WO2012009391A3 - Improved method of removing hydrogen sulfide - Google Patents

Improved method of removing hydrogen sulfide Download PDF

Info

Publication number
WO2012009391A3
WO2012009391A3 PCT/US2011/043780 US2011043780W WO2012009391A3 WO 2012009391 A3 WO2012009391 A3 WO 2012009391A3 US 2011043780 W US2011043780 W US 2011043780W WO 2012009391 A3 WO2012009391 A3 WO 2012009391A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen sulfide
removing hydrogen
improved method
nitroxide
sulfide
Prior art date
Application number
PCT/US2011/043780
Other languages
French (fr)
Other versions
WO2012009391A2 (en
Inventor
Dennis R. Compton
J. Byron Strickland
Original Assignee
Nalco Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Company filed Critical Nalco Company
Priority to CN2011800347098A priority Critical patent/CN103003395A/en
Priority to KR1020137003668A priority patent/KR20130047738A/en
Priority to RU2013102415/04A priority patent/RU2562610C2/en
Priority to SG2013003025A priority patent/SG187080A1/en
Priority to CA2805402A priority patent/CA2805402C/en
Priority to JP2013519782A priority patent/JP5815699B2/en
Priority to EP11807421.0A priority patent/EP2593534A4/en
Priority to MX2013000511A priority patent/MX2013000511A/en
Priority to BR112013000887A priority patent/BR112013000887A2/en
Publication of WO2012009391A2 publication Critical patent/WO2012009391A2/en
Publication of WO2012009391A3 publication Critical patent/WO2012009391A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/152—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention provides a method of removing hydrogen sulfide from hydrocarbon fluids. The method involves using a nitroxide molecule to promote a sulfide scavenger such as alkyl-triazine. The nitroxide effectively accelerates the scavengers activity. This allows for the avoidance of the introduction of halides into the hydrocarbon stream.
PCT/US2011/043780 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide WO2012009391A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CN2011800347098A CN103003395A (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide
KR1020137003668A KR20130047738A (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide
RU2013102415/04A RU2562610C2 (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulphide
SG2013003025A SG187080A1 (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide
CA2805402A CA2805402C (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide
JP2013519782A JP5815699B2 (en) 2010-07-14 2011-07-13 Improved method for removing hydrogen sulfide
EP11807421.0A EP2593534A4 (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide
MX2013000511A MX2013000511A (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide.
BR112013000887A BR112013000887A2 (en) 2010-07-14 2011-07-13 method for reducing the amount of hydrogen sulfide in a hydrocarbon fluid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/835,805 US20120012506A1 (en) 2010-07-14 2010-07-14 Method of removing hydrogen sulfide
US12/835,805 2010-07-14

Publications (2)

Publication Number Publication Date
WO2012009391A2 WO2012009391A2 (en) 2012-01-19
WO2012009391A3 true WO2012009391A3 (en) 2012-05-10

Family

ID=45466087

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/043780 WO2012009391A2 (en) 2010-07-14 2011-07-13 Improved method of removing hydrogen sulfide

Country Status (12)

Country Link
US (1) US20120012506A1 (en)
EP (1) EP2593534A4 (en)
JP (1) JP5815699B2 (en)
KR (1) KR20130047738A (en)
CN (1) CN103003395A (en)
AR (1) AR082847A1 (en)
BR (1) BR112013000887A2 (en)
CA (1) CA2805402C (en)
MX (1) MX2013000511A (en)
RU (1) RU2562610C2 (en)
SG (1) SG187080A1 (en)
WO (1) WO2012009391A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9663390B2 (en) 2013-05-10 2017-05-30 Ecolab Usa Inc. Reduction of hydrogen sulfide and/or malodor gassing from water via the addition of peroxyacetic acid/hydrogen peroxide product
CN105056710B (en) * 2015-08-21 2017-05-24 胜利油田胜利化工有限责任公司 Liquid absorbent for removing hydrogen sulfide in oil gas
CN107502329B (en) * 2016-06-14 2020-07-10 中国石油大学(华东) Eliminating agent for eliminating associated hydrogen sulfide gas in heavy oil thermal recovery
WO2018003623A1 (en) * 2016-06-28 2018-01-04 株式会社クラレ Composition for removing sulfur-containing compound
CA3046068A1 (en) * 2016-12-08 2018-06-14 Ecolab Usa Inc. Hydrogen sulfide scavengers for polymer treated asphalt
WO2024091459A1 (en) * 2022-10-24 2024-05-02 Cameron International Corporation Sulfonyl azide composition for sulfur scavenging in oilfield operations

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5128049A (en) * 1991-01-22 1992-07-07 Gatlin Larry W Hydrogen sulfide removal process
US5922794A (en) * 1997-03-26 1999-07-13 General Electric Company Compositions stabilized with tertiary amine oxides
US20040216370A1 (en) * 2003-03-31 2004-11-04 Gande Matthew E. Diesel fuel composition and a method to improve filterability of diesel fuel
US20050238556A1 (en) * 2004-04-21 2005-10-27 Pakulski Marek K Method of scavenging hydrogen sulfide and/or mercaptans from fluid and gas streams
WO2010150107A1 (en) * 2009-06-26 2010-12-29 M-I Swaco Norge As Scavenger compositions and their use

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2080909C1 (en) * 1988-12-23 1997-06-10 Петролите Холдингз, Инк. Method of selectively reducing hydrogen sulfide and/or organic sulfide content in gaseous and/or liquid streams
US5354453A (en) * 1993-04-13 1994-10-11 Exxon Chemical Patents Inc. Removal of H2 S hydrocarbon liquid
US5980733A (en) * 1994-04-15 1999-11-09 United Laboratories International Method of removing sulfur compounds from hydrocarbon streams
CA2148849A1 (en) * 1994-06-23 1995-12-24 Kishan Bhatia Method of treating sour gas and liquid hydrocarbons
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
EP1065262A1 (en) * 1999-06-29 2001-01-03 The Procter & Gamble Company Bleaching compositions
EP2288677A2 (en) * 2008-04-18 2011-03-02 M-i Swaco Norge As Methods of predicting / optimizing hydrogen sulfide scavenging capacity and reduction of scale formation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5128049A (en) * 1991-01-22 1992-07-07 Gatlin Larry W Hydrogen sulfide removal process
US5922794A (en) * 1997-03-26 1999-07-13 General Electric Company Compositions stabilized with tertiary amine oxides
US20040216370A1 (en) * 2003-03-31 2004-11-04 Gande Matthew E. Diesel fuel composition and a method to improve filterability of diesel fuel
US20050238556A1 (en) * 2004-04-21 2005-10-27 Pakulski Marek K Method of scavenging hydrogen sulfide and/or mercaptans from fluid and gas streams
WO2010150107A1 (en) * 2009-06-26 2010-12-29 M-I Swaco Norge As Scavenger compositions and their use

Also Published As

Publication number Publication date
RU2013102415A (en) 2014-08-20
AR082847A1 (en) 2013-01-16
BR112013000887A2 (en) 2016-05-17
EP2593534A4 (en) 2014-04-23
CN103003395A (en) 2013-03-27
US20120012506A1 (en) 2012-01-19
SG187080A1 (en) 2013-03-28
MX2013000511A (en) 2013-02-27
JP5815699B2 (en) 2015-11-17
EP2593534A2 (en) 2013-05-22
WO2012009391A2 (en) 2012-01-19
JP2013532735A (en) 2013-08-19
CA2805402C (en) 2018-03-13
KR20130047738A (en) 2013-05-08
CA2805402A1 (en) 2012-01-19
RU2562610C2 (en) 2015-09-10

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