WO2011155262A1

WO2011155262A1 - Aqueous resin composition for forming a thick film, and surface treatment method using said composition

Info

Publication number: WO2011155262A1
Application number: PCT/JP2011/059525
Authority: WO
Inventors: 公彦中村
Original assignee: 昭和電工株式会社
Priority date: 2010-06-09
Filing date: 2011-04-18
Publication date: 2011-12-15
Also published as: SG185813A1; JP5611677B2; JP2011256289A; MY156902A; CN102933669A

Abstract

Disclosed is an aqueous resin composition for forming a thick film. Said composition can be used to form a thick film on a target surface of a concrete structure or the like. Furthermore, said film can be dried within 12 hours of application, and the applied film is highly durable and resistant to, for example, water, acids, and alkalis. Also disclosed is a surface treatment method using the aforementioned aqueous resin composition. The disclosed aqueous resin composition is characterized by a nonvolatile content between 65% and 80% by mass and by containing an aqueous synthetic resin emulsion (A) and a glass filler (B). The disclosed surface treatment method is characterized in that an aqueous resin composition for forming a thick film is applied to a target surface and dried, thereby forming a film between 0.1 and 2.0 mm thick. Further provided is a concrete-structure surface-treatment method characterized in that an aqueous resin composition for forming a thick film is applied to a concrete structure and dried.

Description

Aqueous resin composition for thick film construction and surface treatment method using the same

INDUSTRIAL APPLICABILITY The present invention is used in the civil engineering / architecture field, where a glass filler is combined with a water-based synthetic resin emulsion to exhibit excellent drying properties, and a film excellent in water resistance, acid resistance and alkali resistance can be formed. An aqueous resin composition for thick film construction for surface treatment of concrete and mortar and a surface treatment method using the same.

Concrete structures are subject to deterioration under various environmental conditions, and various surface treatment materials are used for the purpose of improving durability. By the way, in recent years, the shift from solvent-based resins to water-based resins has been promoted in the trend of strengthening VOC regulations and the rapid increase in social environmental protection awareness. Similarly, with regard to waterproofing and anticorrosion materials for concrete structures in the civil engineering and construction fields, various problems such as regulations on odors and volatile components and regulations on raw materials used have been addressed due to environmental problems. Development as a waterproofing material and anticorrosion material of resin is required. However, when a water-based resin is used as a waterproof / corrosion-proofing material for a concrete structure in the civil engineering / architectural field, it takes a long time until the coating film is completely dried, and it takes a long time schedule as a process. Therefore, from the viewpoint of durability, vinyl ester resins, polyester resins, epoxy resins, polyureas, urethane resins, etc., which are solvent-based resins having excellent water resistance, acid resistance and alkali resistance are currently used. Water-based resins, including workability, have been considered insufficient as waterproof and anticorrosive materials for concrete structures in the civil engineering and construction fields. Moreover, many crosslinking points cannot be made to exist like solvent type resin, and the intensity | strength as a resin film was also inadequate.

Under such circumstances, in order to provide a water-based ground preparation material having a good polishing workability after being applied on the base material in the ground material conditioning material for a concrete structure, (A) a polymer emulsion; A base material that contains (B) an acrylic emulsion or a synthetic rubber emulsion and (C) talc is disclosed (for example, see Patent Document 1). However, this base preparation material has restrictions on the construction method, and the acid resistance and alkali resistance were not sufficient in thick film construction.

Also disclosed is a composition for reinforced mortar characterized by containing glass fiber, cement, sand and the like in a vinyl acetate-ethylenic copolymer emulsion (see, for example, Patent Document 2). However, since the mortar composition has a non-volatile content that is too high, the viscosity rapidly increases, and there is a problem in workability.

On the other hand, as an aqueous resin composition in which an organic filler is added to a synthetic resin emulsion, for example, an adhesive containing at least one of a styrene-butadiene copolymer resin latex and a chloroprene rubber latex, and an acrylic resin powder (organic filler) The composition is disclosed (for example, refer patent document 3). This is for the purpose of being used as an adhesive, and is not for the purpose of forming a thick film unlike the waterproof / corrosive material of concrete structures. In addition, a vibration-damping composition characterized by containing an organic filler in a base emulsion using a core-shell emulsion has been disclosed (see, for example, Patent Document 4). Cracks may occur during formation.

JP 2009-149767 A JP 2002-179450 A JP 2009-102606 A JP 2005-126645 A

The present invention is capable of thick film construction on a surface to be treated such as a concrete structure and can be dried within 12 hours after coating, and the coated film has excellent durability, for example, water resistance, An object is to provide an aqueous resin composition for thick film construction having acid resistance and alkali resistance, and a surface treatment method using the same.

As a result of intensive studies to solve the above problems, the present inventors have completed the present invention. The present invention relates to an aqueous resin composition for pressure membrane construction, which contains an aqueous synthetic resin emulsion (A) and a glass filler (B) and has a nonvolatile content of 65 to 80% by mass.

The viscosity of the water-based resin composition for pressure membrane construction is preferably 8,000 mPa · s or more.

It is preferable that a glass filler (B) is 25 mass% or more with respect to the non volatile matter of the water based resin composition for thick film construction.

The solid content ratio of the water-based synthetic resin emulsion (A) and the glass filler (B) is preferably 7/3 to 3/7.

The average particle size of the glass filler (B) is preferably 0.3 mm or less.

The aqueous synthetic resin emulsion (A) is preferably a styrene-acrylic resin emulsion or an acrylic resin emulsion.

Further, the present invention provides a surface treatment to be treated, characterized in that a coating film having a film thickness of 0.1 to 2.0 mm is formed by applying an aqueous resin composition for thick film construction to the surface to be treated and drying it. Regarding the method.

Furthermore, the present invention relates to a concrete structure surface treatment method characterized in that a water-based resin composition for thick film construction is applied to a concrete structure and dried.

According to the present invention, it is possible to provide an aqueous resin composition for thick film construction that does not generate odor during work, is environmentally friendly, and has excellent water resistance, acid resistance, and alkali resistance.

Hereinafter, the present invention will be described in detail. The aqueous synthetic resin emulsion (A) used in the present invention is an emulsion polymer that can be obtained by radical polymerization of an ethylenically unsaturated monomer composition using a water-soluble polymer or a surfactant. Or latex polymer. Examples of emulsion polymers include styrene-acrylic resin emulsions, acrylic resin emulsions, ethylene-vinyl acetate emulsions, vinyl acetate emulsions, urethane emulsions, and latex polymers include styrene-butadiene resin latexes. Acrylonitrile-butadiene resin latex, chloroprene resin latex, and the like. A suspension obtained by emulsifying and dispersing an organic resin in water can also be used in combination. Of these, styrene-acrylic resin emulsions and acrylic resin emulsions are preferred from the viewpoints of adjusting properties such as nonvolatile content of the water-based synthetic resin emulsion (A), Tg design of the resin, miscibility and physical properties. In particular, a styrene-acrylic resin emulsion is preferable because of excellent acid resistance and alkali resistance.

The aqueous synthetic resin emulsion (A) used in the present invention is styrene that can be obtained by radical polymerization of an ethylenically unsaturated monomer composition in the presence of water-soluble or water-dispersible polyester. -Acrylic resin emulsion or acrylic resin emulsion. Of these, a styrene-acrylic resin emulsion is preferred because of its excellent acid resistance and alkali resistance.

The amount of water-soluble or water-dispersible polyester is preferably 10% by mass to 30% by mass in terms of solid content in a synthetic resin emulsion obtained by polymerizing an ethylenically unsaturated monomer. More preferably, it is ˜20% by mass. When the water-soluble or water-dispersible polyester is less than 10% by mass, the polymerization stability may be lowered. On the other hand, when it exceeds 30% by mass, the water resistance may be lowered.

Of the resin components of the styrene-acrylic resin emulsion, the component derived from the styrene monomer is preferably 10 to 80% by mass, and more preferably 40 to 60% by mass. When the content is less than 10% by mass, a decrease in toughness is observed as a film physical property. When the content is more than 80% by mass, an increase in the amount of film forming auxiliary agent is required due to the problem of film forming property, causing a decrease in film physical properties. There is a tendency.

The glass filler (B) used in the present invention means glass powder, and examples thereof include glass fiber, glass frit, glass flake, and glass beads. These may be used alone or in combination of two or more. Among these, glass frit and glass flake are preferable from the viewpoints of miscibility and durability.

Moreover, the shape of the cross section of the glass filler (B) includes, in addition to a general spherical shape, an irregular cross-sectional shape and a scale-like shape represented by glass flakes. Among them, a spherical shape is preferable from the viewpoint of miscibility and durability.

The glass filler (B) used in the present invention is preferably used in an amount of 25% by mass or more, more preferably 30% by mass or more, and more preferably 45% by mass with respect to the nonvolatile content of the thick film construction aqueous resin composition. % Or more is particularly preferable, and 50% by mass or more is more preferable. When the ratio of the glass filler (B) to the non-volatile content of the thick film construction water-based resin composition is less than 25% by mass, the thick film dryness tends to deteriorate and the water-stopping property, acid resistance, and alkali resistance tend to decrease.

The average particle size of the glass filler (B) used in the present invention is preferably 0.3 mm or less, more preferably 1 μm to 100 μm from the viewpoint of dispersibility. If the average particle size is larger than 0.3 mm, a uniform dispersion in the resin cannot be obtained, a tendency to separate is observed, it becomes difficult to form a uniform film during film formation, and a decrease in film properties (strength and durability) is observed. It is done.

Further, a small amount of an inorganic filler may be added in order to improve the viscosity within the range not impairing the object of the present invention. As the inorganic filler, known and conventional ones may be used. For example, zinc oxide, titanium oxide, calcium carbonate, silicic acid, silicate, kaolin clay, magnesium oxide, satin white, aluminum oxide, talc, mica, calcined clay, water Examples include aluminum oxide and silica. These may be used alone or in combination of two or more.

Furthermore, a small amount of an organic filler may be added in order to improve the viscosity as long as the object of the present invention is not impaired. The organic filler means a powder of an organic polymer that is hardly soluble in water, and preferably has a solubility in 100 g of water at 23 ° C. and 1 atm of 0.1 g or less. Examples of the organic filler include polyethylene, polypropylene, polystyrene, polymethyl methacrylate and copolymers thereof, vinyl acetate and copolymers thereof, saturated polyester (aliphatic ester type / aromatic ester type), cellulose acetate butyrate, Examples thereof include ε-caprolactone polymer, polybutadiene, and polyvinyl chloride. Further, elastomeric polymers such as styrene-butadiene-styrene (SBS) block polymers, starch powder, cellulose powder and the like can be mentioned. These may be used alone or in combination of two or more. Among these, polystyrene, polyethylene, and polypropylene are preferable from the viewpoints of miscibility and durability.

The average particle size of the organic filler is preferably several μm to 300 μm from the viewpoint of dispersibility.

In the aqueous resin composition for thick film construction of the present invention, the solid content ratio of the aqueous synthetic resin emulsion (A) and the glass filler (B) is preferably 7/3 to 3/7, and 6/4 to 4 / 6 is more preferable. If the solid content ratio of the water-based synthetic resin emulsion (A) and the glass filler (B) is larger than 7/3, that is, if the water-based synthetic resin emulsion (A) component is large, the expected drying property cannot be obtained, and the physical properties of the film Even in (strength etc.), good results cannot be obtained. Moreover, when the solid content ratio of the water-based synthetic resin emulsion (A) and the glass filler (B) is less than 3/7, that is, when the glass filler component is large, stability cannot be maintained, and uniform film formation is difficult. Therefore, it is difficult to obtain a sufficient effect in the durability of the film such as water resistance, acid resistance, and alkali resistance.

In addition, a plasticizer, a tackifier resin, a thickener, a curing agent, an antifoaming agent, a preservative, and the like can be appropriately added depending on the purpose of use.

The minimum film formation temperature of the aqueous resin composition for thick film construction of the present invention is preferably 0 to 5 ° C., particularly preferably 0 ° C. If the temperature is higher than 5 ° C., the film tends to be affected by the drying temperature condition, so that the film formability is likely to be deteriorated, and sufficient film durability tends not to be obtained. Adjustment of the minimum film-forming temperature of the water-based resin composition for thick film construction can be achieved by adding a film-forming auxiliary or by synthesizing an aqueous synthetic resin emulsion (A) having a high minimum film-forming temperature with a low minimum film-forming temperature. It can be carried out by a method such as adding the resin emulsion (A).

The water-based resin composition for thick film construction of the present invention preferably has a nonvolatile content of 65 to 80% by mass, and more preferably 65 to 70% by mass. By adjusting the non-volatile content to 65 to 80% by mass, excellent drying properties can be expressed. If the non-volatile content is less than 65% by mass, the drying property becomes insufficient, and many additives are required for ensuring workability. Further, if the non-volatile content exceeds 80% by mass, a stability problem occurs, and a problem arises in workability due to a rapid increase in viscosity.

The aqueous resin composition for thick film construction of the present invention preferably has a viscosity of 8,000 mPa · s or more, more preferably 9,000 to 60,000 mPa · s. By setting the viscosity to 8,000 mPa · s or more, it is possible to perform a 1 mm thick construction in terms of workability. Although different depending on the construction method, 9,000 to 20,000 mPa · S is desirable when spraying or the like is performed, and 20,000 to 60,000 mPa · S is desirable when performing hand painting work such as candy. When the viscosity is lower than 8,000 mPa · s, there is a concern about the occurrence of cracks when applied to a thick film. Moreover, in workability, problems such as sagging tend to occur.

The aqueous resin composition for thick film construction of the present invention preferably has a film thickness of 0.1 to 2.0 mm, more preferably 0.3 to 1.5 mm after being applied to the surface to be treated and dried. . If the film thickness is less than 0.1 mm, there is an influence of the base, but the continuity of the film becomes insufficient due to the occurrence of pinholes, etc., and if it is more than 2.0 mm, it causes a drying delay, and sufficient performance cannot be exhibited. There is a tendency.

The water-based resin composition for thick film construction of the present invention does not contain a solvent or the like, or contains only a small amount of a solvent or the like, and therefore does not generate odor during work, is environmentally friendly, and has excellent drying properties. By applying the water-based resin composition for thick film construction of the present invention to a surface to be treated such as a concrete structure and drying it at room temperature, a protective film having excellent physical properties such as water resistance, acid resistance and alkali resistance is formed. Therefore, it is thought that the durability of the surface to be treated is improved. Here, the concrete structure is a concept including a structure made of ordinary concrete, mortar, or the like.

Examples of the application method of the thick film construction aqueous resin composition of the present invention include spray coating, roller coating, and iron coating. The coating amount (solid content) may be determined as appropriate according to the purpose of protection, preferably ^{^{0.2kg / m 2 ~ 2.0kg / m}} 2, more preferably 0.3kg ^/ m 2 ~ 1. 2 kg / m ² . The coating amount can not form a sufficient film continuous layer is less than 0.2 kg / m ^2, the occurrence of pinholes are concerned, also be a factor of drying retardant is more than 2.0 kg / m ^2, sufficient Tend to cease to perform well.

When applying the water-based resin composition for thick film construction of the present invention to a surface to be treated such as a concrete structure, it is also possible to use an undercoat paint. Examples of the undercoat paint include acrylic emulsion type undercoat paint (primer, sealer), epoxy type undercoat paint, urethane type, undercoat paint and the like. It can also be used as a cement-based primer. For example, examples of the admixture include cement base preparation such as acrylic emulsion, ethylene-vinyl acetate emulsion, and epoxy emulsion.

Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples, but the present invention is not limited thereto. The properties of the resin emulsions of Examples and Comparative Examples, and the properties, drying properties and cracks of the aqueous resin composition were evaluated by the following methods.

(Non-volatile content)
About 1 g of the resin emulsion or aqueous resin composition was weighed on an aluminum dish having a diameter of 5 cm, dried at 105 ° C. for 1 hour, and the remainder was weighed.

(viscosity)
Using a Brookfield type rotational viscometer, the liquid temperature was 23 ° C., the rotational speed was 10 rpm, and the measurement was performed with a rotor.

(Minimum deposition temperature (MFT))
MFT of the water-based resin composition was measured according to JIS K 6828.

(Evaluation of dryness)
A frame is created on a glass plate, and the water-based resin composition is poured into the glass plate so that the film thickness after drying is 2 mm. The surface is dried in an environment of 20 ° C. × 50% RH. The time until no trace was made was measured.

(crack)
In the above evaluation of drying property, the presence or absence of cracks during drying was visually evaluated.
○: No crack occurred ×: Crack occurred

Example 1
As an aqueous synthetic resin emulsion, emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50% by mass, styrene-derived component 50% by mass of resin component, acrylic acid ester-derived component 50% by mass, viscosity 4 , 500 mPa · s, minimum film forming temperature 0 ° C.), and glass frit CF0007-05B (manufactured by Nippon Frit Co., Ltd .: average particle size 5 μm) was used as the glass filler. 50 parts by mass of CF0007-05B was added to 100 parts by mass of the emulsion (1), and the mixture was stirred with a disper at 3,000 rpm for 20 minutes. In addition, 0.05 part by mass of an antifoaming agent (Nopco 8034L: manufactured by San Nopco Co., Ltd.) was added for defoaming to adjust the aqueous resin composition. The obtained aqueous resin composition was filtered with an 80th filter cloth, and it was confirmed that there was no generation of coarse particles and aggregates. The aqueous resin composition of Example 1 was obtained by such a production method. The properties of the obtained aqueous resin composition were a non-volatile content of 66.7% by mass and a viscosity of 12,000 mPa · s.

(Example 2)
As an aqueous synthetic resin emulsion, emulsion (2) (polyester-styrene-acrylic acid ester copolymer, nonvolatile content 51% by mass, polyester-derived component 10% by mass, styrene-derived component 40% by mass, acrylic acid Ester-derived component 50 mass%, viscosity 500 mPa · s, minimum film forming temperature 40 ° C.), and emulsion (3) (styrene-acrylate copolymer, nonvolatile content 58 mass%, styrene-derived component in resin component 10% by mass, 90% by mass of an acrylate-derived component, a viscosity of 3,000 mPa · s, and a minimum film-forming temperature of 0 ° C. It was used. An aqueous resin composition was obtained in the same manner as in Example 1 except that 50 parts by mass of CF0007-05B was added to 50 parts by mass of emulsion (2) and 50 parts by mass of emulsion (3). MFT was adjusted by mixing emulsion (2) and emulsion (3). The properties of the obtained water-based resin composition were a non-volatile content of 69.3% by mass and a viscosity of 11,000 mPa · s.

(Example 3)
As an aqueous synthetic resin emulsion, 100 parts by mass of emulsion (4) (acrylic ester polymer, nonvolatile content 50% by mass, viscosity 2,500 mPa · s, minimum filming temperature 2 ° C.) is used, and CF0007- Aqueous resin composition was prepared in the same manner as in Example 1 except that 50 parts by mass of 05B (manufactured by Nippon Frit Co., Ltd .: average particle size: 5 μm) and 2 parts by mass of Texanol CS-12 as a film forming aid were added. I got a thing. The properties of the obtained water-based resin composition were a non-volatile content of 66.7% by mass and a viscosity of 13,000 mPa · s.

Example 4
As an aqueous synthetic resin emulsion, 100 parts by mass of emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50% by mass, viscosity 4,500 mPa · s, minimum film forming temperature 0 ° C.) is used as a glass filler. An aqueous resin composition was obtained in the same manner as in Example 1 except that 50 parts by mass of CF0002-30A (manufactured by Nippon Frit Co., Ltd .: average particle size 30 μm) was used. The properties of the obtained water-based resin composition were a non-volatile content of 66.7% by mass and a viscosity of 9,000 mPa · s.

(Example 5)
As an aqueous synthetic resin emulsion, 100 parts by mass of emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50% by mass, viscosity 4,500 mPa · s, minimum film forming temperature 0 ° C.) is used as a glass filler. A water-based resin composition was obtained in the same manner as in Example 1 except that 50 parts by mass of microglass glass flake RCF-150 (manufactured by Nippon Sheet Glass Co., Ltd .: average particle size 150 μm) was used. The properties of the obtained water-based resin composition were a non-volatile content of 66.7% by mass and a viscosity of 13,000 mPa · s.

(Comparative Example 1)
Emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50 mass%, viscosity 4,500 mPa · s, minimum film forming temperature 0 ° C.) without adding glass filler, aqueous resin composition of Comparative Example 1 Used as a product.

(Comparative Example 2)
Emulsion (4) (acrylic ester polymer, non-volatile content 50 mass%, viscosity 2,500 mPa · s, minimum film forming temperature 2 ° C.) without adding glass filler is used as the aqueous resin composition of Comparative Example 2. It was.

(Comparative Example 3)
Emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50 mass%, viscosity 4,500 mPa · s, minimum filming temperature 0 ° C.) is used as the water-based synthetic resin emulsion, and CF0007— 05B (manufactured by Nippon Frit Co., Ltd .: average particle size 5 μm) was used. 12.5 parts by mass of CF0007-05B was added to 100 parts by mass of the emulsion (1), and the mixture was stirred with a disper at 3,000 rpm for 20 minutes. In addition, 0.05 part by mass of an antifoaming agent (Nopco 8034L: manufactured by San Nopco Co., Ltd.) was added for defoaming to adjust the aqueous resin composition. The obtained aqueous resin composition was filtered with an 80th filter cloth, and it was confirmed that there was no generation of coarse particles and aggregates. The aqueous resin composition of Comparative Example 3 was obtained by such a production method. The properties of the obtained water-based resin composition were a non-volatile content of 55.6% by mass and a viscosity of 6,500 mPa · s.

(Comparative Example 4)
Emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50 mass%, viscosity 4,500 mPa · s, minimum film forming temperature 0 ° C.) is used as the water-based synthetic resin emulsion, and microglass is used as the glass filler. Flakes RCF-150 (manufactured by Nippon Sheet Glass Co., Ltd .: average particle size 150 μm) was used. 12.5 parts by mass of RCF-150 was added to 100 parts by mass of the emulsion (1), and the mixture was stirred with a disper at 3,000 rpm for 20 minutes. In addition, 0.05 part by mass of an antifoaming agent (Nopco 8034L: manufactured by San Nopco Co., Ltd.) was added for defoaming to adjust the aqueous resin composition. The aqueous resin composition of Comparative Example 4 was obtained by such a production method. The properties of the obtained water-based resin composition were a non-volatile content of 55.6% by mass and a viscosity of 7,500 mPa · s.

(Comparative Example 5)
Emulsion (1) (styrene-acrylic acid ester copolymer, nonvolatile content 50 mass%, viscosity 4,500 mPa · s, minimum film forming temperature 0 ° C.) is used as the water-based synthetic resin emulsion, and CF007— 05B (Nippon Frit Co., Ltd .: average particle size 5 μm) and CF0002-30A (Nippon Frit Co., Ltd .: average particle size 30 μm) were used. 100 parts by mass of CF-007-05B and 100 parts by mass of CF0002-30A were added to 100 parts by mass of the emulsion (1), and the mixture was stirred with a disper at 3,000 rpm for 20 minutes. In addition, 0.1 part by mass of an antifoaming agent (Nopco 8034L: manufactured by San Nopco Co., Ltd.) was added for defoaming to adjust the aqueous resin composition. The obtained aqueous resin composition was filtered with an 80th filter cloth, and it was confirmed that there was no generation of coarse particles and aggregates. The aqueous resin composition of Comparative Example 5 was obtained by such a production method. The properties of the obtained water-based resin composition were a non-volatile content of 83.3 mass% and a viscosity of 100,000 mPa · s or more.

(Evaluation of acid resistance and alkali resistance)
Evaluation of acid resistance / alkali resistance was carried out using a film prepared by the following method. The aqueous resin composition obtained in each Example and each Comparative Example was poured onto a glass plate on which a release film was pasted so as to be 10 g (solid content) per 100 cm ² . The aqueous resin composition poured onto the glass plate was dried at room temperature for 2 days, vacuum dried for 1 day, and further dried at 40 ° C. for 12 hours to form a film.

The swelling rate and elution rate in the acid resistance evaluation were obtained by cutting the prepared film into 40 mm × 40 mm, measuring the mass, and then dipping in a 10% sulfuric acid aqueous solution at 40 ° C. for 7 days. The immersed film was taken out, the mass was measured, and the swelling ratio was calculated by dividing the increase from the mass before immersion by the mass before immersion. The dissolution rate was calculated by measuring the mass after drying the immersed film at 40 ° C. for 12 hours, and dividing the decrease from the mass before immersion by the mass before immersion.

The film strength retention rate and the film elongation retention rate in the acid resistance evaluation were performed by the following methods. The created film was cut out to 10 mm × 30 mm, a tensile test was performed at a tensile speed of 100 mm / min, and the strength and elongation of the film before being immersed in a 10% sulfuric acid aqueous solution were measured from the maximum strength and the elongation of a marked line of 10 mm. . Next, the prepared film was cut into 10 mm × 30 mm separately, immersed in a 10% sulfuric acid aqueous solution at 40 ° C. for 7 days, and dried at 40 ° C. for 12 hours. Then, the strength and elongation of the immersed film were measured. The film strength retention is calculated by dividing the strength of the film after immersion by the strength of the film before immersion, and the film elongation retention is the elongation of the film after immersion as the elongation of the film before immersion. Calculated by dividing.

In the alkali resistance evaluation, the same method as in the acid resistance evaluation was performed except that a saturated calcium hydroxide aqueous solution was used instead of the 10% sulfuric acid aqueous solution.

(Appearance change)
In addition, in order to evaluate the appearance change, after creating a test piece covering the entire surface of the JIS mortar plate with a water-based resin composition to a thickness of 2 mm, immersed in a 10% sulfuric acid aqueous solution and a saturated calcium hydroxide aqueous solution for 30 days, The presence or absence of appearance changes such as blistering and cracking was visually evaluated.
○: No abnormal appearance (bulging, cracking, etc.)
○-: Small bulges at the end of the specimen △: Small bulges / cracks occur on the surface and end of the specimen XX: Swells and cracks of 1 mm or more occur in the specimen

As can be seen from the results of Tables 1 and 2, the thick film construction aqueous resin compositions of Examples 1, 2, 3, 4 and 5 were compared with those of Comparative Examples 1, 2, 3, and 4, Good results were seen that the drying property was good and no thick film cracks were generated. Moreover, as can be seen from the results of Tables 3 and 4, the films prepared from the aqueous resin compositions for thick film construction of Examples 1, 2, 3, 4 and 5 were eluted as compared with those of the comparative examples. The rate and swelling rate were low, and the acid resistance was found to be significantly superior. Also in the alkali resistance, the resistance was sufficiently improved. Further, it was confirmed that even when immersed in a 10% sulfuric acid solution and a saturated aqueous calcium hydroxide solution for 30 days, there was no change in appearance such as swelling and cracking.

Claims

An aqueous resin composition for thick film construction, comprising an aqueous synthetic resin emulsion (A) and a glass filler (B) and having a nonvolatile content of 65 to 80% by mass.
The aqueous resin composition for thick film construction according to claim 1, wherein the viscosity is 8,000 mPa · s or more.
3. The thick film construction water-based resin composition according to claim 1, wherein the glass filler (B) is 25% by mass or more based on a nonvolatile content of the thick film construction water-based resin composition.
The aqueous system for thick film construction according to any one of claims 1 to 3, wherein the solid content ratio of the aqueous synthetic resin emulsion (A) and the glass filler (B) is 7/3 to 3/7. Resin composition.
The aqueous resin composition for thick film construction according to any one of claims 1 to 4, wherein an average particle size of the glass filler (B) is 0.3 mm or less.
The aqueous resin composition for thick film construction according to any one of claims 1 to 5, wherein the aqueous synthetic resin emulsion (A) is a styrene-acrylic resin emulsion or an acrylic resin emulsion.
A coating film having a film thickness of 0.1 to 2.0 mm is formed by applying the aqueous resin composition for thick film construction according to any one of claims 1 to 6 to a surface to be treated and drying it. A surface treatment method to be treated.
A method for treating a surface of a concrete structure, comprising applying the aqueous resin composition for thick film construction according to any one of claims 1 to 6 to a concrete structure and drying the concrete structure.