WO2011161483A1 - Sea-water salt-plant with overflowing slabs - Google Patents

Sea-water salt-plant with overflowing slabs Download PDF

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Publication number
WO2011161483A1
WO2011161483A1 PCT/HR2011/000027 HR2011000027W WO2011161483A1 WO 2011161483 A1 WO2011161483 A1 WO 2011161483A1 HR 2011000027 W HR2011000027 W HR 2011000027W WO 2011161483 A1 WO2011161483 A1 WO 2011161483A1
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WO
WIPO (PCT)
Prior art keywords
overflowing
sea
salt
pool
slabs
Prior art date
Application number
PCT/HR2011/000027
Other languages
French (fr)
Inventor
Ivan Simic
Original Assignee
Ivan Simic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ivan Simic filed Critical Ivan Simic
Publication of WO2011161483A1 publication Critical patent/WO2011161483A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/04Chlorides
    • C01D3/06Preparation by working up brines; seawater or spent lyes

Definitions

  • the invention relates to sea-water salt-plant with overflowing slabs, intended for yielding of larger quantities of sea salt by benefitting from horizontal air streams.
  • International Patent Classification it is classified as Section E - Fixed Constructions; Class E04 - Building; Subclass E04H - Pools; Group 4/00, that includes various pools.
  • the technical problem solved by this invention relates to the structure and position of salt-plant slabs aimed to better utilisation of natural wind flow, enabling thus larger, more economic and efficient sea-salt production.
  • the sea salt (NaCI) is still being produced in salt-plants built in the Middle Ages or even earlier, their structure and location corresponding to the then state of technology.
  • the pools have been built on flat grounds, with no protection against rain.
  • a rain will decrease the quantity of the crystallised sea-salt, productivity and product quality.
  • Such salt plants are usually built protected from the wind.
  • the essence of the invention is a salt-plant with a pool and one or more horizontal or titled overflowing slabs, placed in one or more columns above the pool. Mutually and relative to the pool, the overflowing slabs may be parallel or under opposite angles.
  • the operating principle of the sea-water salt-plant with overflowing slabs is the constant exposure of a thin layer of sea water to wind streams that evaporate the water aimed to obtaining larger quantities of salt over a shorter period of time, the salt settling in the pool.
  • the sea water is supplied to the slabs and its constant circulation over the overflowing slabs is obtained by a piping distribution equipped with valves and a pump. Given the plant location, the most economic pump powering would be by wind.
  • FIG. 1 shows schematically the operating principle of the sea-water salt-plant with overflowing slabs.
  • Figure 2 shows the sea-water salt-plant containing one pool and two overflowing slabs in a single vertical column above the pool - front view.
  • Figure 3. shows the sea-water salt-plant shown in the Figure 1. - side view.
  • Figure 4. shows the sea-water salt-plant shown in the Figure 1. - top view.
  • Figure 5. shows the upper overflowing slab - top view.
  • Figure 6. shows the upper overflowing slab, cross section Y-Y in the Figure 5.
  • Figure 7. shows the sea-water salt-plant, cross section X-X in the Figure 4.
  • Figure 8. shows the sea-water salt-plant, cross section X-X in the Figure 4. - with rain-water draining hinged covers lowered
  • Figure 9 shows sea-water salt-plant made of one pool and two vertical columns of two overflowing slabs each above the pool - front view.
  • the sea-water salt-plant with overflowing slabs utilises wind stream to evaporate the sea water.
  • Sea water is taken from the pool and flows in a thin layer continuously down one or more overflowing slabs mutually distanced and placed one above the other, in a vertical column above the pool. Wind flows between the slabs, evaporating the sea water. The process is continued as long as the entire sea water from the pool is crystallised into salt and set at the bottom of the pool. This way, the time required to obtain alt is significantly shorter.
  • the embodiment of the sea-water salt-plant with overflowing slabs depends on the terrain relief, aimed to the best possible utilisation of wind direction and force. Hence, the best locations are steep coastlines and cuttings.
  • FIG. 1 shows schematically the operating principle of the sea-water salt-plant with overflowing slabs.
  • the sea-water salt-plant with overflowing slabs can be embodied in several variants. Here are shown only two variants:
  • Variant A is the sea-water salt-plant consisting of one pool and one vertical column of two overflowing slabs.
  • Variant B is the sea-water salt-plant consisting of one pool and two vertical columns of two overflowing slabs each.
  • the overflowing slabs are situated and above the other in a vertical column, positioned horizontally or slanted.
  • the overflowing slabs may be mutually parallel or slanted in opposite directions. This invention description illustrates mutually slanted overflowing slabs.
  • Pool is to accumulate water taken from the sea, where water evaporates and salt sets.
  • the pool is filled with new sea water by a pump.
  • the sea water after passing over the slab, flows into the pool.
  • the sea water flows from one to another slab and, after that, into the pool.
  • the sea water 2 is pumped by the pump P1 into the pool 1, and by the pump P2, through the piping system 3, to the upper overflowing slab 4 that has side walls 5 directing the sea water to the transversal opening 7 across the bottom of the slab 4.
  • the sea water 2 flows by free fall in a thin payer, over the overflowing slab 4, while so flowing exposed to the wind stream that evaporates a part of the water, whereas the remaining sea water passes through the opening 7 and falls to the overflowing slab 9, so that the thin layer of water is still exposed to the wind stream. On this slab too, effected by the wind stream, another part of water evaporate.
  • the set salt is collected from the pool, and the pool is filled with new sea water for the new salt production cycle.
  • the pool and the overflowing slabs may be of different shapes.
  • the pool volume is dimensioned according to the volume of the sea water that is planned to be turned into salt in a single cycle.
  • the uppermost overflowing slab has the hinged side covers 6 that may be lowered down into horizontal position.
  • the lowest overflowing slab in the column may also have hinged side covers 6, removing any rain water that entered the system above and preventing its mixing with the crystallised salt.
  • a larger number of overflowing slabs in a vertical column achieves larger and longer contact of the sea water with sea streams, this, in turn, enhancing the effect of horizontal air streams to water evaporation and yielding of larger quantities of salt.
  • the entire salt production process from starting the pump P1 to fill the pool with new sea water, starting the pump P2 to lift sea water from the pool onto the upper overflowing slab, turning the hinged covers 6 and 10 to take rain water away, and continuous lifting of the remaining sea water onto the overflow slabs until the entire sea water evaporated and crystallised salt is set in the pool, may be automated by means of known electronic and automation elements.
  • a - sea-water salt-plant consisting of one pool and one vertical column of two overflowing slabs
  • B sea-water salt-plant consisting of one pool and two vertical columns of two overflowing slabs each

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Seasonings (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The operating principle of the sea-water salt-plant with overflowing slabs is constant exposure of a thin layer of sea water to air streams, aimed to obtaining larger quantities of salt in as short period of time as possible. The sea-water salt-plant consists of the pool (1). Above the pool is the vertical column made of two or more overflowing slabs (4) and (8). The overflowing slabs may be positioned, mutually and relative to the pool, parallel or at mutually opposite angles. Using several tiers of overflowing slabs enables larger and longer contact of the sea water with wind streams. The overflowing slabs have hinged side covers (6) and (10) to take rain water (13) away from the pool. New sea water is supplied and its constant circulation over the overflowing slabs is maintained by pumps and distribution piping. Given the plant location, the most economic pump powering would be by wind. The embodiment of a sea-water salt-plant with overflowing slabs depends on the terrain relief, aimed to the best possible utilisation of the direction and force. Hence, the best locations are steep coastlines and cuttings. The entire salt production process in sea-water salt-plant with overflowing slabs may be automated by means of known electronic and automation elements.

Description

SEA-WATER SALT-PLANT WITH OVERFLOWING SLABS
INVENTION DESCRIPTION
1. FIELD OF APPLICATION
The invention relates to sea-water salt-plant with overflowing slabs, intended for yielding of larger quantities of sea salt by benefitting from horizontal air streams. In the International Patent Classification, it is classified as Section E - Fixed Constructions; Class E04 - Building; Subclass E04H - Pools; Group 4/00, that includes various pools.
2. TECHNICAL PROBLEM
Since the wind power is taking a special place in the development of new technologies, the wind streaming is to be used to the maximum in salt production as well.
The technical problem solved by this invention relates to the structure and position of salt-plant slabs aimed to better utilisation of natural wind flow, enabling thus larger, more economic and efficient sea-salt production.
3. STATE OF THE ART
The sea salt (NaCI) is still being produced in salt-plants built in the Middle Ages or even earlier, their structure and location corresponding to the then state of technology. The pools have been built on flat grounds, with no protection against rain. A rain will decrease the quantity of the crystallised sea-salt, productivity and product quality. In the current endeavours to increase the sea-plant production, the air flow has not been used to the fullest extent possible. Such salt plants are usually built protected from the wind.
4. ESSENCE OF THE INVENTION
The essence of the invention is a salt-plant with a pool and one or more horizontal or titled overflowing slabs, placed in one or more columns above the pool. Mutually and relative to the pool, the overflowing slabs may be parallel or under opposite angles. The operating principle of the sea-water salt-plant with overflowing slabs is the constant exposure of a thin layer of sea water to wind streams that evaporate the water aimed to obtaining larger quantities of salt over a shorter period of time, the salt settling in the pool.
The sea water is supplied to the slabs and its constant circulation over the overflowing slabs is obtained by a piping distribution equipped with valves and a pump. Given the plant location, the most economic pump powering would be by wind.
5. ILLUSTRATION DESCRIPTIONS
Figure 1. shows schematically the operating principle of the sea-water salt-plant with overflowing slabs.
Figure 2. shows the sea-water salt-plant containing one pool and two overflowing slabs in a single vertical column above the pool - front view.
Figure 3. shows the sea-water salt-plant shown in the Figure 1. - side view.
Figure 4. shows the sea-water salt-plant shown in the Figure 1. - top view.
Figure 5. shows the upper overflowing slab - top view.
Figure 6. shows the upper overflowing slab, cross section Y-Y in the Figure 5.
Figure 7. shows the sea-water salt-plant, cross section X-X in the Figure 4. Figure 8. shows the sea-water salt-plant, cross section X-X in the Figure 4. - with rain-water draining hinged covers lowered
Figure 9. shows sea-water salt-plant made of one pool and two vertical columns of two overflowing slabs each above the pool - front view.
6. DESCRIPTION OF THE INVENTION EMBODIMENT AND FUNCTIONING
The sea-water salt-plant with overflowing slabs utilises wind stream to evaporate the sea water. Sea water is taken from the pool and flows in a thin layer continuously down one or more overflowing slabs mutually distanced and placed one above the other, in a vertical column above the pool. Wind flows between the slabs, evaporating the sea water. The process is continued as long as the entire sea water from the pool is crystallised into salt and set at the bottom of the pool. This way, the time required to obtain alt is significantly shorter.
The embodiment of the sea-water salt-plant with overflowing slabs depends on the terrain relief, aimed to the best possible utilisation of wind direction and force. Hence, the best locations are steep coastlines and cuttings.
Figure 1. shows schematically the operating principle of the sea-water salt-plant with overflowing slabs.
With regard to the number of pools, vertical columns and overflowing slabs in each of them, the sea-water salt-plant with overflowing slabs can be embodied in several variants. Here are shown only two variants:
Variant A, Figures 2., 3. and 4., is the sea-water salt-plant consisting of one pool and one vertical column of two overflowing slabs.
Variant B, Figure 7., is the sea-water salt-plant consisting of one pool and two vertical columns of two overflowing slabs each.
The overflowing slabs are situated and above the other in a vertical column, positioned horizontally or slanted. The overflowing slabs may be mutually parallel or slanted in opposite directions. This invention description illustrates mutually slanted overflowing slabs.
Pool is to accumulate water taken from the sea, where water evaporates and salt sets. The pool is filled with new sea water by a pump.
Where the salt-plant has only one overflowing slab, the sea water, after passing over the slab, flows into the pool. Where the salt-plant has several overflowing slabs, the sea water flows from one to another slab and, after that, into the pool.
Functioning of the invention by the variant A
The sea water 2 is pumped by the pump P1 into the pool 1, and by the pump P2, through the piping system 3, to the upper overflowing slab 4 that has side walls 5 directing the sea water to the transversal opening 7 across the bottom of the slab 4. The sea water 2 flows by free fall in a thin payer, over the overflowing slab 4, while so flowing exposed to the wind stream that evaporates a part of the water, whereas the remaining sea water passes through the opening 7 and falls to the overflowing slab 9, so that the thin layer of water is still exposed to the wind stream. On this slab too, effected by the wind stream, another part of water evaporate. After passing over the tilted overflowing slab 8, water flows through the opening 11, as a thin waterfall, into the pool 1 , where a part of the salt contained in the falling sea-water crystallises. The pump P2 continuously pumps the remaining sea water from the pool onto the upper overflowing slab 4, as long as all the sea water evaporated and the sea salt 12 from it crystallised and set in the pool 1.
After this, the set salt is collected from the pool, and the pool is filled with new sea water for the new salt production cycle.
The pool and the overflowing slabs may be of different shapes. The pool volume is dimensioned according to the volume of the sea water that is planned to be turned into salt in a single cycle.
Productivity of a salt plant with overflowing slabs is much greater than in classic salt plants. The uppermost overflowing slab has the hinged side covers 6 that may be lowered down into horizontal position. The lowest overflowing slab in the column may also have hinged side covers 6, removing any rain water that entered the system above and preventing its mixing with the crystallised salt.
In rainy weather, the pump P2 and supply of the sea water from the pool to the overflowing slab 4 are stopped, and the hinged side covers 6 and turned down, thus taking rain water out of the pool. This protects the already achieved degree of salt crystallisation in the pool, whereas rain makes no harm.
A larger number of overflowing slabs in a vertical column achieves larger and longer contact of the sea water with sea streams, this, in turn, enhancing the effect of horizontal air streams to water evaporation and yielding of larger quantities of salt. The entire salt production process, from starting the pump P1 to fill the pool with new sea water, starting the pump P2 to lift sea water from the pool onto the upper overflowing slab, turning the hinged covers 6 and 10 to take rain water away, and continuous lifting of the remaining sea water onto the overflow slabs until the entire sea water evaporated and crystallised salt is set in the pool, may be automated by means of known electronic and automation elements.
BRIEF DESCRIPTION OF REFERRAL MARKS:
A - sea-water salt-plant consisting of one pool and one vertical column of two overflowing slabs
B - sea-water salt-plant consisting of one pool and two vertical columns of two overflowing slabs each
P1 - pump supplying pool with new sea water
P2 - pump taking sea water from the pool onto the upper overflowing slab
1 - pool
2 - new sea water
3 - piping taking sea water from the pool to the upper overflowing slab
4 - upper overflowing slab
5 - side wall of the overflowing slab 4 6 - hinged cover
7 - opening allowing sea water from the overflowing slab 4 to flow down to the overflowing slab 8
8 - overflowing slab nearest to the pool
9 - side wall of the overflowing slab 8
10 - hinged cover of the overflowing slab 8
11 - opening allowing sea water from the overflowing slab 8 into the pool
12 - crystallised salt in the pool
13 - rain water
7. INVENTION APPLICATION
The invention application is made obvious in its description. Sea-water salt-plant with overflowing slabs is particularly economic if located in areas abounding in winds, regardless of the number of sunny days. These are various cuttings and steep coastlines.
The most economic powering of pumps at such locations is by wind or combined powering.
Experts will find obvious possibilities of numerous modifications and changes in the sea-water salt-plant structure according to this invention, without leaving the scope and spirit of the invention.

Claims

PATENT CLAIMS
1. Sea-water salt-plant with overflowing slabs that, with regard to a number of pools and vertical columns of overflowing slabs may be embodied in several variants, w h e r e i n , according to variant (A), it has one pool (1) supplied with sea water (2) by a pump (P1); the salt-plant further has horizontal or tilted, mutually distanced, overflowing slabs (4) and (8), placed in tiers one above another, in a vertical column above the pool; the salt-plant further has a pump (P2), with distribution piping (3), that lifts sea water from the pool onto the uppermost overflowing slab (4); the overflowing slab (4) has an opening (7) through which sea water flows down to the overflowing slab (8); the overflowing slab (8) has an opening (11) through which sea water flows into the pool; the sea water from the pool (1) is taken by the pump (P2) once again to the overflowing slab (4), whereby a cycle is continuously repeated until the entire sea water in the pool is crystallised and set in the pool as salt (12).
2. The sea-water salt-plant as claimed in Claim 1., w h e r e i n the overflowing slabs (4) and (8) in the vertical column may be placed mutually parallel or tilted at various mutually opposite angles.
3. The sea-water salt-plant as claimed in Claims 1. and 2., w h e r e i n the said overflowing slabs (4) and (8) have hinged side covers (6) and (10) that, in rainy weather, are turned outwards into horizontal position, thus taking rain water (13) away from the pool and preventing it to mix with the crystallised salt.
4. The sea-water salt-plant as claimed in Claims 1., 2. and 3., w h e r e i n the pool and the overflowing slabs may be of various shapes.
5. The sea-water salt-plant as claimed in preceding Claims, w h e r e i n the entire salt-plant operating process, from filling the pool with new sea water until salt is produced, may be automated by means of known electronic and automation elements.
6. The sea-water salt-plant, according to the variant (B), w h e r e i n it has one pool (1) and two vertical columns above the pool, in each vertical column there are placed two mutually distanced overflowing slabs.
PCT/HR2011/000027 2010-06-24 2011-06-20 Sea-water salt-plant with overflowing slabs WO2011161483A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HRP20100353A 2010-06-24
HRP20100353AA HRP20100353C1 (en) 2010-06-24 2010-06-24 Sea-water salt-plant with overflowing pans

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WO2011161483A1 true WO2011161483A1 (en) 2011-12-29

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022033408A1 (en) * 2020-08-12 2022-02-17 暨南大学 Slope crystallization and solid-liquid separation system

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1069792A (en) * 1952-01-07 1954-07-13 Process of concentrating seawater to obtain crystallization of sodium chloride or other salts
FR1270083A (en) * 1960-07-12 1961-08-25 Process and installation for the extraction of sea salts
FR2053982A5 (en) * 1970-03-09 1971-04-16 Damas Raul Evaporative prodn of sodium chloride
GB1267184A (en) * 1970-02-02 1972-03-15

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1069792A (en) * 1952-01-07 1954-07-13 Process of concentrating seawater to obtain crystallization of sodium chloride or other salts
FR1270083A (en) * 1960-07-12 1961-08-25 Process and installation for the extraction of sea salts
GB1267184A (en) * 1970-02-02 1972-03-15
FR2053982A5 (en) * 1970-03-09 1971-04-16 Damas Raul Evaporative prodn of sodium chloride

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022033408A1 (en) * 2020-08-12 2022-02-17 暨南大学 Slope crystallization and solid-liquid separation system

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HRP20100353A2 (en) 2011-12-31
HRPK20100353B3 (en) 2013-02-28
HRP20100353C1 (en) 2021-04-16

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