WO2012077760A1

WO2012077760A1 - Multilayered tube, and method for producing multilayered tube

Info

Publication number: WO2012077760A1
Application number: PCT/JP2011/078464
Authority: WO
Inventors: 嘉彦三杉; 助川　勝通; 剛志稲葉; 安行山口; 一也河原; 俊二笠井; 洋之吉本; 毅芦田
Original assignee: ダイキン工業株式会社; 富士フイルム株式会社
Priority date: 2010-12-09
Filing date: 2011-12-08
Publication date: 2012-06-14
Also published as: JP2012136020A

Abstract

A multilayered tube having excellent chemical resistance, heat resistance, and flexibility is provided. A method for producing the multilayered tube, and an endoscope equipped with the multilayered tube are also provided. The multilayered tube contains an outer layer comprising a porous polytetrafluoroethylene, and an inner layer comprising a melt-processable fluorine resin, and is characterized in that the inner layer is seamless.

Description

Multilayer tube and method of manufacturing the multilayer tube

The present invention relates to a multilayer tube and a method for producing the multilayer tube. The present invention also relates to an endoscope including the multilayer tube.

Fluororesin, especially polytetrafluoroethylene resin [PTFE], has many excellent properties such as heat resistance, chemical resistance, weather resistance, non-adhesiveness, electrical insulation, high frequency characteristics, etc. It is used not only in a wide range of fields.

As one of them, for example, in the medical field, it is known that a tube made of PTFE is useful as a suction tube or the like in an electronic endoscope apparatus (see, for example, Patent Document 1). Patent Document 1 discloses a multilayer tube including a first layer made of PTFE having a solid structure and a second layer made of PTFE having a porous structure laminated on the outer peripheral surface thereof. However, since the first layer of the tube of Patent Document 1 is made of PTFE resin, the strength is low, and there is a risk of breakage when a metal wire or the like is passed inside.

Patent Document 2 discloses a method for producing a tubular body including a PTFE layer. As a tubular body obtained by the production method of Patent Document 2, a tubular body having a tetrafluoroethylene / perfluoro (alkyl vinyl ether) [PFA] layer as a first layer and an expanded PTFE layer as a second layer is disclosed. However, in patent document 2, a 1st layer is formed by the method of winding a PFA film around a core, and it does not disclose about forming by melt molding. Moreover, in patent document 2, a 1st layer is formed from a fluorocarbon film, a seam arises in the 1st layer, and the member etc. which pass through an inside may be caught.

JP-A-7-1630 JP-A-52-144072

The present invention provides a multilayer tube which is excellent in chemical resistance and heat resistance and excellent in flexibility. Moreover, this invention provides the manufacturing method of this multilayer tube, and an endoscope provided with this multilayer tube.

The present invention relates to a multilayer tube including an outer layer made of porous polytetrafluoroethylene and an inner layer made of a melt-processable fluororesin, and the inner layer is seamless.

The melt-processable fluororesin is preferably a fluororesin including a polymer unit based on tetrafluoroethylene and a polymer unit based on perfluoro (alkyl vinyl ether).

The present invention relates to a multilayer tube for medical use.

The present invention relates to an endoscope comprising the multilayer tube.

Further, the present invention provides a process for obtaining a coated core wire by coating a fluororesin that can be melt-processed on the core wire,
Obtaining a polytetrafluoroethylene porous membrane;
Winding the porous membrane around the coated core wire,
Heat-treating the coated core wire around which the porous membrane is wound, and
A step of drawing the core wire from a coated core wire wound with a porous membrane to obtain a multilayer tube;
It is related with the manufacturing method of a multilayer tube which consists of.

It is preferable to wind the porous membrane around the coated core wire in a sushi roll shape.

It is preferable that the porous membrane is wound around the coated core wire in a spiral shape.

Further, the present invention provides a process for obtaining a coated core wire by coating a fluororesin that can be melt-processed on the core wire,
Obtaining a porous tube of polytetrafluoroethylene,
Covering the porous tube over the coated core wire,
A step of heat-treating the coated core wire covered with the porous tube; and
A step of drawing the core wire from a coated core wire covered with a porous tube to obtain a multilayer tube;
It is related with the manufacturing method of a multilayer tube which consists of.

The heat treatment temperature is preferably 320 to 345 ° C.

The multilayer tube of the present invention has excellent chemical resistance and heat resistance, and is excellent in flexibility. Therefore, even when bent with a small bending radius, it does not cause kinking (breaking). It is very useful as a tube in medical equipment. Further, since the inner layer is seamless, members passing through the inside are not caught, and the inside can pass through smoothly, and the production efficiency is higher than that in the case of producing from a film. Furthermore, the manufacturing method of the multilayer tube of this invention can manufacture the multilayer tube which has the above outstanding effects by a simple method.

It is a figure which shows an example of the manufacturing method of this invention. It is a figure which shows an example of the manufacturing method of this invention. It is AA 'sectional drawing of FIG.1 (c). It is BB 'sectional drawing of FIG.2 (c). It is a figure which shows an example of the manufacturing method of this invention.

The multilayer tube of the present invention includes an outer layer made of porous polytetrafluoroethylene [PTFE] and an inner layer made of a melt-processable fluororesin, and the inner layer is seamless.

Porous PTFE can be obtained, for example, by stretching an unstretched PTFE film. A PTFE porous membrane is obtained by stretching an unstretched PTFE film. The stretching may be biaxial stretching or uniaxial stretching, but is preferably uniaxial stretching from the viewpoint of workability and handling. The stretching ratio is not particularly limited, but in the case of uniaxial stretching, it is preferably stretched 2 to 15 times in the longitudinal direction (MD direction), more preferably stretched 3 to 7 times. It is particularly preferable that the film is stretched 3.5 to 6 times. It is preferable that the draw ratio is in the above range because the tube can be prevented from being blocked.

The thickness of the PTFE porous membrane is preferably 50 to 300 μm. More preferably, it is 100 to 250 μm. It is preferable from the point of the obstruction | occlusion prevention effect that a film thickness exists in the said range. The film thickness of the PTFE porous membrane may be 150 μm or more.

PTFE constituting the PTFE porous membrane has stretchability, fibrillation property and non-melt processability. The PTFE constituting the PTFE porous membrane may be a TFE homopolymer composed only of tetrafluoroethylene [TFE], or a modified PTFE composed of TFE and a modified monomer. The modifying monomer is not particularly limited as long as it can be copolymerized with TFE. For example, perfluoroolefin such as hexafluoropropylene [HFP]; chlorofluoroolefin such as chlorotrifluoroethylene [CTFE]; Examples thereof include hydrogen-containing fluoroolefins such as trifluoroethylene and vinylidene fluoride [VdF]; perfluorovinyl ether; perfluoroalkylethylene: ethylene. Moreover, the modified | denatured monomer to be used may be 1 type, and multiple types may be sufficient as it.

In the modified PTFE, the modified monomer unit is preferably 1% by mass or less, more preferably 0.001 to 1% by mass of the total monomer units.

Among these, the material for the porous PTFE membrane used in the present invention is preferably a TFE homopolymer composed only of tetrafluoroethylene [TFE]. In the present invention, it is preferable to use fine PTFE particles (so-called fine powder) obtained by emulsion polymerization.

The PTFE film can be produced by a known method described in Japanese Patent No. 2940166.

The melt-processable fluororesin used for the inner layer is a fluororesin having a melt fluidity. For example, TFE / hexafluoropropylene [HFP] copolymer [FEP], TFE / perfluoro (alkyl vinyl ether) [PAVE] Polymer [PFA], ethylene [Et] / TFE copolymer, Et / TFE / HFP copolymer, polychlorotrifluoroethylene [PCTFE], CTFE / TFE copolymer, Et / CTFE copolymer, polyfluoride Vinylidene [PVdF], TFE / VdF copolymer, VdF / HFP / TFE copolymer, VdF / HFP copolymer, and at least one copolymer selected from the group consisting of polyvinyl fluoride [PVF] Is preferred. Among these, those containing polymerized units based on TFE (hereinafter referred to as TFE units) and polymerized units based on PAVE (hereinafter referred to as PAVE units) are preferable, and TFE / PAVE copolymer [PFA] is more preferable. PFA is preferable because it has a melting point close to that of PTFE and is easily melt-bonded.

The perfluoro (alkyl vinyl ether) is not particularly limited, and for example, the following general formula (1):
CF ₂ = CF-ORf (1)
(In the formula, Rf represents a perfluoro organic group.)
Perfluoro unsaturated compounds represented by the formula: In the present specification, the “perfluoro organic group” means an organic group in which all hydrogen atoms bonded to carbon atoms are substituted with fluorine atoms. The perfluoro organic group may have an etheric oxygen atom.

Examples of the perfluoro (alkyl vinyl ether) include perfluoro (alkyl vinyl ether) [PAVE] in which Rf represents a perfluoroalkyl group having 1 to 10 carbon atoms in the general formula (1). The perfluoroalkyl group preferably has 1 to 5 carbon atoms.

Examples of the perfluoroalkyl group in the PAVE include a perfluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluorobutyl group, a perfluoropentyl group, and a perfluorohexyl group. Perfluoro (propyl vinyl ether) [PPVE] in which the group is a perfluoropropyl group is preferred.

As PFA, those having a PAVE unit of 3 to 8 wt% are preferred, and those having a PAVE unit of 4 to 7.5 wt% are more preferred.

The melt-processable fluororesin used in the present invention preferably has an MFR of 15 to 85 (g / 10 minutes), more preferably 25 to 75 (g / 10 minutes). The MFR is a value that can be measured under the conditions of a temperature of 372 ° C. and a load of 5.0 kg in accordance with ASTM D-1238. Hereinafter, the MFR measurement in this specification follows the above method.

Moreover, the inner layer of the multilayer tube of the present invention is seamless. Here, seamless means a seamless state. In the present invention, since the inner layer is seamless, the inner wall surface is seamless, so that the smoothness is excellent, and members passing through the inside of the tube are not caught and can pass through the inside smoothly. Furthermore, the production efficiency is higher compared to the case of producing from a film.

The thickness of the outer layer of the multilayer tube of the present invention is preferably 50 to 500 μm. More preferably, it is 100 μm or more. Moreover, it is more preferable that it is 400 micrometers or less, and it is still more preferable that it is 300 micrometers or less. The thickness of the outer layer may be 250 μm or less. Further, the thickness of the inner layer is preferably 30 to 150 μm, and more preferably 40 to 80 μm.

For example, the outer layer made of porous polytetrafluoroethylene preferably has a porosity of 50 to 97%, more preferably 70 to 95%.

Although the manufacturing method of the multilayer tube of this invention is not specifically limited, It is preferable to manufacture with the following manufacturing methods of this invention. Hereinafter, the production method of the present invention will be described with reference to FIGS.

The present invention
A step of obtaining a coated core wire 3 by coating and molding a melt-processable fluororesin on the core wire 1;
Obtaining a PTFE porous membrane 4;
Winding the porous membrane 4 around the coated core wire 3;
A step of heat-treating the coated core wire 3 around which the porous film is wound, and
A step of drawing the core wire 1 from the coated core wire 3 around which the porous membrane is wound to obtain a multilayer tube;
(Referred to below as the first manufacturing method, see FIGS. 1 and 2).

As the core wire, one having good peelability and a smooth surface with little unevenness is preferable so that the core wire can be easily removed after the heat treatment. Although the material of a core wire is not specifically limited, For example, stainless steel, copper, aluminum etc. can be mentioned. Among these, a core wire made of stainless steel or copper is preferable because it is not deformed by heat treatment and, as a result, the thickness of the resulting coating layer can be made uniform.

Since the diameter of the core wire corresponds to the inner diameter of the multilayer tube of the present invention, it can be appropriately determined depending on the use of the multilayer tube of the present invention, but is preferably about 1 to 8 mm, for example. For example, when the multilayer tube of the present invention is used for an endoscope scope, the diameter of the core wire is preferably 1.5 to 6 mm, and when the multilayer tube of the present invention is used for a push-pull cable. The core wire preferably has a diameter of 2 to 8 mm.

The production method of the present invention includes a step of coating the core wire with a melt-processable fluororesin to obtain a coated core wire. The above-mentioned thing can be mentioned as a fluororesin which can be melt-processed.

The method of coating the core wire with a melt-processable fluororesin is a method in which a melt-processable fluororesin is melted and coated on the core wire. The specific method is not particularly limited, and can be performed using a known melt extrusion molding machine or the like. In the manufacturing method of the present invention, the first layer is coated at a temperature equal to or higher than the melting point, so that a coating film having a uniform thickness can be formed without a seam (seamless).

The coating thickness of the fluororesin that can be melt-processed before the heat treatment is not particularly limited, and can be appropriately determined depending on the thickness of the inner layer of the multilayer tube obtained after the heat treatment. For example, the coating thickness before heat treatment of a melt-processable fluororesin is preferably 30 to 150 μm, and more preferably 40 to 80 μm.

The production method of the present invention includes a step of winding a PTFE porous membrane around a coated core wire. The method for producing the PTFE porous membrane is as described above.

Moreover, the PTFE porous membrane used when the PTFE porous membrane is wound around the coated core wire is preferably unfired.

The method for winding the PTFE porous membrane around the coated core wire is not particularly limited, but for example, a sushi roll shape (a method of winding at right angles to the longitudinal direction of the coated core wire), A method of winding in a spiral shape (spiral shape) as shown in FIG.

When winding in a sushi roll or spiral, the PTFE porous membrane may be wound so as not to overlap, or may be wound so as to overlap. The case of overlapping will be described below with reference to the drawings.

When the PTFE porous membrane 4 is wound in a sushi roll shape on the inner layer 2 made of a melt-processable fluororesin that is the first layer (FIG. 1 (b)), FIG. 3 (AA ′ in FIG. 1 (c)) As shown in (cross section), the winding end end portion of the PTFE porous membrane 4 overlaps the upper surface of the end portion of the PTFE porous membrane 4, and a gap 6 is formed between the outer peripheral surface of the inner layer 2. The gap 6 is formed in a straight line in the longitudinal direction of the coated core wire 3. Further, as shown in FIG. 4 (BB ′ cross section in FIG. 2C), the gap 6 is formed in a spiral shape even when wound in a spiral shape. 3 and 4 show the case where one layer of the PTFE porous membrane is formed, the same gap is formed when two or more layers are formed.

The formed gap 6 is subjected to heat treatment, so that the melted PTFE is filled into the gap 6, and a substantially smooth PTFE layer is formed on the outer periphery of the inner layer made of a fluororesin that can be melt-processed.

The coating thickness of the PTFE porous membrane before the heat treatment is not particularly limited, and can be appropriately determined depending on the thickness of the outer layer of the multilayer tube obtained after the heat processing. For example, the coating thickness of the PTFE porous membrane before the heat treatment is preferably 100 to 350 μm, more preferably 100 to 300 μm, and further preferably 150 to 250 μm.

The number of windings of the PTFE porous membrane around the coated core wire varies depending on the thickness of the porous membrane and the use of the obtained multilayer tube, but it is usually preferably 1 to 5 layers.

Furthermore, in the manufacturing method of this invention, the process of heat-processing the coated core wire which wound the porous membrane is included. As the heat treatment conditions, both the PTFE layer and the melt-processable fluororesin layer are melted, but it is preferable that the temperature range and time be such that the shape is maintained. Specifically, the heat treatment temperature is preferably 320 to 345 ° C, more preferably 327 to 342 ° C, and further preferably 330 to 338 ° C. The heat treatment time is generally about 30 seconds to 7 minutes, preferably 50 seconds to 5 minutes, although it depends on the firing temperature and the tube thickness. The heat treatment time may be 3 minutes or less. By setting it as the said heating conditions, two layers, the layer which consists of a PTFE layer and a melt processable fluororesin, join, and the integrated multilayer structure is formed.

The multilayer core tube of the present invention can be obtained by pulling out the core wire from the coated core wire around which the obtained porous membrane is wound. Here, the method of pulling out the core wire is not particularly limited. For example, the core wire is stretched by about 10 to 50% with respect to the entire length of the core wire, so that the core wire diameter is about 70 to 90% of the original diameter. The method of pulling out can be mentioned.

Furthermore, the present invention provides
A step of obtaining a coated core wire 3 by coating and molding a melt-processable fluororesin on the core wire 1;
Obtaining a porous tube 5 of PTFE;
Covering the coated core wire with the porous tube 5;
A step of heat-treating the coated core wire 3 covered with the porous tube 5; and
A step of drawing the core wire 1 from the coated core wire 3 covered with the porous tube 5 to obtain a multilayer tube;
(Hereinafter referred to as FIG. 5).

As shown in FIG. 5, the second manufacturing method is different from the first manufacturing method in that the porous PTFE tube 5 is covered with the coated core wire (FIG. 5B), but the other steps are as follows. This is the same as the first manufacturing method.

The method for producing the porous tube is not particularly limited, and for example, it is produced by a known method as described in JP-A-9-241411.
When a multilayer tube is manufactured by the second manufacturing method, for example, porous PTFE can be obtained by stretching an unstretched PTFE tube. A PTFE porous tube is obtained by stretching an unstretched PTFE tube. Stretching is performed, for example, by stretching an unstretched PTFE tube in the tube axis direction. The stretching ratio is not particularly limited, but it is preferably stretched 2 to 15 times in the tube axis direction. More preferably, it is 3.5 to 6 times. It is preferable that the draw ratio is in the above range because the tube can be prevented from being blocked.
At the time of stretching, the film may be stretched while being heated in a high-temperature tank or the like. The heating temperature is not particularly limited, but is preferably 133 to 300 ° C., for example.

The inner diameter of the porous tube is preferably about the same as the outer diameter of the coated core wire, preferably 1 to 10 mm, and more preferably 2 to 6 mm. The inner diameter of the porous tube is preferably about the same as the outer diameter of the coated core wire, but even if it is about 0.2 to 2 mm larger than the outer diameter of the coated core wire, both layers are joined by shrinkage during the heat treatment. The

Further, the thickness of the porous tube is preferably 100 to 300 μm, more preferably 150 to 250 μm.

In the second production method, the porous tube is covered with the coated core wire, and then heat treatment is performed under the conditions, and finally the core wire is pulled out from the coated core wire covered with the porous tube to obtain a multilayer tube. .

The multilayer tube of the present invention can be used for industrial applications such as push-pull cables and medical applications such as catheters and endoscopes. Further specific examples of the medical use include, for example, a body fluid distribution tube, a tube provided in an endoscope apparatus, and the like. Tubes used in such medical fields have excellent airtightness, watertightness, flexibility, flexibility, and bending resistance, as well as inner wall smoothness, contamination resistance, microbial resistance, and prevention of organic matter adhesion. However, the multilayer tube of the present invention satisfies these requirements and can be suitably used in the medical field.

Next, the present invention will be described with reference to examples and comparative examples, but the present invention is not limited to such examples.

(Thickness measurement method)
The tube was cut using a sharp blade such as a razor blade, the cross section was observed at a magnification of 100 times with a microscope, and the film thickness was measured.

Example 1
1) Production of first layer (PFA layer) PFA (trade name: NEOFLON PFA, AP-202, manufactured by Daikin Industries, Ltd., MFR: 72 g / 10 min), die having an inner diameter of 16 mm, and chip having an outer diameter of 14 mm The first layer (seamless) was formed by using a die temperature of 400 ° C. at a speed of 10 m / min on a stainless steel wire having a diameter of 2.0 mm so that the thickness of the PFA layer was 60 μm. Hereinafter, what has the PFA layer which is a 1st layer on a stainless steel wire is called PFA coating | coated core material.

2) Production of second layer (porous PTFE layer) PTFE fine powder (trade name: Polyflon PTFE F-104, manufactured by Daikin Industries, Ltd.) 100 parts by weight is a hydrocarbon-based agent, Isopar M (Exxon Chemical) (Product made) A mixture of 28 parts was paste-extruded to a diameter of 12 mm and formed into a sheet having a thickness of 180 μm and a width of 130 mm using a calendar roll. This 130 mm wide sheet was stretched 5 times in the longitudinal direction (MD direction) of the film at a stretching speed of 10 m / sec to obtain a 110 μm thick PTFE porous sheet.

The obtained PTFE porous sheet was wound around the PFA-coated core material three times in a sushi roll. Hereinafter, it is called a wound product.

3) Heat treatment This wound product was heat-treated in an electric furnace at 340 ° C for 5 minutes. After the heat treatment, cooling was performed, and the stainless steel wire was stretched to a length of 1.3 times and then pulled out to obtain a multilayer tube composed of a PFA layer (thickness 60 μm) and a porous PTFE layer (thickness 300 μm).

Comparative Example 1
1) Production of first layer (PTFE layer) PTFE fine powder (trade name: Polyflon F-208, manufactured by Daikin Industries, Ltd.) was used at a die temperature of 60 ° C. and 10 m / min using a die with an inner diameter of 2.5 mm. The first layer (seamless) was formed by paste extrusion on a stainless steel wire having a diameter of 2.0 mm so that the thickness of the PTFE layer was 90 μm. Hereinafter, what has the PTFE layer which is a 1st layer on a stainless steel wire is called PTFE covering core material.

2) Production of second layer (porous PTFE layer) and heat treatment In the same manner as in Example 1, a PTFE porous sheet was wrapped around a PTFE-coated core material three times in a sushi roll and subjected to heat treatment. It was. After the heat treatment, it was cooled and the stainless steel wire was stretched to a length of 1.3 times and then pulled out to obtain a multilayer tube composed of a PTFE layer (thickness 100 μm) and a porous PTFE layer (thickness 330 μm).

Example 2
1) Production of first layer (PFA layer) A PFA-coated core material was produced in the same manner as in Example 1.

2) Production of second layer (porous PTFE layer) A PTFE porous sheet produced by the same method as in Example 1 was cut to a width of 10 mm, and spirally formed on a PFA-coated core. Winding and heat treatment were performed under the same heating conditions as in Example 1. After the heat treatment, it was cooled, the stainless steel wire was drawn out, and a multilayer tube composed of a PFA layer (thickness 60 μm) and a porous PTFE layer (thickness 330 μm) was obtained.

Comparative Example 2
1) Production of first layer (PTFE layer) A PTFE-coated core material was produced in the same manner as in Comparative Example 1.

2) Preparation of the second layer (porous PTFE layer) and heat treatment A PTFE layer (thickness of 100 μm) and a porous PTFE layer (thickness) were obtained in the same manner as in Example 2 except that a PTFE-coated core material was used. 330 μm) was obtained.

Example 3
1) Production of first layer (PFA layer) A PFA-coated core material was produced in the same manner as in Example 1.

2) Preparation of second layer (porous PTFE layer) 2 kg of PTFE fine powder (trade name: Polyflon PTFE F-104, manufactured by Daikin Industries, Ltd.) and Isopar G (Exxon Chemical Co., Ltd.), a hydrocarbon-based extrusion aid. 205 g) was mixed and aged at room temperature (25 ° C.) for 12 hours. This aged mixture was extruded with a φ50 mm paste extruder. A die having an inner diameter of φ3.0 mm and a chip having an outer diameter of 2.5 mm were used. This extrudate was placed in a high-temperature bath at 160 ° C. for 30 minutes to dry the auxiliary. Furthermore, after putting this tube in a 200 degreeC high temperature tank for 5 minutes, it extended to 2 times length with the temperature, and returned to normal temperature with extending | stretching. As a result, a PTFE porous tube having an inner diameter of 2.4 mm, an outer diameter of 2.9 mm, and a thickness of 250 μm was obtained. The obtained PTFE porous tube was placed on the PFA-coated core material.

3) Heat treatment The PFA-coated core material covered with the PTFE porous tube was heat-treated under the same conditions as in Example 1. After the heat treatment, it was cooled and the stainless steel wire was stretched to 1.3 times the total length and then pulled out to obtain a multilayer tube comprising a PFA layer (thickness 60 μm) and a porous PTFE layer (thickness 250 μm). .

Comparative Example 3
1) Production of first layer (PTFE layer) A PTFE-coated core material was produced in the same manner as in Comparative Example 1.

2) Preparation of the second layer (porous PTFE layer) and heat treatment A PTFE layer (thickness: 100 μm) and a porous PTFE layer (thickness: 250 μm) were produced in the same manner as in Example 3 except that a PTFE-coated core material was used. Was obtained.

Comparative Example 4
A PFA-coated core material was produced in the same manner as in Example 1.
The stainless steel wire in the PFA-coated core material was stretched to a length of 1.3 times and then drawn to obtain a single-layer tube composed of a PFA layer (thickness 60 μm).

The multilayer tube obtained in Examples 1 to 3 and Comparative Examples 1 to 4 was evaluated as follows. The evaluation results are shown in Table 1.

Kink resistance: The obtained multilayer tube was bent so as to have an inner diameter of 20 mm, and the degree of closure of the tube was evaluated according to the following evaluation criteria.
○: The tube was not closed.
X: The tube was closed.

Measuring method of inner surface roughness: According to JIS B 0601.

Tensile modulus measurement method: According to ASTM D638.

In the present invention, the inner layer is made of PFA, which is more seamless than the conventional inner layer PTFE, has a low inner surface roughness, and a high tensile elastic modulus. Scratch resistance and wear resistance can be improved. Moreover, about an outer layer, a extending | stretching tube extrusion can simplify a process and can produce a uniform outer layer.

The multilayer tube of the present invention is excellent in chemical resistance and heat resistance, and has excellent inner surface strength. Therefore, even if it is bent with a small bending radius, it does not cause kinking (breaking). It is very useful as a tube in medical equipment. Further, since the inner layer is seamless, members passing through the inside are not caught, and the inside can pass through smoothly, and the production efficiency is higher than that in the case of producing from a film. Furthermore, the manufacturing method of the multilayer tube of this invention can manufacture the multilayer tube which has the above outstanding effects by a simple method.

1: Core wire 2: Inner layer made of melt-processable fluororesin 3: Coated core wire 4: PTFE porous membrane 5: PTFE porous tube 6: Gap

Claims

A multilayer tube comprising an outer layer made of porous polytetrafluoroethylene and an inner layer made of a melt-processable fluororesin, and the inner layer is seamless.
The multilayer tube according to claim 1, wherein the melt-processable fluororesin is a fluororesin including a polymer unit based on tetrafluoroethylene and a polymer unit based on perfluoro (alkyl vinyl ether).
The multilayer tube according to claim 1 or 2, which is for medical use.
An endoscope comprising the multilayer tube according to any one of claims 1 to 3.
A process of obtaining a coated core wire by coating and forming a melt-processable fluororesin on the core wire;
Obtaining a polytetrafluoroethylene porous membrane;
Winding the porous membrane around the coated core wire,
Heat-treating the coated core wire around which the porous membrane is wound, and
A step of drawing the core wire from a coated core wire wound with a porous membrane to obtain a multilayer tube;
A process for producing a multilayer tube comprising:
The manufacturing method according to claim 5, wherein the porous film is wound around the coated core wire in a sushi roll shape.
The manufacturing method according to claim 5, wherein the porous film is wound around the coated core wire in a spiral shape.
A process of obtaining a coated core wire by coating and forming a melt-processable fluororesin on the core wire;
Obtaining a porous tube of polytetrafluoroethylene,
Covering the porous tube over the coated core wire,
A step of heat-treating the coated core wire covered with the porous tube; and
A step of drawing the core wire from a coated core wire covered with a porous tube to obtain a multilayer tube;
A process for producing a multilayer tube comprising:
The method for producing a multilayer tube according to claim 5 or 8, wherein the melt-processable fluororesin is a fluororesin containing a polymer unit based on tetrafluoroethylene and a polymer unit based on perfluoro (alkyl vinyl ether).
The method for producing a multilayer tube according to claim 5 or 8, wherein the temperature of the heat treatment is 320 to 345 ° C.