WO2012142431A1

WO2012142431A1 - Method of forming membranes with modified stress characteristics

Info

Publication number: WO2012142431A1
Application number: PCT/US2012/033553
Authority: WO
Inventors: Andrew B. GRAHAM; Gary Yama; Gary O'brien
Original assignee: Robert Bosch Gmbh
Priority date: 2011-04-14
Filing date: 2012-04-13
Publication date: 2012-10-18
Also published as: EP2697154A1; US8906730B2; CN103534195A; SG194480A1; JP2014511775A; WO2012142400A1; KR20140026473A; JP2017052092A; JP6346649B2; CN103534195B; KR101932301B1; US20120264250A1

Abstract

A method of modifying stress characteristics of a membrane in one embodiment includes providing a membrane layer, determining a desired stress modification, and forming at least one trough in the membrane layer based upon the determined desired stress modification.

Description

METHOD OF FORMING MEMBRANES WITH MODIFIED STRESS CHARACTERISTICS

This application claims the benefit of U.S. Provisional Application No.

61/475,432, filed on April 14, 2011.

Field of the Invention

[0001] This invention relates to membrane-based devices such as micromechanical electrical system (MEMS) pressure sensors devices or semiconductor devices incorporating a membrane.

Background

[0002] The manufacture of micromechanical electrical system (MEMS) such as pressure sensors and other devices incorporating a membrane poses serious challenges because of the sensitivity of the devices. Typically, the devices which are made of silicon, (polysilicon or silicon-germanium) must exhibit low stress values or predetermined stress values along with low or specific stress gradient properties. Stress reduction is accordingly typically achieved during a stress/stress-gradient relief step during a high temperature annealing process.

[0003] MEMS devices however, can be very complicated devices with a number of mechanical parts that are integrated with other permanent and/or temporary (sacrificial) materials. The integrated parts may exhibit detrimental interactions due to the thermal budget. Thus, subsequent annealing steps could affect the layers previously

deposited/annealed and therefore modify the film stress and stress gradient values of the devices. Thus, the timing and manner in which stress relief is accomplished must be carefully planned. This adds complexity and costs to the manufacturing process.

[0004] Various attempts have been made to control stress in the prior art. Some of those attempts include development of specialized films. While effective at reducing stress, these films suffer various shortcomings such as lack of conductivity, roughness, and irregular electrical properties. Other approaches include the use of doping or specific atmosphere control while depositing films. These approaches affect the chemical composition of the films.

[0005] What is needed, therefore, is a simple and effective approach to modification of stress characteristics within a membrane. A further need exists for an approach to modification of stress characteristics within a membrane that does not alter the chemical composition membrane.

Summary

[0006] A method of modifying stress characteristics of a membrane in one embodiment includes providing a membrane layer, determining a desired stress modification, and forming at least one trough in the membrane layer based upon the determined desired stress modification. BRIEF DESCRIPTION OF THE DRAWINGS

[0007] FIG. 1 depicts a side cross sectional view of a MEMS device with a released membrane wherein stress characteristics have been modified by planned incorporation of a mixture of partial and full depth stress modifying troughs in accordance with principles of the invention;

[0008] FIG. 2 depicts a top plan view of the MEMS device of FIG. 1 showing overlapping troughs used to substantially completely isolate the released membrane from stress generated in the membrane layer outside of the released membrane area;

[0009] FIG. 3 depicts a top plan view of a MEMS device including overlapping troughs wherein some of the troughs are located within the released membrane area so as to modify both the stiffness of the released membrane and the stress characteristics of the released membrane;

[0010] FIG. 4 depicts a top plan view of a MEMS device with troughs extending about the corners of the released membrane, wherein the troughs of FIG. 4 are significantly wider than the troughs of FIG. 3;

[0011] FIG. 5 depicts the modeled results of the application of a pressure to a released membrane incorporating spaced apart troughs along one edge of the membrane resulting in a focusing of stress in the area between the space apart troughs resulting in increased stress levels over a smaller area as compared to edges without troughs;

[0012] FIG. 6 depicts a perspective view of a MEMS device with a released membrane incorporating spaced apart troughs along each edge of the membrane resulting in a focusing of stress in the areas between the spaced apart troughs which are occupied by a respective piezoresistor;

[0013] FIG. 7 depicts a side cross sectional view of a device with a released membrane including troughs which extend upwardly into the membrane layer both in the released membrane portion and the unreleased portion of the membrane layer so as to modify both the stiffness of the released membrane as well as the stress characteristics of the membrane layer;

[0014] FIG. 8 depicts a side cross sectional view of the substrate of FIG. 8 with sacrificial ridges provided on the spacer layer prior to deposition of the membrane layer onto the spacer layer;

[0015] FIG. 9 depicts a side cross sectional view of the substrate of FIG. 8 with sacrificial ridges provided on the spacer layer after deposition of the membrane layer onto the spacer layer; and

[0016] FIGs. 10-13 depict various stages in the manufacture of a device incorporating upwardly extending troughs within a bond ring.

Description

[0017] For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiments illustrated in the drawings and described in the following written specification. It is understood that no limitation to the scope of the invention is thereby intended. It is further understood that the present invention includes any alterations and modifications to the illustrated embodiments and includes further applications of the principles of the invention as would normally occur to one skilled in the art to which this invention pertains.

[0018] FIGs. 1 and 2 depict a MEMS device 100 which may be, for example, a pressure detector. The MEMS device 100 includes a substrate layer 102 and a membrane layer 104 which is spaced apart from the substrate layer 102 by a spacer layer 106. The membrane layer 104 may be a silicon layer and the spacer layer 106 may be an oxide layer.

[0019] The membrane layer 104 has a released membrane portion 108. Stress within the membrane portion 108 is isolated by positioning of full stress troughs 110 and partial stress troughs 112 about the membrane portion 108. In the embodiment of FIGs. 1 and 2, the partial troughs 112 overlap a non-troughed area 114 located between the opposing end portions of the full stress troughs 110. Because the partial stress troughs 112 do not extend completely through the membrane layer 104, the structural integrity of the membrane layer 104 is greater in the area about the partial stress troughs 112 as compared to the structural integrity of the membrane layer 104 in the area about the full stress troughs 110. The stress relief, however, is not as great.

[0020] In the embodiment of FIGs. 1 and 2, all of the stress relief troughs 10 and 112 are located outside of the released membrane 108. Thus, the released membrane 108 is fully supported by an overlying portion 118 that is positioned on an upper surface of the spacer layer 106. Accordingly, the stiffness of the released membrane 108 is primarily dictated by the thickness and material of the released membrane 108, although the width and proximity of the full stress troughs 110 will provide some reduction in the stiffness of the released membrane 108.

[0021] FIG. 3 depicts an embodiment of a MEMS device 130 that provides increased stiffness reduction. The MEMS device 130 includes a plurality of troughs 132 and 134. The troughs 132, which may be full or partial troughs depending upon the desired strength and stress modification, which are located adjacent to a released membrane 136. The troughs 132 will thus have a significant effect on stress modification, but a lesser effect on the stiffness of the membrane 136. The troughs 134, however, are located within the outer perimeter of the released membrane 136. Accordingly, while the combination of the troughs 136 and 134 provide a significant isolation of the released membrane 136 from stresses originating outside of the released membrane 136, the troughs 134 also significantly reduce the stiffness of the membrane 136.

[0022] Accordingly, troughs can be used not only to reduce stress, but also to modify the stiffness of the membrane. By planning the orientation, depth, and location of the troughs, both stress characteristics and stiffness characteristics of a MEMS device can be optimized for a particular application.

[0023] FIG. 4 depicts a MEMS device 140 that includes troughs 142 and a released membrane 144. The troughs 142 are significantly wider than the troughs in the embodiments of FIGs. 1-3. The troughs 142, however, are located only at the corners of the membrane 144. Thus, while the stiffness of the membrane 144 is not significantly reduced, stress patterns will be focused by the troughs 142. Stress focusing is shown, for a different embodiment, in the stress simulation results depicted in FIG. 5.

[0024] FIG. 5 depicts a stress simulation performed on a porous silicon diaphragm 150. The diaphragm 150 is 12 μιη thick and includes two 6μιη troughs 152 and 154. For the depicted simulation, a 100 kPa force was applied at location 156, which is the center of the porous silicon diaphragm 150.

[0025] The resulting stress pattern included a region of high stress (0.884E+08 kPa) in the area 158 immediately around the applied force. Stress was focused as a result of the support of the porous silicon diaphragm 150 at the edges 160, 162, and 164 even without any troughs. The stress at the edges 160, 162, and 164 reached 0.118E+09 kPa. [0026] Stress was also focused at the remaining edge 166. The stress pattern at the edge 166 is modified, however, by the troughs 152 and 154. The stress is concentrated over a smaller area, resulting in a string of stress areas 168 that reach 0.147E+09 kPa. Thus, the troughs 152 and 154 provide stress/strain focusing at predetermined sites. By positioning a piezoresistor at the predetermined site, larger variations in piezoresistor output may be obtained for a given applied pressure. Of course, stress modification may be used in a variety of sensor types in addition to those incorporating piezoresistors including, for example, capacitive sensors.

[0027] The stress modification pattern affected by the troughs 152 and 154 thus show that precise geometry of corrugations (width, depth, shape, etc.) can be used to fine-tune the effect of the troughs. The embodiment of FIG. 6 utilizes the basic arrangement of the troughs 152 and 154 of FIG. 5 in order to maximize sensitivity of a device to a deflection of a membrane. In FIG. 6, a MEMS device 170 includes a released membrane 172. Each edge of the released membrane 172 includes spaced apart trough groups 174. A piezoresistor 176 is positioned in the area between the spaced apart trough groups 174.

[0028] As is evident from FIG. 5, spaced apart troughs 152 and 154 focus stress in the area between the spaced apart troughs 152/154. Likewise, the spaced apart trough groups 174 focus stress in the area occupied by the piezoresistors 178. Thus, any stress in the membrane 172, whether as a result of applied force or differential pressure across the membrane 172, is focused by the spaced apart troughs 152 and 154 into the areas occupied by the piezoresistors 178. If desired, more or fewer groupings of spaced apart troughs may be provided. [0029] In the foregoing embodiments, the partial troughs are depicted as extending downwardly from an upper surface of the devices. If desired, troughs may also be formed which extend upwardly from a lower surface of a membrane layer. For example, FIG. 6 depicts a MEMS device 180 which includes a substrate layer 182 and a membrane layer 184 which is spaced apart from the substrate layer 182 by a spacer layer 186. The membrane layer 184 has a released membrane portion 188.

[0030] Stress within the membrane portion 108 is modified by troughs 190 and 192. The troughs 190 are positioned within the released membrane 188. Thus, the troughs 190 also modify the stiffness of the released membrane 188. The troughs 190 and 192 may be formed in a number of different approaches. For example, the troughs 190 and 192 may be etched into the membrane layer 184, and the membrane layer 184 may then be bonded to the spacer layer 186.

[0031] Alternatively, sacrificial ridges 194 and 196 may be formed on the spacer layer 106 prior to formation of the membrane layer 184 as depicted in FIG. 7. After deposition of the membrane layer 184 (see FIG. 8), the sacrificial ridges 194 and 196 may then be etched. The sacrificial ridges 194 may be etched concurrent with the release of the membrane 188. The sacrificial ridges 196 may be etched separately or at the same time as the membrane release using an etch stop positioned between the sacrificial ridges 196 and the spacer layer 186.

[0032] Devices incorporating bond rings may also be provided with stress modification troughs. One approach to manufacturing such a device is discussed below with reference to FIGs. 9-12. In FIG. 9, a device 200 includes a substrate layer 202, a spacer layer 204, and a device layer 206. The device layer 206 includes a released membrane 208. A bond ring 210 is located on the lower surface of the substrate layer 202. The bond ring 10 may be formed by soldering, eutectic, or any other approach useful in bonding one substrate to another substrate.

[0033] In this embodiment, two different depths are desired for stress modification troughs. Accordingly, in a first etching process, stress modification troughs 212 are etched at locations within the bond ring as depicted in FIG. 10. During an ensuing etching step, additional troughs 214 are etched (FIG. 11). During the second etching step, additional material is etched out of the troughs 212. If desired, troughs of different widths may be provided. The incorporation of troughs having different depths allows for increased substrate strength beneath the released membrane 208 while still providing stress modification.

[0034] When the desired troughs have been formed, the bond ring 210 is used to bond the substrate layer 202 to a base substrate layer 216. If desired, the base substrate layer 216 may be, for example, a cap layer of another MEMS device.

[0035] While the invention has been illustrated and described in detail in the drawings and foregoing description, the same should be considered as illustrative and not restrictive in character. It is understood that only the preferred embodiments have been presented and that all changes, modifications and further applications that come within the spirit of the invention are desired to be protected.

Claims

Claim 1. A method of modifying stress characteristics of a membrane comprising: providing a membrane layer;

determining a desired stress modification; and

forming at least one trough in the membrane layer based upon the determined desired stress modification.

Claim 2. The method of claim 1, further comprising:

releasing the membrane layer from an underlying handle layer.

Claim 3. The method of claim 1, wherein forming at least one trough comprises: determining a trough geometry for the at least one trough based upon the determined desired stress modification.

Claim 4. The method of claim 3, wherein determining a trough geometry comprises:

determining a width, a depth, and a shape of the at least one trough based upon the determined desired stress modification.

Claim 5. The method of claim 1, wherein:

determining a desired stress modification comprises determining a stress focusing area of the membrane; and

forming at least one trough comprises determining a trough pattern based on the determined stress focusing area , and

forming at least one trough based upon the determined trough pattern.

Claim 6. The method of claim 1, wherein:

determining a desired stress modification comprises determining a stress isolating area of the membrane; and

forming at least one trough comprises

determining a trough pattern based on the determined stress isolating area, and

forming at least one trough based upon the determined trough pattern.

Claim 7. The method of claim 3, wherein:

forming at least one trough comprises determining a trough pattern based upon the determined desired stress modification; and

forming at least one trough based upon the determined trough pattern.

Claim 8. The method of claim 7, wherein forming at least one trough comprises forming at least one trough at a location adjacent to a membrane portion of the membrane layer.

Claim 9. The method of claim 7, wherein forming at least one trough comprises forming at least one trough at a location within a membrane portion of the membrane layer.

Claim 10. The method of claim 7, wherein forming at least one trough comprises forming at least one trough parallel to an edge of a membrane portion of the membrane layer.

Claim 11. The method of claim 7, wherein forming at least one trough comprises: forming a first trough with a first trough depth; and

forming a second trough with a second trough depth, wherein the first trough depth is deeper than the second trough depth.

Claim 12. The method of claim 7, wherein forming at least one trough comprises: forming at least a portion of a first trough parallel to an edge of a membrane portion of the membrane layer; and

forming at least a portion of a second trough parallel to the edge of the membrane portion of the membrane layer.

Claim 13. The method of claim 12, wherein the at least a portion of the first trough is parallel to the at least a portion of the second trough.

Claim 14. The method of claim 13, wherein the first trough only partially overlaps the second trough.

Claim 15. The method of claim 7, wherein forming at least one trough comprises forming at least one curved trough.

Claim 16. The method of claim 7, wherein forming at least one trough comprises: forming a first trough through an upper surface of the membrane layer; and forming a second trough through a lower surface of the membrane layer.