WO2011127676A1 - Thin slice material for cigarette and cigarette - Google Patents

Thin slice material for cigarette and cigarette Download PDF

Info

Publication number
WO2011127676A1
WO2011127676A1 PCT/CN2010/073547 CN2010073547W WO2011127676A1 WO 2011127676 A1 WO2011127676 A1 WO 2011127676A1 CN 2010073547 W CN2010073547 W CN 2010073547W WO 2011127676 A1 WO2011127676 A1 WO 2011127676A1
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
cigarette
tobacco
sheet
mass
Prior art date
Application number
PCT/CN2010/073547
Other languages
French (fr)
Chinese (zh)
Inventor
李森盛
赵保军
谢旭东
方维远
陈臣
高占甫
吴莹莹
Original Assignee
厦门中海钓台生物工程有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 厦门中海钓台生物工程有限公司 filed Critical 厦门中海钓台生物工程有限公司
Publication of WO2011127676A1 publication Critical patent/WO2011127676A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/285Treatment of tobacco products or tobacco substitutes by chemical substances characterised by structural features, e.g. particle shape or size
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/287Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B3/00Preparing tobacco in the factory
    • A24B3/14Forming reconstituted tobacco products, e.g. wrapper materials, sheets, imitation leaves, rods, cakes; Forms of such products
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/18Selection of materials, other than tobacco, suitable for smoking

Definitions

  • the invention relates to the technical field of cigarette processing, in particular to a sheet for cigarettes and a cigarette. Background technique
  • zeolite has selective adsorption-catalytic properties, and has strong adsorption effect on harmful substances such as nitrosamines and polycyclic aromatic hydrocarbons in cigarette smoke. Therefore, it is widely used in cigarettes. Reduce damage and reduce focus.
  • zeolite is used as a harm reduction additive in cigarettes: one is to add the zeolite directly to the tobacco; the other is to add the zeolite to the nozzle of the cigarette filter.
  • the zeolite In the first method, the zeolite must first be bonded to a crosslinking agent (for example, silica gel) and then mixed with the gum solution to be added as an additive to the tobacco. During the bonding of the zeolite to the crosslinking agent, the pores and pores on the surface of the zeolite are blocked, greatly reducing the selective adsorption-catalysis. In addition, when the zeolite is directly added to the tobacco, the amount of the zeolite is limited, the amount of the zeolite added is small, and the harm reduction effect is not obvious; in the second mode, the zeolite can be used for the nitrosamines in the mainstream smoke in the early stage of the combustion of the cigarette.
  • a crosslinking agent for example, silica gel
  • the present invention provides a sheet for tobacco, which is added with an appropriate amount of zeolite, which can be directly added to the shredded tobacco, or even directly used for cigarettes, and fully exerts the reduction of the zeolite. Harmful effect, reduce the content of harmful substances in cigarette smoke.
  • the present invention still further provides a cigarette to which the above-mentioned tobacco sheet is added, which is advantageous for reducing the injury to a smoker.
  • the present invention provides a sheet for tobacco, comprising: a sheet base, the sheet base containing
  • the sheet base contains 0.1 to 10% by mass of zeolite.
  • the sheet base contains 5% by mass of zeolite.
  • the present invention also provides a cigarette comprising a flammable portion of the cigarette comprising a tobacco sheet processed using the tobacco sheet provided above.
  • the tobacco flakes have a content of at least 3% by mass of the flammable portion of the cigarette, and the balance is cut tobacco.
  • the tobacco flakes have a silk content of at least 25% of the mass of the flammable portion of the cigarette, and the balance is cut tobacco.
  • the tobacco flakes have a silk content of 25-60% of the mass of the flammable portion of the cigarette.
  • the tobacco sheet and the cigarette provided by the invention the tobacco sheet is used as a carrier, the zeolite having the harm reduction effect is added to the tobacco sheet, and the flake and the flake sheet are respectively shredded, and then mixed in a certain ratio, or The flakes and the flakes are mixed in a certain ratio and then shredded together, and then the mixed silk is rolled into a cigarette.
  • it overcomes the shortcomings of the existing zeolite as a harm reduction additive for cigarettes: it not only solves the problem that the tar-covering filter in the mainstream flue gas reduces the activity of the zeolite, but also solves the limitation of the dose when the zeolite is directly added to the tobacco.
  • the problem is that it can also reduce the harmful components in the sidestream smoke and fully exert the harm reduction effect of the zeolite.
  • the use of flake flakes improves the flammability of cigarettes, and can reduce the release of harmful substances such as CO generated during the combustion of cigarettes, thereby reducing harm. use.
  • FIG. 1 is a flow chart of a method for preparing a sheet for tobacco according to a second embodiment of the present invention
  • FIG. 1 is a flow chart of a method for preparing a cigarette according to a third embodiment of the present invention. detailed description
  • Zeolite is a kind of inorganic aluminosilicate crystal with uniform pores and regular pore structure. Its pore size is equivalent to the general molecular size, and it has a large specific surface area and adsorption capacity. It is a kind of molecular sieve. Most types of zeolite molecular sieves have strong acid centers on the surface, while the crystal has a strong Coulomb field and polarity. It has a unique "selective catalysis" function and strong adsorption separation performance, and it can be replaced by isomorphism. Such physical and chemical methods as well as loading other active components to modify their physicochemical properties. The zeolite is added to the cigarette.
  • the catalytic activity of the zeolite will be excited.
  • the zeolite can adsorb nitrosamines and polycyclic aromatic hydrocarbons in the cigarette smoke. Harmful Substance.
  • a Y-type zeolite it is also possible to selectively adsorb polycyclic aromatic hydrocarbons in the flue gas.
  • the use of zeolite as a harm reduction additive to adsorb harmful substances in cigarette smoke does not fully exert the adsorption of zeolite, and affects the effect of zeolite on the reduction of cigarettes. Based on this, each embodiment of the present invention provides a technical solution capable of giving full play to the adsorption of zeolite.
  • Embodiment 1 provides a sheet for tobacco comprising a sheet base on which a zeolite having a detrimental effect is adsorbed.
  • zeolites such as NaY, NaZSM, NaZSM-5, and NaA can be used.
  • a flake flake is used as a carrier of zeolite, and a zeolite having a detrimental action is added to the cigarette.
  • the zeolite adsorbed in the flake filament will exert its selective adsorption-catalysis effect, reducing the content of harmful components in the cigarette smoke, especially reducing the content of nitrosamines and polycyclic aromatic hydrocarbons. The purpose of harm.
  • the zeolite does not affect the original flavor style of the cigarette when it is burned.
  • the flue-cured flakes provided in this embodiment can effectively reduce the content of harmful components in the cigarette smoke by adsorbing zeolite, and reduce the harm caused by the cigarette smoke to the human body.
  • the content of the zeolite added to the flake sheet is limited.
  • the sheet of the flake sheet contains 0.01 to 40%.
  • the (mass) zeolite preferably contains 0.1 to 10% by mass of zeolite.
  • the zeolite in the technical solution of the present invention may be unmodified or modified, and the present invention does not limit the type of zeolite. However, it is possible to select zeolite types having different pore structures and properties depending on the harm reduction requirements of the cigarette, and to select zeolites having a suitable particle size according to the zeolite addition position requirements determined in the sheet processing.
  • the tobacco sheet in the embodiment may be a tobacco sheet or a non-tobacco sheet.
  • tobacco flakes can be prepared by using a tobacco or tobacco by-product as a raw material, using an existing process (also called a papermaking process), and a pulping and papermaking process, which is discarded in the production of cigarettes. Or rejected tobacco residues, such as straw, tobacco leaf fragments, stems, etc., and may be added to the process for preparing the tobacco sheet (for example, a pulping section, a coating section of the paper product) to prepare a tobacco sheet containing zeolite .
  • the non-tobacco sheet may be made from agricultural by-products other than tobacco, including crop straw, roots, stems, tea leaves, tea stems, and herbs, which provide fibrous tissue, and Non-tobacco flakes can be prepared by a process similar to the preparation of tobacco flakes, and zeolites can also be added during the preparation of non-tobacco flakes to prepare flake flakes comprising zeolite.
  • Embodiment 2 This embodiment exemplifies a process for preparing a flake sheet containing zeolite according to the present invention by taking a flake sheet containing 5% by mass of zeolite. Specifically, in this embodiment, a tobacco flake comprising zeolite is prepared by using agricultural by-products as raw materials, as shown in FIG. 1, comprising the following steps:
  • Step 11 immersing agricultural by-products to obtain a swelling;
  • the agricultural by-product can be placed in hot water of 60-80 ° C for immersion treatment for 20-30 minutes to obtain agricultural by-product swell, or the agricultural by-product is placed at room temperature water (this invention In the room temperature water), the immersion treatment is carried out for 0.5 to 6 hours to obtain the swelling.
  • the solution of the present invention can also select a water soaking material higher than room temperature, but not higher than 80 ° C, and determine an appropriate soaking time according to the water temperature condition.
  • Step 12 the above-mentioned agricultural by-product swelling is subjected to twisting to obtain crude agricultural by-product fibers; specifically, the swollen agricultural by-products can be sent to a spinning machine through a conveying device for silk processing, so as to facilitate Follow-up actions.
  • Step 13 Washing the crude by-product of the agricultural by-product to obtain the agricultural by-product fiber; specifically, the crude agricultural by-product fiber may be placed in hot water of 60-80 ° C for 20-30 minutes of washing treatment; Obtaining agricultural by-product fibers, or placing the crude agricultural by-product fibers in normal temperature water for 30 to 60 minutes to obtain agricultural by-product fibers; by the above washing treatment, impurities in the crude by-products of agricultural by-products can be removed. Cells and partially water-soluble substances, such as nitrogen-containing compounds, are used for the purpose of purifying agricultural by-product fibers.
  • the solution of the present invention can also select water above room temperature, but not higher than 80 ° C as a washing solvent, and determine the appropriate washing time according to the water temperature.
  • Step 14 refining the agricultural by-product fiber to prepare an agricultural by-product slurry, and simultaneously preparing a reinforcing fiber slurry, and mixing the prepared reinforcing fiber slurry with the agricultural by-product slurry to obtain a mixed pulp.
  • the process of preparing the reinforced fiber slurry can be carried out by using a process of preparing a reinforced fiber slurry in a papermaking process, which will not be discussed in detail in this embodiment.
  • the addition of the reinforcing fibers is selective, depending on the strength requirements of the finished sheet. Since the agricultural by-products used have short fibers and a large amount of miscellaneous cells, the strength of the finished product is poor during the papermaking process. Therefore, depending on the type of agricultural by-product selected, it is necessary to add an appropriate amount of reinforcing fibers to most agricultural by-product slurries to increase the strength of the flakes.
  • reinforcing fibers are used to prepare a sheet for tobacco having a strength in accordance with the requirements of the cigarette processing technology.
  • the addition amount of the reinforcing fiber slurry is generally controlled to 0 to 40% by weight of the total amount of the slurry, and the addition amount is preferably 20 to 40% by weight.
  • Step 15 the mixed slurry is sent to the flushing tank, the filler is added and diluted, and the zeolite may be added while adding the filler as needed;
  • a filler for example, light calcium carbonate
  • water for example, water may be added in this step.
  • Dispersion to prepare a flake flake containing 5% by mass of zeolite. This step is the first addition site in which zeolite can be added in this example.
  • Step 16 the diluted mixed slurry is sent to the high-position box, and the retention aid is added to prepare a slurry, and the zeolite may be added while adding the retention aid as needed;
  • the retention of the mixed slurry on the net is increased by adding a retention aid (e.g., guar gum) to the elevated tank, and the slurry pressure of the mixed slurry is stabilized for subsequent papermaking operations.
  • a retention aid e.g., guar gum
  • the retention aid should be a retention aid in accordance with the tobacco industry standard known in the art, and the present invention is not limited to its specific selection, and the addition amount is a conventional addition amount of the retention aid.
  • zeolite may also be added, for example, the zeolite suspension is mixed with a retention aid and added to the mixed slurry, and by controlling the addition amount of the zeolite suspension, a zeolite containing 5% by mass is prepared. The flakes are used. This process is the second addition site in which zeolite can be added in this example.
  • Step 17 feeding the slurry into a forming wire for papermaking to obtain a sheet base
  • Step 18 performing a first drying process on the sheet base to remove most of the moisture in the sheet base; and step 19, feeding the sheet base into the coating tank for coating treatment, and coating the coating liquid as needed Simultaneously adding zeolite;
  • the dried sheet substrate is fed into a coating tank, and the prepared coating liquid is coated on the sheet base in a coating tank, wherein the coating liquid serves to increase the aroma
  • the coating liquid serves to increase the aroma
  • an aqueous solution made of the substance having the above-described effects can be used as the coating liquid in the present embodiment.
  • a zeolite suspension can also be prepared in the process, and the zeolite suspension is mixed with the coating liquid and applied together to the sheet base (the sheet base may already contain zeolite), and the zeolite is controlled.
  • the suspension was added in an amount to prepare a flake sheet containing 5% by mass of zeolite.
  • This coating process is the third addition site in which the zeolite can be added in this example.
  • step 20 the sheet base is subjected to a second drying treatment to obtain a sheet for tobacco that satisfies the needs.
  • a flake sheet having a zeolite content of 5% and a water content of 10 to 13% and a thickness of 0.3 0.4 mm is prepared.
  • the smoke containing zeolite can be prepared through the above three added positions.
  • the zeolite may be added at any of the above-mentioned addition positions, or a combination of the above-mentioned plurality of addition positions may be employed.
  • the content of the zeolite in the flake sheet is the total content.
  • the tobacco flake prepared in this embodiment contains 5% (mass) of zeolite, which is applied to cigarettes, which solves the problem that the tar-covering filter in the mainstream flue gas reduces the activity of the zeolite, and also solves the direct addition of the zeolite on the shredded tobacco.
  • the time-dose is limited, the cross-linking agent blocks the micropores and channels on the surface of the zeolite, and at the same time, the harmful components in the side-flow flue gas are reduced, and the harm reduction effect of the zeolite is fully exerted.
  • a third embodiment of the present invention provides a cigarette, i.e., a flammable portion of the cigarette (in the case of a cigarette with a filter, a portion other than the filter) comprising at least a portion of the tobacco sheet prepared by the method of the second embodiment.
  • a cigarette i.e., a flammable portion of the cigarette (in the case of a cigarette with a filter, a portion other than the filter) comprising at least a portion of the tobacco sheet prepared by the method of the second embodiment.
  • common cigarettes including cigarette paper, cut tobacco and filters.
  • the tobacco shredded tobacco of the present invention is uniformly mixed with the tobacco flakes cut by the tobacco flakes, specifically, the flakes and the flake flakes are respectively shredded, and then mixed in a certain ratio, or the flakes are smoked. After being mixed with a sheet of tobacco in a certain ratio, the yarn is shredded, and then the mixed yarn is rolled into a cigarette.
  • the tobacco sheet of this embodiment can be the sheet for tobacco provided in the first embodiment.
  • the flake sheet comprises a flake base, and the flake base contains 0.01 to 40% by mass of zeolite, preferably 0.1 to 10% by mass of zeolite.
  • the tobacco sheet may be a tobacco sheet or a non-tobacco sheet, which adsorbs zeolite to utilize the adsorption and catalysis of the zeolite to reduce the content of harmful components in the cigarette smoke.
  • the zeolite adsorbed by the flake filaments can effectively reduce the content of harmful components in the cigarette smoke and reduce the harm caused by the cigarette smoke to the human body.
  • the content of the flakes in the cigarette can be at least 3% (mass) of the flammable portion of the cigarette, preferably 25-60% (mass), to achieve the purpose of harm reduction, and Affect the smoking style of cigarettes.
  • the process of preparing the cigarette of the embodiment is described by using the agricultural by-product as an example. As shown in FIG. 2, the method specifically includes:
  • Step 21 preparing a flake sheet containing zeolite by using agricultural by-products as raw materials
  • the tobacco sheet of the present embodiment can be prepared by using the method for preparing the tobacco sheet provided in the second embodiment of the present invention.
  • the content of the zeolite can be
  • the flakes and the obtained flake flakes are respectively shredded, and then mixed in a certain ratio, or the flakes and the obtained flake flakes are mixed in a certain ratio and then shred together, and then the mixed silk rolls are rolled. Made into cigarettes.
  • the process of shredding the tobacco sheet can be carried out by using a shredding process and equipment in the cigarette processing process, and the cut tobacco shred yarn is preferably substantially the same length and width as the shredded tobacco to be mixed with the ordinary shredded tobacco.
  • the process of shredding the flakes and the flakes in a certain ratio and then cutting them together can also be carried out by the shredding process and equipment in the cigarette processing process.
  • the mixing ratio of the tobacco sheet and the tobacco can be 3 to 100%, and the mixing ratio can be determined according to different cigarette requirements, preferably 25 to 60% (mass).
  • the cigarette prepared in the present embodiment is fed with a flake sheet as a carrier, and a zeolite having a detrimental action is added to the flake sheet, and the flake sheet is applied to a cigarette.
  • a zeolite having a detrimental action is added to the flake sheet, and the flake sheet is applied to a cigarette.
  • the cross-linking agent blocks the micropores and channels on the surface of the zeolite, and at the same time reduces the harmful components in the sidestream flue gas, and fully exerts the harm reduction effect of the zeolite.
  • the use of the flake sheet improves the combustibility of the cigarette, and can reduce the release amount of harmful substances such as CO generated during the combustion of the cigarette, thereby reducing the harm.
  • the sensory evaluation test of the cigarette prepared in the present embodiment shows that the cigarette prepared in the embodiment basically maintains the original flavor-absorbing style, and the cigarette in the smoke is added by adding different proportions of the tobacco sheet.
  • Hazardous substances such as nitramine, 3, 4-benzopyrene, phenol, crotonaldehyde, CO, hydrocyanic acid and ammonia were all significantly reduced.
  • the NaY zeolite is selected, and the agricultural by-product is used as the sheet base material.
  • the zeolite suspension is coated on the sheet base together with the coating liquid in the papermaking section.
  • a sheet of tobacco containing 5% by mass of zeolite was prepared.
  • the NaZSM-5 zeolite is selected, and the agricultural by-product is used as the raw material of the flakes.
  • the suspension of the zeolite is added to the mixed slurry together with the retention aid in the pulping section.
  • the flake flakes containing 5% NaY zeolite were shredded, put into the cut tobacco at a 25% addition amount, and rolled into a cigarette. After the sensory evaluation, the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 25.7%, the amount of benzopyrene decreased by 34.8%, and other harmful components were also significantly reduced, while lateral flow The harmful components in the flue gas are also reduced, and the harm reduction effect is remarkable.
  • a sheet of tobacco containing 5% NaY zeolite was shredded, put into the cut tobacco at a 50% addition amount, and rolled into a cigarette.
  • the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 31.7%, the benzopyrene decreased by 41.6%, and other harmful components were also significantly reduced, while the sidestream smoke was also reduced.
  • the harmful components in the group have also been reduced, and the harm reduction effect is remarkable.
  • the flake flakes containing 5% NaZSM-5 zeolite were shredded, put into the cut tobacco at a 25% addition amount, and rolled into a cigarette.
  • the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 27.7%, the benzopyrene decreased by 36.6%, and other harmful components were also significantly reduced, while the sidestream smoke was also reduced.
  • the harmful components in the group have also been reduced, and the harm reduction effect is remarkable.
  • the flakes containing 5% NaZSM-5 zeolite were shredded, put into the cut tobacco at 50% addition, and rolled into a cigarette.
  • the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 36.4%, the amount of polycyclic aromatic hydrocarbons decreased by 43.8%, and other harmful components were also significantly reduced, while lateral flow The harmful components in the flue gas are also reduced, and the harm reduction effect is remarkable.
  • the tobacco sheet and cigarette provided by the invention can effectively reduce the release of harmful substances in the mainstream smoke and sidestream smoke of the cigarette not only under the premise that the cigarette smoking style is basically unchanged. At the same time, it can alleviate the tight supply of tobacco raw materials in the tobacco industry and reduce the use of tobacco in cigarettes, which has great social and economic benefits.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

A thin-slice material for cigarettes and a cigarette using same are provided. The thin-slice material for cigarettes comprises a thin-slice base which contains 0.01 to 40 percent by mass of zeolite. The combustible part of the cigarette comprises at least 3 percent by mass of shreds of said thin-slice material, which are produced by slicing said thin-slice material. Harm-reducing zeolite is added to the cigarette by means of said thin-slice material as a carrier, solving the problem in mainstream cigarette smoke of tar-clogged filters reducing the activity of the zeolite, and solving also the problem of dosage limitations upon zeolite when same is added to shredded tobaccos. At the same time, the amount of harmful ingredients in sidestream smoke are decreased, and full use is made of the harm-reducing effect of zeolite.

Description

烟用薄片及卷烟  Tobacco sheets and cigarettes
技术领域 Technical field
本发明涉及卷烟加工技术领域, 尤其涉及一种烟用薄片及卷烟。 背景技术  The invention relates to the technical field of cigarette processing, in particular to a sheet for cigarettes and a cigarette. Background technique
近年来, 随着人们生活水平和生活质量的不断提高, 消费者对吸烟的安 全性要求越来越高。 因此, 如何降低卷烟烟气中含有的亚硝胺、 稠环芳烃、 一氧化碳(CO )等多种有害物质的含量, 以减轻卷烟燃烧时会产生的主流烟 气中的有害成分对吸烟者健康的危害, 以及散布到人群中的侧流烟气对被动 吸烟者健康的伤害和对环境的污染, 成为目前卷烟行业面临的重要课题。 而 开发具有减害作用的添加剂, 并将其应用到滤嘴和卷烟烟丝中已成为目前应 用最广泛的减害降焦方法。  In recent years, with the continuous improvement of people's living standards and quality of life, consumers are increasingly demanding the safety of smoking. Therefore, how to reduce the content of various harmful substances such as nitrosamines, condensed aromatic hydrocarbons, carbon monoxide (CO) and the like in cigarette smoke to reduce the harmful components in the mainstream smoke generated when the cigarette is burned is healthy for smokers. Hazards, as well as sidestream smoke scattered into the crowd, are harmful to the health of passive smokers and environmental pollution, and have become an important issue facing the cigarette industry. The development of additives with harm reduction effects and their application to filters and cigarette cut tobacco has become the most widely used method of harm reduction and defocusing.
在众多的减害添加剂中, 沸石具有选择性吸附-催化的特性, 对卷烟烟气 中的亚硝胺和多环芳烃等有害物质具有较强的吸附效果, 因此, 被广泛应用 于卷烟中实现减害降焦。 目前, 以沸石作为减害添加剂应用于卷烟中的方式 主要包括两种: 一种是将沸石直接加入到烟丝中; 另一种是将沸石添加到卷 烟滤嘴的嘴棒中。  Among the many harm reduction additives, zeolite has selective adsorption-catalytic properties, and has strong adsorption effect on harmful substances such as nitrosamines and polycyclic aromatic hydrocarbons in cigarette smoke. Therefore, it is widely used in cigarettes. Reduce damage and reduce focus. At present, there are two main ways in which zeolite is used as a harm reduction additive in cigarettes: one is to add the zeolite directly to the tobacco; the other is to add the zeolite to the nozzle of the cigarette filter.
但是, 上述两种方式都有不足。 在方式一中, 沸石必须先与交联剂 (例 如硅胶) 粘合, 再与胶溶液混合, 才能作为添加剂, 添加到烟丝中。 在沸石 与交联剂粘合过程中, 沸石表面的微孔和孔道会被堵塞, 大大降低其选择性 吸附-催化的作用。 另外, 直接在烟丝上添加沸石时, 沸石的添加剂量受限, 沸石加入量小, 减害效果不明显; 在方式二中, 在卷烟燃烧初期沸石可以对 主流烟气中的亚硝胺和多环芳烃等有害物质起到吸附作用, 但是随着卷烟的 燃烧, 越来越多的烟焦油覆盖在嘴棒上, 使滤嘴中沸石的孔径和孔道被堵塞, 活性中心活性降低, 选择性吸附 -催化的作用大大被减弱, 导致其减害效果下 降甚至失活。 并且将沸石加入滤嘴的嘴棒中只能吸附主流烟气中的亚硝胺和 多环芳烃等有害物质, 对侧流烟气不起作用, 而侧流烟气中亚硝胺和多环芳 烃等有害物质的含量远远高于主流烟气中的含量。 因此, 在上述方式中沸石 无法充分发挥其减害作用。 发明内容 However, both of the above methods are insufficient. In the first method, the zeolite must first be bonded to a crosslinking agent (for example, silica gel) and then mixed with the gum solution to be added as an additive to the tobacco. During the bonding of the zeolite to the crosslinking agent, the pores and pores on the surface of the zeolite are blocked, greatly reducing the selective adsorption-catalysis. In addition, when the zeolite is directly added to the tobacco, the amount of the zeolite is limited, the amount of the zeolite added is small, and the harm reduction effect is not obvious; in the second mode, the zeolite can be used for the nitrosamines in the mainstream smoke in the early stage of the combustion of the cigarette. Harmful substances such as aromatic hydrocarbons play an adsorption role, but as the cigarettes burn, more and more smoke tar covers the nozzle bars, causing the pore size and pores of the zeolite in the filter to be blocked, and the active center activity is reduced, selective adsorption. - The effect of catalysis is greatly diminished, resulting in a decrease or even inactivation of its mitigating effect. Moreover, the addition of zeolite to the nozzle of the filter can only adsorb harmful substances such as nitrosamines and polycyclic aromatic hydrocarbons in the mainstream smoke, and does not contribute to the sidestream smoke, and the nitrosamines and polycyclics in the sidestream smoke. The content of harmful substances such as aromatic hydrocarbons is much higher than that in mainstream smoke. Therefore, in the above manner zeolite The harm reduction effect cannot be fully exerted. Summary of the invention
针对现有技术中的缺陷, 本发明提供一种烟用薄片, 该烟用薄片中添加 有适量的沸石, 该烟用薄片可直接添加到烟丝中, 甚至直接用于卷烟, 充分 发挥沸石的减害作用, 减少卷烟烟气中的有害物质的含量。  In view of the defects in the prior art, the present invention provides a sheet for tobacco, which is added with an appropriate amount of zeolite, which can be directly added to the shredded tobacco, or even directly used for cigarettes, and fully exerts the reduction of the zeolite. Harmful effect, reduce the content of harmful substances in cigarette smoke.
本发明还进一步提供了添加了上述烟用薄片的卷烟, 该卷烟有利于降低 吸烟者受到的伤害。  The present invention still further provides a cigarette to which the above-mentioned tobacco sheet is added, which is advantageous for reducing the injury to a smoker.
本发明提供了一种烟用薄片, 包括: 薄片片基, 所述薄片片基中含有 The present invention provides a sheet for tobacco, comprising: a sheet base, the sheet base containing
0.01-40% (质量) 的沸石。 0.01-40% by mass of zeolite.
在上述所提供的烟用薄片中, 所述薄片片基中含有 0.1~10% (质量)的沸 石。  In the above-mentioned tobacco sheet, the sheet base contains 0.1 to 10% by mass of zeolite.
在上述所提供的烟用薄片中, 所述薄片片基中含有 5% (质量) 的沸石。 本发明还提供一种卷烟, 该卷烟的可燃部分包含有利用上述提供的烟用 薄片加工的烟用薄片丝。  In the above-mentioned tobacco sheet, the sheet base contains 5% by mass of zeolite. The present invention also provides a cigarette comprising a flammable portion of the cigarette comprising a tobacco sheet processed using the tobacco sheet provided above.
在上述的卷烟中, 所述烟用薄片丝含量至少为该卷烟可燃部分质量的 3%, 余量为烟丝。  In the above cigarette, the tobacco flakes have a content of at least 3% by mass of the flammable portion of the cigarette, and the balance is cut tobacco.
上述提供的卷烟中, 所述烟用薄片丝含量至少为该卷烟可燃部分质量的 25%, 余量为烟丝。  In the cigarette provided above, the tobacco flakes have a silk content of at least 25% of the mass of the flammable portion of the cigarette, and the balance is cut tobacco.
上述提供的卷烟中, 所述烟用薄片丝含量为该卷烟可燃部分质量的 25-60%。  In the cigarette provided above, the tobacco flakes have a silk content of 25-60% of the mass of the flammable portion of the cigarette.
本发明提供的烟用薄片及卷烟, 以烟用薄片作为载体, 将具有减害作用 的沸石添加到烟用薄片中, 并将片烟与烟用薄片分别切丝, 然后按一定比例 混合, 或者将片烟与烟用薄片按一定的比例混合后一起切丝, 然后将混合丝 卷制成烟支。 一方面, 克服了现有沸石作为减害添加剂应用于卷烟时的不足: 既解决了主流烟气中的焦油覆盖滤嘴降低沸石活性的问题, 也解决了在烟丝 上直接添加沸石时剂量受限的问题, 同时还能减少侧流烟气中的有害成分, 充分发挥了沸石的减害作用。 另一方面, 烟用薄片的使用提高了卷烟的燃烧 性, 可以降低卷烟燃烧过程中产生的 CO等有害物质的释放量, 起到减害作 用。 附图说明 The tobacco sheet and the cigarette provided by the invention, the tobacco sheet is used as a carrier, the zeolite having the harm reduction effect is added to the tobacco sheet, and the flake and the flake sheet are respectively shredded, and then mixed in a certain ratio, or The flakes and the flakes are mixed in a certain ratio and then shredded together, and then the mixed silk is rolled into a cigarette. On the one hand, it overcomes the shortcomings of the existing zeolite as a harm reduction additive for cigarettes: it not only solves the problem that the tar-covering filter in the mainstream flue gas reduces the activity of the zeolite, but also solves the limitation of the dose when the zeolite is directly added to the tobacco. The problem is that it can also reduce the harmful components in the sidestream smoke and fully exert the harm reduction effect of the zeolite. On the other hand, the use of flake flakes improves the flammability of cigarettes, and can reduce the release of harmful substances such as CO generated during the combustion of cigarettes, thereby reducing harm. use. DRAWINGS
为了更清楚地说明本发明实施例或现有技术中的技术方案, 下面将对实 施例或现有技术描述中所需要使用的附图作一筒单地介绍, 显而易见地, 下 面描述中的附图是本发明的一些具体实施例,对于本领域普通技术人员来讲, 在不付出创造性劳动的前提下, 还可以对它们提出不同的修改方案。  In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings to be used in the embodiments or the description of the prior art will be briefly described below, and obviously, the attached in the following description The drawings are some specific embodiments of the present invention, and those skilled in the art can also propose different modifications to them without any creative work.
图 1为本发明实施例二提供的烟用薄片的制备方法的流程图;  1 is a flow chart of a method for preparing a sheet for tobacco according to a second embodiment of the present invention;
图 为本发明实施例三提供的卷烟的制备方法的流程图。 具体实施方式  Figure is a flow chart of a method for preparing a cigarette according to a third embodiment of the present invention. detailed description
为使本发明实施例的目的、 技术方案和技术效果更加清楚, 下面将结合 本发明具体实施例及相应附图, 对本发明实施例中的技术方案进行清楚、 完 整地描述, 但以下实施例不能理解为对本发明的可实施范围的限定, 基于本 发明中的实施例, 本领域普通技术人员在没有做出创造性劳动的前提下所获 得的所有其它实施例, 都属于本发明保护的范围。  The technical solutions in the embodiments of the present invention are clearly and completely described in conjunction with the specific embodiments of the present invention and the accompanying drawings, but the following embodiments cannot be used to describe the embodiments of the present invention. It is to be understood that the scope of the present invention is defined by the scope of the present invention, and all other embodiments obtained by those skilled in the art based on the embodiments of the present invention without creative efforts are within the scope of the present invention.
沸石是一类具有均勾微孔和规整孔道结构的无机硅铝酸盐晶体, 其孔径 与一般分子大小相当, 且具有大的比表面积和吸附容量, 是分子筛的一种。 大部分种类的沸石分子筛表面有较强的酸中心, 同时晶内有强大的库仑场和 极性作用, 具有独特的 "择形催化" 功能以及强的吸附分离性能, 并且它可 通过同晶取代等物理化学方法以及负载其它活性组分来修饰其物理化学性 质。 将沸石加入卷烟中, 在卷烟燃烧时的高温区域(温度可高达 800°C ) , 沸 石的催化活性将被激发, 此时, 沸石将可以吸附卷烟烟气中的亚硝胺和多环 芳烃等有害物质。 例如, 当采用 Y-型沸石时, 还可以选择性的吸附烟气中的 多环芳烃。 但现有技术中, 使用沸石作为减害添加剂吸附卷烟烟气中有害物 质的方式, 都不能充分发挥沸石的吸附作用, 影响了沸石在卷烟中的减害效 果。 基于此, 本发明各实施例提供一种能够充分发挥沸石吸附作用的技术方 案。  Zeolite is a kind of inorganic aluminosilicate crystal with uniform pores and regular pore structure. Its pore size is equivalent to the general molecular size, and it has a large specific surface area and adsorption capacity. It is a kind of molecular sieve. Most types of zeolite molecular sieves have strong acid centers on the surface, while the crystal has a strong Coulomb field and polarity. It has a unique "selective catalysis" function and strong adsorption separation performance, and it can be replaced by isomorphism. Such physical and chemical methods as well as loading other active components to modify their physicochemical properties. The zeolite is added to the cigarette. In the high temperature region where the cigarette is burned (the temperature can be as high as 800 ° C), the catalytic activity of the zeolite will be excited. At this time, the zeolite can adsorb nitrosamines and polycyclic aromatic hydrocarbons in the cigarette smoke. Harmful Substance. For example, when a Y-type zeolite is used, it is also possible to selectively adsorb polycyclic aromatic hydrocarbons in the flue gas. However, in the prior art, the use of zeolite as a harm reduction additive to adsorb harmful substances in cigarette smoke does not fully exert the adsorption of zeolite, and affects the effect of zeolite on the reduction of cigarettes. Based on this, each embodiment of the present invention provides a technical solution capable of giving full play to the adsorption of zeolite.
实施例一 本实施例提供一种烟用薄片, 包括薄片片基, 薄片片基上吸附有具有减 害作用的沸石。 其中, 沸石可以选用 NaY, NaZSM、 NaZSM-5、 NaA等沸石。 本实施例以烟用薄片作为沸石的载体,将具有减害作用的沸石添加到卷烟中。 在卷烟燃烧时, 烟用薄片丝中吸附的沸石将发挥其选择性的吸附-催化作用, 降低卷烟烟气中的有害成分的含量, 尤其可以明显降低亚硝胺和多环芳烃含 量, 达到减害的目的。 同时, 沸石燃烧时不会影响卷烟的原有吸味风格。 Embodiment 1 The present embodiment provides a sheet for tobacco comprising a sheet base on which a zeolite having a detrimental effect is adsorbed. Among them, zeolites such as NaY, NaZSM, NaZSM-5, and NaA can be used. In this embodiment, a flake flake is used as a carrier of zeolite, and a zeolite having a detrimental action is added to the cigarette. When the cigarette is burned, the zeolite adsorbed in the flake filament will exert its selective adsorption-catalysis effect, reducing the content of harmful components in the cigarette smoke, especially reducing the content of nitrosamines and polycyclic aromatic hydrocarbons. The purpose of harm. At the same time, the zeolite does not affect the original flavor style of the cigarette when it is burned.
本实施例提供的烟用薄片通过吸附的沸石可以有效降低卷烟烟气中的有 害成分的含量, 降低卷烟烟气对人体造成的危害。 但是, 由于制备烟用薄片 的工艺、 以及烟用薄片自身的特性的限制, 烟用薄片中添加沸石的含量是有 限制的, 本实施例中烟用薄片的薄片片基中含有 0.01~40% (质量) 的沸石, 优选的为含 0.1~10% (质量) 的沸石。 本发明技术方案中的沸石可以是未经 改性处理的, 也可以是经过改性处理的, 本发明不对沸石的类型进行限制。 但可以根据香烟的减害需要选择孔结构和性质不同的沸石种类, 并且根据薄 片加工中确定的沸石添加位置要求, 选择合适粒径的沸石。  The flue-cured flakes provided in this embodiment can effectively reduce the content of harmful components in the cigarette smoke by adsorbing zeolite, and reduce the harm caused by the cigarette smoke to the human body. However, due to the process of preparing the flake sheet and the limitation of the characteristics of the flake sheet itself, the content of the zeolite added to the flake sheet is limited. In the present embodiment, the sheet of the flake sheet contains 0.01 to 40%. The (mass) zeolite preferably contains 0.1 to 10% by mass of zeolite. The zeolite in the technical solution of the present invention may be unmodified or modified, and the present invention does not limit the type of zeolite. However, it is possible to select zeolite types having different pore structures and properties depending on the harm reduction requirements of the cigarette, and to select zeolites having a suitable particle size according to the zeolite addition position requirements determined in the sheet processing.
其中, 本实施例中的烟用薄片可以采用烟草薄片或非烟草薄片。 若采用 烟草薄片,则可以以烟草或烟草副产物为原料,采用现有工艺(也称造纸法), 经制浆和抄造工序, 制备烟草薄片, 所述烟草副产物是指香烟生产中被废弃 或剔除的烟草剩余物, 例如秸秆、 烟叶碎片、 烟梗等, 并且可以在制备烟草 薄片的过程(例如: 制浆工段、 抄造产物的涂布工段) 中添加沸石以制备包 含沸石的烟用薄片。  Among them, the tobacco sheet in the embodiment may be a tobacco sheet or a non-tobacco sheet. If tobacco flakes are used, tobacco flakes can be prepared by using a tobacco or tobacco by-product as a raw material, using an existing process (also called a papermaking process), and a pulping and papermaking process, which is discarded in the production of cigarettes. Or rejected tobacco residues, such as straw, tobacco leaf fragments, stems, etc., and may be added to the process for preparing the tobacco sheet (for example, a pulping section, a coating section of the paper product) to prepare a tobacco sheet containing zeolite .
若采用非烟草薄片, 非烟草薄片可以采用除烟草以外的农业副产物作为 原料, 所述农业副产物包括可提供纤维组织的农作物秸杆、 根、 茎、 茶叶、 茶梗以及草本植物等, 并可采用类似制备烟草薄片的工艺制备非烟草薄片, 同样可以在制备非烟草薄片的过程中添加沸石以制备包含沸石的烟用薄片。  If a non-tobacco sheet is used, the non-tobacco sheet may be made from agricultural by-products other than tobacco, including crop straw, roots, stems, tea leaves, tea stems, and herbs, which provide fibrous tissue, and Non-tobacco flakes can be prepared by a process similar to the preparation of tobacco flakes, and zeolites can also be added during the preparation of non-tobacco flakes to prepare flake flakes comprising zeolite.
实施例二 本实施例以制备含有 5% (质量)的沸石的烟用薄片为例, 说明本发明所 述包含沸石的烟用薄片的制备过程。 具体的, 本实施例以农业副产物为原料 来制备包含沸石的烟用薄片, 如图 1所示, 包括如下步骤:  [Embodiment 2] This embodiment exemplifies a process for preparing a flake sheet containing zeolite according to the present invention by taking a flake sheet containing 5% by mass of zeolite. Specifically, in this embodiment, a tobacco flake comprising zeolite is prepared by using agricultural by-products as raw materials, as shown in FIG. 1, comprising the following steps:
步骤 11 , 将农业副产物进行浸泡处理, 获取润胀物; 具体地, 可以将农业副产物置于 60~80°C的热水中进行时间为 20~30分 钟的浸泡处理以获取农业副产物润胀物, 或者将农业副产物置于常温水(本 发明中也称室温水) 中进行时间为 0.5~6 小时的浸泡处理以获取润胀物。 当 然, 本发明方案也可以选择高于室温, 但不高于 80°C的水浸泡原料, 根据水 温情况确定适当的浸泡时间。 Step 11: immersing agricultural by-products to obtain a swelling; Specifically, the agricultural by-product can be placed in hot water of 60-80 ° C for immersion treatment for 20-30 minutes to obtain agricultural by-product swell, or the agricultural by-product is placed at room temperature water (this invention In the room temperature water), the immersion treatment is carried out for 0.5 to 6 hours to obtain the swelling. Of course, the solution of the present invention can also select a water soaking material higher than room temperature, but not higher than 80 ° C, and determine an appropriate soaking time according to the water temperature condition.
步骤 12,将上述农业副产物的润胀物进行搓丝,获取农业副产物粗纤维; 具体地, 可以通过输送装置将已经润胀的农业副产物送入搓丝机进行搓 丝处理, 以便于后续操作。  Step 12, the above-mentioned agricultural by-product swelling is subjected to twisting to obtain crude agricultural by-product fibers; specifically, the swollen agricultural by-products can be sent to a spinning machine through a conveying device for silk processing, so as to facilitate Follow-up actions.
步骤 13 , 对农业副产物粗纤维进行洗涤处理, 获取农业副产物纤维; 具体地, 可以将农业副产物粗纤维置于 60~80 °C的热水中进行时间为 20-30 分钟的洗涤处理以获取农业副产物纤维, 或者将农业副产物粗纤维置 于常温水中进行时间为 30~60分钟的洗涤处理以获取农业副产物纤维; 通过 上述洗涤处理, 可以去除农业副产物粗纤维中的杂细胞和部分水溶性物质, 例如含氮化合物, 以达到净化农业副产物纤维的目的。 当然, 本发明方案也 可以选择高于室温, 但不高于 80°C的水作为洗涤溶剂, 根据水温情况确定适 当的洗涤时间。  Step 13: Washing the crude by-product of the agricultural by-product to obtain the agricultural by-product fiber; specifically, the crude agricultural by-product fiber may be placed in hot water of 60-80 ° C for 20-30 minutes of washing treatment; Obtaining agricultural by-product fibers, or placing the crude agricultural by-product fibers in normal temperature water for 30 to 60 minutes to obtain agricultural by-product fibers; by the above washing treatment, impurities in the crude by-products of agricultural by-products can be removed. Cells and partially water-soluble substances, such as nitrogen-containing compounds, are used for the purpose of purifying agricultural by-product fibers. Of course, the solution of the present invention can also select water above room temperature, but not higher than 80 ° C as a washing solvent, and determine the appropriate washing time according to the water temperature.
步骤 14, 将农业副产物纤维进行磨浆处理, 制取农业副产物浆料, 同时, 制取强化纤维浆料, 并将制取的强化纤维浆料与农业副产物浆料混合, 获取 混合浆料;  Step 14: refining the agricultural by-product fiber to prepare an agricultural by-product slurry, and simultaneously preparing a reinforcing fiber slurry, and mixing the prepared reinforcing fiber slurry with the agricultural by-product slurry to obtain a mixed pulp. Material
在该步骤中, 强化纤维浆料的制取过程可以采用造纸工艺中制取强化纤 维浆料的工序, 本实施例不再详细论述。 该强化纤维的加入是选择性的, 根 据所得到的薄片成品强度需要而定。 由于所使用的农业副产物的纤维短、 杂 细胞含量多, 在抄造过程中其成品的强度较差。 因此, 根据所选用农业副产 物种类不同, 在多数农业副产物浆料中加入适量的强化纤维增加薄片的强度 是必要的。 本实施例中通过加入强化纤维浆料, 利用强化加纤维以制备强度 符合卷烟加工工艺要求的烟用薄片。 强化纤维浆料的加入量一般控制在成浆 总量的 0~40wt%, 加入量在 20~40wt%是比较好的。  In this step, the process of preparing the reinforced fiber slurry can be carried out by using a process of preparing a reinforced fiber slurry in a papermaking process, which will not be discussed in detail in this embodiment. The addition of the reinforcing fibers is selective, depending on the strength requirements of the finished sheet. Since the agricultural by-products used have short fibers and a large amount of miscellaneous cells, the strength of the finished product is poor during the papermaking process. Therefore, depending on the type of agricultural by-product selected, it is necessary to add an appropriate amount of reinforcing fibers to most agricultural by-product slurries to increase the strength of the flakes. In the present embodiment, by adding a reinforcing fiber slurry, reinforcing fibers are used to prepare a sheet for tobacco having a strength in accordance with the requirements of the cigarette processing technology. The addition amount of the reinforcing fiber slurry is generally controlled to 0 to 40% by weight of the total amount of the slurry, and the addition amount is preferably 20 to 40% by weight.
步骤 15 , 将混合浆料送入沖浆池, 添加填料并进行稀释处理, 可根据需 要在添加填料的同时添加沸石; 在该过程中, 通过向沖浆池中添加填料(例如轻质碳酸钙) , 并加入水 稀释混合浆料到所需的浓度, 同时可以在该步骤中添加适量沸石悬浊液(例 如, 水分散液) , 以制备含有 5% (质量)的沸石的烟用薄片。 该步骤为本实 施例中可以添加沸石的第一添加位置。 Step 15, the mixed slurry is sent to the flushing tank, the filler is added and diluted, and the zeolite may be added while adding the filler as needed; In this process, by adding a filler (for example, light calcium carbonate) to the slurry tank, and adding water to dilute the mixed slurry to a desired concentration, an appropriate amount of zeolite suspension (for example, water may be added in this step). Dispersion) to prepare a flake flake containing 5% by mass of zeolite. This step is the first addition site in which zeolite can be added in this example.
步骤 16, 将经稀释处理的混合浆料送入高位箱, 添加助留剂, 制取成浆, 可根据需要在添加助留剂的同时添加沸石;  Step 16, the diluted mixed slurry is sent to the high-position box, and the retention aid is added to prepare a slurry, and the zeolite may be added while adding the retention aid as needed;
在该过程中, 通过向高位箱中添加助留剂 (例如瓜尔胶) 以增大混合浆 料上网时的留着率, 并稳定混合浆料的浆压以便于后续抄造操作。 所述助留 剂应为本领域公知的符合烟草行业标准的助留剂, 本发明对其具体选择不做 限制, 其添加量为助留剂的常规添加量。 在该过程中也可以添加沸石, 例如 将沸石悬浊液与助留剂混合后一起添加到混合浆料中, 并通过控制沸石悬浊 液的添加量, 以制取含有 5% (质量)沸石的烟用薄片。 该过程为本实施例中 可以添加沸石的第二添加位置。  In this process, the retention of the mixed slurry on the net is increased by adding a retention aid (e.g., guar gum) to the elevated tank, and the slurry pressure of the mixed slurry is stabilized for subsequent papermaking operations. The retention aid should be a retention aid in accordance with the tobacco industry standard known in the art, and the present invention is not limited to its specific selection, and the addition amount is a conventional addition amount of the retention aid. In the process, zeolite may also be added, for example, the zeolite suspension is mixed with a retention aid and added to the mixed slurry, and by controlling the addition amount of the zeolite suspension, a zeolite containing 5% by mass is prepared. The flakes are used. This process is the second addition site in which zeolite can be added in this example.
步骤 17, 将成浆送入成形网进行抄造处理, 获取薄片片基;  Step 17, feeding the slurry into a forming wire for papermaking to obtain a sheet base;
步骤 18,对薄片片基进行第一次烘干处理,去除薄片片基中大部分水分; 步骤 19, 将薄片片基送入涂布槽进行涂布处理, 可根据需要在涂布涂布 液的同时添力口沸石;  Step 18: performing a first drying process on the sheet base to remove most of the moisture in the sheet base; and step 19, feeding the sheet base into the coating tank for coating treatment, and coating the coating liquid as needed Simultaneously adding zeolite;
具体地, 将经过烘干处理后的薄片片基送入涂布槽, 在涂布槽中将制备 好的涂布液涂布在薄片片基上, 其中, 涂布液的作用是为了增加香气量、 去 除杂气、 提高烟气浓度、 降低刺激性、 改善余味、 提高口感舒适性等, 因此, 具有上述作用的物质制成的水溶液均可作为本实施例中的涂布液。 同时, 在 该过程中也可以制备沸石悬浊液, 将沸石悬浊液与涂布液进行混合后一起涂 布到薄片片基上(该薄片片基可能已经含有了沸石) , 并通过控制沸石悬浊 液的添加量, 以制取含有 5% (质量)沸石的烟用薄片。 该涂布过程为本实施 例中可以添加沸石的第三添加位置。  Specifically, the dried sheet substrate is fed into a coating tank, and the prepared coating liquid is coated on the sheet base in a coating tank, wherein the coating liquid serves to increase the aroma The amount, the removal of the gas, the increase in the concentration of the smoke, the reduction of the irritation, the improvement of the aftertaste, the improvement of the mouthfeel comfort, and the like, therefore, an aqueous solution made of the substance having the above-described effects can be used as the coating liquid in the present embodiment. At the same time, a zeolite suspension can also be prepared in the process, and the zeolite suspension is mixed with the coating liquid and applied together to the sheet base (the sheet base may already contain zeolite), and the zeolite is controlled. The suspension was added in an amount to prepare a flake sheet containing 5% by mass of zeolite. This coating process is the third addition site in which the zeolite can be added in this example.
步骤 20,对薄片片基进行第二次烘干处理,以制取满足需要的烟用薄片。 例如, 制取含沸石量为 5%、 含水量为 10~13%的、 厚度为 0.3 0.4毫米的烟用 薄片。  In step 20, the sheet base is subjected to a second drying treatment to obtain a sheet for tobacco that satisfies the needs. For example, a flake sheet having a zeolite content of 5% and a water content of 10 to 13% and a thickness of 0.3 0.4 mm is prepared.
在此需要说明的是, 通过以上三个添加位置均可以制备出含有沸石的烟 用薄片, 本发明中根据制备卷烟的要求, 添加沸石可以采用在上述任意一个 添加位置进行添加的方式, 也可以采用在上述多个添加位置同时添加的组合 方式。 当在多个位置添加沸石时, 所述烟用薄片中沸石的含量为总含量。 It should be noted that the smoke containing zeolite can be prepared through the above three added positions. In the present invention, depending on the requirements for preparing the cigarette, the zeolite may be added at any of the above-mentioned addition positions, or a combination of the above-mentioned plurality of addition positions may be employed. When the zeolite is added at a plurality of positions, the content of the zeolite in the flake sheet is the total content.
本实施例制备的烟用薄片中含有 5% (质量)的沸石, 应用于卷烟中, 既 解决了主流烟气中的焦油覆盖滤嘴降低沸石活性的问题, 也解决了在烟丝上 直接添加沸石时剂量受限、 交联剂堵塞沸石表面微孔和通道的问题, 同时还 能降低侧流烟气中的有害成分, 充分发挥了沸石的减害作用。  The tobacco flake prepared in this embodiment contains 5% (mass) of zeolite, which is applied to cigarettes, which solves the problem that the tar-covering filter in the mainstream flue gas reduces the activity of the zeolite, and also solves the direct addition of the zeolite on the shredded tobacco. The time-dose is limited, the cross-linking agent blocks the micropores and channels on the surface of the zeolite, and at the same time, the harmful components in the side-flow flue gas are reduced, and the harm reduction effect of the zeolite is fully exerted.
实施例三  Embodiment 3
本发明实施例三提供一种卷烟, 即, 该卷烟的可燃部分(如果是带过滤 嘴的香烟, 则指除滤嘴外的部分) 至少包含部分利用实施例二方法制备的烟 用薄片。 对于常见的卷烟, 包括烟纸、 烟丝和过滤嘴。 本发明提供的卷烟的 烟丝中均匀地混合有所述烟用薄片切成的烟用薄片丝, 具体地, 将片烟与烟 用薄片分别切丝, 然后按一定的比例混合, 或者将片烟与烟用薄片按一定的 比例混合后一起切丝, 然后将混合丝卷制成烟支。 本实施例的烟用薄片可以 采用实施例一提供的烟用薄片。 其中, 烟用薄片包括薄片片基, 而薄片片基 中含有 0.01~40% (质量) 的沸石, 优选的为含有 0.1~10% (质量) 的沸石。 所述烟用薄片可以采用烟草薄片或非烟草薄片, 所述烟用薄片吸附了沸石以 利用沸石的吸附和催化作用起到降低卷烟烟气中有害成分的含量。  A third embodiment of the present invention provides a cigarette, i.e., a flammable portion of the cigarette (in the case of a cigarette with a filter, a portion other than the filter) comprising at least a portion of the tobacco sheet prepared by the method of the second embodiment. For common cigarettes, including cigarette paper, cut tobacco and filters. The tobacco shredded tobacco of the present invention is uniformly mixed with the tobacco flakes cut by the tobacco flakes, specifically, the flakes and the flake flakes are respectively shredded, and then mixed in a certain ratio, or the flakes are smoked. After being mixed with a sheet of tobacco in a certain ratio, the yarn is shredded, and then the mixed yarn is rolled into a cigarette. The tobacco sheet of this embodiment can be the sheet for tobacco provided in the first embodiment. Among them, the flake sheet comprises a flake base, and the flake base contains 0.01 to 40% by mass of zeolite, preferably 0.1 to 10% by mass of zeolite. The tobacco sheet may be a tobacco sheet or a non-tobacco sheet, which adsorbs zeolite to utilize the adsorption and catalysis of the zeolite to reduce the content of harmful components in the cigarette smoke.
本实施例的卷烟中, 通过烟用薄片丝中吸附的沸石可以有效降低卷烟烟 气中的有害成分的含量, 降低卷烟烟气对人体造成的危害。 而根据卷烟的不 同需求,卷烟中烟用薄片丝的含量至少可以为卷烟的可燃部分的 3% (质量), 优选的为 25~60% (质量), 即可达到减害的目的, 又不影响卷烟的吸食风格。 当该卷烟的可燃部分全部由以非烟草薄片为原料的烟用薄片丝加工 (烟用薄 片丝含量为 100% ) 而成时, 得到的卷烟为完全不含烟丝的安全卷烟。  In the cigarette of the present embodiment, the zeolite adsorbed by the flake filaments can effectively reduce the content of harmful components in the cigarette smoke and reduce the harm caused by the cigarette smoke to the human body. According to the different needs of cigarettes, the content of the flakes in the cigarette can be at least 3% (mass) of the flammable portion of the cigarette, preferably 25-60% (mass), to achieve the purpose of harm reduction, and Affect the smoking style of cigarettes. When the flammable portion of the cigarette is entirely processed from a tobacco sheet which is made of a non-tobacco sheet (the tobacco sheet has a silk content of 100%), the obtained cigarette is a safe cigarette which is completely free of cut tobacco.
本实施例仍以农业副产物为原料为例说明制备本实施例的卷烟的流程, 如图 2所示, 具体包括:  In this embodiment, the process of preparing the cigarette of the embodiment is described by using the agricultural by-product as an example. As shown in FIG. 2, the method specifically includes:
步骤 21 , 以农业副产物为原料制备含有沸石的烟用薄片;  Step 21, preparing a flake sheet containing zeolite by using agricultural by-products as raw materials;
本步骤可以采用本发明实施例二提供的烟用薄片的制备方法来制备本实 施例的烟用薄片, 详细过程可以参见实施例二的描述, 其中沸石的含量可以 步骤 22,将片烟和所得到的烟用薄片分别切丝,然后按一定的比例混合, 或者将片烟与所得到的烟用薄片按一定的比例混合后一起切丝 , 然后将混合 丝卷制成烟支。 In this step, the tobacco sheet of the present embodiment can be prepared by using the method for preparing the tobacco sheet provided in the second embodiment of the present invention. For the detailed process, refer to the description of the second embodiment, wherein the content of the zeolite can be In step 22, the flakes and the obtained flake flakes are respectively shredded, and then mixed in a certain ratio, or the flakes and the obtained flake flakes are mixed in a certain ratio and then shred together, and then the mixed silk rolls are rolled. Made into cigarettes.
其中, 将烟用薄片切丝的过程可采用卷烟加工工艺中的切丝工序和设备 实现, 所切出的烟用薄片丝优选为与烟丝的长度、 宽度大致相同, 以便与普 通烟丝进行混合。 同样地, 将片烟与烟用薄片按一定的比例混合后一起切丝 的过程也可采用卷烟加工工艺中的切丝工序和设备实现。 其中烟用薄片与烟 丝的混合比例可以为 3~100%,该混合比例可以根据不同的卷烟需求而定,优 选的为 25~60% (质量) 。  Wherein, the process of shredding the tobacco sheet can be carried out by using a shredding process and equipment in the cigarette processing process, and the cut tobacco shred yarn is preferably substantially the same length and width as the shredded tobacco to be mixed with the ordinary shredded tobacco. Similarly, the process of shredding the flakes and the flakes in a certain ratio and then cutting them together can also be carried out by the shredding process and equipment in the cigarette processing process. The mixing ratio of the tobacco sheet and the tobacco can be 3 to 100%, and the mixing ratio can be determined according to different cigarette requirements, preferably 25 to 60% (mass).
本实施例制备的卷烟, 以烟用薄片作为载体, 将具有减害作用的沸石添 加到烟用薄片中, 并将所述烟用薄片应用于卷烟。 一方面, 克服了现有沸石 作为减害添加剂应用于卷烟时的不足: 既解决了主流烟气中的焦油覆盖滤嘴 降低沸石活性的问题, 也解决了在烟丝上直接添加沸石时剂量受限、 交联剂 堵塞沸石表面微孔和通道的问题, 同时还能降低侧流烟气中的有害成分, 充 分发挥了沸石的减害作用。 另一方面, 烟用薄片的使用提高了卷烟的燃烧性, 可以降低卷烟燃烧过程中产生的 CO等有害物质的释放量, 起到减害作用。  The cigarette prepared in the present embodiment is fed with a flake sheet as a carrier, and a zeolite having a detrimental action is added to the flake sheet, and the flake sheet is applied to a cigarette. On the one hand, it overcomes the shortcomings of the existing zeolite as a harm reduction additive for cigarettes: it not only solves the problem that the tar-covering filter in the mainstream flue gas reduces the activity of the zeolite, but also solves the limitation of the dose when the zeolite is directly added to the tobacco. The cross-linking agent blocks the micropores and channels on the surface of the zeolite, and at the same time reduces the harmful components in the sidestream flue gas, and fully exerts the harm reduction effect of the zeolite. On the other hand, the use of the flake sheet improves the combustibility of the cigarette, and can reduce the release amount of harmful substances such as CO generated during the combustion of the cigarette, thereby reducing the harm.
进一步, 通过对本实施例所制备的卷烟进行感官评吸测试, 测试结果表 明本实施例制备的卷烟基本保持原有的吸味风格, 而通过添加不同比例的烟 用薄片, 其烟气中的亚硝胺、 3 , 4-苯并芘、 苯酚、 巴豆醛、 CO、 氢氰酸以 及氨等有害物质均有明显降低。  Further, the sensory evaluation test of the cigarette prepared in the present embodiment shows that the cigarette prepared in the embodiment basically maintains the original flavor-absorbing style, and the cigarette in the smoke is added by adding different proportions of the tobacco sheet. Hazardous substances such as nitramine, 3, 4-benzopyrene, phenol, crotonaldehyde, CO, hydrocyanic acid and ammonia were all significantly reduced.
下面通过具体实验数据说明本发明实施例提供的烟用薄片应用于卷烟中 的作用和效果。  The action and effect of the tobacco sheet provided by the embodiment of the present invention in cigarettes will be described below by specific experimental data.
选用 NaY沸石, 以农业副产物为薄片片基原料, 根据本发明实施例二提 供的方法, 在抄造工段中, 将沸石制成悬浊液与涂布液一起涂布在薄片片基 上, 以制备含有 5% (质量)沸石的烟用薄片。  The NaY zeolite is selected, and the agricultural by-product is used as the sheet base material. According to the method provided in the second embodiment of the present invention, the zeolite suspension is coated on the sheet base together with the coating liquid in the papermaking section. A sheet of tobacco containing 5% by mass of zeolite was prepared.
选用 NaZSM-5沸石, 以农业副产物为薄片片基原料,根据本发明实施例 二提供的方法, 在制浆工段中, 将沸石制成悬浊液与助留剂一起添加到混合 浆料中, 以制得含有 5% (质量) 沸石的烟用薄片。 实验 1 The NaZSM-5 zeolite is selected, and the agricultural by-product is used as the raw material of the flakes. According to the method provided in the second embodiment of the present invention, the suspension of the zeolite is added to the mixed slurry together with the retention aid in the pulping section. To produce a sheet of tobacco containing 5% by mass of zeolite. Experiment 1
将含有 5%NaY沸石的烟用薄片切丝, 以 25%添加量捧入烟丝中, 卷成 烟支。 经感官评吸, 卷烟原有的吸食风格基本不变, 且烟气测试结果显示: 亚硝胺的量降低 25.7%,苯并芘的量降低 34.8%,其它有害成分也有明显降低, 同时侧流烟气中的有害成分也得到了降低, 减害效果显著。  The flake flakes containing 5% NaY zeolite were shredded, put into the cut tobacco at a 25% addition amount, and rolled into a cigarette. After the sensory evaluation, the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 25.7%, the amount of benzopyrene decreased by 34.8%, and other harmful components were also significantly reduced, while lateral flow The harmful components in the flue gas are also reduced, and the harm reduction effect is remarkable.
实验 2  Experiment 2
将含有 5%NaY沸石的烟用薄片切丝, 以 50%添加量捧入烟丝中, 卷成 烟支。 经感官评吸, 卷烟原有的吸食风格基本不变, 且烟气测试结果显示: 亚硝胺的量降低 31.7%, 苯并芘降低 41.6%, 其它有害成分也有明显降低, 同 时侧流烟气中的有害成分也得到了降低, 减害效果显著。  A sheet of tobacco containing 5% NaY zeolite was shredded, put into the cut tobacco at a 50% addition amount, and rolled into a cigarette. After the sensory evaluation, the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 31.7%, the benzopyrene decreased by 41.6%, and other harmful components were also significantly reduced, while the sidestream smoke was also reduced. The harmful components in the group have also been reduced, and the harm reduction effect is remarkable.
实验 3  Experiment 3
将含有 5%NaZSM-5沸石的烟用薄片切丝, 以 25%添加量捧入烟丝中, 卷成烟支。 经感官评吸, 卷烟原有的吸食风格基本不变, 且烟气测试结果显 示:亚硝胺的量降低 27.7% ,苯并芘降低 36.6%,其它有害成分也有明显降低, 同时侧流烟气中的有害成分也得到了降低, 减害效果显著。  The flake flakes containing 5% NaZSM-5 zeolite were shredded, put into the cut tobacco at a 25% addition amount, and rolled into a cigarette. After the sensory evaluation, the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 27.7%, the benzopyrene decreased by 36.6%, and other harmful components were also significantly reduced, while the sidestream smoke was also reduced. The harmful components in the group have also been reduced, and the harm reduction effect is remarkable.
实验 4  Experiment 4
将含有 5%NaZSM-5沸石的薄片切丝, 以 50%添加量捧入烟丝中, 卷成 烟支。 经感官评吸, 卷烟原有的吸食风格基本不变, 且烟气测试结果显示: 亚硝胺的量降低 36.4% , 多环芳烃的量降低 43.8%,其它有害成分也有明显降 低, 同时侧流烟气中的有害成分也得到了降低, 减害效果显著。  The flakes containing 5% NaZSM-5 zeolite were shredded, put into the cut tobacco at 50% addition, and rolled into a cigarette. After the sensory evaluation, the original smoking style of the cigarette was basically unchanged, and the smoke test results showed that the amount of nitrosamine decreased by 36.4%, the amount of polycyclic aromatic hydrocarbons decreased by 43.8%, and other harmful components were also significantly reduced, while lateral flow The harmful components in the flue gas are also reduced, and the harm reduction effect is remarkable.
进一步, 通过上述实验数据可以看出, 本发明提供的烟用薄片及卷烟, 不仅在保持卷烟吸食风格基本不变的前提下, 能够有效减少卷烟主流烟气和 侧流烟气中有害物质的释放量, 同时可以緩解烟草行业的烟草原料供应紧张 的状况, 降低卷烟中烟草的使用量, 具有很大的社会效益和经济效益。  Further, it can be seen from the above experimental data that the tobacco sheet and cigarette provided by the invention can effectively reduce the release of harmful substances in the mainstream smoke and sidestream smoke of the cigarette not only under the premise that the cigarette smoking style is basically unchanged. At the same time, it can alleviate the tight supply of tobacco raw materials in the tobacco industry and reduce the use of tobacco in cigarettes, which has great social and economic benefits.
最后应说明的是: 以上实施例仅用以说明本发明的技术方案, 而非对其 限制; 尽管参照前述实施例对本发明进行了详细的说明, 本领域的普通技术 人员应当理解: 其依然可以对前述各实施例所记载的技术方案进行修改, 或 者对其中部分技术特征进行等同替换; 而这些修改或者替换, 并不使相应技 术方案的本质脱离本发明各实施例技术方案的精神和范围。  It should be noted that the above embodiments are only for explaining the technical solutions of the present invention, and are not intended to be limiting; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those skilled in the art that: The technical solutions described in the foregoing embodiments are modified, or some of the technical features are equivalently replaced. The modifications and substitutions do not depart from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims

权利 要求 Rights request
1、 一种烟用薄片, 包括薄片片基, 其特征在于, 所述薄片片基中含有 0.01-40% (质量) 的沸石。  A sheet for cigarettes, comprising a sheet base, characterized in that the sheet base contains 0.01 to 40% by mass of zeolite.
2、 根据权利要求 1所述的烟用薄片, 其特征在于, 所述薄片片基中含有 0.1-10% (质量) 的沸石。  The sheet for tobacco according to claim 1, wherein the sheet base contains 0.1 to 10% by mass of zeolite.
3、 根据权利要求 1所述的烟用薄片, 其特征在于, 所述薄片片基中含有 5% (质量) 的沸石。  The sheet for tobacco according to claim 1, wherein the sheet base contains 5% by mass of zeolite.
4、 一种卷烟, 其特征在于, 该卷烟的可燃部分包含有利用权利要求 1-3 任一项所述的烟用薄片加工的烟用薄片丝。  A cigarette characterized in that the flammable portion of the cigarette comprises a shredded tobacco sheet processed by the tobacco sheet according to any one of claims 1 to 3.
5、 根据权利要求 4所述的卷烟, 其特征在于, 所述烟用薄片丝含量至少 为该卷烟可燃部分质量的 3%, 余量为烟丝。  The cigarette according to claim 4, wherein the tobacco flakes have a content of at least 3% by mass of the flammable portion of the cigarette, and the balance is cut tobacco.
6、 根据权利要求 4所述的卷烟, 其特征在于, 所述烟用薄片丝含量至少 为该卷烟可燃部分质量的 25%, 余量为烟丝。  The cigarette according to claim 4, wherein the tobacco flakes have a content of at least 25% by mass of the flammable portion of the cigarette, and the balance is cut tobacco.
7、 根据权利要求 6所述的卷烟, 其特征在于, 所述烟用薄片丝含量为该 卷烟可燃部分质量的 25-60%。  The cigarette according to claim 6, wherein the tobacco flakes have a silk content of from 25 to 60% by mass of the flammable portion of the cigarette.
PCT/CN2010/073547 2010-04-15 2010-06-04 Thin slice material for cigarette and cigarette WO2011127676A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201010149468.9 2010-04-15
CN2010101494689A CN102217791A (en) 2010-04-15 2010-04-15 Tobacco sheet and cigarette

Publications (1)

Publication Number Publication Date
WO2011127676A1 true WO2011127676A1 (en) 2011-10-20

Family

ID=44774701

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2010/073547 WO2011127676A1 (en) 2010-04-15 2010-06-04 Thin slice material for cigarette and cigarette

Country Status (2)

Country Link
CN (1) CN102217791A (en)
WO (1) WO2011127676A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110313631A (en) * 2018-03-30 2019-10-11 上海新型烟草制品研究院有限公司 A method of for adsorbing tobacco-specific nitrosamine in buccal cigarette offal

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1259322A (en) * 2000-02-01 2000-07-12 杨厚发 Safety type tobacco sheet and its tobacco product
CN1404778A (en) * 2002-11-05 2003-03-26 蒋岭章 Low-harmness safety cigarette and its processing method

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW536395B (en) * 1998-04-16 2003-06-11 Rothmans Benson & Hedges Cigarette sidestream smoke treatment material
CN1106806C (en) * 1998-09-02 2003-04-30 南京大学 Cigarette with low or moderate nitrosamines content in smoke and preparation thereof
CN1096883C (en) * 1999-09-24 2002-12-25 唐志群 Preservative
CN1315419C (en) * 2005-06-29 2007-05-16 韶关学院 Preparation method of environment-friendly type cigarette with sub-micron modified meerschaum composite additive
CN101103839A (en) * 2006-07-13 2008-01-16 河南省轻工业科学研究所 Paper-making method producing recombination tobacco leaf method
CN101268859B (en) * 2008-03-31 2010-06-02 中国烟草总公司郑州烟草研究院 Method for reducing harmful constituent in tobacco slice of papermaking method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1259322A (en) * 2000-02-01 2000-07-12 杨厚发 Safety type tobacco sheet and its tobacco product
CN1404778A (en) * 2002-11-05 2003-03-26 蒋岭章 Low-harmness safety cigarette and its processing method

Also Published As

Publication number Publication date
CN102217791A (en) 2011-10-19

Similar Documents

Publication Publication Date Title
EP2840911B1 (en) Smoking articles
WO2011127678A1 (en) Cigarette flake and preparation method thereof and the cigarette
US9220296B2 (en) Method of reducing tobacco-specific nitrosamines
WO2011127679A1 (en) Sheet for cigarette, preparation method thereof, and cigarette
WO2011127680A1 (en) Sheet for cigarette, preparation method thereof, and cigarette
CN103211288B (en) Thin section for tobacco and cigarette
KR20180044311A (en) Graphene sorbent, its preparation methods and uses, and cigarette filter tips and cigarettes
GB2119220A (en) Novel shredded tobacco stem material
CN106376968A (en) Cigarette with recreated cut tobacco leaves and cut stems as cut tobacco and filter tip containing nano granular material
EP2846651B1 (en) Tobacco product that produces lower carbon monoxide to tar ratio
KR20230068414A (en) Filters for smoking or vaping articles comprising a non-woven substrate
JP4044731B2 (en) Smoking
CN102783710A (en) Preparation method for plant swelling fiber composite cigarette filter tip
WO2011127681A1 (en) Cigarette flake and preparation method thereof, and the cigarette
WO2011127675A1 (en) Cigarette sheet and cigarette
WO2011127676A1 (en) Thin slice material for cigarette and cigarette
WO2011127677A1 (en) Cigarette sheet and cigarette
CN1276735C (en) Filter unit for filter-cigarettes and filter cigarettes
WO2011127674A1 (en) Thin slice material for cigarette and cigarette
CN113944065B (en) Harm-reducing cigarette paper and preparation method thereof
CN115581307B (en) Heated cigarette tobacco sheet containing oxygen storage material and preparation method thereof
KR100196012B1 (en) Cigarette filter
JPH0112472B2 (en)
CA1157732A (en) Tobacco stem material

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10849685

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 05/03/2013)

122 Ep: pct application non-entry in european phase

Ref document number: 10849685

Country of ref document: EP

Kind code of ref document: A1