WO2012003611A1 - Semiconductor device and menufacturing method thereof - Google Patents
Semiconductor device and menufacturing method thereof Download PDFInfo
- Publication number
- WO2012003611A1 WO2012003611A1 PCT/CN2010/001428 CN2010001428W WO2012003611A1 WO 2012003611 A1 WO2012003611 A1 WO 2012003611A1 CN 2010001428 W CN2010001428 W CN 2010001428W WO 2012003611 A1 WO2012003611 A1 WO 2012003611A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- band gap
- gate stack
- compound semiconductor
- semiconductor substrate
- semiconductor layer
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 127
- 238000000034 method Methods 0.000 title claims abstract description 36
- 150000001875 compounds Chemical class 0.000 claims abstract description 55
- 239000000758 substrate Substances 0.000 claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 238000005530 etching Methods 0.000 claims description 18
- -1 AlGaSb Inorganic materials 0.000 claims description 13
- 238000005468 ion implantation Methods 0.000 claims description 12
- 229910000673 Indium arsenide Inorganic materials 0.000 claims description 11
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 claims description 11
- 238000002955 isolation Methods 0.000 claims description 11
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 10
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 8
- 229920005591 polysilicon Polymers 0.000 claims description 8
- 229910000577 Silicon-germanium Inorganic materials 0.000 claims description 7
- 229910017115 AlSb Inorganic materials 0.000 claims description 6
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 claims description 6
- 229910005542 GaSb Inorganic materials 0.000 claims description 6
- 229910001218 Gallium arsenide Inorganic materials 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 6
- WPYVAWXEWQSOGY-UHFFFAOYSA-N indium antimonide Chemical compound [Sb]#[In] WPYVAWXEWQSOGY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910001423 beryllium ion Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 60
- 239000000463 material Substances 0.000 description 16
- 238000001020 plasma etching Methods 0.000 description 10
- 230000005669 field effect Effects 0.000 description 8
- 150000004767 nitrides Chemical class 0.000 description 7
- 229920002120 photoresistant polymer Polymers 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 241000272522 Anas Species 0.000 description 1
- 229910004166 TaN Inorganic materials 0.000 description 1
- 229910004200 TaSiN Inorganic materials 0.000 description 1
- 229910010038 TiAl Inorganic materials 0.000 description 1
- 229910008482 TiSiN Inorganic materials 0.000 description 1
- 229910008599 TiW Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- H01L29/7783—
-
- H01L29/267—
-
- H01L29/66462—
Definitions
- the present invention relates to the field of semiconductors, and more particularly to a novel semiconductor device and a method of fabricating the same, and more particularly to a high performance III-V metal oxide semiconductor field effect transistor (MOSFET) and a method of fabricating the same.
- MOSFET metal oxide semiconductor field effect transistor
- MOSFET Metal Organic field effect transistors
- compressive stress along the channel helps to improve the performance of pFETs (p-type field effect transistors)
- tensile stress along the channel helps improve the performance of nFETs (n-type field effect transistors).
- the formation of SiGe embedded in the source/drain regions has been shown to effectively introduce compressive stresses in the channel and thereby improve the performance of the pFET.
- the formation of Si:C embedded in the source and drain has been shown to effectively introduce tensile stress in the channel and thereby improve the performance of the nFET.
- III-V compound semiconductors contribute to improved carrier mobility. Therefore, the application of III-V compound semiconductors in integrated circuit processes has been explored. However, to date, there is no effective means for applying stress in such devices made of III-V semiconductors.
- An object of the present invention is to provide a semiconductor device and a method of fabricating the same that overcome the above problems in the prior art.
- a method of fabricating a semiconductor device comprising: epitaxially growing a wide band gap III-V compound semiconductor layer/narrow band gap III-V compound semiconductor layer/wide band gap III on a bulk semiconductor substrate a stacked structure of a group V compound semiconductor layer; forming a gate stack on the stacked structure; forming an embedded strain region in the bulk semiconductor substrate; and on both sides of the gate stack, in the stack Source/drain regions are formed in the layer structure.
- the wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb; and the narrow band gap III-V compound semiconductor includes InAs, InGaAs Any one of GaAs, GaSb, InGaSb, and InSb.
- the wide band gap ⁇ -V compound semiconductor layer has a thickness of 1 to 5 nm; and the narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
- the gate stack comprises a high k gate dielectric / metal gate stack or a high k gate dielectric / metal gate / polysilicon stack.
- the gate stack comprises a gate dielectric/polysilicon gate stack, and after forming the source/drain regions, the method further comprises: removing the gate stack; forming an alternate high k gate dielectric/metal gate stack.
- the step of forming the embedded strain region comprises: forming a sacrificial strain region on both sides of the gate stack and embedding the semiconductor substrate; removing the sacrificial strain region; forming an embedded strain region.
- the step of forming the sacrificial strain region comprises: implanting As or P into the semiconductor substrate on both sides of the gate stack to form a sacrificial strain region.
- the semiconductor substrate includes shallow trench isolation for isolating adjacent devices.
- the step of removing the sacrificial strain region to form an embedded strain region includes: etching from the upper portion of the shallow trench isolation to a portion of the shallow trench isolation; selectively etching the remaining shallow trench isolation and Sacrificial strain zone; by epitaxial growth, an embedded strain zone is formed.
- the method further comprises: covering the gate stack with the dielectric layer and the top and outer sides of the remaining stacked structures on both sides.
- the narrow band gap III-V compound semiconductor layer comprises at least one layer.
- the bulk semiconductor substrate comprises Si
- the embedded strain region comprises Si:C or SiGe.
- the step of forming source/drain regions comprises: forming source/drain regions in a stacked structure on both sides of the gate stack by ion implantation; wherein for nMOSFET, implanted ions include Si or S; for pMOSFET, implanted The ions include Zn or Be.
- a semiconductor device comprising: a bulk semiconductor substrate; a stacked structure comprising a wide band gap III-V compound semiconductor layer/narrow band gap III-V compound semiconductor layer/wide band gap III a -V group compound semiconductor layer formed on the bulk semiconductor substrate; a gate stack formed on the stacked structure; an embedded strain region formed on both sides of the gate stack, embedded in the bulk semiconductor substrate And a source/drain region formed in a stacked structure on both sides of the gate stack.
- the wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb; and the narrow band gap ⁇ -V compound semiconductor package Any of InAs, InGaAs, GaAs, GaSb, InGaSb, and InSb.
- the wide band gap III-V compound semiconductor layer has a thickness of 1 to 5 nm; and the narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
- the narrow band gap III-V compound semiconductor layer comprises at least one layer.
- the bulk semiconductor substrate comprises Si
- the embedded strain region comprises Si:C or SiGe.
- the source/drain regions include Si or S ions; and for the pMOSFET, the source/drain regions include Zn or Be ions.
- stress is applied to source/drain regions formed in a III-V compound semiconductor stacked structure formed on a bulk semiconductor substrate by forming an embedded strain region in a bulk semiconductor substrate.
- stress is effectively applied to the ⁇ -type compound semiconductor device to improve its performance without adversely affecting its structure.
- 1 to 12 are schematic cross-sectional views showing stages of a semiconductor device according to a first embodiment of the present invention during fabrication
- 13 to 26 are schematic cross-sectional views showing stages of a semiconductor device in accordance with a second embodiment of the present invention during fabrication. detailed description
- FIG. 1 A schematic diagram of a layer structure in accordance with an embodiment of the present invention is shown in the accompanying drawings.
- the figures are not drawn to scale, and some details are exaggerated for clarity and some details may be omitted.
- the various regions, the shapes of the layers, and the relative sizes and positional relationships between the figures are merely exemplary, and may vary in practice due to manufacturing tolerances or technical limitations, and those skilled in the art will It is desirable to additionally design regions/layers having different shapes, sizes, relative positions. (First Embodiment)
- a first embodiment of the present invention will be described below with reference to Figs.
- the manufacturing process according to the present invention starts from a bulk wafer such as a bulk Si wafer. Specifically, a stacked structure of a wide band gap III-V compound semiconductor material and a narrow band gap III-V compound semiconductor material is epitaxially grown on a bulk wafer, i.e., a semiconductor substrate 1001.
- a bulk wafer i.e., a semiconductor substrate 1001.
- the following structure can be grown: two layers of wide band gap semiconductor material such as InAlAs 1002 and 1004, and a layer of narrow band gap material sandwiched between them, such as InAs or InGaAs 1003.
- the narrow band gap material layer can include at least one layer.
- the wide band gap material layers such as InAlAs 1002 and 1004 may have a thickness of about 1 to 5 nm, and the narrow band gap material layers such as InAs or InGaAs 1003 may have a thickness of about 5 to 20 nm.
- Such epitaxial growth can be carried out, for example, by techniques such as molecular beam epitaxy (MBE).
- MBE molecular beam epitaxy
- the wide band gap III-V compound semiconductor may include InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, Any one of InAlSb; and the narrow band gap III-V compound semiconductor may include any one of InAs, InGaAs, GaAs, GaSb, InGaSb, InSb.
- a preferred combination may include any one or combination of the following: a wide band gap III-V compound semiconductor may be InAlAs or InP, a narrow band gap III-V compound semiconductor may be InAs or InGaAs; or a wide band gap III-V compound
- the semiconductor may be AlGaAs or InGaP, the narrow band gap III-V compound semiconductor may be GaAs; or the wide band gap III-V compound semiconductor may be InAlSb, AlSb or AlGaSb, and the narrow band gap III-V compound semiconductor may be GaSb, AnAs or InSb.
- the stacked structure and the semiconductor substrate 1001 are embedded to form a shallow trench isolation (STI) 1005 to isolate the individual devices. region.
- STI shallow trench isolation
- Such an STI structure can be formed, for example, from SiO 2 .
- a gate stack is formed on the substrate subjected to the above processing.
- a high-k gate dielectric/metal gate stack can be employed. Specifically, first, as shown in FIG. 3, a high-k gate dielectric layer 1006 and a metal layer 1007 are sequentially deposited on the structure shown in FIG.
- the high-k gate dielectric layer 1006 can be ⁇ 2 and the metal 1007 can be tungsten (W).
- the high-k gate dielectric layer 1006 may have a thickness of about 2 to 4 nm, and the metal layer 1007 may have a thickness of about 50 to 150 nm.
- the metal layer 1007 is patterned to form a gate stack.
- a photoresist 1008 is coated on the metal layer 1007 and then exposed through a mask to pattern the photoresist 1008 into a desired gate stack shape. Subsequently, the metal layer 1007 is etched (eg, reactive ion etching RIE) to form a corresponding gate stack. After etching, the photoresist 1008 is removed.
- the structure of the gate stack may also be composed of a high-k dielectric material/metal/polysilicon stack or a gate dielectric layer/conductive material/polysilicon stack, or a combination of other combinations, which is not limited in the present invention.
- the high-k gate dielectric 1006 is preferably not simultaneously etched to protect the underlying stacked structure.
- the present invention is not limited to this.
- the high-k gate dielectric layer 1006 can also be etched simultaneously such that it forms a final gate stack with the metal layer 1007.
- side walls 1009 are formed on both sides of the formed gate stack.
- the side wall 1009 can include a nitride.
- the spacers 1009 are formed, for example, by depositing a layer of nitride and selectively etching the layer nitride (e.g., RIE) so that the nitride remains only on the side of the gate stack.
- an embedded strain region may be formed in the semiconductor substrate 1001 to apply stress to the subsequently formed source/drain regions.
- a sacrificial strain region can be formed first in the semiconductor substrate, and then the sacrificial strain region can be replaced to form a final embedded strain region.
- ion implantation is performed using, for example, As or P plasma.
- the energy of the ion implantation is controlled so that the implanted ions can enter the semiconductor substrate 1001 under the stacked structure on both sides of the gate stack.
- heat treatment may optionally be performed, for example, annealing at a temperature of about 800-900 ° C to activate the implanted As or P ions to form the sacrificial strain region 1010.
- This ion implantation is similar to the source/drain ion implantation process in conventional CMOS processes and will not be described here.
- the implanted group III or V element ions such as As or P
- the ion implantation has little effect on the laminated structure (e.g., InAlAs/InAs).
- the sacrificial strain zone can be "replaced" to enable the stressed strain zone to be replaced by the embedded strain zone with stress to achieve the stress structure.
- the high-k gate dielectric layer 1006 can be sequentially applied (if the high-k gate dielectric 1006 has been etched together when the metal 1007 is etched, it is not required here) and the STI 1005 is performed. Selective etching (eg, RIE). Specifically, the high-k gate dielectric 1006 is selectively etched to remain only under the gate stack and the sidewall spacers; in addition, the STI 1005 is selectively etched such that a portion of the sidewall of the semiconductor substrate 1001 is exposed ( In the present embodiment, a portion of the sacrificial strain region 1010 is exposed.
- RIE reactive etching
- an etch protection layer e.g., nitride
- the etch protection layer 1011 covers the gate stack and the top and sidewalls of the stacked structure.
- the STI 1005 is further selectively etched (eg, RIE) to substantially remove the STI 1005 to fully expose the sacrificial strain region 1010.
- the sacrificial strain region 1010 is selectively etched to substantially remove the sacrificial strain region 1010.
- This selective etching can be achieved by the difference in the impurity concentration, for example, by an etchant such as KOH, TMAH, EDP, ⁇ 2 ⁇ 4 ⁇ ⁇ 2 0 .
- the formation of the embedded strain zone can be performed. Specifically, as shown in Fig. 11, in the cavity formed in the semiconductor substrate 1001 by removing the sacrificial strain region 1010, the embedded strain region 1012 is formed by selective epitaxial growth.
- the lattice structure of the embedded strain region 1012 is different from the lattice structure of the semiconductor substrate 1001 (for example, Si), thereby generating a certain stress, and the stress can be transmitted to the laminated structure, especially the narrow band gap material.
- the embedded strain region 1012 can be Si:C to generate tensile stress; and for a pFET (p-type field effect transistor), the embedded strain region 1012 can be SiGe for Produces compressive stress.
- the embedded strain zone is formed in the above manner. It should be noted that those skilled in the art can design other ways to form such an embedded strain zone without departing from the scope of the invention.
- An important feature of the present invention is to form an embedded strain region in a bulk semiconductor substrate to apply stress to source/drain regions formed in a III-V compound semiconductor stacked structure formed on a bulk semiconductor substrate, rather than embedding The specific formation of the strain zone.
- the source may be formed on both sides of the gate stack, such as in the III-V compound semiconductor stacked structure (particularly in the narrow band gap material layer 1003), for example by ion implantation or the like. / Drain area (not shown).
- Si or S can be used for ion implantation
- pFETs Zn or Be can be used for ion implantation.
- the semiconductor device includes: a bulk semiconductor substrate 1001; a stacked structure (1002, 1003, 1004) formed on the bulk semiconductor substrate 1001, including a wide band gap III-V compound semiconductor layer (1002) / narrow band gap III-V compound semiconductor layer (1003) / wide band gap III-V compound semiconductor layer (1004); gate stack formed on the stacked structure (1006, 1007); on both sides of the gate stack, in the semiconductor An embedded strain region (1012) embedded in the substrate 1001; and a source/drain region formed in the stacked structure (1002, 1003, 1004).
- a coating layer 1013 such as an oxide may be formed on the device structure formed as described above.
- the oxide is simultaneously deposited in the STI trench to form the STI again.
- a contact portion 1014 that is in contact with the source/drain regions may be formed.
- the contact portion 1014 is formed, for example, by etching a contact hole, then forming a liner in the contact hole, and finally filling the metal plug. Since the top has a coating 1013, and there is still a width The bandgap semiconductor material layer 1004, therefore the contact holes should penetrate deep into the narrow bandgap semiconductor material layer 1003 to form a good contact.
- the material of the liner may be formed of any one or more of the following: TaN, TiN, Ta, Ti, TiSiN, TaSiN, TiW, WN or Ru.
- the material of the metal plug may be: W, Al, Cu or TiAl.
- the method of forming the source/drain regions is not limited to the above-described manner of ion implantation.
- the cladding is removed over the stacked structures on both sides of the gate stack and a metal layer is formed.
- a preferred metal material is TaN.
- the source/drain regions can also be realized by the metal-semiconductor junction formed by the metal in contact with the underlying semiconductor, thus forming a Schottky barrier.
- the method of the present invention can also be compatible with replacement gate processes.
- a second embodiment of the present invention will be described with reference to Figs. 13 to 26, in which a replacement gate process is incorporated.
- differences between the second embodiment and the first embodiment will be mainly described; for steps not described in detail, reference may be made to the description of the corresponding steps in the above first embodiment.
- Like reference numerals in the drawings denote like parts.
- a stacked structure is formed on a semiconductor substrate 2001, for example, epitaxially grown InAlAs 2002, InAs/InGaAs 2003 > InAlAs2004.
- the composition of the laminated structure can be referred to the description of the previous embodiment.
- InAlAs 2002 and 2004 may have a thickness of about 1 to 5 nm
- InAs or InGaAs 2003 may have a thickness of about 5 to 20 nm.
- STI 2005 can be formed as shown in FIG.
- a sacrificial gate stack is formed on the substrate subjected to the above processing.
- a sacrificial gate dielectric 2006 and a sacrificial gate body 2007 are sequentially deposited on the structure shown in FIG.
- the sacrificial gate dielectric 2006 may be Si0 2 and the sacrificial gate body 2007 may be polysilicon.
- the thickness of the sacrificial gate dielectric 2006 may be about 2 to 4 nm, and the thickness of the sacrificial gate body 2007 may be about 50 to 150 nm.
- the sacrificial gate body 2007 is patterned to form a sacrificial gate stack.
- the photoresist 2008 is patterned, for example, on the sacrificial gate body 2007, and then exposed through a mask to form the desired gate stack shape. Subsequently, the sacrificial gate body 2007 is etched (eg, RIE) to form a corresponding gate stack. After the etching, the photoresist 2008 is removed.
- RIE etching
- sidewalls 2009 e.g., nitride
- ion implantation of the sacrificial strain region is performed as shown in Fig. 18, and annealing treatment is performed to activate the implanted ions (e.g., As or P), thereby forming a sacrificial strain region 2010, as shown in Fig. 19.
- implanted ions e.g., As or P
- the sacrificial strain zone 2010 is subjected to a replacement process to form an embedded strain zone.
- the sacrificial gate dielectric 2006 is selectively etched (eg, RIE) to remain only under the gate stack and the sidewall spacers; in addition, the STI 2005 is selectively etched (eg, RIE) to expose A portion of the sidewall of the semiconductor substrate 2001 (in this embodiment, a portion of the sacrificial strain region 2010 is exposed).
- an etch protection layer 2011 is formed to cover the gate stack and the stacked structure.
- the embedded strain region 2012 is formed by selective epitaxial growth.
- the embedded strain region 2012 can be Si:C to generate tensile stress; and for a pFET (p-type field effect transistor), the embedded strain region 2012 can be SiGe for Produces compressive stress.
- an interlayer dielectric layer 2013 (for example, SiO 2 ) is deposited on the structure shown in FIG. 23 and planarized until reaching the etch protection layer 2011.
- replacement gate processing is performed. Specifically, the etch protection layer 2011 on top of the sacrificial gate stack is removed by selective etching (eg, RIE). Then, the sacrificial gate body 2007 is further removed by selective etching (eg, RIE); the sacrificial gate dielectric 2006 may serve as an etch stop layer during the etching process.
- a high-k gate dielectric 2014 for example, HfO 2
- a metal layer 2015 for example, W
- the gate stack may also include a high-k gate dielectric/metal gate/polysilicon stack. .
- the replacement gate treatment is preferably performed after the source/drain regions are formed in the stacked structure to avoid the process of forming the source/drain regions from affecting the gate performance.
- a coating 2016, such as a nitride is formed on the device structure formed as described above.
- a contact portion 2017 that is in contact with the source/drain regions can be formed.
- the contact portion 2017 is formed, for example, by etching a contact hole and then filling a metal such as W.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
A semiconductor device and a manufacturing method thereof are provided. The method includes that: epitaxially growing a stack structure comprised of wide band-gap III-V group compound semiconductor layer (1002)/ narrow band-gap III-V group compound semiconductor layer (1003)/ wide band-gap III-V group compound semiconductor layer (1004) on a body semiconductor substrate (1001); forming a gate stack on the stack structure; forming embedded strain zones in the body semiconductor substrate; forming source/drain regions on both sides of the gate stack and in the stack structure.
Description
半导体器件及其制作方法 Semiconductor device and manufacturing method thereof
技术领域 Technical field
本发明涉及半导体领域, 更具体地, 涉及一种新颖的半导体器件及其制作方法, 特别是一种高性能 III-V族金属氧化物半导体场效应晶体管 (MOSFET) 及其制作方 法。 背景技术 The present invention relates to the field of semiconductors, and more particularly to a novel semiconductor device and a method of fabricating the same, and more particularly to a high performance III-V metal oxide semiconductor field effect transistor (MOSFET) and a method of fabricating the same. Background technique
已经证实, 沟道中的应变可以显著影响金属氧化物半导体场效应晶体管 It has been confirmed that the strain in the channel can significantly affect the metal oxide semiconductor field effect transistor
(MOSFET) 中载流子的迁移率。 例如, 沿沟道的压缩应力有助于改善 pFET (p型场 效应晶体管)的性能, 而沿沟道的拉伸应力有助于改善 nFET (n型场效应晶体管) 的 性能。 The mobility of carriers in (MOSFET). For example, compressive stress along the channel helps to improve the performance of pFETs (p-type field effect transistors), while tensile stress along the channel helps improve the performance of nFETs (n-type field effect transistors).
对于 pFET,形成嵌入在源 /漏区中的 SiGe已经被证明能够在沟道中有效引入压缩 应力并从而提高 pFET的性能。 类似地, 对于 nFET, 形成嵌入在源和漏中的 Si:C已 经被证明能够在沟道中有效引入拉伸应力并从而提高 nFET的性能。 For pFETs, the formation of SiGe embedded in the source/drain regions has been shown to effectively introduce compressive stresses in the channel and thereby improve the performance of the pFET. Similarly, for nFETs, the formation of Si:C embedded in the source and drain has been shown to effectively introduce tensile stress in the channel and thereby improve the performance of the nFET.
已经发现, III-V族化合物半导体有助于改进载流子迁移率。 因此, 目前已经在探 索 III-V族化合物半导体在集成电路工艺中的应用。 但是, 迄今为止, 尚没有有效的 手段来在这种通过 III-V族半导体制成的器件中施加应力。 It has been found that III-V compound semiconductors contribute to improved carrier mobility. Therefore, the application of III-V compound semiconductors in integrated circuit processes has been explored. However, to date, there is no effective means for applying stress in such devices made of III-V semiconductors.
有鉴于此, 需要提供一种新颖的半导体器件及其制作方法, 特别是一种 III-V族 In view of the above, there is a need to provide a novel semiconductor device and a method of fabricating the same, and more particularly to a III-V family.
MOSFET及其制作方法, 其中可以有效地向其沟道区施加应力, 从而改进其性能。 发明内容 A MOSFET and a method of fabricating the same, in which stress can be effectively applied to a channel region thereof to improve its performance. Summary of the invention
本发明的目的在于提供一种半导体器件及其制作方法, 以克服上述现有技术中的 问题。 SUMMARY OF THE INVENTION An object of the present invention is to provide a semiconductor device and a method of fabricating the same that overcome the above problems in the prior art.
根据本发明的一个方面, 提供了一种制作半导体器件的方法, 包括: 在体半导体 衬底上外延生长宽带隙 III-V族化合物半导体层 /窄带隙 III-V族化合物半导体层 /宽带 隙 III-V族化合物半导体层的叠层结构; 在所述叠层结构上形成栅堆叠; 在所述体半 导体衬底中形成嵌入式应变区; 以及在所述栅堆叠的两侧、 在所述叠层结构中形成源 /漏区。
优选地, 所述宽带隙 III-V族化合物半导体包括 InAlAs、 InP、 AlSb、 AlGaSb、 GaP、 InGaP、 AlGaAs、 InAlSb中的任一种; 以及所述窄带隙 III-V族化合物半导体包 括 InAs、 InGaAs、 GaAs、 GaSb、 InGaSb、 InSb中的任一种。 According to an aspect of the invention, a method of fabricating a semiconductor device is provided, comprising: epitaxially growing a wide band gap III-V compound semiconductor layer/narrow band gap III-V compound semiconductor layer/wide band gap III on a bulk semiconductor substrate a stacked structure of a group V compound semiconductor layer; forming a gate stack on the stacked structure; forming an embedded strain region in the bulk semiconductor substrate; and on both sides of the gate stack, in the stack Source/drain regions are formed in the layer structure. Preferably, the wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb; and the narrow band gap III-V compound semiconductor includes InAs, InGaAs Any one of GaAs, GaSb, InGaSb, and InSb.
优选地,所述宽带隙 ΙΠ-V族化合物半导体层的厚度为 l〜5nm;所述窄带隙 III-V 族化合物半导体层的厚度为 5〜20nm。 Preferably, the wide band gap ΙΠ-V compound semiconductor layer has a thickness of 1 to 5 nm; and the narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
优选地, 所述栅堆叠包括高 k栅介质 /金属栅堆叠或高 k栅介质 /金属栅 /多晶硅堆 叠。 Preferably, the gate stack comprises a high k gate dielectric / metal gate stack or a high k gate dielectric / metal gate / polysilicon stack.
优选地, 所述栅堆叠包括栅介质 /多晶硅栅堆叠, 在形成源 /漏区之后, 该方法进 一步包括: 去除所述栅堆叠; 形成替代的高 k栅介质 /金属栅堆叠。 Preferably, the gate stack comprises a gate dielectric/polysilicon gate stack, and after forming the source/drain regions, the method further comprises: removing the gate stack; forming an alternate high k gate dielectric/metal gate stack.
优选地, 形成嵌入式应变区的步骤包括: 在所述栅堆叠的两侧且嵌入所述半导体 衬底形成牺牲应变区; 去除所述牺牲应变区; 形成嵌入式应变区。 其中, 形成牺牲应 变区的步骤包括:在所述栅堆叠的两侧向所述半导体衬底注入 As或 P, 以形成牺牲应 变区。 Preferably, the step of forming the embedded strain region comprises: forming a sacrificial strain region on both sides of the gate stack and embedding the semiconductor substrate; removing the sacrificial strain region; forming an embedded strain region. Wherein the step of forming the sacrificial strain region comprises: implanting As or P into the semiconductor substrate on both sides of the gate stack to form a sacrificial strain region.
优选地, 所述半导体衬底上包括浅沟槽隔离用于隔离相邻的器件。 从而, 去除所 述牺牲应变区, 形成嵌入式应变区的步骤包括: 从所述浅沟槽隔离的上方向下刻蚀至 部分浅沟槽隔离露出;选择性刻蚀余下的浅沟槽隔离以及牺牲应变区;通过外延生长, 形成嵌入式应变区。 进一步优选地, 在选择性刻蚀余下的浅沟槽隔离之前, 所述方法 进一步包括: 采用介质层覆盖所述栅堆叠以及两侧余下的叠层结构顶部和外侧。 Preferably, the semiconductor substrate includes shallow trench isolation for isolating adjacent devices. Thus, the step of removing the sacrificial strain region to form an embedded strain region includes: etching from the upper portion of the shallow trench isolation to a portion of the shallow trench isolation; selectively etching the remaining shallow trench isolation and Sacrificial strain zone; by epitaxial growth, an embedded strain zone is formed. Further preferably, before selectively etching the remaining shallow trench isolation, the method further comprises: covering the gate stack with the dielectric layer and the top and outer sides of the remaining stacked structures on both sides.
优选地, 所述窄带隙 III-V族化合物半导体层包括至少一层。 Preferably, the narrow band gap III-V compound semiconductor layer comprises at least one layer.
优选地, 所述体半导体衬底包括 Si, 所述嵌入式应变区包括 Si:C或 SiGe。 Preferably, the bulk semiconductor substrate comprises Si, and the embedded strain region comprises Si:C or SiGe.
优选地, 形成源 /漏区的步骤包括: 通过离子注入在所述栅堆叠两侧的叠层结构中 形成源 /漏区; 其中对于 nMOSFET, 注入的离子包括 Si或 S; 对于 pMOSFET, 注入 的离子包括 Zn或 Be。 Preferably, the step of forming source/drain regions comprises: forming source/drain regions in a stacked structure on both sides of the gate stack by ion implantation; wherein for nMOSFET, implanted ions include Si or S; for pMOSFET, implanted The ions include Zn or Be.
根据本发明的另一方面, 提供了一种半导体器件, 包括: 体半导体衬底; 叠层结 构, 包括宽带隙 III-V族化合物半导体层 /窄带隙 III-V族化合物半导体层 /宽带隙 III-V 族化合物半导体层, 形成在所述体半导体衬底上; 栅堆叠, 形成在所述叠层结构上; 嵌入式应变区, 形成在所述栅堆叠两侧, 嵌入所述体半导体衬底中; 以及源 /漏区, 形 成在所述栅堆叠两侧的叠层结构中。 According to another aspect of the present invention, there is provided a semiconductor device comprising: a bulk semiconductor substrate; a stacked structure comprising a wide band gap III-V compound semiconductor layer/narrow band gap III-V compound semiconductor layer/wide band gap III a -V group compound semiconductor layer formed on the bulk semiconductor substrate; a gate stack formed on the stacked structure; an embedded strain region formed on both sides of the gate stack, embedded in the bulk semiconductor substrate And a source/drain region formed in a stacked structure on both sides of the gate stack.
优选地, 所述宽带隙 III-V族化合物半导体包括 InAlAs、 InP、 AlSb、 AlGaSb、 GaP、 InGaP、 AlGaAs、 InAlSb中的任一种; 以及所述窄带隙 ΙΠ-V族化合物半导体包
括 InAs、 InGaAs、 GaAs、 GaSb、 InGaSb、 InSb中的任一种。 Preferably, the wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb; and the narrow band gap ΙΠ-V compound semiconductor package Any of InAs, InGaAs, GaAs, GaSb, InGaSb, and InSb.
优选地,所述宽带隙 III-V族化合物半导体层的厚度为 l〜5nm;所述窄带隙 III-V 族化合物半导体层的厚度为 5〜20nm。 Preferably, the wide band gap III-V compound semiconductor layer has a thickness of 1 to 5 nm; and the narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
优选地, 所述窄带隙 III-V族化合物半导体层包括至少一层。 Preferably, the narrow band gap III-V compound semiconductor layer comprises at least one layer.
优选地, 所述体半导体衬底包括 Si, 所述嵌入式应变区包括 Si:C或 SiGe。 Preferably, the bulk semiconductor substrate comprises Si, and the embedded strain region comprises Si:C or SiGe.
优选地, 对于 nMOSFET, 所述源 /漏区中包括 Si或 S离子; 对于 pMOSFET, 所 述源 /漏区中包括 Zn或 Be离子。 Preferably, for the nMOSFET, the source/drain regions include Si or S ions; and for the pMOSFET, the source/drain regions include Zn or Be ions.
根据本发明的实施例, 通过在体半导体衬底中形成嵌入式应变区, 向体半导体衬 底上形成的 III-V族化合物半导体叠层结构中形成的源 /漏区施加应力。 从而有效地向 ιιι-ν族化合物半导体器件施加应力以改善其性能, 而不会对其结构造成不利影响。 附图说明 According to an embodiment of the present invention, stress is applied to source/drain regions formed in a III-V compound semiconductor stacked structure formed on a bulk semiconductor substrate by forming an embedded strain region in a bulk semiconductor substrate. Thereby, stress is effectively applied to the ι-type compound semiconductor device to improve its performance without adversely affecting its structure. DRAWINGS
通过以下参照附图对本发明实施例的描述, 本发明的上述以及其他目的、 特征和 优点将更为清楚, 在附图中: The above and other objects, features and advantages of the present invention will become more apparent from
图 1〜12示出了根据本发明第一实施例的半导体器件在制造期间各阶段的示意截 面图; 以及 1 to 12 are schematic cross-sectional views showing stages of a semiconductor device according to a first embodiment of the present invention during fabrication;
图 13〜26示出了根据本发明第二实施例的半导体器件在制造期间各阶段的示意 截面图。 具体实施方式 13 to 26 are schematic cross-sectional views showing stages of a semiconductor device in accordance with a second embodiment of the present invention during fabrication. detailed description
以下, 通过附图中示出的具体实施例来描述本发明。 但是应该理解, 这些描述只 是示例性的, 而并非要限制本发明的范围。 此外, 在以下说明中, 省略了对公知结构 和技术的描述, 以避免不必要地混淆本发明的概念。 Hereinafter, the present invention will be described by way of specific embodiments shown in the drawings. However, it is to be understood that the description is not intended to limit the scope of the invention. In addition, descriptions of well-known structures and techniques are omitted in the following description in order to avoid unnecessarily obscuring the inventive concept.
在附图中示出了根据本发明实施例的层结构示意图。 这些图并非是按比例绘制 的, 其中为了清楚的目的, 放大了某些细节, 并且可能省略了某些细节。 图中所示出 的各种区域、 层的形状以及它们之间的相对大小、 位置关系仅是示例性的, 实际中可 能由于制造公差或技术限制而有所偏差, 并且本领域技术人员根据实际所需可以另外 设计具有不同形状、 大小、 相对位置的区域 /层。 (第一实施例)
以下将参照附图 1〜12来描述本发明的第一实施例。 A schematic diagram of a layer structure in accordance with an embodiment of the present invention is shown in the accompanying drawings. The figures are not drawn to scale, and some details are exaggerated for clarity and some details may be omitted. The various regions, the shapes of the layers, and the relative sizes and positional relationships between the figures are merely exemplary, and may vary in practice due to manufacturing tolerances or technical limitations, and those skilled in the art will It is desirable to additionally design regions/layers having different shapes, sizes, relative positions. (First Embodiment) A first embodiment of the present invention will be described below with reference to Figs.
如图 1所示, 根据本发明的制造工艺从体晶片如体 Si晶片开始。具体地, 在体晶片 即半导体衬底 1001上外延生长宽带隙 III-V族化合物半导体材料与窄带隙 III-V族化合 物半导体材料的叠层结构。 例如, 可以生长如下结构: 两层宽带隙半导体材料层如 InAlAs 1002和 1004, 以及夹在它们之间的一层窄带隙材料层如 InAs或 InGaAs 1003。 窄带隙材料层可以包括至少一层。例如, 宽带隙材料层如 InAlAs 1002和 1004的厚度可 以为约 l〜5nm, 窄带隙材料层如 InAs或 InGaAs 1003的厚度可以为约 5〜20nm。这种外 延生长例如可以通过分子束外延 (MBE) 等技术来进行。 As shown in Fig. 1, the manufacturing process according to the present invention starts from a bulk wafer such as a bulk Si wafer. Specifically, a stacked structure of a wide band gap III-V compound semiconductor material and a narrow band gap III-V compound semiconductor material is epitaxially grown on a bulk wafer, i.e., a semiconductor substrate 1001. For example, the following structure can be grown: two layers of wide band gap semiconductor material such as InAlAs 1002 and 1004, and a layer of narrow band gap material sandwiched between them, such as InAs or InGaAs 1003. The narrow band gap material layer can include at least one layer. For example, the wide band gap material layers such as InAlAs 1002 and 1004 may have a thickness of about 1 to 5 nm, and the narrow band gap material layers such as InAs or InGaAs 1003 may have a thickness of about 5 to 20 nm. Such epitaxial growth can be carried out, for example, by techniques such as molecular beam epitaxy (MBE).
当然,在此也可以采用其他宽 /窄带隙 III-V族化合物半导体材料层的组合, 例如所 述宽带隙 III-V族化合物半导体可以包括 InAlAs、 InP、 AlSb、 AlGaSb、 GaP、 InGaP、 AlGaAs、 InAlSb中的任一种; 以及所述窄带隙 III-V族化合物半导体可以包括 InAs、 InGaAs、 GaAs、 GaSb、 InGaSb、 InSb中的任一种。 Of course, combinations of other wide/narrow band gap III-V compound semiconductor material layers may also be used herein. For example, the wide band gap III-V compound semiconductor may include InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, Any one of InAlSb; and the narrow band gap III-V compound semiconductor may include any one of InAs, InGaAs, GaAs, GaSb, InGaSb, InSb.
优选的组合可以包括以下的任一组或其他组合: 宽带隙 III- V族化合物半导体可以 为 InAlAs或 InP, 窄带隙 III-V族化合物半导体可以为 InAs或 InGaAs; 或者宽带隙 III-V 族化合物半导体可以为 AlGaAs或 InGaP, 窄带隙 III-V族化合物半导体可以为 GaAs; 或 者宽带隙 III-V族化合物半导体可以为 InAlSb、 AlSb或 AlGaSb, 窄带隙 III-V族化合物半 导体可以为 GaSb、 AnAs或 InSb。 A preferred combination may include any one or combination of the following: a wide band gap III-V compound semiconductor may be InAlAs or InP, a narrow band gap III-V compound semiconductor may be InAs or InGaAs; or a wide band gap III-V compound The semiconductor may be AlGaAs or InGaP, the narrow band gap III-V compound semiconductor may be GaAs; or the wide band gap III-V compound semiconductor may be InAlSb, AlSb or AlGaSb, and the narrow band gap III-V compound semiconductor may be GaSb, AnAs or InSb.
如图 2所示, 优选地, 在半导体衬底 1001包括以上形成的叠层结构中, 嵌入所述 叠层结构和半导体衬底 1001形成浅沟槽隔离 (STI) 1005, 以隔离各单独的器件区域。 这种 STI结构例如可以由 Si02形成。 As shown in FIG. 2, preferably, in the stacked structure in which the semiconductor substrate 1001 includes the above, the stacked structure and the semiconductor substrate 1001 are embedded to form a shallow trench isolation (STI) 1005 to isolate the individual devices. region. Such an STI structure can be formed, for example, from SiO 2 .
接下来, 在经过如上处理的衬底上形成栅堆叠。 在本发明中, 例如可以采用高 k 栅介质 /金属栅堆叠。 具体地, 首先如图 3所示, 在图 2所示的结构上依次淀积高 k栅介 质层 1006和金属层 1007。例如,高 k栅介质层 1006可以为 ΗίΌ2,金属 1007可以为钨(W)。 在此, 高 k栅介质层 1006的厚度可以为约 2〜4nm, 金属层 1007的厚度可以为约 50〜 150nm。 然后, 如图 4所示, 对金属层 1007进行构图, 以形成栅堆叠。 具体地, 例如在 金属层 1007上涂覆光刻胶 1008, 然后通过掩模曝光, 将光刻胶 1008构图为所需的栅堆 叠形状。 随后, 对金属层 1007进行刻蚀 (例如, 反应离子刻蚀 RIE), 形成相应的栅堆 叠。 在刻蚀之后, 去除光刻胶 1008。 栅堆叠的结构还可以由高 k介质材料 /金属 /多晶硅 叠层或栅介质层 /导电材料 /多晶硅叠层, 或者是其他组合的叠层构成, 本发明对此不 做限制。
在此, 需要注意的是, 在该步骤中, 优选地并没有同时刻蚀高 k栅介质 1006, 以 便保护其下的叠层结构。 但是, 本发明并不局限于此。 也可同时对高 k栅介质层 1006 进行刻蚀, 从而其与金属层 1007—起形成最终的栅堆叠。 Next, a gate stack is formed on the substrate subjected to the above processing. In the present invention, for example, a high-k gate dielectric/metal gate stack can be employed. Specifically, first, as shown in FIG. 3, a high-k gate dielectric layer 1006 and a metal layer 1007 are sequentially deposited on the structure shown in FIG. For example, the high-k gate dielectric layer 1006 can be ΗίΌ 2 and the metal 1007 can be tungsten (W). Here, the high-k gate dielectric layer 1006 may have a thickness of about 2 to 4 nm, and the metal layer 1007 may have a thickness of about 50 to 150 nm. Then, as shown in FIG. 4, the metal layer 1007 is patterned to form a gate stack. Specifically, for example, a photoresist 1008 is coated on the metal layer 1007 and then exposed through a mask to pattern the photoresist 1008 into a desired gate stack shape. Subsequently, the metal layer 1007 is etched (eg, reactive ion etching RIE) to form a corresponding gate stack. After etching, the photoresist 1008 is removed. The structure of the gate stack may also be composed of a high-k dielectric material/metal/polysilicon stack or a gate dielectric layer/conductive material/polysilicon stack, or a combination of other combinations, which is not limited in the present invention. Here, it should be noted that in this step, the high-k gate dielectric 1006 is preferably not simultaneously etched to protect the underlying stacked structure. However, the present invention is not limited to this. The high-k gate dielectric layer 1006 can also be etched simultaneously such that it forms a final gate stack with the metal layer 1007.
接着, 如图 5所示, 在形成的栅堆叠两侧形成侧墙 1009。 例如, 侧墙 1009可以包 括氮化物。 具体地, 例如通过淀积一层氮化物并对该层氮化物进行选择性刻蚀 (如 RIE), 使得氮化物仅留在栅堆叠的侧面, 从而形成侧墙 1009。 Next, as shown in Fig. 5, side walls 1009 are formed on both sides of the formed gate stack. For example, the side wall 1009 can include a nitride. Specifically, the spacers 1009 are formed, for example, by depositing a layer of nitride and selectively etching the layer nitride (e.g., RIE) so that the nitride remains only on the side of the gate stack.
在如上所述形成了栅堆叠及侧墙之后, 可以在半导体衬底 1001中形成嵌入式应变 区, 以便向随后形成的源 /漏区施加应力。 为了形成这种嵌入式应变区, 在此例如可以 首先在半导体衬底中形成牺牲应变区, 然后通过替换这种牺牲应变区, 来形成最终的 嵌入式应变区。 After the gate stack and the spacers are formed as described above, an embedded strain region may be formed in the semiconductor substrate 1001 to apply stress to the subsequently formed source/drain regions. In order to form such an embedded strain region, for example, a sacrificial strain region can be formed first in the semiconductor substrate, and then the sacrificial strain region can be replaced to form a final embedded strain region.
具体地, 如图 6所示, 例如使用 As或 P等离子, 进行离子注入。 控制离子注入的能 量,使得注入的离子能够进入到栅堆叠两侧叠层结构之下的半导体衬底 1001中。然后, 如图 7所示, 可选地可以进行热处理, 例如在约 800-900°C的温度下进行退火, 以激活 所注入的 As或 P离子, 从而形成牺牲应变区 1010。 这种离子注入类似于常规 CMOS工 艺中源 /漏的离子注入工艺, 这里不多加描述。 在此, 由于注入的也是 III或 V族元素离 子 (如 As或 P), 从而这种离子注入对于叠层结构 (如 InAlAs/InAs) 的影响很小。 Specifically, as shown in Fig. 6, ion implantation is performed using, for example, As or P plasma. The energy of the ion implantation is controlled so that the implanted ions can enter the semiconductor substrate 1001 under the stacked structure on both sides of the gate stack. Then, as shown in Fig. 7, heat treatment may optionally be performed, for example, annealing at a temperature of about 800-900 ° C to activate the implanted As or P ions to form the sacrificial strain region 1010. This ion implantation is similar to the source/drain ion implantation process in conventional CMOS processes and will not be described here. Here, since the implanted group III or V element ions (such as As or P), the ion implantation has little effect on the laminated structure (e.g., InAlAs/InAs).
在如上所述形成牺牲应变区之后, 可以对牺牲应变区进行 "替换"处理, 以能够 采用具有应力的嵌入式应变区来代替牺牲应变区, 从而实现应力结构。 After the sacrificial strain zone is formed as described above, the sacrificial strain zone can be "replaced" to enable the stressed strain zone to be replaced by the embedded strain zone with stress to achieve the stress structure.
为此, 首先需要将牺牲应变区部分露出, 并从而将其去除。 因此, 可以如图 8所 示, 依次对高 k栅介质层 1006 (如果以上在对金属 1007刻蚀时已经一起对高 k栅介质 1006进行了刻蚀, 则在此不需要) 以及 STI 1005进行选择性刻蚀 (例如, RIE)。 具体 地, 对高 k栅介质 1006进行选择性刻蚀, 使其仅留在栅堆叠以及侧墙之下; 另外, 对 STI 1005进行选择性刻蚀, 使得露出半导体衬底 1001的一部分侧壁 (在本实施例中, 露出牺牲应变区 1010的一部分)。 To do this, it is first necessary to expose the sacrificial strain zone portion and thereby remove it. Therefore, as shown in FIG. 8, the high-k gate dielectric layer 1006 can be sequentially applied (if the high-k gate dielectric 1006 has been etched together when the metal 1007 is etched, it is not required here) and the STI 1005 is performed. Selective etching (eg, RIE). Specifically, the high-k gate dielectric 1006 is selectively etched to remain only under the gate stack and the sidewall spacers; in addition, the STI 1005 is selectively etched such that a portion of the sidewall of the semiconductor substrate 1001 is exposed ( In the present embodiment, a portion of the sacrificial strain region 1010 is exposed.
然后, 在此优选地, 如图 9所示, 淀积一层刻蚀保护层 (例如氮化物) 1011, 并 对其进行构图以去除其位于 STI 1005之上的部分。 因此, 该刻蚀保护层 1011覆盖了栅 堆叠以及叠层结构的顶部和侧壁。 Then, preferably, as shown in Fig. 9, an etch protection layer (e.g., nitride) 1011 is deposited and patterned to remove portions thereof above the STI 1005. Therefore, the etch protection layer 1011 covers the gate stack and the top and sidewalls of the stacked structure.
接着, 如图 10所示, 进一步选择性刻蚀(例如, RIE) STI 1005, 从而基本上去除 了 STI 1005 , 以充分露出牺牲应变区 1010。 随后, 对牺牲应变区 1010进行选择性刻蚀, 以基本上去除牺牲应变区 1010。 在此, 由于牺牲应变区 1010与半导体衬底 1001之间掺
杂浓度的差异, 可以实现这种选择性刻蚀, 例如通过 KOH、 TMAH、 EDP、 Ν2Η4·Η20 等刻蚀剂。 Next, as shown in FIG. 10, the STI 1005 is further selectively etched (eg, RIE) to substantially remove the STI 1005 to fully expose the sacrificial strain region 1010. Subsequently, the sacrificial strain region 1010 is selectively etched to substantially remove the sacrificial strain region 1010. Here, due to the sacrificial strain region 1010 and the semiconductor substrate 1001 This selective etching can be achieved by the difference in the impurity concentration, for example, by an etchant such as KOH, TMAH, EDP, Ν 2 Η 4 · Η 2 0 .
在如上所述在牺牲应变区 1010所在位置处形成了空洞之后, 可以进行嵌入式应变 区的形成。 具体地, 如图 11所示, 在半导体衬底 1001中由于去除了牺牲应变区 1010而 形成的空洞中, 通过选择性外延生长, 形成嵌入式应变区 1012。 嵌入式应变区 1012的 晶格结构与半导体衬底 1001 (例如 Si) 的晶格结构存在一定的差异, 从而产生一定的 应力, 这种应力可以传递到其上的叠层结构特别是窄带隙材料层 1003中 (在该窄带隙 材料层 1003中形成本实施例晶体管结构的源 /漏以及沟道区), 从而在窄带隙材料层 1003中产生向沟道区施加的应力。 例如, 对于 nFET (n型场效应晶体管), 嵌入式应变 区 1012可以为 Si:C, 以便产生拉伸应力; 而对于 pFET (p型场效应晶体管), 嵌入式应 变区 1012可以为 SiGe, 以便产生压缩应力。 After the void is formed at the location of the sacrificial strain zone 1010 as described above, the formation of the embedded strain zone can be performed. Specifically, as shown in Fig. 11, in the cavity formed in the semiconductor substrate 1001 by removing the sacrificial strain region 1010, the embedded strain region 1012 is formed by selective epitaxial growth. The lattice structure of the embedded strain region 1012 is different from the lattice structure of the semiconductor substrate 1001 (for example, Si), thereby generating a certain stress, and the stress can be transmitted to the laminated structure, especially the narrow band gap material. In the layer 1003 (the source/drain and channel regions of the transistor structure of the present embodiment are formed in the narrow band gap material layer 1003), stress applied to the channel region is generated in the narrow band gap material layer 1003. For example, for an nFET (n-type field effect transistor), the embedded strain region 1012 can be Si:C to generate tensile stress; and for a pFET (p-type field effect transistor), the embedded strain region 1012 can be SiGe for Produces compressive stress.
这样, 以上述方式形成了嵌入式应变区。 这里需要指出的是, 本领域技术人员在 不脱离本发明范围的前提下, 可以设计其他方式来形成这种嵌入式应变区。 本发明的 重要特征在于在体半导体衬底中形成嵌入式应变区, 以便向体半导体衬底上形成的 III-V族化合物半导体叠层结构中形成的源 /漏区施加应力,而并非在于嵌入式应变区的 具体形成方式。 Thus, the embedded strain zone is formed in the above manner. It should be noted that those skilled in the art can design other ways to form such an embedded strain zone without departing from the scope of the invention. An important feature of the present invention is to form an embedded strain region in a bulk semiconductor substrate to apply stress to source/drain regions formed in a III-V compound semiconductor stacked structure formed on a bulk semiconductor substrate, rather than embedding The specific formation of the strain zone.
在如上所述形成了嵌入式应变区之后, 可以例如通过离子注入等方式在栅堆叠的 两侧、 在 III-V族化合物半导体叠层结构中 (特别是在窄带隙材料层 1003中) 形成源 / 漏区 (图中未示出)。 例如, 对于 nFET, 可以利用 Si或 S进行离子注入; 对于 pFET, 可以利用 Zn或 Be进行离子注入。 After the embedded strain regions are formed as described above, the source may be formed on both sides of the gate stack, such as in the III-V compound semiconductor stacked structure (particularly in the narrow band gap material layer 1003), for example by ion implantation or the like. / Drain area (not shown). For example, for nFETs, Si or S can be used for ion implantation; for pFETs, Zn or Be can be used for ion implantation.
这样, 就形成了根据本发明实施例的半导体器件的基本结构。 如图 11所示, 该半 导体器件包括: 体半导体衬底 1001 ; 在体半导体衬底 1001上形成的叠层结构 (1002, 1003, 1004), 包括宽带隙 III-V族化合物半导体层 (1002) /窄带隙 III-V族化合物半导 体层(1003 )/宽带隙 III-V族化合物半导体层(1004);在叠层结构上形成的栅堆叠(1006, 1007); 在栅堆叠两侧、 在半导体衬底 1001中嵌入的嵌入式应变区 (1012); 以及形成 叠层结构 (1002, 1003, 1004) 中的源 /漏区。 Thus, the basic structure of the semiconductor device according to the embodiment of the present invention is formed. As shown in FIG. 11, the semiconductor device includes: a bulk semiconductor substrate 1001; a stacked structure (1002, 1003, 1004) formed on the bulk semiconductor substrate 1001, including a wide band gap III-V compound semiconductor layer (1002) / narrow band gap III-V compound semiconductor layer (1003) / wide band gap III-V compound semiconductor layer (1004); gate stack formed on the stacked structure (1006, 1007); on both sides of the gate stack, in the semiconductor An embedded strain region (1012) embedded in the substrate 1001; and a source/drain region formed in the stacked structure (1002, 1003, 1004).
最后, 在上述基本结构的基础上, 可以如图 12所示, 在如上所述形成的器件结构 上形成一覆层 1013, 如氧化物。 该氧化物同时淀积在 STI沟槽中, 从而再次形成 STI。 另外, 可以形成与源 /漏区接触的接触部 1014。接触部 1014例如通过刻蚀接触孔, 然后 在接触孔中形成衬层, 最后填充金属塞来形成。 由于顶部有覆层 1013, 并且还存在宽
带隙半导体材料层 1004, 因此接触孔应当深入到窄带隙半导体材料层 1003中, 从而形 成良好接触。衬层的材料可以是以下的任一种或多种形成: TaN、 TiN、 Ta、 Ti、 TiSiN、 TaSiN、 TiW、 WN或 Ru。 金属塞的材料可以是: W、 Al、 Cu或 TiAl等材料。 Finally, on the basis of the above basic structure, as shown in Fig. 12, a coating layer 1013 such as an oxide may be formed on the device structure formed as described above. The oxide is simultaneously deposited in the STI trench to form the STI again. In addition, a contact portion 1014 that is in contact with the source/drain regions may be formed. The contact portion 1014 is formed, for example, by etching a contact hole, then forming a liner in the contact hole, and finally filling the metal plug. Since the top has a coating 1013, and there is still a width The bandgap semiconductor material layer 1004, therefore the contact holes should penetrate deep into the narrow bandgap semiconductor material layer 1003 to form a good contact. The material of the liner may be formed of any one or more of the following: TaN, TiN, Ta, Ti, TiSiN, TaSiN, TiW, WN or Ru. The material of the metal plug may be: W, Al, Cu or TiAl.
形成源 /漏区的方法不限于上述离子注入的方式。可选地, 在栅堆叠的两侧的叠层 结构上去除覆层, 并形成金属层。 优选的金属材料是 TaN。 金属与下方的半导体接触 形成的金属 -半导体结, 因而形成了肖特基势垒 (Schottky Barrier), 则也能够实现源 / 漏区。 The method of forming the source/drain regions is not limited to the above-described manner of ion implantation. Optionally, the cladding is removed over the stacked structures on both sides of the gate stack and a metal layer is formed. A preferred metal material is TaN. The source/drain regions can also be realized by the metal-semiconductor junction formed by the metal in contact with the underlying semiconductor, thus forming a Schottky barrier.
(第二实施例) (Second embodiment)
本发明的方法还可以与替换栅极工艺相兼容。 以下, 将参照附图 13〜26来描述本 发明的第二实施例, 在该实施例中结合了替换栅极工艺。 以下, 将着重描述第二实施 例与第一实施例的不同之处; 对于没有详尽说明的步骤, 可以参照以上第一实施例中 对于相应步骤的描述。 附图中相似的标记表示相似的部件。 The method of the present invention can also be compatible with replacement gate processes. Hereinafter, a second embodiment of the present invention will be described with reference to Figs. 13 to 26, in which a replacement gate process is incorporated. Hereinafter, differences between the second embodiment and the first embodiment will be mainly described; for steps not described in detail, reference may be made to the description of the corresponding steps in the above first embodiment. Like reference numerals in the drawings denote like parts.
首先,如图 13所示,在半导体衬底 2001上形成叠层结构,例如依次外延生长 InAlAs 2002、 InAs/InGaAs 2003 > InAlAs2004。 叠层结构的组成可以参考上一实施例的描述。 First, as shown in Fig. 13, a stacked structure is formed on a semiconductor substrate 2001, for example, epitaxially grown InAlAs 2002, InAs/InGaAs 2003 > InAlAs2004. The composition of the laminated structure can be referred to the description of the previous embodiment.
例如, InAlAs 2002和 2004的厚度可以为约 l〜5nm, InAs或 InGaAs 2003的厚度可 以为约 5〜20nm。 For example, InAlAs 2002 and 2004 may have a thickness of about 1 to 5 nm, and InAs or InGaAs 2003 may have a thickness of about 5 to 20 nm.
优选地, 可以如图 14所示, 形成 STI 2005。 Preferably, STI 2005 can be formed as shown in FIG.
然后, 如图 15和 16所述, 在经过如上处理的衬底上形成牺牲栅堆叠。 具体地, 如 图 15所示, 在图 14所示的结构上依次淀积牺牲栅介质 2006和牺牲栅主体 2007。 例如, 牺牲栅介质 2006可以为 Si02, 牺牲栅主体 2007可以为多晶硅。 在此, 牺牲栅介质 2006 的厚度可以为约 2〜4nm, 牺牲栅主体 2007的厚度可以为约 50〜150nm。 然后, 如图 16 所示, 对牺牲栅主体 2007进行构图, 以形成牺牲栅堆叠。 具体地, 例如在牺牲栅主体 2007上涂覆光刻胶 2008,然后通过掩模曝光,将光刻胶 2008构图为所需的栅堆叠形状。 随后, 对牺牲栅主体 2007进行刻蚀 (例如, RIE), 形成相应的栅堆叠。 在刻蚀之后, 去除光刻胶 2008。 Then, as described in FIGS. 15 and 16, a sacrificial gate stack is formed on the substrate subjected to the above processing. Specifically, as shown in FIG. 15, a sacrificial gate dielectric 2006 and a sacrificial gate body 2007 are sequentially deposited on the structure shown in FIG. For example, the sacrificial gate dielectric 2006 may be Si0 2 and the sacrificial gate body 2007 may be polysilicon. Here, the thickness of the sacrificial gate dielectric 2006 may be about 2 to 4 nm, and the thickness of the sacrificial gate body 2007 may be about 50 to 150 nm. Then, as shown in FIG. 16, the sacrificial gate body 2007 is patterned to form a sacrificial gate stack. Specifically, the photoresist 2008 is patterned, for example, on the sacrificial gate body 2007, and then exposed through a mask to form the desired gate stack shape. Subsequently, the sacrificial gate body 2007 is etched (eg, RIE) to form a corresponding gate stack. After the etching, the photoresist 2008 is removed.
接着, 如图 17所示, 在形成的牺牲栅堆叠两侧形成侧墙 2009 (例如, 氮化物)。 随后,如图 18所示进行牺牲应变区的离子注入,并进行退火处理以激活注入的离子(如 As或 P ), 从而形成牺牲应变区 2010, 如图 19所示。 Next, as shown in FIG. 17, sidewalls 2009 (e.g., nitride) are formed on both sides of the formed sacrificial gate stack. Subsequently, ion implantation of the sacrificial strain region is performed as shown in Fig. 18, and annealing treatment is performed to activate the implanted ions (e.g., As or P), thereby forming a sacrificial strain region 2010, as shown in Fig. 19.
接下来, 对牺牲应变区 2010进行替换处理, 以形成嵌入式应变区。 为此, 首先如
图 20所示, 对牺牲栅介质 2006进行选择性刻蚀(例如 RIE), 使其仅留在栅堆叠以及侧 墙之下; 另外, 对 STI 2005进行选择性刻蚀 (例如 RIE), 使得露出半导体衬底 2001的 一部分侧壁 (在本实施例中, 露出牺牲应变区 2010的一部分)。 然后, 如图 21所示, 形成刻蚀保护层 2011, 以覆盖栅堆叠以及叠层结构。 Next, the sacrificial strain zone 2010 is subjected to a replacement process to form an embedded strain zone. To do this, first of all As shown in FIG. 20, the sacrificial gate dielectric 2006 is selectively etched (eg, RIE) to remain only under the gate stack and the sidewall spacers; in addition, the STI 2005 is selectively etched (eg, RIE) to expose A portion of the sidewall of the semiconductor substrate 2001 (in this embodiment, a portion of the sacrificial strain region 2010 is exposed). Then, as shown in FIG. 21, an etch protection layer 2011 is formed to cover the gate stack and the stacked structure.
接着, 如图 22所示, 通过选择性刻蚀, 去除 STI 2005以及牺牲应变区 2010。 然后, 如图 23所示, 在半导体衬底 2001中由于去除了牺牲应变区 2010而形成的空洞中, 通过 选择性外延生长, 形成嵌入式应变区 2012。 例如, 对于 nFET (n型场效应晶体管), 嵌 入式应变区 2012可以为 Si:C, 以便产生拉伸应力; 而对于 pFET (p型场效应晶体管), 嵌入式应变区 2012可以为 SiGe, 以便产生压縮应力。 Next, as shown in FIG. 22, the STI 2005 and the sacrificial strain region 2010 are removed by selective etching. Then, as shown in Fig. 23, in the cavity formed by the sacrificial strain region 2010 in the semiconductor substrate 2001, the embedded strain region 2012 is formed by selective epitaxial growth. For example, for an nFET (n-type field effect transistor), the embedded strain region 2012 can be Si:C to generate tensile stress; and for a pFET (p-type field effect transistor), the embedded strain region 2012 can be SiGe for Produces compressive stress.
随后, 如图 24所示, 在图 23所示的结构上淀积层间介质层 2013 (例如 Si02), 并对 其进行平坦化直至到达刻蚀保护层 2011。 Subsequently, as shown in FIG. 24, an interlayer dielectric layer 2013 (for example, SiO 2 ) is deposited on the structure shown in FIG. 23 and planarized until reaching the etch protection layer 2011.
接着, 如图 25所示, 进行替换栅处理。 具体地, 通过选择性刻蚀(例如 RIE), 去 除位于牺牲栅堆叠顶部的刻蚀保护层 2011。然后,进一步通过选择性刻蚀(例如, RIE), 去除牺牲栅主体 2007; 在刻蚀过程中, 牺牲栅介质 2006可以充当刻蚀停止层。 在由于 去除牺牲栅主体 2007而形成的开口中, 依次形成高 k栅介质 2014 (例如 HfO2) 和金属 层 2015 (例如 W), 从而形成替代栅堆叠。 在此, 栅堆叠也可以包括高 k栅介质 /金属栅 /多晶硅堆叠。 . Next, as shown in FIG. 25, replacement gate processing is performed. Specifically, the etch protection layer 2011 on top of the sacrificial gate stack is removed by selective etching (eg, RIE). Then, the sacrificial gate body 2007 is further removed by selective etching (eg, RIE); the sacrificial gate dielectric 2006 may serve as an etch stop layer during the etching process. In the opening formed by removing the sacrificial gate body 2007, a high-k gate dielectric 2014 (for example, HfO 2 ) and a metal layer 2015 (for example, W) are sequentially formed, thereby forming a replacement gate stack. Here, the gate stack may also include a high-k gate dielectric/metal gate/polysilicon stack. .
在此, 优选地在叠层结构中形成源 /漏区之后再进行替换栅处理, 以避免形成源 / 漏区的工艺对栅性能造成影响。 Here, the replacement gate treatment is preferably performed after the source/drain regions are formed in the stacked structure to avoid the process of forming the source/drain regions from affecting the gate performance.
最后, 如图 26所示, 在如上所述形成的器件结构上形成一覆层 2016, 如氮化物。 可以形成与源 /漏区接触的接触部 2017。接触部 2017例如通过刻蚀接触孔, 然后填充金 属如 W来形成。 Finally, as shown in Fig. 26, a coating 2016, such as a nitride, is formed on the device structure formed as described above. A contact portion 2017 that is in contact with the source/drain regions can be formed. The contact portion 2017 is formed, for example, by etching a contact hole and then filling a metal such as W.
在以上的描述中, 仅说明了替换栅工艺的一种示例。 本领域技术人员可以清楚, 其他形式的替换栅工艺也可以应用于本发明中。 In the above description, only one example of the replacement gate process has been described. It will be apparent to those skilled in the art that other forms of replacement gate processes can also be employed in the present invention.
在以上的描述中, 对于各层的构图、 刻蚀等技术细节并没有做出详细的说明。 但 是本领域技术人员应当理解,可以通过现有技术中的各种手段,来形成所需形状的层、 区域等。 另外, 为了形成同一结构, 本领域技术人员还可以设计出与以上描述的方法 并不完全相同的方法。 In the above description, the technical details of patterning, etching, and the like of each layer are not described in detail. However, it should be understood by those skilled in the art that layers, regions, and the like of a desired shape can be formed by various means in the prior art. In addition, in order to form the same structure, those skilled in the art can also design a method that is not exactly the same as the method described above.
以上参照本发明的实施例对本发明予以了说明。 但是, 这些实施例仅仅是为了说 明的目的, 而并非为了限制本发明的范围。 本发明的范围由所附权利要求及其等价物
限定。 不脱离本发明的范围, 本领域技术人员可以做出多种替换和修改, 这些替换和 修改都应落在本发明的范围之内。
The invention has been described above with reference to the embodiments of the invention. However, these examples are for illustrative purposes only and are not intended to limit the scope of the invention. The scope of the invention is defined by the appended claims and their equivalents Limited. Numerous alternatives and modifications may be made by those skilled in the art without departing from the scope of the invention.
Claims
1. 一种制作半导体器件的方法, 包括: A method of fabricating a semiconductor device, comprising:
在体半导体衬底上外延生长宽带隙 III-V族化合物半导体层 /窄带隙 III-V族化合物 半导体层 /宽带隙 πι-ν族化合物半导体层的叠层结构; Epitaxial growth of a wide band gap III-V compound semiconductor layer on a bulk semiconductor substrate / narrow band gap III-V compound semiconductor layer / wide band gap πι-ν group compound semiconductor layer stack structure;
在所述叠层结构上形成栅堆叠; Forming a gate stack on the stacked structure;
在所述体半导体衬底中形成嵌入式应变区; 以及 Forming an embedded strain region in the bulk semiconductor substrate;
在所述栅堆叠的两侧、 在所述叠层结构中形成源 /漏区。 Source/drain regions are formed in the stacked structure on both sides of the gate stack.
2. 根据权利要求 1所述的方法, 其中, 2. The method according to claim 1, wherein
所述宽带隙 III-V族化合物半导体包括 InAlAs、 InP、 AlSb、 AlGaSb、 GaP、 InGaP、 AlGaAs、 InAlSb中的任一种; 以及 The wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb;
所述窄带隙 III-V族化合物半导体包括 InAs、 InGaAs、 GaAs、 GaSb、 InGaSb、 InSb 中的任一种。 The narrow band gap III-V compound semiconductor includes any one of InAs, InGaAs, GaAs, GaSb, InGaSb, and InSb.
3. 根据权利要求 1所述的方法, 其中, 所述宽带隙 III-V族化合物半导体层的厚 度为 l〜5nm; 所述窄带隙 III-V族化合物半导体层的厚度为 5〜20nm。 The method according to claim 1, wherein the wide band gap III-V compound semiconductor layer has a thickness of 1 to 5 nm; and the narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
4. 根据权利要求 1所述的方法, 其中, 所述栅堆叠包括高 k栅介质 /金属栅堆叠 或高 k栅介质 /金属栅 /多晶硅堆叠。 4. The method of claim 1, wherein the gate stack comprises a high k gate dielectric / metal gate stack or a high k gate dielectric / metal gate / polysilicon stack.
5. 根据权利要求 1 所述的方法, 其中, 所述栅堆叠包括栅介质 /多晶硅栅堆叠, 在形成源 /漏区之后, 该方法进一步包括: 5. The method of claim 1, wherein the gate stack comprises a gate dielectric/polysilicon gate stack, and after forming the source/drain regions, the method further comprises:
去除所述栅堆叠; Removing the gate stack;
形成替代的高 k栅介质 /金属栅堆叠。 An alternative high k gate dielectric/metal gate stack is formed.
6. 根据权利要求 1所述的方法, 其中, 形成嵌入式应变区的步骤包括: 在所述栅堆叠的两侧且嵌入所述半导体衬底形成牺牲应变区; 6. The method according to claim 1, wherein the step of forming an embedded strain region comprises: forming a sacrificial strain region on both sides of the gate stack and embedding the semiconductor substrate;
去除所述牺牲应变区; Removing the sacrificial strain zone;
形成嵌入式应变区。 Form an embedded strain zone.
7. 根据权利要求 6所述的方法, 其中, 形成牺牲应变区的步骤包括- 在所述栅堆叠的两侧向所述半导体衬底注入 As或 P, 以形成牺牲应变区。 7. The method of claim 6, wherein the step of forming the sacrificial strain region comprises implanting As or P into the semiconductor substrate on both sides of the gate stack to form a sacrificial strain region.
8. 根据权利要求 7所述的方法, 其中, 所述半导体衬底上包括浅沟槽隔离用于隔 离相邻的器件, 则去除所述牺牲应变区, 形成嵌入式应变区的步骤包括- 从所述浅沟槽隔离的上方向下刻蚀至部分浅沟槽隔离露出; 8. The method of claim 7, wherein the semiconductor substrate comprises shallow trench isolation for isolating adjacent devices, Removing the sacrificial strain region, the step of forming the embedded strain region includes - etching from the upper portion of the shallow trench isolation to a portion of the shallow trench isolation;
选择性刻蚀余下的浅沟槽隔离以及牺牲应变区; Selectively etching the remaining shallow trench isolation and sacrificial strain regions;
通过外延生长, 形成嵌入式应变区。 By epitaxial growth, an embedded strain region is formed.
9. 根据权利要求 8所述的方法, 其中, 在选择性刻蚀余下的浅沟槽隔离之前, 所 述方法进一步包括: 9. The method of claim 8 wherein, prior to selectively etching the remaining shallow trench isolation, the method further comprises:
采用介质层覆盖所述栅堆叠以及两侧余下的叠层结构顶部和外侧。 The gate stack and the top and outer sides of the remaining laminate structures on both sides are covered with a dielectric layer.
10. 根据权利要求 1所述的方法, 其中,所述窄带隙 m-v族化合物半导体层包括 至少一层。 10. The method according to claim 1, wherein the narrow band gap m-v compound semiconductor layer comprises at least one layer.
11. 根据权利要求 1所述的方法, 其中, 所述体半导体衬底包括 si, 所述嵌入式 应变区包括 Si:C或 SiGe。 11. The method of claim 1, wherein the bulk semiconductor substrate comprises si, and the embedded strain region comprises Si:C or SiGe.
12. 根据权利要求 1至 11中任一项所述的方法, 其中, 形成源 /漏区的步骤包括: 通过离子注入在所述栅堆叠两侧的叠层结构中形成源 /漏区,其中对于 n型半导体 器件, 注入的离子包括 Si或 S; 对于 p型半导体器件, 注入的离子包括 Zn或 Be。 The method according to any one of claims 1 to 11, wherein the forming the source/drain regions comprises: forming source/drain regions in a stacked structure on both sides of the gate stack by ion implantation, wherein For an n-type semiconductor device, the implanted ions include Si or S; for a p-type semiconductor device, the implanted ions include Zn or Be.
13. 一种半导体器件, 包括: 13. A semiconductor device comprising:
体半导体衬底; Bulk semiconductor substrate;
叠层结构, 包括宽带隙 m-v族化合物半导体层 /窄带隙 m-v族化合物半导体层 / 宽带隙 III-V族化合物半导体层, 形成在所述体半导体衬底上; a stacked structure comprising a wide band gap m-v compound semiconductor layer/narrow band gap m-v compound semiconductor layer/wide band gap III-V compound semiconductor layer formed on the bulk semiconductor substrate;
栅堆叠, 形成在所述叠层结构上; a gate stack formed on the stacked structure;
嵌入式应变区, 形成在所述栅堆叠两侧, 嵌入所述体半导体衬底中; 以及 源 /漏区, 形成在所述栅堆叠两侧的叠层结构中。 Embedded strain regions are formed on both sides of the gate stack, embedded in the bulk semiconductor substrate; and source/drain regions are formed in a stacked structure on both sides of the gate stack.
14. 根据权利要求 13所述的半导体器件, 其中, 14. The semiconductor device according to claim 13, wherein
所述宽带隙 III-V族化合物半导体包括 InAlAs、 InP、 AlSb、 AlGaSb、 GaP、 InGaP、 AlGaAs、 InAlSb中的任一种; 以及 The wide band gap III-V compound semiconductor includes any one of InAlAs, InP, AlSb, AlGaSb, GaP, InGaP, AlGaAs, InAlSb;
所述窄带隙 III-V族化合物半导体包括 InAs、 InGaAs、 GaAs、 GaSb、 InGaSb、 InSb 中的任一种。 The narrow band gap III-V compound semiconductor includes any one of InAs, InGaAs, GaAs, GaSb, InGaSb, and InSb.
15. 根据权利要求 13所述的方法, 其中, 所述宽带隙 III-V族化合物半导体层的 厚度为!〜 5nm; 所述窄带隙 III-V族化合物半导体层的厚度为 5〜20nm。 15. The method according to claim 13, wherein the thickness of the wide band gap III-V compound semiconductor layer is! 〜 5 nm; The narrow band gap III-V compound semiconductor layer has a thickness of 5 to 20 nm.
16. 根据权利要求 13所述的方法, 其中, 所述窄带隙 m-v族化合物半导体层包 括至少一层。 16. The method according to claim 13, wherein the narrow band gap mv group compound semiconductor layer comprises at least one layer.
17. 根据权利要求 13所述的半导体器件, 其中, 所述体半导体衬底包括 Si, 所述 嵌入式应变区包括 Si:C或 SiGe。 17. The semiconductor device according to claim 13, wherein the bulk semiconductor substrate comprises Si, and the embedded strain region comprises Si:C or SiGe.
18. 根据权利要求 13至 17中任一项所述的半导体器件, 其中, 对于 n型半导体 器件, 所述源 /漏区中包括 Si或 S离子; 对于 p型半导体器件, 所述源 /漏区中包括 Zn 或 Be离子。 The semiconductor device according to any one of claims 13 to 17, wherein, for the n-type semiconductor device, Si or S ions are included in the source/drain regions; and for the p-type semiconductor device, the source/drain The zone includes Zn or Be ions.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010102272712A CN102315126A (en) | 2010-07-07 | 2010-07-07 | Semiconductor device and method for manufacturing the same |
CN201010227271.2 | 2010-07-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012003611A1 true WO2012003611A1 (en) | 2012-01-12 |
WO2012003611A8 WO2012003611A8 (en) | 2012-04-26 |
Family
ID=45428160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2010/001428 WO2012003611A1 (en) | 2010-07-07 | 2010-09-17 | Semiconductor device and menufacturing method thereof |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN102315126A (en) |
WO (1) | WO2012003611A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9922830B2 (en) | 2014-04-07 | 2018-03-20 | International Business Machines Corporation | Hybrid III-V technology to support multiple supply voltages and off state currents on same chip |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108493273B (en) * | 2018-05-02 | 2023-11-21 | 浙江焜腾红外科技有限公司 | II-type superlattice infrared detector absorption region structure |
CN116487266B (en) * | 2023-04-25 | 2024-08-23 | 北京北方华创微电子装备有限公司 | Method for manufacturing semiconductor device |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1599960A (en) * | 2001-12-03 | 2005-03-23 | 克里公司 | Strain balanced nitride heterojunction transistors and methods of fabricating strain balanced nitride heterojunction transistors |
CN1797787A (en) * | 2004-12-30 | 2006-07-05 | 中国科学院半导体研究所 | Structure for improving Schottky performance of grid electrode of gallium nitride based transistor in high electron mobility |
US20080006818A1 (en) * | 2006-06-09 | 2008-01-10 | International Business Machines Corporation | Structure and method to form multilayer embedded stressors |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7129126B2 (en) * | 2003-11-05 | 2006-10-31 | International Business Machines Corporation | Method and structure for forming strained Si for CMOS devices |
US7923782B2 (en) * | 2004-02-27 | 2011-04-12 | International Business Machines Corporation | Hybrid SOI/bulk semiconductor transistors |
US7135724B2 (en) * | 2004-09-29 | 2006-11-14 | International Business Machines Corporation | Structure and method for making strained channel field effect transistor using sacrificial spacer |
CN101449366A (en) * | 2006-06-23 | 2009-06-03 | 国际商业机器公司 | Buried channel mosfet using iii-v compound semiconductors and high k gate dielectrics |
US7585711B2 (en) * | 2006-08-02 | 2009-09-08 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor-on-insulator (SOI) strained active area transistor |
CN100527371C (en) * | 2007-09-14 | 2009-08-12 | 北京大学 | Portion exhausted SOI MOS transistor preparation method |
-
2010
- 2010-07-07 CN CN2010102272712A patent/CN102315126A/en active Pending
- 2010-09-17 WO PCT/CN2010/001428 patent/WO2012003611A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1599960A (en) * | 2001-12-03 | 2005-03-23 | 克里公司 | Strain balanced nitride heterojunction transistors and methods of fabricating strain balanced nitride heterojunction transistors |
CN1797787A (en) * | 2004-12-30 | 2006-07-05 | 中国科学院半导体研究所 | Structure for improving Schottky performance of grid electrode of gallium nitride based transistor in high electron mobility |
US20080006818A1 (en) * | 2006-06-09 | 2008-01-10 | International Business Machines Corporation | Structure and method to form multilayer embedded stressors |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9922830B2 (en) | 2014-04-07 | 2018-03-20 | International Business Machines Corporation | Hybrid III-V technology to support multiple supply voltages and off state currents on same chip |
US10366892B2 (en) | 2014-04-07 | 2019-07-30 | International Business Machines Corporation | Hybrid III-V technology to support multiple supply voltages and off state currents on same chip |
Also Published As
Publication number | Publication date |
---|---|
CN102315126A (en) | 2012-01-11 |
WO2012003611A8 (en) | 2012-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10217672B2 (en) | Vertical transistor devices with different effective gate lengths | |
KR101592400B1 (en) | Methods of Manufacturing Semiconductor Devices and Structures Thereof | |
CN106033757B (en) | High mobility device with anti-punch through layer and method of forming the same | |
US12027607B2 (en) | Methods for GAA I/O formation by selective epi regrowth | |
CN106206730A (en) | Semiconductor device and manufacture method thereof including FinFET | |
US20160190280A1 (en) | Structure and formation method of semiconductor device structure with gate stack | |
US9276117B1 (en) | Structure and method and FinFET device | |
US20180083136A1 (en) | Methods of forming a vertical transistor device | |
TW201802893A (en) | Methods of forming semiconductor devices | |
TW201635517A (en) | Electrically insulated fin structure(s) with alternative channel materials and fabrication methods | |
CN104241134A (en) | Non-Planar Transistors with Replacement Fins and Methods of Forming the Same | |
US9564488B2 (en) | Strained isolation regions | |
TWI736988B (en) | Semiconductor device and method of fabricating the same | |
US20120292637A1 (en) | Dual Cavity Etch for Embedded Stressor Regions | |
KR20140143869A (en) | Semiconductor device having strained channel layer and method of manufacturing the same | |
US10199392B2 (en) | FinFET device having a partially dielectric isolated fin structure | |
TW201618193A (en) | Method for fabricating semiconductor structures including transistor channels having different strain states, and related semiconductor structures | |
US20060125028A1 (en) | MOSFET device with localized stressor | |
US20090142892A1 (en) | Method of fabricating semiconductor device having thin strained relaxation buffer pattern and related device | |
KR102426239B1 (en) | Dual gate dielectric transistor | |
US9437740B2 (en) | Epitaxially forming a set of fins in a semiconductor device | |
WO2012003611A1 (en) | Semiconductor device and menufacturing method thereof | |
US9514996B2 (en) | Process for fabricating SOI transistors for an increased integration density | |
US10680065B2 (en) | Field-effect transistors with a grown silicon-germanium channel | |
TWI854630B (en) | Method for fabricating semiconductor device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10854271 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 10854271 Country of ref document: EP Kind code of ref document: A1 |