WO2012125003A2 - 여과 장치 및 이를 위한 중공사막 모듈 - Google Patents
여과 장치 및 이를 위한 중공사막 모듈 Download PDFInfo
- Publication number
- WO2012125003A2 WO2012125003A2 PCT/KR2012/001912 KR2012001912W WO2012125003A2 WO 2012125003 A2 WO2012125003 A2 WO 2012125003A2 KR 2012001912 W KR2012001912 W KR 2012001912W WO 2012125003 A2 WO2012125003 A2 WO 2012125003A2
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- WIPO (PCT)
- Prior art keywords
- header
- fiber membrane
- hollow fiber
- support
- membrane module
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/02—Hollow fibre modules
- B01D63/04—Hollow fibre modules comprising multiple hollow fibre assemblies
- B01D63/043—Hollow fibre modules comprising multiple hollow fibre assemblies with separate tube sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/08—Prevention of membrane fouling or of concentration polarisation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/21—Specific headers, end caps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2315/00—Details relating to the membrane module operation
- B01D2315/06—Submerged-type; Immersion type
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/20—Prevention of biofouling
Definitions
- the present invention relates to a filtration device and a hollow fiber membrane module for the same.
- One of the separation methods using a filtration membrane is a method using a hollow fiber membrane.
- hollow fiber membranes have been widely used in the field of precision filtration such as sterile water, drinking water, ultrapure water production, but recently, sewage / wastewater treatment, solid-liquid separation in septic tanks, removal of suspended solids (SS) from industrial wastewater, and river water Filtration, filtration of industrial water, filtration of swimming pool water, and the like have expanded their application ranges.
- Filtration methods using hollow fiber membranes can be classified into submerged and pressurized according to their operation.
- the hollow fiber membrane bundle is immersed in the tank formed below the surface of ground, with the raw water to be treated.
- a negative pressure is applied to the inside of the hollow fiber membrane so that only the fluid except the contaminant selectively penetrates the hollow fiber membrane.
- the present invention relates to a filtration device and a hollow fiber membrane module therefor that can prevent problems caused by the above limitations and disadvantages of the related art.
- One aspect of the present invention is a needle that can be easily installed, can be safely and conveniently maintained, has a high hollow fiber membrane module density, is suitable for standardization, has excellent drain efficiency, and has high commerciality. It is to provide a knowledge filtering device.
- a tank into which feed water to be treated is introduced-the tank has a first stepped surface therein and a second stepped surface opposite to the first stepped surface -; And a hollow fiber membrane module immersed in raw water introduced into the tank, wherein the hollow fiber membrane module includes first and second headers and a hollow fiber membrane therebetween, wherein the first and second headers of the first header are provided.
- a filtration device is provided, characterized in that the distal ends are respectively supported by the first and second stepped surfaces.
- the first header having a catchment space therein;
- a hollow fiber membrane having one end ported to the first header through a first pinned layer and in fluid communication with a collecting space of the first header;
- a second header positioned below the first header during the water treatment operation, and the other end of the hollow fiber membrane is ported through a second fixed layer;
- a support for supporting the first and second headers in such a manner that the distance between the first and second headers can be varied within a predetermined range.
- the filtration device of the present invention by placing the collecting space of the tank lower than the water level of the raw water to be treated in the tank, it is possible to reduce the amount of energy required for the filtration operation.
- the submerged filtration device of the present invention is not only advantageous for standardization, but is also provided on the ground, so that its appearance can be improved, thereby improving its marketability.
- the gap between the headers of both ends of the hollow fiber membrane can be automatically narrowed according to the shrinkage degree of the hollow fiber membrane, so that the hollow fiber membrane is damaged or hollow due to the membrane shrinkage.
- the separation of the desert and the header can be prevented. That is, the hollow fiber membrane module of the present invention can respond to the shrinkage of the hollow fiber membrane itself.
- FIG. 2 is a cross sectional view along line AA ′ of the tank illustrated in FIG. 1;
- FIG. 3 is a perspective view of a hollow fiber membrane module according to an embodiment of the present invention.
- FIG. 4 is a cross-sectional view along the line II ′ of the hollow fiber membrane module of FIG. 3,
- Figure 5 is a partially exploded perspective view illustrating a fastening structure of the moving header and the support according to an embodiment of the present invention
- FIGS. 6 to 9 are partially exploded perspective views illustrating a fastening structure of a moving header and a support according to other embodiments of the present invention.
- FIG. 11 is a cross-sectional view along the line B-B 'of the filtration device of FIG.
- FIG. 12 illustrates a method in which a hollow fiber membrane module is fixed to a step surface of a tank according to another embodiment of the present invention.
- FIG. 1 is a perspective view of a filtration device according to an embodiment of the present invention.
- the filtration device of the present invention includes a tank 200 of the type illustrated in FIG.
- Raw water to be treated is introduced into the tank 200 through the raw water inlet port 230.
- Permeate that has penetrated the hollow fiber membrane (not shown) mounted in the tank 200 is discharged out of the tank 200 through the production water discharge port 221. That is, a negative pressure is provided to the hollow fiber membrane through the production water discharge port 221.
- the tank 200 of the present invention may include a sludge discharge part 240 in the form of a light beam subsidiary below.
- the tank 200 of the present invention may further include legs 250 longer than the height of the sludge discharge part 240.
- the tank 200 of the filtration device of the present invention Since the tank 200 of the filtration device of the present invention is placed on the ground, maintenance of the filtration device can be performed more safely and conveniently. In addition, since the sludge generated in the tank 200 can be naturally discharged out of the tank 200 through the sludge discharge unit 240 and the sludge discharge port 241 by gravity, the filtration device of the present invention is excellent drain efficiency Has
- the filtration apparatus of this invention can provide the ease of installation similarly to a pressure type.
- the tank 200 has an opening at the top for mounting and maintenance of the hollow fiber membrane module (not shown). Through this opening, the hollow fiber membrane module can be introduced into or out of the tank 200.
- the filtering device of the present invention may further include a lid 300 for covering the upper opening of the tank 200.
- FIG. 2 is a cross sectional view along line AA ′ of the tank illustrated in FIG. 1;
- the tank 200 of the present invention has a first stepped surface 211 therein and a second stepped surface 212 on an opposite side of the first stepped surface 211.
- An inner space of the tank 200 may be divided into an upper space above and a lower space below the first and second stepped surfaces 211 and 212. That is, the tank 200 of the present invention includes an upper space and a lower space.
- the horizontal cross-sectional area of the upper space of the tank 200 is larger than the horizontal cross-sectional area of the lower space.
- a collecting space 220 for the production water penetrating the hollow fiber membrane Directly below the first stepped surface 211 of the tank 200 is provided a collecting space 220 for the production water penetrating the hollow fiber membrane, the production water flowing into the collecting space 220 is discharge port 221 Is discharged through.
- the tank 200 of the present invention may further include an overflow discharge port 260 for discharging excess raw water out of the tank 200 when raw water flowing through the raw water inlet 230 exceeds a predetermined level. have.
- FIG. 3 is a perspective view of the hollow fiber membrane module 100 according to an embodiment of the present invention
- Figure 4 is a cross-sectional view along the line II 'of the hollow fiber membrane module 100 of FIG.
- the hollow fiber membrane module 100 includes a first hollow fiber membrane 130 between the first header 110, the second header 120, and the first and second headers 110 and 120. It includes. According to an embodiment of the present invention, the length L1 of the first header 110 is longer than the length L2 of the second header 120.
- the second header 120 is positioned below the first header 110, and the hollow fiber membrane 130 is arranged such that its longitudinal direction is perpendicular to the surface of the water.
- Polymer resin that can be used in the production of the hollow fiber membrane 130 of the present invention is polysulfone resin, polyethersulfone resin, sulfonated polysulfone resin, polyvinylidene fluoride (PVDF) resin, polyacrylonitrile (PAN) resin , Polyimide resin, polyamideimide resin, and polyesterimide resin.
- the hollow fiber membrane 130 may be in the form of a single membrane or a composite membrane.
- the hollow fiber membrane 130 may include a tubular braid and a polymer thin film coated on the surface thereof.
- the tubular braid may be made of polyester or nylon.
- the hollow fiber membrane module 100 when the hollow fiber membrane module 100 is mounted in the tank 200, only the first header 110 of the hollow fiber membrane module 100 has tanks at the first and second end portions 111 and 112. It is supported by the first and second stepped surfaces 211 and 212 of the 200 and the second header 120 is not directly connected to the tank 200 so that it can move relatively freely. To explain). That is, when the water treatment operation is performed while the plurality of hollow fiber membrane modules 100 are mounted in the tank 200, collision between adjacent second headers 120 may occur, and such collision may continue. In this case, damage to the vertical membrane modules 100 may be caused.
- the hollow fiber membrane module 100 of the present invention may include the first and second headers 110. It further comprises a support 150 for connecting and supporting 120.
- the support 150 may include the first and second headers 110 and 120 in such a manner that a distance between the first and second headers 110 and 120 may vary within a predetermined range. ). Two supports 150 may be fastened with fastening members 160 at both ends of the first and second headers 110 and 120, respectively.
- one end of the support 150 is inserted into the groove formed in the first header 110 and then fixed with the fastening member 160. That is, the first header 110 is a fixed header fastened so that the support 150 can not move relatively.
- the second header 120 is a moving header fastened so that the support 150 can be moved relatively. Accordingly, the distance between the first and second headers 110 and 120 is increased by moving the second header 120 relative to the support 150 while the first header 110 is fixed to the support 150. It may vary within a predetermined range.
- the headers 110 having both ends of the hollow fiber membrane 130 ported without artificial adjustment from the outside of the module 100 may be ported.
- 120 may be spontaneously narrowed according to the degree of contraction of the hollow fiber membrane 130.
- the fastening member 160 inserted into and fixed to the second header 120, which is a moving header, is guided by the slit S of the support 150 to be within the length range of the slit S, that is, 0.5 of the hollow fiber membrane 130 length. It is possible to move relative to the support 150 in the range of 3 to 3%. In other words, the support 150 may move relative to the second header 120 and the fastening member 160, and the guide member 122 guides the relative movement of the support 150.
- the second header 120 which is a moving header, has a guide member 122 for guiding the relative movement of the support 150, but the guide member 122 is merely optional. It does not limit the invention as such. That is, the second header 120 may be configured of only the main body without the guide member, and the fastening member 160 may be inserted into and fixed to the main body through the slit S of the support 150. In this case, the fastening member 160 has a second header 120 and the support 150, which are moving headers, in addition to the body 161 that is inserted and fixed to the header body 121 through the slit S of the support 150. Head 162 may be included to prevent separation.
- the fastening member 160 inserted into and fixed to the support 150 may be guided by the slit S of the guide member 122 to move relative to the guide member 122 within the length range of the slit S. have. At this time, the guide member 122 guides the relative movement of the support 150.
- the fastening member 160 may include a body 161 and a head 162.
- the body 161 of the fastening member 160 is inserted and fixed to the support 150 through the slit S of the guide member 122.
- the head 162 of the fastening member 160 prevents the guide member 122 and the support 150 from being separated.
- the moving header includes a header body 125 and a guide member 126 located at its distal end.
- An open slit S is formed in the guide member 126.
- the support 150 includes a protrusion 151 at its distal end.
- the protrusion 151 of the support 150 is inserted into the slit S through the open portion of the slit S of the guide member 126. . Subsequently, the guide member 126 and the support 150 are separated from each other to prevent the protrusion 151 of the support 150 from being separated through the opened portion of the slit S of the guide member 126.
- a stopper 172 is coupled to the header body 125 and the guide member 126 to prevent it.
- the protrusion 151 of the support 150 may be guided by the slit S of the guide member 126 to move relative to the guide member 126 and the second header 120. Will be. That is, the moving header can move relative to the first header 110 into which the support 150 is inserted and fixed.
- the stopper 171 for preventing the moving header 123 and the support 150 from being separated is formed in the groove. (G) is coupled to the side of the formed moving header 123.
- the protrusion 151 of the support 150 may be guided by the groove G of the moving header 123 to move relative to the moving header 123. That is, the moving header 123 may move relative to the first header 110 into which the support 150 is inserted and fixed.
- the moving header includes a header body 121 and a protrusion 127 on the side of the header body 121.
- a slit S into which the projection 127 of the moving header is inserted.
- 10 and 11 are cross-sectional views along the line AA ′ and B-B ′ of the filtration device of FIG. 1.
- the distance between the headers 110 and 120 in which both ends of the hollow fiber membrane 130 are ported is variable. Therefore, by introducing the hollow fiber membrane module 100 into the tank 200 in the absence of the deflection of the hollow fiber membrane 130, it is possible to prevent membrane damage due to a bump against the neighboring module or the tank wall. Even if the shrinkage of the hollow fiber membrane 130 occurs during the water treatment operation, the gap between the headers 110 and 120 on which both ends of the hollow fiber membrane 130 are ported is automatically narrowed according to the shrinkage degree of the hollow fiber membrane 130. Damage to the module 100 due to shrinkage can be prevented.
- a hole H is formed in the first stepped surface 211 of the tank 200, and the discharge port OP of the first header 110 is inserted into the hole H of the first stepped surface 211.
- the first header 110 is in fluid communication with the catchment space 220 of the tank 200. Therefore, the production water passing through the hollow fiber membrane 130 flows through the hollow and the first header 110 collecting space of the hollow fiber membrane 130 to the collecting space 220 of the tank 200.
- the O-ring is interposed between the outer circumferential surface of the discharge port OP of the first header 110 and the inner circumferential surface of the hole H of the first stepped surface 211 so that untreated raw water is collected in the tank 200 ( 220 may be prevented from entering.
- the second header 120 of the hollow fiber membrane module 100 when the hollow fiber membrane module 100 is mounted in the tank 200 through an opening in the upper portion of the tank 200, the second header 120 of the hollow fiber membrane module 100 is The length L2 of the second header 120 is short enough to pass through the first and second stepped surfaces 211 and 212 of the tank 200.
- the length L1 of the first header 110 of the hollow fiber membrane module 100 is long enough to be simultaneously supported by the first and second stepped surfaces 211 and 212. That is, the length L1 of the first header 110 of the hollow fiber membrane module 100 is longer than the length L2 of the second header 120.
- FIG. 12 illustrates a method in which the second distal end 112 of the first header 110 of the hollow fiber membrane module 100 is fixed to the second step surface 212 of the tank 200 according to another embodiment of the present invention. do.
- the second end portion 112 of the first header 110 is provided.
- the second end portion 112 is fixed to the second stepped surface 212 by the fastening means 510.
- a fastening hole 112a through which the fastening means 510 may be inserted is formed at the second end portion 112 of the first header 110.
- the second header 120 is moved up and down within the length range of the slit S, i.e., 0.5 to 3% of the length of the hollow fiber membrane 130 due to the bubbles ejected from the diffuser 400 and rising. Will vibrate.
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- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
Claims (24)
- 처리되어야 할 원수(feed water)가 유입되는 탱크 - 상기 탱크는 그 내부에 제1 단차면, 및 상기 제1 단차면의 반대 측에 제2 단차면을 가짐 - ; 및상기 탱크 내에 유입된 원수에 침지되는 중공사막 모듈 - 상기 중공사막 모듈은 제1 및 제2 헤더들과 이들 사이의 중공사막을 포함함 - 을 포함하되,상기 제1 헤더의 제1 및 제2 말단부들이 상기 제1 및 제2 단차면들에 의해 각각 지지되는 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 제1 헤더의 길이는 상기 제2 헤더의 길이보다 긴 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 탱크는 상기 제1 및 제2 단차면들 위의 상부 공간과 상기 제1 및 제2 단차면들 아래의 하부 공간을 포함하고,상기 상부 공간의 수평 단면적은 상기 하부 공간의 수평 단면적보다 큰 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 탱크는 상기 중공사막 모듈에 의해 생산된 투과수를 위한 집수공간을 포함하는 것을 특징으로 하는 여과 장치.
- 제 4 항에 있어서,상기 탱크의 집수공간은 상기 중공사막 모듈의 상기 제1 헤더보다 낮은 위치에 있는 것을 특징으로 하는 여과 장치.
- 제 4 항에 있어서,상기 제1 단차면에는 홀이 형성되어 있고,상기 제1 헤더의 제1 말단부가 상기 제1 단차면의 홀에 삽입됨으로써 상기 제1 헤더가 상기 탱크의 집수공간과 유체 연통하는 것을 특징으로 하는 여과 장치.
- 제 6 항에 있어서,상기 제1 헤더의 제2 말단부는 상기 제2 단차면에 체결수단에 의해 고정되는 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 제1 및 제2 단차면들에는 상기 제1 헤더의 제1 및 제2 말단부들의 형태 및 크기에 대응하는 홈들이 각각 형성된 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 탱크는 그 하부에 상광하협 형태의 슬러지 배출부를 포함하는 것을 특징으로 하는 여과 장치.
- 제 1 항에 있어서,상기 탱크는, 상기 유입되는 원수가 소정 수위를 초과할 경우 초과되는 원수를 상기 탱크 밖으로 배출하기 위한 오버플로우 배출구를 포함하는 것을 특징으로 하는 여과 장치.
- 내부에 집수 공간을 갖는 제1 헤더;제1 고정층을 통해 일단이 상기 제1 헤더에 포팅되어 있으며, 상기 제1 헤더의 집수 공간과 유체 연통하는 중공사막;수 처리 작업 중에 상기 제1 헤더의 하방에 위치하며 상기 중공사막의 타단이 제2 고정층을 통해 포팅되어 있는 제2 헤더; 및상기 제1 및 제2 헤더들 사이의 거리가 소정의 범위 내에서 가변될 수 있는 방식으로 상기 제1 및 제2 헤더들을 지지하는 지지체를 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 11 항에 있어서,상기 제1 및 제2 헤더들 중 적어도 하나는 상기 지지체가 상대적 이동이 가능하도록 체결된 이동 헤더인 것을 특징으로 하는 중공사막 모듈.
- 제 12 항에 있어서,상기 지지체에는 슬릿이 형성되어 있고,상기 중공사막 모듈은 상기 슬릿을 관통하여 상기 이동 헤더에 삽입 고정되는 체결부재를 더 포함하며,상기 체결부재는 상기 지지체의 슬릿에 의해 안내되어 상기 지지체에 대해 상대적 이동을 할 수 있는 것을 특징으로 하는 중공사막 모듈.
- 제 13 항에 있어서,상기 체결부재는,상기 슬릿을 관통하여 상기 이동 헤더에 삽입 고정되는 바디; 및상기 이동 헤더와 상기 지지체가 분리되는 것을 방지하기 위한 헤드를 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 12 항에 있어서,상기 이동 헤더는 상기 지지체의 상대적 이동을 안내하기 위한 가이드 부재를 포함하고,상기 지지체는 상기 가이드 부재에 삽입되는 것을 특징으로 하는 중공사막 모듈.
- 제 15 항에 있어서,상기 가이드 부재에는 슬릿이 형성되어 있고,상기 중공사막 모듈은 상기 가이드 부재의 슬릿을 통해 상기 지지체에 삽입되는 체결부재를 더 포함하며,상기 체결부재는 상기 가이드 부재의 슬릿에 의해 안내되어 상기 가이드 부재에 대해 상대적 이동을 할 수 있는 것을 특징으로 하는 중공사막 모듈.
- 제 16 항에 있어서,상기 체결부재는,상기 가이드 부재의 슬릿을 통해 상기 지지체에 삽입되는 바디; 및상기 가이드 부재와 상기 지지체가 분리되는 것을 방지하기 위한 헤드를 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 15 항에 있어서,상기 지지체는 돌기를 포함하고,상기 가이드 부재에는 상기 지지체의 돌기가 삽입되는 슬릿이 형성되어 있으며,상기 지지체의 돌기는 상기 가이드 부재의 슬릿에 의해 안내되어 상기 가이드 부재에 대해 상대적 이동을 할 수 있는 것을 특징으로 하는 중공사막 모듈.
- 제 18 항에 있어서,상기 가이드 부재와 상기 지지체가 분리되는 것을 방지하기 위한 스토퍼를 더 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 12 항에 있어서,상기 지지체는 돌기를 포함하고,상기 이동 헤더의 측면에는 상기 지지체의 돌기가 삽입되는 홈이 형성되어 있고,상기 홈은 상기 지지체의 길이 방향을 따라 길게 연장되어 형성되어 있으며,상기 지지체의 돌기는 상기 홈에 의해 안내되어 상기 이동 헤더에 대해 상대적 이동을 할 수 있는 것을 특징으로 하는 중공사막 모듈.
- 제 20 항에 있어서,상기 이동 헤더와 상기 지지체가 분리되는 것을 방지하기 위한 스토퍼를 더 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 12 항에 있어서,상기 이동 헤더는 돌기를 포함하고,상기 지지체에는 상기 이동 헤더의 돌기가 삽입되는 슬릿이 형성되어 있으며,상기 이동 헤더의 돌기는 상기 지지체의 슬릿에 의해 안내되어 상기 지지체에 대해 상대적 이동을 할 수 있는 것을 특징으로 하는 중공사막 모듈.
- 제 22 항에 있어서,상기 이동 헤더와 상기 지지체가 분리되는 것을 방지하기 위하여 상기 지지체의 슬릿을 통과하여 돌출된 상기 돌기의 말단부에 장착되는 스토퍼를 더 포함하는 것을 특징으로 하는 중공사막 모듈.
- 제 11 항에 있어서,상기 제1 헤더의 길이가 상기 제2 헤더의 길이보다 긴 것을 특징으로 하는 중공사막 모듈.
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JP2013558791A JP5797285B2 (ja) | 2011-03-16 | 2012-03-16 | ろ過装置及びそのための中空糸膜モジュール |
US14/004,769 US20140027360A1 (en) | 2011-03-16 | 2012-03-16 | Filtration apparatus and hollow fiber membrane module therefor |
CN201280013456.0A CN103442789B (zh) | 2011-03-16 | 2012-03-16 | 过滤设备和用于该过滤设备的中空纤维膜模块 |
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KR1020110029613A KR101818415B1 (ko) | 2011-03-31 | 2011-03-31 | 중공사막 모듈 및 이것이 장착된 여과 장치 |
KR10-2011-0029613 | 2011-03-31 | ||
KR10-2011-0030017 | 2011-04-01 | ||
KR1020110030017A KR101777554B1 (ko) | 2011-03-16 | 2011-04-01 | 여과 장치 및 이를 위한 중공사막 모듈 |
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JP2015536825A (ja) * | 2012-12-28 | 2015-12-24 | コーロン インダストリーズ インク | ろ過装置 |
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WO2018101557A1 (ko) * | 2016-11-30 | 2018-06-07 | 두산중공업 주식회사 | 막 여과 시스템 및 이를 포함하는 막 생물반응기 |
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