WO2012105453A1 - Filter for cigarette and cigarette with filter - Google Patents

Filter for cigarette and cigarette with filter Download PDF

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Publication number
WO2012105453A1
WO2012105453A1 PCT/JP2012/051839 JP2012051839W WO2012105453A1 WO 2012105453 A1 WO2012105453 A1 WO 2012105453A1 JP 2012051839 W JP2012051839 W JP 2012051839W WO 2012105453 A1 WO2012105453 A1 WO 2012105453A1
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WO
WIPO (PCT)
Prior art keywords
fragrance
filter
cigarette
releasing
pure
Prior art date
Application number
PCT/JP2012/051839
Other languages
French (fr)
Japanese (ja)
Inventor
弘 四分一
Original Assignee
日本たばこ産業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本たばこ産業株式会社 filed Critical 日本たばこ産業株式会社
Priority to EP12741795.4A priority Critical patent/EP2671461A4/en
Priority to CN201280007566.6A priority patent/CN103458718B/en
Priority to RU2013140541/12A priority patent/RU2575450C2/en
Priority to JP2012555843A priority patent/JP5453553B2/en
Publication of WO2012105453A1 publication Critical patent/WO2012105453A1/en
Priority to US13/957,793 priority patent/US20130312778A1/en

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/048Tobacco smoke filters characterised by their shape or structure containing additives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/283Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
    • A24B15/284Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances the additive being bound to a host by chemical, electrical or like forces, e.g. use of precursors, inclusion complexes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking

Definitions

  • the present invention relates to a cigarette filter and a cigarette with a filter.
  • Cigarettes equipped with a tobacco filter incorporating a yarn containing a tobacco smoke modifier are known (for example, Patent Documents 1 and 2).
  • the tobacco smoke modifier may add flavor or aroma into the tobacco mainstream smoke passing through the filter.
  • An object of the present invention is to provide a cigarette filter and a cigarette provided with such a filter that make it possible to taste a different scent for each puff when the cigarette is smoked.
  • a fragrance release member comprising a filter body, a fragrance carrier comprising one or more individual yarns, and a plurality of fragrance release components carried on the fragrance carrier, and the fragrance release.
  • the member is incorporated into the filter body so as to extend along the central axis of the filter body, and one fragrance release component emits a fragrance fragrance different from the other one or more fragrance release components,
  • the fragrance release behavior of the fragrance release component is different from the fragrance release behavior of one or more other fragrance release components, said fragrance release component combined with pure fragrance, pure fragrance combined with cyclodextrin and dextrin
  • a cigarette filter selected from the group consisting of pure fragrances is provided.
  • a cigarette with a filter including a cigarette rod and a filter connected to one end of the cigarette rod, wherein the filter is constituted by the filter of the present invention.
  • the cigarette filter of the present invention makes it possible to taste a different scent for each puff when smoking a cigarette.
  • a cigarette filter includes a filter main body, a fragrance release member including a fragrance carrier composed of at least one individual yarn, and a plurality of fragrance release components carried on the fragrance carrier.
  • the aroma release member is incorporated in the filter body so as to extend along the central axis of the filter body.
  • One scent-releasing component releases a different perfume scent than the other one or more scent-releasing components.
  • the fragrance release behavior of one fragrance release component is different from the fragrance release behavior of one or more other fragrance release components.
  • the fragrance releasing component is selected from the group consisting of pure fragrance, pure fragrance combined with cyclodextrin, and pure fragrance combined with dextrin.
  • the filter body into which the fragrance releasing member is incorporated includes, for example, cellulose acetate fiber tow and is usually cylindrical.
  • the length of the filter body is usually 100 mm to 140 mm, and the diameter is usually 15 mm to 26 mm.
  • the fragrance release member includes a fragrance carrier made of at least one individual yarn and a plurality of fragrance release components carried on the fragrance carrier.
  • the fragrance release member may comprise a fragrance carrier and a plurality of fragrance release components.
  • the yarn constituting the fragrance carrier can be composed of a single fiber (filament) or a bundle of a plurality of fibers (filament), and includes monofilament yarn and multifilament yarn.
  • the multifilament yarn includes various processed yarns.
  • Thread material is not particularly limited.
  • the yarn can be made of a natural material such as cotton, wool or silk, or a synthetic material such as polypropylene, polyethylene or cellulose acetate.
  • the diameter of the yarn is usually 0.3 to 2.5 mm, preferably 0.7 mm to 1.5 mm.
  • the length of the yarn is usually the same as the length of the filter body.
  • the yarn typically extends along the central axis of the filter body over the entire length of the filter body, i.e., from the distal end to the proximal end of the filter body.
  • the filter body is provided with a filter whose outer periphery is wound by a filter wrapper such as thin paper.
  • the aroma releasing component is selected from the group consisting of (i) pure fragrance, (ii) pure fragrance combined with cyclodextrin, and (iii) pure fragrance combined with dextrin.
  • Pure fragrance is the fragrance itself.
  • pure flavors include acetanisole, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract, amyl alcohol, amyl butyrate, trans-anethole, star anise oil, apple juice, peruvian balsam oil, beeswax absolute, benzaldehyde, Benzoin resinoid, benzyl alcohol, benzyl benzoate, benzyl phenylacetate, benzyl propionate, 2,3-butanedione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamom oil, carob brolute, ⁇ -carotene, carrot juice, L Carvone, ⁇
  • the fragrance-releasing component consisting of pure fragrance can be supported on the yarn by dissolving it in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. and soaking the solution into the yarn.
  • the fragrance-releasing component consisting of pure fragrance combined with cyclodextrin is suspended in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. It can be supported on.
  • An emulsifier such as a sucrose fatty acid ester, a dispersant, and an antifoaming agent can be added to the suspension.
  • a fragrance-releasing component consisting of pure fragrance combined with dextrin is suspended in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. It can be carried on a yarn.
  • An emulsifier such as a sucrose fatty acid ester, a dispersant, and an antifoaming agent can be added to the suspension.
  • a fragrance-releasing component consisting of a pure fragrance combined with dextrin is optionally added to an aqueous solution of dextrin in which an emulsifier is dissolved, emulsified with a homomixer, sprayed using a spray dryer, and dried. By doing so, it can be obtained in the form of a fine powder of dextrin containing a fragrance.
  • One fragrance-releasing component releases a fragrance fragrance different from one or more other fragrance-releasing components. That is, the pure fragrance contained in one fragrance-releasing component is a fragrance that emits a different fragrance from the pure fragrance contained in one or more other fragrance-releasing components.
  • the fragrance release behavior of one fragrance release component is different from the fragrance release behavior of one or more other fragrance release components.
  • the fragrance-releasing component made of pure fragrance releases the fragrance almost in proportion to the amount of tar in the cigarette mainstream smoke flowing into the filter when the cigarette is smoked.
  • the aroma release component consisting of pure fragrance combined with cyclodextrin is a specific smoke component in cigarette mainstream smoke that flows into the filter when smoking cigarette ( In particular, a fragrance is released by a rise in heat and a component having a vapor pressure at a level that is distributed between the liquid phase and the solid phase at room temperature.
  • the fragrance-releasing component consisting of pure fragrance combined with dextrin mixesed with dextrin) releases fragrance mainly due to the moisture in the cigarette mainstream smoke flowing into the filter and the rise of heat.
  • the fragrance release component consisting of pure fragrance the fragrance release component consisting of pure fragrance combined with cyclodextrin, and the fragrance release component consisting of pure fragrance combined with dextrin are each per puff when smoking cigarettes.
  • the amount of perfume fragrance they release is different.
  • cigarettes equipped with filters containing a plurality of different fragrance-releasing components can taste a blend of different amounts of different fragrances per puff, in addition to the flavor of the cigarette itself when smoked.
  • a method described in Japanese Patent Publication No. Sho 63-38187 can be applied. That is, for example, in a general cigarette filter manufacturing machine, immediately before the step of wrapping the opened cellulose acetate fiber bundle with a filter wrapper and forming it into a rod shape, the yarn is put at a predetermined position in the circumferential direction of the cellulose acetate fiber bundle. A guide and a mandrel to be guided are installed, and the yarn can be inserted into the cellulose acetate fiber bundle by passing the yarn through the guide and the mandrel. Needless to say, the thread is impregnated with the perfume-releasing component as described above before being inserted into the cellulose acetate fiber bundle.
  • the perfume carrier is composed of a plurality of individual yarns, and the plurality of aroma release components can be carried on different individual yarns.
  • the cigarette filter according to the first aspect includes a filter body in which a plurality of fragrance release members each made of one or more individual yarns including an fragrance release component are incorporated, and the fragrance in one fragrance release member is the same. Is different from the fragrance in one or more other fragrance release members, and the fragrance release behavior of one fragrance release member is different from the fragrance release behavior of the other one or more fragrance release members. .
  • different yarns carrying different aroma releasing components can be colored differently from each other.
  • the fragrance carrier is composed of one or more individual yarns, and each individual yarn carries a plurality of aroma release components including different pure fragrances.
  • the individual yarn is composed of a plurality of filaments, one filament is loaded with one fragrance release component, the other one or more filaments are loaded with another fragrance release component, and these filaments are twisted together. It is convenient to make a single thread. That is, in the second aspect, the fragrance release member is composed of one or more individual yarns carrying different fragrance release components.
  • the cigarette of the present invention includes the above-described filter of the present invention at one end of a cigarette rod.
  • the cigarette rod is the same as the cigarette rod of a cigarette with a normal filter, and is composed of a rod of tobacco filler such as tobacco cut and cigarette wrapping paper that wraps the outer peripheral surface of the tobacco filler rod.
  • the filter is connected to the cigarette rod by chip paper.
  • the length of the cigarette rod is usually 40 mm to 70 mm, and the diameter may be the same as the diameter of the filter, or in order to make the connection with the filter by chip paper using glue more reliable. It may be slightly larger (up to 0.5 mm) than the diameter.
  • FIG. 1 is an enlarged schematic perspective view showing an example of a filter according to the first aspect of the present invention.
  • a filter 10 shown in FIG. 1 has a cylindrical filter body 110 made of tow of cellulose acetate fibers bound with a plasticizer such as triacetin.
  • a plurality of aroma release members extending in parallel with the central axis of the filter main body 110 are incorporated.
  • the plurality of fragrance release members are composed of a plurality of individual yarns each carrying a fragrance release component including a pure fragrance.
  • One of these fragrance release members includes a pure fragrance different from the pure fragrance contained in the other one or more fragrance release members.
  • two fragrance releasing members 121 and 122 are incorporated in the filter main body 110.
  • the fragrance release member 121 is made of cotton yarn 121a carrying a fragrance release component made of pure fragrance A
  • the fragrance release member 122 is made of pure fragrance B combined with cyclodextrin or pure fragrance C combined with dextrin.
  • the pure fragrance A is a fragrance different from the pure fragrance B and / or the pure fragrance C.
  • the cotton yarns 121a and 122a can be colored in different colors.
  • the filter body 110 provides the filter 10 with the outer peripheral surface thereof being wrapped by a filter wrapper 130.
  • the filter 10 defines a distal end surface 10a and a proximal end surface 10b. When the filter 10 is connected to the cigarette rod, the distal end surface 10a can come into contact with the proximal end surface of the cigarette rod.
  • a filter area including the base end face 10b of the filter 10 is given by a smoker.
  • FIG. 2 is a schematic perspective view showing another example of the filter according to the first aspect of the present invention in an enlarged manner.
  • the filter 20 shown in FIG. 2 has the same structure as the filter 10 of FIG. 1 except that the three fragrance releasing members 221, 222, and 223 are incorporated in the filter body 110.
  • the fragrance release member 221 is made of a cotton yarn 221a carrying a fragrance release component made of pure fragrance A
  • the fragrance release member 222 is made of a cotton yarn 222a carrying a fragrance release component made of pure fragrance B combined with a cyclodextrin.
  • the fragrance release member 223 is made of a cotton thread 223a carrying a fragrance release component composed of pure fragrance C combined with dextrin.
  • the pure fragrance A, the pure fragrance B, and the pure fragrance C are different fragrances, and thus emit different fragrances.
  • the cotton yarns 221a, 222a, and 223a can be colored in different colors.
  • the cotton yarn 221a can be colored blue
  • the cotton yarn 222a can be colored yellow
  • the cotton yarn 223a can be colored pink.
  • FIG. 3 is an enlarged schematic diagram illustrating an example of a filter according to the second aspect of the present invention.
  • the filter 30 shown in FIG. 3 is different from the fragrance release members 121 and 122 except that the fragrance release member 310 composed of a single thread 310a carrying a plurality of fragrance release components is incorporated in the filter body 110. It has the same structure as the filter 10 shown in FIG.
  • the yarn 310a carrying a plurality of fragrance components includes, for example, a cotton filament carrying a fragrance release component consisting of pure fragrance A, a cotton filament carrying a fragrance release component consisting of pure fragrance B combined with cyclodextrin, and a dextrin
  • Cotton filaments carrying fragrance-releasing components comprising pure fragrance C combined with can be made by twisting together.
  • the pure fragrance A, the pure fragrance B, and the pure fragrance C may be different fragrances, and thus emit different fragrances.
  • Two or more aroma release members 310 can be inserted through the filter body 110.
  • FIG. 4 is an enlarged schematic perspective view showing an example of a cigarette with a filter according to the present invention.
  • the cigarette 40 with a filter shown in FIG. 4 includes a cigarette rod 410 having a distal end 410a and a proximal end 410b constituting an ignition end, and a filter 420 having a distal end 420a and a proximal end 420b.
  • the cigarette rod 410 and the filter 420 are connected by a chip paper 430 with the base end 410b of the cigarette rod and the tip 420a of the filter abutting each other.
  • the cigarette rod 410 is composed of the above-described tobacco filler rod 411 and cigarette wrapping paper 412 wrapping the outer peripheral surface of the tobacco filler rod 411.
  • the filter 420 is configured by the filter of the present invention.
  • the filter 420 can be configured by the filter 10 shown in FIG. 1, the filter 20 shown in FIG. 2, or the filter 30 shown in FIG.
  • FIG. 5 shows the amount of perfume (delivery amount) delivered from the filter into the cigarette mainstream smoke passing through the filter 420 when the cigarette shown in FIG. 4 having the filter 20 shown in FIG. It is a graph for demonstrating the change for every puff.
  • a fragrance release member made of cotton yarn 221 a carrying a fragrance release component made of pure fragrance A, and a fragrance release component made of pure fragrance B combined with cyclodextrin.
  • a fragrance release member comprising a cotton yarn 222a carrying a fragrance
  • a fragrance release member comprising a cotton yarn 223a carrying a fragrance release component comprising a pure fragrance C combined with dextrin are incorporated.
  • the pure fragrance A, the pure fragrance B, and the pure fragrance C are different from each other.
  • the amount of the fragrance delivered from the fragrance release member A into the cigarette mainstream smoke gradually increases almost linearly for each puff (curve a).
  • the amount of the fragrance delivered from the fragrance release member B into the mainstream smoke of the cigarette is larger than the case of the fragrance release member A from the beginning to the middle of the puff, but gradually decreases thereafter, and the fragrance is delivered in the latter stage of the puff.
  • the amount is less than in the case of the fragrance release member A (curve b).
  • the amount of the fragrance delivered from the fragrance releasing member C into the mainstream smoke of the cigarette is very small from the early stage to the middle stage of the puff, but increases rapidly in the later stage of the puff, and the amount of fragrance delivered from the fragrance releasing members A and B (Curve c).
  • Example 1 In this example, a filter having the structure shown in FIG. 1 was produced, and this was connected to a cigarette rod to produce a cigarette with a filter, which was subjected to sensory evaluation.
  • the specifications of the cellulose acetate fiber tow constituting the filter body were a single fineness of 2.5 denier and a total fineness of 35000 denier, and the cross-sectional shape of each fiber was Y-shaped.
  • the filter wrapper had an air permeability of 10,000 coresta units (CU), a basis weight of 24.0 g / m 2 and a width of 26.5 mm.
  • the obtained long filter body had a circumference of 24.5 mm and a length of 100 mm.
  • the cigarette with a filter was produced with a normal cigarette hoist using this long filter body and the cigarette filler, cigarette wrapping paper, and chip paper necessary for producing a cigarette rod of a commercial cigarette product (Salem Alaska).
  • the long filter body was divided into four pieces, and a length of 25 mm was abutted with the cigarette rod per cigarette.
  • the specifications of the cigarette rod were a circumferential length of 24.5 mm and a length of 84 mm.
  • Sensation of menthol Received expert training in cigarette savory evaluation, and scored sensory scores based on the following criteria by seven professional evaluators from the applicant company in charge of savory evaluation and savory development. was calculated.
  • the sensory score of the menthol feeling of the cigarette product showing the strongest menthol feeling is set to 2.0 (reference point), and the sensory score of the menthol feeling of the cigarette product without the menthol feeling was set at 1.0 point (reference point), and the cigarette produced in Example 1 was scored in 0.1 point increments as compared to both reference points.
  • Sense of sweetness The above seven expert evaluators assigned sensory scores according to the following criteria and calculated the average value.
  • the sensory score of the sweetness of the cigarette product showing the strongest sweetness is set to 2.0 (reference point), and the sweetness of the cigarette product with the weakest sweetness is set.
  • the sensory score of the feeling was set at 1.0 (reference point), and the cigarette produced in Example 1 was scored in 0.1 point increments as compared to both reference points.
  • the sweetness and menthol feeling changed greatly as the puff progressed. That is, it is considered that menthol not included in cyclodextrin migrated from cotton yarn to other parts (cigarette carved, cellulose acetate fiber, etc.) during the storage, and was distributed in an almost equilibrium state in the cigarette.
  • the delivery of menthol into cigarette mainstream smoke is similar to the tar-puff behavior of cigarette mainstream smoke.
  • the sweet flavor (ethyl butyrate) encapsulated in cyclodextrin remains in the cotton yarn during the above storage and is released depending on the amount of mainstream smoke that passes through the mainstream smoke through the filter due to smoking. Therefore, compared with menthol not included in cyclodextrin, the sweetness is strongly expressed in the first half of smoke absorption.
  • Example 2 L-menthol-containing dextrin powder was produced as follows. That is, 1 part by weight of sucrose fatty acid ester (“Ryoto Sugar Ester S-1170” manufactured by Mitsubishi Chemical Foods Co., Ltd.) as an emulsifier was added to 59 parts by weight of purified water and stirred at 60 ° C. for 10 minutes. To the obtained solution, 40 parts by weight of dextrin (“Sandek # 185” manufactured by Sanwa Starch Co., Ltd.) was added and stirred for 30 minutes. While maintaining the obtained solution at 50 to 60 ° C., 13.67 parts by weight of L-menthol was added and dissolved.
  • sucrose fatty acid ester (“Ryoto Sugar Ester S-1170” manufactured by Mitsubishi Chemical Foods Co., Ltd.) as an emulsifier was added to 59 parts by weight of purified water and stirred at 60 ° C. for 10 minutes.
  • 40 parts by weight of dextrin (“Sandek # 185” manufactured by Sanwa
  • the obtained solution was emulsified with a TK homomixer at 12000 rpm for 10 minutes to obtain a spray solution. While maintaining this spray solution at 50 to 60 ° C., it was sent to a spray dryer (“Spray Dryer MDL-050M” manufactured by Fujisaki Electric Co., Ltd.) and spray-dried at 180 ° C. Thus, dextrin powder containing 25% by weight of L-menthol Got.
  • a perfume discharge member manufacturing apparatus comprising a 20/16 bleached cotton yarn cheese, a perfume tank, a perfume feed pump, a perfume applicator and the like is attached to a normal filter manufacturing machine, and the perfume tank.
  • the filter wrapper was the same as that used in Example 1.
  • the obtained long filter body had a circumference of 24.5 mm and a length of 100 mm.
  • Two types of cigarette samples A and B with a filter were prepared in the same manner as in Example 1 except that the obtained long filter body was used.
  • the cigarette sample A with a filter contains L-menthol not added to the dextrin (addition amount: 11.5 g per 25 mm filter length), and the cigarette sample B with the filter contains the L-menthol contained in the dextrin powder.
  • -It contained menthol (addition amount: 10.0 g per 25 mm filter length).
  • the ventilation resistance of both filters was the same.
  • the obtained cigarette samples A and B with a filter were stored for one month in the same manner as in Example 1, and then the amount of menthol in the mainstream smoke for each puff was measured as follows.
  • results shown in Table 2 are shown as a graph in FIG. In FIG. 7, the line segment a indicates the result for the sample A, and the line segment b indicates the result for the sample B.

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

A filter for cigarette which comprises a filter body (110) and flavor-releasing members (121, 122), said flavor-releasing members comprising a flavoring agent carrier consisting of one or more separate strings (121a, 122a) and multiple flavor-releasing components being held on the flavoring agent carrier, characterized in that: the flavor-releasing members (121, 122) are integrated within the filter body (110) in such a manner as extending along the central axis of the filter body (110); one flavor-releasing component releases a flavor of a flavoring agent that is different from the flavor(s) released by the other one or more flavor-releasing components; the flavoring agent-releasing behavior of one flavor-releasing component differs from the flavoring agent-releasing behaviors of the other one or more flavor-releasing components; and the flavor-releasing components are selected from the group consisting of a pure flavoring agent, a pure flavoring agent combined with cyclodextrin and a pure flavoring agent combined with dextrin.

Description

シガレット用フィルタおよびフィルタ付きシガレットCigarette filter and filter cigarette
 本発明は、シガレット用フィルタおよびフィルタ付きシガレットに関する。 The present invention relates to a cigarette filter and a cigarette with a filter.
 タバコ煙改質剤を含む糸を組み込んだタバコフィルタを備えるシガレットが知られている(例えば、特許文献1、2)。かかるシガレットを喫煙すると、タバコ煙改質剤は、フィルタを通るタバコ主流煙中に、味または芳香を添加し得る。 Cigarettes equipped with a tobacco filter incorporating a yarn containing a tobacco smoke modifier are known (for example, Patent Documents 1 and 2). When smoking such cigarettes, the tobacco smoke modifier may add flavor or aroma into the tobacco mainstream smoke passing through the filter.
特公昭63-38187号公報Japanese Patent Publication No. 63-38187 英国特許出願公開第2070409号明細書British Patent Application No. 2070409
 上記先行技術文献は、1本の糸に2種以上の煙改質剤を担持させること、および2本あるいはそれ以上の糸に同種または異種の煙改質剤を担持させることを開示している。しかしながら、シガレットを喫煙したときに、パフ毎に異なる香りを味わうようにさせるという技術思想は示されていない。 The above prior art documents disclose carrying two or more types of smoke modifiers on one yarn, and carrying the same or different types of smoke modifiers on two or more yarns. . However, there is no technical idea that when a cigarette is smoked, a different scent is tasted for each puff.
 本発明は、シガレットを喫煙したときに、パフ毎に異なる香りを味わうことを可能にするシガレット用フィルタおよび係るフィルタを備えたシガレットを提供することを目的とする。 An object of the present invention is to provide a cigarette filter and a cigarette provided with such a filter that make it possible to taste a different scent for each puff when the cigarette is smoked.
 本発明の一つの側面によれば、フィルタ本体、および1本以上の個別糸からなる香料担体と、前記香料担体に担持された複数の香気放出成分とを含む香気放出部材を備え、前記香気放出部材は、前記フィルタ本体の中心軸に沿って延びるように前記フィルタ本体内に組み込まれ、一の香気放出成分は、他の一またはそれ以上の香気放出成分とは異なる香料香気を放出し、一の香気放出成分の香料放出挙動は、他の一またはそれ以上の香気放出成分の香料放出挙動と異なり、前記香気放出成分は、純香料、サイクロデキストリンと組み合わされた純香料およびデキストリンと組み合わされた純香料からなる群の中から選ばれるシガレット用フィルタが提供される。 According to one aspect of the present invention, there is provided a fragrance release member comprising a filter body, a fragrance carrier comprising one or more individual yarns, and a plurality of fragrance release components carried on the fragrance carrier, and the fragrance release. The member is incorporated into the filter body so as to extend along the central axis of the filter body, and one fragrance release component emits a fragrance fragrance different from the other one or more fragrance release components, The fragrance release behavior of the fragrance release component is different from the fragrance release behavior of one or more other fragrance release components, said fragrance release component combined with pure fragrance, pure fragrance combined with cyclodextrin and dextrin A cigarette filter selected from the group consisting of pure fragrances is provided.
 本発明の他の側面によれば、シガレットロッドと、前記シガレットロッドの一端に接続されたフィルタを備え、前記フィルタが本発明のフィルタにより構成されるフィルタ付きシガレットが提供される。 According to another aspect of the present invention, there is provided a cigarette with a filter including a cigarette rod and a filter connected to one end of the cigarette rod, wherein the filter is constituted by the filter of the present invention.
 本発明のシガレット用フィルタは、シガレットを喫煙したときに、パフ毎に異なる香りを味わうことを可能にする。 The cigarette filter of the present invention makes it possible to taste a different scent for each puff when smoking a cigarette.
本発明の第1の態様に係るフィルタの一例を拡大して示す概略斜視図である。It is a schematic perspective view which expands and shows an example of the filter which concerns on the 1st aspect of this invention. 本発明の第1の態様に係るフィルタの別の例を拡大して示す概略斜視図である。It is a schematic perspective view which expands and shows another example of the filter which concerns on the 1st aspect of this invention. 本発明の第2の態様に係るフィルタの一例を拡大して示す概略図である。It is the schematic which expands and shows an example of the filter which concerns on the 2nd aspect of this invention. 本発明によるシガレットの一例を拡大して示す概略斜視図である。It is a schematic perspective view which expands and shows an example of the cigarette by this invention. 本発明によるシガレットの一例を喫煙したときのパフ回数に対するタバコ主流煙中への香料香気のデリバリー量の変化を説明するためのグラフ。The graph for demonstrating the change of the delivery amount of the fragrance | flavor fragrance | flavor in the tobacco mainstream smoke with respect to the frequency | count of the puff when smoking an example of the cigarette by this invention. 後述する例1で作製したフィルタ付きシガレットにおけるパフ毎の官能評価結果を示すグラフである。It is a graph which shows the sensory evaluation result for every puff in the cigarette with a filter produced in Example 1 mentioned later. 後述する例2で作製したフィルタ付きシガレットにおける香料の放出挙動を示すグラフ。The graph which shows the discharge | release behavior of the fragrance | flavor in the cigarette with a filter produced in Example 2 mentioned later.
 以下、本発明の態様を説明する。 Hereinafter, aspects of the present invention will be described.
 本発明の一つの側面によるシガレット用フィルタは、フィルタ本体、および少なくとも1本の個別糸からなる香料担体と、香料担体に担持された複数の香気放出成分とを含む香気放出部材を備える。香気放出部材は、フィルタ本体の中心軸に沿って延びるようにフィルタ本体内に組み込まれている。一の香気放出成分は、他の一またはそれ以上の香気放出成分とは異なる香料香気を放出する。一の香気放出成分の香料香気放出挙動は、他の一またはそれ以上の香気放出成分の香料香気放出挙動と異なる。そして、香気放出成分は、純香料、サイクロデキストリンと組み合わされた純香料およびデキストリンと組み合わされた純香料からなる群の中から選ばれる。 A cigarette filter according to one aspect of the present invention includes a filter main body, a fragrance release member including a fragrance carrier composed of at least one individual yarn, and a plurality of fragrance release components carried on the fragrance carrier. The aroma release member is incorporated in the filter body so as to extend along the central axis of the filter body. One scent-releasing component releases a different perfume scent than the other one or more scent-releasing components. The fragrance release behavior of one fragrance release component is different from the fragrance release behavior of one or more other fragrance release components. The fragrance releasing component is selected from the group consisting of pure fragrance, pure fragrance combined with cyclodextrin, and pure fragrance combined with dextrin.
 香気放出部材が組み込まれるフィルタ本体は、例えば、セルロースアセテート繊維のトウを含み、通常、円柱状である。フィルタ本体の長さは、通常、100mm~140mmであり、直径は、通常、15mm~26mmである。 The filter body into which the fragrance releasing member is incorporated includes, for example, cellulose acetate fiber tow and is usually cylindrical. The length of the filter body is usually 100 mm to 140 mm, and the diameter is usually 15 mm to 26 mm.
 香気放出部材は、少なくとも1本の個別糸からなる香料担体と、香料担体に担持された複数の香気放出成分とを含む。香気放出部材は、香料担体と複数の香気放出成分からなり得る。 The fragrance release member includes a fragrance carrier made of at least one individual yarn and a plurality of fragrance release components carried on the fragrance carrier. The fragrance release member may comprise a fragrance carrier and a plurality of fragrance release components.
 香料担体を構成する糸は、1本の繊維(フィラメント)あるいは複数本の繊維(フィラメント)の束からなることができ、モノフィラメント糸およびマルチフィラメント糸が含まれる。マルチフィラメント糸には、種々の加工糸が含まれる。 The yarn constituting the fragrance carrier can be composed of a single fiber (filament) or a bundle of a plurality of fibers (filament), and includes monofilament yarn and multifilament yarn. The multifilament yarn includes various processed yarns.
 糸の材質に特に制限はない。例えば、糸は、綿、ウール、シルク等の天然素材、ポリプロピレン、ポリエチレン、セルロースアセテート等の合成素材により作ることができる。 Thread material is not particularly limited. For example, the yarn can be made of a natural material such as cotton, wool or silk, or a synthetic material such as polypropylene, polyethylene or cellulose acetate.
 糸の直径は、通常、0.3~2.5mm、好ましくは0.7mm~1.5mmである。糸の長さは、通常、フィルタ本体の長さと同じである。糸は、通常、フィルタ本体の中心軸に沿って、フィルタ本体の全長にわたって、すなわちフィルタ本体の先端から基端まで、延びる。フィルタ本体は、外周が薄葉紙等のフィルタラッパーにより巻かれてフィルタを提供する。 The diameter of the yarn is usually 0.3 to 2.5 mm, preferably 0.7 mm to 1.5 mm. The length of the yarn is usually the same as the length of the filter body. The yarn typically extends along the central axis of the filter body over the entire length of the filter body, i.e., from the distal end to the proximal end of the filter body. The filter body is provided with a filter whose outer periphery is wound by a filter wrapper such as thin paper.
 香気放出成分は、(i)純香料、(ii)サイクロデキストリンと組み合わされた純香料および(iii)デキストリンと組み合わされた純香料からなる群の中から選ばれる。純香料は、香料それ自体である。純香料の例には、アセトアニソール、アセトフェノン、アセチルピラジン、2-アセチルチアゾール、アルファルファエキストラクト、アミルアルコール、酪酸アミル、トランス-アネトール、スターアニス油、リンゴ果汁、ペルーバルサム油、ミツロウアブソリュート、ベンズアルデヒド、ベンゾインレジノイド、ベンジルアルコール、安息香酸ベンジル、フェニル酢酸ベンジル、プロピオン酸ベンジル、2,3-ブタンジオン、2-ブタノール、酪酸ブチル、酪酸、カラメル、カルダモン油、キャロブアブロリュート、β-カロテン、ニンジンジュース、L-カルボン、β-カリオフィレン、カシア樹皮油、シダーウッド油、セロリーシード油、カモミル油、シンナムアルデヒド、ケイ皮酸、シンナミルアルコール、ケイ皮酸シンナミル、シトロネラ油、DL-シントネロール、クラリセージエキストラクト、ココア、コーヒー、コニャック油、コリアンダー油、クミンアルデヒド、ダバナ油、δ-デカラクトン、γ-デカラクトン、デカン酸、ディルハーブ油、3,4-ジメチル-1,2-シクロペンタンジオン、4,5-ジメチル-3-ヒドロキシ-2,6-ジヒドロフラン-2-オン、3,7-ジメチル-6-オクテン酸、2,3-ジメチルピラジン、2,5-ジメチルピラジン、2,6-ジメチルピラジン、2-メチル酪酸エチル、酢酸エチル、酪酸エチル、ヘキサン酸エチル、イソ吉草酸エチル、乳酸エチル、ラウリル酸エチル、レブリン酸エチル、エチルマルトール、オクタン酸エチル、オレイン酸エチル、パルミチン酸エチル、フェニル酢酸エチル、プロピオン酸エチル、ステアリン酸エチル、吉草酸エチル、エチルバニリン、エチルバニリングルコシド、2-エチル-3,(5または6)-ジメチルピラジン、5-メチル-3-ヒドロキシ-4-メチル-2(5H)-フラノン、2-エチル-3-メチルピラジン、ユーカリプトール、フェネグリークアブゾリュート、ジェネアブゾリュート、リンドウ根インフュージョン、ゲラニオール、酢酸ゲラニル、ブドウ果汁、グアヤコール、グァバエキストラクト、γ-ヘプタラクトン、γ-ヘキサラクトン、ヘキサン酸、シス-3-ヘキサン-1-オール、酢酸ヘキシル、ヘキシルアルコール、フェニル酢酸ヘキシル、ハチミツ、4-ヒドロキシ-3-ペンテン酸ラクトン、4-ヒドロキシ-4-(3-ヒドロキシ-1-ブテニル)-3,5,5-トリメチル-2-シクロヘキサン-1-オン、4-(パラ-ヒドロキシフェニル)-2-ブタノン、4-ヒドロキシウンデカン酸ナトリウム、インモルテルアブゾリュート、β-イオノン、酢酸イソアミル、酪酸イソアミル、フェニル酢酸イソアミル、酢酸イソブチル、フェニル酢酸イソブチル、ジャスミンアブソリュート、ココナッツティンクチャー、ラプダナム油、レモンテルペンレス油、カンゾウエキストラクト、リナロール、酢酸リナル、ロページ根油、マルトール、メープルシロップ、メントール(L-メントール)、メントン、酢酸L-メンチル、パラメトキシベンズアルデヒド、メチル-2-ピロリルケトン、アントラニル酸メチル、フェニル酢酸メチル、サリチル酸メチル、4’-メチルアセトフェノン、メチルシクロペンテノロン、3-メチル吉草酸、ミモザアブロリュート、トウミツ、ミリチン酸、ネロール、ネロリドール、γ-ノナラクトン、ナツメグ油、δ-オクタラクトン、オクタナール、オクタン酸、オレンジフラワー油、オレンジ油、オリス油、パルミチン酸、ペパーミント油、プリグレインパラグアイ油、フェネチルアルコール、フェニル酢酸フェネチル、フェニル酢酸、ピペロナール、プラムエキストラクト、プロペニルグアエトール、酢酸プロピル、3-プロビリデンフタリド、プルーン果汁、ピルビン酸、レーズンエキストラクト、ローズ油、ラム酒、セージ油、サンダルウッド油、スペアミント油、スチラックスアブソリュート、マリーゴールド油、ディーディスティレート、α-テルピネオール、酢酸テルピニル、5,6,7,8-テトラヒドロキサリン、1,5,5,9-テトラメチル-13-オキサクロロ(8.3.0.0(4.9))トリデカン、2,3,5,6-テトラメチルピラジン、タイム油、トマトエキストラクト、2-トリデカノン、クエン酸トリメチル、4-(2,6,6-トリメチル-1,3-シクロヘキセニル)2-ブテン-4-オン、2,6,6-トリメチル-2-シクロヘキセン-1,4-ジオン、4-(2,6,6-トリメチル-1、3-シクロヘキサジエニル)2-ブテン-4-オン、2,3,5-トリメチルピラジン、γ-ウンデカラクトン、γ-バレロラクトン、バニラエキス、バニリン、ペラトルアルデヒド、バイオレットリーフアブソリュート等が含まれる。 The aroma releasing component is selected from the group consisting of (i) pure fragrance, (ii) pure fragrance combined with cyclodextrin, and (iii) pure fragrance combined with dextrin. Pure fragrance is the fragrance itself. Examples of pure flavors include acetanisole, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract, amyl alcohol, amyl butyrate, trans-anethole, star anise oil, apple juice, peruvian balsam oil, beeswax absolute, benzaldehyde, Benzoin resinoid, benzyl alcohol, benzyl benzoate, benzyl phenylacetate, benzyl propionate, 2,3-butanedione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamom oil, carob brolute, β-carotene, carrot juice, L Carvone, β-caryophyllene, cassia bark oil, cedarwood oil, celery seed oil, camomil oil, cinnamaldehyde, cinnamic acid, cinnamyl alcohol, cinnamyl cinnamate, Citronella oil, DL-cintonellol, clary sage extract, cocoa, coffee, cognac oil, coriander oil, cuminaldehyde, dabana oil, δ-decalactone, γ-decalactone, decanoic acid, dill herb oil, 3,4-dimethyl-1, 2-cyclopentanedione, 4,5-dimethyl-3-hydroxy-2,6-dihydrofuran-2-one, 3,7-dimethyl-6-octenoic acid, 2,3-dimethylpyrazine, 2,5-dimethyl Pyrazine, 2,6-dimethylpyrazine, ethyl 2-methylbutyrate, ethyl acetate, ethyl butyrate, ethyl hexanoate, ethyl isovalerate, ethyl lactate, ethyl laurate, ethyl levulinate, ethyl maltol, ethyl octanoate, oleic acid Ethyl, ethyl palmitate, ethyl phenylacetate, ethyl propionate Chill, ethyl stearate, ethyl valerate, ethyl vanillin, ethyl vanillin glucoside, 2-ethyl-3, (5 or 6) -dimethylpyrazine, 5-methyl-3-hydroxy-4-methyl-2 (5H) -furanone , 2-ethyl-3-methylpyrazine, eucalyptol, pheneglyk absolute, gene absolute, gentian root infusion, geraniol, geranyl acetate, grape juice, guaiacol, guava extract, γ-heptalactone, γ-hexalactone , Hexanoic acid, cis-3-hexane-1-ol, hexyl acetate, hexyl alcohol, hexyl phenyl acetate, honey, 4-hydroxy-3-pentenoic acid lactone, 4-hydroxy-4- (3-hydroxy-1-butenyl ) -3,5,5-trimethyl- 2-cyclohexane-1-one, 4- (para-hydroxyphenyl) -2-butanone, sodium 4-hydroxyundecanoate, immortel absolute, β-ionone, isoamyl acetate, isoamyl butyrate, isoamyl phenylacetate, isobutyl acetate , Isobutyl phenylacetate, jasmine absolute, coconut tincture, rapdanum oil, lemon terpenes oil, licorice extract, linalool, linal acetate, ropage root oil, maltol, maple syrup, menthol (L-menthol), menthone, L-acetate Menthyl, paramethoxybenzaldehyde, methyl-2-pyrrolyl ketone, methyl anthranilate, methyl phenylacetate, methyl salicylate, 4'-methylacetophenone, methylcyclopentenolone, 3 Methyl valeric acid, mimosa broult, honey, myristic acid, nerol, nerolidol, γ-nonalactone, nutmeg oil, δ-octalactone, octanal, octanoic acid, orange flower oil, orange oil, oris oil, palmitic acid, peppermint oil , Pre-grain paraguay oil, phenethyl alcohol, phenethyl alcohol, phenyl acetate, piperonal, plum extract, propenyl guaetol, propyl acetate, 3-propylidenephthalide, prune juice, pyruvic acid, raisin extract, rose oil, Rum, sage oil, sandalwood oil, spearmint oil, stylax absolute, marigold oil, de distilate, α-terpineol, terpinyl acetate, 5,6,7,8- tetrahydroxari 1,5,5,9-tetramethyl-13-oxachloro (8.3.0.0 (4.9)) tridecane, 2,3,5,6-tetramethylpyrazine, thyme oil, tomato extract 2-tridecanone, trimethyl citrate, 4- (2,6,6-trimethyl-1,3-cyclohexenyl) 2-buten-4-one, 2,6,6-trimethyl-2-cyclohexene-1,4 -Dione, 4- (2,6,6-trimethyl-1,3-cyclohexadienyl) 2-buten-4-one, 2,3,5-trimethylpyrazine, γ-undecalactone, γ-valerolactone, Vanilla extract, vanillin, peratoraldehyde, violet leaf absolute and the like are included.
 純香料からなる香気放出成分は、ポリプロピレングリコール、グリセリン、エタノール、水、トリグリセリド、トリアセチン、クエン酸トリエチル等に溶解し、その溶液を糸にしみこませることによって糸に担持させることができる。サイクロデキストリンと組み合わされた純香料からなる香気放出成分は、ポリプロピレングリコール、グリセリン、エタノール、水、トリグリセリド、トリアセチン、クエン酸トリエチル等中に懸濁させ、その懸濁液を糸にしみこませることによって糸に担持させることができる。懸濁液には、ショ糖脂肪酸エステルのような乳化剤、分散剤、消泡剤を加えることができる。また、デキストリンと組み合わされた純香料からなる香気放出成分は、ポリプロピレングリコール、グリセリン、エタノール、水、トリグリセリド、トリアセチン、クエン酸トリエチル等中に懸濁させ、その懸濁液を糸にしみこませることによって糸に担持させることができる。懸濁液には、ショ糖脂肪酸エステルのような乳化剤、分散剤、消泡剤を加えることができる。一例として、デキストリンと組み合わされた純香料からなる香気放出成分は、任意に乳化剤等を溶解したデキストリンの水溶液に香料を添加し、ホモミキサーで乳化させ、これをスプレードライヤーを用いて噴霧し、乾燥することにより、香料を含有するデキストリン微粉末の形態で得ることができる。 The fragrance-releasing component consisting of pure fragrance can be supported on the yarn by dissolving it in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. and soaking the solution into the yarn. The fragrance-releasing component consisting of pure fragrance combined with cyclodextrin is suspended in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. It can be supported on. An emulsifier such as a sucrose fatty acid ester, a dispersant, and an antifoaming agent can be added to the suspension. A fragrance-releasing component consisting of pure fragrance combined with dextrin is suspended in polypropylene glycol, glycerin, ethanol, water, triglyceride, triacetin, triethyl citrate, etc. It can be carried on a yarn. An emulsifier such as a sucrose fatty acid ester, a dispersant, and an antifoaming agent can be added to the suspension. As an example, a fragrance-releasing component consisting of a pure fragrance combined with dextrin is optionally added to an aqueous solution of dextrin in which an emulsifier is dissolved, emulsified with a homomixer, sprayed using a spray dryer, and dried. By doing so, it can be obtained in the form of a fine powder of dextrin containing a fragrance.
 一の香気放出成分は、他の一またはそれ以上の香気放出成分とは異なる香料香気を放出する。すなわち、一の香気放出成分に含まれる純香料は、他の一またはそれ以上の香気放出成分に含まれる純香料とは異なる香気を発する香料である。 One fragrance-releasing component releases a fragrance fragrance different from one or more other fragrance-releasing components. That is, the pure fragrance contained in one fragrance-releasing component is a fragrance that emits a different fragrance from the pure fragrance contained in one or more other fragrance-releasing components.
 一の香気放出成分の香料香気放出挙動は、他の一またはそれ以上の香気放出成分の香料香気放出挙動と異なる。純香料からなる香気放出成分は、シガレットを喫煙したとき、フィルタに流入するシガレット主流煙中のタール量にほぼ比例して香気を放出する。サイクロデキストリンと組み合わされた純香料(この場合、純香料はサイクロデキストリンに包接される)からなる香気放出成分は、シガレットを喫煙したとき、フィルタに流入するシガレット主流煙中の特定の煙成分(特に、常温で液相と固相との両相に分配するレベルの蒸気圧を有する成分)および熱の上昇により香気を放出する。デキストリンと組み合わされた(デキストリンと混合された)純香料からなる香気放出成分は、主に、フィルタに流入するシガレット主流煙中の水分、および熱の上昇により香気を放出する。 The fragrance release behavior of one fragrance release component is different from the fragrance release behavior of one or more other fragrance release components. The fragrance-releasing component made of pure fragrance releases the fragrance almost in proportion to the amount of tar in the cigarette mainstream smoke flowing into the filter when the cigarette is smoked. The aroma release component consisting of pure fragrance combined with cyclodextrin (in this case, the pure fragrance is included in cyclodextrin) is a specific smoke component in cigarette mainstream smoke that flows into the filter when smoking cigarette ( In particular, a fragrance is released by a rise in heat and a component having a vapor pressure at a level that is distributed between the liquid phase and the solid phase at room temperature. The fragrance-releasing component consisting of pure fragrance combined with dextrin (mixed with dextrin) releases fragrance mainly due to the moisture in the cigarette mainstream smoke flowing into the filter and the rise of heat.
 すなわち、純香料からなる香気放出成分と、サイクロデキストリンと組み合わされた純香料からなる香気放出成分と、デキストリンと組み合わされた純香料からなる香気放出成分とは、シガレットを喫煙したとき、パフ毎にそれらが放出する香料香気の量が異なる。かくして、異なる複数の香気放出成分を含むフィルタを備えたシガレットは、これを喫煙したとき、シガレット自体の香喫味に加えて、パフ毎に異なる量の異種香料香気のブレンドを味わうことができる。 In other words, the fragrance release component consisting of pure fragrance, the fragrance release component consisting of pure fragrance combined with cyclodextrin, and the fragrance release component consisting of pure fragrance combined with dextrin are each per puff when smoking cigarettes. The amount of perfume fragrance they release is different. Thus, cigarettes equipped with filters containing a plurality of different fragrance-releasing components can taste a blend of different amounts of different fragrances per puff, in addition to the flavor of the cigarette itself when smoked.
 香気放出部材が組み込まれたフィルタ本体を製造するためには、例えば特公昭63-38187号公報に記載されている方法を適用することができる。すなわち、例えば、一般的なシガレットフィルタ製造機械において、開繊したセルロースアセテート繊維束をフィルタラッパーで包みロッド状に成形する工程の直前に、セルロースアセテート繊維束の円周方向の所定位置に、糸を案内するガイドとマンドレルを設置し、糸をそのガイドとマンドレルに通じることでセルロースアセテート繊維束内に挿入することができる。いうまでもなく、その糸は、セルロースアセテート繊維束に挿入する前に、上述の通り、香料放出成分をしみこませておく。 In order to manufacture a filter body in which an aroma releasing member is incorporated, for example, a method described in Japanese Patent Publication No. Sho 63-38187 can be applied. That is, for example, in a general cigarette filter manufacturing machine, immediately before the step of wrapping the opened cellulose acetate fiber bundle with a filter wrapper and forming it into a rod shape, the yarn is put at a predetermined position in the circumferential direction of the cellulose acetate fiber bundle. A guide and a mandrel to be guided are installed, and the yarn can be inserted into the cellulose acetate fiber bundle by passing the yarn through the guide and the mandrel. Needless to say, the thread is impregnated with the perfume-releasing component as described above before being inserted into the cellulose acetate fiber bundle.
 本発明の第1の態様において、香料担体は、複数の個別糸からなり、複数の香気放出成分は、それぞれ異なる個別糸に担持され得る。この第1の態様によるシガレット用フィルタは、香気放出成分を含む1本以上の個別糸からそれぞれなる複数の香気放出部材が組み込まれたフィルタ本体を含み、一の香気放出部材における香料は同じであるが、他の一またはそれ以上の香気放出部材における香料とは異なり、かつ一の香気放出部材の香料放出挙動が他の一またはそれ以上の香気放出部材の香料放出挙動と異なるフィルタということができる。第1の態様において、異なる香気放出成分を担持する異なる糸は互いに異なる色に着色させることができる。 In the first aspect of the present invention, the perfume carrier is composed of a plurality of individual yarns, and the plurality of aroma release components can be carried on different individual yarns. The cigarette filter according to the first aspect includes a filter body in which a plurality of fragrance release members each made of one or more individual yarns including an fragrance release component are incorporated, and the fragrance in one fragrance release member is the same. Is different from the fragrance in one or more other fragrance release members, and the fragrance release behavior of one fragrance release member is different from the fragrance release behavior of the other one or more fragrance release members. . In the first aspect, different yarns carrying different aroma releasing components can be colored differently from each other.
 本発明の第2の態様において、香料担体は1本以上の個別糸からなり、各個別糸が、異種純香料を含む複数の香気放出成分を担持する。この場合、個別糸を複数のフィラメントから構成し、一のフィラメントに一の香気放出成分を担持させ、他の一またはそれ以上のフィラメントに他の香気放出成分を担持させて、これらフィラメントを撚り合わせて1本の糸を作ることが好都合である。すなわち、第2の態様において、香気放出部材は、それぞれ異なる香気放出成分を担持した1本以上の個別糸からなる。 In the second aspect of the present invention, the fragrance carrier is composed of one or more individual yarns, and each individual yarn carries a plurality of aroma release components including different pure fragrances. In this case, the individual yarn is composed of a plurality of filaments, one filament is loaded with one fragrance release component, the other one or more filaments are loaded with another fragrance release component, and these filaments are twisted together. It is convenient to make a single thread. That is, in the second aspect, the fragrance release member is composed of one or more individual yarns carrying different fragrance release components.
 本発明のシガレットは、上記本発明のフィルタを、シガレットロッドの一端に備える。シガレットロッドは、通常のフィルタ付きシガレットのシガレットロッドと同様のものであり、タバコ刻等のタバコ充填材のロッドと、タバコ充填材ロッドの外周面を包むシガレット巻紙により構成される。フィルタは、チップペーパーによりシガレットロッドに接続される。シガレットロッドの長さは、通常、40mm~70mmであり、直径は、フィルタの直径と同じ場合もあるし、あるいは糊を用いたチップペーパーによるフィルタとの接続をより確実にするために、フィルタの直径よりもやや(最大で0.5mm)大きい場合もある。 The cigarette of the present invention includes the above-described filter of the present invention at one end of a cigarette rod. The cigarette rod is the same as the cigarette rod of a cigarette with a normal filter, and is composed of a rod of tobacco filler such as tobacco cut and cigarette wrapping paper that wraps the outer peripheral surface of the tobacco filler rod. The filter is connected to the cigarette rod by chip paper. The length of the cigarette rod is usually 40 mm to 70 mm, and the diameter may be the same as the diameter of the filter, or in order to make the connection with the filter by chip paper using glue more reliable. It may be slightly larger (up to 0.5 mm) than the diameter.
 次に、図面を参照して、本発明の態様を説明する。全図にわたり、同様の要素には同じ符号を付して、その繰り返しの説明を省略する。 Next, aspects of the present invention will be described with reference to the drawings. Throughout the drawings, similar elements are denoted by the same reference numerals, and repeated description thereof is omitted.
 図1は、本発明の第1の態様に係るフィルタの一例を拡大して示す概略斜視図である。図1に示されるフィルタ10は、例えばトリアセチンのような可塑剤で結着されたセルロースアセテート繊維のトウからなる、円柱状フィルタ本体110を有する。フィルタ本体110内には、それぞれフィルタ本体110の中心軸に平行に延びる複数の香気放出部材が組み込まれている。複数の香気放出部材は、それぞれ純香料を含む香気放出成分を担持した複数の個別糸からなる。これら香気放出部材のうちの一つは、他の一つまたはそれ以上の香気放出部材に含まれる純香料とは異なる純香料を含む。図1においては、2つの香気放出部材121および122がフィルタ本体110内に組み込まれている。例えば、香気放出部材121は、純香料Aからなる香気放出成分を担持した綿糸121aからなり、香気放出部材122は、サイクロデキストリンと組み合わされた純香料Bもしくはデキストリンと組み合わされた純香料Cからなる香気放出成分を担持した綿糸122aからなり、ここで、純香料Aは、純香料Bおよび/または純香料Cと異なる香料である。綿糸121a、122aは互いに異なる色に着色することができる。フィルタ本体110は、その外周面がフィルタラッパー130により包まれて、フィルタ10を提供する。フィルタ10は、先端面10aと基端面10bを規定する。フィルタ10をシガレットロッドと接続するとき、先端面10aがシガレットロッドの基端面と当接し得る。フィルタ10の基端面10bを含むフィルタ領域が喫煙者により銜えられる。 FIG. 1 is an enlarged schematic perspective view showing an example of a filter according to the first aspect of the present invention. A filter 10 shown in FIG. 1 has a cylindrical filter body 110 made of tow of cellulose acetate fibers bound with a plasticizer such as triacetin. In the filter main body 110, a plurality of aroma release members extending in parallel with the central axis of the filter main body 110 are incorporated. The plurality of fragrance release members are composed of a plurality of individual yarns each carrying a fragrance release component including a pure fragrance. One of these fragrance release members includes a pure fragrance different from the pure fragrance contained in the other one or more fragrance release members. In FIG. 1, two fragrance releasing members 121 and 122 are incorporated in the filter main body 110. For example, the fragrance release member 121 is made of cotton yarn 121a carrying a fragrance release component made of pure fragrance A, and the fragrance release member 122 is made of pure fragrance B combined with cyclodextrin or pure fragrance C combined with dextrin. The pure fragrance A is a fragrance different from the pure fragrance B and / or the pure fragrance C. The cotton yarns 121a and 122a can be colored in different colors. The filter body 110 provides the filter 10 with the outer peripheral surface thereof being wrapped by a filter wrapper 130. The filter 10 defines a distal end surface 10a and a proximal end surface 10b. When the filter 10 is connected to the cigarette rod, the distal end surface 10a can come into contact with the proximal end surface of the cigarette rod. A filter area including the base end face 10b of the filter 10 is given by a smoker.
 図2は、本発明の第1の態様に係るフィルタの別の例を拡大して示す概略斜視図である。図2に示すフィルタ20は、3つの香気放出部材221、222、223がフィルタ本体110内に組み込まれていること以外は、図1のフィルタ10と同様の構造を有する。例えば、香気放出部材221は、純香料Aからなる香気放出成分を担持した綿糸221aからなり、香気放出部材222は、サイクロデキストリンと組み合わされた純香料Bからなる香気放出成分を担持した綿糸222aからなり、香気放出部材223は、デキストリンと組み合わされた純香料Cからなる香気放出成分を担持した綿糸223aからなる。ここで、例えば、純香料Aと純香料Bと純香料Cとは互いに異なる香料であり、従って互いに異なる香気を発する。そして、綿糸221a、222a、223aは互いに異なる色に着色することができる。例えば、綿糸221aは、ブルーに、綿糸222aは、イエローに、綿糸223aは、ピンクに着色することができる。 FIG. 2 is a schematic perspective view showing another example of the filter according to the first aspect of the present invention in an enlarged manner. The filter 20 shown in FIG. 2 has the same structure as the filter 10 of FIG. 1 except that the three fragrance releasing members 221, 222, and 223 are incorporated in the filter body 110. For example, the fragrance release member 221 is made of a cotton yarn 221a carrying a fragrance release component made of pure fragrance A, and the fragrance release member 222 is made of a cotton yarn 222a carrying a fragrance release component made of pure fragrance B combined with a cyclodextrin. The fragrance release member 223 is made of a cotton thread 223a carrying a fragrance release component composed of pure fragrance C combined with dextrin. Here, for example, the pure fragrance A, the pure fragrance B, and the pure fragrance C are different fragrances, and thus emit different fragrances. The cotton yarns 221a, 222a, and 223a can be colored in different colors. For example, the cotton yarn 221a can be colored blue, the cotton yarn 222a can be colored yellow, and the cotton yarn 223a can be colored pink.
 図3は、本発明の第2の態様に係るフィルタの一例を拡大して示す概略図である。図3に示すフィルタ30は、香気放出部材121および122の代わりに、複数の香気放出成分を担持した1本の糸310aからなる香気放出部材310がフィルタ本体110内に組み込まれている以外は、図1に示すフィルタ10と同様の構造を有する。複数の香気成分を担持した糸310aは、例えば、純香料Aからなる香気放出成分を担持した綿フィラメントと、サイクロデキストリンと組み合わされた純香料Bからなる香気放出成分を担持した綿フィラメントと、デキストリンと組み合わされた純香料Cからなる香気放出成分を担持した綿フィラメントを互いに撚り合わせて作ることができる。ここで、純香料Aと純香料Bと純香料Cとは互いに異なる香料であり得、従って互いに異なる香気を発する。香気放出部材310は2本以上をフィルタ本体110に挿通させることができる。 FIG. 3 is an enlarged schematic diagram illustrating an example of a filter according to the second aspect of the present invention. The filter 30 shown in FIG. 3 is different from the fragrance release members 121 and 122 except that the fragrance release member 310 composed of a single thread 310a carrying a plurality of fragrance release components is incorporated in the filter body 110. It has the same structure as the filter 10 shown in FIG. The yarn 310a carrying a plurality of fragrance components includes, for example, a cotton filament carrying a fragrance release component consisting of pure fragrance A, a cotton filament carrying a fragrance release component consisting of pure fragrance B combined with cyclodextrin, and a dextrin Cotton filaments carrying fragrance-releasing components comprising pure fragrance C combined with can be made by twisting together. Here, the pure fragrance A, the pure fragrance B, and the pure fragrance C may be different fragrances, and thus emit different fragrances. Two or more aroma release members 310 can be inserted through the filter body 110.
 図4は、本発明のフィルタ付きシガレットの一例を拡大して示す概略斜視図である。図4に示すフィルタ付きシガレット40は、着火端を構成する先端410aと基端410bを有するシガレットロッド410、および先端420aと基端420bを有するフィルタ420を備える。シガレットロッド410とフィルタ420とは、シガレットロッドの基端410bとフィルタの先端420aとが当接して、チップペーパー430により接続されている。シガレットロッド410は、上に述べたタバコ充填材のロッド411と、タバコ充填材ロッド411の外周面を包むシガレット巻紙412から構成される。フィルタ420は、本発明のフィルタにより構成される。例えば、フィルタ420は、図1に示すフィルタ10、図2に示すフィルタ20または図3に示すフィルタ30により構成することができる。 FIG. 4 is an enlarged schematic perspective view showing an example of a cigarette with a filter according to the present invention. The cigarette 40 with a filter shown in FIG. 4 includes a cigarette rod 410 having a distal end 410a and a proximal end 410b constituting an ignition end, and a filter 420 having a distal end 420a and a proximal end 420b. The cigarette rod 410 and the filter 420 are connected by a chip paper 430 with the base end 410b of the cigarette rod and the tip 420a of the filter abutting each other. The cigarette rod 410 is composed of the above-described tobacco filler rod 411 and cigarette wrapping paper 412 wrapping the outer peripheral surface of the tobacco filler rod 411. The filter 420 is configured by the filter of the present invention. For example, the filter 420 can be configured by the filter 10 shown in FIG. 1, the filter 20 shown in FIG. 2, or the filter 30 shown in FIG.
 図5は、フィルタ420として図2に示すフィルタ20を備えた図4に示すシガレットを喫煙したとき、フィルタ420を通過するシガレット主流煙中にフィルタから送給される香料の量(デリバリー量)のパフ毎の変化を説明するためのグラフである。 FIG. 5 shows the amount of perfume (delivery amount) delivered from the filter into the cigarette mainstream smoke passing through the filter 420 when the cigarette shown in FIG. 4 having the filter 20 shown in FIG. It is a graph for demonstrating the change for every puff.
 例えば、フィルタ20の本体110内には、純香料Aからなる香気放出成分を担持した綿糸221aからなる香気放出部材(香気放出部材A)、サイクロデキストリンと組み合わされた純香料Bからなる香気放出成分を担持した綿糸222aからなる香気放出部材(香気放出部材B)、デキストリンと組み合わされた純香料Cからなる香気放出成分を担持した綿糸223aからなる香気放出部材(香気放出部材C)が組み込まれており、ここで、純香料Aと純香料Bと純香料Cとは互いに異なる。香気放出部材Aからタバコ主流煙中に送給される香料の量は、パフ毎にほぼ直線的に漸増する(曲線a)。香気放出部材Bからタバコ主流煙中に送給される香料の量は、パフの初期から中期に掛けては香気放出部材Aの場合よりも多いが、その後漸減し、パフ後期には香料のデリバリー量は、香気放出部材Aの場合よりも少なくなる(曲線b)。香気放出部材Cからタバコ主流煙中に送給される香料の量は、パフ初期から中期にかけては非常に少ないが、パフ後期に急激に増加し、香気放出部材AおよびBからの香料デリバリー量よりも多くなる(曲線c)。かくして、喫煙者は、本発明のフィルタ付きシガレットを喫煙したとき、シガレット自体の香喫味に加えて、パフ毎に異なる量の異種香料香気のブレンドを味わうことができる。 For example, in the main body 110 of the filter 20, a fragrance release member (fragrance release member A) made of cotton yarn 221 a carrying a fragrance release component made of pure fragrance A, and a fragrance release component made of pure fragrance B combined with cyclodextrin. A fragrance release member (fragrance release member B) comprising a cotton yarn 222a carrying a fragrance, and a fragrance release member (fragrance release member C) comprising a cotton yarn 223a carrying a fragrance release component comprising a pure fragrance C combined with dextrin are incorporated. Here, the pure fragrance A, the pure fragrance B, and the pure fragrance C are different from each other. The amount of the fragrance delivered from the fragrance release member A into the cigarette mainstream smoke gradually increases almost linearly for each puff (curve a). The amount of the fragrance delivered from the fragrance release member B into the mainstream smoke of the cigarette is larger than the case of the fragrance release member A from the beginning to the middle of the puff, but gradually decreases thereafter, and the fragrance is delivered in the latter stage of the puff. The amount is less than in the case of the fragrance release member A (curve b). The amount of the fragrance delivered from the fragrance releasing member C into the mainstream smoke of the cigarette is very small from the early stage to the middle stage of the puff, but increases rapidly in the later stage of the puff, and the amount of fragrance delivered from the fragrance releasing members A and B (Curve c). Thus, when a smoker smokes a cigarette with a filter according to the present invention, in addition to the flavor of the cigarette itself, the smoker can taste a blend of different amounts of different flavors for each puff.
 以下、本発明を実施例により説明するが、本発明は、以下の実施例により限定されるものではない。 Hereinafter, although an example explains the present invention, the present invention is not limited to the following example.
 例1
 本例では、図1に示す構造のフィルタを作製し、これをシガレットロッドに接続してフィルタ付きシガレットを作製し、官能評価に供した。
Example 1
In this example, a filter having the structure shown in FIG. 1 was produced, and this was connected to a cigarette rod to produce a cigarette with a filter, which was subjected to sensory evaluation.
 具体的には、特公昭63-38187号公報に記載の方法に倣い、通常のフィルタ製造機に、イギリス式番手表示で20/8の漂白綿糸のチーズ、香料槽、香料送給ポンプ、香料アプリケータ等からなる香料放出部材製造装置を2組付設し、一方の香料放出部材製造装置の香料槽にL-メントールのポリプロプレン溶液(濃度70%)を入れ、他方の香料放出部材製造装置の香料槽にポリプロピレングリコールに分散させたα-サイクロデキストリン包接酪酸エチル(甘み香料)(濃度50%)を入れた。両香料放出部材製造装置とフィルタ製造機を駆動し、所望のフィルタ長尺体を作製した。フィルタ本体を構成するセルロースアセテート繊維トウの仕様は、単繊度2.5デニール、総繊度35000デニールであり、各繊維の断面形状はY字状であった。フィルタラッパーは、通気度が10000コレスタ単位(CU)であり、坪量が24.0g/m2であり、幅が26.5mmであった。得られたフィルタ長尺体は、円周が24.5mmであり、長さが100mmであった。 Specifically, following the method described in Japanese Examined Patent Publication No. Sho 63-38187, a 20/8 bleached cotton yarn cheese, a perfume tank, a perfume feed pump, a perfume application on a normal filter manufacturing machine with a British count display. 2 sets of fragrance release member manufacturing equipment consisting of a scent, etc., L-menthol polypropylene solution (concentration 70%) is placed in the fragrance tank of one fragrance release member manufacture apparatus, and the fragrance of the other fragrance release member manufacture apparatus Α-cyclodextrin inclusion ethyl butyrate (sweet flavor) (concentration 50%) dispersed in polypropylene glycol was placed in the tank. Both fragrance | flavor discharge | release member manufacturing apparatuses and the filter manufacturing machine were driven, and the desired filter elongate body was produced. The specifications of the cellulose acetate fiber tow constituting the filter body were a single fineness of 2.5 denier and a total fineness of 35000 denier, and the cross-sectional shape of each fiber was Y-shaped. The filter wrapper had an air permeability of 10,000 coresta units (CU), a basis weight of 24.0 g / m 2 and a width of 26.5 mm. The obtained long filter body had a circumference of 24.5 mm and a length of 100 mm.
 このフィルタ長尺体と、市販のシガレット製品(セーラム・アラスカ)のシガレットロッドを作製するに必要なタバコ充填材、シガレット巻紙、チップペーパーを用い、通常のシガレット巻き上げ機でフィルタ付きシガレットを製造した。その際、フィルタ長尺体は4つに分割され、シガレット1本当たり、25mmの長さ分がシガレットロッドと突き合わされた。 The cigarette with a filter was produced with a normal cigarette hoist using this long filter body and the cigarette filler, cigarette wrapping paper, and chip paper necessary for producing a cigarette rod of a commercial cigarette product (Salem Alaska). At that time, the long filter body was divided into four pieces, and a length of 25 mm was abutted with the cigarette rod per cigarette.
 シガレットロッドの仕様は、円周長が24.5mmであり、長さが84mmであった。 The specifications of the cigarette rod were a circumferential length of 24.5 mm and a length of 84 mm.
 作製したフィルタ付きシガレット20本を通常のシガレットパッケージに入れ、密封した。シガレットパッケージを温度22℃、相対湿度60%の環境下に1ヶ月保管した。保管後、フィルタ付きシガレットをパッケージから取り出し、7人のパネラーにより喫煙し、香喫味の官能評価を行った。 20 Twenty produced cigarettes with a filter were put in a normal cigarette package and sealed. The cigarette package was stored in an environment at a temperature of 22 ° C. and a relative humidity of 60% for 1 month. After storage, the cigarette with a filter was taken out from the package, smoked by seven panelists, and sensory evaluation of the flavor was performed.
 官能評価は、シガレット1本に付き、1パフ目から7パフ目まで、各パフ毎に以下の香喫味評価項目に対して採点を行った。 Sensory evaluation was given to each cigarette from the 1st puff to the 7th puff, and the following flavor evaluation items were scored for each puff.
 <香喫味評価項目>
 メントール感:シガレットの香喫味評価の専門訓練を受けており、香喫味の評価や香喫味開発を担当している出願人会社の専門評価者7名により以下の基準で官能スコアをつけ、平均値を算出した。
<Savory evaluation items>
Sensation of menthol: Received expert training in cigarette savory evaluation, and scored sensory scores based on the following criteria by seven professional evaluators from the applicant company in charge of savory evaluation and savory development. Was calculated.
 出願人会社が販売するシガレット製品のうち、最も強いメントール感を示すシガレット製品のメントール感の官能スコアを2.0点(基準点)に設定し、メントール感のないシガレット製品のメントール感の官能スコアを1.0点(基準点)に設定し、例1で作製したシガレットが、両基準点と比較して何点の評価となるか、0.1点刻で採点した。 Among the cigarette products sold by the applicant company, the sensory score of the menthol feeling of the cigarette product showing the strongest menthol feeling is set to 2.0 (reference point), and the sensory score of the menthol feeling of the cigarette product without the menthol feeling Was set at 1.0 point (reference point), and the cigarette produced in Example 1 was scored in 0.1 point increments as compared to both reference points.
 甘さ感:上記7名の専門評価者により以下の基準で官能スコアをつけ、平均値を算出した。 Sense of sweetness: The above seven expert evaluators assigned sensory scores according to the following criteria and calculated the average value.
 出願人会社が販売するシガレット製品のうち、最も強い甘さ感を示すシガレット製品の甘さ感の官能スコアを2.0点(基準点)に設定し、甘さ感の最も弱いシガレット製品の甘さ感の官能スコアを1.0点(基準点)に設定し、例1で作製したシガレットが、両基準点と比較して何点の評価となるか、0.1点刻で採点した。 Among the cigarette products sold by the applicant company, the sensory score of the sweetness of the cigarette product showing the strongest sweetness is set to 2.0 (reference point), and the sweetness of the cigarette product with the weakest sweetness is set. The sensory score of the feeling was set at 1.0 (reference point), and the cigarette produced in Example 1 was scored in 0.1 point increments as compared to both reference points.
 この7人の評価結果を平均した結果を官能スコアとして下記表1に示す。
Figure JPOXMLDOC01-appb-T000001
The results of averaging the evaluation results of these seven people are shown in Table 1 below as sensory scores.
Figure JPOXMLDOC01-appb-T000001
 また、表1に示す結果をグラフとして図6に示す。図6において線分aは甘さ感についての結果を、線分bはメントール感についての結果を示す。 Also, the results shown in Table 1 are shown as a graph in FIG. In FIG. 6, line segment a indicates the result of sweetness, and line segment b indicates the result of menthol feeling.
 上記結果からわかるように、甘さ感とメントール感がパフの進行につれ、大きく変化した。すなわち、サイクロデキストリンに包接されていないメントールは、前記保管中に綿糸から他の部位(タバコ刻、セルロースアセテート繊維等)に移行し、シガレット内で平衡状態に近い状態で分布したものと考えられ、シガレット主流煙中へのメントールのデリバリーは、シガレット主流煙中のタールのパフ毎の挙動と類似するものとなっている。他方、サイクロデキストリンに包接した甘み香料(酪酸エチル)は、上記保管中も綿糸中にとどまり、喫煙により主流煙がフィルタ中を通過した時点から、通過する主流煙の量に強く依存して放出されるため、サイクロデキストリンに包接されていないメントールに比べて、吸煙の前半に強く甘さ感が発現されている。 As can be seen from the above results, the sweetness and menthol feeling changed greatly as the puff progressed. That is, it is considered that menthol not included in cyclodextrin migrated from cotton yarn to other parts (cigarette carved, cellulose acetate fiber, etc.) during the storage, and was distributed in an almost equilibrium state in the cigarette. The delivery of menthol into cigarette mainstream smoke is similar to the tar-puff behavior of cigarette mainstream smoke. On the other hand, the sweet flavor (ethyl butyrate) encapsulated in cyclodextrin remains in the cotton yarn during the above storage and is released depending on the amount of mainstream smoke that passes through the mainstream smoke through the filter due to smoking. Therefore, compared with menthol not included in cyclodextrin, the sweetness is strongly expressed in the first half of smoke absorption.
 例2
 この例では、以下の通り、L-メントール含有デキストリン粉末を製造した。 
 すなわち、精製水59重量部に、乳化剤としてショ糖脂肪酸エステル(三菱化学フーズ社製「リョートーシュガーエステルS-1170」)1重量部を添加し、60℃で10分間攪拌した。得られた溶液に、デキストリン(三和澱粉社製「サンデック#185」)40重量部を添加し、30分間攪拌した。得られた溶液を50~60℃に保持しながら、L-メントール13.67重量部を添加し、溶解させた。得られた溶液を、TKホモミキサーにより12000rpmで10分間乳化させてスプレー溶液を得た。このスプレー溶液を50~60℃に保持しながら、スプレードライヤー(藤崎電機社製「スプレードライヤーMDL-050M」に送り、180℃で噴霧乾燥した。こうして、L-メントール25重量%を含有したデキストリン粉末を得た。
Example 2
In this example, L-menthol-containing dextrin powder was produced as follows.
That is, 1 part by weight of sucrose fatty acid ester (“Ryoto Sugar Ester S-1170” manufactured by Mitsubishi Chemical Foods Co., Ltd.) as an emulsifier was added to 59 parts by weight of purified water and stirred at 60 ° C. for 10 minutes. To the obtained solution, 40 parts by weight of dextrin (“Sandek # 185” manufactured by Sanwa Starch Co., Ltd.) was added and stirred for 30 minutes. While maintaining the obtained solution at 50 to 60 ° C., 13.67 parts by weight of L-menthol was added and dissolved. The obtained solution was emulsified with a TK homomixer at 12000 rpm for 10 minutes to obtain a spray solution. While maintaining this spray solution at 50 to 60 ° C., it was sent to a spray dryer (“Spray Dryer MDL-050M” manufactured by Fujisaki Electric Co., Ltd.) and spray-dried at 180 ° C. Thus, dextrin powder containing 25% by weight of L-menthol Got.
 次に、通常のフィルタ製造機に、イギリス式番手表示で20/16の漂白綿糸のチーズ、香料槽、香料送給ポンプ、香料アプリケータ等からなる香料放出部材製造装置を付設し、その香料槽にL-メントールのポリプロプレン溶液(濃度70%)またはポリプロピレングリコールに分散させた上記L-メントール含有デキストリン粉末を入れた。香料放出部材製造装置とフィルタ製造機を駆動し、所望のフィルタ長尺体を作製した。フィルタ本体を構成するセルロースアセテート繊維トウの仕様は、単繊度3.5デニール、総繊度35000デニールであり、各繊維の断面形状はY字状であった。フィルタラッパーは、例1で用いたものと同じであった。得られたフィルタ長尺体は、円周が24.5mmであり、長さが100mmであった。香料を担持した綿糸は、フィルタ長尺体の中央に挿通された。 Next, a perfume discharge member manufacturing apparatus comprising a 20/16 bleached cotton yarn cheese, a perfume tank, a perfume feed pump, a perfume applicator and the like is attached to a normal filter manufacturing machine, and the perfume tank. The L-menthol-containing polypropylene solution (concentration 70%) or the above-mentioned L-menthol-containing dextrin powder dispersed in polypropylene glycol was placed in The fragrance | flavor discharge | release member manufacturing apparatus and the filter manufacturing machine were driven, and the desired filter elongate body was produced. The specifications of the cellulose acetate fiber tow constituting the filter body were a single fineness of 3.5 denier and a total fineness of 35000 denier, and the cross-sectional shape of each fiber was Y-shaped. The filter wrapper was the same as that used in Example 1. The obtained long filter body had a circumference of 24.5 mm and a length of 100 mm. The cotton yarn carrying the fragrance was inserted into the center of the long filter body.
 得られたフィルタ長尺体を用いた以外は、例1と同様に、2種類のフィルタ付きシガレット試料AおよびBを作製した。フィルタ付きシガレット試料Aは、デキストリンに含有させていないL-メントール(添加量:25mmのフィルタ長当たり11.5g)を含むものであり、フィルタ付きシガレット試料Bは、上記デキストリン粉末に含有させたL-メントール(添加量:25mmのフィルタ長当たり10.0g)を含むものであった。なお、フィルタシガレット試料AおよびBにおいて、両フィルタの通気抵抗は、同じであった。 Two types of cigarette samples A and B with a filter were prepared in the same manner as in Example 1 except that the obtained long filter body was used. The cigarette sample A with a filter contains L-menthol not added to the dextrin (addition amount: 11.5 g per 25 mm filter length), and the cigarette sample B with the filter contains the L-menthol contained in the dextrin powder. -It contained menthol (addition amount: 10.0 g per 25 mm filter length). In filter cigarette samples A and B, the ventilation resistance of both filters was the same.
 得られたフィルタ付きシガレット試料AおよびBを、例1と同様に1ヶ月保管した後、パフ毎の主流煙中のメントール量を以下のように測定した。 The obtained cigarette samples A and B with a filter were stored for one month in the same manner as in Example 1, and then the amount of menthol in the mainstream smoke for each puff was measured as follows.
 5本掛けロータリー型自動喫煙器を用い、同じ仕様のフィルタ付きシガレット試料を5本セットし、ISO標準喫煙条件下で7パフまで喫煙を行った。パフ毎に、予め設置したガラス繊維フィルタにシガレット主流煙成分を捕集し、これをエタノールで抽出し、ガスクロマトグラフによりメントール量を測定した。同じ仕様のシガレット試料につき同じ操作を2回行い、パフ毎の主流煙中のメントール量の平均値を算出し、その平均値を、7パフ合計のメントール量の平均値で除して、百分率で表し、評価結果とした。結果を下記表2に示す。
Figure JPOXMLDOC01-appb-T000002
Five cigarette samples with filters of the same specification were set using a 5-spindle rotary type automatic smoker, and smoked up to 7 puffs under ISO standard smoking conditions. For each puff, cigarette mainstream smoke components were collected on a glass fiber filter installed in advance, extracted with ethanol, and the amount of menthol was measured by gas chromatography. Perform the same operation twice for the cigarette sample of the same specification, calculate the average value of the menthol amount in the mainstream smoke for each puff, and divide the average value by the average value of the menthol amount of the total of 7 puffs. It was expressed as an evaluation result. The results are shown in Table 2 below.
Figure JPOXMLDOC01-appb-T000002
 また、表2に示す結果をグラフとして図7に示す。図7において線分aは、試料Aについての結果を、線分bは、試料Bについての結果を示す。 Also, the results shown in Table 2 are shown as a graph in FIG. In FIG. 7, the line segment a indicates the result for the sample A, and the line segment b indicates the result for the sample B.
 試料Aと試料Bについての結果を比較してわかるように、パフの進行につれ、主流煙中のメントールの量、すなわちメントール感の強さが両者間で大きく異なる。試料Bにおいては、メントールをデキストリンに含有(担持)させているので、フィルタを通過する主流煙中の水分によってメントールがデキストリンから放出されるので、7パフ目で主流煙中のメントール量が著しく増加している。この現象は、6パフまでの水分の累積と、フィルタに燃焼部が近づくことで通気性を有するシガレット巻紙による主流煙の希釈が相対的に減少することにより、フィルタを通過する主流煙中の水分温度が上昇することがその要因と考えられる。 As can be seen by comparing the results for Sample A and Sample B, as the puff progresses, the amount of menthol in the mainstream smoke, that is, the strength of the menthol feeling, differs greatly between the two. In Sample B, since menthol is contained (supported) in dextrin, menthol is released from the dextrin by moisture in the mainstream smoke passing through the filter, so that the amount of menthol in the mainstream smoke increases significantly at the seventh puff. is doing. This phenomenon is caused by the accumulation of water up to 6 puffs and the relative reduction in dilution of mainstream smoke by cigarette wrapping paper that has air permeability due to the proximity of the combustion section to the filter. The reason is that the temperature rises.
 例1および例2に示すように、種々の香料を担持した香気放出部材からの香気放出挙動が明らかとなった。これらの香気放出挙動の結果から、本発明に従い、それぞれ異なる香料を担持する複数本の香料放出部材を組み込んだフィルタを付設したシガレットが、パフ毎に異なる香りを味わうことを可能にすることが明らかであろう。 As shown in Examples 1 and 2, the fragrance release behavior from the fragrance release member carrying various fragrances was clarified. From the results of these fragrance release behaviors, it is clear that cigarettes equipped with a filter incorporating a plurality of fragrance release members each carrying different fragrances according to the present invention make it possible to taste different fragrances for each puff. Will.
 10,20,30,420…フィルタ、110…フィルタ本体、121~122,221~223,310…香気放出部材、121a,122a,221a,222a,223a,310a…個別糸、130…フィルタラッパー、40…フィルタ付きシガレット、410…シガレットロッド、411…タバコ充填材ロッド、412…シガレット巻紙、430…チップペーパー 10, 20, 30, 420 ... filter, 110 ... filter body, 121-122, 221-223, 310 ... aroma release member, 121a, 122a, 221a, 222a, 223a, 310a ... individual yarn, 130 ... filter wrapper, 40 ... Cigarette with filter, 410 ... Cigarette rod, 411 ... Tobacco filler rod, 412 ... Cigarette paper, 430 ... Chip paper

Claims (5)

  1.  フィルタ本体、および1本以上の個別糸からなる香料担体と、前記香料担体に担持された複数の香気放出成分とを含む香気放出部材を備え、前記香気放出部材は、前記フィルタ本体の中心軸に沿って延びるように前記フィルタ本体内に組み込まれ、一の香気放出成分は、他の一またはそれ以上の香気放出成分とは異なる香料香気を放出し、一の香気放出成分の香料放出挙動は、他の一またはそれ以上の香気放出成分の香料放出挙動と異なり、前記香気放出成分は、純香料、サイクロデキストリンと組み合わされた純香料およびデキストリンと組み合わされた純香料からなる群の中から選ばれることを特徴とするシガレット用フィルタ。 A fragrance carrier comprising a filter body and a fragrance carrier comprising one or more individual yarns, and a plurality of fragrance release components carried on the fragrance carrier, wherein the fragrance release member is disposed on a central axis of the filter body; Embedded in the filter body so as to extend along, one fragrance releasing component emits a fragrance fragrance different from one or more other fragrance releasing components, and the fragrance releasing behavior of one fragrance releasing component is: Unlike the fragrance release behavior of one or more other fragrance release components, the fragrance release component is selected from the group consisting of pure fragrance, pure fragrance combined with cyclodextrin, and pure fragrance combined with dextrin Cigarette filter characterized by the above.
  2.  前記香料担体が、複数の個別糸からなり、前記複数の香気放出成分は、それぞれ異なる個別糸に担持されている請求項1に記載のシガレット用フィルタ。 The cigarette filter according to claim 1, wherein the fragrance carrier is composed of a plurality of individual yarns, and the plurality of fragrance release components are respectively carried on different individual yarns.
  3.  前記複数の香気放出成分が、1本の個別糸に担持されている請求項1に記載のシガレット用フィルタ。 The cigarette filter according to claim 1, wherein the plurality of aroma release components are carried on one individual yarn.
  4.  前記個別糸が、着色されている請求項1~3のいずれか1項に記載のシガレット用フィルタ。 The cigarette filter according to any one of claims 1 to 3, wherein the individual yarn is colored.
  5.  シガレットロッドと、前記シガレットロッドの一端に接続されたフィルタを備え、前記フィルタが請求項1~4のいずれか一項に記載のフィルタにより構成されるフィルタ付きシガレット。 A cigarette with a filter comprising a cigarette rod and a filter connected to one end of the cigarette rod, the filter comprising the filter according to any one of claims 1 to 4.
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JPWO2012105453A1 (en) 2014-07-03
CN103458718A (en) 2013-12-18
EP2671461A4 (en) 2017-03-15
RU2013140541A (en) 2015-03-10
US20130312778A1 (en) 2013-11-28
TW201236588A (en) 2012-09-16
CN103458718B (en) 2015-03-25
EP2671461A1 (en) 2013-12-11

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