WO2012121651A1 - Gaz d'appoint et de protection pour matériaux de fenêtre de passage de lumière et pour une amélioration de la résolution spatiale en chromatographie en phase gazeuse - détection d'uv - Google Patents
Gaz d'appoint et de protection pour matériaux de fenêtre de passage de lumière et pour une amélioration de la résolution spatiale en chromatographie en phase gazeuse - détection d'uv Download PDFInfo
- Publication number
- WO2012121651A1 WO2012121651A1 PCT/SE2012/050245 SE2012050245W WO2012121651A1 WO 2012121651 A1 WO2012121651 A1 WO 2012121651A1 SE 2012050245 W SE2012050245 W SE 2012050245W WO 2012121651 A1 WO2012121651 A1 WO 2012121651A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- light
- flow
- absorbing chamber
- light absorbing
- Prior art date
Links
- 238000004817 gas chromatography Methods 0.000 title claims abstract description 9
- 230000001681 protective effect Effects 0.000 title claims description 8
- 239000000463 material Substances 0.000 title description 6
- 238000001514 detection method Methods 0.000 title description 5
- 239000000126 substance Substances 0.000 claims abstract description 28
- 238000010521 absorption reaction Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000011002 quantification Methods 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 105
- 239000013307 optical fiber Substances 0.000 claims description 14
- 238000007865 diluting Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims 1
- 230000008859 change Effects 0.000 description 4
- 210000001072 colon Anatomy 0.000 description 4
- 230000031700 light absorption Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000002503 metabolic effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 206010013654 Drug abuse Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000007107 Stomach Ulcer Diseases 0.000 description 1
- 230000032912 absorption of UV light Effects 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910052805 deuterium Inorganic materials 0.000 description 1
- 206010012601 diabetes mellitus Diseases 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 208000020016 psychiatric disease Diseases 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/74—Optical detectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/15—Preventing contamination of the components of the optical system or obstruction of the light path
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/15—Preventing contamination of the components of the optical system or obstruction of the light path
- G01N2021/151—Gas blown
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/33—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
- G01N2021/335—Vacuum UV
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/74—Optical detectors
- G01N2030/746—Optical detectors detecting along the line of flow, e.g. axial
Definitions
- the present invention relates Gas Chromatography, GC - Ultraviolet absorption, UV - spectroscopy, GC-UV, to detect, identify and analyse gases, liquids and solid known and unknown substances from high to very low
- concentrations and is directed to a method and an apparatus for obtaining photonic signal levels and spatial resolution from samples in gas phase of substances in a first flow of gas by a first step comprising selection by time by gas chromatography and by a second step comprising absorption of photons by UV light down to 120 nm of wavelength that passes a light absorbing chamber for identification and quantification of substances.
- the basic technology is known and used for various purposes. Such solutions are disclosed in US6305213 and US4668091 , Verner Lüsson et. al.
- the invention relates to physical, mechanical and software control solutions.
- the invention solves one of the major problems to achieve in order to detect absorption of very short wavelengths (typically down to 120nm) for identification of unknown substances in gas phase.
- Gas chromatography UV - spectroscopy is used for identification and quantification of various substances that can be transformed into gas.
- the technology is based on that substances in gas phase first passes through a heated column where the gas has a substance dependent velocity through the column and when the gas to be analyzed leaves the first heated column and enters a chamber where UV light passes the gas, absorb light when the light passes the gas, in a spectral way, so the photonic spectrum relates with very high accuracy to the identity of the substance.
- the light used for the absorption shall preferably have a broad spectrum of wavelengths to allow absorption over a broad spectrum of wavelengths.
- the passage, chamber, where light penetrates the gas shall be designed to have the gas absorb as much light as possible and to achieve maximum resolution in the analysis, the cross section area and the chamber volume shall be kept as small as possible.
- the chamber shall be heated to have the substances in gas phase to remain in gas phase and not sublimate.
- the process is basically a gas chromatography apparatus where a chamber with a light path is added in the end of the column so the separated gas components eluting from the gas chromatograph passes through the chamber and absorbs light with a spectrum that is related to the gas.
- the remaining lights then passes into a spectrograph and further on to a light sensitive sectioned array preferably a CCD, Charge Coupled Device, so the spatial light components hits individual light sensitive elements enabling spatial detection of the light and thereby allows identification of the substance to be analyzed.
- a light sensitive sectioned array preferably a CCD, Charge Coupled Device
- Materials used in such windows can be made of MgF 2 or material with similar optical properties with the drawback like of being sensitive to rapid degradation and consequently loss of transparency and other optical properties if exposed to various chemical substances.
- Any physical window acts as a filter of passing photons in particular for short wavelength photons. It is also important to keep the spectrograph, its dispersive element and photon sensitive array clean from contamination like particles and residuals from gases, like sublimated matter from gas in order to keep the functionality of the spectrograph.
- a drawback with prior art is that a physical window has to be cleaned or replaced regularly due to contamination if not being protected by any means. Another issue is measurements with GC-UV, as substances in gas phase enter the light absorbing chamber, is that several substances can protrude the chamber almost with the same velocity and at the same time reducing the ability the physical separation and thereby reducing the ability to chemical identification and quantification.
- An object of the present invention is to eliminate at least one of the drawbacks mentioned above, which is achieved by assigning to the
- the invention is very versatile and can be used in various applications such as hand held portable and laboratory based bench top instruments.
- One particular use is for detection of metabolic or other substances emanating from living cells, tissues and in particular that can be found in exhaled air, saliva, sweat, blood and urine from humans, animals, organisms and plants etc. for detection of various deceases and metabolic activities for example caused by stress.
- Substances can be such as nitrogen oxide, urea, acetone, isoprene, carbon disulfide coming from diseases like gastric ulcers, asthma, diabetes, psychiatric disorders, drug abuse, stress conditions and intoxications, etc.
- Many of those metabolic substances in gas phase have significant high absorption of UV light in a spectrum ranging from about 120 nm wave length and longer.
- the light entrance to the spectrograph is provided with a physical solid barrier like a physical window that has the transparency for UV light from 130 nm wave length with a prevention of gas to be analyzed to come in contact with the window by a flow over the window with gas such as N, He, H or other gases that leaves the window material unaffected.
- gas such as N, He, H or other gases that leaves the window material unaffected.
- a similar solution can be used to protect a similar window close to the light source in the light path where UV light enters a light absorbing chamber.
- a similar solution can be used to protect a similar window close to the light source in the light path where UV light enters a light absorbing chamber.
- injected flush gas at the light entrance to the light absorption chamber can be used to change, increase the speed of gas to be analyzed through the light absorption chamber and thereby change the separation ability of the substances better from each other and thereby change and also increase the spatial resolution.
- Such separation can be made nonlinear to the velocity of the gas to be analyzed entering the light absorption chamber and can vary over time by change of pressure and flow of this, the make-up gas.
- the gas that is used for protecting the windows can simultaneously also be used for diluting and increasing the speed of gas through the light absorbing chamber, in relation to the source of the gas, to shorten the time in the light absorption chamber for the gas to be analyzed and thereby increase spectral - spatial resolution of the readout in the spectrometer.
- This can be referred to as make up gas.
- gas used for protecting the window of the light source can simultaneously also be used for flushing through the spectrometer to produce a gas flow of the same make up gas or other with similar properties, in opposite direction to the gas to be analyzed approaching the spectrometer trough the light pipe, to eliminate the flow of gas to be analyzed to enter the spectrometer or reach the window to the spectrometer.
- the same type of gas can be simultaneously used for all the above functions or different types of gas can be used for the different aspects of the invention.
- Different pressure at the different locations directs the flow of gas in a desired way from locations with higher pressure to locations with lower pressure. Protection by a gas that flushes the windows preventing the substances to be analyzed in gas phase to reach the surfaces of the windows facing light absorbing chamber in GC-UV applications.
- Fig. 1 is a schematic view of a first embodiment of an apparatus in accordance with the invention.
- Fig. 2 is a schematic view of a second embodiment of an apparatus in accordance with the invention.
- Fig. 1 shows schematically a set up comprising a gas chromatograph (13), a UV-light source (6) connected to a first end of an elongated light absorbing chamber or pipe (3).
- the UV light source (6) is a deuterium lamp.
- a spectrometer (1 ) is arranged with an opening without a protective window.
- the elongated light absorbing chamber (3) shown in Fig. 1 is a light pipe of hollow core type. It can be provided with an Al reflective mirror on the inside or be made of quarts or as a further alternative be made of sapphire.
- said elongated light absorbing chamber or pipe (3) is enclosed in a heated body (9) capable of providing a temperature of 50 - 280 °C.
- a gas chromatograph colon (13) is connected with a pipe (8) to said first end of said elongated light absorbing chamber (3) for injecting gas to be analyzed from said gas chromatograph colon (13) in close proximity to the light source (6).
- a gas distribution control and gas flow regulator (12) provides a flow of gas to said spectrometer (1) preventing gas from said gas chromatograph colon (13) from entering said spectrometer (1 ) since the gas from said spectrometer (1 ) has an opposite direction of flow relative the gas to be analyzed from said gas chromatograph colon (13).
- a window (5) which can be formed as a lens, is arranged as a protection over said UV-light source (6).
- the lens (5) can be made of synthetic fused silica alternative sapphire.
- Said gas distribution control and gas flow regulator (12) also provides a flush gas flow through an inlet (7) at a first end of said elongated light absorbing chamber (3) in order to prevent the gas to be analyzed to reach the window (5) of the UV light source (6).
- the flow of gas through the inlet (7) can be 0.5 - 10 ml/min.
- a second optical fiber (2) connects a second end of said elongated light absorbing chamber (3) to the opening of said spectrometer (1 ).
- said first optical fiber (4) and said second optical fiber (2) are hollow core type fibers typically made of quarts or silica.
- a light path formed by said first optical fiber (4), said elongated light absorbing chamber (3) and said second optical fiber (2) guides light from said UV-light source (6) to said spectrometer (1 ).
- a gas flow output (10) is provided at the second end of said elongated light absorbing chamber (3).
- the embodiment shown in Fig. 2 basically comprises the same components as the embodiment shown in Fig. 1. However, the embodiment shown in Fig. 2 a spectrometer (1) is arranged with an opening covered by a protective window (15). The second optical fiber (2) extends between the second end of said elongated light absorbing chamber (3) and said protective window (15) and is provided with an extension.
- a gas pipe (14) is connected to said gas distribution control and gas flow regulator (12) to receive a flow of gas that is directed to the extension of said protective window (15). The gas to be analyzed is prevented from reaching the protective window (15) to the spectrometer (1) by a flow of another gas through the pipe (14) has an opposite direction of flow relative the gas to be analyzed.
- the embodiment of the invention shown in Fig. 2 is directed to a method and an apparatus of increasing the long term transparency of light windows of very and increase spatial resolution of read out of short wavelengths, such as 130nm and up, photons in GC-UV applications.
- a spectrograph (1 ) is arranged with a slit where light enters and a dispersive element that reflects the fractioned light.
- a spectrometer is a spectrograph that has a photon collecting device to collect the fractioned light for read out and measurement of spectra.
- the Photon collecting device can be a CCD - Charge Collecting Device.
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
L'invention concerne un procédé et un appareil qui servent à obtenir des niveaux de signaux photoniques et une résolution spatiale à partir d'échantillons en phase gazeuse de substances dans un premier flux de gaz. La présente invention comporte une première étape consistant en la sélection temporelle par chromatographie en phase gazeuse et une deuxième étape consistant en l'absorption de photons par de la lumière ultraviolette jusqu'à une longueur d'ondes de 120 nm qui traverse une chambre d'absorption de lumière afin d'identifier et de quantifier des substances. Un deuxième flux d'un gaz supplémentaire, différent desdits échantillons en phase gazeuse, est dirigé sur des fenêtres de source lumineuse à l'intérieur de la chambre d'absorption de lumière afin de protéger lesdites fenêtres de source lumineuse et d'empêcher que lesdites fenêtres de source lumineuse n'entrent en contact avec les échantillons en phase gazeuse à analyser. L'appareil est constitué d'un chromatographe en phase gazeuse (13) et d'une source de lumière ultraviolette (6) connectée à une chambre d'absorption de lumière allongée (3) servant à l'identification et la quantification de substances. Il comprend en outre une fenêtre (5) sur ladite source de lumière ultraviolette (6) et un régulateur de flux gazeux (12) qui dirige un deuxième flux d'un gaz supplémentaire, différent desdits échantillons en phase gazeuse, à travers une entrée (7) sur ladite fenêtre (5).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US201161449648P | 2011-03-05 | 2011-03-05 | |
US61/449,648 | 2011-03-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012121651A1 true WO2012121651A1 (fr) | 2012-09-13 |
Family
ID=46062712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE2012/050245 WO2012121651A1 (fr) | 2011-03-05 | 2012-03-05 | Gaz d'appoint et de protection pour matériaux de fenêtre de passage de lumière et pour une amélioration de la résolution spatiale en chromatographie en phase gazeuse - détection d'uv |
Country Status (1)
Country | Link |
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WO (1) | WO2012121651A1 (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014062419A1 (fr) | 2012-10-18 | 2014-04-24 | Vuv Analytics, Inc. | Système de spectroscopie d'absorption dans l'ultraviolet sous vide et procédé associé |
WO2014128180A1 (fr) | 2013-02-20 | 2014-08-28 | Chromalytica Ab | Diode électroluminescente ultraviolette utilisée comme source de lumière en chromatographie en phase gazeuse-spectrophotométrie d'absorption uv |
WO2014170384A1 (fr) * | 2013-04-17 | 2014-10-23 | Chromalytica Ab | Unité de désorption thermique directe liée à une chromatographie en phase gazeuse - détection en ultraviolet (uv) |
US10677767B2 (en) | 2018-06-12 | 2020-06-09 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
CN114878496A (zh) * | 2022-04-16 | 2022-08-09 | 国网江苏省电力有限公司超高压分公司 | 基于紫外吸收光谱的环形光纤sf6分解产物检测装置与方法 |
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Cited By (17)
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EP3410097A1 (fr) * | 2012-10-18 | 2018-12-05 | Vuv Analytics, Inc. | Procédé de spectroscopie d'absorption d'ultraviolets sous vide |
US9976996B2 (en) | 2012-10-18 | 2018-05-22 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
JP2016183972A (ja) * | 2012-10-18 | 2016-10-20 | ブイユーブイ・アナリティクス・インコーポレイテッドVUV Analytics,Inc. | 真空紫外吸収分光システム |
US9116158B2 (en) | 2012-10-18 | 2015-08-25 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
US9696286B2 (en) | 2012-10-18 | 2017-07-04 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
US10641749B2 (en) | 2012-10-18 | 2020-05-05 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
EP2909600A4 (fr) * | 2012-10-18 | 2016-09-14 | Vuv Analytics Inc | Système de spectroscopie d'absorption dans l'ultraviolet sous vide et procédé associé |
US9891197B2 (en) | 2012-10-18 | 2018-02-13 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
US10338040B2 (en) | 2012-10-18 | 2019-07-02 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
WO2014062419A1 (fr) | 2012-10-18 | 2014-04-24 | Vuv Analytics, Inc. | Système de spectroscopie d'absorption dans l'ultraviolet sous vide et procédé associé |
US9465015B2 (en) | 2012-10-18 | 2016-10-11 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
JP2016507068A (ja) * | 2013-02-20 | 2016-03-07 | クロマリティカ エービー | 試料を分析するための新しい装置および方法、ならびにその使用 |
CN105308450A (zh) * | 2013-02-20 | 2016-02-03 | 克罗马利蒂卡有限责任公司 | 作为气相色谱-uv吸收光谱中的光源的uv发光二极管 |
WO2014128180A1 (fr) | 2013-02-20 | 2014-08-28 | Chromalytica Ab | Diode électroluminescente ultraviolette utilisée comme source de lumière en chromatographie en phase gazeuse-spectrophotométrie d'absorption uv |
WO2014170384A1 (fr) * | 2013-04-17 | 2014-10-23 | Chromalytica Ab | Unité de désorption thermique directe liée à une chromatographie en phase gazeuse - détection en ultraviolet (uv) |
US10677767B2 (en) | 2018-06-12 | 2020-06-09 | Vuv Analytics, Inc. | Vacuum ultraviolet absorption spectroscopy system and method |
CN114878496A (zh) * | 2022-04-16 | 2022-08-09 | 国网江苏省电力有限公司超高压分公司 | 基于紫外吸收光谱的环形光纤sf6分解产物检测装置与方法 |
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