WO2013006623A1 - Zeolite nanosheet membrane - Google Patents
Zeolite nanosheet membrane Download PDFInfo
- Publication number
- WO2013006623A1 WO2013006623A1 PCT/US2012/045411 US2012045411W WO2013006623A1 WO 2013006623 A1 WO2013006623 A1 WO 2013006623A1 US 2012045411 W US2012045411 W US 2012045411W WO 2013006623 A1 WO2013006623 A1 WO 2013006623A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxide material
- exfoliated
- nanosheets
- polymer
- film
- Prior art date
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- 239000010457 zeolite Substances 0.000 title claims abstract description 41
- 239000002135 nanosheet Substances 0.000 title claims description 137
- 239000012528 membrane Substances 0.000 title abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 81
- 239000000725 suspension Substances 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims description 26
- 239000004793 Polystyrene Substances 0.000 claims description 15
- 238000002441 X-ray diffraction Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 229920002223 polystyrene Polymers 0.000 claims description 15
- -1 polypropylene Polymers 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 238000001354 calcination Methods 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 9
- 230000034655 secondary growth Effects 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000004677 Nylon Substances 0.000 claims description 4
- 229920001721 Polyimide Polymers 0.000 claims description 4
- 239000004642 Polyimide Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229920001610 polycaprolactone Polymers 0.000 claims description 4
- 239000004632 polycaprolactone Substances 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229920000193 polymethacrylate Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 4
- 229920003288 polysulfone Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 abstract description 36
- 230000003197 catalytic Effects 0.000 abstract description 3
- 239000002808 molecular sieve Substances 0.000 abstract description 3
- 239000010409 thin film Substances 0.000 abstract description 3
- 238000004377 microelectronic Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 30
- 238000000576 coating method Methods 0.000 description 30
- 238000004630 atomic force microscopy Methods 0.000 description 18
- 239000002114 nanocomposite Substances 0.000 description 14
- 238000005457 optimization Methods 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- 206010040844 Skin exfoliation Diseases 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 238000004299 exfoliation Methods 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000004627 transmission electron microscopy Methods 0.000 description 12
- 238000003917 TEM image Methods 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- 238000004088 simulation Methods 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 10
- 230000002194 synthesizing Effects 0.000 description 10
- 230000000875 corresponding Effects 0.000 description 9
- 238000002003 electron diffraction Methods 0.000 description 9
- 125000004429 atoms Chemical group 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 238000000024 high-resolution transmission electron micrograph Methods 0.000 description 6
- 230000000737 periodic Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000001878 scanning electron micrograph Methods 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 6
- 238000005119 centrifugation Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 229940078552 o-xylene Drugs 0.000 description 5
- 239000012466 permeate Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 230000002522 swelling Effects 0.000 description 5
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N Azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 235000012970 cakes Nutrition 0.000 description 4
- 238000002524 electron diffraction data Methods 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000000329 molecular dynamics simulation Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- 238000007873 sieving Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- 102000014961 Protein Precursors Human genes 0.000 description 3
- 108010078762 Protein Precursors Proteins 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000005804 alkylation reaction Methods 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 238000010884 ion-beam technique Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- URLKBWYHVLBVBO-UHFFFAOYSA-N p-xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 3
- 229920001142 polymer nanocomposite Polymers 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000004400 29Si cross polarisation magic angle spinning Methods 0.000 description 2
- 229910016523 CuKa Inorganic materials 0.000 description 2
- XBGNERSKEKDZDS-UHFFFAOYSA-N N-[2-(dimethylamino)ethyl]acridine-4-carboxamide Chemical compound C1=CC=C2N=C3C(C(=O)NCCN(C)C)=CC=CC3=CC2=C1 XBGNERSKEKDZDS-UHFFFAOYSA-N 0.000 description 2
- 229910008069 Si-O-H Inorganic materials 0.000 description 2
- 229910006283 Si—O—H Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000004422 calculation algorithm Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000005712 crystallization Effects 0.000 description 2
- 238000010192 crystallographic characterization Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 235000015114 espresso Nutrition 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxyl anion Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229910052627 muscovite Inorganic materials 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 238000000696 nitrogen adsorption--desorption isotherm Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 125000004430 oxygen atoms Chemical group O* 0.000 description 2
- 230000003334 potential Effects 0.000 description 2
- 238000001144 powder X-ray diffraction data Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 150000003738 xylenes Chemical class 0.000 description 2
- MNDIARAMWBIKFW-UHFFFAOYSA-N 1-Bromohexane Chemical compound CCCCCCBr MNDIARAMWBIKFW-UHFFFAOYSA-N 0.000 description 1
- QYOXLKAKUAASNA-UHFFFAOYSA-N 1-bromodocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCBr QYOXLKAKUAASNA-UHFFFAOYSA-N 0.000 description 1
- DKNWSYNQZKUICI-UHFFFAOYSA-N Amantadine Chemical compound C1C(C2)CC3CC2CC1(N)C3 DKNWSYNQZKUICI-UHFFFAOYSA-N 0.000 description 1
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- 235000004418 Durio kutejensis Nutrition 0.000 description 1
- 238000005004 MAS NMR spectroscopy Methods 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N Methyl iodide Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000003247 decreasing Effects 0.000 description 1
- 230000001627 detrimental Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001747 exhibiting Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- CKHJYUSOUQDYEN-UHFFFAOYSA-N gallium(3+) Chemical compound [Ga+3] CKHJYUSOUQDYEN-UHFFFAOYSA-N 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium(0) Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000011031 large scale production Methods 0.000 description 1
- 238000000707 layer-by-layer assembly Methods 0.000 description 1
- 230000000670 limiting Effects 0.000 description 1
- 238000000449 magic angle spinning nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000000873 masking Effects 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000000877 morphologic Effects 0.000 description 1
- 230000036961 partial Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002829 reduced Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000001988 small-angle X-ray diffraction Methods 0.000 description 1
- 238000000371 solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000807 solvent casting Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 230000005428 wave function Effects 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0046—Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0076—Pretreatment of inorganic membrane material prior to membrane formation, e.g. coating of metal powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/027—Silicium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/130,589 US10005077B2 (en) | 2011-07-03 | 2012-07-03 | Zeolite nanosheet membrane |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161504214P | 2011-07-03 | 2011-07-03 | |
| US61/504,214 | 2011-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2013006623A1 true WO2013006623A1 (en) | 2013-01-10 |
Family
ID=47437412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2012/045411 WO2013006623A1 (en) | 2011-07-03 | 2012-07-03 | Zeolite nanosheet membrane |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US10005077B2 (und) |
| WO (1) | WO2013006623A1 (und) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014057504A1 (en) | 2012-10-12 | 2014-04-17 | Council Of Scientific & Industrial Research | Porous crystalline frameworks, process for the preparation therof and their mechanical delamination to covalent organic nanosheets (cons) |
| CN104310413A (zh) * | 2014-10-21 | 2015-01-28 | 太原理工大学 | 一种制备己内酰胺的薄层纳米片状全硅分子筛的制备方法及应用 |
| US10005674B2 (en) | 2014-06-27 | 2018-06-26 | Regents Of The University Of Minnesota | Silica support structure for a zeolite membrane |
| US10005077B2 (en) | 2011-07-03 | 2018-06-26 | Regents Of The University Of Minnesota | Zeolite nanosheet membrane |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9186622B1 (en) * | 2014-06-11 | 2015-11-17 | Hamilton Sundstrand Corporation | Device for separation of oxygen and nitrogen |
| US10213748B2 (en) | 2015-12-21 | 2019-02-26 | Regents Of The University Of Minnesota | Pore opened zeolite nanosheets and their suspensions and methods and uses related thereto |
| US10744748B2 (en) * | 2016-02-29 | 2020-08-18 | The Industry & Academic Cooperation In Chungnam National University (Iac) | Micro nanoporous membrane, preparing method thereof and microfluidic device using thereof |
| US10793442B2 (en) * | 2018-06-15 | 2020-10-06 | The University Of Massachusetts | Exfoliation of zeolites in functionalized polymers |
| CN110759351B (zh) * | 2018-07-26 | 2022-11-18 | 中国科学院金属研究所 | 一种晶振表面分子筛膜材料及其制备方法和应用 |
| WO2020210460A1 (en) * | 2019-04-09 | 2020-10-15 | Georgia Tech Research Corporation | Zeolite membranes, molecular separation methods, and manufacturing processes for zeolite membranes |
| KR102267465B1 (ko) * | 2019-08-14 | 2021-06-22 | 고려대학교 산학협력단 | 단순 소성을 통한 나노판형 제올라이트의 제조방법과 이로부터 제조된 나노판형 제올라이트 입자 |
| US20220384833A1 (en) * | 2021-01-04 | 2022-12-01 | Bettergy Corp. | Systems including ion exchange membranes and methods of making the same |
| CN114649553B (zh) * | 2022-02-11 | 2023-04-14 | 南京工业大学 | 一种沸石分子筛纳米片负载的多孔膜、制备方法及其在锌基液流电池中的应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2279159C1 (ru) * | 2004-10-21 | 2006-06-27 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Композиционный материал для сепараторов щелочных аккумуляторных батарей и способ его получения |
| US7357836B2 (en) * | 2003-03-06 | 2008-04-15 | University Of Massachusetts | Crystalline membranes |
| WO2009108166A2 (en) * | 2007-11-05 | 2009-09-03 | Regents Of The University Of Minnesota | Layered zeolite materials and methods related thereto |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5453298A (en) | 1990-11-08 | 1995-09-26 | California Institute Of Technology | Method for forming H2-permselective oxide membranes |
| US5278115A (en) | 1992-05-04 | 1994-01-11 | Mobil Oil Corp. | Method for preparing a pillared layered oxide material |
| US6844291B2 (en) * | 2002-02-28 | 2005-01-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve compositions, catalyst thereof, their making and use in conversion processes |
| US6863983B2 (en) | 2002-06-25 | 2005-03-08 | University Of Massachusetts | Layered silicate material and applications of layered materials with porous layers |
| CN101137427B (zh) | 2005-03-09 | 2011-08-03 | 加利福尼亚大学校务委员会 | 纳米复合材料膜及其制备和使用方法 |
| JP5135671B2 (ja) | 2005-09-28 | 2013-02-06 | 三菱化学株式会社 | ゼオライト分離膜の製造方法 |
| KR100727288B1 (ko) | 2005-10-14 | 2007-06-13 | 한국과학기술원 | 메조다공성 골격을 갖는 미세다공성 결정성 분자체의제조방법 |
| JP5324067B2 (ja) | 2006-08-22 | 2013-10-23 | 日本碍子株式会社 | ゼオライト膜の製造方法 |
| US8263035B2 (en) | 2006-10-26 | 2012-09-11 | Davis Tracy M | Forming nanoparticles in basic amino acid sols |
| US7919421B2 (en) | 2006-12-21 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation |
| TWI349015B (en) * | 2007-05-15 | 2011-09-21 | Univ Nat Taiwan | Method for forming polymer-clay nanocomposite latex and its application on sealing and semi-conductive materials |
| US20110009256A1 (en) | 2007-07-17 | 2011-01-13 | Regents Of The University Of Minnesota | Novel microporous silicate materials and methods for making and using the same |
| US7938894B2 (en) | 2008-02-14 | 2011-05-10 | Conocophillips Company | Hybrid organic-inorganic gas separation membranes |
| KR100978490B1 (ko) | 2008-05-21 | 2010-08-30 | 서강대학교산학협력단 | 다양한 두께를 갖는 모든 ｂ-축이 기질에 대해서 수직으로배향된 ＭＦＩ형 제올라이트 박막 및 그의 제조방법 |
| GR20080100438A (el) | 2008-06-27 | 2010-01-27 | Γεωργιος Σακελλαροπουλος | Μεθοδος χημικης διεισδυσης ατμων χαμηλης θερμοκρασιας, για την τροποποιηση του μεγεθους των πορων και την επιδιορθωση ατελειων σε μικροπορωδεις και νανοπορωδεις μεμβρανες |
| CN102333584A (zh) | 2009-02-27 | 2012-01-25 | 三菱化学株式会社 | 无机多孔支持体-沸石膜复合体、其制造方法和使用其的分离方法 |
| US20100304953A1 (en) | 2009-05-21 | 2010-12-02 | Battelle Memorial Institute | Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics |
| US8715392B2 (en) | 2009-05-21 | 2014-05-06 | Battelle Memorial Institute | Catalyzed CO2-transport membrane on high surface area inorganic support |
| KR101147008B1 (ko) | 2009-06-22 | 2012-05-22 | 한국과학기술원 | 단일 단위 결정 격자 한 개 또는 10개 이하가 연결되어 규칙적이거나 불규칙적이게 배열된, 다중 또는 단일 판상구조의 제올라이트 및 유사 제올라이트 물질 |
| WO2013006623A1 (en) | 2011-07-03 | 2013-01-10 | Regents Of The University Of Minnesota | Zeolite nanosheet membrane |
-
2012
- 2012-07-03 WO PCT/US2012/045411 patent/WO2013006623A1/en active Application Filing
- 2012-07-03 US US14/130,589 patent/US10005077B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7357836B2 (en) * | 2003-03-06 | 2008-04-15 | University Of Massachusetts | Crystalline membranes |
| RU2279159C1 (ru) * | 2004-10-21 | 2006-06-27 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Композиционный материал для сепараторов щелочных аккумуляторных батарей и способ его получения |
| WO2009108166A2 (en) * | 2007-11-05 | 2009-09-03 | Regents Of The University Of Minnesota | Layered zeolite materials and methods related thereto |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10005077B2 (en) | 2011-07-03 | 2018-06-26 | Regents Of The University Of Minnesota | Zeolite nanosheet membrane |
| WO2014057504A1 (en) | 2012-10-12 | 2014-04-17 | Council Of Scientific & Industrial Research | Porous crystalline frameworks, process for the preparation therof and their mechanical delamination to covalent organic nanosheets (cons) |
| US10005674B2 (en) | 2014-06-27 | 2018-06-26 | Regents Of The University Of Minnesota | Silica support structure for a zeolite membrane |
| CN104310413A (zh) * | 2014-10-21 | 2015-01-28 | 太原理工大学 | 一种制备己内酰胺的薄层纳米片状全硅分子筛的制备方法及应用 |
| CN104310413B (zh) * | 2014-10-21 | 2016-04-06 | 太原理工大学 | 一种制备己内酰胺的薄层纳米片状全硅分子筛的制备方法及应用 |
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|---|---|
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