WO2012011768A2

WO2012011768A2 - Cleanser composition for removing makeup from the skin

Info

Publication number: WO2012011768A2
Application number: PCT/KR2011/005412
Authority: WO
Inventors: 정창조; 김대경; 이존환; 김현나
Original assignee: (주)아모레퍼시픽
Priority date: 2010-07-23
Filing date: 2011-07-22
Publication date: 2012-01-26
Also published as: WO2012011768A3

Abstract

The present invention relates to a cleanser composition for removing makeup from the skin. The composition of the present invention comprises a silicon-based surfactant and a polyol, or comprises a silicon-based surfactant, in which PEG is added to both terminals of silicon to increase hydrophilicity, and a surfactant having a foam-generating ability, to thereby effectively removing makeup and provide users with refreshed feeling after washing.

Description

【Specification】

[Name of invention]

Makeup cleaner composition

Technical Field

<1> The present invention relates to a makeup detergent composition that effectively removes makeup and at the same time provides freshness after cleansing.

Background Art

<2> As more and more women wear makeup, erasing becomes more important than wearing makeup. In general, makeup users have used double cleansing using a cleanser such as soap or cleansing products after removing makeup using cleansing cream or oil when removing makeup. Therefore, in order to solve such a double face-to-face, the non-ionic surfactant-based cleansing water or wash-off type cleansing oil has been developed. However, these products have been developed more focused on one aspect because it was difficult to solve both the purpose of removing makeup and refreshing cleansing at once.

<3> In addition, the development of a cleaner that can remove makeup by physical force by using scrub beads, etc. These products remove make up and dead skin by physical stimulation, but if used repeatedly, it causes irritation of sebaceous glands. And symptoms such as redness of the face appear. In addition, it is easy to get into the eyes, and if you get into the eyes, it is difficult to wash off, causing pain.

[Detailed Description of the Invention]

[Technical problem]

Thus, the present inventors found that a silicone-based surfactant is used as a surfactant in a detergent composition, and when used with a specific polyol, the makeup may be well erased and the residue may be less refreshed after washing.

In addition, it has been found that silicone-based surfactants in which PEG is added to both ends of the silicone can provide a bubble-type cleaner that has excellent bubble retention ability, excellent makeup removal effect, and cleansing.

Accordingly, it is an object of the present invention to provide a cleansing composition capable of refreshing the face with effective makeup removal.

Technical Solution

<7> In order to achieve the above object, the present invention is a silicone-based surfactant and poly It provides a makeup cleaner composition comprising a.

In addition, the present invention provides a detergent composition comprising a silicone-based surfactant having a high hydrophilicity by adding PEG to both ends of the silicone and a surfactant having a foaming ability as an active ingredient.

Advantageous Effects

Makeup makeup composition according to the present invention, while the makeup is effectively removed, there is no residue can be a refreshing face wash and can eliminate the hassle of the double face wash.

[Brief Description of Drawings]

<ιο> Figure 1 shows the result after applying the lipstick to the bioskin and then removed using various silicone-based surfactants.

<π> Figure 2 shows the result after removing the lipstick using various polyols after applying the lipstick to the bioskin.

Figure 3 shows the result after removing the makeup using Comparative Example 1 of the cleaning composition prepared by applying the lipstick to the bioskin and then the composition of Table 3. 4 is a lipstick applied to a bioskin, and then a polyol is glyces_26 (M-Hydro).

It shows the result after removing makeup using the cleaning composition prepared by fixing with EG) and formulated according to the type of silicone surfactant.

FIG. 5 shows the application of lipstick to bioskin followed by polyol methyl glue-

It shows the result after removing makeup using the cleaning composition prepared by fixing to 20 (GLUCAM E-20) and formulating according to the type of silicone surfactant.

FIG. 6 illustrates the application of a lipstick to a bioskin and then varying the content of PEG-dimethicone isostearate (Si 1 wax WD-IS) and glycerin -26 (M—Hydro EG), which are silicone surfactants. The result after removing make-up using the detergent composition prepared by prescription is shown.

7 is a result of measuring the friction of Comparative Example 1 and Example 1.

8 is a graph showing the bubble power of the bubble foam type detergent composition according to the present invention.

9 is a photograph showing the makeup removal power of the bubble product type cleaner composition according to the present invention.

[Best form for implementation of the invention]

<19> The present invention is a cleansing clean through simultaneous cleansing with effective makeup removal This provides a possible makeup cleanser composition.

The present invention provides a makeup detergent composition comprising a silicone-based surfactant and a polyol.

The silicone-based surfactants included in the composition of the present invention may be dimethicone PEG-8 laurate, dimethicone PEG-8 succinate, PEG-12 dimethicone (PEG- 12 Dimethicone, PEG-10 Dimethicone, PEG7-Dimethicone Isostearate, Organomodified trimethyl ammonium chloride polydimethylsi 1 ixane, Silicon Quarter Si 1 ic le quaternium-8, silicon quaternium-20, Isopropyl phenyl Dimethicone, cetyl PEG / PPG-10 / 1 dimethicone (Cetyl PEG / PPG-10 / 1 Dimethicone) and lauryl PEG— 8 dimethicone may be one or more selected from the group consisting of, in particular, dimethicone page-7 isostearate It is preferable to use.

Representative structural formulas of the dimethicone page-7 isostearate used in the present invention are represented by the following Chemical Formula 1.

[Formula 1]

_{_{_{_{CH 3 CH 3 CH 3 CH 3}}}} CH 3 - Si - O - (Si -0) a - (Si - -Si - CH 3

o wherein "R" is derived from C18 methyl branched isostearic acid, with a total of 18 carbon atoms.

In addition, the polyol included in the composition of the present invention is PEG.PPG.polybutylene glycol -8.5.3 glycerin (PEG.PPG.Polybutylene Glycol-8.5.3 Glycerin), methyl glutes- 20 (Methyl Gluceth-20), Glycereth-26 (Glycereth_26), Hexylene Glycol, Diglycerin / Methyl Gluces-10 / PEG150 / PPG30 / Eryoxy Diglycol / Glyceres-12 / Diethoxydi Glycol (Diglycerine / methyl g 1 ucet h-10 / PEG150 / PPG30 / Et hoxy

At least one selected from the group consisting of Diglycol / Glycereth-12 / Diethoxydiglycol, Glycerine, Butylene Glycol, Propylene Glycol, PEG-400 and Dipropyleneglycol In particular, it is preferable to use glycerin -26.

The content of the silicone-based surfactant and the polyol used in the present invention may be 12 to 50 weight ¾ '' based on the total weight of the composition.

Specifically, the content of the silicone surfactant used in the present invention is 2 to 30% by weight based on the total weight of the composition, preferably 10 to 30% by weight. This is to maximize the makeup efficacy and usability of the cleaning composition and to balance the component content with other components.

In addition, the content of the polyol used in the present invention, based on the total weight of the composition

It may be 10 to 28% by weight. The added polyol, together with the silicone-based surfactant, serves to increase the make-up removal force.

Meanwhile, the composition of the present invention may further contain a fatty acid salt for a refreshing feeling. The fatty acid salt may include laurate, myristic acid salt or a mixture thereof. Generally, a soap component having a carboxyl group or a surfactant is used for the detergent used to give a refreshing feeling. This is because soap components or surfactants with a carboxyl group create a feeling of crispness by generating divalent ions and soap-soap in water when washing the face.

<3i> The fatty acid salt is contained in an amount of 5 to 40% by weight based on the total weight of the composition.

This is because fatty acids are suitable for increasing freshness and formulating when used in amounts in the above ranges.

In addition, the present invention provides a makeup detergent composition comprising a silicone-based surfactant and a surfactant having a foam forming ability.

The silicone-based surfactant included in the composition of the present invention is a compound having high hydrophilicity by adding polyethylene glycol (PEG) to both ends of the silicone, and particularly, a bis-pG-18 having excellent cleansing and bubble retention. Preference is given to using dimethyl ether dimethicone (Bis-PEG-18 dimethyl ether dimethicone).

In addition, the foam-forming surfactant contained in the composition of the present invention Fatty acid soap, sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, lauryl glucose carboxylate, potassium glycinate, lauryl glucoside, decyl glucoside, coco glucoside, cocamidoprofil It may be a surfactant capable of foaming in anionic, nonionic or amphoteric ions such as betaine and cocamidopropyl hydroxy sultaine.

Particularly, the composition of the present invention preferably uses fatty acid soap for fresh face wash, which refers to fatty acid salts produced by the neutralization reaction of fatty acids and alkali chemicals. More specifically, saturated fatty acids having 12 to 22 carbon atoms, which form fatty acid soaps from fatty acids, may be used. Specific examples thereof include lauric acid, mystic acid, palmitic acid, stearic acid and behenic. There is an acid.

The content of the silicone surfactant used in the present invention is 5 to 30% by weight based on the total weight of the composition. It is less than 5% by weight make-up removal power is lower, more than 30% by weight is difficult to formulate, it may cause eye irritation, so the content was limited as described above.

In addition, the content of the foam-forming surfactant used in the present invention is 5 to 30% by weight based on the total weight of the composition. If the content is less than 5% by weight, the detergency is poor, and if the content exceeds 30% by weight ¾> it is not preferable because it can cause eye irritation when entering the eye and it is difficult to make a bubble product with a high viscosity.

In addition, the composition of the present invention may further contain at least one polyol selected from the group consisting of glycerin, butylene glycol and propylene glycol to help bubble retention. This not only increases the makeup removal power additionally, but also drains the bubbles.

Helps maintain foaming by preventing drainage.

The content of the polyol is 5 to 20% by weight based on the total weight of the composition. At less than 5% by weight, the effect is insignificant, and at more than 20% by weight, since the foam formation decreases due to the increase in viscosity, the content is limited as described above.

In one embodiment of the present invention, at least one surfactant having a foaming ability, based on the total weight of the composition 5 to 30% by weight, 5 to 30% by weight of a bis-P-E-18 dimethyl ether dimethicone, 5 to polyol It provides a bubble foam type detergent composition consisting of 20% by weight and 20 to 85% by weight of purified water.

<41> The cleaning composition of the present invention is preferably a bubble article type that is discharged in the form of bubbles through a forming container (bubble article container).

[Form for implementation of invention] Hereinafter, the configuration and effects of the present invention will be described in more detail with reference to test examples and examples. However, these test examples and examples are provided only for the purpose of illustration to help the understanding of the present invention, but the scope and scope of the present invention is not limited by the following examples.

<43>

Test Example 1 Surfactant and Polyol Selection Experiment

Since most makeup products contain a large amount of oily raw materials such as silicone oil, the silicone-based surfactants were considered in consideration of the selection of the surfactant.

The silicone surfactant was selected from 11 raw materials of SILTECH in consideration of compatibility with water and oil as shown in Table 1 below, and a makeup removal test was performed.

<47> [Table 1]

<48>

<49> Makeup removal test is to apply a certain amount of lipstick to the bioskin

After drying for 1 hour and 30 minutes in the hood, it was confirmed by removing the raw material. The results are shown in FIG.

1, it can be seen that samples 2, 5, 6, 8, and 9 remove the lipstick most effectively. However, sample 9 was insoluble in the water phase and was excluded from this experiment.

<51>

Next, the following ten polyols were selected to test makeup removal ability of the polyol.

<53> [Table 2]

<54>

The test method is the same as the method used for the silicon-based surfactant, the results are shown in FIG.

Test results confirmed that the most clear of glycerin -26 (M- Hydro EG) and methyl gluses -20 (GLUCAM E-20).

<57>

[Test Example 2] Prescription Experiment 1

According to the result of Test Example 1, dimethicone PEG- in silicon-based surfactant

8 succinate (Silube CS-1), PEG7-dimethicone isostearate (Silwax WD-IS), organic modified trimethylammonium chloride polydimethylsiloxane (Silquat 3180), and silicon quaternium-20 (Silplex J2-S) After selecting the poly glycerol -26 (M-Hydro EG) in the polyol as shown in Table 3 to fix the glycerin -26 and formulated according to the type of silicone surfactant to prepare a cleaning composition (unit: weight%) .

<60> [Table 3]

<61>

<62> <Manufacturing method>

<63> Add water and glycerin, add fatty acids (lauric acid, myristic acid), and add 65

After melting to warm to ° C and neutralized with TEA for 30 minutes, the silicone-based surfactant and poly, fragrance, preservatives, etc. were prepared at around 40 ^° C.

<64>

The makeup removal effect was observed in the same manner as in the method used in Test Example 1 prepared detergent composition, the results are shown in Figures 3-4.

3 to 4, when the polyol was fixed with glycerin -26 (M-Hydro EG), it was used when it was used with PEG7-dimethicone isostearate (Silwax WD-IS) in a silicone-based surfactant. You can see that the removal effect is the best.

<67>

Test Example 3 Prescription Experiment 2

As shown in Table 4, poly was fixed to methyl glueses 20 (GLUCAM E-20) and prepared by formulating a cleaning composition according to the type of silicone surfactant (unit: weight «.

<70> [Table 4]

<71>

The cleaning composition of Table 4 was prepared in the same manner as in Test Example 3, and the make-up removal effect was observed in the same manner as the method used in Test Example 1, and the results thereof are shown in FIG. It was.

Referring to FIG. 5, when the poly was fixed with methyl glueses-20 (GLUCAM E-20), the make-up was removed when used with PEG7-dimethicone isostearate (Silwax WD-IS) in a silicone-based surfactant. You can see the effect is the best.

<74>

[Experiment 4] Prescription Experiment 3

<76> PEG7-dimethicone isostearate as a silicone-based surfactant as shown in Table 5 below

(Silwax WD-IS) and poly-glycerin-26 (M-Hydro EG) were prepared by prescribing the cleaning composition in different amounts (unit: weight%).

<77> [Table 5]

Example Work Example 9 Example 10 Examination Example 11 Example 12 Water 12.43 43.2 43.2 43.2 Interest Rate Serine 10 10 10 10 Oily Lauric Acid 3 3 3 3 Myristic Acid 7 7 7 7 Neutralization TEA 6.8 6.8 6.8 6.8

Sili silwax WD-IS 2 5 10 30 Nose SilplexJ2-S

Interface

Active si lube CS-1

Article Silauat 3180

Poly GLUCAM E-20

O-Hydro EG 28 25 20 0 Incense, appropriate amount, ¾ amount, Preservative phenoxyethanol amount, appropriate amount

워 명 심 심 13 시 14 심 15 시 16 수상 16 63.2 43.2 71.2 53.2 interest rate 10 10 10 10 paid lauric acid 3 3 3 3 myristic acid 7 7 7 7 neutralization TEA 6.8 6.8 6.8 6.8 Article

Silly silwax WD-IS 0 0 2 20 nose SilplexJ2-S

Interface

Active si lube CS-1

Article Silauat 3180

Poly GLUCAM E-20

Required M-Hydro EG 10 30 0 0 The cleaning composition of Table 5 was prepared in the same manner as in Test Example 3, and the make-up removal effect was observed in the same manner as the method used in Test Example 1, and the results are shown in FIG.

Looking at Figure 6, the PEG7-dimethicone isostearate (Silwax WD-IS) was confirmed that the more effective than the Comparative Example 1 as the amount of use increases. However, when the amount of PEG7-dimethicone isostearate (Silwax TO-IS) exceeded 30% by weight, the effect was not increased further.

Test Example 5 Friction Test

In order to measure the fresh cleansing feeling, a friction test was performed using a friction tester (KATO Tech. Co., Ltd.), and the friction test was performed on Comparative Examples 1 and 1 above. In order to compare with the state before washing, hand cream was applied and friction force was measured. The results are shown in FIG.

Specific test methods are as follows.

1) Zero the friction tester (0SC: 10, BAL: 0, MES: 0).

2) Adjust the speed to lmm / sec.

3) Cut the bioskin into 25 圓 X 170 瞧 and install it.

4) Press RES, MIU, MMD to check the zero point.

5) Place the weight on the bioskin so that the measurement panel is level.

6) Press MES start to measure and then measure the frictional force by reading the MIU value. As a result, the cleaning composition according to the present invention was able to confirm a skin friction force similar to that of Comparative Example 1, which is a general cleaning agent containing no silicone-based surfactant.

[Example 17-19 and Comparative Example 2-3]

To the compositions of Table 6 to Examples 17-19 and Comparative Example 2-3 were prepared. Comparative Example 2 is a general bubble cleansing product composition, Comparative Example 3 is a bubble cleansing product composition containing a PHYG-7 dimethicone isostearate, Examples 17 to 19 are bis-PG-18 dimethyl of the present invention Bubble cleansing foam composition containing ether dimethicone. Also, compare Examples 2 to 3 and Example 17 are 20% by weight of the content of fatty acid soap relative to the total weight of the composition, Examples 18-19 reduce the fatty acid soap content to 10% by weight of half, instead to improve the foaming force Cocamidopropyl hydroxy sulfane or polyloglycerin, butyleneglycol was used as a co-surfactant (unit: weight%).

Table 6

<98>

<99> <Manufacturing Method of Comparative Example 2>

First, the chelating agent was added to purified water, and fatty acid, polyol, and the like were added thereto, followed by heating and dissolving ^at about 70 ^° C., neutralization by addition of alkali, followed by mixing and cooling with flavor and preservative. .

<101>

<102> <Comparative Example 3 and Manufacturing Method of Examples 17 to 19>

First, the chelating agent is added to purified water, and then, polyol and fatty acid are added thereto, heated and dissolved at about 70 ^° C., neutralized by addition of alkali, and then bis-pizzy-18 dimethyl ether dimethicone or fiji. -7 dimethicone isostearate was added and dissolved. Subsequently, additives such as fragrance and preservatives were added to the mixture, followed by cooling.

<104>

[Test Example 6] Bubble Test

<106> Part Tester (foam tester, SITA foam tester) to compare the product forming ability

R-2000). After diluting the sample with distilled water to make an aqueous solution of 0.5%, the volume of foam generated by stirring the 250m £ solution for 10 times was measured. Stirring speed was maintained at 800 rpm for 10 seconds. The measurement was repeated three times to obtain an average value. The results are shown in FIG.

As can be seen from the results of FIG. 8, Example 17 containing bis-pG-18 dimethyl ether dimethicone was similarly high as that of Comparative Example 2, which has a general foaming force. On the other hand, Comparative Example 3 containing a sebum-7 dimethicone isostearate has a lower foaming force than Examples 17-19, and when applied to a bubble article because the viscosity is high, bubbles are not easily formed and it is easily broken off. It was found that the foam was not discharged well but quickly disappeared. In addition, Example 18 reduces the content of fatty acid soap in half than that of Example 17, and instead improves the foaming force using the amphoteric surfactant cocamidopropyl hydroxy sulphate and polyolol to improve the foaming force similar to that of Example 17 Could get In Example 19, the fatty acid soap was contained in an amount of 10% by weight based on the total weight of the composition, and the polyol mixture of glycerin and butylene glycol was further included in the same manner as in Example 18 to improve foaming power. Than foam was lower.

<108>

[Test Example 7] Makeup Removal Test

<ιιο> Make-up removal test is applied to a certain amount of lipstick on bioskin (bioskin, beau lax), dried for 5 minutes, the surface is completely hardened, and then put into a forming container (Comparative Examples 2 to 3 and Example 17 ~ 19) were pumped 3 times each and rubbed 20 times with a stop and then rinsed with water to compare the cleansing force. The results are shown in FIG.

<ιιι> As can be seen from the result of FIG. 9, the Example is compared with the general bubble product of Comparative Example 2

Lipstick removal was significantly better in 17-19. Particularly, in Example 18 and Example 19, although the content of fatty acid soap is lower than that of Example 17, it further contains an auxiliary surfactant and a polyol, thereby providing excellent foaming and cleansing power, and simultaneously removing makeup and washing the face. The effect was excellent as a possible bubble product.

Claims

[Range of request]

[Claim 11

Makeup detergent composition comprising a silicone-based surfactant and a polyol.

[Claim 2]

The method of claim 1, wherein the silicone-based surfactant is dimethicone PEG-8 laurate, Dimethicone PEG-8 succinate, PEG-12 dimethicone (PEG-12 Dimethicone, PEG-10 Dimethicone, PEG7-Dimethicone Isostearate, Organomodified trimethyl ammonium chloride polydimethylsi 1 ixane, Silicon Quaternium 1 8 (Si 1 icone quaternium-8), Si Π cone quaternium-20, Isopropyl phenyl Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone (Cetyl PEG / At least one makeup cleaner composition selected from the group consisting of PPG-10 / 1 Dimethicone) and Lauryl PEG-8 Dimethicone.

[Claim 3]

The method of claim 1, wherein the polyol is PEG.PPG.Polybutylene glycol -8.5.3 Glycerin (PEG.PPG.Polybutylene Glycol-8.5.3 Glycerin), Methyl Gluceth-20, Glyceres -26 (GIycereth-26), Hexylene Glycol, Diglycerin / Methyl Glycols -10 / PEG150 / PPG30 / Eryoxy Diglycol / Glyceres-12 / Diglycerine / Methyl Glycol-10 / PEG150 / PPG30 / Ethoxy Diglycol / Glycereth-12 / Diethoxydiglycol), Glycerine, Butylene Glycol, Propylene Glycol, PEG— 400 and Dipropyleneglycol Makeup cleaner composition is one or more selected from.

[Claim 4]

The makeup detergent composition according to claim 1, wherein the silicone surfactant is dimethicone -7 isostearate and poly is glycerin -26.

[Claim 5]

The method of claim 1, wherein the silicone-based surfactant is contained in an amount of 2 to 30% by weight based on the total weight of the composition, the polyol is contained in an amount of 10 to 28%> based on the total weight of the composition, the surfactant And a sum of the polyol content is 12 to 50% by weight based on the total weight of the composition.

[Claim 6]

The makeup cleaner composition of claim 1, wherein the cleaning composition further contains a fatty acid salt.

[Claim 7]

The makeup detergent composition of claim 6, wherein the fatty acid salt is laurate, myristic acid salt, or a mixture thereof.

[Claim 8]

A makeup detergent composition comprising a silicone-based surfactant having increased hydrophilicity by adding PEG to both ends of the silicone and a surfactant having foam forming ability.

[Claim 9]

The method of claim 8, wherein the silicone-based surfactant to increase the hydrophilicity by adding PEG to both ends of the silicone is bis-PG-18 dimethyl ether dimethicone (Bis-PEG-18 dimethyl ether dimethicone) Detergent composition.

[Claim 10]

The makeup detergent composition according to claim 8, wherein the silicone-based surfactant having increased hydrophilicity by adding PEG to both ends of the silicone is contained in an amount of 5 to 30% by weight based on the total weight of the composition.

[Claim 11]

The method of claim 8, wherein the surfactant is a fatty acid soap, sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, lauryl glucose carboxylate, potassium glycinate, lauryl glucoside, decyl Glucoside, coco glucoside, cocamidopropyl betaine and cocamidopropyl hydroxy sultaine make-up cleaning composition, characterized in that at least one member selected from the group consisting of.

[Claim 12]

The makeup cleaner composition according to claim 11, wherein the fatty acid soap is at least one selected from the group consisting of lauric acid, myractic acid, palmitic acid, stearic acid and behenic acid.

[Claim 13]

The makeup detergent composition according to claim 8, wherein the surfactant is contained in an amount of 5 to 30% by weight based on the total weight of the composition.

[Claim 14] The makeup cleaner composition according to claim 8, wherein the composition further contains at least one polyol selected from the group consisting of glycerin, butylene glycol and propylene glycol.

[Claim 15]

15. The makeup cleaner composition of claim 14, wherein the polyol is contained in an amount of 5 to 20 weight ¾> based on the total weight of the composition.

[Claim 16]

The makeup cleaner composition according to any one of claims 8 to 15, wherein the composition is a bubble article type.

[Claim 17]

The makeup cleaner composition according to any one of claims 1 to 16, wherein the composition removes makeup and washes at the same time.