WO2012016513A1 - 具有副巷道的原地浸取引流收液工艺 - Google Patents
具有副巷道的原地浸取引流收液工艺 Download PDFInfo
- Publication number
- WO2012016513A1 WO2012016513A1 PCT/CN2011/077907 CN2011077907W WO2012016513A1 WO 2012016513 A1 WO2012016513 A1 WO 2012016513A1 CN 2011077907 W CN2011077907 W CN 2011077907W WO 2012016513 A1 WO2012016513 A1 WO 2012016513A1
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- WO
- WIPO (PCT)
- Prior art keywords
- roadway
- collecting
- liquid
- liquid collection
- auxiliary
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 78
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 19
- 238000002386 leaching Methods 0.000 title claims abstract description 19
- 238000007789 sealing Methods 0.000 claims abstract description 29
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 20
- 239000011707 mineral Substances 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000012452 mother liquor Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 230000008595 infiltration Effects 0.000 claims description 6
- 238000001764 infiltration Methods 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 230000002265 prevention Effects 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 15
- 150000002910 rare earth metals Chemical class 0.000 abstract description 15
- 238000004064 recycling Methods 0.000 abstract 2
- 238000005259 measurement Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/02—Apparatus therefor
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
- E21B43/283—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent in association with a fracturing process
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C41/00—Methods of underground or surface mining; Layouts therefor
- E21C41/26—Methods of surface mining; Layouts therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to the technical field of mineral exploitation, in particular to an in-situ leaching drainage liquid collection process, in particular to a in-situ leaching and liquid collection process of a full double ion adsorption type rare earth ore.
- the first type of liquid collection technology is artificial false bottom interception and liquid collection.
- the technology adopts engineering technical measures such as liquid collecting roadway, intercepting hole and cement slurry to prevent seepage treatment of liquid collecting project, and set artificial liquid mother collecting system, but the mother liquid is collected.
- the anti-seepage technology of the intercepting hole is not mature enough, which often leads to the plugging of the intercepting hole and the anti-seepage material anti-seepage to the upper half wall and the side wall of the intercepting hole, which hinders the normal collection of the mother liquid.
- the mother liquor loss rate is large.
- the intercept hole does not control the mother liquor infiltration well.
- the mother liquor collection system has the loss rate of the pre-mineral solution and the rare earth mother liquor.
- the balance is not conducive to the recovery of rare earth mother liquor, thereby reducing the recovery rate of rare earths, forming a bottleneck that is difficult to increase the recovery rate of rare earths, and will also cause environmental pollution and other problems.
- the second liquid-receiving technique is a technique of artificially feeding water into a lean ore-free layer and a non-mineral layer to saturate it to form an artificial water-sealed floor.
- the biggest disadvantages of artificial water-sealed bottom plate are long process cycle, long tail liquid collection time, low mother liquor concentration, harsh implementation conditions, difficult implementation, and especially difficult to control the stability of mountain slopes. In actual mining activities, artificial water seals are rarely used.
- the object of the present invention is to provide an in-situ leaching drainage liquid collection process with a secondary roadway, so that most of the pre-mineral liquid (more than 80%) penetrates below the engineering control surface to improve the lean or non-mineral layer below the engineering control surface.
- the water content so as to increase the ratio of the pre-mineral solution into the lean or no ore zone and reduce the ratio of the mother liquor to the ground, thereby achieving the purpose of improving the recovery of the rare earth.
- the process can reduce the loss rate of the mother liquor, is beneficial to the recovery of the rare earth mother liquor, can reduce the environmental pollution problem, and can also improve the rare earth recovery rate.
- the present invention provides an in-situ leaching drainage liquid collection process having a secondary roadway, characterized in that:
- the auxiliary roadway is arranged on both sides of the collecting roadway, and the pressure gradient is alternately changed, and finally a multi-channel mother liquid drainage liquid collecting control engineering surface is formed on the plane composed of the ore body between the liquid collecting roadway, the auxiliary roadway and the roadway, and Forming a mother liquor collection control system together with a lean or no ore zone that changes the water content;
- a sealing wall is arranged in the collecting roadway, and the front part of the sealing wall is connected to the roadway opening by a conduit, and the pipe is controlled by a ball valve switch at the exit;
- a high and low pressure gradient zone is formed on the plane formed between the ore body and the engineering control surface by the change of the pressure gradient, and finally a multi-channel mother liquor collection engineering system is formed;
- the liquid collection roadway is set according to the following principles:
- the height of the collecting tunnel in the ore body is between 0.015% and 0.02% of the bottom of the ore body;
- the liquid collection roadway is arranged along the mountain body
- the location of the collection tunnel is preferably passed through a good grade of the ore body.
- the auxiliary roadway is arranged on both sides of the collecting roadway, and the auxiliary roadway and the liquid collecting roadway together form a multi-channel mother liquid drainage liquid collecting control engineering surface.
- a plurality of sealing walls are arranged in the collecting roadway, and the sealing wall is an impervious wall embedded in the surrounding of the roadway to prevent the outflow of the pre-mineral liquid, so that the pre-mineral liquid is infiltrated along the engineering control surface, and the roadway collapse is prevented before and after the sealing of the wall.
- a sealing wall is arranged every 20 to 30 meters in the direction of the working face to the collecting channel, and a plurality of sealing walls can be arranged up to a distance of 10 meters from the roadway.
- the location of the sealing wall can be in front of and adjacent to the roadway support column to prevent the sealing wall from collapsing.
- the sealing wall can be set by means of red bricks embedded in the roadway.
- the front part of the sealing wall is filled with anti-blocking materials, and the lower part is connected to the collecting roadway by a conduit. At the same time, attention should be paid to the anti-blocking measures of the roadway and the pipeline.
- the duct is controlled by a ball valve switch at the exit. The ball valve switch is used to detect whether there is a mother liquid.
- a high and low pressure gradient zone is formed between the ore body and the engineering control surface by increasing and releasing the pressure, and finally forming a plurality of
- the channel mother liquor recovery control engineering system forms a mother liquor collection control system together with the lean or no-mineral zone that changes the water content.
- the lower front conduit of the plugging wall is opened with a ball valve at the outlet, and the main purpose is to control the infiltration of the pre-mine solution and the collection of the mother liquor.
- the anti-blocking material may be firewood.
- the conduit can be a plastic coil or a PVC tube.
- the pipeline is inspected daily (or according to its characteristics) for the presence of mother liquor.
- the purpose is to reduce the pre-mine solution to the engineering control surface as much as possible, and reduce the infiltration of the mother liquor at the engineering control surface. Capacity; 2
- the ball valve switch is released.
- the multi-channel, liquid-collecting roadway and the lean or non-mineral zone that change the water content form a mother liquid collection system; if there is no mother liquid, the ball valve switch is closed.
- the number of daily inspections should be flexibly controlled according to the characteristics of the pre-mineral liquid, up to once a day. Through multiple inspections, a multi-pass mother liquor recovery control surface is formed which, together with its lower saturated or nearly saturated water cover, ultimately forms a mother liquor collection system for a water seal, high pressure gradient multiple mother fluid drainage path.
- 2 to 3 strips are arranged to follow the trend or tendency of the mountain body, and the collecting channel which is supplemented by the position where the grade is distributed on the plane as much as possible is gentle, and the slope is 1 to 2°, which is advantageous for Infiltration of pre-mineral liquid.
- the sealing wall may not be provided, and the static pressure grouting method is adopted to make most of the ore liquid infiltrated into the water sealing bottom plate along the ore body between the roadway.
- the plurality of collecting lanes are parallel collecting lanes with a spacing of 15-20 meters.
- the sections of the collecting roadway and the auxiliary roadway are trapezoidal, and the lower bottom width and the upper bottom width of the liquid collecting roadway are respectively 1.4 to 1.6 times of the auxiliary roadway, and the height of the liquid collecting roadway is 0.8 to 1.0 times of the auxiliary roadway. .
- the section of the collecting roadway is a trapped liquid-collecting roadway having a width of 1.2 m at the bottom, a width of 0.7 m and a height of 1.7 m, and a section of the auxiliary roadway having a width of 0.8 m at the bottom and a width of 0.4 m and a height of 1.6 ⁇ . 1.7 meters.
- the auxiliary roadway is arranged on both sides of the collecting roadway, and the interval between the auxiliary roadways is 5-10 meters, and the liquid collecting roadway is at an angle of 90[deg.] or parallel to each other.
- the anti-seepage treatment may not be performed on the bottom of the collecting roadway and the auxiliary roadway.
- the bottom of the collecting roadway and the auxiliary roadway are treated with a dilution cement slurry for anti-seepage treatment.
- a red brick building is embedded around the roadway to set the sealing wall, and the sealing wall is not provided under special geological conditions.
- the front part of the sealing wall is filled with firewood, and the lower part is connected to the roadway opening with a 1.5 to 3 inch (inner diameter 5 cm) plastic coil or PVC pipe.
- the switching operation of the ball valve switch is combined multiple times, forming a combination of engineering control surface and mineral reduction and increasing pressure gradient, by increasing and decreasing pressure in the ore body and engineering control A high-low pressure gradient zone is formed between the faces, and finally a multi-channel mother liquor collection system with a water seal and a high pressure gradient is formed.
- the pre-mineral solution in the in-situ leaching of the ion-adsorbing rare earth is effectively utilized, and about 15% of the water is contained in the granite weathering crust or the volcanic tuff ion-adsorbing rare earth ore, and the in-situ dip is performed.
- the geotechnical engineering was injected with static pressure grouting, it was first rushed out and called the pre-mineral solution.
- the process causes most of the pre-mineral liquid (about 80% or more) to penetrate into the lean ore-free zone, and alternately operates by reducing and increasing the pressure gradient between the control surface of the liquid-collecting project and the ore to form a multi-channel mother liquor.
- the drainage control surface is finally introduced to improve the water content of the lean ore-free zone, prevent the infiltration of the rare earth mother liquor, reduce the amount of leaching agent, and reduce the loss rate of the mother liquor.
- the multi-channel mother liquor recovery control surface is formed by the process of the invention, which is beneficial to the recovery of the rare earth mother liquor and reduces the environmental pollution problem.
- Theoretical and practical use have confirmed that the rare earth resource recovery rate according to the present invention is increased by at least 10% or more, that is, the rare earth recovery rate is improved.
- FIG. 1 is a plan view of a roadway connecting a roadway of a liquid collection roadway according to the present invention.
- the specific implementation method of the technical solution of the present invention is as follows: according to the ore body grade distribution and hydraulic principle, the height in the ore body is between 0.015% and 0.02% of the bottom of the ore body, and the trend or tendency along the mountain body is Mainly, as much as possible by the position where the grade is distributed high on the plane, the liquid collection roadway 1 is set, and the slope is 1 to 2°.
- the auxiliary roadway 8 is arranged at intervals of 5 to 10 meters on both sides of the collecting roadway, and the cement slurry anti-seepage measures can be implemented at the bottom of the roadway 1.
- a plurality of support columns 7 may be disposed on both sides of the collection roadway 1.
- the sealing wall 3 is implemented every 20 to 30 meters and in front of the nearby support column 7, thereby dividing the liquid collection roadway 1 into several sections.
- the bottom is connected to the laneway by a coil or PVC pipe 4 to collect the mother liquor.
- Each of the liquid collection roadways 1 separated by the sealing wall 3 is provided with a coil or a PVC pipe 4 connected to the roadway opening.
- the roadway in front of the sealing wall 3 (the side away from the ball valve 6) is filled with anti-blocking firewood 5, and is subjected to anti-blocking treatment, and the ball valve 6 is connected at the outlet of the coil or PVC pipe 4.
- the pre-mineral liquid is infiltrated along the control surface formed by the liquid collection roadway 1 and the auxiliary roadway 8, and the liquid collection system is opened when the mother liquid is present.
- a multi-channel mother liquor collection engineering system is finally formed, which together with the lean or no-mineral zone that changes the water content forms a mother liquor collection system.
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Geochemistry & Mineralogy (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Remote Sensing (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Gas Separation By Absorption (AREA)
- Underground Structures, Protecting, Testing And Restoring Foundations (AREA)
- Road Paving Structures (AREA)
Description
Claims (10)
- 一种具有副巷道的原地浸取引流收液工艺,其特征在于:1) 在矿体中设置多条集液巷道;2) 在集液巷道两侧设置副巷道,通过增加释放压力,最终形成在集液巷道、副巷道及巷道之间的矿土组成的平面上的多通道的母液引流收液控制工程面;3) 在集液巷道中设置封堵墙,封堵墙下部用导管连接至巷道口,导管在出口处用球阀开关控制;4) 在检测操作或生产过程中,通过压力梯度的改变,在矿体与工程控制面之间形成压力梯度的改变,最终形成多通路的母液收集工程系统,该系统与改变含水率的贫矿层或无矿层共同组成母液收集系统;5)特定的收液条件下,可仅设置主巷道、副巷道,而不设置封堵墙及不对巷道底部进行防渗处理。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述集液巷道的位置依以下原则确定:1) 集液巷道在矿体中的高度为在矿体底部0.015%~0.02%之间;2) 集液巷道沿山体走向布置;3) 集液巷道的位置为尽可能的通过矿体品位好的部位。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述集液巷道的坡度为1~2°,所述集液巷道为2~3条平行的、间距20~30米、沿山体走向或倾向的集液巷道。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述副巷道间的间隔5~10米,与集液巷道呈90°角或副巷道之间相互平行。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述集液巷道底部采用稀释水泥浆进行防渗处理。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述设置在集液巷道两侧的副巷道底部,采用稀释水泥浆进行防渗处理。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述封堵墙为嵌入巷道四周的不透水墙,封堵墙前后进行预防巷道坍塌施工。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:所述封堵墙前部用防堵物料充填,封堵墙下部集液管在巷道出口处用球阀开关控制矿前液下渗和母液的收集。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:多次对球阀开关的开关操作组合,形成在工程控制面处与矿土的减小和增大压力梯度组合,最终形成了水封、高压力梯度的多通路母液收集系统。
- 根据权利要求1所述的原地浸取引流收液工艺,其特征在于:集液巷道和副巷道的截面都呈梯形,集液巷道的下底宽、上底宽分别为副巷道的1.4~1.6倍、集液巷道的高为副巷道的0.8~1.0倍。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2011288098A AU2011288098A1 (en) | 2010-08-03 | 2011-08-02 | Liquid guiding and collection process with secondary channels for in situ leaching |
EP11814096.1A EP2602426A1 (en) | 2010-08-03 | 2011-08-02 | Liquid guiding and collection process with secondary channels for in situ leaching |
US13/814,112 US20130200681A1 (en) | 2010-08-03 | 2011-08-02 | Liquid collection process with secondary channels for in-situ leaching an ore body to extract rare earth elements |
JP2013522090A JP2013535598A (ja) | 2010-08-03 | 2011-08-02 | その位置での溶脱のための第2チャンネルを有する液体ガイド及び回収方法 |
KR1020137005515A KR101407350B1 (ko) | 2010-08-03 | 2011-08-02 | 희토를 추출하기 위하여 보조 채널을 이용하여 광체를 현장 침출하는 액체 수집 방법 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN2010102478132A CN101906536B (zh) | 2010-08-03 | 2010-08-03 | 具有副巷道的原地浸取引流收液工艺 |
CN201010247813.2 | 2010-08-03 |
Publications (1)
Publication Number | Publication Date |
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WO2012016513A1 true WO2012016513A1 (zh) | 2012-02-09 |
Family
ID=43262120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2011/077907 WO2012016513A1 (zh) | 2010-08-03 | 2011-08-02 | 具有副巷道的原地浸取引流收液工艺 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20130200681A1 (zh) |
EP (1) | EP2602426A1 (zh) |
JP (1) | JP2013535598A (zh) |
KR (1) | KR101407350B1 (zh) |
CN (1) | CN101906536B (zh) |
AU (1) | AU2011288098A1 (zh) |
WO (1) | WO2012016513A1 (zh) |
Cited By (1)
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CN101906536B (zh) * | 2010-08-03 | 2012-01-04 | 江西稀有金属钨业控股集团有限公司 | 具有副巷道的原地浸取引流收液工艺 |
CN101936166B (zh) * | 2010-08-03 | 2013-03-13 | 江西稀有金属钨业控股集团有限公司 | 具有导流孔的原地浸取引流收液工艺 |
CN105177282B (zh) * | 2015-09-11 | 2017-05-10 | 四川共拓岩土科技股份有限公司 | 一种防止离子型稀土矿山体滑移的注液装置 |
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CN110685693B (zh) * | 2019-10-25 | 2024-08-27 | 江西离子型稀土工程技术研究有限公司 | 一种离子型稀土原地浸矿截流收液装置及其使用方法 |
CN111944997B (zh) * | 2020-08-06 | 2022-07-12 | 四川共拓岩土科技股份有限公司 | 一种水平孔电渗管道收液法 |
CN112048618B (zh) * | 2020-09-11 | 2022-03-04 | 江西理工大学 | 提高离子型稀土原地浸矿母液收集效率的方法 |
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CN101906536A (zh) * | 2010-08-03 | 2010-12-08 | 江西稀有金属钨业控股集团有限公司 | 具有副巷道的原地浸取引流收液工艺 |
CN201802377U (zh) * | 2010-08-03 | 2011-04-20 | 江西稀有金属钨业控股集团有限公司 | 具有副巷道的原地浸取引流收液系统 |
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2011
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- 2011-08-02 EP EP11814096.1A patent/EP2602426A1/en not_active Withdrawn
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- 2011-08-02 KR KR1020137005515A patent/KR101407350B1/ko not_active IP Right Cessation
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EP1375456A2 (en) * | 2002-06-26 | 2004-01-02 | Union Espanola De Explosivos S.A. | Process for the "in situ" manufacturing of explosive mixtures |
CN101906536A (zh) * | 2010-08-03 | 2010-12-08 | 江西稀有金属钨业控股集团有限公司 | 具有副巷道的原地浸取引流收液工艺 |
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CN113832342A (zh) * | 2021-10-19 | 2021-12-24 | 赣州有色冶金研究所有限公司 | 一种完全型人造底板造设方法和应用 |
Also Published As
Publication number | Publication date |
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KR101407350B1 (ko) | 2014-06-13 |
KR20130041298A (ko) | 2013-04-24 |
EP2602426A1 (en) | 2013-06-12 |
US20130200681A1 (en) | 2013-08-08 |
JP2013535598A (ja) | 2013-09-12 |
AU2011288098A1 (en) | 2013-02-28 |
CN101906536A (zh) | 2010-12-08 |
CN101906536B (zh) | 2012-01-04 |
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