WO2012134211A3 - Microgel and method for preparing same, and water-soluble paint composition - Google Patents

Microgel and method for preparing same, and water-soluble paint composition Download PDF

Info

Publication number
WO2012134211A3
WO2012134211A3 PCT/KR2012/002358 KR2012002358W WO2012134211A3 WO 2012134211 A3 WO2012134211 A3 WO 2012134211A3 KR 2012002358 W KR2012002358 W KR 2012002358W WO 2012134211 A3 WO2012134211 A3 WO 2012134211A3
Authority
WO
WIPO (PCT)
Prior art keywords
microgel
water
paint composition
preparing same
shell
Prior art date
Application number
PCT/KR2012/002358
Other languages
French (fr)
Korean (ko)
Other versions
WO2012134211A2 (en
Inventor
문태권
이종택
이현숙
박종윤
고건혁
Original Assignee
주식회사 케이씨씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 케이씨씨 filed Critical 주식회사 케이씨씨
Priority to CN201280016943.2A priority Critical patent/CN103562275B/en
Publication of WO2012134211A2 publication Critical patent/WO2012134211A2/en
Publication of WO2012134211A3 publication Critical patent/WO2012134211A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/075—Macromolecular gels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0052—Preparation of gels
    • B01J13/0065—Preparation of gels containing an organic phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/20—After-treatment of capsule walls, e.g. hardening
    • B01J13/22—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/02—Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
    • C08J2205/024—Organogel, i.e. a gel containing an organic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

According to the present invention, a method for preparing a microgel comprises: a step of preparing a core; a step of forming a first shell on the core; and a step of forming a second shell on the first shell. The step of forming the first shell and/or the step of forming the second shell uses unsaturated monomers containing hydroxyl radicals and comprising polyalkylene glycols.
PCT/KR2012/002358 2011-03-31 2012-03-30 Microgel and method for preparing same, and water-soluble paint composition WO2012134211A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201280016943.2A CN103562275B (en) 2011-03-31 2012-03-30 Microgel and preparation method thereof, and water-soluble coating composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0029374 2011-03-31
KR1020110029374A KR101828605B1 (en) 2011-03-31 2011-03-31 Microgel and method for manufacturing the same, and water-soluble paint composition

Publications (2)

Publication Number Publication Date
WO2012134211A2 WO2012134211A2 (en) 2012-10-04
WO2012134211A3 true WO2012134211A3 (en) 2012-12-27

Family

ID=46932154

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/002358 WO2012134211A2 (en) 2011-03-31 2012-03-30 Microgel and method for preparing same, and water-soluble paint composition

Country Status (3)

Country Link
KR (1) KR101828605B1 (en)
CN (1) CN103562275B (en)
WO (1) WO2012134211A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108348884A (en) * 2015-10-30 2018-07-31 科莱恩国际有限公司 The metal dispersion of stability with raising
CN108905914B (en) * 2018-06-25 2020-10-27 浙江大学 One-step method for preparing biocompatible oil-core microcapsule and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990060694A (en) * 1997-12-31 1999-07-26 김충세 Core / shell microgel containing alkylene monoisocyanate / poly (ethylene oxide) monoalcohol monomer and coating composition containing same
EP1693429A1 (en) * 2005-02-22 2006-08-23 Kansai Paint Co., Ltd. Aqueous intermediate coating composition and method for forming multilayer coating film
JP2007056077A (en) * 2005-08-22 2007-03-08 Nof Corp Method for producing core-shell type polymer particle
KR100827464B1 (en) * 2001-12-29 2008-05-06 주식회사 케이씨씨 Method for preparing reverse-phased core/shell type microgel and water-soluble coating composition containing core/shell type microgel prepared thereby

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3320698B2 (en) * 1999-12-09 2002-09-03 大日本塗料株式会社 Aqueous paint composition
JP2004059622A (en) * 2002-07-25 2004-02-26 Kansai Paint Co Ltd Water-based coating composition
CN1282677C (en) * 2004-09-21 2006-11-01 华南理工大学 Hydroxyl acrylic acid emulsion with microgel nuclear structure and preparation process and application thereof
DE102009012455A1 (en) * 2009-03-12 2010-09-23 Follmann & Co. Gesellschaft Für Chemie-Werkstoffe Und -Verfahrenstechnik Mbh & Co. Kg Improved microcapsules and their preparation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990060694A (en) * 1997-12-31 1999-07-26 김충세 Core / shell microgel containing alkylene monoisocyanate / poly (ethylene oxide) monoalcohol monomer and coating composition containing same
KR100827464B1 (en) * 2001-12-29 2008-05-06 주식회사 케이씨씨 Method for preparing reverse-phased core/shell type microgel and water-soluble coating composition containing core/shell type microgel prepared thereby
EP1693429A1 (en) * 2005-02-22 2006-08-23 Kansai Paint Co., Ltd. Aqueous intermediate coating composition and method for forming multilayer coating film
JP2007056077A (en) * 2005-08-22 2007-03-08 Nof Corp Method for producing core-shell type polymer particle

Also Published As

Publication number Publication date
CN103562275A (en) 2014-02-05
CN103562275B (en) 2016-01-27
WO2012134211A2 (en) 2012-10-04
KR20120111083A (en) 2012-10-10
KR101828605B1 (en) 2018-02-13

Similar Documents

Publication Publication Date Title
EP3495525A4 (en) Non-oriented electromagnetic steel sheet, production method for non-oriented electromagnetic steel sheet, and production method for motor core
WO2012074814A3 (en) Microstructured articles comprising nanostructures and method
EP3176285A4 (en) Electrical steel sheet for stacking, stacked electrical steel sheet, method of manufacturing stacked electrical steel sheet, and iron core for automotive motor
EP3581665A4 (en) Method for producing non-oriented electromagnetic steel sheet, method for producing motor core, and motor core
EP2816709B8 (en) Rotor core, motor, and method for manufacturing motor
EP3075872A4 (en) Hot-formed steel sheet member, method for producing same, and steel sheet for hot forming
WO2013046060A9 (en) Paper and methods of making paper
EP2680632A4 (en) Relay station, base station and communication method
EP2612764A4 (en) Metal payment card, and method for producing same
WO2012148880A3 (en) A method for the preparation of doped single graphene sheets
EP2489764A4 (en) Die and method for manufacturing die, and anti-reflection coating
WO2013034979A3 (en) Crystalline forms of cabazitaxel
EP2548986A4 (en) Steel for nitrocarburization, nitrocarburized components, and production method for same
WO2014083162A3 (en) Method for preparing an optionally functionalised glass having bimodal porosity, and said glass
EP3075882A4 (en) Composition for non-oriented electrical steel sheet, method of manufacturing non-oriented electrical steel sheet product, and non-oriented electrical steel sheet product
MY175675A (en) Composition for producing oil
WO2014057418A3 (en) Solution phase processes for the manufacture of macrocyclic depsipeptides and new intermediates
WO2010128487A3 (en) Information medium having antiviral properties, and method for making same
WO2012051117A3 (en) Substituted benzamides and their uses
WO2014057419A3 (en) Aldehyde acetal based processes for the manufacture of macrocyclic depsipeptides and new intermediates
WO2012136909A3 (en) Thixotropic α-lactalbumin hydrogels, method for preparing same and uses thereof
WO2013164839A3 (en) Amorphous form of apixaban, process of preparation and compositions thereof
WO2014027171A3 (en) Communication system and method
WO2014091167A3 (en) Cyclopropylboronic compounds, method for preparing same and use thereof
WO2012141447A3 (en) Apparatus and method for creating coupon for free gift

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12764278

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12764278

Country of ref document: EP

Kind code of ref document: A2