WO2012009396A3 - Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons - Google Patents

Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons Download PDF

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Publication number
WO2012009396A3
WO2012009396A3 PCT/US2011/043793 US2011043793W WO2012009396A3 WO 2012009396 A3 WO2012009396 A3 WO 2012009396A3 US 2011043793 W US2011043793 W US 2011043793W WO 2012009396 A3 WO2012009396 A3 WO 2012009396A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen sulfide
alpha
hydrocarbons
removal
amino ethers
Prior art date
Application number
PCT/US2011/043793
Other languages
French (fr)
Other versions
WO2012009396A2 (en
Inventor
Dennis R. Compton
Byron J. Strickland
Juan M. Garcia, Iii
Original Assignee
Nalco Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Company filed Critical Nalco Company
Priority to BR112013000890A priority Critical patent/BR112013000890A2/en
Priority to JP2013519783A priority patent/JP5890409B2/en
Priority to RU2013102414/04A priority patent/RU2563633C2/en
Priority to SG2013002993A priority patent/SG187078A1/en
Priority to EP20110807425 priority patent/EP2593535A4/en
Priority to CA2805404A priority patent/CA2805404C/en
Priority to KR1020137003671A priority patent/KR20130047739A/en
Priority to CN201180034667.8A priority patent/CN103403129B/en
Priority to MX2013000507A priority patent/MX2013000507A/en
Publication of WO2012009396A2 publication Critical patent/WO2012009396A2/en
Publication of WO2012009396A3 publication Critical patent/WO2012009396A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/152—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Gas Separation By Absorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention provides a method of removing hydrogen sulfide from hydrocarbon fluids. The method involves using an alpha-amino ether as a hydrogen sulfide scavenger. This allows for the introduction of an oil soluble scavenger in lieu of water-soluble scavengers.
PCT/US2011/043793 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons WO2012009396A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
BR112013000890A BR112013000890A2 (en) 2010-07-14 2011-07-13 method for reducing the amount of hydrogen sulfide in a hydrocarbon fluid
JP2013519783A JP5890409B2 (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers to remove hydrogen sulfide from hydrocarbons
RU2013102414/04A RU2563633C2 (en) 2010-07-14 2011-07-13 Application of alpha-aminoethers for removal of hydrogen sulphide from hydrocarbons
SG2013002993A SG187078A1 (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons
EP20110807425 EP2593535A4 (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons
CA2805404A CA2805404C (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons
KR1020137003671A KR20130047739A (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons
CN201180034667.8A CN103403129B (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons
MX2013000507A MX2013000507A (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/836,037 2010-07-14
US12/836,037 US20120012507A1 (en) 2010-07-14 2010-07-14 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons

Publications (2)

Publication Number Publication Date
WO2012009396A2 WO2012009396A2 (en) 2012-01-19
WO2012009396A3 true WO2012009396A3 (en) 2012-05-18

Family

ID=45466088

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/043793 WO2012009396A2 (en) 2010-07-14 2011-07-13 Use of alpha-amino ethers for the removal of hydrogen sulfide from hydrocarbons

Country Status (12)

Country Link
US (1) US20120012507A1 (en)
EP (1) EP2593535A4 (en)
JP (1) JP5890409B2 (en)
KR (1) KR20130047739A (en)
CN (1) CN103403129B (en)
AR (1) AR082165A1 (en)
BR (1) BR112013000890A2 (en)
CA (1) CA2805404C (en)
MX (1) MX2013000507A (en)
RU (1) RU2563633C2 (en)
SG (1) SG187078A1 (en)
WO (1) WO2012009396A2 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8663457B2 (en) * 2011-11-23 2014-03-04 General Electric Company Methods and compounds for improving sulfide scavenging activity
US9108899B2 (en) 2011-12-30 2015-08-18 General Electric Company Sulfide scavengers, methods for making and methods for using
US9278307B2 (en) 2012-05-29 2016-03-08 Baker Hughes Incorporated Synergistic H2 S scavengers
EP2935770B1 (en) 2012-12-19 2020-04-08 Nalco Company Squeeze treatment for in situ scavenging of hydrogen sulfide
WO2014100052A1 (en) * 2012-12-19 2014-06-26 Nalco Company Scavenging hydrogen sulfide
US9630139B2 (en) * 2012-12-19 2017-04-25 Ecolab Usa Inc. Functionalized hydrogen sulfide scavengers
EP2951149B1 (en) 2013-01-30 2018-10-10 Ecolab USA Inc. Hydrogen sulfide scavengers
US9663390B2 (en) 2013-05-10 2017-05-30 Ecolab Usa Inc. Reduction of hydrogen sulfide and/or malodor gassing from water via the addition of peroxyacetic acid/hydrogen peroxide product
WO2014210166A1 (en) 2013-06-27 2014-12-31 Ecolab Usa Inc. Epoxide-based hydrogen sulfide scavengers
US9273254B2 (en) 2013-12-20 2016-03-01 Ecolab Usa Inc. Amino acetals and ketals as hydrogen sulfide and mercaptan scavengers
US9458393B2 (en) 2014-04-15 2016-10-04 Ecolab Usa Inc. Hydantoins as hydrogen sulfide and mercaptan scavengers
US10308886B2 (en) 2015-04-22 2019-06-04 Ecolab Usa Inc. Development of a novel high temperature stable scavenger for removal of hydrogen sulfide
US10584286B2 (en) 2015-09-08 2020-03-10 Ecolab Usa Inc. Hydrogen sulfide scavengers
US10513662B2 (en) 2017-02-02 2019-12-24 Baker Hughes, A Ge Company, Llc Functionalized aldehydes as H2S and mercaptan scavengers
EP3623034A4 (en) 2017-05-12 2021-01-13 Kuraray Co., Ltd. Device for removing sulfur-containing compound and method for removing sulfur-containing compound
WO2018218641A1 (en) * 2017-06-02 2018-12-06 General Electric Company Method of mitigation of tramp amines in application of h2s scavengers
WO2019014415A1 (en) 2017-07-13 2019-01-17 Ecolab USA, Inc. Method of removing a sulfur containing compound by adding a composition
CA3127439A1 (en) 2019-01-23 2020-07-30 Championx Usa Inc. Complete removal of solids during hydrogen sulfide scavenging operations using a scavenger and a michael acceptor
US20240110091A1 (en) 2022-09-21 2024-04-04 Championx Usa Inc. Compositions and methods for scavenging sulfur-containing compounds

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057403A (en) * 1973-10-29 1977-11-08 Fluor Corporation Gas treating process
US4556546A (en) * 1983-05-04 1985-12-03 Air Products And Chemicals, Inc. Bis tertiary amino alkyl derivatives as solvents for acid gas removal from gas streams
US4618481A (en) * 1985-08-30 1986-10-21 Exxon Research And Engineering Co. Absorbent composition containing a severely hindered amino compound and an amine salt and process for the absorption of H2 S using the same
US5074991A (en) * 1989-02-13 1991-12-24 Petrolite Corporation Suppression of the evolution of hydrogen sulfide gases

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405582A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using diaminoether solutions
CA2017047C (en) * 1989-08-01 1999-08-17 Jerry J. Weers Method of scavenging hydrogen sulfide from hydrocarbons
CA2148849A1 (en) * 1994-06-23 1995-12-24 Kishan Bhatia Method of treating sour gas and liquid hydrocarbons
NO982505L (en) * 1997-06-04 1998-12-07 Nalco Exxon Energy Chem Lp Composition and process for desulfurization of gaseous or liquid hydrocarbons, aqueous systems and mixtures thereof
CA2445422A1 (en) * 2001-04-25 2002-10-31 Clearwater International, Llc Treatment of hydrocarbons containing sulfides
ES2521624T3 (en) * 2005-08-09 2014-11-13 Exxonmobil Research And Engineering Company Alkylamino alkyloxy (alcohol) monoalkyl ether for acid gas washing process
RU2349627C2 (en) * 2005-10-27 2009-03-20 Ахматфаиль Магсумович Фахриев Hydrogen sulphide and/or low-molecular mercaptan remover and method of using it
US20110155646A1 (en) * 2008-09-02 2011-06-30 Karas Lawrence John Process for removing hydrogen sulfide in crude oil
US9394396B2 (en) * 2011-06-21 2016-07-19 Baker Hughes Incorporated Hydrogen sulfide scavenger for use in hydrocarbons

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057403A (en) * 1973-10-29 1977-11-08 Fluor Corporation Gas treating process
US4556546A (en) * 1983-05-04 1985-12-03 Air Products And Chemicals, Inc. Bis tertiary amino alkyl derivatives as solvents for acid gas removal from gas streams
US4618481A (en) * 1985-08-30 1986-10-21 Exxon Research And Engineering Co. Absorbent composition containing a severely hindered amino compound and an amine salt and process for the absorption of H2 S using the same
US5074991A (en) * 1989-02-13 1991-12-24 Petrolite Corporation Suppression of the evolution of hydrogen sulfide gases
US5074991C1 (en) * 1989-02-13 2001-05-08 Baker Hughes Inc Suppression of the evolution of hydrogen sulfide gases

Also Published As

Publication number Publication date
WO2012009396A2 (en) 2012-01-19
EP2593535A2 (en) 2013-05-22
MX2013000507A (en) 2013-02-27
EP2593535A4 (en) 2014-04-23
CN103403129B (en) 2015-05-20
JP5890409B2 (en) 2016-03-22
RU2563633C2 (en) 2015-09-20
CA2805404A1 (en) 2012-01-19
KR20130047739A (en) 2013-05-08
US20120012507A1 (en) 2012-01-19
CN103403129A (en) 2013-11-20
CA2805404C (en) 2018-11-27
AR082165A1 (en) 2012-11-14
JP2013531728A (en) 2013-08-08
SG187078A1 (en) 2013-02-28
BR112013000890A2 (en) 2016-05-17
RU2013102414A (en) 2014-08-20

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