WO2012103602A1 - Dissolution de c02 - Google Patents

Dissolution de c02 Download PDF

Info

Publication number
WO2012103602A1
WO2012103602A1 PCT/BE2012/000003 BE2012000003W WO2012103602A1 WO 2012103602 A1 WO2012103602 A1 WO 2012103602A1 BE 2012000003 W BE2012000003 W BE 2012000003W WO 2012103602 A1 WO2012103602 A1 WO 2012103602A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
gas
previous
zone
dissolution
Prior art date
Application number
PCT/BE2012/000003
Other languages
English (en)
Inventor
Guy DERDELINCKX
Johan Martens
Jan RONGÉ
Firmin VELGHE
Original Assignee
Katholieke Universiteit Leuven
M4E N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Katholieke Universiteit Leuven, M4E N.V. filed Critical Katholieke Universiteit Leuven
Publication of WO2012103602A1 publication Critical patent/WO2012103602A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2373—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm
    • B01F23/2375—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm for obtaining bubbles with a size below 1 µm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B01F23/23231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits being at least partially immersed in the liquid, e.g. in a closed circuit
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/236—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2373—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/238—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using vibrations, electrical or magnetic energy, radiations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3131—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit with additional mixing means other than injector mixers, e.g. screens, baffles or rotating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3133—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit characterised by the specific design of the injector
    • B01F25/31331—Perforated, multi-opening, with a plurality of holes
    • B01F25/313311—Porous injectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/45—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4521—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through orifices in elements, e.g. flat plates or cylinders, which obstruct the whole diameter of the tube
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • B01F25/53—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is discharged from and reintroduced into a receptacle through a recirculation tube, into which an additional component is introduced
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/05—Mixers using radiation, e.g. magnetic fields or microwaves to mix the material
    • B01F33/053—Mixers using radiation, e.g. magnetic fields or microwaves to mix the material the energy being magnetic or electromagnetic energy, radiation working on the ingredients or compositions for or during mixing them
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00—Fermentation processes for beer
    • C12C11/11—Post fermentation treatments, e.g. carbonation, or concentration
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/481—Treatment of water, waste water, or sewage with magnetic or electric fields using permanent magnets
    • C02F1/482—Treatment of water, waste water, or sewage with magnetic or electric fields using permanent magnets located on the outer wall of the treatment device, i.e. not in contact with the liquid to be treated, e.g. detachable
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/484—Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/24—CO2

Definitions

  • the present invention relates generally to an apparatus and method for enhanced dissolving or dissolving with an increased saturation efficiency of carbon dioxide (CO2) into an aqueous liquid, more particularly to a system and method for enhanced C02 in water dissolution from CO2 gas.
  • the present invention relates in particular to an apparatus and method for in-line carbonation of aqueous liquids with increased dissolving with increased saturation efficiency of CO2 from a CO2 gas or from gas whereof an essential part is C02.
  • One method for carbonating aqueous liquids involves using yeast.
  • some yeast is added to a sweet sugar-based liquid.
  • the yeast bacteria consume the sugars and produce carbon dioxide as a by-product.
  • This carbon dioxide production continues for a number of days in a warm environment after which it is to be kept refrigerated.
  • This ferment carbonation can result in a CO2 content of about 3 g/1 or a bit more depending on the height of the fermentation tank.
  • additional carbonation by additional or other means is still necessary, in particular for two reasons. Firstly the natural carbonation process during fermentation is not sufficiently reliable or controllable to steer it to a desired and/or predictable end concentration of solved CO2.
  • a possible physical process of producing carbonated water (water containing carbon dioxide) or other carbonated aqueous liquids can be by passing carbon dioxide under pressure through such water or other aqueous liquid.
  • the process usually involves high pressures of carbon dioxide at a relatively high especially when the system is susceptible to pressure drops, whereby carbon dioxide used for carbonation is compressed carbon dioxide.
  • the solubility of CO2 in water varies according to the temperature of the water and the pressure of the gas. It decreases with increased temperature and increases with increased pressure. At 15.5°C and a pressure of 1 atm (15 psi), water will absorb its own volume of carbon dioxide.
  • Raising the pressure to 10 atm (150 psi) will bring about an increase in the gas solubility to around 9.5 volumes. Since it is easy it is simpler to carbonate if the product temperature is low early carbonators used refrigeration to carbonate at ca. 4°C. For instance the product is spread over chilled plates, such that the product runs down the plates as a thin film. This is carried out in a constant pressure carbon dioxide atmosphere. The product being chilled as a film maximises the surface area available to the carbon dioxide thus promoting effective carbonation. This energy usage of this process is however high.
  • Japanese Patent No. 2, 810,694 which describes the use of a hollow yarn membrane module incorporating plural porous hollow yarn membranes whose both ends are open and further the Japanese Patent Nos. 3,048,499 and the 3,048,501, Japanese Patent Application Laid-Open No.2001-293344 and the like which propose methods of using a nonporous hollow yarn membrane as a hollow yarn membrane.
  • carbonated water is produced using a membrane, a so- called one-pass type in which carbonated water is produced by passing raw water through a carbon dioxide gas dissolver having a membrane module.
  • the Japanese Patent JP2006020985 describes the use of micropore systems in an apparatus for diffusing carbon dioxide in a water volume.
  • Another method for carbonating liquids includes using dry ice as a source of carbon dioxide.
  • carbon dioxide is in a solid state, and is placed into the liquid to be carbonated.
  • the carbon dioxide sublimates from a solid to gaseous state, and carbonates the liquid.
  • Such beer foam further comprises polypeptides of different groups with different relative hydrophobicity. As the hydrophobicity of the polypeptide groups increases, so does the stability of the foam.
  • the dissolved CO2 is responsible for the flavour. If a beer is not properly saturated with carbonic acid then beer's characteristics of full taste is lacking or a feeling of full taste is not observed by a significant portion of consumers, representatives in a taste panel or beer sommeliers. Moreover above a certain level of carbonation carbon dioxide has a preserving property, having an effective antimicrobial effect against moulds and yeasts.
  • Present invention provides a solution for enhanced dissolving of C0 2 gas into an aqueous liquid.
  • the system of invention provides improvements on above mentioned drawbacks.
  • the present invention solves the problems of the related art by provided a system that allows a selective increase of the dissolution efficiency of some gas compounds versus other gas compounds out of a gas mixture.
  • the invention is broadly drawn to a flow through and eventually recirculation method of C0 2 has and a flow through or flow through recirculation apparatus for enriching an aqueous liquid fluid with CO2 compounds of the flow through CO2 gas.
  • the method and apparatus can be used CO2 dissolution in small volume reservoirs (for instance bottles) or in large liquid bodies (for instance in industrial reactors).
  • the present invention relates generally to an apparatus and method for increased dissolving with increased saturation efficiency of CO2 into an aqueous liquid from a CO2 gas or from gas whereof an essential part is C02.
  • present invention concerns enhancing dissolution of CO2 molecules in an aqueous liquid from a CO2 gas stream.
  • the CO2 gas fluid and aqueous liquid fluid are combined in a line or fluid conduit (e.g. tube or pipe) and flow through a zone of reduced pressure under a permanent field which is generated by a surrounding permanent magnet or assembly of permanent magnets.
  • the apparatus can be further foreseen further downstream with a fluid reservoir in a closed container (e.g. closed drum) to with a valve outlet to tap volumes of said carbonated aqueous liquid.
  • a fluid reservoir in a closed container e.g. closed drum
  • the CO2 gas fluid is aspirated in the confined environment of the flow through (eventually recirculation) system.
  • the CO2 gas can be released from a pressurized CO2 gas storage container or carbon dioxide storage systems or it can be sucked through the inlet port into a zone of the liquid fluid line or fluid conduit (e.g. tube or pipe ) which has a narrower inner diameter than upstream or downstream of the narrower passage so that if operational the motile liquid in this constricted section of the liquid fluid line or fluid conduit (e.g. tube or pipe ) will induce a pressure drop in the zones compared to directly upstream or downstream or even near vacuum creation that is compensated by aspiration of the CO2 gas fluid through a gas inlet port.
  • a zone of the liquid fluid line or fluid conduit e.g. tube or pipe
  • the liquid fluid line or fluid conduit e.g. tube or pipe
  • the CO2 gas is released through a porous device as vapour bubbles locoregional or adjacent before , neighboring before or in front near or abut the zone of the liquid fluid line or fluid conduit (e.g. tube or pipe ) which has a narrower inner diameter than upstream or downstream of the narrower passage or alternatively locoregional or adjacent before , neighboring before or in front near or abut the zone in the liquid fluid line or fluid conduit (e.g. tube or pipe ) which is separated by an in line entrance shield or wall and an outlet shield or wall which comprises openings that are smaller than the inner diameter of the liquid fluid line or fluid conduit (e.g. tube or pipe ).
  • the zone of the liquid fluid line or fluid conduit e.g. tube or pipe
  • the zone in the liquid fluid line or fluid conduit e.g. tube or pipe
  • an outlet shield or wall which comprises openings that are smaller than the inner diameter of the liquid fluid line or fluid conduit (e.g. tube or pipe ).
  • the CO2 gas fluid and liquid fluid is mixed under a magnetic field, preferably a permanent magnetic field, while passing through a section of the conduit that is surrounded a permanent magnet or permanent magnet assembly or an electro conductive coil.
  • This section can be with narrower inner diameter than upstream or downstream or can be shielded or formed by the in line transversal wall with openings smaller than the inner diameter of said the liquid fluid line or fluid conduit (e.g. tube or pipe).
  • a means to increase the effective magnetic field is to flow the aqueous liquid through a number of magnets arranged in series (especially for limiting or prolonging the duration of treatment) and/or to re-circulate the aqueous liquid several times, i.e. preferably at least 10 times, more preferably at least 40 times, through the same magnetic field.
  • each said magnetic field used for carrying out the method of the invention is at least about 0.2 Telsa (2,000 gauss) or at least 0,2 Telsa (2,000 gauss) at the active region thereof and preferably in at a value from the range of 0,20 to 2 Tesla, more preferably of 0,50 to 1,5 Tesla, yet more preferably of 0,60 to 1,20 Tesla and yet more preferably of 0.65 to 1 Tesla, yet more preferably of 0,70 to 0,80 Tesla and most preferably of 0,75 Tesla or about 0,75 Tesla and the flow rate through each said magnetic field of the aqueous liquid to be carbonated is at a value from the range of 0,1 to 5 1/s, more preferably 0,15 to 0,3 and yet more preferably 0,2 to 2,5 1/s.
  • magnetic field used for carrying out the method of the invention is at least about 0.2 Telsa (2,000 gauss) or at least 0,2 Telsa (2,000 gauss) at the active region thereof and preferably in at a value from the range of 0,20 to 2 Tesla, more preferably of 0,50 to 1,5 Tesla, yet more preferably of 0,60 to 1,20 Tesla and yet more preferably of 0.65 to 1 Tesla, yet more preferably of 0,70 to 0,80 Tesla and most preferably of 0,75 Tesla or about 0,75 Tesla and the linear flow rate of said aqueous fluid flowing through each said magnetic field is between 0.25 and 25 m/s. Further scope of applicability of the present invention will become apparent from the detailed description given hereinafter.
  • Metal means a metal or an alloy of one or more metals.
  • Microbubble means a bubble with a diameter less than 50 microns.
  • Nanobubble means a bubble with a diameter less than that necessary to break the surface tension of water. Nanobubbles remain suspended in the water, giving the water an opalescent or milky appearance.
  • a nanobubble under the critical diameter is a nanobubble with a diameter under 110 nm, preferably under 100 nm and yet more preferably under 90 nm .
  • such C0 2 nanobubbles under the critical diameter are generated by a nonobubbles generator to achieve an effect of increased CO2 when forced through the magnet mixer of present invention.
  • At higher that pressure than atmospheric pressure such nanobubble under the critical diameter are yet smaller.
  • Supersaturated means CO2 at a higher concentration than normal calculated CO2 solubility at a particular temperature and pressure.
  • Supercarbonated water means water with an CO2 content at least 120% of that calculated to be saturated at a temperature.
  • An "aqueous medium” can be water but it can for instance also comprise a beverage or a beverage concentrate for instance a beverages such as coffee, coffee-flavoured milk, black tea, tea with milk, soybean milk, nutrition-supplement drink, vegetable drink, vinegar drink, juice, cola, mineral water, sport drink, and the like; alcohol drinks such as beer, wine, cocktail, sour, and the like; milk and dairy products such as milk, yogurt, cheese, and the like; and others.
  • a beverages such as coffee, coffee-flavoured milk, black tea, tea with milk, soybean milk, nutrition-supplement drink, vegetable drink, vinegar drink, juice, cola, mineral water, sport drink, and the like
  • alcohol drinks such as beer, wine, cocktail, sour, and the like
  • milk and dairy products such as milk, yogurt, cheese, and the like; and others.
  • Water means a fluid wherein the main chemical substance is with the chemical formula H 2 0.
  • the present invention water can have different origins or uses it can be one or more of the following groundwater, meltwater, meteoric water, fresh water, surface water, mineral water, brackish water, seawater, tap water, bottled water, drinking water or potable water, purified water, laboratory-grade, analytical-grade or reagent-grade water or highly purified often broadly classified as Type I, Type II, or Type III in this category including but is not limited to distilled water, double distilled water or deionized water, soft water , hard water; distilled water, double distilled water, deionized water, drinking water, wastewater and/or surface water.
  • Water, as the main component of a soft drink usually accounts for between 85 and 95% of the product and acts as a carrier for the other ingredients.
  • Carbonation usually refers to the dissolving of carbon dioxide in an aqueous solution and carbonation occurs when carbon dioxide is dissolved in water or an aqueous solution. This process is generally represented a reaction, where water and gaseous carbon dioxide react to form a dilute solution of carbonic acid.
  • the amount of carbon dioxide which a solution can maintain depends on the temperature and pressure. The higher the temperature the greater the pressure required to maintain the carbon dioxide in solution. Conversely, the lower the temperature the greater the amount of carbon dioxide that is retained in Solution. Any decrease in pressure, or increase in temperature, will render the mixture metastable, that is, supersaturated, such that the temperature/pressure combination is insufficient to keep the carbon dioxide in solution.
  • Dissolved carbon dioxide can be measured and expressed.
  • Carbon dioxide storage systems are available in the art. They are normally sited outside with suitable weather protection for the associated electrical equipment or when situated inside a building then adequate ventilation is provided. Basic requirement of such tank is to maintain a constant tank temperature independent of the environment and the withdrawal rate of the CO2 gas.
  • the tank is normally insulated with at least 10 cm thick urethane. This is normally covered with a pre-painted aluminium jacket.
  • the actual tank is usually constructed in fine-grain carbon steel. It is normal practice for a bulk vessel to have at least two suitably sized relief valves, connected to the vessel via a changeover valve. This allows one valve to be maintained whilst the other is in operation. A normal storage pressure is in the region of 20.5 bar at -17°C. This has been found to be the most practical operating level and has been adopted as the worldwide standard by most carbon dioxide suppliers.
  • the solubility of gases is generally defined by Henry's law is used to quantify the solubility of gases in solvents.
  • the solubility of a gas in a solvent is directly proportional to the partial pressure of that gas above the solvent. This relationship is written as: where kH is a temperature-dependent constant, p is the partial pressure (atm), and c is the concentration of the dissolved gas in the liquid (mol/L).
  • the solubility of gases is sometimes also quantified using Bunsen solubility coefficient.
  • solvation is defined as an interaction of a solute with the solvent, which leads to stabilization of the solute species in the solution.
  • solvated state whereby an ion in a solution is complexed by solvent molecules.
  • the concept of the solvation interaction can also be applied to an insoluble material, for example, solvation of functional groups on a surface of ion-exchange resin.
  • Solvation is, in concept, distinct from dissolution and solubility.
  • Dissolution is a kinetic process, and is quantified by its rate. Solubility quantifies the dynamic equilibrium state achieved when the rate of dissolution equals the rate of precipitation. The consideration of the units makes the distinction clearer. Complexation can be described by coordination number and the complex stability constants. The typical unit for dissolution rate is mol/s. The unit for solubility can be mol/kg.
  • the device of present invention concerns to increase the dissolution, solubility or solvation of C0 2 compounds in a watery fluid by dissolving such under reduced pressure and under magnetization or by releasing microbubbles of such CO2 gas in watery fluid under reduced pressure and under magnetization comprises use of magnets electromagnets or preferably permanent magnets.
  • a permanent magnet is an object made from a material that is magnetized and creates its own persistent magnetic field. Materials that can be magnetized, which are also the ones that are strongly attracted to a magnet, are called ferromagnetic (or ferromagnetic). These include iron, nickel, cobalt, some alloys of rare earth metals, and some naturally occurring minerals such as lodestone.
  • Ferromagnetic materials can be divided into magnetically "soft” materials like annealed iron which can be magnetized but don't tend to stay magnetized and magnetically “hard” materials, which do.
  • Permanent magnets are made from “hard” ferromagnetic materials which are subjected to special processing in a powerful magnetic field during manufacture, to align their internal microcrystalline structure, making them very hard to demagnetize.
  • Different types of permanent magnets are suitable for present invention for instance permanent magnets comprising magnetic metallic elements, composite permanent magnets, injection molded permanent magnets, flexible permanent magnets, rare earth magnets, single-molecule magnets (SMMs) and single-chain magnets (SCMs° or nano-structured magnets.
  • Magnetic metallic elements concerns magnets that are composed of or that comprise paramagnetic materials which have unpaired electron spins, for instance such paramagnetic materials such as iron ore (magnetite or lodestone), cobalt and nickel, as well the rare earth metals gadolinium and dysprosium (when at a very low temperature).
  • Composite permanent magnets comprise materials such as Ceramic or ferrite, Alnico (magnets are made by casting or sintering a combination of aluminium, nickel and cobalt with iron and small amounts of other elements added to enhance the properties of the magnet) or Ticonal (an alloy of titanium, cobalt, nickel, and aluminium, with iron and small amounts of other elements).
  • the injection molded magnets are a composite of various types of resin and magnetic powders, allowing parts of complex shapes to be manufactured by injection molding.
  • the physical and magnetic properties of the product depend on the raw materials.
  • Flexible magnets are similar to injection molded magnets, using a flexible resin or binder such as vinyl, and produced in flat strips, shapes or sheets. These magnets are lower in magnetic strength but can be very flexible, depending on the binder used.
  • Rare earth (lanthanoid) elements have a partially occupied f electron shell (which can accommodate up to 14 electrons.) The spin of these electrons can be aligned, resulting in very strong magnetic fields, and therefore these elements are used in compact high- strength magnets where their higher price is not a concern.
  • SMMs Single-molecule magnets
  • SCMs single-chain magnets
  • D anisotropy of the zero field splitting
  • Nano-structured magnets comprise nano-structured materials which exhibit energy waves called magnons.
  • An electromagnet is a type of magnet whose magnetic field is produced by the flow of electric current. The magnetic field disappears when the current ceases.
  • a possible set up for present invention is simple electromagnet consisting of a coil of insulated wire wrapped around the metal liquid fluid line or fluid conduit (e.g. tube or pipe) forming the magnetic zone for enhanced C0 2 gas dissolution. The strength of magnetic field generated is proportional to the amount of current.
  • a rotary vane pump with a period of 28s recirculated water was pumped through a liquid guidance pipe in a recirculation system which comprised liquid guidance lines, the pump, a water sampling unit, a CO2 gas guidance connected to the liquid guidance line with its input port connected to porous device, sintered porous metal length 195 mm, inner diameter 16 mm and pores of 25 ⁇ (Cegelec/M4E) in the gas guidance line to introduce carbon dioxide inline in the liquid guidance line through the porous device, a gas debit meter (Cegelec/M4E) to sense and control the C0 2 flow into the liquid guidance line, and further comprising a container or closed reservoir (e.g.
  • Solved C0 2 was measured online by a CCh-sensor (Hach UltraTM Orbisphere 3658) for selective in situ CO2 measurement. The solved CO2 concentration was also measured by a GC analysis (HP 6890 chromatograph with TCD detector). We used a mol sieve type column to have strong adsorption of the water and fast elution of the gas phase. Samples of 4 ⁇ (1:15 split ration) were injected and helium was the drive gas.
  • the device of the present invention was allowed to take in CO2 gas to solve this CO2 in a line or fluid conduit (e.g. tube or pipe) that recirculated water back towards the closed container (e.g. drum or closed reservoir).
  • a line or fluid conduit e.g. tube or pipe
  • the closed container e.g. drum or closed reservoir.
  • Each such experiment was operated with two experimental conditions: 1) whereby the device of present invention was operated without magnet and 2) the condition whereby the device of present invention was operated with magnet (Cegelec/M4EJ.
  • the water temperature was 15-20 °C.
  • the magnet induced a magnetic field of 0.75 Tesla.
  • Carbon dioxide from a carbon dioxide tank or carbon dioxide storage systems was guided through a gas guidance pipe towards a beer guidance tube and the carbon dioxide was introduced in line of the beer guidance tube through porous device (a sintered porous metal).
  • a permanent magnet (Cegelec/M4E) is placed surrounding the liquid guidance conduit (tube, pipeline or duct) next after the sintered porous metal.
  • the zone in the liquid guidance tube on which the surrounding magnet can be mounted is separated at the proximal and at the distal end inline septum, wall or partition wherein there is a at least one opening which opening(s) have a surface that is smaller than the inner diameter of the liquid guidance conduit (tube, pipeline or duct) Cegelec/M4E). This forms the magnet zone when the magnet is mounted.
  • Example 1 In a first phase we operated the system of present invention (Example 1) under atmospheric pressure (water reservoir open - water in contact with air) and CO2 gas was introduced inline according to the protocol of example 1. In a second phase the system was closed (confined water reservoir) and the pressure was increased up to 1.5 bar and CO2 gas was introduced inline according to the protocol of example 1. When the magnet was mounted on the recirculation system a considerable increase of CO2 solution was obtained. The water temperature was 15-20 °C.
  • Example 1 In a first phase we operated the system of present invention (Example 1) under atmospheric pressure (water reservoir open - water in contact with air) and CO2 gas was introduced inline according to the protocol of example 1. In a second phase the system was closed (confined water reservoir) and the pressure was increased up to 2.5 bar. When the magnet was mounted on the recirculation system a considerable increase of CO2 solution was obtained; The water temperature was 15-20 °C.
  • Figure 4 provides a graphic display of dissolved CO2 in the experiment at 2,5 bar
  • the retardation or phase lag was 20 s. This can be explained because in this experimental set up the dissolved CO2 concentration was measured after the sintered metal and in its direct proximity instead of after the sintered metal two meters further in the water guidance pipeline.
  • the concentration of dissolved CO2 increased with 2,8 %/s whereby a maximal level was reached after 60 s (2,1 period of recirculation).
  • concentration of dissolved CO2 increased with 1,6 %/s whereby a maximal level was reached after 100 s (3,6 periods of recirculation).
  • Figure 11 is a graphic display of the dissolved CO2 concentration for mixing of CO2 vapor nanobubbles in water under a magnetic field or without magnetic field the speed of CO2 solving and the yield is displayed.
  • the magnetic field induces a faster solution of the C0 2 gas that was introduced inline as vapor bubbles in motile or flowing water and mixed with the liquid phase under a magnetic field.
  • the CO2 gas dissolution is faster and its yield is higher (expressed as % of introduced C0 2 gas that is dissolved).
  • Figure 11 displays the average time to reach the maximal levels and the maximal reached yield per experiment per experiment.
  • Figure 1 2 provides a graphic display on the dissolved C0 2 -concentration with and without venturi mixing at 1 bar in the water guidance line after the venture system (as displayed in a graphic scheme in Fig. 19 A). .
  • Fig 19 B the watery liquid as vapour bubbles
  • Fig. 19 A a venturi mixture
  • the first system of fig 19 B whereby C0 2 gas is passed through a nanobubble generator for generation generation C0 2 gas nanobubbles or C0 2 gas micro/nanobubbles (comprising nanoscale-sized C0 2 bubbles) for instance by pushing it under pressure or by a gas pump through a microporous devices to release nanobubbles.
  • the proximal part (where it joined in the liquid fluid guidance conduit (pipeline, tube or duct) near the magnetic mixer) of the C0 2 inlet port comprises a nanobubble creation means for instance microporous means to inflow in the aqueous fluid C0 2 gas in the form of vapour bubbles with a critical diameter under 110 nm, preferably under 100 nm and most preferably under 90 nm.
  • the microporous means can be in the form of a plate but it can be formed in various geometrical forms. It further may comprise or consist of various materials such a ceramic in case it comprises a micro-porous ceramic filter.
  • the sintered metal device of Cegelec/M4E (Fig 16 see element (5)).
  • vapor nanobubbles with critical diameter are released near or abut the entrance of a magnet venture mix for instance they are released near or abut the septum , wall or partition ((7) in fig 19 B) with entrance opening or openings (which is or are together narrower than inner transverse section of the liquid guidance conduit (pipeline, tube or duct)) into the magnetic zone in the liquid guidance conduit (pipeline, tube or duct).
  • a second system for efficient carbonation of aqueous fluids that we observed is displayed in the graphic scheme of fig. C.
  • the C0 2 gas is introduced near or abut or in the magnetic zone directly in the zone of reduced pressure of a magnet venture.
  • Figure 13 provides a graphic display on the dissolved C02-concentration for a C0 2 gas that was introduced into the water stream under a pressure of 1 bar.
  • This study on the flow levels of CO2 gas and water provided the following observations.
  • Example 7 Disinfection of the aqueous fluids in the magnet system
  • the samples were spread in blood-agar plates and then were incubated at 37°C in a bacteriology laboratory. After one day the results were expressed in total number of colonies per plate.
  • the control group consisted of the same set up with the same amount of E. coli passing through demagnetized control device (CD). Results were compared with a student t-test for dependent samples. The table shows a statistically significant reduction in the number of colonies in the infected urine after passing through the permanent magnetic device at 4 hrs and at 8hrs. In the control group there were no statistical changes.
  • the method according to the invention involves re-circulating (e.g. in a closed circuit) two or more times a C02 gas fluid / aqueous liquid fluid mixture through a magnetic field(s) preferably of 0.20 to 2 Tesla, more preferably of 0.50 to 1.5 Tesla, yet more preferably of 0.60 to 1.20 Tesla and yet more preferably of 0.65 to 1 Tesla, yet more preferably of 0.70 to 0.80 Tesla and most preferably of 0.75 Tesla or about 0.75 Tesla.
  • the magnetic field in a specific zone of the liquid guidance conduit can for instance be created by a permanent magnet or by an electromagnet.
  • the number of re-circulation times may be easily adapted to the specific average size targeted for the specific bioactive compound involved in a certain application.
  • the CO2 gas fluid / aqueous liquid fluid mixture is flowed or circulated through the magnetic field (s) at a speed which allows the magnetic treatment to effectively perform a size reduction of the vapour bubbles to a significant extent.
  • the linear flow rate of said fluid through each said magnetic field is between about 0.25 and 25 m/s.
  • the residence time of said fluid through each said magnetic field is preferably between about 60 microseconds and 10 seconds, depending upon the number or recirculation times.
  • the magnetic treatment of the invention resulted in a size reduction of the CO2 vapour bubbles in the liquid fluid of a gas that was infused in said the liquid fluid under reduced pressure directly in said the magnet venture or if the C0 2 was released a vapour bubbles with a size under a critical size of less than 100 nm in nearby in front of the magnet venturi.
  • the bubble size distributions in the gas-liquid flow is altered and the vapour bubbles reduce and C0 2 gas is dissolved when the aqueous liquid is not yet supersaturated or not yet supercarbonated water.
  • vapour bubbles Depending upon the population of vapour bubbles and the extent to which such size reduction occurs, and how it affects the appearance of the fluids by reduction or increase of the vapour bubbles can be measured in tubes and vessels by methods of three-dimensional still pictures and optical particle sizing techniques such as holography, particle imaging velocimetriy and sizing, laser light sheet and particle light scattering techniques. These techniques of sensing are most suitable for droplet well known in the art. Furthermore there are sensors in the art to directly measure the level of CO2 gas solutions in a liquid. Therefore of the magnet field a directly been characterized, as will be described in the following other embodiments of this invention.
  • Beer pipe section 125 mm
  • Dissolved C02 is measured in line by specific ORBISPHERE electrodes located five meters after gas injection
  • Fig. 1 is a graphic display of dissolved C0 2 concentration when CO2 was introduced in the system of example 1 at different pressure.
  • Fig. 2 is a graphic display of dissolved CO2 concentration when C0 2 was introduced in the system of example 1 at atmospheric pressure.
  • Fig. 4 is a graphic display of dissolved C0 2 concentration when CO2 was introduced in the system of example 1 at a pressure of 2,5 bar.
  • Fig 5 shows a member 1 is a transverse section of the liquid fluid line or liquid fluid conduit (e.g. tube or pipe) and 2 is a transverse section of the permanent magnet (Fig. 5A) or of an assembly of permanent magnets (Fig. 5B).
  • Figure 5 provides a picture of a transverse section through the liquid fluid line or liquid fluid conduit (e.g. tube or pipe) and magnet or magnet assembly.
  • the set of permanent magnets can comprise different members of permanent magnets that are adjacent to each other's aligned around the liquid fluid line or liquid fluid conduit (e.g. tube or pipe) whereby the different permanent magnet members are aligned radial around the liquid fluid line or liquid fluid conduit (e.g. tube or pipe (as demonstrated in the transfer section on fig. 5 B).
  • the set or assembly permanent magnet is preferably demountable.
  • Fig 6 provides a schematic overview of the C0 2 gas fluid in liquid fluid enrichment system (11).
  • This enrichment system comprises a closed container or closed reservoir (6) (e.g. drum or tank) which when operational in comprises a passage liquid.
  • the container or closed reservoir (6) has an inlet port and an outlet port.
  • the outlet port can be connected with a recirculation system (10).
  • the recirculation system can comprises a liquid fluid line or liquid fluid conduit (e.g. tube or pipe) (3) which comprises a (recirculation) pump (5) and the CO2 gas injector (1) and magnetic C0 2 gas solubilisation system of present invention (4) as described in the figures 5 - 6 or in figure 18.
  • the examples provide different experimental condition whereby water was recirculated through the system (9) sampled and analysed.
  • the container or closed reservoir (6) (e.g. drum or tank) can comprise a second inlet port (7) and a second outlet port (8) to tap liquid fluid or to provide the container or closed reservoir (6) with new liquid fluid.
  • the examples provide different experimental conditions whereby water was recirculated through the system (9) sampled and analysed.
  • Fig. 7 is a graphic display of the dissolved C0 2 concentration for C0 2 water mixing under a magnetic field or without magnetic field. The speed of C02 solving and the yield are displayed.
  • Fig. 8 is a graphic display of the dissolved C02-concentration with and without venture at 1 bar pressure.
  • Fig. 9 is a graphic display of the dissolved C02-concentration at a pressure of 1 bar, for different C0 2 gas- en water flows.
  • Fig. 10 displays a specific embodiment of entrance device of the zone in the pipeline, tube or duct of the aqueous liquid guidance that can be surrounded by a magnet or magnet assembly.
  • the entrance device is provides with a shield (8) and therein one or more entrance ports (9) and (10).
  • the one or more entrance ports result in the aqueous liquid being forced through a narrower opening than the inner diameter of the pipeline, tube or duct of the aqueous liquid guidance.
  • Specific forms of said the entrance port(s) can induce a turbulence in the magnetic zone for optimal mixing of said the CO2 gas, in particular the gas bubbles, with the aqueous liquid under the magnetic field.
  • Fig 11 displays an embodiment of an output device that can be mounted between aqueous liquid guidance conduits (pipeline, tube or duct) after the magnetic zone (This zone in the pipeline, tube or duct of the aqueous liquid guidance that is designed to be surrounded by a magnet or magnet assembly).
  • This output device has a shield (6) and therein at least one opening or port that is smaller than the inner diameter of the liquid guidance conduits (pipeline, tube or duct); in a preferred embodiment the surface of the opening or port or the multiple openings or ports is smaller than the surface of the opening or port or the multiple openings or ports in the entrance device of the magnetic zone ( Figure 10)
  • Figure 12 and 13 displays the proximal end of the sintered metal device which is mounted at the inlet port of the CO2 gas guidance conduct (tube, pipeline or duct) which is aqueous liquid guidance conduits (pipeline, tube or duct) (2) before the magnetic zone (This zone in the pipeline, tube or duct of the aqueous liquid guidance that is designed to be surrounded by a magnet or magnet assembly).
  • the sintered metal device is in the form of a tube, pipeline or duct with a microporous wall where trough when operational C0 2 vapour bubbles escape.
  • Fig 14 is a graphic display of an embodiment of present invention.
  • Element 3 represent a magnet or a magnet assembly surrounding a particular zone (the magnetic zone) in the liquid guidance conduit (2) (tube, pipeline or duct) which magnetic zone is preceded by a shield with entrance port or ports (e.g. 7) and an end shield with output port or ports (6).
  • a C0 2 guidance conduit (pipeline, tube or duct) (1) enters in the liquid guidance conduit (2) in a zone preceding and neighbouring the magnetic zone at the proximal end of as CO2 guidance conduit (pipeline, tube or duct) (1); the sintered metal device (5) is mounted that if operational releases C0 2 as vapour bubbles through its porous wall.
  • FIG 15 is a graphic scheme of a system whereby the CO2 gas is introduced in the liquid guidance conduit abut to entrance of the magnetic mixer through a nanobubble generator (5) which in the examples is a sintered porous metal tube.
  • CO2 gas can be from a carbon dioxide storage systems (16) for instance a CO2 gas container for instance a cylinder.
  • a drive pump (9) can drive aqueous liquid through a liquid guidance conduit (duct, tube or pipeline) and consequently through the magnet mixer which comprises a 1) liquid guidance conduit (duct, tube or pipeline) (2) with upstream the nanobubble generator (5) and gas fluid outlet and 2) a magnetic zone that is formed by two partitions ((8) or (6)) opposed to the flow direction or positioned transverse in the liquid passage conduit and which partitions have each at least one aperture (7, 9 or 10) so that the aperture area in each partition is smaller or narrower than the internal cross sectional area narrower than respective cross sectional areas of the conduit (directly) upstream and downstream of such partition and whereby 4) a permanent magnet is or an assembly of permanent magnets (3) is mountable adjacent to said zone for instance radially surrounding said conduit of said zone and 4) a gas conduit with an outer input port coupled with a (inject - outlet) port to the liquid conduit in a position to deliver or introduce a gas into the nanobubble generator (5).
  • Figure 16 is a graphic scheme of a magnetic mixer (15) of present invention for CO2 dissolution or carbonation of aqueous fluids bodies while bathing in said the aqueous fluids bodies.
  • Such magnetic mixer of present invention is when operational engaged with a CO2 gas delivery conduit. Instead of bathing in the aqueous fluid body such CO2 dissolution magnetic mixer can be engaged with an aqueous liquid conduit for in line carbonation.
  • Element 3 is a magnet for instance an electromagnet, a permanent magnet or a permanent magnet assembly. (9 and/or 10) is an aperture in a transverse partition in the liquid conduit of said the magnet mixture (15) and (7) is an aperture in a transverse partition in the liquid conduit of said the magnet mixture (15) downstream in the liquid flow.
  • Element 9 is a drive pump.
  • the method, system and apparatus of invention can be used for in line or batch carbonation of water, aqueous liquids and vegetable, root or fruit juices. It can for instance be used for integration in the brewery process to carbonate beers before storage in a confined environment for instance before bottling.
  • the methods, systems or installations of present invention can be used to carbonate an aqueous liquid to react the dissolved C0 2 with substances in the liquid for instance to react the dissolved CO2 with calcium to calcium carbonate.
  • a particular use is dissolving CO2 in a juice to precipitate impurities for instance to precipitate impurities in beetroot juices by reacting the dissolved CO2 with calcium to calcium carbonate.
  • a particular embodiment of present invention is introducing CO2 gas and in particular C0 2 gas inline in a beer stream and mixing such under a magnetic field and a beer temperature at a value of the range of 1 to 10 °C, preferably 1 to 5 °C, more preferably 1,5 to 3 °C, yet more preferably 1,7 to 2,5°C, yet more preferably 1,8 to 2,2 °C and most preferably 2°C or about 2°C.
  • the pressure in the beer guidance line is hereby at a value of the range of 1 to 3 bar, preferably 1,2 to 2,5 bar, yet more preferably 1,4 to 2,2 bar, yet more preferably 1,5 to 2 bar, yet more preferably 1,6 to 1,8 bar, yet more preferably 1,65 to 1,75 bar and most preferably 1,7 bar or 1,8 bar.
  • a concentration of dissolved CO2 of 4 - 6 g/1, for instance 5 g/1 or about 5 g/1 can be reached in particularly since the conditions of C0 2 input flow and of liquid flow are controllable and adjustable.
  • the CO2 can be introduced in the beer guidance conduit (tube, pipeline or duct) as nanobubbles under a critical size of less than 100 nm diameter near or abut the entrance of the magnetic zone in said the beer guidance conduit (tube, pipeline or duct).
  • a critical size of less than 100 nm diameter near or abut the entrance of the magnetic zone in said the beer guidance conduit (tube, pipeline or duct).
  • magnetic zone or the internal diameter of tube, pipeline or duct is smaller than that of the tube, pipeline or duct directly before or after the magnetic zone or at some distance before or after the magnetic zone.
  • the magnetic zone is separated from the other parts of the tube , pipeline or duct by a septum, wall or partition distal and proximal of the magnetic zone which septum, wall or partition has an entrance or an outlet opening which is smaller than the inner diameter of the beer guidance conduit(tube , pipeline or duct) or each such septum, wall or partition has several openings of which the surface is smaller than the surface of the inner transverse section of the beer guidance conduit(tube , pipeline or duct).
  • the CO2 gas is injected directly into the upstream part of the magnetic zone under a reduced pressure when operational.
  • this method further involves the use of at least one in situ CO2 sensor for monitoring dissolved CO2 and to produce a signal indicative for the dissolved CO2 at the end of the line or inline.
  • at least one sensor can be connected to an electronic controller to process the sensor signals into a signal that activates a programmable actuator for modulating CO2 gas flow or a that activates a programmable actuator for modulating the beer liquid flow.
  • two in situ CO2 sensors are used, so that one sensor is checked against the other.
  • the actuator can for instance be a pump or valve actuator.
  • the CO2 gas is preferably introduced in the liquid guidance conduit (pipeline, tube or duct) through a porous tube with micropores of a size of a value between 5 to 50 ⁇ , preferably between 10 to 40 ⁇ , more preferably between 15 to 30 ⁇ , yet more preferably 20 to 28 ⁇ , yet more preferably 22 to 27 ⁇ , yet more preferably 24 to 26 ⁇ and most preferably 25 ⁇ or about 25 ⁇ .
  • the microporous device can for instance be comprise a sintered metal for instance with a length of a value from arrange of 50 to 250 mm, preferably 100 to 230 mm, yet more preferably from 150 to 220 mm, yet more preferably 180 to 210 mm , yet more preferably 190 to 2OO mm and most preferably 195 mm or about 195 mm and an inner diameter of a value of the range 8 to 24 mm, preferably the range of 10 to 20 mm, yet more preferably from 12 to 18 mm, yet more preferably the range from 14 to 17 mm and most preferably 16 mm or about 16 mm.
  • the men skilled in the art when informed about these values will understand that the carbonator can be upscalled so that these dimensions of tubes or pipelines will enlarge.
  • the same of a similar method is suitable for carbonation of other aqueous liquids for instance such that after carbonation it is one of the following: carbonated water, champagne, cola, diet coke, carbonated yogurt snack or sparkling yogurt (i.e. Fizzix ), sparkling wine, soft drink or tonic water.
  • CO2 gas in line delivery is that the pressure drop is smaller than for delivery of C0 2 gas in large volumes of liquids.
  • our systems requires less powerful pumps and less energy is consumed for carbonation of aqueous liquids, in particular with the increase carbonation efficiency in the magnetic field zone.
  • the carbonator of present invention or this carbonator integrated in an inline aqueous fluid flow pipeline, tube or duct system will occupy less space. It can be build compact because the magnet or magnet assembly will result in a condition that the length of the fluid flow pipeline, tube or duct can be reduced for solving the CO2 gas.
  • the system of present invention comprises a C0 2 gas fluid port a) locoregional before the magnetized flow zone of the liquid fluid guidance, duct or passage (the part of the liquid fluid guidance, duct or passage that is surrounded by permanent magnets, by an assembly of permanent magnets or by an array of permanent magnets eventually as an annular ring around said this guidance, duct or passage part) or b) adjacent to the magnetized flow zone of the liquid fluid guidance, duct or passage or c) directly associated with the magnetized flow zone of a liquid fluid guidance, duct or passage.
  • This port can collect the C0 2 gas fluid from an open or a closed environment.
  • the port is preferably through the C0 2 gas fluid guidance, duct or passage (e.g. tube) engaged with such environment to suck or aspirate said CO2 gas fluid into the magnetized zone of the liquid fluid guidance, duct or passage so that when operational the CO2 gas fluid and the fluid liquid mix in the chamber or the guidance, duct or passage zone that is under a permanent magnetic field.
  • C0 2 gas fluid guidance, duct or passage e.g. tube
  • tube can be bound or coupled to the magnetized liquid fluid guidance, duct or passage so that can flow gas that it leads to the magnetized liquid fluid guidance, duct or passage through the aperture of the liquid fluid guidance, duct or passage inject port directly so that C0 2 gas fluid is directly disposed into the enclosure or confined environment of the magnetized zone of the liquid fluid guidance, duct or passage or directly in front abut to the magnetized zone of the liquid fluid guidance, duct or passage or (locoregional) juxtaposed (according to the flow stream direction) positioned in front of the magnetized zone of the liquid fluid guidance, duct or passage so that CO2 gas fluid / liquid fluid mixing can occur in the magnetized low pressure environment.
  • a specific embodied feature of present invention has a technical advantage that CO2 gas fluid can be infused from a non-pressurized environment by the flow of the motive liquid fluid in the liquid fluid guidance, duct or passage so that without a separate CO2 gas fluid drive such as gas pump or without high-pressure gas as the working CO2 gas fluid the gas is infused into the magnetized zone of the liquid fluid guidance, duct or passage.
  • a separate CO2 gas fluid drive such as gas pump or without high-pressure gas as the working CO2 gas fluid the gas is infused into the magnetized zone of the liquid fluid guidance, duct or passage.
  • the low pressure in the magnetic zone receives CO2 gas fluid through the inject port as a suction fluid into the and the second technical advantage that higher gas in a liquid fluid with increased saturation efficiency and to enhanced gas dissolution is achieved than for a gas that has been introduced on a place that is remote from the magnetized zone of the liquid fluid guidance, duct or passage.
  • C0 2 gas fluid / liquid fluid mixing under reduced pressure and permanent magnetic field provided, for instance in a taper of the liquid fluid guidance, duct or passage surrounded by permanent magnets, drastically increased gas dissolution versus gas injected into the water flowing in a tube at another given point.
  • the efficiency of gas dissolving depends on presence of the magnetic field, the reduced pressure drop and mixing time in the magnetized low pressure zone.
  • Another advantage of present invention is that the moving water has significantly reduced bacterial load, in particular of waterborne pathogens if it is recirculated over this system.
  • This recirculation process allows to slow microbial growth in aquatic systems and in particularly recirculating aquatic systems with an organic load. This effect is still enhanced if the inlet CO2 gas fluid comprised a steam.
  • the efficiency of low heat pasteurization depends on presence of the magnetic field, the reduced pressure drop and mixing time in the magnetized low pressure zone.
  • the method of present and use of apparatus of present invention solve the technical problem of selective solving of gas molecules of a C0 2 gas fluid in order to achieve a drain of liquid fluid that is selectively enriched with the dissolved CO2
  • the method of present invention concerns aspiration in zone of reduced pressure and permanent magnetization for instance in the narrower or slimmer diameter of a liquid guidance pipe or the tapered zone of a liquid guidance with motive liquid which is surrounded by a permanent magnet or an assembly or array of magnets that surround said narrower or tapered part of the liquid conduit or that are combined with, connected to or associated with the conduit in a position at its narrower or slimmer diameter of a liquid guidance pipe or the tapered zone.
  • the magnets can be positioned radial around said this narrower diameter zone of the liquid conduit.
  • a particular embodiment of present invention is a magnetic carbonation system that increases the dissolution of CO2 molecules from CO2 gas which is aspirated in a defined position of the system so that CO2 gas nanobubbles are mixed with a watery fluid under a permanent magnetization and decreased pressure.
  • the CO2 enriched motive watery fluid can be further transported by a conduit to a reactor that needs CO2 enriched watery fluid for instance an anaerobic bioreactors or an algae farming tank.
  • anaerobic organisms are most commonly employed because for instance in biogas fermenters. It will be appreciated that CO2 must be supplied to such processes in order to maintain a high contaminant destruction rate.
  • the denitrification process and an algae culture process benefits input of C0 2 .
  • Present invention in a certain embodiment concerns an apparatus and a method for creating the fluid/CC gas mixing directly in an environment, chamber or tube under permanent magnetic field under a reduced pressure and gradually increasing the pressure as the after the magnetic field as the fluid moves further in tube.
  • the method of selectively solving of C0 2 molecules of a gas mixture concerns establishing a pressure drop in a flow of an aqueous liquid through a conduit or pipe and aspiration of the gas mixture into the pressure drop zone and mixing said fluid and gas under reduced pressure or near to vacuum under a permanent magnetic field and gradually increasing the pressure to a value of the range between 2 to 7 bar, preferably between 2,5 to 6 bar, yet more preferably between 3 and 6 bar and most preferably between 3.5 and 5 bar after the magnetization as the fluid moves further through the part of the conduit or pipe that is not surrounded by magnets.
  • the apparatus can further be foreseen of an open container for resting and release of the not dissolved CO2 gas elements for instance in a case these need to be recycled and re aspirated back into the magnet venture.
  • the liquid enriched with the dissolved CO2 flow will be flow through a line or conduit to a mechanical reactor, biochemical, bioreactor or another destination and unsolved C0 2 gas elements are remove from the mixture or combination, isolated and set apart in or guided to another unit eventually for recirculation or other uses.
  • the apparatus of present invention can concerns an aqueous liquid fluid source in which CO2 gas is introduced via a gas dissolution means or the apparatus can simple bath into the liquid fluid source (Fig. 2O) whereby an inlet port of the CO2 gas fluid conduit baths in to a C0 2 gas atmosphere for instance in a C0 2 storage container.
  • a regulating means before the injection port can operate to infuse or aspirate the CO2 gas fluid at selected range and grade into the reduced pressure or near vacuum magnetized zone of a motile water body or watery fluid body.
  • each said magnetic field in the carbonator is at least 0,2 Tesla (2,000 gauss) and the linear flow rate of said fluid through each said magnetic field is preferably between 0.25 and 25 m/s.
  • the effect of the method of CO2 gas in liquid dissolution is more important when the strength of the magnetic field is higher and/or the number of flows through the magnetic field is higher. Since the strength of each commercially available magnet is usually limited to about 1 Tesla (10,000 gauss), a means to increase the effective magnetic field is to carry out the fluid and CO2 gas mixing through a number of magnets arranged in series (especially for limiting the duration of treatment) in a zone of reduced pressure and/or to re-circulate the suspension several times through the same zone and to adjust the C0 2 gas aspiration by a valve in front of the C0 2 gas inlet port into the magnetized and reduced pressure for instance near vacuum zone.
  • flowing said fluid through the magnetic field(s) is preferably effected at a temperature below the Curie temperature of the magnetic material used for generating said magnetic field(s), e.g. below about 400°C for a magnetic device of the Al- Ni-Co type.
  • the motile liquid flowing through said magnetic field(s) is preferably effected at a temperature between the freezing temperature and 50°C while flowing said fluid through said magnetic field(s). For instance when said fluid is water under atmospheric pressure, flowing said liquid through said magnetic field(s) is preferably effected at a temperature between about 2°C and 50°C.
  • the method for disinfection, pasteurization or disinfecting according to the invention involves re-circulating (e.g. in a closed circuit) two or more times the fluid.
  • the magnetic field and may be easily adapted to the microbial load for specific pathogens in a certain industrial application.
  • the method for selective dissolution of CO2 gas according to the invention involves re-circulating (e.g. in a closed circuit) two or more times the fluid wherein amounts CO2 gas are aspirated in the magnetic field/reduced pressure zone. It is important that the aqueous liquid flows through the magnetic field(s) at reduced pressure wherein the C0 2 gas is aspirated while mixed is at a speed which allows the magnetic treatment and mixing to effectively perform the dissolution of certain gas elements to a significant extent.
  • the aqueous liquid wherein CO2 nanobubbles of preferably less than 100 nm size are introduced flows through the magnetic field(s) at reduced pressure wherein the CO2 gas and aqueous fluid mixed is at a speed which allows the magnetic treatment and mixing to effectively perform the dissolution of certain gas elements to a significant extent.
  • the linear flow rate of said fluid through each said magnetic field is between 0.25 and 25 m/s.
  • the residence time of said fluid through each said magnetic field is preferably between 60 microseconds and 10 seconds, depending upon the number or re-circulation times.
  • a post-processing step may be reinstallation of a pressure increase in the confined environment of the liquid conduit, flowing the mixture to a unit for separation where the un dissolved gas elements are separated for instance by into a recirculation gas conduit to present this CO2 back to the dissolution device.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • Genetics & Genomics (AREA)
  • Food Science & Technology (AREA)
  • Wood Science & Technology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Electromagnetism (AREA)
  • Medicinal Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)

Abstract

La présente invention se rapporte de manière générale à un appareil et à un procédé destinés à une dissolution améliorée ou une dissolution à efficacité de saturation accrue de dioxyde de carbone (C02) dans un liquide aqueux, plus particulièrement à un système et à un procédé destinés à une dissolution améliorée de CO2 dans l'eau à partir de gaz CO2. La présente invention se rapporte en particulier à un appareil et à un procédé destinés à une carbonatation en ligne de liquides aqueux avec une dissolution accrue à efficacité de saturation accrue de C02 à partir d'un gaz C02 ou à partir d'un gaz dont une majeure partie est du CO2 par écoulement d'un mélange de gaz et de liquide dans une zone entourée d'un aimant permanent (3) ou d'un ensemble d'aimants permanents.
PCT/BE2012/000003 2011-01-31 2012-01-31 Dissolution de c02 WO2012103602A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161462332P 2011-01-31 2011-01-31
US61/462,332 2011-01-31

Publications (1)

Publication Number Publication Date
WO2012103602A1 true WO2012103602A1 (fr) 2012-08-09

Family

ID=45999493

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE2012/000003 WO2012103602A1 (fr) 2011-01-31 2012-01-31 Dissolution de c02

Country Status (1)

Country Link
WO (1) WO2012103602A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10252226B2 (en) 2014-04-28 2019-04-09 Blueingreen Llc Systems and methods for dissolving a gas into a liquid
WO2019126877A1 (fr) * 2017-12-27 2019-07-04 Gis Gas Infusion Systems, Inc. Système saturateur en ligne à haute pression et à haut débit et procédé associé
US10933388B1 (en) 2017-07-07 2021-03-02 Jmf Watercraft Design Llc H20-oxygenation method and oxygenated live well
GB2617830A (en) * 2022-04-18 2023-10-25 English N A system, method and generator for generating solvated guest-moiety nano-clusters in liquids

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2424477A1 (de) * 1974-05-20 1975-12-04 Reichgraeflich Von Plettenberg Durchlaufverfahren zum impraegnieren von getraenken, insbesondere wein, mit kohlendioxyd
JPH0348501A (ja) 1989-07-17 1991-03-01 Kyocera Corp 方形導波管
JPH0348499A (ja) 1989-04-13 1991-03-01 Olympus Optical Co Ltd 電気装置
JP2810694B2 (ja) 1989-04-20 1998-10-15 花王株式会社 浴湯用炭酸温水の生成方法及び装置
US6036054A (en) 1998-05-22 2000-03-14 Sturman Bg, Llc Attachment adapted for a carbonated liquid container
JP2001293344A (ja) 2000-04-18 2001-10-23 Mitsubishi Rayon Eng Co Ltd 炭酸水製造装置および炭酸水製造方法
JP2003112796A (ja) 2001-08-03 2003-04-18 Nas Toa Co Ltd 飲料用カーボネーション装置
JP2006020985A (ja) 2004-07-05 2006-01-26 Kiyoshi Owada 微小孔を用いた入浴剤用炭酸ガス拡散装置
US7296508B2 (en) 2004-05-17 2007-11-20 Robert John Hillyer Simple inexpensive home carbonation device
EP2060318A1 (fr) * 2007-11-15 2009-05-20 YARA International ASA Appareil et procédé pour générer et distribuer des bulles dans un mélange gaz-liquide
EP2060319A1 (fr) * 2006-08-21 2009-05-20 Eiji Matsumura Dispositif de mélange gaz/liquide
US20100147690A1 (en) * 2008-12-16 2010-06-17 Geir Corporation Oxygenation of a Fluid
WO2010095626A1 (fr) * 2009-02-17 2010-08-26 小出 平一 Dispositif de brassage et de mélange

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2424477A1 (de) * 1974-05-20 1975-12-04 Reichgraeflich Von Plettenberg Durchlaufverfahren zum impraegnieren von getraenken, insbesondere wein, mit kohlendioxyd
JPH0348499A (ja) 1989-04-13 1991-03-01 Olympus Optical Co Ltd 電気装置
JP2810694B2 (ja) 1989-04-20 1998-10-15 花王株式会社 浴湯用炭酸温水の生成方法及び装置
JPH0348501A (ja) 1989-07-17 1991-03-01 Kyocera Corp 方形導波管
US6036054A (en) 1998-05-22 2000-03-14 Sturman Bg, Llc Attachment adapted for a carbonated liquid container
JP2001293344A (ja) 2000-04-18 2001-10-23 Mitsubishi Rayon Eng Co Ltd 炭酸水製造装置および炭酸水製造方法
JP2003112796A (ja) 2001-08-03 2003-04-18 Nas Toa Co Ltd 飲料用カーボネーション装置
US7296508B2 (en) 2004-05-17 2007-11-20 Robert John Hillyer Simple inexpensive home carbonation device
JP2006020985A (ja) 2004-07-05 2006-01-26 Kiyoshi Owada 微小孔を用いた入浴剤用炭酸ガス拡散装置
EP2060319A1 (fr) * 2006-08-21 2009-05-20 Eiji Matsumura Dispositif de mélange gaz/liquide
EP2060318A1 (fr) * 2007-11-15 2009-05-20 YARA International ASA Appareil et procédé pour générer et distribuer des bulles dans un mélange gaz-liquide
US20100147690A1 (en) * 2008-12-16 2010-06-17 Geir Corporation Oxygenation of a Fluid
WO2010095626A1 (fr) * 2009-02-17 2010-08-26 小出 平一 Dispositif de brassage et de mélange

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"Methods of analysis. 5th edition,", 1949, AMERICAN SOCIETY OF BREWING CHEMISTS
BROOKS T; KEEVIL CW: "A simple artificial urine for the growth of urinary pathogens", LETT APPL MICROBIOL, vol. 24, no. 3, 1997, pages 203 - 206
OR WILHELM, E. ET AL.: "Low-pressure solubility of gases in liquid water", CHEM. REV., vol. 77, 1977, pages 219 - 262, XP002592790

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10252226B2 (en) 2014-04-28 2019-04-09 Blueingreen Llc Systems and methods for dissolving a gas into a liquid
US10933388B1 (en) 2017-07-07 2021-03-02 Jmf Watercraft Design Llc H20-oxygenation method and oxygenated live well
WO2019126877A1 (fr) * 2017-12-27 2019-07-04 Gis Gas Infusion Systems, Inc. Système saturateur en ligne à haute pression et à haut débit et procédé associé
GB2617830A (en) * 2022-04-18 2023-10-25 English N A system, method and generator for generating solvated guest-moiety nano-clusters in liquids
GB2617896A (en) * 2022-04-18 2023-10-25 English N Nanoclusters

Similar Documents

Publication Publication Date Title
US8142550B2 (en) Oxygenation of a fluid
US6530895B1 (en) Oxygenating apparatus, method for oxygenating a liquid therewith, and applications thereof
CA2667634C (fr) Dispositif de melange et ses fluides de sortie
AU715815B2 (en) Oxygenating apparatus, method for oxygenating water therewith, and applications thereof
US5904851A (en) Oxygenating apparatus, method for oxygenating liquid therewith, and applications thereof
WO2012103602A1 (fr) Dissolution de c02
CN104624070A (zh) 气液混合系统及方法
CN103406082A (zh) 一种电磁强化液体中气体溶解的方法及其装置
JP2005271648A (ja) 船舶のバラスト水の処理装置
AU2014200893B2 (en) Mixing device and output fluids of same
RU2013148869A (ru) Прибор для растворения газов
CA2881274C (fr) Dispositif de melange et ses fluides de sortie
CN202808533U (zh) 天然水的活化和存储装置
AU6304699A (en) Oxygenating apparatus, method for oxygenating water therewith, and applications thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12716185

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12716185

Country of ref document: EP

Kind code of ref document: A1