WO2012152740A3 - Synthesis of nanoparticles comprising oxidation sensitive metals with tuned particle size and high oxidation stability - Google Patents
Synthesis of nanoparticles comprising oxidation sensitive metals with tuned particle size and high oxidation stability Download PDFInfo
- Publication number
- WO2012152740A3 WO2012152740A3 PCT/EP2012/058339 EP2012058339W WO2012152740A3 WO 2012152740 A3 WO2012152740 A3 WO 2012152740A3 EP 2012058339 W EP2012058339 W EP 2012058339W WO 2012152740 A3 WO2012152740 A3 WO 2012152740A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nanoparticles
- citrate
- capped
- thin
- synthesis
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/056—Submicron particles having a size above 100 nm up to 300 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Process for the synthesis of nanoparticles comprising oxidation sensitive metals, in particular copper comprising the following steps: Preparation and nucleation of citrate-capped Metal-hydroxide nanoparticles, reduction of the intermediate citrate-capped Metal-hydroxide nanoparticles to Metal0 by reduction via NaBH4 Cu0 nanoparticles with narrow size distribution are obtained by NaBH4 Li-induced reduction of CUCI2 2H2O in diethylene glycol. The course of the reaction essentially involves an intermediate formation of Cu(OH)2 nanoparticles as well as the presence of citrate to control the nucleation of almost monodisperse and non-agglomerated Cu0 nanoparticles. The citrate-capped Cu0 nanoparticles of the invention are surprisingly stable against air oxidation. Via simple solvent evaporation, porous Cu0 thin-films are prepared on glass substrates that exhibit bulk-like sheet resistances of 0.23 - 0.42 Ωϛ after vacuum sintering at 250 °C (bulk-Cu sheet under similar conditions with: 0.3 Ωϛ). With these features the as-prepared, citrate-capped Cu0 nanoparticles become highly relevant to electronic devices in particular thin-film electronics, thin-film sensors and high-power batteries.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11165705A EP2522445A1 (en) | 2011-05-11 | 2011-05-11 | Synthesis of nanoparticles comprising oxidation sensitive metals with tuned particle size and high oxidation stability |
EP11168094.8 | 2011-05-11 | ||
EP11165705.2 | 2011-05-11 | ||
EP11168094A EP2529861A1 (en) | 2011-05-30 | 2011-05-30 | Synthesis of Nanoparticles comprising oxidation sensitive metals with Tuned Particle Size and High Oxidation Stability |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012152740A2 WO2012152740A2 (en) | 2012-11-15 |
WO2012152740A3 true WO2012152740A3 (en) | 2013-01-10 |
Family
ID=46044702
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/058339 WO2012152740A2 (en) | 2011-05-11 | 2012-05-07 | Synthesis of nanoparticles comprising oxidation sensitive metals with tuned particle size and high oxidation stability |
Country Status (2)
Country | Link |
---|---|
TW (1) | TW201306974A (en) |
WO (1) | WO2012152740A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9700940B2 (en) | 2012-09-27 | 2017-07-11 | Lockheed Martin Corporation | Metal nanoparticles formed around a nucleus and scalable processes for producing same |
CN103408896B (en) * | 2013-05-21 | 2016-01-27 | 中国科学院深圳先进技术研究院 | A kind of epoxy resin composite material containing Nanometer Copper and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070190323A1 (en) * | 2006-02-15 | 2007-08-16 | Samsung Electro-Mechanics Co., Ltd. | Method of producing metal nanoparticles |
JP2010189681A (en) * | 2009-02-17 | 2010-09-02 | Hitachi Ltd | Method for producing oxidation resistant copper nanoparticle, and joining method using the same |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE112005003693T5 (en) | 2005-09-30 | 2008-08-07 | Inspire AG für mechatronische Produktionssysteme und Fertigungstechnik | Pressure cell and printhead for printing molten metals |
JP2008190020A (en) | 2007-02-07 | 2008-08-21 | Osaka Univ | Method for forming metal nanoparticle in medium |
-
2012
- 2012-05-07 WO PCT/EP2012/058339 patent/WO2012152740A2/en active Application Filing
- 2012-05-10 TW TW101116603A patent/TW201306974A/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070190323A1 (en) * | 2006-02-15 | 2007-08-16 | Samsung Electro-Mechanics Co., Ltd. | Method of producing metal nanoparticles |
JP2010189681A (en) * | 2009-02-17 | 2010-09-02 | Hitachi Ltd | Method for producing oxidation resistant copper nanoparticle, and joining method using the same |
Non-Patent Citations (1)
Title |
---|
KYLER J. CARROLL ET AL: "Preparation of Elemental Cu and Ni Nanoparticles by the Polyol Method: An Experimental and Theoretical Approach", JOURNAL OF PHYSICAL CHEMISTRY C, vol. 115, no. 6, 17 February 2011 (2011-02-17), pages 2656 - 2664, XP055044673, ISSN: 1932-7447, DOI: 10.1021/jp1104196 * |
Also Published As
Publication number | Publication date |
---|---|
WO2012152740A2 (en) | 2012-11-15 |
TW201306974A (en) | 2013-02-16 |
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