WO2012005055A1 - Waste plastic pyrolizing apparatus - Google Patents

Waste plastic pyrolizing apparatus Download PDF

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Publication number
WO2012005055A1
WO2012005055A1 PCT/JP2011/061165 JP2011061165W WO2012005055A1 WO 2012005055 A1 WO2012005055 A1 WO 2012005055A1 JP 2011061165 W JP2011061165 W JP 2011061165W WO 2012005055 A1 WO2012005055 A1 WO 2012005055A1
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WO
WIPO (PCT)
Prior art keywords
tank
thermal decomposition
waste plastic
pyrolysis
superheated steam
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PCT/JP2011/061165
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French (fr)
Japanese (ja)
Inventor
中塚 廣重
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株式会社オールマイティー
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Publication of WO2012005055A1 publication Critical patent/WO2012005055A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2385/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon; Derivatives of such polymers
    • C08J2385/02Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon; Derivatives of such polymers containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics

Definitions

  • the present invention relates to a thermal decomposition treatment apparatus for waste plastic.
  • waste plastic is put into a thermal decomposition tank provided in the thermal decomposition processing equipment, and the thermal decomposition tank is heated and decomposed to heat pyrolysis gas by heating the thermal decomposition tank from the outside.
  • the oil is obtained by cooling the generated pyrolysis gas.
  • waste plastics subjected to such oily treatment those that are discharged mainly from medical institutions and classified as so-called infectious medical wastes need to be sterilized prior to thermal decomposition treatment. Waste plastic classified as infectious medical waste is sterilized by a sterilization apparatus, then transferred from the sterilization apparatus to a thermal decomposition tank, and thermally decomposed in a thermal decomposition layer (see, for example, Patent Document 1).
  • the waste plastic Since the capacity of the pyrolysis tank is not sufficient in the oiling treatment as described above, the waste plastic is put into the pyrolysis tank so that as much waste plastic sterilized by the sterilizer can be put into the pyrolysis tank as much as possible. It is necessary to crush with a crushing device before transferring and then reduce the volume. In addition, when crushing waste plastic, if the metal is mixed in the waste plastic, the crushing device may be clogged and the operation may stop or break down. Therefore, it is necessary to separate and remove the metal from the waste plastic in advance. was there. Thus, in the conventional pyrolysis processing apparatus, it is necessary to perform pretreatment such as metal separation, crushing, and volume reduction on the waste plastic to be processed, so that the processing time of the entire oil conversion processing is increased. There was a problem.
  • an object of the present invention is to provide a thermal decomposition treatment apparatus that can shorten the treatment time.
  • a thermal decomposition treatment apparatus is made to solve the above-described problem, and is a thermal decomposition treatment apparatus for thermally decomposing waste plastic, which includes a thermal decomposition tank that accommodates waste plastic, Provided in the pyrolysis tank, heating means for heating the waste plastic in the pyrolysis tank, control means for controlling the heating amount of the heating means to adjust the temperature in the pyrolysis tank, It has.
  • the heating means is provided in the thermal decomposition tank, so that the heating means is provided in the thermal decomposition tank more than the conventional thermal decomposition apparatus in which the heating means is provided outside the thermal decomposition tank. Since the rate of temperature rise is increased, the capacity of the pyrolysis tank can be expanded without extending the heating time as compared with the conventional pyrolysis apparatus. For this reason, a large amount of waste plastic can be put into the pyrolysis tank in its original form, and the sterilization process and pyrolysis process of the waste plastic can be continuously performed in the pyrolysis tank.
  • the thermal decomposition treatment apparatus can eliminate the waste plastic pretreatment process such as metal separation, crushing, and volume reduction, and the waste plastic transfer process from the sterilization treatment apparatus to the thermal decomposition treatment apparatus. Therefore, the processing time can be shortened and the cost can be reduced.
  • the heating means is preferably a superheated steam supply pipe that is heated by energization.
  • This superheated steam supply pipe changes the saturated steam supplied to the inside by being heated to superheated steam, and discharges this superheated steam into the thermal decomposition tank.
  • the inside of the thermal decomposition tank can be more efficiently heated by the heat of the superheated steam and the superheated steam supply pipe itself.
  • the thermal decomposition treatment apparatus can be used as a dry heat sterilization apparatus only by energizing the superheated steam supply pipe.
  • the said thermal decomposition processing apparatus may be equipped with the cooler for cooling superheated steam in the outer side of the said thermal decomposition tank.
  • This cooler can cool and condense excess superheated steam discharged from the pyrolysis tank and return it to the pyrolysis tank. According to this structure, it can prevent that the inside of a thermal decomposition tank becomes a high voltage
  • the pyrolysis apparatus may include a stirrer whose rotating shaft extends parallel to the inner bottom surface of the pyrolysis tank.
  • the agitator is configured to be able to transport waste plastic toward the waste plastic discharge port formed in the thermal decomposition tank. According to this configuration, the waste plastic after pyrolysis in the pyrolysis tank can be efficiently discharged out of the pyrolysis tank.
  • control means has heating means so that the temperature in the thermal decomposition tank becomes a first temperature for sterilizing the waste plastic and a second temperature for oiling the waste plastic. The amount of heating can be controlled.
  • the control means may further control the heating amount of the heating means so that the temperature in the pyrolysis tank becomes a third temperature for carbonizing organic matter such as waste plastic and wood chips / paper waste.
  • the processing time can be shortened.
  • FIG. 1 is an overall schematic diagram of a waste plastic oil processing system according to the present embodiment.
  • the thermal decomposition treatment apparatus 1 cools and condenses the thermal decomposition tank 2, the superheated steam supply pipe 3 for introducing the superheated steam into the thermal decomposition tank 2, and the superheated steam.
  • a cooler 4 (cooling means) is provided.
  • the pyrolysis tank 2 has a substantially rectangular parallelepiped shape and is hollow so that waste plastic can be accommodated therein. As shown in FIG. 2, on the upper surface of the thermal decomposition tank 2, there is provided a lid portion 21 that can be opened and closed for charging waste plastic, and a discharge pipe 23 for discharging thermal decomposition gas generated from the waste plastic. An electric damper 24 for adjusting the flow rate of the pyrolysis gas is attached to the discharge pipe 23. Further, a safety valve 25 and a cooling shower supply port 26 for supplying a shower of cooling water into the pyrolysis tank 2 are provided on the upper surface of the pyrolysis tank 2. As shown in FIGS.
  • the left side surface of the pyrolysis tank 2 has two door portions 27 (discharge ports) that can be opened and closed in order to take out so-called residues that are carbides generated after the pyrolysis treatment. Further, a nitrogen gas inlet 28 for injecting cooling nitrogen gas into the pyrolysis tank 2 is formed. A blower 6 for cooling the pyrolysis tank 2 is installed below the pyrolysis tank 2 as shown in FIG.
  • the pyrolysis tank 2 is provided with two agitators 5 for agitating the waste plastic during the pyrolysis treatment.
  • the stirrer 5 has a rotating shaft 51 extending in parallel to the bottom surface of the pyrolysis tank 2, and the rotating shaft 51 is provided with a plurality of blades 53 around it and can be rotated in both directions by a motor 52. ing.
  • the stirrer 5 stirs the waste plastic in the pyrolysis tank 2 when the rotary shaft 51 rotates in one direction by the motor 52, and the waste plastic in the pyrolysis tank 2 when the rotary shaft 51 rotates in the reverse direction. It is configured to carry toward the side.
  • the pressure gauge 7 for measuring the pressure in the pyrolysis tank 2 and the heat in the pyrolysis tank 2 are made not to escape.
  • a heat insulating material 8 is provided.
  • the superheated steam supply pipe 3 is provided in the pyrolysis tank 2, and is disposed so as to be folded up and down on the front and rear side wall surfaces in the pyrolysis tank 2. .
  • the superheated steam supply pipe 3 is configured as a so-called heater pipe that is heated to a maximum of 900 ° C. by energization, and changes saturated steam sent from an electric once-through boiler 300 described later and passing through the inside into 200 to 750 ° C. superheated steam.
  • the heating amount of the superheated steam supply pipe 3 is automatically controlled by an operation panel 9 (control means) with a built-in sequencer.
  • the material for the superheated steam supply pipe 3 one having corrosion resistance at high temperatures is preferable, and for example, a nickel chromium alloy can be used.
  • the nickel-chromium alloy is not particularly limited, but preferably contains 58 to 63% nickel and 21 to 25% chromium, for example, Inconel (registered trademark) 601.
  • the size of the superheated steam supply pipe 3 is not particularly limited, but the outer diameter is 26.7 mm, the inner diameter is 21.3 mm, and the length is 15 to It is preferable that it is 18m, for example, is piping size 15A.
  • the cooler 4 includes a cooling pipe 42 that is a double pipe, and the cooling pipe 42 has a water supply port for supplying cooling water between the inner pipe and the outer pipe. 421 and a water discharge port 422 for discharging the cooling water are provided.
  • the cooling pipe 42 introduces the superheated steam in the pyrolysis tank 2 into the inner pipe via the first conduit 41a, and cools and condenses the superheated steam with cooling water flowing between the inner pipe and the outer pipe. Thereafter, the cooling pipe 42 returns the superheated steam that has been cooled and condensed into water into the pyrolysis tank 2 through the second conduit 41b.
  • the first conduit 41a is provided with an electromagnetic valve 43 for stopping the discharge of superheated steam from the pyrolysis tank 2, and the second conduit 41b is used to prevent the backflow of superheated steam after condensation.
  • the check valve 44 is provided.
  • the thermal decomposition apparatus 1 configured as described above is disposed in the uppermost stream of the waste plastic oil processing system 100 as shown in FIG.
  • the pyrolysis apparatus 1 is connected to an electric once-through boiler 300 for generating saturated steam by introducing and heating the water stored in the water tank 200.
  • a catalyst tower 500 for reforming the pyrolysis gas with a zeolite catalyst or the like is disposed downstream of the pyrolysis apparatus 1. Between the catalyst tower 500 and the pyrolysis apparatus 1, the pyrolysis is performed.
  • a scrubber 400 is provided for neutralizing the gas with a calcium hydroxide solution to remove chlorine in the pyrolysis gas. In the scrubber 400, a hypo (sodium thiosulfate) solution is used as a reducing agent.
  • a condensing device 600 for cooling and condensing the pyrolysis gas to produce oil is disposed downstream of the catalyst tower 500.
  • the condensing device 600 includes two cooling tanks 601, and cooling water cooled by the cooling tower 602 flows on the outer surfaces of the two cooling tanks 601. Further, a centrifuge 700 for separating water from the generated oil is disposed downstream of the condenser 600.
  • the oil from which water has been separated by the centrifuge 700 is stored in the oil tank 800 via the first FA filter 801, and the water separated from the oil is stored in the water tank 200 via the second FA filter 201. Stored.
  • off-gas that is not condensed in the condenser 600 is washed by the caustic soda solution in the off-gas washing tank 901, temporarily stored in the off-gas tank 902, and then purified by the PIP titanium natural catalyst in the off-gas purifier 903. Thereafter, the off-gas is sterilized by the titanium oxide photocatalytic ceramic filter, which is a photocatalyst, in the off-gas purification device 900 and exhausted into the atmosphere from the exhaust duct 904.
  • the lid portion 21 is opened and waste plastics that are infectious medical waste are put into the thermal decomposition tank 2. Then, the cover part 21 is closed and the inside of the thermal decomposition tank 2 is sealed (refer FIG. 2).
  • the superheated steam supply pipe 3 is heated up to 900 ° C. by energization, and the inside of the thermal decomposition tank 2 is heated by the heat of the superheated steam supply pipe 3 itself.
  • the heating amount of the superheated steam supply pipe 3 is automatically controlled by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not increase any more,
  • the temperature in the pyrolysis tank 2 is maintained at 180 ° C. or higher (first temperature) for at least 30 minutes. Thereby, the waste plastic which is the infectious medical waste in the thermal decomposition tank 2 is dry heat sterilized.
  • the electric damper 24 is opened and the discharge pipe 23 is opened.
  • the electric once-through boiler 300 is operated, and water is supplied into the electric once-through boiler 300 via the water softener. Water in the tank 200 is supplied.
  • saturated steam is generated in the electric once-through boiler 300, and this saturated steam is sent from the electric once-through boiler 300 to the superheated steam supply pipe 3.
  • the superheated steam supply pipe 3 is heated up to 900 ° C. by energization, whereby the saturated steam sent from the electric once-through boiler 300 in the superheated steam supply pipe 3 is changed to superheated steam of 200 to 750 ° C.
  • the superheated steam thus generated is discharged from the superheated steam supply pipe 3 into the thermal decomposition tank 2, and the inside of the thermal decomposition tank 2 is rapidly heated by the superheated steam and the superheated steam supply pipe 3. Since the electromagnetic valve 43 is closed and the electric damper 24 is opened, excess superheated steam in the thermal decomposition tank 2 is not discharged to the cooler 4 but is discharged to the discharge pipe 23.
  • the temperature in the pyrolysis tank 2 rises, the waste plastic in the pyrolysis tank 2 starts to melt.
  • the motor 52 of the stirrer 5 is driven and the rotating shaft 51 is rotated at a predetermined rotational speed, the stirrer 5 stirs the molten waste plastic in the pyrolysis tank 2 (see FIG. 4).
  • the heating in the pyrolysis tank 2 is continued until the temperature in the pyrolysis tank 2 reaches 250 to 500 ° C. (second temperature). to continue.
  • the heating amount of the superheated steam supply pipe 3 is automatically controlled by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not exceed the second temperature.
  • the temperature in the pyrolysis tank 2 is maintained at the second temperature for a predetermined time (preferably 120 to 150 minutes), thereby Pyrolysis gas is generated from waste plastic.
  • the pyrolysis gas generated in this manner is discharged out of the pyrolysis tank 2 through the discharge pipe 23.
  • the pyrolysis gas is reformed into a low boiling point gas by removing chlorine from the scrubber 400 and touching the catalyst in the catalyst tower 500.
  • the reformed pyrolysis gas is supplied to the condensing device 600, passes through the cooling tank 601 of the condensing device 600, and is cooled and condensed by the cooling water flowing on the outer surface of the cooling tank 601. Thereby, oil is produced
  • the oil produced in the condensing device 600 is sent to the centrifuge 700, and water is separated by the centrifuge 700.
  • the oil from which water has been separated by the centrifuge 700 passes through the first FA filter 801 to remove formaldehyde, and is then stored in the oil tank 800.
  • the water separated from the oil by the centrifuge 700 passes through the second FA filter 201 to remove formaldehyde, and then is returned to the water tank 200 to be reused for the generation of saturated steam.
  • the pyrolysis gas contains components that are not condensed by the condenser 600.
  • the off gas that has not been condensed in the cooling tank 601 of the condenser 600 is sent out to the off gas cleaning tank 901.
  • the off-gas is cleaned in the off-gas cleaning tank 901, temporarily stored in the off-gas tank 902, and then supplied to the off-gas purifier 903 for purification and organic decomposition.
  • the purified and organically decomposed off-gas is then sterilized in the off-gas purification apparatus 900 and discharged from the exhaust duct 904 to the atmosphere.
  • the waste plastic after pyrolysis gas generation is carbonized in the pyrolysis tank 2. More specifically, the superheated steam at 500 to 750 ° C. is heated in the superheated steam supply pipe 3 by heating the superheated steam supply pipe 3 to 900 ° C. by energization with the electromagnetic valve 43 closed and the electric damper 24 open. Is generated.
  • This superheated steam is introduced into the pyrolysis tank 2 from the superheated steam supply pipe 3, and the temperature in the pyrolysis tank 2 is increased to 450 to 650 ° C. (third temperature) by the superheated steam and superheated steam supply pipe 3. .
  • the heating amount of the superheated steam supply pipe 3 is automatically controlled from 0 by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not exceed the third temperature. After the temperature in the pyrolysis tank 2 reaches the third temperature, the temperature in the pyrolysis tank 2 is maintained at this third temperature for a predetermined time (preferably 10 to 20 minutes). A carbide called residue is produced. In the carbonization treatment, a slight amount of pyrolysis gas is generated, but this pyrolysis gas is also recovered in the same line as the oil conversion treatment described above.
  • the operation of the electric once-through boiler 300 is stopped, the energization of the superheated steam supply pipe 3 is stopped, the heating of the superheated steam supply pipe 3 is stopped, and the pyrolysis tank 2 is naturally cooled.
  • a cooling shower can be supplied into the thermal decomposition tank 2 from the cooling shower supply port 26, and the inside of the thermal decomposition tank 2 can also be forcedly cooled.
  • nitrogen gas may be injected into the pyrolysis tank 2 from the nitrogen gas inlet 28, or air may be blown toward the pyrolysis tank 2 by the blower 6.
  • the pyrolysis apparatus 1 can efficiently heat the inside of the pyrolysis tank 2 by supplying superheated steam into the pyrolysis tank 2.
  • the capacity of can be increased. For this reason, it becomes possible to throw a large amount of waste plastics to be processed into the pyrolysis tank 2 as it is, and the sterilization process and the pyrolysis process can be continuously performed in the pyrolysis tank 2.
  • the processing time of the entire oil processing can be shortened, and the oil processing can be performed efficiently.
  • a stirrer 5 is provided in parallel with the bottom surface of the thermal decomposition tank 2 in the thermal decomposition tank 2. That is, since the end portion of the agitator 5 does not protrude from the upper surface of the pyrolysis tank 2, the door portion 2 for introducing waste plastic can be enlarged on the upper surface of the pyrolysis tank 2.
  • the superheated steam supply pipe 3 is disposed on the front side wall surface and the rear side wall surface in the thermal decomposition tank 2, but is not limited to this as long as it is provided in the thermal decomposition tank 2.
  • the waste plastic put into the tank 2 it may be provided on the left and right wall surfaces, the ceiling surface, the bottom surface, or the center part in the pyrolysis tank 2.
  • the heating means was the superheated steam supply pipe 3, if it was provided in the thermal decomposition tank 2, it will not be limited to this, For example, an electric heater etc. may be sufficient and a superheat is carried out.
  • the steam supply pipe 3 and an electric heater may be used in combination.
  • the sterilization process was performed only by heating the superheated steam supply pipe 3 by electricity supply, it introduce
  • the inside of the thermal decomposition tank 2 may be heated by the superheated steam.
  • the electric damper 24 of the discharge pipe 23 and the electromagnetic valve 43 of the cooler 4 are closed to seal the pyrolysis tank 2 and the superheated steam supply pipe 3 is heated up to 900 ° C. by energization. And the electric once-through boiler 300 is operated.
  • the saturated steam sent from the electric once-through boiler 300 to the superheated steam supply pipe 3 is changed to superheated steam at 200 to 750 ° C. in the superheated steam supply pipe 3, and the superheated steam is thermally decomposed from the superheated steam supply pipe 3. It is discharged into the tank 2.
  • the inside of the pyrolysis tank 2 is heated to 180 ° C. or more (first temperature), and the inside of the pyrolysis tank 2 is maintained at the first temperature for at least 30 minutes. To sterilize the waste plastic.
  • the cooler 4 when the sterilization process is performed using both the heat of the superheated steam supply pipe 3 and the superheated steam, it is preferable to use the cooler 4. More specifically, when the electric damper 24 is closed and the electromagnetic valve 43 is opened during the sterilization process, excess superheated steam in the thermal decomposition tank 2 is passed through the first conduit 41a to the inner pipe of the cooling pipe 42. To be introduced. The superheated steam is cooled and condensed in the inner pipe of the cooling pipe 42 by the cooling water flowing between the inner pipe and the outer pipe, and then returned to the pyrolysis tank 2 through the second conduit 41b (FIG. 6). Thereby, it can prevent that the inside of the thermal decomposition tank 2 becomes a high voltage
  • the superheated steam condensed by the cooler 4 to become water can be sterilized by a photocatalyst such as titanium oxide outside the thermal decomposition tank 2 and reused. Moreover, the excess superheated steam discharged
  • the thermal decomposition processing apparatus 1 performed the sterilization process and the thermal decomposition process, it is not limited to this, It can also be used independently as a sterilization apparatus.
  • the pyrolysis tank 2 was substantially rectangular parallelepiped shape, it is not limited to this, It is not limited to this, It can be set as various shapes, such as column shape and polygonal column shape.
  • stirrer 5 became a shape with the some blade
  • thermal decomposition processing apparatus 1 was arrange

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

Disclosed is a waste plastic pyrolizing apparatus that can reduce processing time. Specifically disclosed is a pyrolizing device for pyrolizing waste plastic and comprising: a pyrolitic vessel that houses the waste plastic; a heating means disposed in the pyrolitic vessel and that heats the waste plastic inside the pyrolitic vessel; and a control means that controls the amount of heat applied by the heating means in order to adjust the temperature inside the pyrolitic vessel.

Description

廃プラスチックの熱分解処理装置Waste plastic thermal decomposition equipment
 本発明は、廃プラスチックの熱分解処理装置に関するものである。 The present invention relates to a thermal decomposition treatment apparatus for waste plastic.
 近年、循環型経済社会を形成するための取り組みがさまざまな分野で行われ始め、廃プラスチックについてもそのリサイクルの必要性が高まっている。廃プラスチックのリサイクル処理の一つとして、廃プラスチックから油を取り出す油化という処理が知られている。この油化処理では、熱分解処理装置に備えられた熱分解槽に廃プラスチックを投入し、熱分解槽を外側から加熱することで熱分解槽内の廃プラスチックを加熱分解して熱分解ガスを生成し、その生成した熱分解ガスを冷却して油を得ている。このような油化処理が施される廃プラスチックのうち、主に医療関係機関より排出され、いわゆる感染医療廃棄物に分類されるものは、熱分解処理に先立って滅菌処理を行う必要がある。感染医療廃棄物に分類される廃プラスチックは、滅菌処理装置によって滅菌された後、滅菌処理装置から熱分解槽へと移され、熱分解層内で加熱分解される(例えば特許文献1参照)。 In recent years, efforts to form a recycling-oriented economic society have begun in various fields, and the need to recycle waste plastics is also increasing. As one of the recycling processes of waste plastics, a process called oil conversion for extracting oil from waste plastics is known. In this oil conversion treatment, waste plastic is put into a thermal decomposition tank provided in the thermal decomposition processing equipment, and the thermal decomposition tank is heated and decomposed to heat pyrolysis gas by heating the thermal decomposition tank from the outside. The oil is obtained by cooling the generated pyrolysis gas. Among waste plastics subjected to such oily treatment, those that are discharged mainly from medical institutions and classified as so-called infectious medical wastes need to be sterilized prior to thermal decomposition treatment. Waste plastic classified as infectious medical waste is sterilized by a sterilization apparatus, then transferred from the sterilization apparatus to a thermal decomposition tank, and thermally decomposed in a thermal decomposition layer (see, for example, Patent Document 1).
特許第4153923号公報Japanese Patent No. 4153923
 上述したような油化処理においては、熱分解槽の容量が十分でないため、滅菌装置によって滅菌処理された廃プラスチックをできるだけ多く熱分解槽に投入することができるよう、廃プラスチックを熱分解槽に移す前に破砕装置で破砕し、その後減容する必要がある。また、廃プラスチックを破砕する際、廃プラスチックに金属が混入していると破砕装置が詰まりによって運転停止したり故障したりする可能性があるため、事前に廃プラスチックから金属を分離及び除去する必要があった。このように、従来の熱分解処理装置においては、処理対象の廃プラスチックに対して金属分離、破砕、及び減容といった前処理を行う必要があるため、油化処理全体としての処理時間が長くなるという問題があった。 Since the capacity of the pyrolysis tank is not sufficient in the oiling treatment as described above, the waste plastic is put into the pyrolysis tank so that as much waste plastic sterilized by the sterilizer can be put into the pyrolysis tank as much as possible. It is necessary to crush with a crushing device before transferring and then reduce the volume. In addition, when crushing waste plastic, if the metal is mixed in the waste plastic, the crushing device may be clogged and the operation may stop or break down. Therefore, it is necessary to separate and remove the metal from the waste plastic in advance. was there. Thus, in the conventional pyrolysis processing apparatus, it is necessary to perform pretreatment such as metal separation, crushing, and volume reduction on the waste plastic to be processed, so that the processing time of the entire oil conversion processing is increased. There was a problem.
 そこで、本発明は、処理時間を短縮可能な熱分解処理装置を提供することを課題とする。 Therefore, an object of the present invention is to provide a thermal decomposition treatment apparatus that can shorten the treatment time.
 本発明に係る熱分解処理装置は、上記課題を解決するためになされたものであり、廃プラスチックを熱分解するための熱分解処理装置であって、廃プラスチックを収容する熱分解槽と、前記熱分解槽内に設けられており、前記熱分解槽内の廃プラスチックを加熱する加熱手段と、前記熱分解槽内の温度を調整するために前記加熱手段の加熱量を制御する制御手段と、を備えている。 A thermal decomposition treatment apparatus according to the present invention is made to solve the above-described problem, and is a thermal decomposition treatment apparatus for thermally decomposing waste plastic, which includes a thermal decomposition tank that accommodates waste plastic, Provided in the pyrolysis tank, heating means for heating the waste plastic in the pyrolysis tank, control means for controlling the heating amount of the heating means to adjust the temperature in the pyrolysis tank, It has.
 本発明に係る熱分解処理装置は、加熱手段が熱分解槽内に設けられていることにより、熱分解槽の外に加熱手段が設けられていた従来の熱分解装置よりも熱分解槽内の温度上昇速度が速くなるため、従来の熱分解装置と比較して加熱時間を延ばすことなく熱分解槽の容量を拡大することができる。このため、廃プラスチックを熱分解槽内に原型のまま大量に投入することができ、熱分解槽内において廃プラスチックの滅菌処理及び熱分解処理を連続して行うことが可能となる。このように、本発明に係る熱分解処理装置は、金属分離、破砕、及び減容といった廃プラスチックの前処理工程と滅菌処理装置から熱分解処理装置への廃プラスチックの移動工程とを省くことができるため、処理時間を短縮することができ、経費の削減をすることができる。 In the thermal decomposition treatment apparatus according to the present invention, the heating means is provided in the thermal decomposition tank, so that the heating means is provided in the thermal decomposition tank more than the conventional thermal decomposition apparatus in which the heating means is provided outside the thermal decomposition tank. Since the rate of temperature rise is increased, the capacity of the pyrolysis tank can be expanded without extending the heating time as compared with the conventional pyrolysis apparatus. For this reason, a large amount of waste plastic can be put into the pyrolysis tank in its original form, and the sterilization process and pyrolysis process of the waste plastic can be continuously performed in the pyrolysis tank. As described above, the thermal decomposition treatment apparatus according to the present invention can eliminate the waste plastic pretreatment process such as metal separation, crushing, and volume reduction, and the waste plastic transfer process from the sterilization treatment apparatus to the thermal decomposition treatment apparatus. Therefore, the processing time can be shortened and the cost can be reduced.
 また、上記熱分解処理装置において、加熱手段は、通電により自身が加熱される過熱蒸気供給管であることが好ましい。この過熱蒸気供給管は、自身が加熱されることで内部に供給される飽和蒸気を過熱蒸気へと変化させ、この過熱蒸気を熱分解槽内に放出する。この過熱蒸気及び過熱蒸気供給管自身の熱により、熱分解槽内をより効率よく加熱することができる。 Further, in the above thermal decomposition treatment apparatus, the heating means is preferably a superheated steam supply pipe that is heated by energization. This superheated steam supply pipe changes the saturated steam supplied to the inside by being heated to superheated steam, and discharges this superheated steam into the thermal decomposition tank. The inside of the thermal decomposition tank can be more efficiently heated by the heat of the superheated steam and the superheated steam supply pipe itself.
 また、上記熱分解処理装置は、過熱蒸気供給管を通電することのみで、乾熱滅菌装置としての使用ができる。 In addition, the thermal decomposition treatment apparatus can be used as a dry heat sterilization apparatus only by energizing the superheated steam supply pipe.
 また、上記熱分解処理装置は、過熱蒸気を冷却するための冷却器を前記熱分解槽の外側に備えていてもよい。この冷却器は、熱分解槽内から排出された余剰の過熱蒸気を冷却凝縮して熱分解槽内に戻すことができる。この構成によれば、熱分解槽内に送り込まれる過熱蒸気により熱分解槽内が高圧になるのを防止することができる。 Moreover, the said thermal decomposition processing apparatus may be equipped with the cooler for cooling superheated steam in the outer side of the said thermal decomposition tank. This cooler can cool and condense excess superheated steam discharged from the pyrolysis tank and return it to the pyrolysis tank. According to this structure, it can prevent that the inside of a thermal decomposition tank becomes a high voltage | pressure by the superheated steam sent in a thermal decomposition tank.
 また、上記熱分解処理装置は、回転軸が熱分解槽の内側底面に平行に延びる攪拌器を備えていてもよい。この攪拌器によって熱分解槽内の廃プラスチックを攪拌することで、熱分解処理後の廃プラスチック、木片・紙屑等の有機物の残渣を粉状にすることができるとともに、熱分解槽内をより効率よく加熱することができる。 The pyrolysis apparatus may include a stirrer whose rotating shaft extends parallel to the inner bottom surface of the pyrolysis tank. By stirring the waste plastic in the pyrolysis tank with this stirrer, the waste plastic after pyrolysis treatment and organic residue such as wood chips and paper waste can be made into powder and more efficient in the pyrolysis tank Can be heated well.
 上記攪拌器は、熱分解槽に形成された廃プラスチックの排出口に向かって廃プラスチックを運搬可能なよう構成されている。この構成によれば、熱分解槽内における熱分解後の廃プラスチックを熱分解槽の外に効率よく排出することができる。 The agitator is configured to be able to transport waste plastic toward the waste plastic discharge port formed in the thermal decomposition tank. According to this configuration, the waste plastic after pyrolysis in the pyrolysis tank can be efficiently discharged out of the pyrolysis tank.
 また、上記熱分解処理装置において、制御手段は、熱分解槽内の温度が廃プラスチックを滅菌するための第1の温度及び廃プラスチックを油化するための第2の温度となるよう、加熱手段の加熱量を制御することができる。 Further, in the above thermal decomposition treatment apparatus, the control means has heating means so that the temperature in the thermal decomposition tank becomes a first temperature for sterilizing the waste plastic and a second temperature for oiling the waste plastic. The amount of heating can be controlled.
 上記制御手段は、さらに、熱分解槽内の温度が廃プラスチック、及び木片・紙屑等の有機物を炭化するための第3の温度となるよう、加熱手段の加熱量を制御してもよい。 The control means may further control the heating amount of the heating means so that the temperature in the pyrolysis tank becomes a third temperature for carbonizing organic matter such as waste plastic and wood chips / paper waste.
 本発明によれば、処理時間を短縮することができる。 According to the present invention, the processing time can be shortened.
本実施形態に係る熱分解処理装置の正面断面図である。It is front sectional drawing of the thermal decomposition processing apparatus which concerns on this embodiment. 本実施形態に係る熱分解処理装置の平面図である。It is a top view of the thermal decomposition processing apparatus which concerns on this embodiment. 本実施形態に係る熱分解処理装置の左側面図である。It is a left view of the thermal decomposition processing apparatus which concerns on this embodiment. 図1のA-A断面図である。FIG. 2 is a cross-sectional view taken along the line AA in FIG. 本実施形態に係る熱分解処理装置の右側面図である。It is a right view of the thermal decomposition processing apparatus which concerns on this embodiment. 本実施形態に係る冷却器の正面拡大図である。It is a front enlarged view of the cooler concerning this embodiment. 本実施形態に係る廃プラスチック油化処理システムの全体概略図である。1 is an overall schematic diagram of a waste plastic oil processing system according to the present embodiment.
 以下、本発明に係る熱分解処理装置の一実施形態について図面を参照しつつ説明する。 Hereinafter, an embodiment of a thermal decomposition processing apparatus according to the present invention will be described with reference to the drawings.
 本実施形態に係る熱分解処理装置1は、図1に示すように、熱分解槽2、この熱分解槽2内に過熱蒸気を導入するための過熱蒸気供給管3、及び過熱蒸気を冷却凝縮するための冷却器4(冷却手段)を備えている。 As shown in FIG. 1, the thermal decomposition treatment apparatus 1 according to the present embodiment cools and condenses the thermal decomposition tank 2, the superheated steam supply pipe 3 for introducing the superheated steam into the thermal decomposition tank 2, and the superheated steam. A cooler 4 (cooling means) is provided.
 熱分解槽2は、略直方体状であり、内部に廃プラスチックを収容可能なよう中空となっている。図2に示すように、この熱分解槽2の上面には、廃プラスチックを投入するために開閉可能な蓋部21、及び廃プラスチックから発生する熱分解ガスを排出するための排出管23が設けられており、排出管23には熱分解ガスの流量を調節するための電動ダンパ24が取り付けられている。また、熱分解槽2の上面には、安全弁25や、熱分解槽2内に冷却水のシャワーを供給するための冷却シャワー供給口26が設けられている。図2及び図3に示すように、熱分解槽2の左側面には、熱分解処理後に生成される炭化物であるいわゆる残渣を取り出すために、開閉可能な2つの扉部27(排出口)が設けられ、また、熱分解槽2内に冷却用の窒素ガスを注入するための窒素ガス注入口28が形成されている。熱分解槽2の下方には、図1に示すように、熱分解槽2を冷却するための送風機6が設置されている。 The pyrolysis tank 2 has a substantially rectangular parallelepiped shape and is hollow so that waste plastic can be accommodated therein. As shown in FIG. 2, on the upper surface of the thermal decomposition tank 2, there is provided a lid portion 21 that can be opened and closed for charging waste plastic, and a discharge pipe 23 for discharging thermal decomposition gas generated from the waste plastic. An electric damper 24 for adjusting the flow rate of the pyrolysis gas is attached to the discharge pipe 23. Further, a safety valve 25 and a cooling shower supply port 26 for supplying a shower of cooling water into the pyrolysis tank 2 are provided on the upper surface of the pyrolysis tank 2. As shown in FIGS. 2 and 3, the left side surface of the pyrolysis tank 2 has two door portions 27 (discharge ports) that can be opened and closed in order to take out so-called residues that are carbides generated after the pyrolysis treatment. Further, a nitrogen gas inlet 28 for injecting cooling nitrogen gas into the pyrolysis tank 2 is formed. A blower 6 for cooling the pyrolysis tank 2 is installed below the pyrolysis tank 2 as shown in FIG.
 図4に示すように、熱分解槽2には、熱分解処理中に廃プラスチックを攪拌するための2つの攪拌器5が設けられている。攪拌器5は、熱分解槽2の底面に平行に延びる回転軸51を有しており、この回転軸51は、周囲に複数の羽根53が取り付けられ、モータ52により双方向に回転可能となっている。攪拌器5は、回転軸51がモータ52により一方向に回転すると熱分解槽2内の廃プラスチックを攪拌し、回転軸51が逆方向に回転すると熱分解槽2内の廃プラスチックを扉部27側に向かって運搬するよう構成されている。また、図1及び図4に示すように、熱分解槽2内には、熱分解槽2内の圧力を測定するための圧力計7、及び熱分解槽2内の熱を逃がさないようにするための断熱材8が設けられている。 As shown in FIG. 4, the pyrolysis tank 2 is provided with two agitators 5 for agitating the waste plastic during the pyrolysis treatment. The stirrer 5 has a rotating shaft 51 extending in parallel to the bottom surface of the pyrolysis tank 2, and the rotating shaft 51 is provided with a plurality of blades 53 around it and can be rotated in both directions by a motor 52. ing. The stirrer 5 stirs the waste plastic in the pyrolysis tank 2 when the rotary shaft 51 rotates in one direction by the motor 52, and the waste plastic in the pyrolysis tank 2 when the rotary shaft 51 rotates in the reverse direction. It is configured to carry toward the side. Moreover, as shown in FIG.1 and FIG.4, in the pyrolysis tank 2, the pressure gauge 7 for measuring the pressure in the pyrolysis tank 2 and the heat in the pyrolysis tank 2 are made not to escape. A heat insulating material 8 is provided.
 過熱蒸気供給管3は、図1及び図4に示すように、熱分解槽2内に設けられており、熱分解槽2内の前側壁面及び後側壁面において上下で折り返すように配置されている。過熱蒸気供給管3は、通電により最高900℃まで加熱されるいわゆるヒータ管として構成され、後述する電気貫流ボイラ300から送られ内部を通過する飽和蒸気を200~750℃の過熱蒸気に変化させる。この過熱蒸気供給管3の加熱量は、シーケンサ内蔵型の操作盤9(制御手段)によって自動制御される。過熱蒸気供給管3の材質としては、高温下における耐食性を有するものが好ましく、例えば、ニッケルクロム合金を使用することができる。ニッケルクロム合金は、特に限定されるものではないが、ニッケルを58~63%、クロムを21~25%含有するものが好ましく、例えば、インコネル(登録商標)601である。また、熱分解槽2の容量が4.16mの場合、過熱蒸気供給管3の大きさは、特に限定されるものではないが、外径26.7mm、内径21.3mm、長さ15~18mであることが好ましく、例えば、配管サイズ15Aである。 As shown in FIGS. 1 and 4, the superheated steam supply pipe 3 is provided in the pyrolysis tank 2, and is disposed so as to be folded up and down on the front and rear side wall surfaces in the pyrolysis tank 2. . The superheated steam supply pipe 3 is configured as a so-called heater pipe that is heated to a maximum of 900 ° C. by energization, and changes saturated steam sent from an electric once-through boiler 300 described later and passing through the inside into 200 to 750 ° C. superheated steam. The heating amount of the superheated steam supply pipe 3 is automatically controlled by an operation panel 9 (control means) with a built-in sequencer. As the material for the superheated steam supply pipe 3, one having corrosion resistance at high temperatures is preferable, and for example, a nickel chromium alloy can be used. The nickel-chromium alloy is not particularly limited, but preferably contains 58 to 63% nickel and 21 to 25% chromium, for example, Inconel (registered trademark) 601. When the capacity of the pyrolysis tank 2 is 4.16 m 3 , the size of the superheated steam supply pipe 3 is not particularly limited, but the outer diameter is 26.7 mm, the inner diameter is 21.3 mm, and the length is 15 to It is preferable that it is 18m, for example, is piping size 15A.
 図5に示すように、熱分解槽2の右側面には4つの冷却器4が取り付けられている。図6に示すように、冷却器4は二重管である冷却管42を備えており、この冷却管42には、内管と外管との間に冷却水を供給するための水供給口421、及びこの冷却水を排出するための水排出口422が設けられている。冷却管42は、熱分解槽2内の過熱蒸気を第1の導管41aを介して内管に導入し、この過熱蒸気を内管と外管との間を流れる冷却水によって冷却凝縮する。その後、冷却管42は、冷却凝縮されて水となった過熱蒸気を第2の導管41bを介して熱分解槽2内へと戻す。第1の導管41aには熱分解槽2内からの過熱蒸気の排出を停止するための電磁弁43が設けられており、第2の導管41bには凝縮後の過熱蒸気の逆流を防止するためのチャッキ弁44が設けられている。 As shown in FIG. 5, four coolers 4 are attached to the right side surface of the pyrolysis tank 2. As shown in FIG. 6, the cooler 4 includes a cooling pipe 42 that is a double pipe, and the cooling pipe 42 has a water supply port for supplying cooling water between the inner pipe and the outer pipe. 421 and a water discharge port 422 for discharging the cooling water are provided. The cooling pipe 42 introduces the superheated steam in the pyrolysis tank 2 into the inner pipe via the first conduit 41a, and cools and condenses the superheated steam with cooling water flowing between the inner pipe and the outer pipe. Thereafter, the cooling pipe 42 returns the superheated steam that has been cooled and condensed into water into the pyrolysis tank 2 through the second conduit 41b. The first conduit 41a is provided with an electromagnetic valve 43 for stopping the discharge of superheated steam from the pyrolysis tank 2, and the second conduit 41b is used to prevent the backflow of superheated steam after condensation. The check valve 44 is provided.
 上述したように構成された熱分解装置1は、図7に示すように、廃プラスチック油化処理システム100の最上流に配置されている。熱分解処理装置1には、水タンク200内に貯蔵された水を内部に導入して加熱することで飽和蒸気を発生させるための電気貫流ボイラ300が接続されている。熱分解処理装置1の下流には、ゼオライト触媒等によって熱分解ガスを改質するための触媒塔500が配置されており、この触媒塔500と熱分解処理装置1との間には、熱分解ガスを水酸化カルシウム液によって中和して熱分解ガス中の塩素を除去するためのスクラバー400が設けられている。なお、スクラバー400においては還元剤としてハイポ(チオ硫酸ナトリウム)液が使用される。触媒塔500の下流には、熱分解ガスを冷却凝縮して油を生成するための凝縮装置600が配置されている。この凝縮装置600は、2つの冷却タンク601を備えており、この2つの冷却タンク601の外側面にはクーリングタワー602によって冷却された冷却水が流される。さらに、凝縮装置600の下流には、生成された油から水を分離するための遠心分離機700が配置されている。この遠心分離機700によって水が分離された油は、第1のFAフィルタ801を介して油タンク800に貯蔵され、油から分離された水は第2のFAフィルタ201を介して水タンク200に貯蔵される。また、凝縮装置600で凝縮されないいわゆるオフガスは、オフガス洗浄タンク901で苛性ソーダ液によって洗浄され、オフガスタンク902に一旦収容された後、オフガス浄化器903でPIPチタン自然触媒により、浄化される。その後、オフガスは、オフガス浄化装置900で光触媒である酸化チタン光触媒セラミックフィルタによって殺菌され、排気ダクト904より大気中に排気される。 The thermal decomposition apparatus 1 configured as described above is disposed in the uppermost stream of the waste plastic oil processing system 100 as shown in FIG. The pyrolysis apparatus 1 is connected to an electric once-through boiler 300 for generating saturated steam by introducing and heating the water stored in the water tank 200. A catalyst tower 500 for reforming the pyrolysis gas with a zeolite catalyst or the like is disposed downstream of the pyrolysis apparatus 1. Between the catalyst tower 500 and the pyrolysis apparatus 1, the pyrolysis is performed. A scrubber 400 is provided for neutralizing the gas with a calcium hydroxide solution to remove chlorine in the pyrolysis gas. In the scrubber 400, a hypo (sodium thiosulfate) solution is used as a reducing agent. A condensing device 600 for cooling and condensing the pyrolysis gas to produce oil is disposed downstream of the catalyst tower 500. The condensing device 600 includes two cooling tanks 601, and cooling water cooled by the cooling tower 602 flows on the outer surfaces of the two cooling tanks 601. Further, a centrifuge 700 for separating water from the generated oil is disposed downstream of the condenser 600. The oil from which water has been separated by the centrifuge 700 is stored in the oil tank 800 via the first FA filter 801, and the water separated from the oil is stored in the water tank 200 via the second FA filter 201. Stored. In addition, so-called off-gas that is not condensed in the condenser 600 is washed by the caustic soda solution in the off-gas washing tank 901, temporarily stored in the off-gas tank 902, and then purified by the PIP titanium natural catalyst in the off-gas purifier 903. Thereafter, the off-gas is sterilized by the titanium oxide photocatalytic ceramic filter, which is a photocatalyst, in the off-gas purification device 900 and exhausted into the atmosphere from the exhaust duct 904.
 次に、上述したように構成された熱分解処理装置1、及びこの熱分解処理装置1が設置された廃プラスチック油化処理システム100の作動方法について説明する。 Next, the operation method of the thermal decomposition processing apparatus 1 configured as described above and the waste plastic oil processing system 100 in which the thermal decomposition processing apparatus 1 is installed will be described.
 まず、排出管23の電動ダンパ24及び冷却器4の電磁弁43を閉じた状態で、蓋部21を開けて熱分解槽2内に感染医療廃棄物である廃プラスチックを投入する。その後、蓋部21を閉め、熱分解槽2内を密閉する(図2参照)。 First, in a state where the electric damper 24 of the discharge pipe 23 and the electromagnetic valve 43 of the cooler 4 are closed, the lid portion 21 is opened and waste plastics that are infectious medical waste are put into the thermal decomposition tank 2. Then, the cover part 21 is closed and the inside of the thermal decomposition tank 2 is sealed (refer FIG. 2).
 次に、過熱蒸気供給管3を通電により最高900℃まで加熱し、この過熱蒸気供給管3自身の熱により熱分解槽2内を加熱する。熱分解槽2内の温度が180℃を越えた時点で、過熱蒸気供給管3の加熱量は、熱分解槽2内の温度がそれ以上上昇しないよう、操作盤9のシーケンサにより自動制御され、熱分解槽2内の温度は180℃以上(第1の温度)で少なくとも30分間維持される。これにより、熱分解槽2内の感染医療廃棄物である廃プラスチックが乾熱滅菌される。 Next, the superheated steam supply pipe 3 is heated up to 900 ° C. by energization, and the inside of the thermal decomposition tank 2 is heated by the heat of the superheated steam supply pipe 3 itself. When the temperature in the pyrolysis tank 2 exceeds 180 ° C., the heating amount of the superheated steam supply pipe 3 is automatically controlled by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not increase any more, The temperature in the pyrolysis tank 2 is maintained at 180 ° C. or higher (first temperature) for at least 30 minutes. Thereby, the waste plastic which is the infectious medical waste in the thermal decomposition tank 2 is dry heat sterilized.
 次に、冷却器4の電磁弁43を閉じたまま、電動ダンパ24を開いて排出管23を開放した後、電気貫流ボイラ300を作動させ、この電気貫流ボイラ300内に軟水器を介して水タンク200内の水を供給する。これにより、電気貫流ボイラ300内で飽和蒸気が発生し、この飽和蒸気が電気貫流ボイラ300から過熱蒸気供給管3へと送られる。過熱蒸気供給管3は通電により最高900℃まで加熱され、これにより、過熱蒸気供給管3において電気貫流ボイラ300から送られてきた飽和蒸気が200~750℃の過熱蒸気へと変化する。このようにして生じた過熱蒸気は過熱蒸気供給管3から熱分解槽2内へと放出され、熱分解槽2内はこの過熱蒸気及び過熱蒸気供給管3によって急速に加熱される。なお、電磁弁43が閉じ、電動ダンパ24が開いているため、熱分解槽2内の余剰の過熱蒸気は冷却器4には排出されず、排出管23に排出される。熱分解槽2内の温度が上昇すると、熱分解槽2内の廃プラスチックが溶融し始める。このとき、攪拌器5のモータ52を駆動させ、回転軸51を所定の回転数で回転させると、攪拌器5が熱分解槽2内の溶融した廃プラスチックを攪拌する(図4参照)。 Next, with the electromagnetic valve 43 of the cooler 4 closed, the electric damper 24 is opened and the discharge pipe 23 is opened. Then, the electric once-through boiler 300 is operated, and water is supplied into the electric once-through boiler 300 via the water softener. Water in the tank 200 is supplied. Thereby, saturated steam is generated in the electric once-through boiler 300, and this saturated steam is sent from the electric once-through boiler 300 to the superheated steam supply pipe 3. The superheated steam supply pipe 3 is heated up to 900 ° C. by energization, whereby the saturated steam sent from the electric once-through boiler 300 in the superheated steam supply pipe 3 is changed to superheated steam of 200 to 750 ° C. The superheated steam thus generated is discharged from the superheated steam supply pipe 3 into the thermal decomposition tank 2, and the inside of the thermal decomposition tank 2 is rapidly heated by the superheated steam and the superheated steam supply pipe 3. Since the electromagnetic valve 43 is closed and the electric damper 24 is opened, excess superheated steam in the thermal decomposition tank 2 is not discharged to the cooler 4 but is discharged to the discharge pipe 23. When the temperature in the pyrolysis tank 2 rises, the waste plastic in the pyrolysis tank 2 starts to melt. At this time, when the motor 52 of the stirrer 5 is driven and the rotating shaft 51 is rotated at a predetermined rotational speed, the stirrer 5 stirs the molten waste plastic in the pyrolysis tank 2 (see FIG. 4).
 このように、熱分解槽2内の廃プラスチックを攪拌器5により攪拌しながら、熱分解槽2内の温度が250~500℃(第2の温度)となるまで熱分解槽2内の加熱を続ける。過熱蒸気供給管3の加熱量は、熱分解槽2内の温度が第2の温度を超えないよう、操作盤9のシーケンサにより自動制御される。熱分解槽2内の温度が第2の温度になった後、熱分解槽2内をこの第2の温度に所定時間(好ましくは120~150分間)維持することにより、熱分解槽2内の廃プラスチックより熱分解ガスが生成される。 In this way, while the waste plastic in the pyrolysis tank 2 is stirred by the stirrer 5, the heating in the pyrolysis tank 2 is continued until the temperature in the pyrolysis tank 2 reaches 250 to 500 ° C. (second temperature). to continue. The heating amount of the superheated steam supply pipe 3 is automatically controlled by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not exceed the second temperature. After the temperature in the pyrolysis tank 2 reaches the second temperature, the temperature in the pyrolysis tank 2 is maintained at the second temperature for a predetermined time (preferably 120 to 150 minutes), thereby Pyrolysis gas is generated from waste plastic.
 このようにして生成された熱分解ガスは、排出管23より熱分解槽2の外に排出される。この熱分解ガスは、図7に示すように、スクラバー400によって塩素が取り除かれ、触媒塔500内の触媒に触れることによって低沸点のガスに改質される。改質された熱分解ガスは、凝縮装置600へと供給され、凝縮装置600の冷却タンク601内を通過し、冷却タンク601の外側面を流れる冷却水によって冷却凝縮される。これにより、熱分解ガスから油が生成される。凝縮装置600において生成された油は、遠心分離機700に送られ、この遠心分離機700によって水分が分離される。遠心分離機700によって水分が分離された油は、第1のFAフィルタ801を通過してホルムアルデヒドが除去された後、油タンク800に貯蔵される。一方、遠心分離機700によって油から分離された水分は、第2のFAフィルタ201を通過してホルムアルデヒドが除去された後、水タンク200へと戻され、飽和蒸気の生成に再利用される。 The pyrolysis gas generated in this manner is discharged out of the pyrolysis tank 2 through the discharge pipe 23. As shown in FIG. 7, the pyrolysis gas is reformed into a low boiling point gas by removing chlorine from the scrubber 400 and touching the catalyst in the catalyst tower 500. The reformed pyrolysis gas is supplied to the condensing device 600, passes through the cooling tank 601 of the condensing device 600, and is cooled and condensed by the cooling water flowing on the outer surface of the cooling tank 601. Thereby, oil is produced | generated from pyrolysis gas. The oil produced in the condensing device 600 is sent to the centrifuge 700, and water is separated by the centrifuge 700. The oil from which water has been separated by the centrifuge 700 passes through the first FA filter 801 to remove formaldehyde, and is then stored in the oil tank 800. On the other hand, the water separated from the oil by the centrifuge 700 passes through the second FA filter 201 to remove formaldehyde, and then is returned to the water tank 200 to be reused for the generation of saturated steam.
 ここで、熱分解ガス中には凝縮装置600によって凝縮されない成分も含まれている。このため、凝縮装置600の冷却タンク601では凝縮されなかったオフガスが、オフガス洗浄タンク901へと送り出される。オフガスは、オフガス洗浄タンク901で洗浄され、オフガスタンク902に一旦収容された後、オフガス浄化器903に供給されて浄化・有機分解される。浄化・有機分解されたオフガスは、その後、オフガス浄化装置900において殺菌され、排気ダクト904から大気中に排出される。 Here, the pyrolysis gas contains components that are not condensed by the condenser 600. For this reason, the off gas that has not been condensed in the cooling tank 601 of the condenser 600 is sent out to the off gas cleaning tank 901. The off-gas is cleaned in the off-gas cleaning tank 901, temporarily stored in the off-gas tank 902, and then supplied to the off-gas purifier 903 for purification and organic decomposition. The purified and organically decomposed off-gas is then sterilized in the off-gas purification apparatus 900 and discharged from the exhaust duct 904 to the atmosphere.
 このように油化処理をした後、熱分解槽2内において熱分解ガス生成後の廃プラスチックの炭化処理を行う。詳述すると、電磁弁43を閉じ電動ダンパ24を開いたままの状態で、過熱蒸気供給管3を通電により最高900℃まで加熱することで過熱蒸気供給管3内において500~750℃の過熱蒸気を発生させる。この過熱蒸気を過熱蒸気供給管3から熱分解槽2内に導入し、過熱蒸気及び過熱蒸気供給管3により、熱分解槽2内の温度を450~650℃(第3の温度)まで上昇させる。過熱蒸気供給管3の加熱量は、熱分解槽2内の温度が第3の温度を超えないよう、操作盤9のシーケンサに0より自動制御される。熱分解槽2内の温度が第3の温度になった後、熱分解槽2内をこの第3の温度に所定時間(好ましくは10~20分間)維持することにより、熱分解槽2内において残渣と呼ばれる炭化物が生成される。なお、炭化処理においても熱分解ガスがわずかに発生するが、この熱分解ガスについても前述の油化処理と同ラインで回収される。 After oiling in this way, the waste plastic after pyrolysis gas generation is carbonized in the pyrolysis tank 2. More specifically, the superheated steam at 500 to 750 ° C. is heated in the superheated steam supply pipe 3 by heating the superheated steam supply pipe 3 to 900 ° C. by energization with the electromagnetic valve 43 closed and the electric damper 24 open. Is generated. This superheated steam is introduced into the pyrolysis tank 2 from the superheated steam supply pipe 3, and the temperature in the pyrolysis tank 2 is increased to 450 to 650 ° C. (third temperature) by the superheated steam and superheated steam supply pipe 3. . The heating amount of the superheated steam supply pipe 3 is automatically controlled from 0 by the sequencer of the operation panel 9 so that the temperature in the pyrolysis tank 2 does not exceed the third temperature. After the temperature in the pyrolysis tank 2 reaches the third temperature, the temperature in the pyrolysis tank 2 is maintained at this third temperature for a predetermined time (preferably 10 to 20 minutes). A carbide called residue is produced. In the carbonization treatment, a slight amount of pyrolysis gas is generated, but this pyrolysis gas is also recovered in the same line as the oil conversion treatment described above.
 炭化処理の後、電気貫流ボイラ300の作動を停止するとともに、過熱蒸気供給管3への通電を止めることで過熱蒸気供給管3の加熱を停止し、熱分解槽2を自然冷却させる。なお、冷却シャワー供給口26より熱分解槽2内に冷却シャワーを供給し、熱分解槽2内を強制的に冷却することもできる。また、冷却シャワーと併せて、窒素ガス注入口28より熱分解槽2内に窒素ガスを注入したり、送風機6により熱分解槽2に向かって送風したりしてもよい。 After the carbonization treatment, the operation of the electric once-through boiler 300 is stopped, the energization of the superheated steam supply pipe 3 is stopped, the heating of the superheated steam supply pipe 3 is stopped, and the pyrolysis tank 2 is naturally cooled. In addition, a cooling shower can be supplied into the thermal decomposition tank 2 from the cooling shower supply port 26, and the inside of the thermal decomposition tank 2 can also be forcedly cooled. Further, in combination with the cooling shower, nitrogen gas may be injected into the pyrolysis tank 2 from the nitrogen gas inlet 28, or air may be blown toward the pyrolysis tank 2 by the blower 6.
 熱分解槽2を冷却した後、扉部27を閉めた状態のまま、攪拌器5の回転軸51をモータ52により油化処理中の回転方向と逆方向に所定の回転数で回転させる。これにより、熱分解槽2内の残渣は扉部27側へと運搬されて扉部27近傍に集められるため、扉部27から残渣を容易に回収することができる。 After cooling the pyrolysis tank 2, the rotating shaft 51 of the stirrer 5 is rotated by the motor 52 at a predetermined rotational speed in the direction opposite to the rotational direction during the oiling process while the door portion 27 is closed. Thereby, since the residue in the pyrolysis tank 2 is conveyed to the door part 27 side and collected in the door part 27 vicinity, a residue can be easily collect | recovered from the door part 27. FIG.
 以上のように、本実施形態に係る熱分解処理装置1は、熱分解槽2内に過熱蒸気を供給することにより、熱分解槽2内を効率よく加熱することができるため、熱分解槽2の容量を大きくすることができる。このため、処理対象の廃プラスチックを原型のまま熱分解槽2内に大量に投入することが可能となり、熱分解槽2内において滅菌処理と熱分解処理とを連続して行うことができる。この結果、油化処理全体の処理時間を短縮することができ、効率的に油化処理を行うことができる。また、本実施形態の熱分解処理装置1は、熱分解槽2内において、攪拌器5が熱分解槽2の底面と平行に設けられている。すなわち、攪拌器5の端部が熱分解槽2の上面に突出しないため、熱分解槽2の上面において廃プラスチックを投入するための扉部2を大きくすることができる。 As described above, the pyrolysis apparatus 1 according to the present embodiment can efficiently heat the inside of the pyrolysis tank 2 by supplying superheated steam into the pyrolysis tank 2. The capacity of can be increased. For this reason, it becomes possible to throw a large amount of waste plastics to be processed into the pyrolysis tank 2 as it is, and the sterilization process and the pyrolysis process can be continuously performed in the pyrolysis tank 2. As a result, the processing time of the entire oil processing can be shortened, and the oil processing can be performed efficiently. Further, in the thermal decomposition treatment apparatus 1 of the present embodiment, a stirrer 5 is provided in parallel with the bottom surface of the thermal decomposition tank 2 in the thermal decomposition tank 2. That is, since the end portion of the agitator 5 does not protrude from the upper surface of the pyrolysis tank 2, the door portion 2 for introducing waste plastic can be enlarged on the upper surface of the pyrolysis tank 2.
 以上、本発明の実施形態について説明したが、本発明はこれらに限定されるものではなく、本発明の趣旨を逸脱しない限りにおいて種々の変更が可能である。例えば、上記実施形態において、過熱蒸気供給管3は熱分解槽2において前側壁面及び後側壁面に配置されていたが、熱分解槽2内に設けられていればこれに限定されず、熱分解槽2内に投入される廃プラスチックの形状等に応じて、熱分解槽2内の左右壁面や天井面、底面、中央部に設けてもよい。 As mentioned above, although embodiment of this invention was described, this invention is not limited to these, A various change is possible unless it deviates from the meaning of this invention. For example, in the above-described embodiment, the superheated steam supply pipe 3 is disposed on the front side wall surface and the rear side wall surface in the thermal decomposition tank 2, but is not limited to this as long as it is provided in the thermal decomposition tank 2. Depending on the shape or the like of the waste plastic put into the tank 2, it may be provided on the left and right wall surfaces, the ceiling surface, the bottom surface, or the center part in the pyrolysis tank 2.
 また、上記実施形態において、加熱手段は過熱蒸気供給管3であったが、熱分解槽2内に設けられていればこれに限定されず、例えば、電熱ヒータ等であってもよいし、過熱蒸気供給管3と電熱ヒータ等とを併用してもよい。 Moreover, in the said embodiment, although the heating means was the superheated steam supply pipe 3, if it was provided in the thermal decomposition tank 2, it will not be limited to this, For example, an electric heater etc. may be sufficient and a superheat is carried out. The steam supply pipe 3 and an electric heater may be used in combination.
 また、上記実施形態において、過熱蒸気供給管3を通電により加熱することのみによって滅菌処理を行っていたが、過熱蒸気供給管3の加熱及び過熱蒸気供給管3を介して熱分解槽2に導入される過熱蒸気によって熱分解槽2内を加熱してもよい。詳述すると、滅菌処理の際、排出管23の電動ダンパ24及び冷却器4の電磁弁43を閉じて熱分解槽2を密閉しておき、過熱蒸気供給管3を通電により最高900℃まで加熱するとともに電気貫流ボイラ300を作動させる。これにより、電気貫流ボイラ300から過熱蒸気供給管3へと送られた飽和蒸気が過熱蒸気供給管3において200~750℃の過熱蒸気へと変化し、過熱蒸気が過熱蒸気供給管3から熱分解槽2内へ放出される。この過熱蒸気及び過熱蒸気供給管3自身の熱により、熱分解槽2内を180℃以上(第1の温度)になるまで加熱し、熱分解槽2内を第1の温度に少なくとも30分間維持することで廃プラスチックの滅菌処理を行う。 Moreover, in the said embodiment, although the sterilization process was performed only by heating the superheated steam supply pipe 3 by electricity supply, it introduce | transduces into the thermal decomposition tank 2 through the heating of the superheated steam supply pipe 3, and the superheated steam supply pipe 3. The inside of the thermal decomposition tank 2 may be heated by the superheated steam. Specifically, during the sterilization process, the electric damper 24 of the discharge pipe 23 and the electromagnetic valve 43 of the cooler 4 are closed to seal the pyrolysis tank 2 and the superheated steam supply pipe 3 is heated up to 900 ° C. by energization. And the electric once-through boiler 300 is operated. As a result, the saturated steam sent from the electric once-through boiler 300 to the superheated steam supply pipe 3 is changed to superheated steam at 200 to 750 ° C. in the superheated steam supply pipe 3, and the superheated steam is thermally decomposed from the superheated steam supply pipe 3. It is discharged into the tank 2. With the heat of the superheated steam and the superheated steam supply pipe 3 itself, the inside of the pyrolysis tank 2 is heated to 180 ° C. or more (first temperature), and the inside of the pyrolysis tank 2 is maintained at the first temperature for at least 30 minutes. To sterilize the waste plastic.
 このように過熱蒸気供給管3の自身の熱と過熱蒸気とを併用して滅菌処理を行う場合、冷却器4を使用することが好ましい。詳述すると、滅菌処理の際、電動ダンパ24を閉じるとともに電磁弁43を開いておくことで、熱分解槽2内の余剰の過熱蒸気が第1の導管41aを介して冷却管42の内管へ導入される。この過熱蒸気は、冷却管42の内管において、内管と外管との間を流れる冷却水により冷却凝縮され、その後、第2の導管41bを介して熱分解槽2内に戻される(図6参照)。これにより、熱分解槽2内が高圧になるのを防止することができる。なお、冷却器4によって凝縮され水となった過熱蒸気を熱分解槽2の外で酸化チタン等の光触媒により殺菌し、再利用することもできる。また、冷却器4を使用せず、熱分解槽2から排出された余剰の過熱蒸気を焼却することもできる。この場合、過熱蒸気が外気に触れる前に焼却することが好ましい。 Thus, when the sterilization process is performed using both the heat of the superheated steam supply pipe 3 and the superheated steam, it is preferable to use the cooler 4. More specifically, when the electric damper 24 is closed and the electromagnetic valve 43 is opened during the sterilization process, excess superheated steam in the thermal decomposition tank 2 is passed through the first conduit 41a to the inner pipe of the cooling pipe 42. To be introduced. The superheated steam is cooled and condensed in the inner pipe of the cooling pipe 42 by the cooling water flowing between the inner pipe and the outer pipe, and then returned to the pyrolysis tank 2 through the second conduit 41b (FIG. 6). Thereby, it can prevent that the inside of the thermal decomposition tank 2 becomes a high voltage | pressure. The superheated steam condensed by the cooler 4 to become water can be sterilized by a photocatalyst such as titanium oxide outside the thermal decomposition tank 2 and reused. Moreover, the excess superheated steam discharged | emitted from the thermal decomposition tank 2 can also be incinerated without using the cooler 4. FIG. In this case, it is preferable to incinerate before the superheated steam touches the outside air.
 また、上記実施形態において、熱分解処理装置1は、滅菌処理及び熱分解処理を行っていたがこれに限定されず、滅菌装置として単独使用することもできる。 Moreover, in the said embodiment, although the thermal decomposition processing apparatus 1 performed the sterilization process and the thermal decomposition process, it is not limited to this, It can also be used independently as a sterilization apparatus.
 また、上記実施形態において、熱分解槽2は略直方体状であったがこれに限定されず、円柱状、多角柱状等種々の形状とすることができる。 Moreover, in the said embodiment, although the pyrolysis tank 2 was substantially rectangular parallelepiped shape, it is not limited to this, It can be set as various shapes, such as column shape and polygonal column shape.
 また、上記実施形態において、攪拌器5は複数の羽根53を有した形状となっていたが、熱分解槽2内の廃プラスチックを攪拌することができればこれに限定されず、スクリュー状等種々の形状とすることができる。 Moreover, in the said embodiment, although the stirrer 5 became a shape with the some blade | wing 53, if it can stir the waste plastic in the thermal decomposition tank 2, it will not be limited to this, Various things, such as screw shape, are included. It can be a shape.
 また、上記実施形態において、熱分解処理装置1は、図7に示されるような廃プラスチック油化処理システム100に配置されていたが、これに限定されず、様々な公知の廃プラスチック油化処理システムに配置することができる。 Moreover, in the said embodiment, although the thermal decomposition processing apparatus 1 was arrange | positioned in the waste plastic oil-ized processing system 100 as shown in FIG. 7, it is not limited to this, Various well-known waste plastic oil-ized processing. Can be placed in the system.
1     熱分解処理装置
2     熱分解槽
27   扉部(排出口)
3     過熱蒸気供給管
4     冷却器(冷却手段)
5     攪拌器
9     操作盤(制御手段)
1 Pyrolysis treatment device 2 Pyrolysis tank 27 Door (discharge port)
3 Superheated steam supply pipe 4 Cooler (cooling means)
5 Stirrer 9 Operation panel (control means)

Claims (7)

  1.  廃プラスチックを熱分解するための熱分解処理装置であって、
     廃プラスチックを収容する熱分解槽と、
     前記熱分解槽内に設けられており、前記熱分解槽内の廃プラスチッ
      クを加熱する加手段と、
      前記熱分解槽内の温度を調整するために前記加熱手段の加熱量を制
      御する制御手段と、
     を備えた熱分解処理装置。
    A thermal decomposition treatment apparatus for thermally decomposing waste plastic,
    A pyrolysis tank containing waste plastic;
    A heating means provided in the pyrolysis tank and heating waste plastic in the pyrolysis tank;
    Control means for controlling the heating amount of the heating means in order to adjust the temperature in the pyrolysis tank;
    A thermal decomposition processing apparatus comprising:
  2.  前記加熱手段は、通電により自身が加熱されることで内部に供給される飽和蒸気を過熱蒸気へと変化させ、前記過熱蒸気を前記熱分解槽内に放出する、過熱蒸気供給管である、請求項1に記載の熱分解処理装置。 The heating means is a superheated steam supply pipe that changes the saturated steam supplied to the inside by being heated by energization into superheated steam and releases the superheated steam into the pyrolysis tank. Item 2. The thermal decomposition treatment apparatus according to Item 1.
  3.  前記過熱蒸気を冷却するための冷却器を前記熱分解槽の外側にさら
      に備え、
     前記冷却器は、前記熱分解槽から排出された過熱蒸気を冷却凝縮して前記熱分解槽内に戻す、請求項2に記載の熱分解処理装置。
    A cooler for cooling the superheated steam is further provided outside the pyrolysis tank;
    The thermal decomposition processing apparatus according to claim 2, wherein the cooler cools and condenses superheated steam discharged from the thermal decomposition tank and returns it to the thermal decomposition tank.
  4.  回転軸が前記熱分解槽の内側底面に平行に延び、前記熱分解槽内の廃プラスチックを攪拌するための攪拌器をさらに備える、請求項1~3のいずれかに記載の熱分解処理装置。 The thermal decomposition treatment apparatus according to any one of claims 1 to 3, further comprising a stirrer for rotating the rotating shaft parallel to an inner bottom surface of the thermal decomposition tank and stirring the waste plastic in the thermal decomposition tank.
  5.  前記熱分解槽は、廃プラスチックを排出するための排出口が形成さ
      れており、
     前記攪拌器は、前記熱分解槽内の廃プラスチックを前記排出口に向かって運搬する、請求項4に記載の熱分解処理装置。
    The pyrolysis tank is formed with a discharge port for discharging waste plastic,
    The pyrolysis apparatus according to claim 4, wherein the agitator conveys waste plastic in the pyrolysis tank toward the discharge port.
  6.  前記制御手段は、前記熱分解槽内の温度が廃プラスチックを滅菌するための第1の温度及び廃プラスチックを油化するための第2の温度となるよう、前記加熱手段の加熱量を制御する、請求項1~5に記載の熱分解処理装置。 The control means controls the heating amount of the heating means so that the temperature in the pyrolysis tank becomes a first temperature for sterilizing the waste plastic and a second temperature for oiling the waste plastic. The thermal decomposition treatment apparatus according to any one of claims 1 to 5.
  7.  前記制御手段は、前記熱分解槽内の温度が廃プラスチックを炭化するための第3の温度となるよう、前記加熱手段の加熱量を制御する、請求項6に記載の熱分解処理装置。 The thermal decomposition processing apparatus according to claim 6, wherein the control means controls the heating amount of the heating means so that the temperature in the thermal decomposition tank becomes a third temperature for carbonizing the waste plastic.
PCT/JP2011/061165 2010-07-09 2011-05-16 Waste plastic pyrolizing apparatus WO2012005055A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115011369A (en) * 2022-06-15 2022-09-06 四川正迈时代环境科技有限公司 Thermal desorption treatment method for oil-based detritus mud

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6517495B2 (en) * 2014-10-31 2019-05-22 トクデン株式会社 Oil refiner
JP2018099635A (en) * 2016-12-19 2018-06-28 株式会社Gb総合知財経営事務所 Organic waste treatment system and organic waste treatment method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002102819A (en) * 2000-09-28 2002-04-09 E & N:Kk Heat treatment method of medical waste and its apparatus
JP2004292550A (en) * 2003-03-26 2004-10-21 Hokuriku Electric Power Co Inc:The Apparatus for superheated steam type thermal decomposition
JP2005139303A (en) * 2003-11-06 2005-06-02 Nippon Kankyo Techno Kk Carbonizing treatment system for organic matter
JP2008266394A (en) * 2007-04-17 2008-11-06 Almighty:Kk Waste plastics treating system
JP2009121724A (en) * 2007-11-13 2009-06-04 Orient:Kk Superheated-steam emitting device and sterilization unit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002102819A (en) * 2000-09-28 2002-04-09 E & N:Kk Heat treatment method of medical waste and its apparatus
JP2004292550A (en) * 2003-03-26 2004-10-21 Hokuriku Electric Power Co Inc:The Apparatus for superheated steam type thermal decomposition
JP2005139303A (en) * 2003-11-06 2005-06-02 Nippon Kankyo Techno Kk Carbonizing treatment system for organic matter
JP2008266394A (en) * 2007-04-17 2008-11-06 Almighty:Kk Waste plastics treating system
JP2009121724A (en) * 2007-11-13 2009-06-04 Orient:Kk Superheated-steam emitting device and sterilization unit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115011369A (en) * 2022-06-15 2022-09-06 四川正迈时代环境科技有限公司 Thermal desorption treatment method for oil-based detritus mud

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