber in a state in which the swollen plasticized animal hair fiber bundle is in close contact with the second upstream roller and the first downstream roller in the drawing mechanism.
  • the bundle is stretched.
  • the swollen plasticized animal hair fiber bundle is separated from the second upstream roller until it comes into contact with the first downstream roller (hereinafter referred to as “drawing zone”). It is possible to perform a stretching process of 80% or more of a desired stretching ratio at a very short distance.
  • the device for producing stretchable animal hair fibers is designed based on a very simple process. For this reason, the manufacturing apparatus of the stretchable diameter animal hair fiber which concerns on this invention is compact, and can reduce a capital investment cost.
  • the rotation axis of the first upstream roller and the rotation axis of the second downstream roller are connected. It is preferable that a virtual straight line or a virtual extended straight line intersect with a virtual straight line or a virtual extended straight line connecting the rotation axis of the second upstream roller and the rotation axis of the first downstream roller.
  • the swollen plasticized animal hair fiber bundle includes an upstream nip portion, a second upstream roller, a first downstream roller, and a downstream nip portion in this order, a first upstream roller, a second upstream roller, a first downstream roller, and Contact the second downstream roller.
  • a virtual line or a virtual extension line connecting the rotation axis of the first upstream roller and the rotation axis of the second upstream roller, and a rotation axis of the first downstream roller and a rotation axis of the second downstream roller are connected.
  • the virtual line or the virtual extension line may be parallel or crossed.
  • the linear distance between the rotation shaft of the second upstream roller and the rotation shaft of the first downstream roller is such that the rotation shaft of the first upstream roller and the second downstream roller It is preferable that the distance is shorter than the linear distance from the rotation axis of the roller.
  • the first upstream roller, the second upstream roller, the first downstream roller, and the second downstream roller preferably all have the same radius.
  • the swollen plasticized animal hair fiber bundle when viewed along the rotation axis of the first upstream roller, is at least a specific outer peripheral surface of the second upstream roller. It is preferable to contact a portion (hereinafter referred to as “first outer peripheral surface portion”) and a specific outer peripheral surface portion (hereinafter referred to as “second outer peripheral surface portion”) of the first downstream roller.
  • first outer peripheral surface portion refers to "the rotation axis of the first upstream roller and the rotation of the second upstream roller” from the "upstream nip portion" when viewed along the rotation axis of the first upstream roller.
  • the second outer peripheral surface portion is “a virtual extension that connects the rotation axis of the first downstream roller and the rotation axis of the second downstream roller.
  • the outer peripheral surface portion of the first downstream roller from the “intersection on the opposite side of the downstream nip portion” to the “downstream nip portion” of the intersection of the “line” and “the outer periphery of the first downstream roller”.
  • the swollen plasticized animal hair fiber bundle contacts at least about 1/2 of the circumference of the second upstream roller and about 1/2 of the circumference of the first downstream roller (top roller). .
  • the first outer peripheral surface portion and the second outer peripheral surface portion are not less than 3/5 of the outer peripheral length of the second upstream roller and the first downstream roller when viewed along the rotation axis of the first upstream roller.
  • the distance from the “upstream nip portion” to “the point where the swollen plasticized animal hair fiber bundle is separated from the second upstream roller” is 1 ⁇ 2 or more of the outer peripheral length of the second upstream roller.
  • it is 3/5 or more of the outer peripheral length of the second upstream roller.
  • the distance from “the point at which the swollen plasticized animal hair fiber bundle first contacts the first downstream roller” to the “downstream nip portion” is 1 ⁇ 2 or more of the outer peripheral length of the first downstream roller. Preferably, it is more preferably 3/5 or more of the outer peripheral length of the first downstream roller.
  • first outer peripheral surface portion and the second outer peripheral surface portion are formed at the upper and lower portions when the S-shape or the reverse S-shape is divided into three equal parts when viewed along the rotation axis of the first upstream roller. Equivalent to. Further, the first outer peripheral surface portion and the second outer peripheral surface portion do not face each other.
  • a virtual straight line connecting the rotation shaft of the first upstream roller and the rotation shaft of the second downstream roller, the rotation shaft of the second upstream roller, and the first The virtual straight line connecting the rotation axis of the downstream roller may be located on the same virtual straight line.
  • the swollen plasticized animal hair fiber bundle is composed of the first upstream roller, the second upstream roller, the second upstream roller, the second upstream roller, the first downstream roller, and the downstream nip portion in this order. Contact one downstream roller and a second downstream roller.
  • the environmental temperature at the time of stretching the swollen plasticized animal hair fiber bundle is not particularly limited, and is preferably in the range of 20 ° C. to 80 ° C.
  • the viewpoint that the swollen plasticized animal hair fiber bundle can be put into the next immobilization step while the swollen plasticized animal hair fiber bundle is sufficiently contained in the swollen plasticized animal hair fiber bundle "and" there is a need for a heating source From the viewpoint of realizing a reduction in manufacturing cost, improvement in workability, simplification of equipment structure or reduction in capital investment cost ”, it should be within a range of 20 ° C. to 30 ° C. (room temperature). More preferred.
  • the stretching may be performed in a swelling plasticizer. In such a case, the manufacturing apparatus can be made more compact.
  • stretched shape animal hair fiber bundle after stretching By stretching and stretching the swollen plasticized animal hair fiber bundle after stretching, the stretched shape animal hair can be temporarily retained in its stretched shape and restored to the state of substantially raw hair before stretching as necessary.
  • Fiber hereinafter referred to as “stretched restored animal hair fiber”
  • the stretched and plasticized animal hair fiber bundle after stretching is heated (fixed), oxidized and neutralized, washed with water, and dried to allow the stretched shape animal hair fiber (which can retain the stretched shape permanently) (Hereinafter referred to as “stretch-immobilized animal hair fibers”). That is, in the method for producing a stretched animal hair fiber according to the present invention, stretched and restored animal hair fibers and stretch-fixed animal hair fibers, two types of stretched and stretched animal hair fibers each having different characteristics can be produced. .
  • the stretched and stretched diameter of the animal hair fiber surface can be controlled relatively easily while suppressing glare on the surface of the animal hair fiber without increasing the complexity and size of the equipment and reducing the productivity.
  • Animal hair fibers can be produced.
  • peripheral speed of the first downstream roller is set higher than the peripheral speed of the second upstream roller. For this reason, the swollen plasticized animal hair fiber bundle that flows from the second upstream roller toward the first downstream roller is stretched.
  • the distance between the upstream nip portion and the downstream nip portion along the fiber flow is preferably 60 mm or more and 300 mm or less, and more preferably 80 mm or more and 250 mm or less.
  • the diameter of the rollers in the nip roller group can be made appropriate, and the single fiber can easily be prevented from being pulled out or unevenly drawn. Because it can.
  • the animal hair fiber can be stretched even if the stretch span is equal to or greater than the average length of the animal hair fiber, and the animal hair fiber It has been clarified by experiments of the present inventors that the animal hair fiber can be stretched even if the fiber is untwisted.
  • the average length of a general wool fiber is 60 mm to 100 mm.
  • the wool fiber is stably stretched even if the stretch span is set to 200 mm. We were able to.
  • the wool fiber bundle before stretching contains a swelling plasticizer and becomes soft and adheres closely to the outer peripheral surfaces of the second upstream roller and the first downstream roller. For this reason, even if the drawing span is equal to or greater than the average length of animal hair fibers, there is little occurrence of drafts (relative displacement between fibers), such as a single fiber bundle in which single fibers are continuously connected. It is inferred that the animal hair fibers are uniformly stretched.
  • the length of the stretching zone is preferably in the range of 5 mm to 50 mm, more preferably in the range of 5 mm to 30 mm, and still more preferably in the range of 10 mm to 30 mm.
  • the swollen plasticized animal hair fibers can be uniformly drawn, and even if the short animal hair fibers are long, It can be stretched in the same way as hair fibers.
  • the manufacturing apparatus can be made compact and the single fiber can be prevented from coming off.
  • the swollen plasticized animal hair fiber bundle is stretched at a magnification of 1.1 to 3.0 times.
  • the swollen plasticized animal hair fiber bundle is drawn at such a draw ratio, it is 18.7 ⁇ m (display name SUPER100), which is necessary for the production of thin, lightweight, comfortable clothes and high-grade clothing, This is because animal hair fibers having a fiber diameter of 13 to 17 ⁇ m with an extremely small amount of hair production can be stably supplied at low cost.
  • the swollen plasticized animal hair fiber bundle is stretched only by the upstream nip roller pair and the downstream nip roller pair.
  • a swollen plasticized animal hair fiber bundle is stretched with only the upstream nip roller pair and the downstream nip roller pair, it is stretched in a short time with a short stretch span, thus preventing the occurrence of fiber breakage, fiber slippage, and uneven stretching. Because it can be done.
  • the animal hair fiber bundle and the swollen plasticized animal hair fiber bundle are preferably untwisted.
  • the animal hair fiber bundle is pre-twisted, or the animal hair fiber bundle is drawn and fixed while being twisted.
  • the animal hair fiber bundles are twisted in this way. If the animal hair fiber bundles are not twisted, the single fibers will come loose, and the fibers will wind around the multi-stage drawing roller, causing problems in the process. This is because there is a tendency that a single fiber that is not stretched is mixed with the stretched fiber and the quality of the animal fiber with a long stretched diameter is deteriorated.
  • an untwisted animal hair fiber bundle can be directly stretched.
  • a stretched animal hair fiber having a mild appearance with suppressed glare can be provided. Further, in such a case, the manufacturing facility can be reduced in size and the handling of the manufacturing facility can be simplified, so that the workability can be improved and the investment cost can be suppressed.
  • the manufacturing apparatus of this extended stretchable animal hair fiber has a heating apparatus and an oxidation neutralization apparatus. Then, in this method for producing an elongated stretched animal hair fiber, after the swollen plasticized animal hair fiber bundle is stretched, the swollen plasticized animal hair fiber bundle is stretched by a heating device in a state where the swollen plasticized animal hair fiber bundle is kept in tension. The hair fiber bundle is heated to a temperature in the range of 60 ° C. to 150 ° C. to fix the swollen plasticized animal hair fiber in the swollen plasticized animal hair fiber bundle, and the swollen plasticized animal using an oxidation neutralizer. The hair fibers are neutralized after being oxidized.
  • immobilization refers to fixing a swollen plasticized animal hair fiber bundle that has been stretched at a predetermined magnification in the length direction to a stretched shape (maintaining the stretched shape), Means to manufacture.
  • the shape of the stretch-immobilized animal hair fiber is not substantially lost by subsequent spinning, dyeing, arranging process, or handling and processing after processing as clothing.
  • a heating apparatus For example, a steam supply apparatus, a heating press apparatus, a heating drum apparatus etc. are mentioned.
  • the heating method of the heating device is not particularly limited, and examples thereof include an electric heating method, a high-frequency heating method, a high-temperature oil, a circulating heating method such as steam and hot air, and the like.
  • the immobilization temperature is within the above-described temperature range, the shape of the extended stretchable animal hair fiber can be permanently immobilized stably.
  • the apparatus for producing an elongated stretchable animal hair fiber further has a heating roller.
  • a heating apparatus heats a heating roller, and a swelling plasticization animal hair fiber bundle is directly contacted and fixed to the outer surface of a heating roller.
  • the swollen plasticized animal hair fiber bundle is fixed while being pressed by a heating roller and at least one pressure roller.
  • the stretched stretchable animal hair fiber bundle can be fixed in a wet state (as if it is similar to a condition heated by steam).
  • the swollen plasticized animal hair fiber bundle preferably contains 60% by weight or more of the swollen plasticizer, and contains 70% by weight or more of the swollen plasticizer. Is more preferable. This is because, when the water content of the swollen plasticized animal hair fiber bundle is low, the glass transition temperature of the protein constituting the animal hair fiber becomes high, and the fixation of the animal fiber with a stretched diameter by heating becomes unstable.
  • the content of the swelling plasticizer in the swollen plasticized animal fiber bundle is determined based on the experimental results under predetermined conditions such as the temperature of the heating roller, the fixing speed, and the amount of the drawn animal fiber bundle introduced. It is preferable to do.
  • a stretched restored animal hair spun yarn can be produced from the stretched and stretched animal hair fiber obtained by the above-described method of producing a stretched and stretched animal hair fiber.
  • the stretched restored animal hair spun yarn may be immersed in warm water of 80 to 100 degrees C. In such a case, the stretched restored animal hair spun yarn may be boiled.
  • a stretch-restored composite animal hair spun yarn can also be produced by combining the same stretched diameter animal hair fiber and other fibers.
  • fibers other than the stretched and contracted diameter animal hair fibers for example, unstretched animal hair fibers and synthetic fibers are preferable.
  • the stretched and restored composite animal hair spun yarn can provide a spun yarn having a new shape and design by stretching and restoring the stretched diameter animal hair fiber.
  • a restored animal hair spun yarn can be produced by substantially restoring the above-described stretched restored animal hair spun yarn or stretched restored composite animal hair spun yarn to the fiber shape before stretching.
  • a fabric can be manufactured using such a restored animal hair spun yarn.
  • Such a restored animal hair spun yarn and fabric can improve the bulkiness and the covering ratio of the spun yarn of the core-sheath structure, and thus can provide a new spun yarn and fabric. .
  • the stretched restored animal hair spun yarn or stretched restored composite animal hair spun yarn is substantially restored to the fiber shape before stretching.
  • a restored animal blanket fabric can be produced. That is, a knitted fabric that cannot be knitted with the current knitting machine can be manufactured by boiling a knitted fabric knitted with the maximum cover factor and restoring it to a substantially raw hair state after knitting.
  • the single fiber having a circular cross-sectional shape in the radial direction in at least a part of the longitudinal direction, and the cross-sectional shape in the radial direction are It is preferable that non-circular single fibers are mixed. This is because glare on the fiber surface can be prevented.
  • the average fiber diameter of the single fiber is preferably in the range of 13 ⁇ m to 28 ⁇ m, more preferably in the range of 13 ⁇ m to 25 ⁇ m, and still more preferably in the range of 13 ⁇ m to 22 ⁇ m. . This is because, as described above, the production of small animal hair fibers is small, and the animal hair fibers having the diameter as described above can be stably supplied in the present situation accompanied by a rise in price.
  • the same stretchable animal hair fiber bundle can be mixed with other animal hair fiber bundles such that such a stretchable animal hair fiber bundle becomes a main component.
  • spun yarns and fabrics woven fabrics, knitted fabrics, felts, etc.
  • a stretched fixed animal hair fiber spun yarn can be produced from the above-mentioned stretched and contracted animal hair fiber bundle or mixed animal hair fiber bundle.
  • a fabric can be manufactured using such stretched fixed animal hair fiber spun yarn. Such a fabric can stably supply a clothing product having a texture and feel equivalent to that of natural animal hair fibers with a small amount of natural hair production, regardless of the price of the raw hair.
  • the stretch and shrinkage of the animal hair fiber surface is suppressed relatively easily and without increasing the complexity and size of the equipment and reducing the productivity. Diameter animal hair fibers can be produced.
  • the stretched and restored animal hair fiber according to the embodiment of the present invention is mainly manufactured through a swelling plasticization process, a stretching process, a water washing process, and a drying process.
  • the stretch-immobilized animal hair fiber according to the embodiment of the present invention is mainly manufactured through a swelling plasticization process, a stretching process, a fixing process, an oxidation neutralization / water washing process, and a drying process.
  • both the stretch-restored animal hair fibers and the stretch-immobilized animal hair fibers are manufactured using the animal hair fiber-stretching and fixing device 100 shown in FIG.
  • arrows A, B, and C indicate the flow direction of the animal hair fiber bundle in the animal hair fiber drawing and fixing device 100.
  • the stretch restored animal hair fiber is a stretch-stretched animal hair fiber that can temporarily retain the stretched shape and restore it to the state of substantially raw hair before stretching as required. Further, the stretch-immobilized animal hair fiber is an elongated stretch-diameter animal hair fiber that can keep the stretched shape permanently.
  • animal hair fiber which can be applied to the present invention
  • these animal hair fiber bundles 1, untwisted animal hair fiber bundles (top sliver) in which a plurality of single fibers are preliminarily arranged can be used.
  • Such animal hair fiber bundles are generally commercially available.
  • the average length of animal hair fiber is 20 mm or more, and it is more preferable that it is 30 mm or more.
  • the swelling plasticization processing apparatus 30 mainly includes a swelling plasticization tank 4 and a plurality of guide rollers 3.
  • the swelling plasticization tank 4 is filled with the swelling plasticizing aqueous solution 2 as shown in FIG.
  • the guide roller 3 is disposed inside the swelling plasticization tank 4, and guides the untwisted animal hair fiber bundle 1 into the swelling plasticization tank 4 and immerses it in the swelling plasticization aqueous solution 2.
  • Examples of the swollen plasticized aqueous solution 2 include an aqueous solution in which an additive is dissolved in water.
  • the swelling plasticization aqueous solution 2 may be what has been used conventionally.
  • the additive include a surfactant, a hydrogen bond cleaving agent, a crosslink bond cleaving agent, and a hydrophobic bond relaxing agent.
  • the surfactant include an alkylphenyl ether type activator.
  • disulfide bond cleaving agents for example, sulfur-containing amino acids such as thiol compounds (thioglycolic acid, mercaptopropionic acid, thioglycerin, L-cystine, etc.), alkyl mercaptans, mercapto alcohols, mercaptoamines, etc.
  • reducing agents such as sodium sulfite, sodium bisulfite, monoethanolamine sulfite, and monoethanolamine bisulfite.
  • the additives are not limited to those described above. Moreover, you may mix and use an additive.
  • the amount of additive added to water varies depending on the type of additive used and the purpose of use, so it cannot be said unconditionally, but when using a surfactant or the like for the purpose of enhancing the penetration effect into the fiber, 10 g / L or less is appropriate.
  • the cross-linking cleavage agent is a symmetric reducing agent, thioglycolic acid, mercaptoethanol or the like
  • the addition amount is preferably in the range of 0.05% by weight to 10% by weight. More preferably, it is in the range of not less than 8% and not more than 8 wt%.
  • the temperature during the swelling plasticization treatment is not particularly limited, but is preferably in the range of 30 ° C. or more and 80 ° C. or less.
  • the pH of the swollen plasticized aqueous solution 2 is preferably in the range of 7 or more and 10 or less (in the range of weak alkalinity to medium alkalinity).
  • the treatment time during the swelling plasticization treatment may be a time when the swelling plasticization aqueous solution 2 penetrates into the interior of the animal hair fibers sufficiently uniformly and the animal hair fibers are sufficiently swollen.
  • the manufacturing conditions described above may be set in consideration of the manufacturing cost, the stability of the quality of the obtained stretch-stretched animal hair fiber, and the like.
  • the drawing mechanism 40 mainly includes a back roller pair 10 and a front roller pair 20, and is disposed on the downstream side in the fiber flow direction of the swelling plasticizing apparatus 30.
  • the back roller pair 10 mainly includes a top roller (hereinafter referred to as “back top roller”) 11 and a bottom roller (hereinafter referred to as “back bottom roller”) 12.
  • the front roller pair 20 is disposed upstream of the fiber flow direction.
  • the back top roller 11 and the back bottom roller 12 are disposed so as to contact each other, and a nip portion 10N is formed at the contact portion.
  • the front roller pair 20 is mainly composed of a top roller (hereinafter referred to as “front top roller”) 21 and a bottom roller (hereinafter referred to as “front bottom roller”) 22 as shown in FIGS. It is arranged downstream of the back roller pair 10 in the fiber flow direction.
  • the front top roller 21 and the front bottom roller 22 are disposed so as to contact each other, and a nip portion 20N is formed at the contact portion.
  • the back bottom roller 12 and the front bottom roller 22 are metallic.
  • the surface structure of these bottom rollers 12 and 22 is a fluid structure.
  • the back top roller 11 and the front top roller 21 are preferably rubber-covered rollers. This is because the gripping force of the swollen plasticized animal hair fiber bundle 5 at each of the nip portions 10N and 20N can be made uniform.
  • the fluidized structure and the rubber hardness are “the gripping force of the swollen plasticized animal hair fiber bundle 5 at the nip portions 10N and 20N” and “the swollen plasticized animal hair fiber bundle 5 at the nip portions 10N and 20N”
  • the damage to the swollen plasticized animal hair fiber bundle 5 may be optimized after examining the experimental results. From the actual experimental results, the diameters of the back top roller 11, the back bottom roller 12, the front top roller 21, and the front bottom roller 22 are preferably in the range of 15 mm to 45 mm. Further, the diameters of the back bottom roller 12 and the front top roller 21 may be the same or different.
  • the stretching mechanism 40 when viewed along the rotation axes of the rollers 11, 12, 21, and 22, that is, when viewed from the side, the rotation shaft of the back top roller 11 and the front bottom roller 22. And the virtual straight line connecting the rotation axis of the back bottom roller 12 and the rotation axis of the front top roller 21 intersect, and the rotation axis of the back top roller 11 and the back bottom roller 12
  • the back roller pair 10 and the front roller pair 20 are arranged so that a virtual straight line connecting the rotation shaft and a virtual straight line connecting the rotation shaft of the front top roller 21 and the rotation shaft of the front bottom roller 22 are parallel to each other. ing. Further, as shown in FIGS.
  • the back roller pair 10 and the front roller pair 20 include a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12, and the front top roller.
  • An imaginary straight line connecting the rotation axis of 21 and the rotation axis of the front bottom roller 22 is disposed so as to be inclined by a predetermined angle D from the upstream side in the fiber flow direction toward the downstream side in the fiber flow direction.
  • the distance of the imaginary straight line connecting the rotation axis of the back bottom roller 12 and the rotation axis of the front top roller 21 is the imaginary straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the front bottom roller 22. It is shorter than the distance (see FIGS. 1 and 2). That is, the distance between the back bottom roller 12 and the front top roller 21 is shorter than the distance between the back top roller 11 and the front bottom roller 22.
  • the peripheral speed of the front roller pair 20 (peripheral speed of the top roller 21 of the front roller pair 20) is increased at a predetermined magnification with respect to the peripheral speed of the back roller pair 10 (peripheral speed of the bottom roller 12 of the back roller pair 10).
  • the swollen plasticized animal hair fiber bundle 5 can be stretched at a desired magnification.
  • the swollen plasticized animal hair fiber bundle 5 is stretched (stretched in the length direction) at a magnification in the range of 1.1 to 2.0 times.
  • the average fiber diameter is 13 ⁇ m to 38 ⁇ m.
  • the draw ratio is calculated from the following formula (1).
  • the stretching process of the swollen plasticized animal hair fiber bundle 5 in the stretching mechanism 40 will be described in detail.
  • the swollen plasticized animal hair fiber bundle 5 is guided from the swollen plasticizing apparatus 30 to the drawing mechanism 40 via the guide roller 6.
  • the stretching mechanism 40 as shown in FIGS. 1 and 2, the swollen plasticized animal hair fiber bundle 5 is stretched in the order of the back top roller 11, the back bottom roller 12, the front top roller 21, and the front bottom roller 22. It is.
  • the shape of the swollen plasticized animal hair fiber bundle 5 from the back top roller 11 to the back bottom roller 12 becomes an inverted S-shape, and the swelling from the nip portion 10N to the nip portion 20N.
  • the shape of the plasticized animal hair fiber bundle 5 is S-shaped, and the shape of the swollen plasticized animal hair fiber bundle 5 from the front top roller 21 to the front bottom roller 22 is inverted S-shaped.
  • the swollen plasticized animal hair fiber bundle 5 is gripped at two locations, that is, the nip portion 10N of the back roller pair 10 and the nip portion 20N of the front roller pair 20, as shown in FIGS. It will be.
  • the swelling plasticized animal hair fiber bundle 5 is substantially drawn by the back bottom roller 12 and the front top roller 21 (see FIGS. 1 and 2).
  • the region from the nip portion 10N to the nip portion 20N is referred to as “stretched span”, and “swelled plasticized animal hair fiber bundle 5 from the point that the swollen plasticized animal hair fiber bundle 5 is separated from the back bottom roller 12”.
  • the region 10 up to “the first point of contact with the front top roller 21” is referred to as “stretching zone”.
  • the back roller pair 10 and the front roller pair 20 include a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12, and the rotation axis of the front top roller 21 and the front roller.
  • An imaginary straight line connecting the rotation axis of the bottom roller 22 is arranged so as to be inclined by a predetermined angle D from the upstream side in the fiber flow direction toward the downstream side in the fiber flow direction. This is because the stretched span is longer than the average length of the single fibers, and the swollen plasticized animal hair fiber bundle 5 is brought into contact with the outer peripheral surfaces of the back bottom roller 12 and the front top roller 21 as long as possible.
  • the tensile tension on the swollen plasticized animal hair fiber bundle 5 in the drawing zone can be received on the contact surface of the back bottom roller 12 and the front top roller 21 with the swollen plasticized animal hair fiber bundle 5. It is important to do so.
  • the length of the stretched span is preferably in the range of 60 mm or more and 300 mm or less, and more preferably in the range of 80 mm or more and 200 mm or more. This is because, when the length of the stretched span is within this range, it is possible to effectively prevent the short fibers from dropping and uneven stretching.
  • a pressure of 0.1 kg / cm 2 to 3.0 kg / cm 2 is applied to each nip portion 10N, 20N. Is preferred.
  • the length of the stretching zone 19 is not particularly limited, and is determined in consideration of work efficiency and quality stability, but is generally preferably in the range of 5 mm to 50 mm, preferably 5 mm or more. It is more preferably within a range of 30 mm or less, and further preferably within a range of 10 mm or more and 30 mm or less. Further, it is preferable that only one stretching zone 19 is provided in the stretching mechanism 40. This is because it is possible to produce stretch-restored animal hair fibers and stretch-immobilized animal hair fibers of stable quality. Further, in this stretching zone 19, stretching of 80 to 90% is performed. This is apparent from the photograph of FIG. In FIG.
  • a location indicated by reference numeral 91 is a location corresponding to the nip portion 10 ⁇ / b> N of the back roller pair 10
  • a location indicated by reference numeral 94 is a location corresponding to the nip portion 20 ⁇ / b> N of the front roller pair 20.
  • a location indicated by reference numeral 92 is a location corresponding to the starting point of the stretching zone 19 (point on the back bottom roller 12 side)
  • a location indicated by reference numeral 93 is the end point of the stretching zone 19 (point on the front top roller 21 side).
  • the drying step is refrained after the water washing step. That is, in the drying step, the stretched and swollen plasticized animal hair fiber bundle 14 after washing with water is dried. Specifically, in this drying step, the stretched and swollen plasticized animal hair fiber bundle 14 after washing with water is brought into contact with a heating roller 15 set at a temperature of 50 ° C. or less to be primarily dried, and then further stretched. The swollen plasticized animal hair fiber bundle 14 is sent to the drying device 80 on the downstream side in the fiber flow direction, and is secondarily dried by the drying device 80. Even in this drying step, a tension of about 1.01 to 1.03 times is applied to the stretched and swollen plasticized animal hair fiber bundle 14.
  • the immobilization process is reserved after the stretching process. That is, in the fixing step, the shape of the stretched and swollen plasticized animal hair fiber in the stretched and swollen plasticized animal hair fiber bundle 14 is fixed. Specifically, in this fixing step, the stretched and swollen plasticized animal hair fiber bundle 14 is guided from the front bottom roller 22 to the pair of cleaning rollers 24 and 25 (in this fixing step, the stretched and swollen plasticized material is used.
  • the animal hair fiber bundle 14 is not washed with water but only passes through the pair of washing rollers 24 and 25), and is directly brought into contact with the heating roller 15 having a smooth outer peripheral surface to fix the shape of the stretch-swelled plasticized animal hair fiber.
  • a plurality of pressure rollers 16 are pressed against the heating roller 15.
  • the pressure roller 16 serves to press the stretched and swollen plasticized animal hair fiber bundle 14 against the heating roller 15. For this reason, at least a part of the longitudinal direction of the stretch-immobilized animal hair fiber is deformed into an elliptical cross-sectional shape. Due to this deformation, glare of the stretch-immobilized animal hair fibers is suppressed, and as a result, a mellow gloss is imparted to the stretch-immobilized animal hair fibers.
  • FIG. 4 is a photomicrograph of stretch-fixed wool fibers on the side not in contact with the heating roller 15. It can be seen from the micrograph of FIG. 4 that the wool fibers are stretched at equal intervals along the scale.
  • the cross section of the stretch-fixed wool fiber on the side not in contact with the heating roller 15 has a circular shape like the raw wool.
  • FIG. 5 is an electron micrograph of the stretch-fixed wool fiber on the side in contact with the heating roller 15. In the figure, a part of the stretch-immobilized wool fiber is deformed from a circular shape to a semicircular shape (see reference numeral 27 in FIG. 5).
  • FIG. 6 is a photomicrograph of the cross section of the stretch-immobilized wool fiber. In this figure, it can be seen that a partial cross section of the stretch-immobilized wool fiber is deformed from a circular shape to an elliptical shape.
  • the temperature of the heating roller 15 is preferably set to a temperature within a range of 60 ° C. to 150 ° C., and more preferably set to a temperature within a range of 70 ° C. to 120 ° C. preferable. This is because when the temperature of the heating roller 15 falls within the above range, the stretched and swollen plasticized animal hair fibers can be stably and uniformly fixed.
  • the heat source of the heating roller 15 for example, an electric heater, a high-frequency heating source, or a circulating fluid (such as hot liquid or hot air) is preferably used.
  • the outer peripheral surface of the heating roller 15 is coated with a fluorine resin, a silicone resin, or the like. This is because the releasability of the stretched and swollen plasticized animal hair fiber bundle 14 can be improved.
  • the diameter and number of the pressure rollers 16 are not particularly limited. Specifically, it is preferable that pressure rollers having a diameter of 30 mm to 50 mm are installed around the heating roller 15 at intervals of 50 mm to 100 mm. Moreover, it is preferable that the pressure roller 16 presses both end shaft portions thereof toward both end shafts of the heating roller 15. Further, the pressure applied by the pressure roller 16 to the heating roller 15 is preferably adjusted by an air cylinder, a spring or the like. The pressure roller 16 is preferably a driven roller that rotates as the heating roller 15 rotates. The pressure roller 16 is preferably covered with an elastic body such as silicone rubber.
  • the hardness of the elastic body is preferably in the range of 30 degrees to 80 degrees, and more preferably in the range of 40 degrees to 60 degrees.
  • the elastic body may be a sponge.
  • the pressure applied to the heating roller 15 is such that evaporation of the swelling plasticizer and fixation of the stretched and swollen plasticized animal hair fibers are performed in a steam atmosphere.
  • the conditions such as the pressure of the roller 16, the hardness of the elastic body of the pressure roller 16, the fixing temperature, the rotation speed of the heating roller 15 and the pressure roller 16 are preferably set.
  • the stretch-immobilized animal hair fiber bundle 18 is separated from the heating roller 15 via the separation roller pair 17, and is separated into the oxidation neutralization treatment tank 60 and the water washing treatment tank 70. Guide in order to neutralize and wash with water.
  • a tension of about 1.01 to 1.03 times is applied to the stretch-immobilized animal hair fiber bundle 18.
  • the stretch-swelled plasticized animal hair fibers are fixed by heat treatment, it is not necessary to regenerate the cross-linking of the animal hair fibers by the action of the oxidizing agent.
  • a basic drug is used as the swelling plasticizing aqueous solution 2 in the swelling plasticization step, it is preferable to provide this step as a neutralization treatment. This is because yellowing and deterioration of physical properties of the stretch-immobilized animal hair fibers can be prevented.
  • general-purpose oxidizing agents such as hydrogen peroxide, formic acid, acetic acid, hydrochloric acid, and sulfuric acid can be used.
  • Drying step As described above, in the animal hair fiber stretching and fixing device 100, when stretched and immobilized animal hair fibers are produced, the drying step is refrained after the oxidation neutralization / water washing step. That is, in the drying step, the stretch-immobilized animal hair fiber bundle 18 after oxidative neutralization is dried. Specifically, in this drying step, the stretch-immobilized animal hair fiber bundle 18 after the oxidation neutralization is guided to the drying device 80 and dried. Even in this drying step, a tension of about 1.01 to 1.03 times is applied to the stretch-immobilized animal hair fiber bundle 18.
  • the swollen plasticized animal hair fiber bundle 5 is looped over the outer peripheral surfaces of the back bottom roller 12 and the front top roller 21, and as a result, the back bottom roller 12 and the swollen plasticized animal hair fiber bundle 5 are in close contact with the outer peripheral surface of the front top roller 21 for a long time.
  • stretching mechanism 40 which concerns on this Embodiment, even if the pressure applied to nip part 10N and 20N is low, the swelling plasticization animal hair fiber bundle 5 can fully be hold
  • the swollen plasticized animal hair fiber bundle 5 in a wet state is brought into direct contact with the surface of the heating roller 15 in the fixing process. For this reason, at the initial stage when the swollen plasticized animal hair fiber bundle 5 comes into contact with the heating roller 15, it is contained in the swollen plasticized animal hair fiber bundle 5 as the temperature of the swollen plasticized animal hair fiber bundle 5 increases. The temperature of the swollen plasticizer is also increased, and steam is generated around the swollen plasticized animal hair fiber bundle 5 to create an environment in which the swollen plasticized animal hair fiber bundle 5 is heated in the steam. it can. For this reason, when this animal hair fiber drawing and fixing method is used, the immobilization of the swollen plasticized animal hair fibers can be realized in a short time without using complicated equipment such as a steam chamber in the immobilization process. .
  • the back roller pair 10 and the front roller pair 20 are arranged so that the imaginary straight line connecting the rotation axis of the front bottom roller 22 and the rotation axis of the front bottom roller 22 is parallel, but the back roller pair 10 and the front roller pair 20 are arranged.
  • the virtual straight line connecting the rotation axis of the front top roller 21 and the rotation axis of the front top roller 21 intersects, and the virtual extension straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12 and the front top roller 21.
  • a virtual extension straight line connecting the rotation axis of the front bottom roller 22 and the rotation axis of the front bottom roller 22 may be arranged to intersect each other.
  • the cleaning roller pairs 24 and 25, the oxidation neutralization treatment tank 60, the water washing treatment tank 70, and the drying device 80 are incorporated.
  • the animal hair fiber stretching and fixing device 100 may be provided separately. For example, these configurations may be incorporated in a dyeing machine or the like independent from the animal hair fiber drawing and fixing device 100.
  • the virtual straight line are in the same virtual straight line connecting the rotation axis of the top roller 121, roller pair 110 and the front roller pair 120 may be disposed.
  • An untwisted wool fiber bundle (top sliver 23 g / m) containing wool fibers having an average fiber diameter of 22.50 ⁇ m and an average length of 95 mm was prepared.
  • an aqueous sodium hydroxide solution was added to thioglycolic acid (Sakai Chemical Co., Ltd.) to prepare a 3.9 wt% thioglycolic acid aqueous solution having a pH of 9.00.
  • this aqueous thioglycolic acid solution was used as a swelling plasticizer.
  • the wool fiber bundle was stretched over the above-described animal fiber drawing and fixing device 100 as shown in FIG. Next, after the swelling plasticizer was put into the swelling plasticization tank 4, the swelling plasticizer was warmed to 40 degrees C. Thereafter, the wool fiber bundle was immersed in a swelling plasticizer for 40 minutes to perform a swelling plasticization treatment of the wool fiber bundle. Next, the swollen plasticized wool fiber bundle (hereinafter referred to as “swelled plasticized wool fiber bundle”) is drawn out from the swollen plasticizing tank 4 while containing the swollen plasticizer, and the swollen plasticized wool fiber bundle is drawn. Was stretched by the stretching mechanism 40 at a speed of 8.6 cm / min.
  • the back roller pair 10 and the front roller pair 20 are fibers with respect to the vertical axis so that the swollen plasticized wool fiber bundle comes into contact with about 3/5 of the outer periphery of the back bottom roller 12 and the front bottom roller 22 in a side view. It was inclined 45 degrees upstream in the flow direction (see FIG. 2 and the like). Furthermore, the length of the stretching zone was set to 14 mm. Then, after sequentially stretching the swollen plasticized wool fiber bundle by such a drawing mechanism 40, the swollen plasticized wool fiber bundle after stretching (hereinafter referred to as “stretched swollen plasticized wool fiber bundle”) is transferred from the front bottom roller 22.
  • the drawn and swollen plasticized wool fibers in the drawn and swollen plasticized wool fiber bundle were fixed by being guided to the heating roller 15 through the cleaning roller pairs 24 and 25 and in direct contact with the heated roller 15.
  • the fixing process was performed in a state where the peripheral speed of the heating roller 15 was 1.02 times the peripheral speed of the front roller pair 20, that is, the stretched and swollen plasticized wool fiber bundle was in tension. .
  • the heating roller 15 was heated by a built-in electric heater so that the outer diameter was 210 mm and the surface temperature was 80 degrees C.
  • the contact time of the stretched and swollen plasticized wool fiber bundle with the heating roller 15 was 110 seconds. As shown in FIG.
  • pressure rollers silicone rubber-coated stainless steel rollers having a diameter of 27 mm
  • Each pressure roller 16 was pressed against the heating roller 15 with a pressure of 1.5 kg / cm 2 by an air cylinder.
  • the wet ratio of the stretched and swollen plasticized wool fiber bundle before being brought into contact with the heating roller 15 was 81% by weight. At this time, the stretch span was 116 mm.
  • the fixed stretch-swelling plasticized wool fiber bundle (hereinafter referred to as “stretch-fixed wool fiber bundle”) is immersed in 1% by weight hydrogen peroxide water at 40 ° C. for 30 minutes to be oxidized, It was washed with water and further neutralized by immersion in 0.3% by weight of acetic acid for 30 minutes.
  • the average fiber diameter of the stretch-immobilized wool fiber thus obtained was 19.39 ⁇ m (measured according to JIS L1081A method). That is, the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 14% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing.
  • FIG. 7 shows the fiber diameter distribution of (i) the wool fiber bundle before stretching and fixing, (ii) the wool fiber bundle after stretching and (iii) the wool fiber bundle after boiling and fixing. Indicated. From FIG. 7, it can be seen that the fiber diameter distribution of the raw hair is slid in the fine count direction almost as it is due to the final stretching and fixing. That is, in the present drawing fixation, high-precision drawing is performed on the wool fiber bundle. Further, the stretch-fixed wool fiber bundle includes fibers having an elliptical cross section, and has a mellow appearance characteristic.
  • the average fiber diameter of the obtained stretch-immobilized wool fiber was 15.13 ⁇ m.
  • the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 18% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing.
  • this stretch-immobilized wool fiber bundle was boiled with boiling water for 15 minutes, and then the average fiber diameter of the stretch-immobilized wool fibers was measured again. At this time, the average fiber diameter of the stretch-fixed wool fibers was 15.20 ⁇ m. For this reason, it was confirmed that this stretch-immobilized wool fiber was completely immobilized.
  • a stretch-fixed cashmere fiber bundle was produced in the same manner as in Example 1 except that an untwisted cashmere fiber bundle (top sliver 17 g / m) having an average fiber diameter of 17.0 ⁇ m and an average length of 53 mm was used.
  • the average fiber diameter of the obtained stretch-immobilized cashmere fiber was 14.13 ⁇ m.
  • the single fiber of the cashmere fiber bundle after stretching and fixing is reduced in diameter by about 17% on average with respect to the single fiber of the cashmere fiber bundle before stretching and fixing.
  • this stretch-immobilized cashmere fiber bundle was boiled with boiling water for 15 minutes, and then the average fiber diameter of the stretch-immobilized cashmere fibers was measured again. At this time, the average fiber diameter of the stretch-immobilized cashmere fibers was 14.19 ⁇ m. For this reason, it was confirmed that this stretch-immobilized cashmere fiber was completely immobilized.
  • FIG. 8 shows the fiber diameter distribution of (i) a cashmere fiber bundle before stretch fixation, (ii) a cashmere fiber bundle after stretch fixation, and (iii) a cashmere fiber bundle after boiling treatment after stretch fixation. Indicated. From FIG. 8, it can be seen that the fiber diameter distribution of the raw hair is slid in the fine count direction almost as it is due to the final stretching and fixing. That is, in the present drawing and fixing, the cashmere fiber bundle is drawn with high accuracy.
  • the stretched swollen plasticized wool fiber bundle is heated from the front bottom roller 22 through the cleaning roller pairs 24 and 25 to a heating roller having a surface temperature of 50 degrees C. 15 and directly contacting the heating roller 15 to dry the stretched and swollen plasticized wool fiber bundle, and (ii) the pressure roller 16 is set to 1.8 kg / cm 2 with respect to the heating roller 15 by an air cylinder.
  • the stretched and swollen plasticized wool fiber bundle is directly guided to the drying device 80 without passing through the oxidation neutralization treatment tank 60 and the water washing treatment tank 70.
  • a stretched and restored wool fiber bundle was produced in the same manner as in Example 1 except that the bundle was wind-dried at a temperature of 50 ° C. or less with a drying device 80 and wound.
  • the stretched and swollen plasticized wool fiber bundle is washed and dried in a state where the peripheral speed of the heating roller 15 is 1.02 times the peripheral speed of the front roller pair 20, that is, the stretched and swollen plasticized wool fiber bundle is in tension. It was done in a let-down state.
  • the average fiber diameter of the obtained stretched and restored wool fiber was 19.62 ⁇ m. That is, the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 13.5% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing. Further, this stretch-fixed wool fiber bundle was immersed in warm water of 80 ° C. for 15 minutes, and then the average fiber diameter of the stretch-restored wool fiber was measured again. At this time, the average fiber diameter of the stretched restored wool fiber was 22.58 ⁇ m. In other words, this stretched and restored wool fiber was restored to raw hair by immersion in warm water.
  • a 60th stretch-restored wool spun yarn was produced using the stretch-restored wool fiber bundle produced in Example 4. Subsequently, a stretch-reconstructed composite wool spun yarn of 36th single yarn having a core-sheath structure in which the stretch-restored wool spun yarn was used as a core yarn and a cashmere sliver as a sheath yarn was produced by a conventional method. And when this stretched and restored composite woolen spun yarn is immersed in warm water of 80 ° C. for 15 minutes and taken out and dried, the stretched and restored woolen spun yarn of the core yarn is restored to the shape before stretching and the length is shortened, As a result, a spun yarn having a surface covered with bulky cashmere was obtained.
  • the stretched and restored wool spun yarn produced in Example 4 was spun into a 60th double yarn, and the double yarn was circularly knitted using a 16 gauge circular knitting machine at 3.5 times to prepare a knitted fabric.
  • the circular knitted fabric was boiled in boiling water for 15 minutes, then treated with 1% by weight hydrogen peroxide at 40 ° C. for 30 minutes, washed with water, and further washed with 0.3% by weight aqueous acetic acid solution for 30 minutes. Neutralize for minutes.
  • the knitted fabric contracted by 48% in the transverse (wale) direction and by 50% in the longitudinal (course) direction compared to before boiling.
  • the cover factor (CF) of the knitted fabric before boiling was 0.45
  • the cover factor (CF) of the knitted fabric after boiling was 0.85.
  • the average fiber diameter of the stretched and restored wool fiber was measured by disassembling the knitted fabric, the value was 22.58 ⁇ m. That is, the stretched and restored wool fiber was restored to raw hair by immersion in warm water.
  • the knitted fabric before boiling is shown in FIG. 9, and the knitted fabric after boiling is shown in FIG.
  • the stretched and contracted diameter animal hair fiber according to the present invention is an animal hair fiber having a fiber diameter thinner than that of natural fiber, and can be suitably used for clothing such as innerwear or high-class clothing. Moreover, this stretchable diameter animal hair fiber can be applied to a wide range of fields, such as chairs, interior materials, interior materials, etc., such as carpets, aircraft, and railways.

Abstract

The present invention addresses the problem of manufacturing drawn reduced-diameter animal fibers relatively simply and easily while suppressing glare on the surfaces of animal fibers without complicating and upsizing a facility and reducing productivity. In this drawn reduced-diameter animal fiber manufacturing method, first an animal fiber bundle (1) is passed through a swelling and plasticization treatment device (30) to produce a swelled and plasticized animal fiber bundle (5). Thereafter, between an upstream nip portion (10N) of an upstream nip roller pair (10) and a downstream nip portion (20N) of a downstream nip roller pair (20) in side view, the swelled and plasticized animal fiber bundle is drawn while moving in the shape of an S or an inverted S from the upstream nip portion to the downstream nip portion.

Description

延伸縮径獣毛繊維の製造方法ならびに延伸復元獣毛紡績糸、延伸復元複合獣毛紡績糸、復元獣毛紡績糸、復元獣毛布帛、延伸縮径獣毛繊維束、獣毛繊維束、延伸固定獣毛繊維紡績糸および布帛Production method of stretch stretched animal hair fiber, stretched restored animal hair spun yarn, stretched restored composite animal hair spun yarn, restored animal hair spun yarn, restored animal hair fabric, stretched stretched animal hair fiber bundle, animal hair fiber bundle, stretched Fixed animal hair fiber spun yarn and fabric
 本発明は、獣毛繊維を延伸して単繊維の長さを長化させると共に繊維径を縮径させる延伸縮径獣毛繊維の製造方法に関する。 The present invention relates to a method for producing an extended stretched animal hair fiber in which animal hair fibers are stretched to increase the length of a single fiber and reduce the fiber diameter.
 また、本発明は、延伸縮径獣毛繊維から成る延伸復元獣毛紡績糸、延伸縮径獣毛繊維を含む延伸復元複合獣毛紡績糸、延伸復元獣毛紡績糸または延伸復元複合獣毛紡績糸からなる復元獣毛紡績糸、復元獣毛紡績糸を含む布帛、延伸復元獣毛紡績糸または延伸復元複合獣毛紡績糸を含む復元獣毛布帛、延伸縮径獣毛繊維束、延伸縮径獣毛繊維束を主成分とする獣毛繊維束、延伸縮径獣毛繊維束または獣毛繊維束からなる延伸固定獣毛繊維紡績糸、延伸固定獣毛繊維紡績糸を含む布帛に関する。 The present invention also relates to a stretch-restored animal hair spun yarn composed of a stretch-expanded diameter animal hair fiber, a stretch-restored composite animal hair spun yarn containing a stretch-stretched-animal hair fiber, a stretch-restored animal hair spun yarn, or a stretch-restored composite animal hair spinning. Restored animal hair spun yarn made of yarn, fabric containing restored animal hair spun yarn, restored animal hair spun yarn containing stretched restored animal hair spun yarn or stretched restored animal hair spun yarn, stretched stretch animal hair fiber bundle, stretch stretched diameter The present invention relates to an animal hair fiber bundle comprising an animal hair fiber bundle as a main component, a stretched and fixed animal hair fiber spun yarn composed of an extended stretched animal hair fiber bundle or an animal hair fiber bundle, and a fabric comprising a stretched and fixed animal hair fiber spun yarn.
 近年、四季の移り変わりや生活環境の変化あるいはファッションやデザインの変転に伴って、衣料品の多様化がめざましく、四季を問わず獣毛繊維の需要が増大している。 In recent years, with the change of the four seasons, the living environment, and the change of fashion and design, the diversification of clothing has been remarkable, and the demand for animal hair fibers is increasing regardless of the seasons.
 ところで、オールシーズン用の衣料品には、肌触りや風合い等、衣料としての基本的な特性のみならず、薄さや軽量、保温性や吸湿速乾性などの特性も要求される。このような需要や要求に対しては、繊維径の細い獣毛繊維を使用することが好ましく、例えば、一般的な羊毛衣料品であれば、繊維径が19.5μmから22μmのものが多用されている。また、生地が薄く軽量で肌触りの良い衣料品や高級ブランド衣料品には、18.7μm(表示名SUPER100’s)や、16.0μm(SUPER150’s)、13.5μm(SUPER200’s)等の外径が更に細い羊毛やカシミヤ繊維が使用される。ところが、獣毛繊維は天然産物であるため、SUPER100’s以下の産毛量は極端に少なく、産毛量の増減によって投機的な対象にもなる。このため、獣毛繊維は、価格が高騰しやすい傾向にあり、供給も不安定になりがちである。このため、繊維産業界では、繊維径が細く安定した品質の獣毛繊維を安価に製造することができる技術の開発が望まれていた。 By the way, clothing for all seasons is required to have not only basic characteristics as clothing such as touch and texture, but also characteristics such as thinness, light weight, heat retention and moisture absorption quick drying. For such demands and demands, it is preferable to use animal hair fibers having a small fiber diameter. For example, in the case of general wool clothing, those having a fiber diameter of 19.5 μm to 22 μm are often used. ing. Moreover, 18.7 μm (display name SUPER100's), 16.0 μm (SUPER150's), 13.5 μm (SUPER200's), etc. are used for clothing that is thin and lightweight and has good touch and high quality brand clothing. Wool or cashmere fibers with a thinner outer diameter are used. However, since animal hair fiber is a natural product, the amount of hair production below SUPER100's is extremely small, and it becomes a speculative target by increasing or decreasing the amount of hair production. For this reason, animal hair fibers tend to be expensive in price, and supply tends to be unstable. For this reason, in the textile industry, it has been desired to develop a technique capable of producing animal hair fibers having a small fiber diameter and stable quality at low cost.
 このような要望に対して繊維産業界では、永年の知恵と工夫により多くの技術が開発されてきた。これらの一般的な技術としては、太番手(繊維径の大きい繊維)の獣毛繊維を延伸して細長化すると共に繊維径を細くして細番手の獣毛繊維を製造しようとするものである。 In response to such demands, many technologies have been developed in the textile industry with years of wisdom and ingenuity. As these general techniques, an animal hair fiber having a thick count (fiber having a large fiber diameter) is stretched to be elongated and an animal hair fiber having a fine count is manufactured by reducing the fiber diameter. .
 そして、このような細番手の獣毛繊維は、通常、獣毛繊維束を加撚する工程、加撚した獣毛繊維束を膨潤可塑化させる工程、獣毛繊維の架橋結合または水素結合を切断するために獣毛繊維に対して還元処理を行う工程、還元処理後の膨潤可塑化獣毛繊維束を延伸する工程、延伸した膨潤可塑化獣毛繊維束を延伸したままの状態で固定化する工程、固定化処理を安定させるために膨潤可塑化獣毛繊維束に対して酸化処理等を行う工程を経て製造される。 Such fine count animal hair fibers usually have a step of twisting an animal hair fiber bundle, a step of swelling and plasticizing the twisted animal hair fiber bundle, a cross-linkage or a hydrogen bond of the animal hair fiber. To reduce the animal hair fibers, to stretch the swollen plasticized animal hair fiber bundle after the reduction treatment, and to fix the stretched swollen plasticized animal hair fiber bundle in the stretched state. In order to stabilize the process and the immobilization process, it is manufactured through a process of oxidizing the swollen plasticized animal hair fiber bundle.
 具体的には、過去に「実質的に無撚の走行する繊維集合体を処理して繊維を可塑化させ、延伸の際に繊維集合体の実質的なドラフトが生じないように繊維集合体を充分に加撚し、その引き伸ばしをセットする方法において、繊維集合体に付与される撚を仮撚とし、繊維集合体が引き伸ばされ、セットされる間その引き伸ばしが付与される方法」が提案されている(例えば、特表平05-500989号公報等参照)。しかし、このように可塑化されている繊維集合体に撚りを掛けた状態で繊維集合体を延伸すると、撚りによってねじられた繊維同士の接触部分が、延伸時の外力によってお互いが押し付けられ、その接触部分に凹凸の跡形が生じてしまう。このように、単繊維の表面に凹凸が付いた繊維は、ギラツキが生じやすくなる。さらに、繊維を延伸するための加熱、加撚および延伸が同一設備で行われることになるため、設備が複雑で大型化する問題がある。また、この方法では、延伸した繊維集合体をセットするために、その繊維集合体がスチームチャンバー内を通過するときにおいてもその繊維集合体を回転させてその撚りを維持させる必要がある。このため、このような方法は煩雑である。 Specifically, in the past, “the fiber assembly is treated so that the fiber assembly that runs substantially untwisted is processed to plasticize the fiber so that a substantial draft of the fiber assembly does not occur during stretching. In a method of sufficiently twisting and setting the stretching, a method is proposed in which the twist applied to the fiber assembly is set as a false twist, the fiber assembly is stretched, and the stretching is applied while being set. '' (See, for example, Japanese Patent Publication No. 05-500989). However, when the fiber assembly is stretched in a state where the fiber assembly plasticized in this way is twisted, the contact portions of the fibers twisted by the twist are pressed against each other by the external force during stretching, Uneven marks are formed at the contact area. As described above, the fiber having irregularities on the surface of the single fiber is likely to cause glare. Furthermore, since heating, twisting and stretching for stretching the fibers are performed in the same facility, there is a problem that the facility is complicated and large. Further, in this method, in order to set the stretched fiber assembly, it is necessary to maintain the twist by rotating the fiber assembly even when the fiber assembly passes through the steam chamber. For this reason, such a method is complicated.
 また、過去に「繊維長30mm以上の獣毛繊維の無撚スライバーを80度Cの熱水や薬液に浸漬した後、その獣毛繊維の無撚スライバーを最初6個のニップローラ間で各々1.05倍ずつに延伸し、次いで、6個のニップローラ間で1.49倍に延伸し、それと同時に2kg/cmの蒸気圧でスチーミング処理して還元セットを行い、さらに後工程において、その獣毛繊維の無撚スライバーをトップ染色機に投入して、pH7、40度C、10分間の条件下で1%の過酸化水素で酸化処理した後、バックウォシャーで洗浄し、乾燥する方法」が提案されている(特開平07-003556号公報等参照)。このような方法では、繊維の表面に凹凸が形成されることがなくなり繊維のギラツキが抑制されるものの、素抜けした繊維が延伸ローラへ巻き付く等のトラブルも発生しやすく、生産性の低下に伴うコスト高等が問題となる。また、この方法では、延伸が膨潤液中で行われ、また、固定化処理が2kg/cmの蒸気圧下で行われるため、工程や設備構造も煩雑かつ複雑である。 In addition, in the past, after immersing an untwisted sliver of animal hair fiber having a fiber length of 30 mm or more in hot water or chemical solution at 80 ° C., the untwisted sliver of animal hair fiber was first placed between the first six nip rollers. Stretched by 05 times, then stretched by 1.49 times between 6 nip rollers, and at the same time, a reduction set was performed by steaming with a steam pressure of 2 kg / cm 2. A method in which a non-twisted sliver of hair fibers is put into a top dyeing machine, oxidized with 1% hydrogen peroxide under conditions of pH 7, 40 degrees C, 10 minutes, then washed with a backwasher and dried. It has been proposed (see JP 07-003556 A). In such a method, unevenness is not formed on the surface of the fiber and the glare of the fiber is suppressed. However, troubles such as winding of the loose fiber around the drawing roller are likely to occur, resulting in a decrease in productivity. The associated high costs are a problem. Further, in this method, stretching is performed in the swelling liquid, and the immobilization treatment is performed under a vapor pressure of 2 kg / cm 2 , so that the process and the equipment structure are complicated and complicated.
 さらに、過去に「実撚した獣毛スライバーを前処理槽に送り込んで可塑化および膨潤化した後、その実撚可塑化獣毛スライバーをトップローラおよびボトムローラで構成される第1のニップローラ群でニップし、この「第1のニップローラ群」と「その下流にあるトップローラおよびボトムローラで構成された第2のニップローラ群」との間に置かれた還元処理液槽およびスチーム処理機内に実撚可塑化獣毛スライバーを通しながら、両ニップローラ群の回転速度の差を利用して延伸し、延伸された実撚可塑化獣毛スライバーを湯洗槽から酸化槽に送った後、中和槽中で実撚可塑化獣毛スライバーに1.01倍程度の緊張を掛けた状態で実撚可塑化獣毛スライバーを中和処理し、解撚機により実撚獣毛スライバーを解撚する方法」が提案されている(特開2001-003238号公報等参照)。この方法では、延伸の初期工程から解撚機で解撚させるまで、非常に長い間、獣毛スライバーに張力が掛けられている。したがって、この方法では、機械的あるいは化学的な処理中に繊維が切断され、脱落する短繊維が延伸ローラへ巻き付いたり処理槽に浮遊したりする等のトラブルも発生しやすく、生産性の低下に伴うコスト高等が問題となるだけでなく、製造設備が重厚長大になる問題もある。 Further, in the past, after the actual twisted animal hair sliver was sent to the pretreatment tank for plasticization and swelling, the actual twist plasticized animal hair sliver was nipped by a first nip roller group composed of a top roller and a bottom roller. In the reduction treatment liquid tank and the steam treatment machine placed between the "first nip roller group" and the "second nip roller group composed of a top roller and a bottom roller downstream thereof" After passing through the chemical animal hair sliver, it is drawn using the difference in rotational speed between the nip rollers, and the stretched real twist plasticized animal hair sliver is sent from the water bath to the oxidation tank, and then in the neutralization tank. Proposed a method of neutralizing the actual twist plasticized animal hair sliver with about 1.01 times tension applied to the actual twist plasticized animal hair sliver and then untwisting the actual twisted animal hair sliver with an untwisting machine Is (See JP 2001-003238 A). In this method, tension is applied to the animal hair sliver for a very long time from the initial stage of drawing to untwisting with an untwisting machine. Therefore, in this method, the fiber is cut during the mechanical or chemical treatment, and troubles such as short fibers that fall off wind around the drawing roller or float in the treatment tank are likely to occur, resulting in a decrease in productivity. In addition to the high costs involved, there is also a problem that manufacturing equipment becomes heavy and long.
特表平05-500989号公報Japanese National Patent Publication No. 05-500989 特開平07-003556号公報JP 07-003556 A 特開2001-003238号公報JP 2001-003238 A
 本発明の課題は、設備の複雑化や大型化、生産性の低下を伴うことなく、獣毛繊維表面のギラツキを抑えながら比較的簡便に延伸縮径獣毛繊維を製造する方法を提供することにある。 An object of the present invention is to provide a method for producing a stretched and contracted diameter animal hair fiber relatively easily while suppressing glare on the surface of the animal hair fiber without complicating or increasing the size of the facility and reducing the productivity. It is in.
 本発明の一局面に係る延伸縮径獣毛繊維の製造方法は、膨潤可塑化処理装置と、上流ニップローラ対および下流ニップローラ対を有する延伸機構とを備える延伸縮径獣毛繊維の製造装置において実行される。膨潤可塑化処理装置では、獣毛繊維束が膨潤可塑化剤で膨潤可塑化処理されて膨潤可塑化獣毛繊維束が作製される。なお、ここにいう「膨潤可塑化剤」とは、例えば、適当な混合剤、添加剤、水素結合切断剤、架橋切断剤、疎水結合弛緩剤などを配合した水溶液であって、後述するように獣毛繊維束中の獣毛繊維を柔軟化させたり、獣毛繊維中の架橋を切断することにより獣毛繊維を可塑化させたりして延伸を容易にするために用いられる。また、上流ニップローラ対は、第1の上流ローラおよび第2の上流ローラから構成される。なお、第1の上流ローラと第2の上流ローラとは互いに接触するように配置され、その接触箇所に上流ニップ部が形成される。また、下流ニップローラ対は、第1の下流ローラおよび第2の下流ローラから構成される。なお、第1の下流ローラと第2の下流ローラとは互いに接触するように配置され、その接触箇所に下流ニップ部が形成される。 A method for producing an extended stretchable animal hair fiber according to an aspect of the present invention is performed in an apparatus for producing an extended stretchable animal hair fiber including a swelling plasticizing apparatus and a stretching mechanism having an upstream nip roller pair and a downstream nip roller pair. Is done. In the swelling plasticization processing apparatus, the animal hair fiber bundle is subjected to the swelling plasticization treatment with the swelling plasticizer to produce the swelling plasticized animal hair fiber bundle. The “swelling plasticizer” herein is an aqueous solution containing, for example, an appropriate mixture, additive, hydrogen bond cleaving agent, cross-linking cleaving agent, hydrophobic bond relaxing agent, etc. It is used for facilitating drawing by softening animal hair fibers in the animal hair fiber bundle or plasticizing the animal hair fibers by cutting the crosslinks in the animal hair fibers. The upstream nip roller pair includes a first upstream roller and a second upstream roller. The first upstream roller and the second upstream roller are arranged so as to contact each other, and an upstream nip portion is formed at the contact portion. Further, the downstream nip roller pair includes a first downstream roller and a second downstream roller. Note that the first downstream roller and the second downstream roller are disposed so as to contact each other, and a downstream nip portion is formed at the contact portion.
 そして、この延伸縮径獣毛繊維の製造方法では、先ず、獣毛繊維束が膨潤可塑化処理装置に通されて膨潤可塑化獣毛繊維束が作製される。そして、その後、第1の上流ローラの回転軸に沿って見た場合において、上流ニップ部と下流ニップ部との間において膨潤可塑化獣毛繊維束が上流ニップ部から下流ニップ部に向かってS字状または逆S字状に流れる状態で膨潤可塑化獣毛繊維束が延伸される。つまり、この延伸縮径獣毛繊維の製造方法では、延伸機構において、膨潤可塑化獣毛繊維束が第2の上流ローラおよび第1の下流ローラに対して密着した状態で膨潤可塑化獣毛繊維束が延伸される。また、この延伸縮径獣毛繊維の製造方法では、膨潤可塑化獣毛繊維束が第2の上流ローラを離れてから第1の下流ローラに接触するまでの間(以下「延伸ゾーン」という)の非常に短い距離で所望の延伸倍率の80%以上の延伸処理を行うことができる。このため、この延伸縮径獣毛繊維の製造方法では、比較的短い単繊維を含む無撚の獣毛繊維束であっても安定して均一に延伸することができる。したがって、この延伸縮径獣毛繊維の製造方法では、表面のギラツキを抑えながら安定した品質の延伸縮径獣毛繊維を製造することができる。なお、延伸処理後、膨潤可塑化獣毛繊維束は水洗された後に乾燥されることが好ましい。 Then, in this method for producing an elongated stretched animal hair fiber, first, the animal hair fiber bundle is passed through a swelling plasticizing apparatus to produce a swollen plasticized animal hair fiber bundle. After that, when viewed along the rotation axis of the first upstream roller, the swollen plasticized animal hair fiber bundle is S from the upstream nip portion toward the downstream nip portion between the upstream nip portion and the downstream nip portion. The swollen plasticized animal hair fiber bundle is drawn in a state of flowing in a letter shape or an inverted S shape. That is, in this method for producing an elongated stretched animal hair fiber, the swollen plasticized animal hair fiber is in a state in which the swollen plasticized animal hair fiber bundle is in close contact with the second upstream roller and the first downstream roller in the drawing mechanism. The bundle is stretched. Further, in this method for producing an extended stretchable animal hair fiber, the swollen plasticized animal hair fiber bundle is separated from the second upstream roller until it comes into contact with the first downstream roller (hereinafter referred to as “drawing zone”). It is possible to perform a stretching process of 80% or more of a desired stretching ratio at a very short distance. For this reason, in this method for producing an elongated stretchable animal hair fiber, even an untwisted animal hair fiber bundle containing relatively short single fibers can be stably and uniformly stretched. Therefore, according to this method for producing an extended stretchable animal hair fiber, it is possible to produce an extended stretchable animal hair fiber having a stable quality while suppressing surface glare. After the stretching treatment, the swollen plasticized animal hair fiber bundle is preferably dried after being washed with water.
 上述の通り、延伸縮径獣毛繊維の製造装置は、非常にシンプルな工程に基づき設計される。このため、本発明に係る延伸縮径獣毛繊維の製造装置は、コンパクトであり、設備投資費を軽減することができる。 As described above, the device for producing stretchable animal hair fibers is designed based on a very simple process. For this reason, the manufacturing apparatus of the stretchable diameter animal hair fiber which concerns on this invention is compact, and can reduce a capital investment cost.
 なお、この延伸縮径獣毛繊維の製造装置では、第1の上流ローラの回転軸に沿って見た場合において、第1の上流ローラの回転軸と第2の下流ローラの回転軸とを結ぶ仮想直線または仮想延長直線と、第2の上流ローラの回転軸と第1の下流ローラの回転軸とを結ぶ仮想直線または仮想延長直線とが交差することが好ましい。そして、膨潤可塑化獣毛繊維束は、上流ニップ部、第2の上流ローラ、第1の下流ローラおよび下流ニップ部の順に第1の上流ローラ、第2の上流ローラ、第1の下流ローラおよび第2の下流ローラに接触する。なお、第1の上流ローラの回転軸と第2の上流ローラの回転軸とを結ぶ仮想線または仮想延長線と、第1の下流ローラの回転軸と第2の下流ローラの回転軸とを結ぶ仮想線または仮想延長線とは、平行であってもよい、交差してもよい。 Note that, in this apparatus for producing an elongated stretchable animal hair fiber, when viewed along the rotation axis of the first upstream roller, the rotation axis of the first upstream roller and the rotation axis of the second downstream roller are connected. It is preferable that a virtual straight line or a virtual extended straight line intersect with a virtual straight line or a virtual extended straight line connecting the rotation axis of the second upstream roller and the rotation axis of the first downstream roller. The swollen plasticized animal hair fiber bundle includes an upstream nip portion, a second upstream roller, a first downstream roller, and a downstream nip portion in this order, a first upstream roller, a second upstream roller, a first downstream roller, and Contact the second downstream roller. Note that a virtual line or a virtual extension line connecting the rotation axis of the first upstream roller and the rotation axis of the second upstream roller, and a rotation axis of the first downstream roller and a rotation axis of the second downstream roller are connected. The virtual line or the virtual extension line may be parallel or crossed.
 また、この延伸縮径獣毛繊維の製造装置では、第2の上流ローラの回転軸と第1の下流ローラの回転軸との直線距離は、第1の上流ローラの回転軸と第2の下流ローラの回転軸との直線距離よりも短いことが好ましい。なお、第1の上流ローラ、第2の上流ローラ、第1の下流ローラおよび第2の下流ローラは、全て同一の半径を有することが好ましい。 Further, in this apparatus for producing an elongated stretchable animal hair fiber, the linear distance between the rotation shaft of the second upstream roller and the rotation shaft of the first downstream roller is such that the rotation shaft of the first upstream roller and the second downstream roller It is preferable that the distance is shorter than the linear distance from the rotation axis of the roller. The first upstream roller, the second upstream roller, the first downstream roller, and the second downstream roller preferably all have the same radius.
 また、この延伸縮径獣毛繊維の製造方法では、第1の上流ローラの回転軸に沿って見た場合において、膨潤可塑化獣毛繊維束は、少なくとも、第2の上流ローラの特定外周面部分(以下「第1外周面部分」という)および第1の下流ローラの特定外周面部分(以下「第2外周面部分」という)に接触することが好ましい。なお、第1外周面部分とは、第1の上流ローラの回転軸に沿って見た場合において、「上流ニップ部」から「「第1の上流ローラの回転軸と第2の上流ローラの回転軸とを結ぶ仮想延長線」と「第2の上流ローラの外周線」との交点のうち上流ニップ部と反対側の交点」までの第2の上流ローラの外周面部分である。また、第2外周面部分とは、第1の上流ローラの回転軸に沿って見た場合において、「「第1の下流ローラの回転軸と第2の下流ローラの回転軸とを結ぶ仮想延長線」と「第1の下流ローラの外周線」との交点のうち下流ニップ部と反対側の交点」から「下流ニップ部」までの第1の下流ローラの外周面部分である。すなわち、膨潤可塑化獣毛繊維束は、少なくとも、第2の上流ローラの円周の約1/2および第1の下流ローラ(トップローラ)の円周の約1/2に接触することになる。なお、第1外周面部分および第2外周面部分は、第1の上流ローラの回転軸に沿って見た場合において、第2の上流ローラおよび第1の下流ローラの外周長の3/5以上を占めることが好ましい。また、言い換えると、「上流ニップ部」から「膨潤可塑化獣毛繊維束が第2の上流ローラから離れる点」までの距離が第2の上流ローラの外周長の1/2以上であることが好ましく、第2の上流ローラの外周長の3/5以上であることがより好ましい。また、「膨潤可塑化獣毛繊維束が第1の下流ローラに最初に接触する点」から「下流ニップ部」までの距離が第1の下流ローラの外周長の1/2以上であることが好ましく、第1の下流ローラの外周長の3/5以上であることがより好ましい。膨潤可塑化獣毛繊維束が第2の上流ローラおよび第1の下流ローラの外周面に接触している長さが長いほど、ローラ外周面上での膨潤可塑化獣毛繊維束の接触抵抗が大きくなり、無撚りの膨潤可塑化獣毛繊維束であっても素抜けを防止することできると共に膨潤可塑化獣毛繊維束を均一に延伸することができるからである。 Moreover, in this method for producing an elongated stretchable animal hair fiber, when viewed along the rotation axis of the first upstream roller, the swollen plasticized animal hair fiber bundle is at least a specific outer peripheral surface of the second upstream roller. It is preferable to contact a portion (hereinafter referred to as “first outer peripheral surface portion”) and a specific outer peripheral surface portion (hereinafter referred to as “second outer peripheral surface portion”) of the first downstream roller. Note that the first outer peripheral surface portion refers to "the rotation axis of the first upstream roller and the rotation of the second upstream roller" from the "upstream nip portion" when viewed along the rotation axis of the first upstream roller. This is the outer peripheral surface portion of the second upstream roller up to the intersection of the virtual extension line connecting the shaft and the outer peripheral line of the second upstream roller on the opposite side of the upstream nip. Further, when viewed along the rotation axis of the first upstream roller, the second outer peripheral surface portion is “a virtual extension that connects the rotation axis of the first downstream roller and the rotation axis of the second downstream roller. The outer peripheral surface portion of the first downstream roller from the “intersection on the opposite side of the downstream nip portion” to the “downstream nip portion” of the intersection of the “line” and “the outer periphery of the first downstream roller”. That is, the swollen plasticized animal hair fiber bundle contacts at least about 1/2 of the circumference of the second upstream roller and about 1/2 of the circumference of the first downstream roller (top roller). . The first outer peripheral surface portion and the second outer peripheral surface portion are not less than 3/5 of the outer peripheral length of the second upstream roller and the first downstream roller when viewed along the rotation axis of the first upstream roller. Preferably. In other words, the distance from the “upstream nip portion” to “the point where the swollen plasticized animal hair fiber bundle is separated from the second upstream roller” is ½ or more of the outer peripheral length of the second upstream roller. Preferably, it is 3/5 or more of the outer peripheral length of the second upstream roller. Further, the distance from “the point at which the swollen plasticized animal hair fiber bundle first contacts the first downstream roller” to the “downstream nip portion” is ½ or more of the outer peripheral length of the first downstream roller. Preferably, it is more preferably 3/5 or more of the outer peripheral length of the first downstream roller. The longer the length at which the swollen plasticized animal hair fiber bundle is in contact with the outer peripheral surfaces of the second upstream roller and the first downstream roller, the greater the contact resistance of the swollen plasticized animal hair fiber bundle on the roller outer peripheral surface. This is because even a non-twisted swollen plasticized animal hair fiber bundle can prevent unplugging and can uniformly stretch the swollen plasticized animal hair fiber bundle.
 ちなみに、第1外周面部分および第2外周面部分は、第1の上流ローラの回転軸に沿って見た場合において、S字または逆S字を上下に三等分した場合の上部および下部に相当する。また、第1外周面部分と第2外周面部分とは、互いに対向しない。 By the way, the first outer peripheral surface portion and the second outer peripheral surface portion are formed at the upper and lower portions when the S-shape or the reverse S-shape is divided into three equal parts when viewed along the rotation axis of the first upstream roller. Equivalent to. Further, the first outer peripheral surface portion and the second outer peripheral surface portion do not face each other.
 また、この延伸縮径獣毛繊維の製造方法では、第1の上流ローラの回転軸と第2の下流ローラの回転軸とを結ぶ仮想直線と、第2の上流ローラの回転軸と第1の下流ローラの回転軸とを結ぶ仮想直線とが同一仮想直線上に位置してもかまわない。かかる場合であっても、膨潤可塑化獣毛繊維束は、上流ニップ部、第2の上流ローラ、第1の下流ローラおよび下流ニップ部の順に第1の上流ローラ、第2の上流ローラ、第1の下流ローラおよび第2の下流ローラに接触する。なお、かかる場合、第1の上流ローラの回転軸と第2の上流ローラの回転軸とを結ぶ仮想線と、第1の下流ローラの回転軸と第2の下流ローラの回転軸とを結ぶ仮想線とも、同一仮想直線に位置することになる。 Further, in this method for producing an extended stretchable animal hair fiber, a virtual straight line connecting the rotation shaft of the first upstream roller and the rotation shaft of the second downstream roller, the rotation shaft of the second upstream roller, and the first The virtual straight line connecting the rotation axis of the downstream roller may be located on the same virtual straight line. Even in such a case, the swollen plasticized animal hair fiber bundle is composed of the first upstream roller, the second upstream roller, the second upstream roller, the second upstream roller, the first downstream roller, and the downstream nip portion in this order. Contact one downstream roller and a second downstream roller. In such a case, the imaginary line connecting the rotation axis of the first upstream roller and the rotation axis of the second upstream roller, and the imaginary line connecting the rotation axis of the first downstream roller and the rotation axis of the second downstream roller. Both lines are located on the same virtual straight line.
 なお、膨潤可塑化獣毛繊維束の延伸時における環境温度は、特に限定されることはなく、20度Cから80度Cの範囲内であることが好ましく、「膨潤可塑化剤の水分の蒸発を防ぐと共に膨潤可塑化獣毛繊維束に膨潤可塑化剤を十分に含ませたまま膨潤可塑化獣毛繊維束を次の固定化工程に投入することができる観点」および「加熱源を必要とせず、製造コストの低減および作業性の向上、設備構造の簡素化あるいは設備投資費の低減を実現することができる観点」から、20度Cから30度Cの範囲内(室温)であることがより好ましい。なお、延伸は、膨潤可塑化剤中で行われてもよい。かかる場合、製造装置をよりコンパクトにすることができる。 The environmental temperature at the time of stretching the swollen plasticized animal hair fiber bundle is not particularly limited, and is preferably in the range of 20 ° C. to 80 ° C. The viewpoint that the swollen plasticized animal hair fiber bundle can be put into the next immobilization step while the swollen plasticized animal hair fiber bundle is sufficiently contained in the swollen plasticized animal hair fiber bundle "and" there is a need for a heating source From the viewpoint of realizing a reduction in manufacturing cost, improvement in workability, simplification of equipment structure or reduction in capital investment cost ”, it should be within a range of 20 ° C. to 30 ° C. (room temperature). More preferred. The stretching may be performed in a swelling plasticizer. In such a case, the manufacturing apparatus can be made more compact.
 また、延伸後の膨潤可塑化獣毛繊維束を水洗、乾燥させることにより、延伸形状を一時的に保持させ必要に応じて延伸前の略原毛の状態に復元させることができる延伸縮径獣毛繊維(以下「延伸復元獣毛繊維」という)を製造することができる。また、延伸後の膨潤可塑化獣毛繊維束を加熱(固定化)、酸化および中和し、水洗、乾燥させることにより、延伸形状を永久的に保持させることができる延伸縮径獣毛繊維(以下「延伸固定化獣毛繊維」という)を製造することができる。すなわち、本発明に係る延伸縮径獣毛繊維の製造方法では、延伸復元獣毛繊維および延伸固定化獣毛繊維、それぞれ異なる特性を有する二種類の延伸縮径獣毛繊維を製造することができる。 Further, by stretching and stretching the swollen plasticized animal hair fiber bundle after stretching, the stretched shape animal hair can be temporarily retained in its stretched shape and restored to the state of substantially raw hair before stretching as necessary. Fiber (hereinafter referred to as “stretched restored animal hair fiber”) can be produced. Further, the stretched and plasticized animal hair fiber bundle after stretching is heated (fixed), oxidized and neutralized, washed with water, and dried to allow the stretched shape animal hair fiber (which can retain the stretched shape permanently) ( (Hereinafter referred to as “stretch-immobilized animal hair fibers”). That is, in the method for producing a stretched animal hair fiber according to the present invention, stretched and restored animal hair fibers and stretch-fixed animal hair fibers, two types of stretched and stretched animal hair fibers each having different characteristics can be produced. .
 よって、この延伸縮径獣毛繊維の製造方法を利用すれば、設備の複雑化や大型化、生産性の低下を伴うことなく、獣毛繊維表面のギラツキを抑えながら比較的簡便に延伸縮径獣毛繊維を製造することができる。 Therefore, if this method for producing stretched and stretched animal hair fibers is used, the stretched and stretched diameter of the animal hair fiber surface can be controlled relatively easily while suppressing glare on the surface of the animal hair fiber without increasing the complexity and size of the equipment and reducing the productivity. Animal hair fibers can be produced.
 なお、第1の下流ローラの周速度は、第2の上流ローラの周速度よりも高く設定される。このため、第2の上流ローラから第1の下流ローラに向かって流れる膨潤可塑化獣毛繊維束が延伸されることになる。 Note that the peripheral speed of the first downstream roller is set higher than the peripheral speed of the second upstream roller. For this reason, the swollen plasticized animal hair fiber bundle that flows from the second upstream roller toward the first downstream roller is stretched.
 また、繊維流れに沿った上流ニップ部と下流ニップ部との間(以下「延伸スパン」という)の距離は60mm以上300mm以下であることが好ましく、80mm以上250mm以下であることがより好ましい。繊維流れに沿った上流ニップ部と下流ニップ部との距離をこの範囲内とすると、ニップローラ群中のローラの径を適切にすることができると共に単繊維の素抜けや延伸ムラを抑制しやすくすることができるからである。なお、この延伸縮径獣毛繊維の製造方法を利用すれば、延伸スパンが獣毛繊維原毛の平均長さ以上であってもその獣毛繊維を延伸することができ、また、その獣毛繊維が無撚りであってもその獣毛繊維を延伸することができることが本願発明者らの実験によって明らかになった。例えば、一般的な羊毛繊維の平均長さは60mmから100mmであるが、本発明に係る延伸縮径獣毛繊維の製造方法では、延伸スパンを200mmに設定しても安定して羊毛繊維を延伸することができた。通常、平均長さ60mmの羊毛繊維束を延伸しようとする場合、延伸スパンが200mmであると、羊毛繊維束中の個々の単繊維が、上記いずれのニップ部でも把持されない状態が生じることになる。しかしながら、この延伸縮径獣毛繊維の製造方法では、延伸前の羊毛繊維束が膨潤可塑化剤を含有して柔らかくなると共に第2の上流ローラおよび第1の下流ローラの外周面に密着する。このため、延伸スパンが獣毛繊維の平均長さ以上であってもドラフト(繊維同士の相対的なズレ)の発生が少なく、単繊維同士が連続して連なった一本の繊維束のような状態となって獣毛繊維が均一に延伸されるものと推察される。 Further, the distance between the upstream nip portion and the downstream nip portion along the fiber flow (hereinafter referred to as “stretching span”) is preferably 60 mm or more and 300 mm or less, and more preferably 80 mm or more and 250 mm or less. When the distance between the upstream nip portion and the downstream nip portion along the fiber flow is within this range, the diameter of the rollers in the nip roller group can be made appropriate, and the single fiber can easily be prevented from being pulled out or unevenly drawn. Because it can. In addition, if the manufacturing method of this stretchable diameter animal hair fiber is used, the animal hair fiber can be stretched even if the stretch span is equal to or greater than the average length of the animal hair fiber, and the animal hair fiber It has been clarified by experiments of the present inventors that the animal hair fiber can be stretched even if the fiber is untwisted. For example, the average length of a general wool fiber is 60 mm to 100 mm. However, in the method for producing an extended stretchable animal hair fiber according to the present invention, the wool fiber is stably stretched even if the stretch span is set to 200 mm. We were able to. Normally, when a wool fiber bundle having an average length of 60 mm is to be drawn, if the drawing span is 200 mm, a state in which individual single fibers in the wool fiber bundle are not gripped in any of the nip portions will occur. . However, in this method for producing an elongated stretchable animal hair fiber, the wool fiber bundle before stretching contains a swelling plasticizer and becomes soft and adheres closely to the outer peripheral surfaces of the second upstream roller and the first downstream roller. For this reason, even if the drawing span is equal to or greater than the average length of animal hair fibers, there is little occurrence of drafts (relative displacement between fibers), such as a single fiber bundle in which single fibers are continuously connected. It is inferred that the animal hair fibers are uniformly stretched.
 また、延伸ゾーンの長さは5mm以上50mm以下の範囲内であることが好ましく、5mm以上30mm以下の範囲内であることがより好ましく、10mm以上30mm以下の範囲内であることがさらに好ましい。 Further, the length of the stretching zone is preferably in the range of 5 mm to 50 mm, more preferably in the range of 5 mm to 30 mm, and still more preferably in the range of 10 mm to 30 mm.
 ところで、膨潤可塑化獣毛繊維の延伸のほとんどは、実質的に延伸ゾーンで行われている。ちなみに、本願発明者らは、膨潤可塑化獣毛繊維束の長手方向に等間隔でマークを付けて膨潤可塑化獣毛繊維束を上述の製造装置に供給して延伸を行い、延伸の大半が延伸ゾーンで行われていることを確認した。 Incidentally, most of the stretching of the swollen plasticized animal hair fibers is substantially performed in the stretching zone. By the way, the inventors of the present invention apply marks at equal intervals in the longitudinal direction of the swollen plasticized animal hair fiber bundle, supply the swollen plasticized animal hair fiber bundle to the above-described manufacturing apparatus, and perform stretching. It was confirmed that this was done in the stretching zone.
 すなわち、この延伸ゾーンの短い距離で膨潤可塑化獣毛繊維を瞬間的に延伸することにより、膨潤可塑化獣毛繊維を均一に延伸することができると共に、短い獣毛繊維であっても長い獣毛繊維と同じように延伸することができる。延伸ゾーンの距離をこの範囲内とすると、製造装置をコンパクト化することができると共に、単繊維の素抜けを抑制することができる。 That is, by instantly stretching the swollen plasticized animal hair fibers at a short distance in the drawing zone, the swollen plasticized animal hair fibers can be uniformly drawn, and even if the short animal hair fibers are long, It can be stretched in the same way as hair fibers. When the distance of the drawing zone is within this range, the manufacturing apparatus can be made compact and the single fiber can be prevented from coming off.
 また、この延伸縮径獣毛繊維の製造方法では、膨潤可塑化獣毛繊維束が1.1倍以上3.0倍以下の倍率で延伸されることが好ましい。膨潤可塑化獣毛繊維束がこのような延伸倍率で延伸されると、薄く軽量で肌触りのよい衣料品や高級な衣料品の製造に必要とされる18.7μm(表示名SUPER100)や、天然の産毛量が極端に少ない繊維径13~17μmの獣毛繊維を安価で安定して供給できるからである。 Further, in this method for producing an elongated stretchable animal hair fiber, it is preferable that the swollen plasticized animal hair fiber bundle is stretched at a magnification of 1.1 to 3.0 times. When the swollen plasticized animal hair fiber bundle is drawn at such a draw ratio, it is 18.7 μm (display name SUPER100), which is necessary for the production of thin, lightweight, comfortable clothes and high-grade clothing, This is because animal hair fibers having a fiber diameter of 13 to 17 μm with an extremely small amount of hair production can be stably supplied at low cost.
 また、この延伸縮径獣毛繊維の製造方法では、上流ニップローラ対および下流ニップローラ対のみで膨潤可塑化獣毛繊維束が延伸されることが好ましい。上流ニップローラ対および下流ニップローラ対のみで膨潤可塑化獣毛繊維束が延伸されると、短い延伸スパンで短時間に延伸がなされるため、繊維切れ、繊維の素抜け、延伸ムラなどの発生を防止することができるからである。 Further, in this method of producing an elongated stretched animal hair fiber, it is preferable that the swollen plasticized animal hair fiber bundle is stretched only by the upstream nip roller pair and the downstream nip roller pair. When a swollen plasticized animal hair fiber bundle is stretched with only the upstream nip roller pair and the downstream nip roller pair, it is stretched in a short time with a short stretch span, thus preventing the occurrence of fiber breakage, fiber slippage, and uneven stretching. Because it can be done.
 また、この延伸縮径獣毛繊維の製造方法では、獣毛繊維束および膨潤可塑化獣毛繊維束は無撚りであることが好ましい。 Further, in this method for producing an elongated stretchable animal hair fiber, the animal hair fiber bundle and the swollen plasticized animal hair fiber bundle are preferably untwisted.
 ところで、従来の獣毛繊維延伸方法では、獣毛繊維束があらかじめ加撚されるか、獣毛繊維束が加撚されながら延伸固定化されている。このように獣毛繊維束が加撚されるのは、獣毛繊維束を加撚しなければ単繊維の素抜けが発生し、多段階の延伸ローラに繊維が巻き付き、工程上のトラブルを発生させたり、延伸されないままの状態の単繊維が延伸された繊維に混ざり込み、延伸縮径獣毛繊維の品質の低下を招いたりする等の問題が生じやすいからである。これに対し、本発明に係る延伸縮径獣毛繊維の製造方法では、上述の通り、無撚りの獣毛繊維束を直接延伸することができる。このため、従来の獣毛繊維延伸方法のように獣毛繊維束の加撚および解撚が不要であり、延伸縮径獣毛繊維の製造コストを低減することができる。また、上述したように、従来の獣毛繊維延伸方法では、膨潤可塑化獣毛繊維束が加撚された状態で延伸されるため、獣毛繊維束中の単繊維に局部的な凹凸変形が生じていた。この結果、得られる延伸縮径獣毛繊維に光の反射によるギラツキが発生していた。これに対し、本発明に係る延伸縮径獣毛繊維の製造方法では、上述の通り、無撚りの獣毛繊維束を直接延伸することができる。このため、この延伸縮径獣毛繊維の製造方法では、ギラツキが抑制されたマイルドな外観を有する延伸獣毛繊維を提供することができる。また、かかる場合、製造設備を小型化することができると共に製造設備の取り扱いが簡単になり、作業性を向上させると共に投資費用などを抑えることができる。 By the way, in the conventional animal hair fiber drawing method, the animal hair fiber bundle is pre-twisted, or the animal hair fiber bundle is drawn and fixed while being twisted. The animal hair fiber bundles are twisted in this way. If the animal hair fiber bundles are not twisted, the single fibers will come loose, and the fibers will wind around the multi-stage drawing roller, causing problems in the process. This is because there is a tendency that a single fiber that is not stretched is mixed with the stretched fiber and the quality of the animal fiber with a long stretched diameter is deteriorated. On the other hand, as described above, in the method for producing an elongated stretchable animal hair fiber according to the present invention, an untwisted animal hair fiber bundle can be directly stretched. This eliminates the need for twisting and untwisting of the animal hair fiber bundle as in the conventional animal hair fiber drawing method, and can reduce the production cost of the stretchable animal hair fiber. In addition, as described above, in the conventional animal hair fiber drawing method, since the swollen plasticized animal hair fiber bundle is drawn in a twisted state, local uneven deformation is caused in the single fiber in the animal hair fiber bundle. It was happening. As a result, glare due to the reflection of light occurred in the obtained stretchable animal hair fiber. On the other hand, as described above, in the method for producing an elongated stretchable animal hair fiber according to the present invention, an untwisted animal hair fiber bundle can be directly stretched. For this reason, in this method for producing an elongated stretchable animal hair fiber, a stretched animal hair fiber having a mild appearance with suppressed glare can be provided. Further, in such a case, the manufacturing facility can be reduced in size and the handling of the manufacturing facility can be simplified, so that the workability can be improved and the investment cost can be suppressed.
 また、この延伸縮径獣毛繊維の製造装置は加熱装置および酸化中和装置を有することが好ましい。そして、この延伸縮径獣毛繊維の製造方法では、膨潤可塑化獣毛繊維束が延伸された後、膨潤可塑化獣毛繊維束が緊張されたままの状態で、加熱装置により膨潤可塑化獣毛繊維束が60度C以上150度C以下の範囲内の温度に加熱されて膨潤可塑化獣毛繊維束中の膨潤可塑化獣毛繊維が固定化され、酸化中和装置により膨潤可塑化獣毛繊維が酸化された後に中和される。なお、ここにいう「固定化」とは、長さ方向に所定の倍率で延伸した膨潤可塑化獣毛繊維束を延伸形状に固定(延伸形状に維持する)させ、延伸固定化獣毛繊維を製造することを意味する。すなわち、延伸固定化獣毛繊維は、その後の紡績や染色、整理工程、あるいは衣料品として加工した後の取り扱いや処理によってその形状が実質的に失われない。また、加熱装置としては、特に限定されないが、例えば、スチーム供給装置、加熱プレス装置、加熱ドラム装置等が挙げられる。また、加熱装置の加熱方法としては、特に限定されないが、電熱加熱方式、高周波加熱方式、高温オイルや、スチーム、熱風などの循環加熱方式などが挙げられる。
 固定化温度が上述の温度範囲内であると、安定して延伸縮径獣毛繊維の形状を永久的に固定化することができる。
Moreover, it is preferable that the manufacturing apparatus of this extended stretchable animal hair fiber has a heating apparatus and an oxidation neutralization apparatus. Then, in this method for producing an elongated stretched animal hair fiber, after the swollen plasticized animal hair fiber bundle is stretched, the swollen plasticized animal hair fiber bundle is stretched by a heating device in a state where the swollen plasticized animal hair fiber bundle is kept in tension. The hair fiber bundle is heated to a temperature in the range of 60 ° C. to 150 ° C. to fix the swollen plasticized animal hair fiber in the swollen plasticized animal hair fiber bundle, and the swollen plasticized animal using an oxidation neutralizer. The hair fibers are neutralized after being oxidized. The term “immobilization” as used herein refers to fixing a swollen plasticized animal hair fiber bundle that has been stretched at a predetermined magnification in the length direction to a stretched shape (maintaining the stretched shape), Means to manufacture. In other words, the shape of the stretch-immobilized animal hair fiber is not substantially lost by subsequent spinning, dyeing, arranging process, or handling and processing after processing as clothing. Moreover, it does not specifically limit as a heating apparatus, For example, a steam supply apparatus, a heating press apparatus, a heating drum apparatus etc. are mentioned. The heating method of the heating device is not particularly limited, and examples thereof include an electric heating method, a high-frequency heating method, a high-temperature oil, a circulating heating method such as steam and hot air, and the like.
When the immobilization temperature is within the above-described temperature range, the shape of the extended stretchable animal hair fiber can be permanently immobilized stably.
 また、この延伸縮径獣毛繊維の製造装置は加熱ローラをさらに有することが好ましい。そして、この延伸縮径獣毛繊維の製造方法では、加熱装置は加熱ローラを加熱し、膨潤可塑化獣毛繊維束は、加熱ローラの外表面に直接接触されて固定化されることが好ましい。 In addition, it is preferable that the apparatus for producing an elongated stretchable animal hair fiber further has a heating roller. And in this manufacturing method of an extended stretchable animal hair fiber, it is preferable that a heating apparatus heats a heating roller, and a swelling plasticization animal hair fiber bundle is directly contacted and fixed to the outer surface of a heating roller.
 このため、この延伸縮径獣毛繊維の製造方法では、シンプルな設備で短時間の間に永久的な固定化処理を実施することができる。また、高圧のスチームチャンバーなどの大がかり設備を必要としないため、設備投資費を軽減することができると共に作業の安全性をも高めることができる。 For this reason, in this method for producing stretched diameter animal hair fibers, it is possible to perform a permanent fixing process with a simple facility in a short time. In addition, since large-scale equipment such as a high-pressure steam chamber is not required, the capital investment cost can be reduced and the safety of work can be improved.
 また、この延伸縮径獣毛繊維の製造方法では、膨潤可塑化獣毛繊維束が加熱ローラと少なくとも1個の加圧ローラとで加圧されながら固定化されることが好ましい。 Further, in this method for producing an elongated stretched animal hair fiber, it is preferable that the swollen plasticized animal hair fiber bundle is fixed while being pressed by a heating roller and at least one pressure roller.
 この延伸縮径獣毛繊維の製造方法では、延伸縮径獣毛繊維束を湿潤状態(あたかもスチームで加熱される条件に類似した状態)としながら固定化することができる。 In this method for producing an extended stretchable animal hair fiber, the stretched stretchable animal hair fiber bundle can be fixed in a wet state (as if it is similar to a condition heated by steam).
 また、この延伸縮径獣毛繊維の製造方法では、膨潤可塑化獣毛繊維束は、膨潤可塑化剤を60重量%以上含有することが好ましく、膨潤可塑化剤を70重量%以上含有することがより好ましい。膨潤可塑化獣毛繊維束の含水率が低いと、獣毛繊維を構成するタンパク質のガラス転移温度が高くなり、加熱による延伸縮径獣毛繊維の固定化が不安定になるからである。なお、膨潤可塑化獣毛繊維束中の膨潤可塑化剤の含有率は、加熱ローラの温度、固定化速度、延伸獣毛繊維束の投入量などの所定条件下における実験結果等に基づいて決定することが好ましい。 Further, in this method for producing an elongated stretched animal hair fiber, the swollen plasticized animal hair fiber bundle preferably contains 60% by weight or more of the swollen plasticizer, and contains 70% by weight or more of the swollen plasticizer. Is more preferable. This is because, when the water content of the swollen plasticized animal hair fiber bundle is low, the glass transition temperature of the protein constituting the animal hair fiber becomes high, and the fixation of the animal fiber with a stretched diameter by heating becomes unstable. The content of the swelling plasticizer in the swollen plasticized animal fiber bundle is determined based on the experimental results under predetermined conditions such as the temperature of the heating roller, the fixing speed, and the amount of the drawn animal fiber bundle introduced. It is preferable to do.
 そして、上述の延伸縮径獣毛繊維の製造方法により得られる延伸縮径獣毛繊維から延伸復元獣毛紡績糸を製造することができる。なお、延伸復元獣毛紡績糸を原毛の状態に復元させるためには、延伸復元獣毛紡績糸を80~100度Cの温水に浸漬すればよい。また、かかる場合、延伸復元獣毛紡績糸を煮沸してもよい。また、同延伸縮径獣毛繊維とそれ以外の繊維とを組み合わせて延伸復元複合獣毛紡績糸を製造することもできる。なお、「延伸縮径獣毛繊維以外の繊維」としては、例えば、未延伸の獣毛繊維や合成繊維が好ましい。延伸復元複合獣毛紡績糸は、延伸縮径獣毛繊維の延伸と復元によって新規な形状やデザインの紡績糸を提供できる。 Then, a stretched restored animal hair spun yarn can be produced from the stretched and stretched animal hair fiber obtained by the above-described method of producing a stretched and stretched animal hair fiber. In order to restore the stretched restored animal hair spun yarn to the original hair state, the stretched restored animal hair spun yarn may be immersed in warm water of 80 to 100 degrees C. In such a case, the stretched restored animal hair spun yarn may be boiled. In addition, a stretch-restored composite animal hair spun yarn can also be produced by combining the same stretched diameter animal hair fiber and other fibers. In addition, as “fibers other than the stretched and contracted diameter animal hair fibers”, for example, unstretched animal hair fibers and synthetic fibers are preferable. The stretched and restored composite animal hair spun yarn can provide a spun yarn having a new shape and design by stretching and restoring the stretched diameter animal hair fiber.
 また、上述の延伸復元獣毛紡績糸または延伸復元複合獣毛紡績糸を延伸前の繊維形状にほぼ復元させることにより、復元獣毛紡績糸を製造することができる。また、このような復元獣毛紡績糸を用いて布帛を製造することができる。このような復元獣毛紡績糸や布帛は、嵩高性や芯鞘構造の紡績糸の鞘部分での被覆率を向上することができ、延いては新規な紡績糸や布帛を提供することができる。 Also, a restored animal hair spun yarn can be produced by substantially restoring the above-described stretched restored animal hair spun yarn or stretched restored composite animal hair spun yarn to the fiber shape before stretching. Moreover, a fabric can be manufactured using such a restored animal hair spun yarn. Such a restored animal hair spun yarn and fabric can improve the bulkiness and the covering ratio of the spun yarn of the core-sheath structure, and thus can provide a new spun yarn and fabric. .
 また、上述の延伸復元獣毛紡績糸または延伸復元複合獣毛紡績糸を布帛に加工した後に延伸復元獣毛紡績糸または延伸復元複合獣毛紡績糸を延伸前の繊維形状にほぼ復元させることにより、復元獣毛布帛を製造することができる。すなわち、最大のカバーファクターで製編した編物を製編後煮沸して略原毛の状態に復元させることによって、現在の製編機では製編することができない編物を製造することができる。 Further, after the above-described stretched restored animal hair spun yarn or stretched restored composite animal hair spun yarn is processed into a fabric, the stretched restored animal hair spun yarn or stretched restored composite animal hair spun yarn is substantially restored to the fiber shape before stretching. A restored animal blanket fabric can be produced. That is, a knitted fabric that cannot be knitted with the current knitting machine can be manufactured by boiling a knitted fabric knitted with the maximum cover factor and restoring it to a substantially raw hair state after knitting.
 なお、上述の延伸縮径獣毛繊維の製造方法により得られる延伸縮径獣毛繊維束では、長手方向の少なくとも一部分において径方向の断面形状が円形である単繊維と、径方向の断面形状が非円形状である単繊維とが混在していることが好ましい。繊維表面のギラツキを防止することができるからである。また、その単繊維の平均繊維径は13μm以上28μm以下の範囲内であることが好ましく、13μm以上25μm以下の範囲内であることがより好ましく、13μm以上22μm以下の範囲内であることがさらに好ましい。上述の通り、細径の獣毛繊維の産出量が少なく、価格の高騰が伴う現状において、上述のような直径を有する獣毛繊維を安定的に供給することができるからである。 In addition, in the extended stretchable animal hair fiber bundle obtained by the above-described method for producing stretchable animal hair fibers, the single fiber having a circular cross-sectional shape in the radial direction in at least a part of the longitudinal direction, and the cross-sectional shape in the radial direction are It is preferable that non-circular single fibers are mixed. This is because glare on the fiber surface can be prevented. The average fiber diameter of the single fiber is preferably in the range of 13 μm to 28 μm, more preferably in the range of 13 μm to 25 μm, and still more preferably in the range of 13 μm to 22 μm. . This is because, as described above, the production of small animal hair fibers is small, and the animal hair fibers having the diameter as described above can be stably supplied in the present situation accompanied by a rise in price.
 また、このような延伸縮径獣毛繊維束が主成分となるように同延伸縮径獣毛繊維束を他の獣毛繊維束と混繊させることもできる。このようにすれば、今までの繊維産業では製造することができなかった新たな特徴を有する紡績糸や布帛(織物、編物、フェルトなど)を創出することができる。 In addition, the same stretchable animal hair fiber bundle can be mixed with other animal hair fiber bundles such that such a stretchable animal hair fiber bundle becomes a main component. In this way, it is possible to create spun yarns and fabrics (woven fabrics, knitted fabrics, felts, etc.) having new characteristics that could not be produced in the textile industry so far.
 また、上述の延伸縮径獣毛繊維束または混繊獣毛繊維束から延伸固定獣毛繊維紡績糸を製造することができる。また、このような延伸固定獣毛繊維紡績糸を用いて布帛を製造することができる。このような布帛は、天然の産毛量の少ない細番手の獣毛繊維と同等の風合いや肌触りを有する衣料製品を、原毛の価格に左右されることなく安定して供給することができる。 Further, a stretched fixed animal hair fiber spun yarn can be produced from the above-mentioned stretched and contracted animal hair fiber bundle or mixed animal hair fiber bundle. Moreover, a fabric can be manufactured using such stretched fixed animal hair fiber spun yarn. Such a fabric can stably supply a clothing product having a texture and feel equivalent to that of natural animal hair fibers with a small amount of natural hair production, regardless of the price of the raw hair.
 本発明に係る延伸縮径獣毛繊維の製造方法を利用すれば、設備の複雑化や大型化、生産性の低下を伴うことなく、獣毛繊維表面のギラツキを抑えながら比較的簡便に延伸縮径獣毛繊維を製造することができる。 If the method for producing stretched diameter animal hair fibers according to the present invention is used, the stretch and shrinkage of the animal hair fiber surface is suppressed relatively easily and without increasing the complexity and size of the equipment and reducing the productivity. Diameter animal hair fibers can be produced.
本発明の実施の形態に係る延伸縮径獣毛繊維の製造装置の模式的概略図である。It is a typical schematic diagram of a manufacturing device of an extended expansion diameter animal hair fiber concerning an embodiment of the invention. 本発明の実施の形態に係る延伸機構の構成を示す模式的概略図である。It is a typical schematic diagram showing the composition of the extending mechanism concerning an embodiment of the invention. 本発明の実施の形態に係る延伸縮径獣毛繊維の延伸状態の一例を示す写真である。It is a photograph which shows an example of the extending | stretching state of the extended expansion-diameter animal hair fiber which concerns on embodiment of this invention. 本発明の実施の形態に係る延伸縮径獣毛繊維の加熱ローラ非接触側表面の電子顕微鏡写真である。It is an electron micrograph of the heating roller non-contact side surface of the extended stretch diameter animal hair fiber which concerns on embodiment of this invention. 本発明の実施の形態に係る延伸縮径獣毛繊維裏面の加熱ローラ接触側表面の電子顕微鏡写真である。It is an electron micrograph of the heating roller contact side surface of the back surface of the extended stretch diameter animal hair fiber which concerns on embodiment of this invention. 本発明の実施の形態に係る延伸縮径獣毛繊維の円周方向断面の電子顕微鏡写真である。It is an electron micrograph of the cross section of the circumference direction of the extended expansion-diameter animal hair fiber which concerns on embodiment of this invention. 本発明の実施例1において製造された延伸縮径獣毛繊維の繊維径分布グラフである。It is a fiber diameter distribution graph of the extended expansion-diameter animal hair fiber manufactured in Example 1 of this invention. 本発明の実施例3において製造された延伸縮径獣毛繊維の繊維径分布グラフである。It is a fiber diameter distribution graph of the extended stretchable animal hair fiber manufactured in Example 3 of this invention. 本発明の実施例6において製造された延伸復元羊毛紡績糸を製編した編地の電子顕微鏡写真である。It is an electron micrograph of the knitted fabric knitted by the stretch restored wool spun yarn manufactured in Example 6 of this invention. 本発明の実施例6において製造された延伸復元羊毛紡績糸を製編した編地を煮沸処理した後の電子顕微鏡写真である。It is an electron micrograph after carrying out the boiling process of the knitted fabric knitted by the stretch | restoration restoration | reconstruction wool spun yarn manufactured in Example 6 of this invention. 変形例(C)に係る延伸機構の構成を示す模式的概略図である。It is a typical schematic diagram showing the composition of the extending mechanism concerning modification (C).
 本発明の実施の形態に係る延伸復元獣毛繊維は、主に、膨潤可塑化工程、延伸工程、水洗工程および乾燥工程を経て製造される。また、本発明の実施の形態に係る延伸固定化獣毛繊維は、主に、膨潤可塑化工程、延伸工程、固定化工程、酸化中和・水洗工程および乾燥工程を経て製造される。なお、具体的には、延伸復元獣毛繊維および延伸固定化獣毛繊維は共に図1に示される獣毛繊維延伸固定装置100を用いて製造される。なお、図1中、符号A、BおよびCの各矢印は、獣毛繊維延伸固定装置100における獣毛繊維束の流れ方向を示している。 The stretched and restored animal hair fiber according to the embodiment of the present invention is mainly manufactured through a swelling plasticization process, a stretching process, a water washing process, and a drying process. In addition, the stretch-immobilized animal hair fiber according to the embodiment of the present invention is mainly manufactured through a swelling plasticization process, a stretching process, a fixing process, an oxidation neutralization / water washing process, and a drying process. Specifically, both the stretch-restored animal hair fibers and the stretch-immobilized animal hair fibers are manufactured using the animal hair fiber-stretching and fixing device 100 shown in FIG. In FIG. 1, arrows A, B, and C indicate the flow direction of the animal hair fiber bundle in the animal hair fiber drawing and fixing device 100.
 なお、延伸復元獣毛繊維とは、延伸形状を一時的に保持させ必要に応じて延伸前の略原毛の状態に復元させることができる延伸縮径獣毛繊維である。また、延伸固定化獣毛繊維とは、延伸形状を永久的に保持させることができる延伸縮径獣毛繊維である。 The stretch restored animal hair fiber is a stretch-stretched animal hair fiber that can temporarily retain the stretched shape and restore it to the state of substantially raw hair before stretching as required. Further, the stretch-immobilized animal hair fiber is an elongated stretch-diameter animal hair fiber that can keep the stretched shape permanently.
 以下、獣毛繊維延伸固定装置100内の各装置を参照しながら上述の各工程について詳述する。 Hereinafter, each process described above will be described in detail with reference to each device in the animal hair fiber drawing and fixing device 100.
 <延伸復元獣毛繊維および延伸固定化獣毛繊維の製造>
 (1)膨潤可塑化工程
 膨潤可塑化工程では、図1に示されるように、無撚りの獣毛繊維束1が膨潤可塑化処理装置30に連続的に導かれて膨潤可塑化処理される。なお、この膨潤可塑化処理としては、従来技術を適用することができる。
<Manufacture of stretched restored animal hair fiber and stretch-fixed animal hair fiber>
(1) Swelling Plasticization Step In the swelling plasticization step, as shown in FIG. 1, the untwisted animal hair fiber bundle 1 is continuously guided to the swelling plasticizing device 30 and subjected to the swelling plasticizing treatment. As this swelling plasticization treatment, a conventional technique can be applied.
 なお、本発明に適用することができる獣毛繊維として代表的なものは羊毛であるが、カシミヤ、モヘヤ、キャメル、アンゴラなども本発明に適用することができる。これらの獣毛繊維束1としては、あらかじめ複数の単繊維を引き揃えた無撚りの獣毛繊維束(トップスライバー)を使用することができる。なお、このような獣毛繊維束は、一般的に市販されている。また、獣毛繊維の平均長さは20mm以上であることが好ましく、30mm以上であることがより好ましい。 In addition, although the typical thing of the animal hair fiber which can be applied to the present invention is wool, cashmere, mohair, camel, angora, etc. can also be applied to the present invention. As these animal hair fiber bundles 1, untwisted animal hair fiber bundles (top sliver) in which a plurality of single fibers are preliminarily arranged can be used. Such animal hair fiber bundles are generally commercially available. Moreover, it is preferable that the average length of animal hair fiber is 20 mm or more, and it is more preferable that it is 30 mm or more.
 膨潤可塑化処理装置30は、図1に示されるように、主に、膨潤可塑化槽4および複数のガイドローラ3から構成される。膨潤可塑化槽4には、図1に示される通り、膨潤可塑化水溶液2が満たされている。ガイドローラ3は、膨潤可塑化槽4の内部に配置されており、無撚りの獣毛繊維束1を膨潤可塑化槽4の内部に導いて膨潤可塑化水溶液2に浸漬させる。 As shown in FIG. 1, the swelling plasticization processing apparatus 30 mainly includes a swelling plasticization tank 4 and a plurality of guide rollers 3. The swelling plasticization tank 4 is filled with the swelling plasticizing aqueous solution 2 as shown in FIG. The guide roller 3 is disposed inside the swelling plasticization tank 4, and guides the untwisted animal hair fiber bundle 1 into the swelling plasticization tank 4 and immerses it in the swelling plasticization aqueous solution 2.
 膨潤可塑化水溶液2としては、水に添加剤を溶解させた水溶液等が挙げられる。なお、膨潤可塑化水溶液2は、従前から使用されているものであっても差し支えない。添加剤としては、例えば、界面活性剤、水素結合切断剤、架橋結合切断剤、疎水結合弛緩剤等が挙げられる。界面活性剤としては、例えば、アルキルフェニルエーテル系活性剤などが挙げられる。また、架橋結合切断剤としては、ジスルフィド結合切断剤、例えばチオール化合物(チオグリコール酸、メルカプトプロピオン酸、チオグリセリン、L-シスチン等)、アルキルメルカプタン、メルカプトアルコール類、メルカプトアミン類などの含硫アミノ酸、亜硫酸ナトリウム、重亜硫酸ナトリウム、モノエタノールアミンサルファイト、モノエタノールアミンバイサルファイト等の還元剤が挙げられる。 Examples of the swollen plasticized aqueous solution 2 include an aqueous solution in which an additive is dissolved in water. In addition, the swelling plasticization aqueous solution 2 may be what has been used conventionally. Examples of the additive include a surfactant, a hydrogen bond cleaving agent, a crosslink bond cleaving agent, and a hydrophobic bond relaxing agent. Examples of the surfactant include an alkylphenyl ether type activator. In addition, as the crosslinker cleaving agent, disulfide bond cleaving agents, for example, sulfur-containing amino acids such as thiol compounds (thioglycolic acid, mercaptopropionic acid, thioglycerin, L-cystine, etc.), alkyl mercaptans, mercapto alcohols, mercaptoamines, etc. And reducing agents such as sodium sulfite, sodium bisulfite, monoethanolamine sulfite, and monoethanolamine bisulfite.
 なお、添加剤は、上述のものに限定されるものではない。また、添加剤は、混合して用いてもよい。添加剤の水への添加量は、使用する添加剤の種類、使用目的により変動するため、一概には言えないが、繊維内部への浸透効果を高める目的で界面活性剤等を使用する場合、10g/L以下が適当である。また、架橋結合切断剤が対称型の還元剤、チオグリコール酸、メルカプトエタノール等である場合、その添加量は、0.05重量%以上10重量%以下の範囲内であることが好ましく、1重量%以上8重量%以下の範囲内であることがより好ましい。 Note that the additives are not limited to those described above. Moreover, you may mix and use an additive. The amount of additive added to water varies depending on the type of additive used and the purpose of use, so it cannot be said unconditionally, but when using a surfactant or the like for the purpose of enhancing the penetration effect into the fiber, 10 g / L or less is appropriate. In addition, when the cross-linking cleavage agent is a symmetric reducing agent, thioglycolic acid, mercaptoethanol or the like, the addition amount is preferably in the range of 0.05% by weight to 10% by weight. More preferably, it is in the range of not less than 8% and not more than 8 wt%.
 また、膨潤可塑化処理時の温度は、特に限定されないが、30度C以上80度C以下の範囲内であることが好ましい。また、膨潤可塑化水溶液2のpHは7以上10以下の範囲内(弱アルカリ性から中アルカリ性の範囲内)であることが好ましい。膨潤可塑化処理時の処理時間は、膨潤可塑化水溶液2が獣毛繊維の内部に十分均一に浸透して獣毛繊維が十分に膨潤した状態になる時間であればよい。上述の製造条件は製造コスト、得られる延伸縮径獣毛繊維の品質の安定性などを考慮して設定すればよい。 Further, the temperature during the swelling plasticization treatment is not particularly limited, but is preferably in the range of 30 ° C. or more and 80 ° C. or less. The pH of the swollen plasticized aqueous solution 2 is preferably in the range of 7 or more and 10 or less (in the range of weak alkalinity to medium alkalinity). The treatment time during the swelling plasticization treatment may be a time when the swelling plasticization aqueous solution 2 penetrates into the interior of the animal hair fibers sufficiently uniformly and the animal hair fibers are sufficiently swollen. The manufacturing conditions described above may be set in consideration of the manufacturing cost, the stability of the quality of the obtained stretch-stretched animal hair fiber, and the like.
 (2)延伸工程
 延伸工程では、図1および図2に示されるように、膨潤可塑化処理装置30において膨潤可塑化処理された獣毛繊維束(以下「膨潤可塑化獣毛繊維束」という)5が延伸機構40において延伸処理される。
(2) Stretching step In the stretching step, as shown in FIG. 1 and FIG. 2, an animal hair fiber bundle (hereinafter referred to as a “swelled plasticized animal hair fiber bundle”) that has undergone swelling plasticization in the swelling plasticizing apparatus 30. 5 is stretched in the stretching mechanism 40.
 延伸機構40は、図1および図2に示されるように、主に、バックローラ対10およびフロントローラ対20から構成されており、膨潤可塑化処理装置30の繊維流れ方向下流側に配置されている。バックローラ対10は、図1および図2に示されるように、主に、トップローラ(以下「バックトップローラ」という)11およびボトムローラ(以下「バックボトムローラ」という)12から構成されており、フロントローラ対20の繊維流れ方向上流側に配置されている。なお、このバックトップローラ11およびバックボトムローラ12は、互いに接触するように配置されており、その接触箇所にニップ部10Nが形成されている。また、フロントローラ対20は、図1および図2に示されるように、主に、トップローラ(以下「フロントトップローラ」という)21およびボトムローラ(以下「フロントボトムローラ」という)22から構成されており、バックローラ対10の繊維流れ方向下流側に配置されている。なお、このフロントトップローラ21およびフロントボトムローラ22は、互いに接触するように配置されており、その接触箇所にニップ部20Nが形成されている。 As shown in FIGS. 1 and 2, the drawing mechanism 40 mainly includes a back roller pair 10 and a front roller pair 20, and is disposed on the downstream side in the fiber flow direction of the swelling plasticizing apparatus 30. Yes. As shown in FIGS. 1 and 2, the back roller pair 10 mainly includes a top roller (hereinafter referred to as “back top roller”) 11 and a bottom roller (hereinafter referred to as “back bottom roller”) 12. The front roller pair 20 is disposed upstream of the fiber flow direction. The back top roller 11 and the back bottom roller 12 are disposed so as to contact each other, and a nip portion 10N is formed at the contact portion. The front roller pair 20 is mainly composed of a top roller (hereinafter referred to as “front top roller”) 21 and a bottom roller (hereinafter referred to as “front bottom roller”) 22 as shown in FIGS. It is arranged downstream of the back roller pair 10 in the fiber flow direction. The front top roller 21 and the front bottom roller 22 are disposed so as to contact each other, and a nip portion 20N is formed at the contact portion.
 なお、バックボトムローラ12およびフロントボトムローラ22は、金属性であることが好ましい。また、これらのボトムローラ12,22の表面構造はフリューデッド構造であることが好ましい。また、バックトップローラ11およびフロントトップローラ21は、ゴム被覆ローラであることが好ましい。各ニップ部10N,20Nでの膨潤可塑化獣毛繊維束5の把持力を均一にすることができるからである。また、フリューデッド構造およびゴム硬度は、「ニップ部10N,20Nでの膨潤可塑化獣毛繊維束5の把持力」および「ニップ部10N,20Nで膨潤可塑化獣毛繊維束5を把持したときに膨潤可塑化獣毛繊維束5に与えるダメージ」等を実験結果等から検討した上で最適化すればよい。なお、実際の実験結果から、バックトップローラ11、バックボトムローラ12、フロントトップローラ21およびフロントボトムローラ22の直径は15mm以上45mm以下の範囲内であることが好ましい。また、バックボトムローラ12およびフロントトップローラ21の直径は、同じであってもよいし、異なっていてもよい。 In addition, it is preferable that the back bottom roller 12 and the front bottom roller 22 are metallic. Moreover, it is preferable that the surface structure of these bottom rollers 12 and 22 is a fluid structure. The back top roller 11 and the front top roller 21 are preferably rubber-covered rollers. This is because the gripping force of the swollen plasticized animal hair fiber bundle 5 at each of the nip portions 10N and 20N can be made uniform. In addition, the fluidized structure and the rubber hardness are “the gripping force of the swollen plasticized animal hair fiber bundle 5 at the nip portions 10N and 20N” and “the swollen plasticized animal hair fiber bundle 5 at the nip portions 10N and 20N” The damage to the swollen plasticized animal hair fiber bundle 5 may be optimized after examining the experimental results. From the actual experimental results, the diameters of the back top roller 11, the back bottom roller 12, the front top roller 21, and the front bottom roller 22 are preferably in the range of 15 mm to 45 mm. Further, the diameters of the back bottom roller 12 and the front top roller 21 may be the same or different.
 また、本実施の形態に係る延伸機構40では、ローラ11,12,21,22の回転軸に沿って見た場合、つまり、側面視した場合、バックトップローラ11の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線と、バックボトムローラ12の回転軸とフロントトップローラ21の回転軸とを結ぶ仮想直線とが交差し、且つ、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想直線と、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線とが平行になるように、バックローラ対10およびフロントローラ対20が配設されている。また、バックローラ対10およびフロントローラ対20は、図1および図2に示されるように、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想直線、および、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線が繊維流れ方向上流側から繊維流れ方向下流側に向かって所定角度Dだけ傾斜するように配設されている。この配設により、バックボトムローラ12の回転軸とフロントトップローラ21の回転軸とを結ぶ仮想直線の距離は、バックトップローラ11の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線の距離よりも短くなっている(図1および図2参照)。すなわち、バックボトムローラ12とフロントトップローラ21との間の距離が、バックトップローラ11とフロントボトムローラ22との間の距離よりも短くなっている。 Further, in the stretching mechanism 40 according to the present embodiment, when viewed along the rotation axes of the rollers 11, 12, 21, and 22, that is, when viewed from the side, the rotation shaft of the back top roller 11 and the front bottom roller 22. And the virtual straight line connecting the rotation axis of the back bottom roller 12 and the rotation axis of the front top roller 21 intersect, and the rotation axis of the back top roller 11 and the back bottom roller 12 The back roller pair 10 and the front roller pair 20 are arranged so that a virtual straight line connecting the rotation shaft and a virtual straight line connecting the rotation shaft of the front top roller 21 and the rotation shaft of the front bottom roller 22 are parallel to each other. ing. Further, as shown in FIGS. 1 and 2, the back roller pair 10 and the front roller pair 20 include a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12, and the front top roller. An imaginary straight line connecting the rotation axis of 21 and the rotation axis of the front bottom roller 22 is disposed so as to be inclined by a predetermined angle D from the upstream side in the fiber flow direction toward the downstream side in the fiber flow direction. With this arrangement, the distance of the imaginary straight line connecting the rotation axis of the back bottom roller 12 and the rotation axis of the front top roller 21 is the imaginary straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the front bottom roller 22. It is shorter than the distance (see FIGS. 1 and 2). That is, the distance between the back bottom roller 12 and the front top roller 21 is shorter than the distance between the back top roller 11 and the front bottom roller 22.
 そして、フロントローラ対20の周速度(フロントローラ対20のトップローラ21の周速度)をバックローラ対10の周速度(バックローラ対10のボトムローラ12の周速度)に対して所定倍率で高めることにより、所望の倍率で膨潤可塑化獣毛繊維束5を延伸処理することができる。なお、本発明の実施の形態では、膨潤可塑化獣毛繊維束5は、1.1倍以上2.0倍以下の範囲内の倍率で延伸される(長さ方向に引き伸ばされる)。獣毛繊維が羊毛である場合、その平均繊維径は13μmから38μmである。このような原毛から13μmから28μmの羊毛繊維を得るためには、1.1倍から2.0倍の倍率で延伸することが好ましく、1.2倍から1.8倍の倍率で延伸することがより好ましい。なお、本実施の形態では、延伸倍率は下式(1)から計算される。 Then, the peripheral speed of the front roller pair 20 (peripheral speed of the top roller 21 of the front roller pair 20) is increased at a predetermined magnification with respect to the peripheral speed of the back roller pair 10 (peripheral speed of the bottom roller 12 of the back roller pair 10). Thus, the swollen plasticized animal hair fiber bundle 5 can be stretched at a desired magnification. In the embodiment of the present invention, the swollen plasticized animal hair fiber bundle 5 is stretched (stretched in the length direction) at a magnification in the range of 1.1 to 2.0 times. When the animal hair fiber is wool, the average fiber diameter is 13 μm to 38 μm. In order to obtain wool fibers of 13 μm to 28 μm from such raw wool, it is preferable to stretch at a magnification of 1.1 to 2.0 times, and to stretch at a magnification of 1.2 to 1.8 times. Is more preferable. In the present embodiment, the draw ratio is calculated from the following formula (1).
  倍率=S/S            (1)
     S:延伸後の獣毛繊維の平均断面積(mm
     S:延伸前の獣毛繊維の平均断面積(mm
Magnification = S 0 / S 1 (1)
S 1 : Average cross-sectional area of animal hair fibers after stretching (mm 2 )
S 0 : Average cross-sectional area of animal hair fibers before stretching (mm 2 )
 以下、延伸機構40における膨潤可塑化獣毛繊維束5の延伸処理について詳述する。
 膨潤可塑化獣毛繊維束5は、膨潤可塑化処理装置30からガイドローラ6を介して延伸機構40に導かれる。そして、延伸機構40では、図1および図2に示されるように、バックトップローラ11、バックボトムローラ12、フロントトップローラ21およびフロントボトムローラ22の順に膨潤可塑化獣毛繊維束5が架け渡される。なお、このとき、延伸機構40を側面視すると、バックトップローラ11からバックボトムローラ12までの膨潤可塑化獣毛繊維束5の形状が逆S字となり、ニップ部10Nからニップ部20Nまでの膨潤可塑化獣毛繊維束5の形状がS字となり、フロントトップローラ21からフロントボトムローラ22までの膨潤可塑化獣毛繊維束5の形状が逆S字となる。また、このとき、膨潤可塑化獣毛繊維束5は、図1および図2に示されるように、バックローラ対10のニップ部10Nおよびフロントローラ対20のニップ部20Nの2箇所で把持されることになる。つまり、この獣毛繊維延伸固定装置100では、膨潤可塑化獣毛繊維束5の延伸は実質的にバックボトムローラ12およびフロントトップローラ21で行われる(図1および図2参照)。なお、以下、ニップ部10Nからニップ部20Nまでの領域を「延伸スパン」と称し、「膨潤可塑化獣毛繊維束5がバックボトムローラ12から離れる点」から「膨潤可塑化獣毛繊維束5がフロントトップローラ21に最初に接触する点」までの領域10を「延伸ゾーン」と称する。
Hereinafter, the stretching process of the swollen plasticized animal hair fiber bundle 5 in the stretching mechanism 40 will be described in detail.
The swollen plasticized animal hair fiber bundle 5 is guided from the swollen plasticizing apparatus 30 to the drawing mechanism 40 via the guide roller 6. In the stretching mechanism 40, as shown in FIGS. 1 and 2, the swollen plasticized animal hair fiber bundle 5 is stretched in the order of the back top roller 11, the back bottom roller 12, the front top roller 21, and the front bottom roller 22. It is. At this time, when the drawing mechanism 40 is viewed from the side, the shape of the swollen plasticized animal hair fiber bundle 5 from the back top roller 11 to the back bottom roller 12 becomes an inverted S-shape, and the swelling from the nip portion 10N to the nip portion 20N. The shape of the plasticized animal hair fiber bundle 5 is S-shaped, and the shape of the swollen plasticized animal hair fiber bundle 5 from the front top roller 21 to the front bottom roller 22 is inverted S-shaped. At this time, the swollen plasticized animal hair fiber bundle 5 is gripped at two locations, that is, the nip portion 10N of the back roller pair 10 and the nip portion 20N of the front roller pair 20, as shown in FIGS. It will be. That is, in this animal hair fiber drawing and fixing device 100, the swelling plasticized animal hair fiber bundle 5 is substantially drawn by the back bottom roller 12 and the front top roller 21 (see FIGS. 1 and 2). Hereinafter, the region from the nip portion 10N to the nip portion 20N is referred to as “stretched span”, and “swelled plasticized animal hair fiber bundle 5 from the point that the swollen plasticized animal hair fiber bundle 5 is separated from the back bottom roller 12”. The region 10 up to “the first point of contact with the front top roller 21” is referred to as “stretching zone”.
 なお、上述したように、バックローラ対10およびフロントローラ対20は、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想直線、および、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線が繊維流れ方向上流側から繊維流れ方向下流側に向かって所定角度Dだけ傾斜するように配設されているが、これは、獣毛繊維束を形成している単繊維の平均長さよりも延伸スパンが長く、バックボトムローラ12およびフロントトップローラ21の外周面に対してできるだけ長く膨潤可塑化獣毛繊維束5を接触させるためである。つまり、この延伸機構40では、延伸ゾーンにおける膨潤可塑化獣毛繊維束5に対する引張張力をバックボトムローラ12およびフロントトップローラ21の膨潤可塑化獣毛繊維束5との接触面で受け止めることができるようにすることが重要である。 As described above, the back roller pair 10 and the front roller pair 20 include a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12, and the rotation axis of the front top roller 21 and the front roller. An imaginary straight line connecting the rotation axis of the bottom roller 22 is arranged so as to be inclined by a predetermined angle D from the upstream side in the fiber flow direction toward the downstream side in the fiber flow direction. This is because the stretched span is longer than the average length of the single fibers, and the swollen plasticized animal hair fiber bundle 5 is brought into contact with the outer peripheral surfaces of the back bottom roller 12 and the front top roller 21 as long as possible. That is, in this drawing mechanism 40, the tensile tension on the swollen plasticized animal hair fiber bundle 5 in the drawing zone can be received on the contact surface of the back bottom roller 12 and the front top roller 21 with the swollen plasticized animal hair fiber bundle 5. It is important to do so.
 なお、本実施の形態において、延伸スパンの長さは、60mm以上300mm以下の範囲内であることが好ましく、80mm以上200mm以上の範囲内であることがより好ましい。延伸スパンの長さをこの範囲内とすると、短繊維の脱落や、延伸ムラを有効に抑制することができるからである。 In the present embodiment, the length of the stretched span is preferably in the range of 60 mm or more and 300 mm or less, and more preferably in the range of 80 mm or more and 200 mm or more. This is because, when the length of the stretched span is within this range, it is possible to effectively prevent the short fibers from dropping and uneven stretching.
 また、延伸スパンにおいて膨潤可塑化獣毛繊維束5のスリップや繊維切れ等が起こらないようにするために、各ニップ部10N,20Nに0.1kg/cmから3.0kg/cmの圧力をかけることが好ましい。 Further, in order to prevent slipping or fiber breakage of the swollen plasticized animal hair fiber bundle 5 in the stretched span, a pressure of 0.1 kg / cm 2 to 3.0 kg / cm 2 is applied to each nip portion 10N, 20N. Is preferred.
 延伸ゾーン19の長さは、特に限定されるものではなく、作業効率や品質の安定を考慮して決定されるが、一般的に、5mm以上50mm以下の範囲内であることが好ましく、5mm以上30mm以下の範囲内であることがより好ましく、10mm以上30mm以下の範囲内であることがさらに好ましい。また、この延伸ゾーン19は、延伸機構40において1つのみ設けられることが好ましい。安定した品質の延伸復元獣毛繊維および延伸固定化獣毛繊維を製造することができるからである。さらに、この延伸ゾーン19では、80から90%の延伸がなされている。これは、図3の写真から明らかである。図3において、符号91で示される箇所はバックローラ対10のニップ部10Nに対応する箇所であり、符号94で示される箇所はフロントローラ対20のニップ部20Nに対応する箇所である。また、符号92で示される箇所は延伸ゾーン19の始点(バックボトムローラ12側の点)に対応する箇所であり、符号93で示される箇所は延伸ゾーン19の終点(フロントトップローラ21側の点)に対応する箇所である。 The length of the stretching zone 19 is not particularly limited, and is determined in consideration of work efficiency and quality stability, but is generally preferably in the range of 5 mm to 50 mm, preferably 5 mm or more. It is more preferably within a range of 30 mm or less, and further preferably within a range of 10 mm or more and 30 mm or less. Further, it is preferable that only one stretching zone 19 is provided in the stretching mechanism 40. This is because it is possible to produce stretch-restored animal hair fibers and stretch-immobilized animal hair fibers of stable quality. Further, in this stretching zone 19, stretching of 80 to 90% is performed. This is apparent from the photograph of FIG. In FIG. 3, a location indicated by reference numeral 91 is a location corresponding to the nip portion 10 </ b> N of the back roller pair 10, and a location indicated by reference numeral 94 is a location corresponding to the nip portion 20 </ b> N of the front roller pair 20. Further, a location indicated by reference numeral 92 is a location corresponding to the starting point of the stretching zone 19 (point on the back bottom roller 12 side), and a location indicated by reference numeral 93 is the end point of the stretching zone 19 (point on the front top roller 21 side). ).
 (3)水洗工程
 上述の通り、獣毛繊維延伸固定装置100において、延伸復元獣毛繊維が製造される場合、延伸工程後に水洗工程が控えている。すなわち、水洗工程では、延伸後の膨潤可塑化獣毛繊維束5が水洗される。具体的には、この水洗工程では、延伸後の膨潤可塑化獣毛繊維束(以下「延伸膨潤可塑化獣毛繊維束」という)14を、水洗機構を有する洗浄ローラ対24,25に導き、洗浄ローラ対24,25により水洗する。なお、この水洗工程では、延伸膨潤可塑化獣毛繊維束14に対して1.01倍から1.03倍程度の張力がかけられている。
(3) Water washing process As above-mentioned, in the animal hair fiber extending | stretching fixing device 100, when an extending | stretching restoration animal hair fiber is manufactured, the water washing process has refrained after the extending process. That is, in the water washing step, the swollen plasticized animal hair fiber bundle 5 after drawing is washed with water. Specifically, in this washing step, the swollen plasticized animal hair fiber bundle (hereinafter referred to as “stretched swollen plasticized animal hair fiber bundle”) 14 after drawing is guided to a pair of washing rollers 24 and 25 having a washing mechanism, Wash with water by the pair of cleaning rollers 24 and 25. In this washing step, a tension of about 1.01 to 1.03 times is applied to the stretched and swollen plasticized animal hair fiber bundle 14.
 (4)乾燥工程
 上述の通り、獣毛繊維延伸固定装置100において、延伸復元獣毛繊維が製造される場合、水洗工程後に乾燥工程が控えている。すなわち、乾燥工程では、水洗後の延伸膨潤可塑化獣毛繊維束14が乾燥させられる。具体的には、この乾燥工程では、水洗後の延伸膨潤可塑化獣毛繊維束14を、50度C以下の温度に設定された加熱ローラ15に接触させて一次乾燥させた後、さらにその延伸膨潤可塑化獣毛繊維束14を繊維流れ方向下流側の乾燥装置80に送り、その乾燥装置80で二次乾燥させる。なお、この乾燥工程でも、延伸膨潤可塑化獣毛繊維束14に対して1.01倍から1.03倍程度の張力がかけられている。
(4) Drying step As described above, in the animal hair fiber stretching and fixing device 100, when stretched and restored animal hair fibers are produced, the drying step is refrained after the water washing step. That is, in the drying step, the stretched and swollen plasticized animal hair fiber bundle 14 after washing with water is dried. Specifically, in this drying step, the stretched and swollen plasticized animal hair fiber bundle 14 after washing with water is brought into contact with a heating roller 15 set at a temperature of 50 ° C. or less to be primarily dried, and then further stretched. The swollen plasticized animal hair fiber bundle 14 is sent to the drying device 80 on the downstream side in the fiber flow direction, and is secondarily dried by the drying device 80. Even in this drying step, a tension of about 1.01 to 1.03 times is applied to the stretched and swollen plasticized animal hair fiber bundle 14.
 (5)固定化工程
 上述の通り、獣毛繊維延伸固定装置100において、延伸固定化獣毛繊維が製造される場合、延伸工程後に固定化工程が控えている。すなわち、固定化工程では、延伸膨潤可塑化獣毛繊維束14中の延伸膨潤可塑化獣毛繊維の形状が固定化される。具体的には、この固定化工程では、延伸膨潤可塑化獣毛繊維束14を、フロントボトムローラ22から洗浄ローラ対24,25に導いた後(なお、この固定化工程では、延伸膨潤可塑化獣毛繊維束14は水洗されずに洗浄ローラ対24,25を通過するのみである)、平滑な外周面を有する加熱ローラ15に直接接触させて延伸膨潤可塑化獣毛繊維の形状を固定化する。なお、本実施の形態において、図1に示されるように、加熱ローラ15に対して複数の加圧ローラ16が圧接されている。この加圧ローラ16は、延伸膨潤可塑化獣毛繊維束14を加熱ローラ15に圧接させる役目を担っている。このため、延伸固定化獣毛繊維の長手方向の少なくとも一部分が、断面形状が楕円状に変形する。この変形により、延伸固定化獣毛繊維のギラツキが抑えられ、その結果、延伸固定化獣毛繊維にまろやかな光沢が付与される。
(5) Immobilization process As described above, in the animal hair fiber stretching and fixing device 100, when stretched and immobilized animal hair fibers are produced, the immobilization process is reserved after the stretching process. That is, in the fixing step, the shape of the stretched and swollen plasticized animal hair fiber in the stretched and swollen plasticized animal hair fiber bundle 14 is fixed. Specifically, in this fixing step, the stretched and swollen plasticized animal hair fiber bundle 14 is guided from the front bottom roller 22 to the pair of cleaning rollers 24 and 25 (in this fixing step, the stretched and swollen plasticized material is used. The animal hair fiber bundle 14 is not washed with water but only passes through the pair of washing rollers 24 and 25), and is directly brought into contact with the heating roller 15 having a smooth outer peripheral surface to fix the shape of the stretch-swelled plasticized animal hair fiber. To do. In the present embodiment, as shown in FIG. 1, a plurality of pressure rollers 16 are pressed against the heating roller 15. The pressure roller 16 serves to press the stretched and swollen plasticized animal hair fiber bundle 14 against the heating roller 15. For this reason, at least a part of the longitudinal direction of the stretch-immobilized animal hair fiber is deformed into an elliptical cross-sectional shape. Due to this deformation, glare of the stretch-immobilized animal hair fibers is suppressed, and as a result, a mellow gloss is imparted to the stretch-immobilized animal hair fibers.
 なお、図4、図5および図6には、延伸固定化羊毛繊維の顕微鏡写真を示す。図4は、加熱ローラ15に接触していない側の延伸固定化羊毛繊維の顕微鏡写真である。図4の顕微鏡写真から、羊毛繊維がスケールごと等間隔に延伸されていることが見て取れる。なお、加熱ローラ15に接触していない側の延伸固定化羊毛繊維の断面は、原毛同様、円形状を呈している。次に、図5は、加熱ローラ15に接触した側の延伸固定化羊毛繊維の電子顕微鏡写真である。図中、延伸固定化羊毛繊維の一部が、円形から半円状の形状に変形している(図5中の符号27参照)。なお、この変形部分が延伸固定化羊毛繊維束中で光を乱反射させるため、延伸固定化羊毛繊維束にまろやかな色調が生じるものと考えられる。また、図6は、延伸固定化羊毛繊維の断面の顕微鏡写真である。本図では、延伸固定化羊毛繊維の一部の断面が円形状から楕円状に変形していることが見て取れる。 In addition, in FIG.4, FIG.5 and FIG.6, the microscope picture of an extending | stretching fixed wool fiber is shown. FIG. 4 is a photomicrograph of stretch-fixed wool fibers on the side not in contact with the heating roller 15. It can be seen from the micrograph of FIG. 4 that the wool fibers are stretched at equal intervals along the scale. In addition, the cross section of the stretch-fixed wool fiber on the side not in contact with the heating roller 15 has a circular shape like the raw wool. Next, FIG. 5 is an electron micrograph of the stretch-fixed wool fiber on the side in contact with the heating roller 15. In the figure, a part of the stretch-immobilized wool fiber is deformed from a circular shape to a semicircular shape (see reference numeral 27 in FIG. 5). In addition, since this deformation | transformation part reflects light irregularly in the extending | stretching fixed wool fiber bundle, it is thought that a mellow color tone arises in an extending | stretching fixed wool fiber bundle. FIG. 6 is a photomicrograph of the cross section of the stretch-immobilized wool fiber. In this figure, it can be seen that a partial cross section of the stretch-immobilized wool fiber is deformed from a circular shape to an elliptical shape.
 また、この固定化工程では、延伸膨潤可塑化獣毛繊維束14(フロントボトムローラ22から分離ローラ対17までの部分)に対して1.01倍から1.03倍程度の張力がかけられている。 In this fixing step, a tension of about 1.01 to 1.03 times is applied to the stretched and swollen plasticized animal hair fiber bundle 14 (the portion from the front bottom roller 22 to the separation roller pair 17). Yes.
 なお、加熱ローラ15の温度は、60度C以上150度C以下の範囲内の温度に設定されることが好ましく、70度C以上120度C以下の範囲内の温度に設定されることがより好ましい。加熱ローラ15の温度を上述の範囲内とすると、延伸膨潤可塑化獣毛繊維の固定化を安定して均一に行うことができるからである。また、加熱ローラ15の熱源としては、例えば、電熱ヒーター、高周波加熱源、循環流体(温熱液や熱風など)が用いられることが好ましい。また、加熱ローラ15の外周面には、フッ素樹脂やシリコーン樹脂などがコーティングされていることが好ましい。延伸膨潤可塑化獣毛繊維束14に対する離型性を向上させることができるからである。 The temperature of the heating roller 15 is preferably set to a temperature within a range of 60 ° C. to 150 ° C., and more preferably set to a temperature within a range of 70 ° C. to 120 ° C. preferable. This is because when the temperature of the heating roller 15 falls within the above range, the stretched and swollen plasticized animal hair fibers can be stably and uniformly fixed. Further, as the heat source of the heating roller 15, for example, an electric heater, a high-frequency heating source, or a circulating fluid (such as hot liquid or hot air) is preferably used. Moreover, it is preferable that the outer peripheral surface of the heating roller 15 is coated with a fluorine resin, a silicone resin, or the like. This is because the releasability of the stretched and swollen plasticized animal hair fiber bundle 14 can be improved.
 また、加圧ローラ16の直径や数は、特に限定させるものではない。具体的には、直径30mmから50mmの範囲内の加圧ローラを加熱ローラ15の周囲に50mmから100mmの範囲内の間隔で設置することが好ましい。また、加圧ローラ16は、その両端軸部を加熱ローラ15の両端軸に向かって押し付けることが好ましい。また、加熱ローラ15に対する加圧ローラ16の加圧力は、エヤーシリンダーやスプリング等によって調整されることが好ましい。また、加圧ローラ16は、加熱ローラ15の回転に伴って回転する従動ローラであることが好ましい。また、加圧ローラ16は、シリコーンゴム等の弾性体によって被覆されていることが好ましい。かかる場合、弾性体の硬度は、30度から80度の範囲内であることが好ましく、40度から60度の範囲内であることがより好ましい。また、弾性体は、スポンジ状であってもかまわない。さらに、加圧ローラ16が加熱ローラ15に対して圧接された状態において膨潤可塑化剤の蒸発と延伸膨潤可塑化獣毛繊維の固定化がスチーム雰囲気で行われるように、加熱ローラ15に対する加圧ローラ16の圧力、加圧ローラ16の弾性体の硬度、固定化温度、加熱ローラ15および加圧ローラ16回転速度等の条件が設定されることが好ましい。 Further, the diameter and number of the pressure rollers 16 are not particularly limited. Specifically, it is preferable that pressure rollers having a diameter of 30 mm to 50 mm are installed around the heating roller 15 at intervals of 50 mm to 100 mm. Moreover, it is preferable that the pressure roller 16 presses both end shaft portions thereof toward both end shafts of the heating roller 15. Further, the pressure applied by the pressure roller 16 to the heating roller 15 is preferably adjusted by an air cylinder, a spring or the like. The pressure roller 16 is preferably a driven roller that rotates as the heating roller 15 rotates. The pressure roller 16 is preferably covered with an elastic body such as silicone rubber. In such a case, the hardness of the elastic body is preferably in the range of 30 degrees to 80 degrees, and more preferably in the range of 40 degrees to 60 degrees. The elastic body may be a sponge. Further, in a state where the pressure roller 16 is pressed against the heating roller 15, the pressure applied to the heating roller 15 is such that evaporation of the swelling plasticizer and fixation of the stretched and swollen plasticized animal hair fibers are performed in a steam atmosphere. The conditions such as the pressure of the roller 16, the hardness of the elastic body of the pressure roller 16, the fixing temperature, the rotation speed of the heating roller 15 and the pressure roller 16 are preferably set.
 (6)酸化中和・水洗工程
 上述の通り、獣毛繊維延伸固定装置100において、延伸固定化獣毛繊維が製造される場合、固定化工程後に酸化中和・水洗工程が控えている。すなわち、酸化中和・水洗工程では、固定化後の延伸膨潤可塑化獣毛繊維束(以下「延伸固定化獣毛繊維束」という)18が、酸化中和および水洗される。具体的には、この酸化中和・水洗工程では、延伸固定化獣毛繊維束18を、分離ローラ対17を介して加熱ローラ15から分離し、酸化中和処理槽60および水洗処理槽70に順に導いて酸化中和および水洗する。なお、この酸化中和・水洗工程では、延伸固定化獣毛繊維束18に対して1.01~1.03倍程度の張力がかけられている。
(6) Oxidation Neutralization / Washing Process As described above, in the animal hair fiber stretching / fixing device 100, when stretched / immobilized animal hair fibers are produced, the oxidation neutralization / water washing process is refrained after the immobilization process. That is, in the oxidation neutralization / water washing step, the stretched and swollen plasticized animal hair fiber bundle (hereinafter referred to as “stretched and immobilized animal hair fiber bundle”) 18 after fixation is subjected to oxidation neutralization and water washing. Specifically, in this oxidation neutralization / water washing step, the stretch-immobilized animal hair fiber bundle 18 is separated from the heating roller 15 via the separation roller pair 17, and is separated into the oxidation neutralization treatment tank 60 and the water washing treatment tank 70. Guide in order to neutralize and wash with water. In this oxidation neutralization / water washing step, a tension of about 1.01 to 1.03 times is applied to the stretch-immobilized animal hair fiber bundle 18.
 本実施の形態では、上述の通り、延伸膨潤可塑化獣毛繊維の固定化は熱処理によって行われるため、酸化剤の作用により獣毛繊維の架橋結合を再生させる必要はない。しかしながら、膨潤可塑化工程において膨潤可塑化水溶液2として塩基性薬剤が使用された場合、その中和処理としてこの工程を設けることが好ましい。延伸固定化獣毛繊維の黄変や物性低下を防止することができるからである。なお、酸化中和工程では、過酸化水素、ギ酸、酢酸、塩酸、硫酸などの汎用的な酸化剤を使用することができる。 In the present embodiment, as described above, since the stretch-swelled plasticized animal hair fibers are fixed by heat treatment, it is not necessary to regenerate the cross-linking of the animal hair fibers by the action of the oxidizing agent. However, when a basic drug is used as the swelling plasticizing aqueous solution 2 in the swelling plasticization step, it is preferable to provide this step as a neutralization treatment. This is because yellowing and deterioration of physical properties of the stretch-immobilized animal hair fibers can be prevented. In the oxidative neutralization step, general-purpose oxidizing agents such as hydrogen peroxide, formic acid, acetic acid, hydrochloric acid, and sulfuric acid can be used.
 (7)乾燥工程
 上述の通り、獣毛繊維延伸固定装置100において、延伸固定化獣毛繊維が製造される場合、酸化中和・水洗工程後に乾燥工程が控えている。すなわち、乾燥工程では、酸化中和後の延伸固定化獣毛繊維束18が乾燥させられる。具体的には、この乾燥工程では、酸化中和後の延伸固定化獣毛繊維束18を乾燥装置80に導いて乾燥させる。なお、この乾燥工程でも、延伸固定化獣毛繊維束18に対して1.01倍から1.03倍程度の張力がかけられている。
(7) Drying step As described above, in the animal hair fiber stretching and fixing device 100, when stretched and immobilized animal hair fibers are produced, the drying step is refrained after the oxidation neutralization / water washing step. That is, in the drying step, the stretch-immobilized animal hair fiber bundle 18 after oxidative neutralization is dried. Specifically, in this drying step, the stretch-immobilized animal hair fiber bundle 18 after the oxidation neutralization is guided to the drying device 80 and dried. Even in this drying step, a tension of about 1.01 to 1.03 times is applied to the stretch-immobilized animal hair fiber bundle 18.
 <獣毛繊維延伸固定装置および獣毛繊維延伸固定方法の特徴>
 (1)
 本実施の形態に係る獣毛繊維延伸固定方法では、延伸や固定化により一部の単繊維が半円状や楕円状に変形するが、従来技術のように繊維表面に不規則な凹凸形状が生じることがない。このため、この獣毛繊維延伸固定方法を利用すれば、マイルドな光沢をおびた延伸復元獣繊維または延伸固定化獣毛繊維を製造することができる。
<Features of animal hair fiber drawing and fixing apparatus and animal hair fiber drawing and fixing method>
(1)
In the animal hair fiber drawing and fixing method according to the present embodiment, some single fibers are deformed into a semicircular shape or an elliptical shape by drawing or fixing, but irregular irregular shapes are formed on the fiber surface as in the prior art. It does not occur. For this reason, if this animal hair fiber extending | stretching fixing method is utilized, the extending | stretching decompression | restoration animal fiber or extending | stretching fixed animal hair fiber which gave mild luster can be manufactured.
 (2)
 本実施の形態に係る獣毛繊維延伸固定方法では、バックボトムローラ12およびフロントトップローラ21の外周面に膨潤可塑化獣毛繊維束5がS字状に掛け渡され、その結果、バックボトムローラ12およびフロントトップローラ21の外周面に対して膨潤可塑化獣毛繊維束5が長く密着する。このため、本実施の形態に係る延伸機構40では、ニップ部10N,20Nにかける圧力が低くても膨潤可塑化獣毛繊維束5を十分に把持することができる。このため、この獣毛繊維延伸固定方法を利用すれば、膨潤可塑化獣毛繊維束5に過度なストレスやダメージを与えることがなく、スリップや糸抜けあるいは獣毛繊維の切断等を防止することができる。
(2)
In the animal hair fiber drawing and fixing method according to the present embodiment, the swollen plasticized animal hair fiber bundle 5 is looped over the outer peripheral surfaces of the back bottom roller 12 and the front top roller 21, and as a result, the back bottom roller 12 and the swollen plasticized animal hair fiber bundle 5 are in close contact with the outer peripheral surface of the front top roller 21 for a long time. For this reason, in the extending | stretching mechanism 40 which concerns on this Embodiment, even if the pressure applied to nip part 10N and 20N is low, the swelling plasticization animal hair fiber bundle 5 can fully be hold | gripped. For this reason, if this animal hair fiber drawing and fixing method is used, it will not cause excessive stress or damage to the swollen plasticized animal hair fiber bundle 5, and it will prevent slipping, thread dropping or animal hair fiber cutting, etc. Can do.
 (3)
 本実施の形態に係る獣毛繊維延伸固定方法では、固定化処理において、湿潤状態の膨潤可塑化獣毛繊維束5を加熱ローラ15の表面に直接接触させる。このため、膨潤可塑化獣毛繊維束5が加熱ローラ15に接触した初期の段階では、膨潤可塑化獣毛繊維束5の温度上昇に伴って、膨潤可塑化獣毛繊維束5に含有されている膨潤可塑化剤の温度も上昇して膨潤可塑化獣毛繊維束5の周囲にスチームが生じ、膨潤可塑化獣毛繊維束5があたかもスチーム中で加熱されているような環境をつくり出すことができる。このため、この獣毛繊維延伸固定方法を利用すると、固定化処理において、スチームチャンバーなどの複雑な設備を使用することなく、短時間で膨潤可塑化獣毛繊維の固定化を実現することができる。
(3)
In the animal hair fiber drawing and fixing method according to this embodiment, the swollen plasticized animal hair fiber bundle 5 in a wet state is brought into direct contact with the surface of the heating roller 15 in the fixing process. For this reason, at the initial stage when the swollen plasticized animal hair fiber bundle 5 comes into contact with the heating roller 15, it is contained in the swollen plasticized animal hair fiber bundle 5 as the temperature of the swollen plasticized animal hair fiber bundle 5 increases. The temperature of the swollen plasticizer is also increased, and steam is generated around the swollen plasticized animal hair fiber bundle 5 to create an environment in which the swollen plasticized animal hair fiber bundle 5 is heated in the steam. it can. For this reason, when this animal hair fiber drawing and fixing method is used, the immobilization of the swollen plasticized animal hair fibers can be realized in a short time without using complicated equipment such as a steam chamber in the immobilization process. .
 <変形例>
 (A)
 先の実施の形態に係る獣毛繊維延伸固定装置100では、延伸機構40を側面視した場合、バックトップローラ11の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線と、バックボトムローラ12の回転軸とフロントトップローラ21の回転軸とを結ぶ仮想直線とが交差し、且つ、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想直線と、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線とが平行になるように、バックローラ対10およびフロントローラ対20が配設されていたが、バックローラ対10およびフロントローラ対20は、バックトップローラ11の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線と、バックボトムローラ12の回転軸とフロントトップローラ21の回転軸とを結ぶ仮想直線とが交差し、且つ、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想延長直線と、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想延長直線とが交差するように配設されてもよい。
<Modification>
(A)
In the animal fiber drawing and fixing device 100 according to the previous embodiment, when the drawing mechanism 40 is viewed from the side, a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the front bottom roller 22, and the back bottom roller A virtual straight line connecting the 12 rotation axes and the rotation axis of the front top roller 21 intersects, and a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12 and the front top roller 21. The back roller pair 10 and the front roller pair 20 are arranged so that the imaginary straight line connecting the rotation axis of the front bottom roller 22 and the rotation axis of the front bottom roller 22 is parallel, but the back roller pair 10 and the front roller pair 20 are arranged. Is a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the front bottom roller 22, and the back bottom roller 1 The virtual straight line connecting the rotation axis of the front top roller 21 and the rotation axis of the front top roller 21 intersects, and the virtual extension straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12 and the front top roller 21. And a virtual extension straight line connecting the rotation axis of the front bottom roller 22 and the rotation axis of the front bottom roller 22 may be arranged to intersect each other.
 (B)
 先の実施の形態に係る獣毛繊維延伸固定装置100には、洗浄ローラ対24,25、酸化中和処理槽60、水洗処理槽70および乾燥装置80が組み込まれていたが、これらの構成は、獣毛繊維延伸固定装置100とは別に設けられてもよい。例えば、これらの構成は、獣毛繊維延伸固定装置100から独立した染色機等に組み込まれてもよい。
(B)
In the animal hair fiber drawing and fixing device 100 according to the previous embodiment, the cleaning roller pairs 24 and 25, the oxidation neutralization treatment tank 60, the water washing treatment tank 70, and the drying device 80 are incorporated. The animal hair fiber stretching and fixing device 100 may be provided separately. For example, these configurations may be incorporated in a dyeing machine or the like independent from the animal hair fiber drawing and fixing device 100.
 (C)
 先の実施の形態に係る獣毛繊維延伸固定装置100では、延伸機構40を側面視した場合、バックトップローラ11の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線と、バックボトムローラ12の回転軸とフロントトップローラ21の回転軸とを結ぶ仮想直線とが交差し、且つ、バックトップローラ11の回転軸とバックボトムローラ12の回転軸とを結ぶ仮想直線と、フロントトップローラ21の回転軸とフロントボトムローラ22の回転軸とを結ぶ仮想直線とが平行になるように、バックローラ対10およびフロントローラ対20が配設されていたが、図11に示されるように、バックトップローラ111の回転軸とフロントボトムローラ122の回転軸とを結ぶ仮想直線と、バックボトムローラ112の回転軸とフロントトップローラ121の回転軸とを結ぶ仮想直線とが同一仮想直線上に存在するように、バックローラ対110およびフロントローラ対120が配設されてもよい。
(C)
In the animal fiber drawing and fixing device 100 according to the previous embodiment, when the drawing mechanism 40 is viewed from the side, a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the front bottom roller 22, and the back bottom roller A virtual straight line connecting the 12 rotation axes and the rotation axis of the front top roller 21 intersects, and a virtual straight line connecting the rotation axis of the back top roller 11 and the rotation axis of the back bottom roller 12 and the front top roller 21. The back roller pair 10 and the front roller pair 20 are arranged so that the virtual straight line connecting the rotation axis of the front bottom roller 22 and the rotation axis of the front bottom roller 22 is parallel, but as shown in FIG. An imaginary straight line connecting the rotation axis of the top roller 111 and the rotation axis of the front bottom roller 122, and the rotation axis of the back bottom roller 112 and the freon. As the virtual straight line are in the same virtual straight line connecting the rotation axis of the top roller 121, roller pair 110 and the front roller pair 120 may be disposed.
 以下、実施例を用いて本発明をさらに詳細に説明する。なお、本発明がこれらの実施例に限定されることはない。 Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples.
 平均繊維直径22.50μm、平均長さ95mmの羊毛繊維を含む無撚りの羊毛繊維束(トップスライバー23g/m)を用意した。次いで、チオグリコール酸(淀化学株式会社)に水酸化ナトリウム水溶液を添加してpH9.00の3.9重量%チオグリコール酸水溶液を調製した。そして、本実施例において、このチオグリコール酸水溶液を膨潤可塑化剤とした。 An untwisted wool fiber bundle (top sliver 23 g / m) containing wool fibers having an average fiber diameter of 22.50 μm and an average length of 95 mm was prepared. Next, an aqueous sodium hydroxide solution was added to thioglycolic acid (Sakai Chemical Co., Ltd.) to prepare a 3.9 wt% thioglycolic acid aqueous solution having a pH of 9.00. In this example, this aqueous thioglycolic acid solution was used as a swelling plasticizer.
 羊毛繊維束を図1に示されるように上述の獣毛繊維延伸固定装置100に架け渡した。次に、膨潤可塑化槽4に膨潤可塑化剤を投入した後、膨潤可塑化剤を40度Cまで温めた。その後、羊毛繊維束を膨潤可塑化剤に40分間浸漬させて、羊毛繊維束の膨潤可塑化処理を行った。次に、膨潤可塑化した羊毛繊維束(以下「膨潤可塑化羊毛繊維束」という)を、膨潤可塑化剤を含んだままの状態で膨潤可塑化槽4から引出し、その膨潤可塑化羊毛繊維束を延伸機構40により8.6cm/分の速度で延伸処理した。なお、バックローラ対10およびフロントローラ対20のトップローラ11,21およびボトムローラ12,22の外径は25mmであった。また、硬度50度、厚み7mmのウレタンゴムで芯金を被覆したローラをトップローラ11,21として用い、ステンレス製の芯金をフリュデット加工したものをボトムローラ12,22として用いた。さらに、バックローラ対10の周速度を8.6cm/分に設定すると共にフロントローラ対20の周速度を15.7cm/分に設定した。つまり、延伸倍率は1.82倍(=15.7/8.6)となる。 The wool fiber bundle was stretched over the above-described animal fiber drawing and fixing device 100 as shown in FIG. Next, after the swelling plasticizer was put into the swelling plasticization tank 4, the swelling plasticizer was warmed to 40 degrees C. Thereafter, the wool fiber bundle was immersed in a swelling plasticizer for 40 minutes to perform a swelling plasticization treatment of the wool fiber bundle. Next, the swollen plasticized wool fiber bundle (hereinafter referred to as “swelled plasticized wool fiber bundle”) is drawn out from the swollen plasticizing tank 4 while containing the swollen plasticizer, and the swollen plasticized wool fiber bundle is drawn. Was stretched by the stretching mechanism 40 at a speed of 8.6 cm / min. The outer diameters of the top rollers 11 and 21 and the bottom rollers 12 and 22 of the back roller pair 10 and the front roller pair 20 were 25 mm. Further, a roller covered with a core metal with urethane rubber having a hardness of 50 degrees and a thickness of 7 mm was used as the top rollers 11 and 21, and a stainless steel core metal was used as the bottom rollers 12 and 22. Further, the peripheral speed of the back roller pair 10 was set to 8.6 cm / min, and the peripheral speed of the front roller pair 20 was set to 15.7 cm / min. That is, the draw ratio is 1.82 times (= 15.7 / 8.6).
 また、側面視において膨潤可塑化羊毛繊維束がバックボトムローラ12およびフロントボトムローラ22の外周の3/5程度に接触するように、バックローラ対10およびフロントローラ対20を垂直軸に対して繊維流れ方向上流側に45度傾けて配設した(図2等参照)。さらに、延伸ゾーンの長さを14mmに設定した。そして、このような延伸機構40により膨潤可塑化羊毛繊維束を順次延伸した後、延伸後の膨潤可塑化羊毛繊維束(以下「延伸膨潤可塑化羊毛繊維束」という)を、フロントボトムローラ22から洗浄ローラ対24,25を介して加熱ローラ15に導くと共に加熱ローラ15に直接接触させて延伸膨潤可塑化羊毛繊維束中の延伸膨潤可塑化羊毛繊維の固定化処理を行った。なお、固定化処理は、加熱ローラ15の周速度がフロントローラ対20の周速度の1.02倍とされた状態、すなわち、延伸膨潤可塑化羊毛繊維束が緊張させられた状態で行われた。なお、また、加熱ローラ15は、外径が210mmであり、表面温度が80度Cとなるように内蔵の電熱ヒーターにより加熱された。また、加熱ローラ15に対する延伸膨潤可塑化羊毛繊維束の接触時間は110秒間であった。また、図1に示されるように、加熱ローラ15の外周上部に、7つの加圧ローラ(直径27mmのシリコーンゴム被覆ステンレスローラ)16を配設した。なお、各加圧ローラ16は、エアーシリンダーにより加熱ローラ15に対して1.5kg/cmの圧力で圧接された。また、加熱ローラ15に接触される前の延伸膨潤可塑化羊毛繊維束の湿潤率は81重量%であった。また、このときの、延伸スパンは116mmであった。 Further, the back roller pair 10 and the front roller pair 20 are fibers with respect to the vertical axis so that the swollen plasticized wool fiber bundle comes into contact with about 3/5 of the outer periphery of the back bottom roller 12 and the front bottom roller 22 in a side view. It was inclined 45 degrees upstream in the flow direction (see FIG. 2 and the like). Furthermore, the length of the stretching zone was set to 14 mm. Then, after sequentially stretching the swollen plasticized wool fiber bundle by such a drawing mechanism 40, the swollen plasticized wool fiber bundle after stretching (hereinafter referred to as “stretched swollen plasticized wool fiber bundle”) is transferred from the front bottom roller 22. The drawn and swollen plasticized wool fibers in the drawn and swollen plasticized wool fiber bundle were fixed by being guided to the heating roller 15 through the cleaning roller pairs 24 and 25 and in direct contact with the heated roller 15. The fixing process was performed in a state where the peripheral speed of the heating roller 15 was 1.02 times the peripheral speed of the front roller pair 20, that is, the stretched and swollen plasticized wool fiber bundle was in tension. . The heating roller 15 was heated by a built-in electric heater so that the outer diameter was 210 mm and the surface temperature was 80 degrees C. The contact time of the stretched and swollen plasticized wool fiber bundle with the heating roller 15 was 110 seconds. As shown in FIG. 1, seven pressure rollers (silicone rubber-coated stainless steel rollers having a diameter of 27 mm) 16 were disposed on the outer periphery of the heating roller 15. Each pressure roller 16 was pressed against the heating roller 15 with a pressure of 1.5 kg / cm 2 by an air cylinder. The wet ratio of the stretched and swollen plasticized wool fiber bundle before being brought into contact with the heating roller 15 was 81% by weight. At this time, the stretch span was 116 mm.
 次いで、固定化された延伸膨潤可塑化羊毛繊維束(以下「延伸固定化羊毛繊維束」という)を、40度Cの1重量%の過酸化水素水に30分間浸漬させて酸化させた後、水洗し、さらに0.3重量%の酢酸に30分間浸漬させて中和させた。このようにして得られた延伸固定化羊毛繊維の平均繊維直径は19.39μmであった(JIS L1081A法に準じて測定)。すなわち、延伸固定化後の羊毛繊維束の単繊維は、延伸固定化前の羊毛繊維束の単繊維に対して平均で約14%縮径されていることになる。また、この延伸固定化羊毛繊維束を沸騰水で15分間煮沸処理を行った後、再び延伸固定化羊毛繊維の平均繊維直径を測定した。このときの延伸固定化羊毛繊維の平均繊維直径は19.25μmであった。このため、この延伸固定化羊毛繊維が完全に固定化されていることが確認された。なお、(i)延伸固定化前の羊毛繊維束、(ii)延伸固定化後の羊毛繊維束および(iii)延伸固定化後に煮沸処理された後の羊毛繊維束の繊維径分布を図7に示した。図7より、本延伸固定化により、原毛の繊維径分布がほぼそのまま細番手方向にスライドされていることがわかる。つまり、本延伸固定化において、羊毛繊維束に対し、高精度な延伸が行われたことになる。また、延伸固定化羊毛繊維束は、断面楕円状の繊維を含み、まろやかな光沢のある外観特性を有していた。 Subsequently, the fixed stretch-swelling plasticized wool fiber bundle (hereinafter referred to as “stretch-fixed wool fiber bundle”) is immersed in 1% by weight hydrogen peroxide water at 40 ° C. for 30 minutes to be oxidized, It was washed with water and further neutralized by immersion in 0.3% by weight of acetic acid for 30 minutes. The average fiber diameter of the stretch-immobilized wool fiber thus obtained was 19.39 μm (measured according to JIS L1081A method). That is, the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 14% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing. Further, this stretch-immobilized wool fiber bundle was boiled with boiling water for 15 minutes, and then the average fiber diameter of the stretch-immobilized wool fibers was measured again. The average fiber diameter of the stretch-immobilized wool fiber at this time was 19.25 μm. For this reason, it was confirmed that this stretch-immobilized wool fiber was completely immobilized. FIG. 7 shows the fiber diameter distribution of (i) the wool fiber bundle before stretching and fixing, (ii) the wool fiber bundle after stretching and (iii) the wool fiber bundle after boiling and fixing. Indicated. From FIG. 7, it can be seen that the fiber diameter distribution of the raw hair is slid in the fine count direction almost as it is due to the final stretching and fixing. That is, in the present drawing fixation, high-precision drawing is performed on the wool fiber bundle. Further, the stretch-fixed wool fiber bundle includes fibers having an elliptical cross section, and has a mellow appearance characteristic.
 また、上述の延伸固定化羊毛繊維束を精紡機に供給して70番手双糸の延伸固定化羊毛紡績糸を製造した後、その延伸固定化羊毛紡績糸からカバーファクター0.49の編物を製造した。この編物は、柔らく、マイルドな光沢を持ち、肌触りがよく、しなやかな風合いを有していた。 Also, after supplying the above-mentioned stretch-fixed wool fiber bundle to a spinning machine to produce a 70-stamp double-stretched-fixed wool spun yarn, a knitted fabric having a cover factor of 0.49 is manufactured from the stretch-fixed wool spun yarn. did. This knitted fabric had a soft, mild luster, a good touch and a supple texture.
 次に、上述の延伸固定化羊毛繊維束とテトロンフィラメント(35デニール)を80:20の割合で精紡機に供給し、100番手双糸の延伸固定化羊毛紡績糸を製造した。その後、当該延伸固定化羊毛紡績糸から織物を製造した。当該織物の浸漬寸法変化率(JIS L 1096 C法)、プレス寸法変化率(JIS L 1096 H-2法)、ハイグラルエキスパンション(浸漬C法準拠)を測定したところ、表1に示す寸法変化率が得られた。すなわち、織物として十分な寸法安定性を有していた。
Figure JPOXMLDOC01-appb-T000001
Next, the above-described stretch-fixed wool fiber bundle and tetron filament (35 denier) were supplied to the spinning machine at a ratio of 80:20 to produce a 100-count double-stretch stretch-fixed wool spun yarn. Thereafter, a woven fabric was produced from the stretch-fixed woolen spun yarn. When the immersion dimensional change rate (JIS L 1096 C method), press dimensional change rate (JIS L 1096 H-2 method), and hygall expansion (based on the immersion C method) of the fabric were measured, the dimensional change rates shown in Table 1 were obtained. Obtained. That is, it had sufficient dimensional stability as a woven fabric.
Figure JPOXMLDOC01-appb-T000001
 平均繊維直径18.50μm、平均長さ77mmの無撚りの羊毛繊維束(トップスライバー22g/m)を用い、フロントローラ対20の周速度を17.2cm/分に設定した以外は、実施例1と同様にして延伸固定化羊毛繊維束を製造した。なお、このときの延伸倍率は2.0倍(=17.2/8.6)となる。 Example 1 except that an untwisted wool fiber bundle (top sliver 22 g / m) having an average fiber diameter of 18.50 μm and an average length of 77 mm was used, and the peripheral speed of the front roller pair 20 was set to 17.2 cm / min. In the same manner, a stretch-fixed wool fiber bundle was produced. In addition, the draw ratio at this time is 2.0 times (= 17.2 / 8.6).
 得られた延伸固定化羊毛繊維の平均繊維直径は15.13μmであった。すなわち、延伸固定化後の羊毛繊維束の単繊維は、延伸固定化前の羊毛繊維束の単繊維に対して平均で約18%縮径されていることになる。また、この延伸固定化羊毛繊維束を沸騰水で15分間煮沸処理を行った後、再び延伸固定化羊毛繊維の平均繊維直径を測定した。このときの延伸固定化羊毛繊維の平均繊維直径は15.20μmであった。このため、この延伸固定化羊毛繊維が完全に固定化されていることが確認された。 The average fiber diameter of the obtained stretch-immobilized wool fiber was 15.13 μm. In other words, the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 18% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing. Further, this stretch-immobilized wool fiber bundle was boiled with boiling water for 15 minutes, and then the average fiber diameter of the stretch-immobilized wool fibers was measured again. At this time, the average fiber diameter of the stretch-fixed wool fibers was 15.20 μm. For this reason, it was confirmed that this stretch-immobilized wool fiber was completely immobilized.
 平均繊維直径17.0μm、平均長さ53mmの無撚りのカシミヤ繊維束(トップスライバー17g/m)を用いた以外は、実施例1と同様にして延伸固定化カシミヤ繊維束を製造した。 A stretch-fixed cashmere fiber bundle was produced in the same manner as in Example 1 except that an untwisted cashmere fiber bundle (top sliver 17 g / m) having an average fiber diameter of 17.0 μm and an average length of 53 mm was used.
 得られた延伸固定化カシミヤ繊維の平均繊維直径は14.13μmであった。すなわち、延伸固定化後のカシミヤ繊維束の単繊維は、延伸固定化前のカシミヤ繊維束の単繊維に対して平均で約17%縮径されていることになる。また、この延伸固定化カシミヤ繊維束を沸騰水で15分間煮沸処理を行った後、再び延伸固定化カシミヤ繊維の平均繊維直径を測定した。このときの延伸固定化カシミヤ繊維の平均繊維直径は14.19μmであった。このため、この延伸固定化カシミヤ繊維が完全に固定化されていることが確認された。なお、(i)延伸固定化前のカシミヤ繊維束、(ii)延伸固定化後のカシミヤ繊維束および(iii)延伸固定化後に煮沸処理された後のカシミヤ繊維束の繊維径分布を図8に示した。図8より、本延伸固定化により、原毛の繊維径分布がほぼそのまま細番手方向にスライドされていることがわかる。つまり、本延伸固定化において、カシミヤ繊維束に対し、高精度な延伸が行われたことになる。 The average fiber diameter of the obtained stretch-immobilized cashmere fiber was 14.13 μm. In other words, the single fiber of the cashmere fiber bundle after stretching and fixing is reduced in diameter by about 17% on average with respect to the single fiber of the cashmere fiber bundle before stretching and fixing. Further, this stretch-immobilized cashmere fiber bundle was boiled with boiling water for 15 minutes, and then the average fiber diameter of the stretch-immobilized cashmere fibers was measured again. At this time, the average fiber diameter of the stretch-immobilized cashmere fibers was 14.19 μm. For this reason, it was confirmed that this stretch-immobilized cashmere fiber was completely immobilized. FIG. 8 shows the fiber diameter distribution of (i) a cashmere fiber bundle before stretch fixation, (ii) a cashmere fiber bundle after stretch fixation, and (iii) a cashmere fiber bundle after boiling treatment after stretch fixation. Indicated. From FIG. 8, it can be seen that the fiber diameter distribution of the raw hair is slid in the fine count direction almost as it is due to the final stretching and fixing. That is, in the present drawing and fixing, the cashmere fiber bundle is drawn with high accuracy.
 (i)延伸機構40により膨潤可塑化羊毛繊維束を順次延伸した後、延伸膨潤可塑化羊毛繊維束を、フロントボトムローラ22から洗浄ローラ対24,25を介して表面温度50度Cの加熱ローラ15に導くと共に加熱ローラ15に直接接触させて延伸膨潤可塑化羊毛繊維束を乾燥させたこと、(ii)エアーシリンダーにより各加圧ローラ16を加熱ローラ15に対して1.8kg/cmの圧力で圧接させたこと、また、(iii)延伸膨潤可塑化羊毛繊維束を酸化中和処理槽60および水洗処理槽70を通過させることなく直接、乾燥装置80に導いて延伸膨潤可塑化羊毛繊維束を乾燥装置80で50度以下の温度で風乾燥させて巻き取ったこと以外は、実施例1と同様にして延伸復元羊毛繊維束を製造した。なお、延伸膨潤可塑化羊毛繊維束の洗浄および乾燥は、加熱ローラ15の周速度がフロントローラ対20の周速度の1.02倍とされた状態、すなわち、延伸膨潤可塑化羊毛繊維束が緊張させられた状態で行われた。 (I) After the swollen plasticized wool fiber bundle is sequentially stretched by the stretching mechanism 40, the stretched swollen plasticized wool fiber bundle is heated from the front bottom roller 22 through the cleaning roller pairs 24 and 25 to a heating roller having a surface temperature of 50 degrees C. 15 and directly contacting the heating roller 15 to dry the stretched and swollen plasticized wool fiber bundle, and (ii) the pressure roller 16 is set to 1.8 kg / cm 2 with respect to the heating roller 15 by an air cylinder. (Iii) The stretched and swollen plasticized wool fiber bundle is directly guided to the drying device 80 without passing through the oxidation neutralization treatment tank 60 and the water washing treatment tank 70. A stretched and restored wool fiber bundle was produced in the same manner as in Example 1 except that the bundle was wind-dried at a temperature of 50 ° C. or less with a drying device 80 and wound. The stretched and swollen plasticized wool fiber bundle is washed and dried in a state where the peripheral speed of the heating roller 15 is 1.02 times the peripheral speed of the front roller pair 20, that is, the stretched and swollen plasticized wool fiber bundle is in tension. It was done in a let-down state.
 得られた延伸復元羊毛繊維の平均繊維直径は19.62μmであった。すなわち、延伸固定化後の羊毛繊維束の単繊維は、延伸固定化前の羊毛繊維束の単繊維に対して平均で約13.5%縮径されていることになる。また、この延伸固定化羊毛繊維束を80度Cの温水に15分間浸漬した後、再び延伸復元羊毛繊維の平均繊維直径を測定した。このときの延伸復元羊毛繊維の平均繊維直径は22.58μmであった。つまり、この延伸復元羊毛繊維は、温水浸漬により原毛に復元していた。 The average fiber diameter of the obtained stretched and restored wool fiber was 19.62 μm. That is, the single fiber of the wool fiber bundle after stretching and fixing is reduced in diameter by about 13.5% on average with respect to the single fiber of the wool fiber bundle before stretching and fixing. Further, this stretch-fixed wool fiber bundle was immersed in warm water of 80 ° C. for 15 minutes, and then the average fiber diameter of the stretch-restored wool fiber was measured again. At this time, the average fiber diameter of the stretched restored wool fiber was 22.58 μm. In other words, this stretched and restored wool fiber was restored to raw hair by immersion in warm water.
 実施例4で製造した延伸復元羊毛繊維束を用いて60番手の延伸復元羊毛紡績糸を作製した。次いで、常法により、この延伸復元羊毛紡績糸を芯糸とし、カシミヤのスライバーを鞘糸とした芯鞘構造の36番手単糸の延伸復元複合羊毛紡績糸を製造した。そして、この延伸復元複合羊毛紡績糸を80度Cの温水に15分間浸漬して取り出し乾燥させたところ、芯糸の延伸復元羊毛紡績糸が延伸前の形状に復元して長さが短くなり、その結果、表面が嵩高なカシミヤで覆われる紡績糸が得られた。 A 60th stretch-restored wool spun yarn was produced using the stretch-restored wool fiber bundle produced in Example 4. Subsequently, a stretch-reconstructed composite wool spun yarn of 36th single yarn having a core-sheath structure in which the stretch-restored wool spun yarn was used as a core yarn and a cashmere sliver as a sheath yarn was produced by a conventional method. And when this stretched and restored composite woolen spun yarn is immersed in warm water of 80 ° C. for 15 minutes and taken out and dried, the stretched and restored woolen spun yarn of the core yarn is restored to the shape before stretching and the length is shortened, As a result, a spun yarn having a surface covered with bulky cashmere was obtained.
 実施例4で製造した延伸復元羊毛紡績糸を60番手双糸に紡績し、その双糸を16ゲージの丸編み機を用いて度目3.5で丸編みして編地を作製した。そして、この丸編み編地を、沸騰水で15分間煮沸した後、40度Cの1重量%過酸化水素水で30分間処理してから水洗し、さらに0.3重量%の酢酸水溶液で30分間中和処理した。その結果、この編地は、煮沸前に比べて横(ウェール)方向で48%、縦(コース)方向で50%収縮していた。また、煮沸前の編地のカバーファクター(CF)が0.45であったのに対して煮沸後の編地のカバーファクター(CF)が0.85になっていた。また、編地を分解して延伸復元羊毛繊維の平均繊維直径を測定したところ、その値は22.58μmであった。つまり、延伸復元羊毛繊維は、温水浸漬により原毛に復元していた。なお、煮沸前の編地を図9に示し、煮沸後の編地を図10に示す。 The stretched and restored wool spun yarn produced in Example 4 was spun into a 60th double yarn, and the double yarn was circularly knitted using a 16 gauge circular knitting machine at 3.5 times to prepare a knitted fabric. The circular knitted fabric was boiled in boiling water for 15 minutes, then treated with 1% by weight hydrogen peroxide at 40 ° C. for 30 minutes, washed with water, and further washed with 0.3% by weight aqueous acetic acid solution for 30 minutes. Neutralize for minutes. As a result, the knitted fabric contracted by 48% in the transverse (wale) direction and by 50% in the longitudinal (course) direction compared to before boiling. The cover factor (CF) of the knitted fabric before boiling was 0.45, whereas the cover factor (CF) of the knitted fabric after boiling was 0.85. Further, when the average fiber diameter of the stretched and restored wool fiber was measured by disassembling the knitted fabric, the value was 22.58 μm. That is, the stretched and restored wool fiber was restored to raw hair by immersion in warm water. In addition, the knitted fabric before boiling is shown in FIG. 9, and the knitted fabric after boiling is shown in FIG.
 本発明に係る延伸縮径獣毛繊維は、天然繊維よりも細い繊維径の獣毛繊維であり、インナーウェアーも含む衣料品あるいは高級衣料品などに好適に用いることができる。また、この延伸縮径獣毛繊維は、絨毯、航空機、鉄道などの椅子や内装材、インテリア材料等、幅広い分野に応用することができる。 The stretched and contracted diameter animal hair fiber according to the present invention is an animal hair fiber having a fiber diameter thinner than that of natural fiber, and can be suitably used for clothing such as innerwear or high-class clothing. Moreover, this stretchable diameter animal hair fiber can be applied to a wide range of fields, such as chairs, interior materials, interior materials, etc., such as carpets, aircraft, and railways.
  1   獣毛繊維束
  2   膨潤可塑化水溶液(膨潤可塑化剤)
  5   膨潤可塑化獣毛繊維束
 10   バックローラ対(上流ニップローラ対)
 10N  ニップ部(上流ニップ部)
 11   バックトップローラ(第1の上流ローラ)
 12   バックボトムローラ(第2の上流ローラ)
 15   加熱ローラ
 16   加圧ローラ
 18   延伸固定化獣毛繊維束または延伸復元獣毛繊維束(延伸縮径獣毛繊維束)
 19   延伸ゾーン
 20   フロントローラ対(下流ニップローラ対)
 20N  ニップ部(下流ニップ部)
 21   フロントトップローラ(第1の下流ローラ)
 22   フロントボトムローラ(第2の下流ローラ)
 30   膨潤可塑化処理装置
 40   延伸機構
 50   固定化装置(加熱装置)
 60   酸化中和処理槽(酸化中和装置)
100   獣毛繊維延伸固定装置(延伸縮径獣毛繊維の製造装置)
1 Animal hair fiber bundle 2 Swelling plasticized aqueous solution (swelling plasticizer)
5 Swelling plasticized animal hair fiber bundle 10 Back roller pair (upstream nip roller pair)
10N nip (upstream nip)
11 Backtop roller (first upstream roller)
12 Back bottom roller (second upstream roller)
15 Heating roller 16 Pressure roller 18 Stretch-fixed animal hair fiber bundle or stretched restored animal hair fiber bundle (extended stretchable animal hair fiber bundle)
19 Stretching zone 20 Front roller pair (downstream nip roller pair)
20N nip (downstream nip)
21 Front top roller (first downstream roller)
22 Front bottom roller (second downstream roller)
30 Swelling plasticization processing equipment 40 Stretching mechanism 50 Immobilization equipment (heating equipment)
60 Oxidation neutralization treatment tank (oxidation neutralization equipment)
100 Animal hair fiber drawing and fixing device

Claims (21)

  1.  獣毛繊維束を膨潤可塑化剤で膨潤可塑化処理して膨潤可塑化獣毛繊維束を作製する膨潤可塑化処理装置と、
     上流ニップ部を形成する第1の上流ローラと第2の上流ローラとから構成される上流ニップローラ対と、下流ニップ部を形成する第1の下流ローラと第2の下流ローラとから構成される下流ニップローラ対とを有する延伸機構と
    を備える延伸縮径獣毛繊維の製造装置において、
     前記獣毛繊維束を前記膨潤可塑化処理装置に通して前記膨潤可塑化獣毛繊維束を作製し、
     前記第1の上流ローラの回転軸に沿って見た場合において、前記上流ニップ部と前記下流ニップ部との間において前記膨潤可塑化獣毛繊維束が前記上流ニップ部から前記下流ニップ部に向かってS字状または逆S字状に流れる状態で前記膨潤可塑化獣毛繊維束を延伸する
    延伸縮径獣毛繊維の製造方法。
    A swelling plasticizing apparatus for producing a swelling plasticized animal hair fiber bundle by swelling plasticizing an animal hair fiber bundle with a swelling plasticizer;
    An upstream nip roller pair composed of a first upstream roller and a second upstream roller forming an upstream nip portion, and a downstream composed of a first downstream roller and a second downstream roller forming a downstream nip portion In an apparatus for producing a stretchable animal hair fiber comprising a drawing mechanism having a nip roller pair,
    The animal hair fiber bundle is passed through the swelling plasticization treatment device to produce the swelling plasticized animal hair fiber bundle,
    When viewed along the rotation axis of the first upstream roller, the swollen plasticized animal hair fiber bundle moves from the upstream nip portion toward the downstream nip portion between the upstream nip portion and the downstream nip portion. A method for producing an elongated stretched animal hair fiber in which the swollen plasticized animal hair fiber bundle is stretched in a state of flowing in an S shape or an inverted S shape.
  2.  前記第1の上流ローラの回転軸に沿って見た場合において、前記第1の上流ローラの回転軸と前記第2の下流ローラの回転軸とを結ぶ仮想直線または仮想延長直線と、前記第2の上流ローラの回転軸と前記第1の下流ローラの回転軸とを結ぶ仮想直線または仮想延長直線とが交差し、
     前記膨潤可塑化獣毛繊維束は、前記上流ニップ部、前記第2の上流ローラ、前記第1の下流ローラおよび前記下流ニップ部の順に前記第1の上流ローラ、前記第2の上流ローラ、前記第1の下流ローラおよび前記第2の下流ローラに接触する
    請求項1に記載の延伸縮径獣毛繊維の製造方法。
    When viewed along the rotation axis of the first upstream roller, a virtual straight line or a virtual extension straight line connecting the rotation axis of the first upstream roller and the rotation axis of the second downstream roller, and the second A virtual straight line or a virtual extension straight line connecting the rotation axis of the upstream roller and the rotation axis of the first downstream roller,
    The swollen plasticized animal hair fiber bundle includes the first upstream roller, the second upstream roller, the upstream nip portion, the second upstream roller, the first downstream roller, and the downstream nip portion in this order. The manufacturing method of the extended expansion diameter animal hair fiber of Claim 1 which contacts a 1st downstream roller and a said 2nd downstream roller.
  3.  前記第2の上流ローラの回転軸と前記第1の下流ローラの回転軸との直線距離は、前記第1の上流ローラの回転軸と前記第2の下流ローラの回転軸との直線距離よりも短い
    請求項2に記載の延伸縮径獣毛繊維の製造方法。
    The linear distance between the rotational axis of the second upstream roller and the rotational axis of the first downstream roller is greater than the linear distance between the rotational axis of the first upstream roller and the rotational axis of the second downstream roller. The manufacturing method of the extended stretch diameter animal hair fiber of Claim 2 short.
  4.  前記膨潤可塑化獣毛繊維束は、前記第1の上流ローラの回転軸に沿って見た場合において、少なくとも、「前記上流ニップ部」から「「前記第1の上流ローラの回転軸と前記第2の上流ローラの回転軸とを結ぶ仮想延長線」と「前記第2の上流ローラの外周線」との交点のうち前記上流ニップ部と反対側の交点」までの前記第2の上流ローラの外周面部分、および、「「前記第1の下流ローラの回転軸と前記第2の下流ローラの回転軸とを結ぶ仮想延長線」と「前記第1の下流ローラの外周線」との交点のうち前記下流ニップ部と反対側の交点」から「前記下流ニップ部」までの前記第1の下流ローラの外周面部分に接触する
    請求項1から3のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    When the swollen plasticized animal hair fiber bundle is viewed along the rotation axis of the first upstream roller, at least from the “upstream nip portion” to “the rotation axis of the first upstream roller and the first rotation roller”. Of the second upstream roller up to the intersection of the virtual extension line connecting the rotation axis of the two upstream rollers and the outer peripheral line of the second upstream roller on the opposite side of the upstream nip. An outer peripheral surface portion, and an intersection of “a virtual extension line connecting the rotation axis of the first downstream roller and the rotation axis of the second downstream roller” and “the outer periphery line of the first downstream roller” 4. The stretchable diameter animal hair fiber according to claim 1, which is in contact with an outer peripheral surface portion of the first downstream roller from an “intersection on the side opposite to the downstream nip portion” to “the downstream nip portion”. Manufacturing method.
  5.  前記第1の上流ローラの回転軸に沿って見た場合において、前記第1の上流ローラの回転軸と前記第2の下流ローラの回転軸とを結ぶ仮想直線と、前記第2の上流ローラの回転軸と前記第1の下流ローラの回転軸とを結ぶ仮想直線とが同一仮想直線上に位置し、
     前記膨潤可塑化獣毛繊維束は、前記上流ニップ部、前記第2の上流ローラ、前記第1の下流ローラおよび前記下流ニップ部の順に前記第1の上流ローラ、前記第2の上流ローラ、前記第1の下流ローラおよび前記第2の下流ローラに接触する
    請求項1に記載の延伸縮径獣毛繊維の製造方法。
    When viewed along the rotation axis of the first upstream roller, an imaginary straight line connecting the rotation axis of the first upstream roller and the rotation axis of the second downstream roller, and the second upstream roller A virtual straight line connecting the rotation axis and the rotation axis of the first downstream roller is located on the same virtual line,
    The swollen plasticized animal hair fiber bundle includes the first upstream roller, the second upstream roller, the upstream nip portion, the second upstream roller, the first downstream roller, and the downstream nip portion in this order. The manufacturing method of the extended expansion diameter animal hair fiber of Claim 1 which contacts a 1st downstream roller and a said 2nd downstream roller.
  6.  前記膨潤可塑化獣毛繊維束は、1.1倍以上3.0倍以下の倍率で延伸される
    請求項1から5のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    The method for producing an elongated stretch-diameter animal hair fiber according to any one of claims 1 to 5, wherein the swollen plasticized animal hair fiber bundle is stretched at a magnification of 1.1 to 3.0 times.
  7.  前記膨潤可塑化獣毛繊維束は、前記上流ニップローラ対および前記下流ニップローラ対のみで延伸される
    請求項1から6のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    7. The method for producing an elongated stretched animal hair fiber according to claim 1, wherein the swollen plasticized animal hair fiber bundle is stretched only by the upstream nip roller pair and the downstream nip roller pair.
  8.  前記獣毛繊維束および前記膨潤可塑化獣毛繊維束は無撚りである
    請求項1から7のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    The method for producing stretched-length animal hair fibers according to any one of claims 1 to 7, wherein the animal hair fiber bundle and the swollen plasticized animal hair fiber bundle are non-twisted.
  9.  前記延伸縮径獣毛繊維の製造装置は、加熱装置と、酸化中和装置とを有し、
     前記膨潤可塑化獣毛繊維束を延伸した後、前記膨潤可塑化獣毛繊維束を緊張させたままの状態で、前記加熱装置により前記膨潤可塑化獣毛繊維束を60度C以上150度C以下の範囲内の温度に加熱して前記膨潤可塑化獣毛繊維束を固定化し、前記酸化中和装置により前記膨潤可塑化獣毛繊維束を酸化した後に中和する
    請求項1から8のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    The apparatus for producing the stretchable animal hair fiber has a heating device and an oxidation neutralization device,
    After the swollen plasticized animal hair fiber bundle is stretched, the swollen plasticized animal hair fiber bundle is kept at 60 ° C. or more and 150 ° C. by the heating device while the swollen plasticized animal hair fiber bundle is kept in tension. The temperature of the following ranges is heated to fix the swollen plasticized animal hair fiber bundle, and the swollen plasticized animal hair fiber bundle is oxidized by the oxidation neutralization device and then neutralized. A method for producing a stretchable animal hair fiber according to claim 1.
  10.  前記延伸縮径獣毛繊維の製造装置は、加熱ローラをさらに有し、
     前記加熱装置は、加熱ローラを加熱し、
     前記膨潤可塑化獣毛繊維束は、前記加熱ローラの外表面に直接接触されて固定化される請求項9に記載の延伸縮径獣毛繊維の製造方法。
    The apparatus for producing an elongated stretchable animal hair fiber further comprises a heating roller,
    The heating device heats the heating roller,
    The method for producing an extended stretchable animal hair fiber according to claim 9, wherein the swollen plasticized animal hair fiber bundle is directly contacted and fixed to the outer surface of the heating roller.
  11.  前記膨潤可塑化獣毛繊維束は、前記加熱ローラと少なくとも1個の加圧ローラとで加圧されながら固定化される
    請求項10に記載の延伸縮径獣毛繊維の製造方法。
    11. The method for producing an extended stretchable animal hair fiber according to claim 10, wherein the swollen plasticized animal hair fiber bundle is fixed while being pressed by the heating roller and at least one pressure roller.
  12.  前記膨潤可塑化獣毛繊維束は、前記膨潤可塑化剤を60重量%以上含有する
    請求項1から11のいずれかに記載の延伸縮径獣毛繊維の製造方法。
    12. The method for producing stretched animal hair fibers according to claim 1, wherein the swollen plasticized animal hair fiber bundle contains 60% by weight or more of the swelling plasticizer.
  13.  請求項1から8のいずれかに記載の延伸縮径獣毛繊維の製造方法により製造される延伸縮径獣毛繊維から成る
    延伸復元獣毛紡績糸。
    A stretched restored animal hair spun yarn comprising an elongated stretch-diameter animal hair fiber produced by the method for producing an elongated stretch-diameter animal hair fiber according to any one of claims 1 to 8.
  14.  請求項1から8のいずれかに記載の延伸縮径獣毛繊維の製造方法により製造される延伸縮径獣毛繊維と、
     前記延伸縮径獣毛繊維以外の繊維と
    を含む、延伸復元複合獣毛紡績糸。
    An elongated stretchable animal hair fiber produced by the method of producing an elongated stretchable animal hair fiber according to any one of claims 1 to 8,
    A stretched restored composite animal hair spun yarn comprising fibers other than the above-mentioned stretched and contracted diameter animal hair fibers.
  15.  請求項13に記載の延伸復元獣毛紡績糸または請求項14に記載の延伸復元複合獣毛紡績糸の前記延伸縮径獣毛繊維の形状が延伸前の繊維形状にほぼ復元されている
    復元獣毛紡績糸。
    The stretched animal hair spun yarn according to claim 13 or the stretched and reconstructed composite animal hair spun yarn according to claim 14, wherein the stretched and stretched animal hair fiber is substantially restored to the fiber shape before stretching. Wool spinning yarn.
  16.  請求項15に記載の復元獣毛紡績糸を含む布帛。 A fabric comprising the restored animal hair spun yarn according to claim 15.
  17.  請求項13に記載の延伸復元獣毛紡績糸または請求項14に記載の延伸復元複合獣毛紡績糸を含み、前記延伸縮径獣毛繊維の形状が延伸前の繊維形態にほぼ復元されることにより製造される復元獣毛布帛。 The stretch-reconstructed animal hair spun yarn according to claim 13 or the stretch-reconstructed composite animal hair spun yarn according to claim 14, wherein the shape of the stretch-expanded animal hair fiber is substantially restored to the fiber form before stretching. A restored animal blanket manufactured by
  18.  長手方向の少なくとも一部分では、径方向の断面形状が円形である単繊維と、径方向の断面形状が非円形状である単繊維とが混在しており、
     前記単繊維の平均繊維径は13μm以上28μm以下の範囲内である
    延伸縮径獣毛繊維束。
    In at least a part of the longitudinal direction, a single fiber having a circular cross-sectional shape in the radial direction and a single fiber having a non-circular cross-sectional shape in the radial direction are mixed,
    An average stretched diameter animal hair fiber bundle in which the average fiber diameter of the single fibers is within a range of 13 μm to 28 μm.
  19.  請求項18に記載の延伸縮径獣毛繊維束を主成分とする獣毛繊維束。 An animal hair fiber bundle mainly composed of the extended stretchable animal hair fiber bundle according to claim 18.
  20.  請求項18に記載の延伸縮径獣毛繊維束または請求項19に記載の獣毛繊維束から形成される延伸固定獣毛繊維紡績糸。 A stretch-fixed animal hair fiber spun yarn formed from the stretched diameter animal hair fiber bundle according to claim 18 or the animal hair fiber bundle according to claim 19.
  21.  請求項20の延伸固定獣毛繊維紡績糸を含み形成される布帛。 21. A fabric comprising the stretch-fixed animal hair fiber spun yarn of claim 20.
PCT/JP2012/066901 2011-08-09 2012-07-02 Drawn reduced-diameter animal fiber manufacturing method, restorable drawn animal fiber spun yarn, restorable drawn composite animal fiber spun yarn, restored animal fiber spun yarn, restored animal fiber cloth, drawn reduced-diameter animal fiber bundle, animal fiber bundle, fixed drawn animal fiber spun yarn, and cloth WO2013021751A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2013527931A JP5938619B6 (en) 2011-08-09 2012-07-02 Production method of stretch stretched animal hair fiber, stretched restored animal hair spun yarn, stretched restored composite animal hair spun yarn, restored animal hair spun yarn, restored animal hair fabric, stretched stretched animal hair fiber bundle, animal hair fiber bundle, stretched Fixed animal hair fiber spun yarn and fabric

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2011174367 2011-08-09
JP2011-174367 2011-08-09
JP2012008007 2012-01-18
JP2012-008007 2012-01-18

Publications (1)

Publication Number Publication Date
WO2013021751A1 true WO2013021751A1 (en) 2013-02-14

Family

ID=47668271

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/066901 WO2013021751A1 (en) 2011-08-09 2012-07-02 Drawn reduced-diameter animal fiber manufacturing method, restorable drawn animal fiber spun yarn, restorable drawn composite animal fiber spun yarn, restored animal fiber spun yarn, restored animal fiber cloth, drawn reduced-diameter animal fiber bundle, animal fiber bundle, fixed drawn animal fiber spun yarn, and cloth

Country Status (2)

Country Link
JP (1) JP6111408B2 (en)
WO (1) WO2013021751A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103361922A (en) * 2013-07-31 2013-10-23 山东南山纺织服饰有限公司 Method of colored wool stretch refining and permanency shaping

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55112330A (en) * 1979-02-16 1980-08-29 Kanebo Ltd Continuous setting of wool fiber bundle
JPS5756539A (en) * 1980-09-18 1982-04-05 Toray Industries Special wood fiber
JPH073556A (en) * 1993-06-10 1995-01-06 Kurabo Ind Ltd Elongated animal fiber and production thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6253477A (en) * 1985-08-28 1987-03-09 ウ−ル デイベロプメント インタ−ナシヨナル リミテイド Method and apparatus for continuous artificial crimping and chemical treatment of keratinous fiber
JP3730733B2 (en) * 1996-11-25 2006-01-05 倉敷紡績株式会社 Elongated animal hair fiber and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55112330A (en) * 1979-02-16 1980-08-29 Kanebo Ltd Continuous setting of wool fiber bundle
JPS5756539A (en) * 1980-09-18 1982-04-05 Toray Industries Special wood fiber
JPH073556A (en) * 1993-06-10 1995-01-06 Kurabo Ind Ltd Elongated animal fiber and production thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103361922A (en) * 2013-07-31 2013-10-23 山东南山纺织服饰有限公司 Method of colored wool stretch refining and permanency shaping
CN103361922B (en) * 2013-07-31 2015-10-07 山东南山纺织服饰有限公司 A kind of method of pigmented wool slenderizing and permanent set

Also Published As

Publication number Publication date
JP2016166440A (en) 2016-09-15
JP6111408B2 (en) 2017-04-12
JP5938619B2 (en) 2016-06-22
JPWO2013021751A1 (en) 2015-03-05

Similar Documents

Publication Publication Date Title
CN110662864B (en) Surface-treated fiber, method for producing same, yarn, and fiber product
JP2983628B2 (en) Staple fiber stretching
JPWO2008012869A1 (en) Weft stretch lining and its manufacturing method
CN1327071C (en) Mercerisation of cellulosic fibres
WO1997013897A1 (en) False twisted yarn
CN113463258B (en) Processing method of woolen sweater capable of being washed by machine
JP6111408B2 (en) Stretched restored animal hair spun yarn, stretched restored composite animal hair spun yarn, restored animal hair spun yarn, restored animal hair spun yarn, stretched stretched animal hair fiber bundle, animal hair fiber bundle, stretched fixed animal hair fiber spun yarn and fabric
KR101876869B1 (en) Method Of Dimensionally Stabilizing Fine Denier Wool―Fabrics
EP0632149B1 (en) Method of manufacturing a slenderized animal wool
CN113882159A (en) High-comfort hemp fabric pretreatment process
JP5938619B6 (en) Production method of stretch stretched animal hair fiber, stretched restored animal hair spun yarn, stretched restored composite animal hair spun yarn, restored animal hair spun yarn, restored animal hair fabric, stretched stretched animal hair fiber bundle, animal hair fiber bundle, stretched Fixed animal hair fiber spun yarn and fabric
JP3113651B1 (en) Elongated animal hair fiber and method for producing the same
CN111893747A (en) Anti-sticking wool fabric and manufacturing method thereof
KR101795632B1 (en) Method Of Fine Denier Treatment For Wool Sliver
KR101514922B1 (en) Method of fine denier treatment for worsted-yarn and treament device
US6716256B2 (en) Method for preparation of slenderized animal fiber
JP3188793B2 (en) Elongated animal hair fiber and method for producing the same
KR20000068297A (en) Lyocell fabrics and their treaement
JP3730733B2 (en) Elongated animal hair fiber and production method thereof
JP2000248461A (en) Production of stretchable woven/knitted fabric consisting of cellulose-based fiber
JP2007169853A (en) Cellulose ester-based twisted yarn, method for producing the same and woven or knitted fabric
KR102146817B1 (en) Method of Manufacturinng the Strechable Wool Textile and the Strechable Wool Textile Produced Thereby
Mori et al. Correlation with itchy feeling of fabric handling change by physicochemical processing of woolen fabric
KR20050021449A (en) Manufacturing process of drawn anti-felting worsted yarn, drawn anti-felting worsted yarn and low-speed drawing machine
CN104328567A (en) Single-faced large jacquard fabric comprising 35 percent of Lyocell fiber, 30 percent of nylon, 20 percent of cotton and 15 percent of spun silk and preparation method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12822744

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2013527931

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12822744

Country of ref document: EP

Kind code of ref document: A1