WO2011124189A3 - Procédé de production d'hydrogène et d'autres produits et dispositif de mise en oeuvre dudit procédé - Google Patents

Procédé de production d'hydrogène et d'autres produits et dispositif de mise en oeuvre dudit procédé Download PDF

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Publication number
WO2011124189A3
WO2011124189A3 PCT/CZ2011/000030 CZ2011000030W WO2011124189A3 WO 2011124189 A3 WO2011124189 A3 WO 2011124189A3 CZ 2011000030 W CZ2011000030 W CZ 2011000030W WO 2011124189 A3 WO2011124189 A3 WO 2011124189A3
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WO
WIPO (PCT)
Prior art keywords
hydrogen
reactor
reaction
production
products
Prior art date
Application number
PCT/CZ2011/000030
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English (en)
Other versions
WO2011124189A4 (fr
WO2011124189A2 (fr
Inventor
Lukáš MOUREK
Ivan TRÁVNÍČEK
Ladislav BÍLÝ
Original Assignee
Mourek Lukas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mourek Lukas filed Critical Mourek Lukas
Priority to EP11728765A priority Critical patent/EP2556017A2/fr
Publication of WO2011124189A2 publication Critical patent/WO2011124189A2/fr
Publication of WO2011124189A3 publication Critical patent/WO2011124189A3/fr
Publication of WO2011124189A4 publication Critical patent/WO2011124189A4/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00—Apparatus for generating gases
    • B01J7/02—Apparatus for generating gases by wet methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/04—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/16—Purification by precipitation or adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/42—Preparation of aluminium oxide or hydroxide from metallic aluminium, e.g. by oxidation
    • C01F7/428—Preparation of aluminium oxide or hydroxide from metallic aluminium, e.g. by oxidation by oxidation in an aqueous solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00259—Preventing runaway of the chemical reaction
    • B01J2219/00263—Preventing explosion of the chemical mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/0027—Pressure relief
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Catalysts (AREA)

Abstract

De l'hydrogène est produit à partir d'aluminium résiduel par sa réaction avec de l'eau en présence d'hydroxyde de sodium en tant que catalyseur. En plus de l'hydrogène, les produits de la réaction sont également l'hydroxyde d'aluminium, le chlorure de sodium, la chaleur et éventuellement l'énergie électrique. La réaction se produit dans le réacteur (1), et l'hydrogène est collecté dans un réservoir d'hydrogène basse pression (3). La caractéristique principale de la production d'hydrogène, selon l'invention, est que le gaz est successivement éliminé du réacteur (1) et/ou d'autres dispositifs accessoires à l'aide d'une pompe à vide (4) à une pression minimale de 0,5 kPa avant la réaction, puis le réacteur est rempli d'hydrogène présentant une pureté minimale de 99,5%, le gaz est à nouveau extrait par pompage, puis on procède à un remplissage ultérieur avec de l'hydrogène présentant une pureté minimale de 99,5% à nouveau jusqu'à atteindre une pression positive d'au moins 0,1 MPa. Le gaz éliminé du réacteur et/ou d'un équipement accessoire à l'aide de la pompe à vide (4) est évacué vers une cheminée (5) et dispersé dans l'atmosphère. L'invention a pour objet un procédé et un dispositif pour la production sûre d'hydrogène à une échelle industrielle et d'autres produits ainsi que leur purification pour une application industrielle appropriée en tant que matières premières pour une autre production industrielle.
PCT/CZ2011/000030 2010-04-07 2011-04-06 Procédé de production d'hydrogène et d'autres produits et dispositif de mise en oeuvre dudit procédé WO2011124189A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11728765A EP2556017A2 (fr) 2010-04-07 2011-04-06 Procédé de production d'hydrogène et d'autres produits et dispositif de mise en oeuvre dudit procédé

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZ20100268A CZ302453B6 (cs) 2010-04-07 2010-04-07 Zpusob výroby vodíku a dalších produktu a zarízení k provádení tohoto zpusobu
CZPV2010-268 2010-04-07

Publications (3)

Publication Number Publication Date
WO2011124189A2 WO2011124189A2 (fr) 2011-10-13
WO2011124189A3 true WO2011124189A3 (fr) 2012-02-23
WO2011124189A4 WO2011124189A4 (fr) 2012-04-19

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Country Status (3)

Country Link
EP (1) EP2556017A2 (fr)
CZ (1) CZ302453B6 (fr)
WO (1) WO2011124189A2 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013150527A1 (fr) * 2012-04-05 2013-10-10 H Force Ltd Système et procédé pour la production efficace d'hydrogène
WO2014062833A1 (fr) * 2012-10-16 2014-04-24 Helton Bill W Catalyseurs de production d'hydrogène et systèmes et procédés associés
CZ2013749A3 (cs) 2013-09-30 2015-03-25 Mourek Lukáš Způsob recyklace odpadního hliníku a zařízení k provádění tohoto způsobu
CN105980295B (zh) * 2013-12-19 2019-06-04 霍尼韦尔国际公司 散热材料及其制造方法
CN104192796B (zh) * 2014-09-04 2016-01-27 桂林浩新科技服务有限公司 一种自搅拌制氢装置
RU173853U1 (ru) * 2016-10-28 2017-09-14 Общество с ограниченной ответственностью "Технологии алюмоэнергетики" (ООО "Технологии алюмоэнергетики") Установка для получения оксидов алюминия высокой чистоты
JP7056372B2 (ja) * 2018-05-22 2022-04-19 Ｊｆｅエンジニアリング株式会社 水素製造方法及び水素製造装置
FR3103482B1 (fr) * 2019-11-25 2022-07-22 Nebula Tech Procédé et installation pour produire de l’hydroxyde d’aluminium
CN115259187B (zh) * 2022-07-25 2024-01-16 河津市炬华铝业有限公司 一种高比表面积大孔拟薄水铝石粉体及其制备方法
GB202213860D0 (en) * 2022-09-22 2022-11-09 Net Zero Scient Ltd Hydrogen production process

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530598A1 (fr) * 1991-09-04 1993-03-10 Deutsche Solvay-Werke Gesellschaft mit beschränkter Haftung Procédé de préparation de chlorure et/ou aluminium basique
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
US6506360B1 (en) * 1999-07-28 2003-01-14 Erling Reidar Andersen Method for producing hydrogen
WO2008114951A1 (fr) * 2007-03-20 2008-09-25 Jung-Tae Park Appareil pour générer de l'hydrogène gazeux en utilisant une composition pour la génération d'hydrogène gazeux et composition pour la génération d'hydrogène gazeux
WO2009018468A1 (fr) * 2007-07-31 2009-02-05 Purdue Research Foundation Système de commande pour un générateur de gaz à la demande
US20100061923A1 (en) * 2008-09-05 2010-03-11 Reddy Alla V K Hydrogen production and use

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3401194A1 (de) 1984-01-14 1985-07-18 Werner 7433 Dettingen Schweikert Einrichtung zum nutzen der energie aus verschiedenen metallabfaellen in verbindung mit natronlauge
JPH01208301A (ja) * 1988-02-15 1989-08-22 Mitsubishi Heavy Ind Ltd 水素発生方法
JP2003226502A (ja) * 2002-02-06 2003-08-12 Mitsubishi Heavy Ind Ltd 水素発生装置及び方法
CN100563820C (zh) 2006-04-29 2009-12-02 刘欣 一种用铝从水中置换出氢气的催化剂
AT504050A1 (de) 2006-08-07 2008-02-15 Alvatec Alkali Vacuum Technolo Wasserstoffgenerator
RU2356830C2 (ru) 2007-06-26 2009-05-27 ОАО Научно-производственное предприятие "Квант" Способ получения водорода
CN101284647B (zh) * 2008-02-29 2011-05-11 邓振炎 表面改性铝粉体与水反应产生氢气的工艺方法
CN101284646B (zh) * 2008-02-29 2011-07-20 上海大学 用纯铝粉体与水反应产生氢气的工艺方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530598A1 (fr) * 1991-09-04 1993-03-10 Deutsche Solvay-Werke Gesellschaft mit beschränkter Haftung Procédé de préparation de chlorure et/ou aluminium basique
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
US6506360B1 (en) * 1999-07-28 2003-01-14 Erling Reidar Andersen Method for producing hydrogen
WO2008114951A1 (fr) * 2007-03-20 2008-09-25 Jung-Tae Park Appareil pour générer de l'hydrogène gazeux en utilisant une composition pour la génération d'hydrogène gazeux et composition pour la génération d'hydrogène gazeux
WO2009018468A1 (fr) * 2007-07-31 2009-02-05 Purdue Research Foundation Système de commande pour un générateur de gaz à la demande
US20100061923A1 (en) * 2008-09-05 2010-03-11 Reddy Alla V K Hydrogen production and use

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
"Alumina Chemicals, Science and Technology Handbook", 1990, THE AMERICAN CERAMIC SOCIETY, INC., ISBN: 0-916094-33-2, article LARRY L. MUSSELMAN: "III Production Processes, Properties, and Applications for Aluminium-Containing Hydroxides", pages: 75 - 92, XP002666075 *
K. H. GAYER, L. C. THOMPSON, O. T. ZAJICEK: "THE SOLUBILITY OF ALUMINUM HYDROXIDE IN ACIDIC AND BASIC MEDIA AT 25 °C", CANADIAN JOURNAL OF CHEMISTRY, 1958, pages 1268 - 1271, XP002666077, Retrieved from the Internet <URL:http://www.nrcresearchpress.com/action/doSearch?sortBy=&startPage=0&pageSize=20&searchText=&title=&author=gayer&abstract=&stemming=yes&publication=40000018&startEarliestMonth=&startEarliestYear=1958&endEarliestMonth=&endEarliestYear=1958> [retrieved on 20111219], DOI: 10.1139/v58-184 *
STOCKBURGER D ET AL: "ON-LINE HYDROGEN GENERATION FROM ALUMINUM IN AN ALKALINE SOLUTION", PROCEEDINGS OF THE ELECTROCHEMICAL SOCIETY, NEW YORK,NY, US, vol. 92-5, 1 January 1991 (1991-01-01), pages 431 - 444, XP001032928 *
W. BLUM: "The Determination of Aluminium as Oxide", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, July 1916 (1916-07-01), pages 1282 - 1297, XP002666076, Retrieved from the Internet <URL:http://pubs.acs.org/doi/abs/10.1021/ja02264a006> [retrieved on 20111219], DOI: 10.1021/ja02264a006 *

Also Published As

Publication number Publication date
WO2011124189A4 (fr) 2012-04-19
EP2556017A2 (fr) 2013-02-13
CZ2010268A3 (cs) 2011-05-25
WO2011124189A2 (fr) 2011-10-13
CZ302453B6 (cs) 2011-05-25

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