WO2011144198A1 - Transport et stockage d'hydrogène - Google Patents

Transport et stockage d'hydrogène Download PDF

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Publication number
WO2011144198A1
WO2011144198A1 PCT/DE2011/000422 DE2011000422W WO2011144198A1 WO 2011144198 A1 WO2011144198 A1 WO 2011144198A1 DE 2011000422 W DE2011000422 W DE 2011000422W WO 2011144198 A1 WO2011144198 A1 WO 2011144198A1
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WO
WIPO (PCT)
Prior art keywords
hydrogen
natural gas
gas
mixture
deposit
Prior art date
Application number
PCT/DE2011/000422
Other languages
German (de)
English (en)
Other versions
WO2011144198A4 (fr
Inventor
Karl-Werner Dietrich
Original Assignee
Karl-Werner Dietrich
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102010020762A external-priority patent/DE102010020762A1/de
Priority claimed from DE102010031777A external-priority patent/DE102010031777A1/de
Priority claimed from DE102010034711A external-priority patent/DE102010034711A1/de
Priority claimed from DE102010035260A external-priority patent/DE102010035260A1/de
Priority claimed from DE102010052260A external-priority patent/DE102010052260A1/de
Application filed by Karl-Werner Dietrich filed Critical Karl-Werner Dietrich
Publication of WO2011144198A1 publication Critical patent/WO2011144198A1/fr
Publication of WO2011144198A4 publication Critical patent/WO2011144198A4/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/506Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification at low temperatures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

Definitions

  • hydrogen produced from solar or wind energy by electrolysis of water, as a secondary energy carrier and introduces it into natural gas
  • renewable energies in the form of hydrogen can be stored and transported together with natural gas. That the hydrogen, also flammable gas, is introduced into natural gas, either in existing natural gas pipelines or directly into a natural gas deposit, and is then either collected in the reservoir or transported to the points of consumption in mixture with natural gas.
  • Hydrogen gas has only 1/8 of the gas density of natural gas (methane)
  • Hydrogen gas has about the same gas volume about 1/3 of the energy content (calorific value) of natural gas (hydrogen: 10.8 kJ / 1 / methane: 35.8 kJ / 1) ⁇ Methane (CH4), the main constituent of natural gas, consumes four times more oxygen than hydrogen (H2) when burned, as the following reaction equations show:
  • the difficulty with such natural gas / hydrogen mixtures is: From the introduction of the volumetric amount of production fluctuating hydrogen into the natural gas, the composition of the gas mixture in the line system can no longer be maintained. That At each sampling point, a different gas mixture can arrive at any time. Also in the natural gas deposit, the hydrogen will be distributed unevenly and therefore creates a fluctuating gas mixture on the delivery side.
  • the burner output can fluctuate considerably with respect to the gas volume of constant gas supply, for example in the case of combustion of the gas, and the air supply is regulated incorrectly.
  • the gas mixture is analyzed and thus, above all, the hydrogen content and thus e.g. the calorific value of the mixture is calculated before combustion
  • the supply of gas mixture is metered so that the burner power remains under control or constant.
  • Point 1 For burners with controlled air supply then the calculated according to point 1. and resulting from the above reaction equations amount of air is added. Point 1 must also be taken into account for the evaluation of the delivered gas mixture, since the billing is based on kWh, that is to say on the performance, but shows today's standard gas meters only the volume consumed. Since hydrogen and natural gas differ significantly in their energy content, the delivered power is calculated from the delivered volume and the average hydrogen content of the meter reading period according to point 1.
  • An object of the present invention is thus a method for the transport and storage of renewable energy, characterized in that renewable energy - present as electrical energy - is converted by water electrolysis in hydrogen as a secondary energy source, the hydrogen thus produced a natural gas pipeline or a natural gas deposit or a natural gas storage is supplied, optionally mixed with the natural gas and thus displaced or replaced the natural gas and transported in mixture with the natural gas in a natural gas pipeline or in the existing natural gas network to the point of consumption, where then the actual gas composition is determined directly before use and, if, for example the use of a combustion is, according to the ratio of natural gas / hydrogen, the gas metering and possibly also the air metering is controlled so that when changing gas composition a controlled or uniform burner function is ensured.
  • the combination of hydrogen and natural gas in the gas line by active mixing is preferred over simply introducing one gas component into the other.
  • active mixing e.g. the gas mixers used in the chemical industry, which serve to mix gaseous reactants are used. Generally suitable are devices which serve to mix gases.
  • the gas mixture according to the invention can then be transported via the existing natural gas network to the point of consumption. But it can also be reserved from the network certain lines leading to selected points of consumption, the hydrogen / natural gas mixture according to the invention.
  • These can be consumables, such as gas-fired power plants, which are already equipped with the analysis and control devices described below in the feed-through phase of the method according to the invention.
  • the determination of hydrogen should preferably be carried out in the gas stream, so that the firing process can be quickly adapted to the current gas composition.
  • a simple measuring method for gas volume and gas composition is, for example: One measures the gas volume over the flow velocity and additionally the gas density over the flow resistance (at then known flow velocity).
  • composition results from the approximately three times greater velocity of sound in hydrogen compared to methane, the main component of natural gas.
  • thermal conductivity (W / m ° K) of hydrogen is about a factor of 5 higher than that of methane.
  • Another possibility is to add to the hydrogen at the point of introduction into the natural gas a messenger substance which is low in concentration and proportional to the amount of hydrogen, and with the aid of which the hydrogen concentration is then e.g. can be determined spectroscopically.
  • the gas mixture according to the invention is suitable for most applications of natural gas, but above all for combustion.
  • burners are particularly to call: burners of heating or steam generating systems, internal combustion engines and gas turbines.
  • An electrolyzer for generating hydrogen from electrical energy.
  • a device for introducing the hydrogen into the natural gas 1.
  • the invention therefore also claims a device combination which comprises the device components 1 to 4 and, with subsequent combustion, the device components 1 to 6. It should be noted that the individual device parts of this entire device can be constructed at geographically distant locations.
  • a consumption meter in which, in addition to the volumetric gas quantity determination (gas meter), the gas composition measured according to 4 in the reading period is included in the calculation of the delivered power (kWh).
  • a gas meter since it always measures the current gas composition, can also be used in the direct vicinity of the burner for controlling the combustion according to the invention.
  • this method By compensating for these fluctuations by more or less addition of natural gas through the deliberate addition of natural gas to the fluctuating hydrogen stream, when derived from the generation of fluctuating renewable energies, this method also effects a stabilization of solar and wind energy.
  • This stabilization can also be achieved by storing hydrogen in natural gas storage facilities. Natural gas deposits have proved their gas-tightness over many thousands of years and should therefore also be suitable for storing hydrogen.
  • the hydrogen is introduced into the natural gas deposit or the natural gas storage facility. You can introduce hydrogen while natural gas is still being pumped. Since the hydrogen does not distribute evenly in the deposit, as soon as the hydrogen arrives at the delivery side, a fluctuating gas mixture is again obtained, which must be determined in its composition during transport, use and evaluation as already described.
  • the hydrogen may be advantageous to introduce hydrogen into the upper region of the natural gas deposit and make the removal at the bottom of the reservoir. As a result, the hydrogen pushes the natural gas out of the reservoir down and the occurrence of hydrogen on the delivery side can be delayed. In the case of natural gas extraction, the hydrogen can also be introduced into the deposit below and mixed with the natural gas.
  • the timing of the transport and the resulting problems with the use of a fluctuating gas mixture can also be delayed by the fact that on the delivery side, as soon as hydrogen is determined in the natural gas, it is separated from the natural gas. After the separation, it can then be returned to the deposit for further storage. Thus, hydrogen is introduced into the deposit over a longer period and unmixed natural gas is recovered. Hydrogen (for example from renewable sources) can thus also be used to export natural gas.
  • Another object of the present invention is thus a method for the extraction of natural gas with hydrogen, characterized in that the hydrogen is introduced / injected into the natural gas deposit and, as soon as the hydrogen-containing natural gas is measured on the production side, this hydrogen separated from Erdeas and back into the deposit is returned or otherwise used, which requires that, from the time of introduction of hydrogen into the natural gas deposit, the extracted natural gas be tested for hydrogen according to the invention.
  • Natural gas and hydrogen are preferably separated from one another by refrigeration, by liquefying the natural gas (methane) and dissipating the hydrogen at a temperature of about 100 ° C lower than gas.
  • the hydrogen content of the gas mixture can also be determined.
  • This variant of the method is particularly suitable where, in any case, the natural gas for transport, e.g. on liquefied gas tankers, liquefied.
  • the gas separated as gas is then returned from the natural gas liquefaction plant to a natural gas field to be retrieved with hydrogen.
  • the ongoing measurement of the hydrogen content in the gas mixture is necessary because only for the natural gas (methane) - share the cooling energy must be supplied to the condensation, or at constant capacity of the liquefaction plant, the gas flow must be adjusted continuously to the content of liquefied natural gas in the gas mixture ,
  • the present invention thus further provides a method for the challenge of natural gas, characterized in that a part of the extracted natural gas is converted by chemical reaction in hydrogen and the hydrogen thus obtained is introduced into the natural gas deposit and displaced there, the natural gas.
  • the central object of the present invention is thus a method for the transport and storage of hydrogen, characterized in that hydrogen is introduced into the natural gas, the hydrogen introduced is transported and / or stored together with the natural gas, and before use or for evaluation the gas mixture of the contained hydrogen content is determined in the gas mixture.
  • the determination of the hydrogen content is preferably carried out in the gas stream.
  • the respective need for one of the two components must be determined by measuring the hydrogen content in the original gas mixture.
  • the natural gas production of hydrogen according to the present invention is equally applicable to both associated and unassociated natural gas.
  • it may be simpler, after removal of the liquid fraction, the condensate and the liquefied petroleum gas (LPG), if appropriate, to recirculate hydrogen together with methane into the deposit over a certain period of time.
  • LPG liquefied petroleum gas
  • Electric energy from an "offshore” wind farm off the German North Sea coast is converted into hydrogen by electrolysis on site, where it is collected and sent to the coast, where gas flows from the East Frisian islands to the country
  • the hydrogen is introduced into the natural gas, mixed with the natural gas and fed as a gas mixture into a gas line or into the gas network
  • the hydrogen content is measured in both incoming gas streams and the respective calorific value is continuously determined
  • the actual hydrogen content in the gas mixture is then determined for calorific value determination and for burner control.
  • renewable energies are not only transported, but also stabilized. Natural gas then fills in the gaps that exist in fluctuating renewable energies. Wind energy is also available in calm weather and solar energy at night.
  • Another object of the present invention is thus a method for transport and to stabilize renewable energy, characterized in that renewable energy - obtained as electrical energy from wind or solar power - is converted at or near its source by water electrolysis in hydrogen, the thus produced Hydrogen is fed into a natural gas pipeline, where it is mixed with natural gas and displaced or replaced natural gas and transported in mixture with the natural gas in a natural gas pipeline or in the natural gas network to the point / s where the current gas composition is determined prior to combustion is and according to the ratio of natural gas to hydrogen, the gas metering and, if necessary, the air supply is controlled so that when changing gas composition is always a controlled and / or constant burner function is ensured.
  • renewable energies can also be stored in conjunction with natural gas.
  • solar and wind power are converted into hydrogen as described and the hydrogen is introduced directly into a natural gas deposit.
  • the hydrogen does not distribute evenly in the deposit, the hydrogen is again obtained on the delivery side of a hydrogen / natural gas mixture with fluctuating composition, in which, as shown above, at the point of consumption, the hydrogen content must be continuously measured.
  • the present invention thus further provides a process for the storage of hydrogen, characterized in that the hydrogen is introduced into a natural gas storage or natural gas reservoir and thus displaces the natural gas, or replaced and then promoted in mixture with the natural gas and in a natural gas pipeline Consumption point is transported, wherein in relation to the hydrogen content fluctuating gas mixtures prior to combustion, the composition is determined and according to the found ⁇
  • Natural gas / hydrogen ratio for combustion The gas metering is regulated in such a way that a controlled burner function is always ensured with changing gas composition. With a clever arrangement of the discharge and delivery point, it can be achieved that hydrogen is introduced into the deposit over a longer period of time and un-mixed natural gas is conveyed. One way is to put the hydrogen gas in the top of the
  • the introduction of hydrogen into a natural gas deposit as described under 2. can be used not only for storage but also for the export of natural gas. That the hydrogen introduced / injected into the deposit pushes the natural gas out of the deposit. Once it is determined that the extracted natural gas contains hydrogen, the hydrogen is separated from natural gas and can be returned to the reservoir. In this way, unmixed natural gas is recovered, while in the reservoir, the supply of gas in the form of hydrogen "grows".
  • Another object of the present invention is therefore a method for storing hydrogen, characterized in that hydrogen is introduced into a natural gas deposit, the hydrogen displaces the natural gas and discharges and, as soon as measured in natural gas hydrogen fractions, the (gaseous) hydrogen after liquefaction the natural gas is transported as liquefied gas, for example, and the gaseous hydrogen is returned to a gas field for further discharge, the overall process of liquefying the natural gas fraction being controlled with respect to the incoming gas quantity and the cooling capacity via the hydrogen fraction measured in the gas mixture. It can be maintained over the entire of the natural gas deposit added hydrogen (hydrogen from the recovery and "new" hydrogen, eg from renewable energy), the pressure in the reservoir during the natural gas production.
  • the hydrogen into a natural gas pipeline, then to lead it to a central natural gas liquefaction plant and to separate it there again from the natural gas.
  • the hydrogen is introduced, where it is extracted and where or in which gas field it is returned depends on the local conditions.
  • the export of natural gas with hydrogen recovered on the production side and returned to the deposit can be continued as long as the recovery of the more valuable natural gas gas justifies this.
  • the amount of recoverable gas can be increased.
  • the present invention thus further relates to the storage of hydrogen, characterized in that the hydrogen is introduced into a natural gas deposit, displaced there, the natural gas and, when the hydrogen is mixed with the natural gas and a natural gas / hydrogen mixture is conveyed from the Gas mixture, the natural gas is separated by refrigeration liquefaction and transported as a liquefied gas and the remaining in the gas phase hydrogen is returned to a natural gas deposit.
  • Process variants 1 and 2 are recommended when natural gas is piped from the gas field to the consumer.
  • Variant 3 is suitable where the natural gas is transported as liquefied gas
  • At the beginning it was shown that there is ample solar or wind energy available in the vicinity of most natural gas fields and natural gas pipelines, which makes the combination according to the invention of natural gas production and natural gas pipelines particularly economical with the storage and transport of renewable energies.
  • Another object of the present invention is therefore the transport and storage of renewable energy, characterized in that the plants for the production of hydrogen from wind or solar energy and plants for the conversion of biomass into hydrogen in the vicinity of a natural gas field or a natural gas pipeline are established and the hydrogen is introduced into the natural gas line or gas field.
  • both the natural gas storage facility or the natural gas storage facility and the pipeline system or gas network is filled with hydrogen and can be hydrogen-fueled from renewable sources
  • Energys are used in place of natural gas.
  • Hydrogen gas can then be extracted from the gas fields and transported in the gas network as long as the wind blows and the sun shines.
  • the present invention is thus the last storage and transport of hydrogen together with the natural gas according to the present description, wherein the hydrogen at the end of natural gas production in the deposit, the pipe system and at the point of consumption follows the natural gas.
  • renewable energies are stored and transported together with natural gas. Since no new transport routes need to be created, they are immediately available to the consumer. And: In gas fields, where renewable energy in the form of hydrogen gradually takes the place of natural gas as an energy carrier, the natural gas contained therein itself becomes renewable energy.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

Avec de l'hydrogène comme support d'énergie secondaire, des énergies renouvelables sont stockées en même temps que le gaz naturel et transportées par le réseau de gaz. Les énergies renouvelables sont plus rapidement disponibles sous forme d'hydrogène que sous forme d'électricité, étant donné que l'on ne doit pas construire de nouvelles lignes à haute tension. En outre, des énergies renouvelables peuvent ainsi supporter une charge de base. La présente invention décrit le transfert par exemple du courant éolien ou du courant solaire en hydrogène et son introduction dans du gaz naturel. En même temps que le gaz naturel, l'hydrogène est stocké dans le gisement de gaz naturel et/ou transporté dans le réseau de gaz de naturel au lieu de consommation. En raison des différences physiques et de combustion existant entre l'hydrogène et le gaz naturel, de tels mélanges ne doivent pas être utilisés dans le cas d'un rapport de mélange discontinu, tel qu'il apparaît dans la nature des énergies renouvelables, sans une mesure permanente de la teneur en hydrogène. Ainsi, par exemple la teneur en hydrogène doit être déterminée directement avant la combustion, et le dosage du mélange de gaz, adapté à sa puissance calorifique. Une mesure, qui devient indispensable pratiquement en tout lieu de consommation et qui doit être accompagnée aussi bien au plan technique qu'au plan juridique. Au plan technique du fait que le compteur à gaz mesure non seulement le volume, mais par exemple par la densité également la teneur en hydrogène et au plan juridique parce que la puissance calorifique variable d'un mélange hydrogène/gaz naturel fluctuant doit être prise en compte dans le droit relatif à l'étalonnage. Comme le traitement selon l'invention d'un mélange gazeux fluctuant nécessite donc une préparation minutieuse pour le marché, il peut être avantageux de collecter l'hydrogène quelque temps dans le gisement de gaz naturel, alors que du gaz naturel non encore mélangé est transporté et livré. A cet effet, l'hydrogène est introduit dans le gisement de gaz naturel et, dès que la présence d'hydrogène peut être décelée dans le gaz naturel transporté, celui-ci est séparé du gaz naturel et réacheminé dans le gisement de gaz naturel. Cette variante de procédé convient particulièrement dans le cas où le gaz naturel peut être toujours liquéfié à froid et séparé de l'hydrogène gazeux sous forme de gaz liquide. L'hydrogène est réacheminé dans le gisement et le gaz naturel est transporté et livré sous forme de gaz liquide. L'hydrogène provenant d'énergies renouvelables peut être utilisé ainsi également par refoulement du gaz naturel dans son gisement de façon avantageuse pour l'extraction de gaz naturel. Du fait qu'on sépare alors pendant une période prolongée l'hydrogène du gaz naturel transporté et qu'on le réachemine, on peut augmenter, en fonction de la structure géologique, également la quantité de gaz naturel exploitable (gaz récupérable) d'un gisement. Le gaz naturel qui, pour un volume de gaz identique, présente pratiquement le triple de la puissance calorifique de l'hydrogène, est soumis avec l'hydrogène léger à une "extraction par lavage" du gisement. Indépendamment de la variante de procédé choisie, l'ensemble de la logistique du gaz naturel sera mis à la disposition des énergies renouvelables sous la forme d'hydrogène à la fin du transport de gaz naturel. Les énergies renouvelables remplacent peu à peu le support énergétique qu'est le gaz naturel dans le gisement, le réseau de gaz ou de façon générale lors du transport ou chez le consommateur, afin de suivre ensuite le gaz naturel. Le gaz naturel devient une matière première qui se régénère - les parcs d'éoliennes et les fermes solaires deviennent des champs de gaz.
PCT/DE2011/000422 2010-05-17 2011-04-19 Transport et stockage d'hydrogène WO2011144198A1 (fr)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
DE102010020762A DE102010020762A1 (de) 2010-05-17 2010-05-17 Transport und Verstetigung erneuerbarer Energien
DE102010020762.4 2010-05-17
DE102010031777A DE102010031777A1 (de) 2010-07-21 2010-07-21 Wasserstoffspeicherung in Erdgaslagerstätten
DE102010031777.2 2010-07-21
DE102010034711.6 2010-08-18
DE102010034711A DE102010034711A1 (de) 2010-08-18 2010-08-18 Selbstausförderung von Erdgas
DE102010035260A DE102010035260A1 (de) 2010-08-24 2010-08-24 Ausförderung von Erdgaslagerstätten mit Wasserstoff und dessen Rückgewinnung
DE102010035260.8 2010-08-24
DE102010052260A DE102010052260A1 (de) 2010-11-23 2010-11-23 Ausförderung von Erdgas enthaltenden Lagerstätten mit Wasserstoff und dessen Rückgewinnung
DE102010052260.0 2010-11-23

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Publication Number Publication Date
WO2011144198A1 true WO2011144198A1 (fr) 2011-11-24
WO2011144198A4 WO2011144198A4 (fr) 2012-01-12

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EP2979743A1 (fr) * 2014-07-28 2016-02-03 Rohöl - Aufsuchungs AG Dispositif et procédé de stockage et distribution d'énergie renouvelable
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AT17434U1 (de) * 2019-08-07 2022-04-15 Oleksandrovych Riepkin Oleksandr Verfahren zur Bildung und Nutzung eines energetischen Systems mit der Integration von Wasserstoff, der unter Verwendung von erneuerbaren Energiequellen erzeugt wurde, in das System
EP4047260A1 (fr) * 2021-02-18 2022-08-24 Linde GmbH Procédé de commande ou de régulation de la teneur en hydrogène d'un gaz naturel transporté par un réseau de gaz naturel
EP4117142A4 (fr) * 2020-03-04 2024-03-27 Land Business Co., Ltd. Système d'alimentation électrique à grande surface

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