WO2011146087A1 - Contenants en carton scellés hermétiquement à performance de barrière améliorée - Google Patents

Contenants en carton scellés hermétiquement à performance de barrière améliorée Download PDF

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Publication number
WO2011146087A1
WO2011146087A1 PCT/US2010/057005 US2010057005W WO2011146087A1 WO 2011146087 A1 WO2011146087 A1 WO 2011146087A1 US 2010057005 W US2010057005 W US 2010057005W WO 2011146087 A1 WO2011146087 A1 WO 2011146087A1
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WO
WIPO (PCT)
Prior art keywords
barrier
container
layer
polyethylene
paperboard
Prior art date
Application number
PCT/US2010/057005
Other languages
English (en)
Inventor
Qihua Xu
Todd Huffman
Timothy Mclaughlin
Zhiquan Q Yan
Original Assignee
Meadwestvaco Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2010/035704 external-priority patent/WO2010135613A1/fr
Application filed by Meadwestvaco Corporation filed Critical Meadwestvaco Corporation
Priority to PCT/US2010/057005 priority Critical patent/WO2011146087A1/fr
Priority to CN2010800681614A priority patent/CN102985325A/zh
Priority to BR112012029568A priority patent/BR112012029568A2/pt
Priority to EP10782768A priority patent/EP2571772A1/fr
Publication of WO2011146087A1 publication Critical patent/WO2011146087A1/fr
Priority to US13/567,385 priority patent/US20120298733A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D3/00—Rigid or semi-rigid containers having bodies or peripheral walls of curved or partially-curved cross-section made by winding or bending paper without folding along defined lines
    • B65D3/22—Rigid or semi-rigid containers having bodies or peripheral walls of curved or partially-curved cross-section made by winding or bending paper without folding along defined lines with double walls; with walls incorporating air-chambers; with walls made of laminated material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31C—MAKING WOUND ARTICLES, e.g. WOUND TUBES, OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31C1/00—Making tubes or pipes by feeding at right angles to the winding mandrel centre line
    • B31C1/06—Making tubes or pipes by feeding at right angles to the winding mandrel centre line and inserting into a tube end a bottom to form a container
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/10—Container closures formed after filling
    • B65D77/20—Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
    • B65D77/2024—Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers the cover being welded or adhered to the container
    • B65D77/2028—Means for opening the cover other than, or in addition to, a pull tab
    • B65D77/2032—Means for opening the cover other than, or in addition to, a pull tab by peeling or tearing the cover from the container

Definitions

  • Paper-based containers with barrier properties are typically formed from paper-based blank comprising paperboard substrate and functionalized layers such as oxygen and moisture barrier layers.
  • the blank is die cut to the desired silhouette and then formed into a shape by wrapping it once around a mandrel.
  • the overlapping ends of the blank form a straight seam having an underlying portion and an overlying portion.
  • FIG.l shows a cross sectional view of the container body 100 made by overlapping ends of the blank 101 into a straight seam having an underlying portion 102 and an overlying portion 103.
  • the raw edge 104 of the underlying portion of the seam is exposed to the container content, resulting in a reduction of the barrier performance of the container.
  • Several techniques have been reported to prevent the raw edge 104 of the seam from being exposing to the packaged content.
  • One approach is to cover the exposed raw edge of the blank with a strip of barrier tape.
  • U.S. Patent No. 5,620,135 discloses a technique for covering the raw edge of the body with a protective covering tape.
  • PCT Application No. WO 2003/106277 discloses a single wrap container having the exposed underlying edge of the paper-based container body enclosed by a tape that comprises a layer of metalized PET interposed between layers of LDPE.
  • Using protective tapes to cover the raw edges has several drawbacks.
  • the adhered protective tape is an additional cost, and may be easily removed. Furthermore, an additional process is required to apply the protective tapes, resulting in further increase in cost and complexity of the manufacturing process.
  • Another approach commonly used in multiply tubular container process is to fold the underlying edge portion of the barrier liner ply into an "anaconda" fold, wherein the underlying edge is folded back on itself and adhere to the overlying edge.
  • An example of such a fold is illustrated in U.S. Patent No. 5,084,284.
  • the main drawback of anaconda fold is the undesired increase in thickness of the seam, as it is three times the thickness of the blank. Cracks tend to form with such high thickness, resulting in a leakage of the contents, an influx of the outside air, and a reduction in barrier performance of the containers.
  • U.S. Patent No. 6,190,485 discloses the production of a hermetically sealed spiral-wound multi-ply container without using "anaconda" fold.
  • this process is based on the use of continuous webs of paperboard ply and liner ply, which requires rather intensive handlings, relatively high shipping and storage costs.
  • a paper-based container comprising a hollow container body having recessed structure on the upper and lower ends, a top lip positioning on the recessed top of the container body, and a bottom positioning on the recessed bottom.
  • the hollow container body is produced by skiving one longitudinal end of a paper-based blank to substantially half its thickness for a predetermined width and then forming a longitudinal groove substantially at the center of the skived portion.
  • a heat- resistant adhesive is applied to the skived portion and irradiated with infrared rays to evaporate water contained therein.
  • the skived portion is then folded about the groove so that the end face of the skived paper and the end face of the unskived portion contact each other. .
  • This process of producing barrier container is, however, rather complicated and high cost due to the use of adhesives and the recessed structure of the upper and lower ends.
  • hermetically sealed paperboard containers with enhanced barrier and seal performances that may be produced by a process that is more effective and economical using commercially available high-speed liquid packaging skiving/hemming/sealing equipment and cup forming machines without the use of adhesives.
  • One advantage of such approach is the potential for the in-plant system, where skived blanks can be shipped flat to the packaging plant where the barrier cups are formed using in-plant cup forming machines.
  • a hermetically-sealed paperboard container may be produced using a conventional converting machine but at a converting temperature of at least 93° C lower than a conventional converting temperature.
  • the formation of pin holes or rupture on the barrier structure during the converting process can be significantly reduced, resulting in the hermetically-sealed paperboard container with enhanced barrier performances.
  • FIG. 1 shows a cross sectional view of the paperboard container body of prior arts, wherein the overlapping ends of the blank form a seam with a raw edge exposed to the packaged content;
  • FIG. 2 shows an example of the typical multilayer barrier structure for the formation of paperboard containers with barrier performance
  • FIG. 3 shows one embodiment of the disclosed multilayer barrier structure
  • FIG. 4 shows a schematic illustration of the formation of container body, wherein the folded longitudinal end of the blank is overlapped inside the other longitudinal end of the blank to form a side seam;
  • FIG. 5 shows one embodiment of the disclosed hermetically-sealed paperboard container, comprising a container body component with a rolled rim on the upper end and a recessed configuration at the lower end, a top lid, and a bottom
  • FIG. 2 shows an example of the typical multilayer material A for the production of containers having barrier performance.
  • the paperboard substrate 1A is coated one side with a heat sealant layer 2A and the other side with a barrier structure, which comprises low density polyethylene (LDPE) polymer 3A, barrier polymer 4A, and tie layer 5A.
  • LDPE low density polyethylene
  • barrier polymer 4A barrier polymer 4A
  • tie layer 5A a layer of heat sealant layer 6A is applied onto the surface of tie layer 5A.
  • the barrier structure may be applied onto the paperboard substrate 1A by co-extrusion of LDPE polymer 3A, EVOH polymer 4A, and tie layer A5.
  • the hermetically-sealed container formed from the multilayer structure of FIG. 2 typically shows insufficient barrier performance, such as oxygen barrier, for various end use packaging applications. This is due to the pin holes or ruptures in the barrier structure formed during the converting process of the multilayer structure into the container. As a result, the formed container exhibits such high oxygen transmission rate that it would not meet shelf life target of 12 to 18 months commonly required for hermetical packaging applications.
  • the formation of pinholes or rupture may be due to the excessive temperatures used during the cup forming (i.e., converting) process, as well as the film breakage due to bottom seal separation by paperboard memory force.
  • the multilayer materials of the present disclosure allow for the converting process into hermetically-sealed container at much lower temperature ranges compared to the standard converting temperatures, thus reducing the formation of pin holes or ruptures in the barrier structure during the converting process.
  • the disclosed multilayer barrier structure may be converted into a hermetically-sealed container at 200° F (93° C) lower than the standard converting temperatures. The formations of pin holes and ruptures during the converting process may be reduced, resulting in the hermetically-sealed container with improved barrier performance. Additionally, the disclosed multilayer barrier materials may provide an improved hot tack strength and overall bond strength.
  • the disclosed multilayer barrier materials may be designed to optimize the barrier performance of the formed hermetically-sealed containers for various packaging end use applications.
  • the barrier structure may be designed for improved gas barrier performance, such as oxygen barrier, with some other barrier properties such as water vapor barrier performance.
  • the disclosed barrier multilayer material comprises:
  • barrier-containing structure positioned on the second side of the substrate, wherein the barrier-containing structure includes at least:
  • a layer comprising a specialized low melting point polyethylene-based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C.
  • the suitable specialized low melting point polyethylene-based polymers having the density and melting point properties in the aforementioned ranges may include, but are not limited to, very low density polyethylene (VLDPE), ionic polyethylene copolymer, and combinations thereof.
  • VLDPE very low density polyethylene
  • ionic polyethylene copolymer ionic polyethylene copolymer
  • VLDPE is recognized by ones skilled in the arts as a substantially linear PE polymer with high levels of short-chain branches that is commonly made by
  • VLDPE polymer is generally characterized by a density range of 0.880-0.915 g/cm 3 .
  • the specialized low melting point polyethylene-based polymer may be a very low density polyethylene having a density range of 0.880 g/cm 3 to 0.915 g/cm 3 and a melting point range of 80° C to 120° C.
  • the specialized low melting point polyethylene-based polymer may be ionic polyethylene copolymers.
  • copolymers include, but are not limited to, SURLYN ® ethylene/methacrylic acid polymers commercially available from Dupont, such as SURLYN ® 1652 with a density of 0.94g/cm 3 and a melting point of 100° C.
  • ethylene/methacrylic acid polymers are disclosed as mere examples, and other
  • polyethylene-based polymers having the specified density and melting point ranges may be readily used in the present disclosure.
  • the barrier-containing structure is performed and then positioned onto the surface of substrate, which may be achieved various known application methods. These application methods may include, but are not limited to, adhesive lamination.
  • each layer component of the barrier-containing structure is co-extruded onto the surface of substrate.
  • each layer component of the barrier-containing structure is applied consecutively onto the surface of substrate.
  • barrier-containing structure may be placed onto the surface of substrate by any other appropriate application techniques, and the aforementioned three embodiments are merely examples.
  • FIG. 3 illustrates one embodiment of the disclosed multilayer barrier material.
  • the multilayer material B comprises a substrate IB; a first heat sealant layer 2B positioned on one side of the substrate; a barrier-containing structure positioned on the other side of the substrate, and optionally, a tie layer 7B positioned between the substrate IB and the barrier-containing structure 3B.
  • the barrier-containing structure may further include at least one of layer of PE-polymer, tie layer, and adhesive tie layer.
  • the barrier-containing structure 3B includes a layer of PE-based polymer 4B, a layer of barrier material 5B, and a layer of specialized low melting point polyethylene-based polymer 6B.
  • the total thickness of the barrier-containing structure 3B is in a range of about 2.0 mils to 4.0 mils. In one embodiment, its thickness is about 3.0 mils.
  • barrier materials may be used in the present disclosure, and its selection depends on the desired level of barrier performance.
  • suitable barrier materials include, but are not limited to, ethylene-vinyl alcohol copolymer (EVOH), nylons, polyethylene terephthalate (PET), polyamide, polyvinylidene chloride, cyclic olefin copolymer, metalized polymer film, materials derived from water-based barrier coatings, and combinations thereof.
  • EVOH ethylene-vinyl alcohol copolymer
  • PET polyethylene terephthalate
  • polyamide polyamide
  • polyvinylidene chloride polyvinylidene chloride
  • cyclic olefin copolymer metalized polymer film
  • materials derived from water-based barrier coatings and combinations thereof.
  • water-based barrier coatings known for imparting the barrier properties to paperboard may be used in the present disclosure to provide a barrier layer.
  • the water-based barrier coatings may include nanoparticles to provide the tortuous effect that hinders the diffused
  • the thickness of the barrier polymer layer may be optimized to provide barrier performance suitable for the selected end use applications.
  • the EVOH may be used as a barrier material for 5B and its layer thickness is tailored to meet the desired oxygen barrier performance of less than 10 cc/100 in 2 /atm/day at a temperature of 23° C and at 0% relative humidity.
  • the EVOH layer thickness is in a range of 0.25 mils to 0.75 mils.
  • the EVOH layer thickness is in a range of 0.25 mils to 0.50 mils.
  • the EVOH layer thickness is in a range of 0.25 mils to 0.40 mils.
  • the specialized low melting point polyethylene-based polymer included in layer 6B in FIG. 3 of the barrier-containing structure 3B has a melting point range of about 80° C to 120° C.
  • the specialized low melting point polyethylene-based polymer has a melting point range of about 100° C to 110° C.
  • the suitable low melting point polyethylene-based polymers having the density and melting point properties in the aforementioned ranges may include, but are not limited to, very low density polyethylene (VLDPE), ionic polyethylene copolymer, and combinations thereof.
  • VLDPE very low density polyethylene
  • ionic polyethylene copolymer ionic polyethylene copolymer
  • the thickness of this 6B layer may be a range of about 0.75 mils to 2.0 mils, which is about 19 mm to 50 mm. In one embodiment, the thickness of this layer may be in a range of about 1.0 mil to 1.6 mils.
  • the barrier-containing structure may further include a layer of PE-based polymer (shown as 4B in the FIG. 3).
  • the PE-based polymer 4B is a linear low density polyethylene (LLDPE) and its layer thickness is tailored to meet the desired performance of the final multilayer barrier structure. In one embodiment, its thickness is in a range of 1.00 mils to 1.60 mils. In one embodiment, its thickness is in a range of 1.20 mils to 1.30 mils.
  • LLDPE linear low density polyethylene
  • Suitable sealant polymers for the 2B layers of the present disclosure may include, but are not limited to, polyester; low density polyethylene (LDPE); high density polyethylene (HDPE); ethylene-vinyl acetate copolymer (EVA); ethylene methyl acrylate (EMA) copolymer; ionomer polymers such as poly(ethylene-co-methacrylic acid) (EMAA) copolymer SURLYN ® commercially available from DuPont; and combinations thereof. fill) The Substrate
  • a variety of paperboard may be used as the substrate. These include, but are not limited to, coated natural kraft board (CNK board), solid bleached sulfate board (SBS), solid unbleached sulfate board (SUS), coated recycled board (CRB), coated white lined chipboard (WLC), folding boxboard (FBB), and other paperboard grades suitable for cup formation.
  • CK board coated natural kraft board
  • SBS solid bleached sulfate board
  • SUS solid unbleached sulfate board
  • CB coated recycled board
  • WLC coated white lined chipboard
  • FBB folding boxboard
  • various substrates known for packaging applications may be used as the substrate.
  • these substrates include, but are not limited to, paper-based material such as paperboard; plastics; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the disclosed multiple barrier material B may include a tie layer 7B positioned between the substrate IB and the barrier-containing structure 3B.
  • Any known tie layer materials may be used in the present disclosure.
  • this optional lie layer may be adhesive tie layer.
  • the PE-based polymer is used as an optional tie layer. Examples of such PE-based polymers suitable for the 7B layers may include, but are not limited to, low density polyethylene (LDPE); high density polyethylene (HDPE); and combinations thereof.
  • the 7B layer is made of LDPE polymer. Formation of the Body Component
  • the disclosed multilayer barrier material is die cut to a desired silhouette to provide a blank including a first and a second longitudinal ends.
  • the first longitudinal end of the blank is skived to a predetermined thickness for a predetermined width.
  • the resulting skived end of the blank is treated with heat, then folded and sealed over the blank to provide the folded first longitudinal end.
  • the container body component 400 is formed by overlapping both longitudinal ends of the blank such that the folded first longitudinal end 401 is inside the second longitudinal end 402, and subsequently the overlapped seam is sealed.
  • the lid component may be derived from any material having appropriate barrier properties for the selected end use applications of the hermetically-seal containers.
  • the lid component comprises plastic; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the lid component comprises a substrate and a layer of barrier material positioned on at least one surface of the substrate.
  • the lid component comprises:
  • barrier-containing structure positioned on at least one surface of the substrate, the barrier-containing structure including:
  • a layer comprising a specialized low melting point polyethylene-based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C.
  • the suitable specialized low melting point polyethylene-based polymers having the density and melting point properties in the aforementioned ranges may include, but are not limited to, very low density polyethylene (VLDPE), ionic polyethylene copolymer, and combinations thereof.
  • Suitable substrates for the lid component may include, but not limited to, paper-based material such as paperboard; plastics; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the lid component comprises a paperboard, a layer of barrier material or of barrier-containing structure on at least one surface of the paperboard, and a sealant layer positioned over the layer of barrier material or of barrier-containing structure.
  • the lid component may be made of the same or similar material as that for the body component.
  • hermetically sealing the lid component to the body component examples include, but are not limited to, hermetically seal the top with a plastic rim; a sealant bead dropped at the step-down area; a sealant bead added to the entire top rim before lidding; a lidding material with a heavy sealant such as those lidding film used for sealing barrier trays; a higher sealing pressure to press down lidding material to flatten the rim for maximum seal; and combinations thereof.
  • the bottom component may be derived from any material having appropriate barrier properties for the selected end use applications of the hermetically-seal containers.
  • the bottom component comprises plastic; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the bottom component comprises a substrate and a layer of barrier material positioned on at least one surface of the substrate.
  • the bottom component comprises:
  • barrier-containing structure positioned on at least one surface of the substrate, the barrier-containing structure including:
  • a layer of barrier material (i) a layer of barrier material, and (ii) a layer comprising a specialized low melting point polyethylene-based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C.
  • the suitable specialized low melting point polyethylene-based polymers having the density and melting point properties in the aforementioned ranges may include, but are not limited to, very low density polyethylene (VLDPE), ionic polyethylene copolymer, and combinations thereof.
  • VLDPE very low density polyethylene
  • ionic polyethylene copolymer ionic polyethylene copolymer
  • Suitable substrates for the bottom component may include, but not limited to, paper-based material such as paperboard; plastics; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the bottom component comprises a paperboard, a layer of barrier material or of barrier-containing structure on at least one surface of the paperboard, and a sealant layer positioned over the layer of barrier material or of barrier-containing structure.
  • the bottom component may be made of the same or similar material as that for the body component.
  • the bottom component may be formed by die-cutting a roll stock, then assembled to the lower end of the body component and hermetically sealed.
  • the body component may be joined with the bottom component by wrapping the body component around the bottom component.
  • the roll stock used for the bottom component may be the same multilayer structure as that for the body component.
  • the bottom may be assembled to the body component by various sealing technologies.
  • sealing may include, but not limited to, hot air heat seal and ultrasound sealing.
  • the sealing process may be optimized based on various factors. Some of these factors include, but are not limited to, the thickness of the sealant layer on the bottom; and the processing conditions such as lower sealing temperature to prevent the formation of pinhole, and higher sealing pressure to minimize the formation of gap between the bottom and the body component.
  • the configuration of the upper and lower ends of the body may be constructed to support the sealing with the lid and the bottom components. Any known configurations for the upper and lower ends of the container body may be used in the present disclosure, and the selection of such
  • the configuration depends on the desired packaging applications of the container.
  • Examples of the configurations for the upper and lower ends of the container body may include, but are not limited to, recessed structure, rolled bead, flange, and combinations thereof.
  • the disclosed multilayer barrier materials may be converted to hermetically- sealed containers with improved barrier performance using the standard cup converting machine and by a careful selection and control of converting process conditions, such as sealing time, temperature and pressure.
  • a typical cup forming machine consists of a blank feeding system, heating elements, carousal forming station, bottom stock web feeding and die cutting, rim curl station, transport system, and a packaging/inspection station.
  • the heating elements provide a controlled heating process to activate the sealant layer.
  • the heating elements are applied for a side seam of the container body component, as well as for the sealing between the container body component and bottom component of the cup.
  • the typical heating method is by blowing hot air through multiple nozzles to the selected areas of the structure. Nonetheless, other heating methods may be used to activate the sealant such as infrared heating.
  • the temperature of the hot air needed to activate the sealant is highly dependent on the sealant composition and speed of the machine (i.e., sealing time).
  • the disclosed hermetically-sealed paperboard container with enhanced barrier performance comprises:
  • A a body component including an upper end, a lower end, and a skive-and-hem side seal, wherein the body component is formed from a multilayer barrier material comprising:
  • barrier-containing structure includes:
  • a layer comprising a specialized low melting point polyethylene- based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C;
  • At least one of the bottom component and the lip component is made of the same multilayer barrier material as that of the body component.
  • At least one of the bottom component and the lip component is made of a material including paper-based material such as paperboard;
  • plastics such as aluminum foil; metallized film; and combinations thereof.
  • At least one of the bottom component and the lip component is made of a multilayer barrier material comprising:
  • barrier-containing structure positioned on the second side of the substrate, wherein the barrier-containing structure includes:
  • layer comprising a specialized low melting point polyethylene-based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C.
  • Examples of substrates include, but not limited to, paper-based material such as paperboard; plastics; foil-based materials such as aluminum foil; metallized film; and combinations thereof.
  • the method of producing a hermetically-sealed paperboard container of the present disclosure comprises steps of:
  • barrier-containing structure includes:
  • layer comprising a specialized low melting point polyethylene-based polymer positioned over the layer of barrier material, the specialized polyethylene-based polymer having a density range of 0.75 g/cm 3 to 1.00 g/cm 3 and a melting point range of 80° C to 120° C;
  • FIG. 5 shows one embodiment of the disclosed hermetically-sealed paperboard container.
  • the container 500 includes a body component 501, a lid component 502, and a bottom component 503.
  • the upper end of the body 501 is rolled over so as to form a bead or flange 504, while the bottom end of the body 501 is constructed into a recessed configuration 505.
  • the lid component 502 is hermetically sealed onto the upper end of the body 501 at the processing conditions that provides the adhesion between the sealant layer 502B of the lid component 502 and the sealant layer 501B of the body 501 at the contact point 506.
  • the bottom 503 component is placed and sealed into the recessed end of the body 501 so that there is adhesion between the sealant layer 503B of the bottom component 503 and the sealant layer 501B of the body 501 at the contact point 507, and the sealant completely fills any gap 507 between the bottom component 503 and the body 501.
  • the disclosed hermetically-sealed paperboard containers are produced from the flat blanks of paperboard having functionalized coating layers, rather than continuous webs of paperboard ply and inner ply of functionalized layers.
  • the flat blanks used in the present disclosure may be shipped and stored flat; therefore, a substantial saving may be achieved due to a reduced storage and shipping costs. Furthermore, the handling efficiency during manufacturing production may be improved significantly because of the compactness of the flat blanks.
  • the disclosed hermetically-sealed containers have excellent barrier
  • the disclosed multilayer barrier materials may be converted to hermetically- sealed containers with improved barrier performance using the standard cup converting machine and by a careful selection and control of converting conditions, such as sealing time, temperature and pressure.
  • TABLE 1 shows the temperatures of hot air needed for preheating and heating the sealant layer prior to a formation of the hermetically-sealed container.
  • the multilayer barrier material of FIG. 3, which is one embodiment of the present disclosure, was used to form hermetically-sealed cup using the convention cup forming machine.
  • the multilayer material of FIG. 2, which is typically used for barrier packaging applications, was used as a control for comparing the converting temperatures needed for the disclosed hermetically- sealed container versus the convention container.
  • the formed containers were tested for pin holes. A red dye solution was dispensed in the formed container and allowed to flow along the bottom seal. After 5 minutes, the container was rinsed out with water, and the pin holes were recognized as red stains.
  • the disclosed multilayer barrier structure allows for a lower converting temperature compared to the typical temperatures needed for the standard converting process.
  • TABLE 1 indicates that the converting temperature may be reduced by at least about 200° F (93° C) when the disclosed multilayer barrier material was used instead of the typical multilayer material. Additionally, the amounts of pin holes formed during the converting process of the disclosed multilayer barrier structure were reduced, if not completely eliminated, which may be due to the lower converting temperature needed compared to the standard converting temperature. Excessive heating is known to cause pin holes in the multilayer structure during the cup forming process.
  • the oxygen barrier performance of the disclosed hermetically-sealed barrier containers was determined based on the oxygen transmission rate (OTR) at 23° C and 0% relative humidity.
  • OTR oxygen transmission rate
  • the container made of the disclosed body component and bottom component was sealed with an aluminum foil lid. Then, the lid was penetrated with inlet and outlet copper pipes and hermetically-sealed with hot melt glue.
  • the inlet was connected to nitrogen supply at a flow rate setting of 10 cc/min.
  • the outlet was connected to the oxygen detector. The readings are taken as the OTR value until the oxygen level reached a stable constant.
  • OTR oxygen transmission rate
  • the disclosed hermetically-sealed barrier containers produced from multilayer structure of FIG. 3 consistently provided OTR below 0.22 cc/100 in 2 /atm/day. Additionally, the
  • hermetically-sealed barrier containers with even further enhanced OTR performance may be achieved.
  • the disclosed hermetically-sealed barrier containers having an OTR of less than 0.10 cc/100 in 2 /atm/day may be obtained for some end use applications.
  • the converting process and the multilayer barrier material may be optimized to provide the hermetically-sealed barrier containers having an OTR range of 0.01-0.10 cc/100 in 2 /atm/day.
  • the disclosed hermetically-sealed barrier container has an OTR range of 0.008-0.056/100 in 2 /atm/day.
  • the disclosed hermetically-sealed paperboard containers provide excellent barrier performance without the need for metal foils or metal lids to impart the barrier properties.
  • the barrier performance of the disclosed container may reach the same excellent level of that for composite cans, while offering benefits of much lighter weight and efficient transportation due to nestability.
  • the disclosed hermetically-sealed barrier containers are suitable as packaging materials of various goods.
  • Examples of such goods include, but are not limited to, snacks, confectionery, soup, chilled ready meal, and meats.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Wrappers (AREA)

Abstract

L'invention porte sur un contenant en carton scellé hermétiquement qui peut être fabriqué à l'aide d'une machine de transformation classique mais à une température de transformation d'au moins 93°C inférieure à une température de transformation classique. La formation de trous d'échappement d'air ou d'une rupture sur la structure de barrière pendant le processus de transformation peut être considérablement réduite, conduisant à un contenant en carton scellé hermétiquement à performance de barrière améliorée.
PCT/US2010/057005 2010-05-21 2010-11-17 Contenants en carton scellés hermétiquement à performance de barrière améliorée WO2011146087A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PCT/US2010/057005 WO2011146087A1 (fr) 2010-05-21 2010-11-17 Contenants en carton scellés hermétiquement à performance de barrière améliorée
CN2010800681614A CN102985325A (zh) 2010-05-21 2010-11-17 具有改进阻挡层性能的密封纸板容器
BR112012029568A BR112012029568A2 (pt) 2010-05-21 2010-11-17 recipientes de papelão hermeticamente vedados com desempenho de barreira aperfeiçoado
EP10782768A EP2571772A1 (fr) 2010-05-21 2010-11-17 Contenants en carton scellés hermétiquement à performance de barrière améliorée
US13/567,385 US20120298733A1 (en) 2010-05-21 2012-08-06 Hermetically Sealed Paperboard Container

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
USPCT/US2010/035704 2010-05-21
PCT/US2010/035704 WO2010135613A1 (fr) 2009-05-21 2010-05-21 Réceptacle en carton fermé hermétiquement à performance de barrière améliorée
PCT/US2010/057005 WO2011146087A1 (fr) 2010-05-21 2010-11-17 Contenants en carton scellés hermétiquement à performance de barrière améliorée

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/035704 Continuation-In-Part WO2010135613A1 (fr) 2009-05-21 2010-05-21 Réceptacle en carton fermé hermétiquement à performance de barrière améliorée

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/567,385 Continuation-In-Part US20120298733A1 (en) 2010-05-21 2012-08-06 Hermetically Sealed Paperboard Container

Publications (1)

Publication Number Publication Date
WO2011146087A1 true WO2011146087A1 (fr) 2011-11-24

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ID=43566698

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Application Number Title Priority Date Filing Date
PCT/US2010/057005 WO2011146087A1 (fr) 2010-05-21 2010-11-17 Contenants en carton scellés hermétiquement à performance de barrière améliorée

Country Status (3)

Country Link
EP (1) EP2571772A1 (fr)
CN (1) CN102985325A (fr)
WO (1) WO2011146087A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014025519A1 (fr) * 2012-08-06 2014-02-13 Meadwestvaco Corporation Contenant en carton hermétiquement fermé
WO2020053474A1 (fr) 2018-09-11 2020-03-19 Ch-Polymers Oy Procédé d'étanchéification de carton
WO2020125832A1 (fr) * 2018-12-20 2020-06-25 Schropp Gmbh & Co. Kg Récipient en papier d'herbe
WO2022047113A1 (fr) * 2020-08-27 2022-03-03 Sonoco Development, Inc. Ensembles récipients dotés de fermetures d'extrémité à base de papier
CN116196641A (zh) * 2022-09-08 2023-06-02 广州泽力医药科技有限公司 一种复合蔬菜汤料包的制备工艺
US12122584B2 (en) 2021-08-27 2024-10-22 Sonoco Development, Inc. Container assemblies with paper-based end closures

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WO2015153854A1 (fr) 2014-04-03 2015-10-08 Printpack Illinois, Inc. Feuilles de thermoformage et récipients thermoformés préparés à partir de celles-ci
CN108860888B (zh) * 2018-08-29 2023-10-20 刘文钦 一种可以强化纸杯卷边盖合的结构
KR20210076850A (ko) * 2019-12-16 2021-06-24 쇼와 덴코 패키징 가부시키가이샤 컵형상 용기 및 그 제조 방법

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014025519A1 (fr) * 2012-08-06 2014-02-13 Meadwestvaco Corporation Contenant en carton hermétiquement fermé
WO2020053474A1 (fr) 2018-09-11 2020-03-19 Ch-Polymers Oy Procédé d'étanchéification de carton
WO2020125832A1 (fr) * 2018-12-20 2020-06-25 Schropp Gmbh & Co. Kg Récipient en papier d'herbe
WO2022047113A1 (fr) * 2020-08-27 2022-03-03 Sonoco Development, Inc. Ensembles récipients dotés de fermetures d'extrémité à base de papier
US12122584B2 (en) 2021-08-27 2024-10-22 Sonoco Development, Inc. Container assemblies with paper-based end closures
CN116196641A (zh) * 2022-09-08 2023-06-02 广州泽力医药科技有限公司 一种复合蔬菜汤料包的制备工艺
CN116196641B (zh) * 2022-09-08 2024-05-03 广州泽力医药科技有限公司 一种复合蔬菜汤料包的制备工艺

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CN102985325A (zh) 2013-03-20

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