WO2012036743A1 - Graisses fluides et huiles comestibles stables et compositions améliorées d'acide ascorbique pour les produire - Google Patents
Graisses fluides et huiles comestibles stables et compositions améliorées d'acide ascorbique pour les produire Download PDFInfo
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- WO2012036743A1 WO2012036743A1 PCT/US2011/001599 US2011001599W WO2012036743A1 WO 2012036743 A1 WO2012036743 A1 WO 2012036743A1 US 2011001599 W US2011001599 W US 2011001599W WO 2012036743 A1 WO2012036743 A1 WO 2012036743A1
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- Prior art keywords
- ascorbic acid
- oil
- less
- micron
- fatty acids
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 title claims abstract description 204
- 235000010323 ascorbic acid Nutrition 0.000 title claims abstract description 101
- 229960005070 ascorbic acid Drugs 0.000 title claims abstract description 101
- 239000011668 ascorbic acid Substances 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 title claims abstract description 84
- 239000012530 fluid Substances 0.000 title claims abstract description 35
- 239000003921 oil Substances 0.000 title claims description 62
- 239000003925 fat Substances 0.000 title description 27
- 239000002245 particle Substances 0.000 claims abstract description 76
- 239000007787 solid Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims description 29
- 230000000087 stabilizing effect Effects 0.000 claims description 24
- 239000003963 antioxidant agent Substances 0.000 claims description 21
- 235000006708 antioxidants Nutrition 0.000 claims description 21
- 235000020748 rosemary extract Nutrition 0.000 claims description 18
- 235000013305 food Nutrition 0.000 claims description 16
- 230000003078 antioxidant effect Effects 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 239000000284 extract Substances 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 13
- 229940092258 rosemary extract Drugs 0.000 claims description 13
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229930003799 tocopherol Natural products 0.000 claims description 12
- 239000011732 tocopherol Substances 0.000 claims description 12
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 10
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 10
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 150000002314 glycerols Chemical class 0.000 claims description 10
- 235000019149 tocopherols Nutrition 0.000 claims description 9
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 claims description 9
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 claims description 8
- -1 polyoxyethylene Polymers 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- IIZBNUQFTQVTGU-PTTKHPGGSA-N (z)-octadec-9-enoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O IIZBNUQFTQVTGU-PTTKHPGGSA-N 0.000 claims description 7
- 239000013049 sediment Substances 0.000 claims description 7
- 239000003996 polyglycerol polyricinoleate Substances 0.000 claims description 6
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 5
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 5
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims description 5
- 241000207923 Lamiaceae Species 0.000 claims description 5
- 235000013628 Lantana involucrata Nutrition 0.000 claims description 5
- 235000006677 Monarda citriodora ssp. austromontana Nutrition 0.000 claims description 5
- 240000007673 Origanum vulgare Species 0.000 claims description 5
- 108010084695 Pea Proteins Proteins 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 5
- 244000269722 Thea sinensis Species 0.000 claims description 5
- 108010046377 Whey Proteins Proteins 0.000 claims description 5
- 102000007544 Whey Proteins Human genes 0.000 claims description 5
- NGHUOSKIZOQGBY-PMDAXIHYSA-N [3-[3-[3-[3-[3-[3-[3-[3-[3-[2,3-bis[[(Z)-octadec-9-enoyl]oxy]propoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-[(Z)-octadec-9-enoyl]oxypropyl] (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(COC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC NGHUOSKIZOQGBY-PMDAXIHYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- 239000010685 fatty oil Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000787 lecithin Substances 0.000 claims description 5
- 235000010445 lecithin Nutrition 0.000 claims description 5
- 229940067606 lecithin Drugs 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 150000004667 medium chain fatty acids Chemical class 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 5
- 235000019702 pea protein Nutrition 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 235000018102 proteins Nutrition 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 5
- 230000001603 reducing effect Effects 0.000 claims description 5
- 241000894007 species Species 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 5
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims description 5
- 150000003626 triacylglycerols Chemical class 0.000 claims description 5
- 235000021119 whey protein Nutrition 0.000 claims description 5
- ARIWANIATODDMH-AWEZNQCLSA-N 1-lauroyl-sn-glycerol Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)CO ARIWANIATODDMH-AWEZNQCLSA-N 0.000 claims description 4
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 108010005094 Advanced Glycation End Products Proteins 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000004062 sedimentation Methods 0.000 abstract description 12
- 235000019198 oils Nutrition 0.000 description 58
- 239000000523 sample Substances 0.000 description 16
- 235000015112 vegetable and seed oil Nutrition 0.000 description 14
- 239000008158 vegetable oil Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 12
- 239000000828 canola oil Substances 0.000 description 11
- 235000019519 canola oil Nutrition 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 8
- 238000003801 milling Methods 0.000 description 8
- 230000002776 aggregation Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000000473 propyl gallate Substances 0.000 description 4
- 235000010388 propyl gallate Nutrition 0.000 description 4
- 229940075579 propyl gallate Drugs 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- 238000010951 particle size reduction Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000004904 shortening Methods 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- ODFAPIRLUPAQCQ-UHFFFAOYSA-M sodium stearoyl lactylate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O ODFAPIRLUPAQCQ-UHFFFAOYSA-M 0.000 description 3
- 239000003724 sodium stearoyl-2-lactylate Substances 0.000 description 3
- 235000010956 sodium stearoyl-2-lactylate Nutrition 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 235000010384 tocopherol Nutrition 0.000 description 3
- 229960001295 tocopherol Drugs 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000002679 ablation Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 2
- 230000005653 Brownian motion process Effects 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 1
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 235000010385 ascorbyl palmitate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005537 brownian motion Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000021149 fatty food Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229940097156 peroxyl Drugs 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010099 solid forming Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
- C11B5/0028—Carboxylic acids; Their derivates
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- Ascorbic is a food additive with that serves a variety of functions in foods. It is an excellent antioxidant / stabilizer under certain circumstances. For example, it can be used to prolong the shelf life of vegetables oils, where its beneficial role appears to be in part due to its ability to reduce and thereby recycle oxidized tocopherol intermediates. As oils oxidize, peroxyl- and alkoxyl radical intermediates are formed. Tocopherols, which are natural antioxidants normally present in vegetable oils, donate a phenolic hydrogen atom to the peroxyl and / or alkoxyl radicals, effectively preventing them from carrying on the oxidation radical chain reaction. In the process, tocopherol radicals are produced.
- Tocopherols are not naturally present in animal fats, but when added are very effective stabilizers. Ascorbic acid / tocopherol combinations in animal fats have proved to be very powerful antioxidant combinations.
- US Patent No. 5,230,836 describes an antioxidant composition consisting essentially of solid particles of ascorbic acid which are less than about 38 microns in size on their largest dimension and their use in stabilizing fatty foods, including food oils. Additional disclosure pertains to an antioxidant composition comprising solid ascorbic acid particles in which essentially all of the particles are less than 20 microns in size on their largest dimension and, further, an
- antioxidant composition comprising solid ascorbic acid particles in which 50% of the particles are less than 10 microns in size on their largest dimension.
- ASCORBALOX is a registered trademark of Kalsec, Inc. This product by itself and in combination with other antioxidants, such as rosemary extract and / or tocopherols, is very useful in the stabilization of vegetable oils, animal fats and a variety of food products.
- the utility of ASCORBALOX® in oil systems is limited by appearance and handling issues. Due to the particulate nature of ascorbic acid and its insolubility in vegetable oil, the oils treated with this product appear hazy or cloudy.
- particulate ascorbic acid consisting essentially of solid particles of ascorbic acid which are less than about 1.0 micron in size, including less than about 0.5 micron in size, on their largest dimension that are effective stabilizers of edible fluid fats and oils.
- ascorbic acid particles of this dimension provide treated oil with a significantly improved visual appearance over oils treated with the ascorbic acid compositions of US Patent No. 5,230,836.
- a significant reduction in haze anjncrease in visual clarity
- significant reduction in the amount of ascorbic acid that settles out of the oil as well as an increase in time before settling occurs can be obtained.
- compositions of ascorbic acid consisting essentially of solid particles of ascorbic acid which are less than about one micron in size on their largest dimension, including ascorbic acid particles which are less than about 0.5 microns in size on their largest dimension, and suspended in a fluid edible carrier, which solid ascorbic acid particles are indefinitely suspendable in a fluid fat or oil, without sedimentation at 1 x g, and are transparent or nearly transparent in the fluid fat or oil which is stabilized by the ascorbic acid composition therein.
- the stabilizing compositions of the instant invention exhibit improved performance characteristics compared to ascorbic acid compositions of US Patent No. 5,230,836 and serve as an antioxidant in foods, vegetable oils, shortenings and animal fats.
- compositions comprising ascorbic acid consisting essentially of solid particles of ascorbic acid which are less than about one micron in size on their largest dimension in combination with other antioxidants, including, but not limited to tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, and hydrolyzed proteins, including hydrolyzed pea proteins.
- antioxidants including, but not limited to tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, and hydrolyzed proteins, including hydrolyzed pea proteins.
- composition of ascorbic acid consisting essentially of solid particles of ascorbic acid which are less than about 0.5 micron in size on their largest dimension and suspended in a fluid edible carrier, which solid ascorbic acid particles are indefinitely suspendable in a fluid fat or oil, without sedimentation at 1 x g and transparent or nearly transparent in the fluid fat or oil, which is stabilized by the ascorbic acid composition therein.
- compositions comprising ascorbic acid consisting essentially of solid particles of ascorbic acid which are less than about 0.5 micron in size on their largest dimension in combination with other antioxidants, including, but not limited to tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, hydrolyzed proteins, including hydrolyzed pea proteins or Maillard reaction products or mixtures thereof.
- antioxidants including, but not limited tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, hydrolyzed proteins, including hydrolyzed pea proteins or Maillard reaction products or mixtures thereof.
- a stabilizing composition comprising solid particles of ascorbic acid which are less than about 1.0 micron in size on their largest dimension, wherein the solid particles are dispersed in an edible substance, such a
- stabilizing composition wherein the solid particles of ascorbic acid are less than about 0.5 micron in size on their largest dimension, wherein the solid particles are dispersed in an edible substance, such a
- stabilizing composition wherein the edible substance is an edible fluid fat or oil, such a
- stabilizing composition further comprising another antioxidant, such a
- stabilizing composition wherein the another antioxidant is selected from tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, hydrolyzed proteins, including hydrolyzed pea proteins, Maillard reaction products and mixtures thereof, such a
- stabilizing composition further comprising a compound selected from glycerol esters; lecithin and lecithin derivatives; mono glycerides; diglycerides; mixtures of mono and diglycerides; mixtures of mono-, di- and triglycerides; capric / caprylic diglycerides; glycerol monolaurate; ethoxylated glycerol esters; ethoxylated fatty acids; propylene glycol stearate; ethoxylated fatty acids and oils; ethoxylated alcohols; sorbitan derivatives; decaglycerol tetraoleate and chemically related species; sulfosuccinates and derivatives; whey protein-based dispersants; silicone glycol copolymers; stearic acid; fatty acids; fatty alcohols; medium-chain fatty acids; medium-chain fatty alcohols; sodium stearoyl-2- lactylate; polyoxyethylene (20)
- the invention pertains to a method of preparing solid particles of ascorbic acid which are less than about 1.0 micron in size on their largest dimension comprising, reducing the particle size of ascorbic acid solids by grinding ascorbic acid to a particle size of less than about 1.0 micron in size, and wherein the solid particles of ascorbic acid are dispersed in an edible substance, such a
- silicone glycol copolymers stearic acid; fatty acids; fatty alcohols; medium-chain fatty acids; medium-chain fatty alcohols; sodium stearoyl-2-lactylate;
- polyglycerol polyricinoleate decaglycerol decaoleate; and mixtures thereof, such a
- method further comprising the step of separating the particles less than about one micron using a mechanical means including a centrifuge, filter or seive, such a
- a mechanical means including a centrifuge, filter or seive
- method of preparing an antioxidant composition comprising, the step of milling a mixture of ascorbic acid, rosemary extract and a food grade surfactant, wherein the ascorbic acid particles in the finished product are less than one micron on their largest dimension, such a
- fluid fats and oils may be stabilized by the addition of compositions comprising particulate ascorbic acid of small enough dimension that the particles remain suspended by the action of Brownian motion. Moreover, if the particles of ascorbic acid are small enough, they lose the ability to scatter light and become transparent, or nearly so.
- particulate ascorbic acid of the appropriate dimensions. This can be
- milling or ablation is aided by the addition of ingredients with surface active properties.
- Such components are an important component of the invention and include food grade surface active ingredients such as those found in McCutcheon's handbook of surfactants. It is important that the surface active ingredients used in the application are food grade materials, since the material will be used in food products. This presents a challenge, because food grade surface active ingredients are a limited subset of surface active ingredients and may not include the most effective structures for effecting particle size reduction.
- the necessary food-grade surface modifying and / or aggregation-preventing substances include, but are not limited to: glycerol esters, lecithin and lecithin derivatives, mono glycerides, diglycerides, mixtures of mono and diglycerides, mixtures of mono-, di- and triglycerides, capric / caprylic diglycerides, glycerol monolaurate, ethoxylated glycerol esters, ethoxylated fatty acids, propylene glycol stearate, ethoxylated fatty acids and oils, ethoxylated alcohols, sorbitan derivatives, decaglycerol tetraoleate and chemically related species,
- sulfosuccinates and derivatives whey protein-based dispersants, silicone glycol copolymers, stearic acid, fatty acids, fatty alcohols, medium-chain fatty acids, medium-chain fatty alcohols, sodium stearoyl-2-lactylate, polyoxyethylene (20) tritallate and maleic or succinic anhydride derivatives, polyglycerol polyricinoleate, decaglycerol decaoleate, or mixtures thereof.
- Another important technical feature of the invention deals with preventing the agglomeration of non-sedimenting small particles, once prepared, into aggregates of larger size that form over time, creating hazy suspensions or precipitate in the form of sediment.
- Surface active substances such as those listed above may be added to the composition to prevent or slow the
- Particles of the appropriate size may also be obtained by separating appropriately sized "fines" from a mixture containing a range of particle sizes by using various sieving or other particle size separation techniques known in the art, including sedimentation, centrifugation, precipitation, filtration and the like.
- Example 1 Preparation of ascorbic acid of particle size ⁇ 5 microns.
- Dry ascorbic acid powder 25% by weight, was combined with 74% by weight of canola oil with 1% by weight of DREWPOL ® PGPR (polyglycerol polyricinoleate) and mixed using a high shear mixer at low speed for 15 minutes.
- DREWPOL ® PGPR polyglycerol polyricinoleate
- This mixture was introduced into a Buhler Laboratory K8 bead mill with 600 ml of 0.5 mm YTZ (yttria-stabilized zerconia) media and recirculated for 90 minutes after which a second 1% by weight of DREWPOL ® PGPR was added and recirculation continued for a total of 150 minutes.
- the resulting milled ascorbic particle size was measured with a Horiba LA930 and was found to have a mean particle size of 0.99 microns with 100% ⁇ 5 microns.
- DREWPOL ® is a registered trademark of the Stepan Company.
- Example 2 Preparation of ascorbic acid of particle size ⁇ 1 microns.
- the resulting milled ascorbic was diluted with an additional 5% canola oil and 5% DREWPOL ® 10- 10-0 and milled in a PML2-Superflow 4 mill with 0.3 mm YTZ media for 120 minutes.
- the particle size of this milled ascorbic reached a mean size of 0.40 microns with 98% of all particles by volume ⁇ 0.75 microns.
- Example 3 A further example of the preparation of ascorbic acid compositions of reduced particle size.
- Canola oil 4050 g was combined with 67.5 g DREWPOL ® 10-10-0
- Samples of 3A, 3B and 3C were dosed separately into canola oil at levels giving 200 ppm ascorbic acid in the final dosed oil and 50 g of each dosed oil was transferred to a 55 ml clear glass centrifuge tube, stoppered and allowed to sit undisturbed at 1 x g to visually examine the appearance and settling behavior.
- a control sample of canola oil dosed at the same level with ASCORBALOX ® the commercially available inventive composition of US Patent No. 5,230,836, was prepared coincidentally. The results after 50 days of undisturbed storage are shown in Table 2.
- Example 4 Preparation of ascorbic acid of particle size ⁇ 0.5 microns.
- Example 2 The milled output of Example 2 is placed in a micromedia mill with 0.05 mm media, diluted with additional vegetable oil and food grade surface active agents and milled for 120 minutes.
- the output shows particle size distribution 100% below 0.5 microns. Further milling reduces the particle size to 0.2 microns and below.
- the material produced by this method when dispersed in vegetable oil is clear and shows no sedimentation after 50 days of undisturbed storage.
- Example 5 Stabilization of Vegetable oil using super-micronized ascorbic acid.
- Sample 5A was prepared from a rosemary extract and a milled ascorbic acid suspension where 50% of ascorbic particles are less than 10 microns
- Sample 5B was prepared from a rosemary extract and a more finely ground ascorbic acid where 98% of ascorbic particles were less than one micron on their largest dimension.
- the preparations were formulated to provide compositions with equal levels of rosemary extract and milled ascorbic acid. These compositions were separately added to canola oil at a level of 2000 ppm and after stirring, observations on optical clarity and sedimentation rate at 1 x g were made. Initially, the oil containing Sample 5B appeared much less hazy than the oil containing Sample 5A. After 50 days of undisturbed settling at 1 x g, the oil fortified with Sample 5B showed less than 10% of the sedimentation of the oil sample treated with Sample 5A.
- Example 6 Stabilization of Vegetable oil using super-micronized ascorbic acid from Example 4.
- the milled ascorbic acid preparation from Example 4 is combined with a rosemary extract to provide compositions with equal levels of rosemary extract and milled ascorbic acid.
- This composition is added to canola oil at a level of 2000 ppm to observe appearance and sedimentation rate.
- the initial oil sample prepared from the ⁇ 0.5 micron ascorbic acid is largely transparent when compared to similar samples prepared with commercially available
- ASCORBALOX ® - containing preparations After 50 days of undisturbed settling at 1 x g, the oil fortified with this super micronized ascorbic acid and rosemary extract shows no sedimentation of the oil sample.
- the initial oil sample prepared from the ⁇ 0.2 micron ascorbic acid is largely transparent.
- the oil fortified with this super micronized ascorbic acid and rosemary extract shows no sedimentation of the oil sample and has superior appearance to identical oils treated with commercially available ASCORBALOX ® - containing preparations.
- the oil treated with the ⁇ 0.2 micron ascorbic acid shows equal or superior antioxidative stability to the samples prepared with commercially available ASCORBALOX ® - containing preparations.
- the ascorbic acid compositions of the present invention are combined with tocopherols, Labiatae herb extracts, rosemary extracts, tea extracts, oregano extracts, BHA, BHT, propyl gallate, TBHQ, and hydrolyzed proteins, including hydrolyzed pea proteins, singly or in combination to create new antioxidant compositions suitable for use in oils, fluid fats and other foods.
- Example 7 Demonstrating the formation of an ascorbic acid composition via a sieving process.
- the ascorbic acid preparation resulting from Example 1 is subjected to a screening or sieving process using suitable equipment.
- the material is placed in contact with a metallic or ceramic element having hole sizes of 0.5 microns.
- the material is treated in a way to allow a portion of the particles less than 0.5 microns to pass through the element, together with a portion of the fluid carrier.
- the material that passes the element contains ascorbic acid can be used as a stabilizer for vegetable oils or fluid animal without forming a sediment upon storage or presenting an unattractive hazy or cloudy appearance.
- Example 8 Demonstrating the formation of an ascorbic acid composition via a centrifugation process.
- Example 1 The ascorbic acid preparation of Example 1 is subjected to a
- Centrifugation results in the formation of a pellet and a supernatant phase.
- One skilled in the art can develop appropriate conditions for operating the centrifuge such that the supernatant phase contains particles less than 1 micron or less than 0.5 microns.
- the supernatant can be separated from the pellet of solid ascorbic acid and used to stabilize vegetable oil as described above.
- Example 9 Demonstrating the preparation of an antioxidant formulation prepared by the milling of a combination of ascorbic acid and rosemary extract.
- a blend of ascorbic acid, rosemary extract, food grade surfactant and optionally vegetable oil as a thinner to control viscosity is milled using the equipment and methods described in Examples 1-4 to prepare antioxidant compositions that can be used to stabilize vegetable oil or fluid fats.
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Abstract
La présente invention concerne des compositions d'acide ascorbique constituées de particules solides d'acide ascorbique dont la taille est inférieure à environ un micron dans leur plus grande dimension et qui sont suspendues dans un vecteur fluide comestible, lesdites particules solides d'acide ascorbique pouvant être indéfiniment suspendues dans une graisse fluide ou une huile sans sédimentation à 1 g, et étant transparentes ou quasi-transparentes dans la graisse fluide ou l'huile qui est stabilisée par la composition d'acide ascorbique qui s'y trouve.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5230836A (en) | 1991-06-20 | 1993-07-27 | Kalamazoo Holdings, Inc. | Low micron-sized ascorbic acid particles, especially a suspension thereof in a medium in which they are insoluble, and the use thereof as an antioxidant for mediums in which the particles remain insoluble |
WO2000006155A1 (fr) * | 1998-07-27 | 2000-02-10 | Sunsmart, Inc. | Composition d'acide ascorbique stabilisee et procede d'utilisation |
WO2001003664A1 (fr) * | 1999-07-08 | 2001-01-18 | International Flora Technologies, Ltd. | Acide ascorbique stabilise, composition et procede d'utilisation |
AU2003204456A1 (en) | 2002-11-23 | 2004-06-10 | Aquanova German Solubilisate Technologies (Agt) Gmbh | Aqueous solution of ascorbic acid and method for producing same |
US7101563B1 (en) * | 2000-03-03 | 2006-09-05 | Australian Importers, Ltd. | Micronized vitamin C formulation |
-
2011
- 2011-09-16 WO PCT/US2011/001599 patent/WO2012036743A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5230836A (en) | 1991-06-20 | 1993-07-27 | Kalamazoo Holdings, Inc. | Low micron-sized ascorbic acid particles, especially a suspension thereof in a medium in which they are insoluble, and the use thereof as an antioxidant for mediums in which the particles remain insoluble |
US5290481A (en) * | 1991-06-20 | 1994-03-01 | Kalamazoo Holdings, Inc. | Low micron-sized ascorbic acid particles, especially a suspension thereof in a medium in which they are insoluble, and the use thereof as an antioxidant for mediums in which the particles remain insoluble |
WO2000006155A1 (fr) * | 1998-07-27 | 2000-02-10 | Sunsmart, Inc. | Composition d'acide ascorbique stabilisee et procede d'utilisation |
WO2001003664A1 (fr) * | 1999-07-08 | 2001-01-18 | International Flora Technologies, Ltd. | Acide ascorbique stabilise, composition et procede d'utilisation |
US7101563B1 (en) * | 2000-03-03 | 2006-09-05 | Australian Importers, Ltd. | Micronized vitamin C formulation |
AU2003204456A1 (en) | 2002-11-23 | 2004-06-10 | Aquanova German Solubilisate Technologies (Agt) Gmbh | Aqueous solution of ascorbic acid and method for producing same |
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