WO2011115394A3 - 바이오 매스를 이용한 수송용 연료 또는 윤활기유의 제조방법 - Google Patents

바이오 매스를 이용한 수송용 연료 또는 윤활기유의 제조방법 Download PDF

Info

Publication number
WO2011115394A3
WO2011115394A3 PCT/KR2011/001754 KR2011001754W WO2011115394A3 WO 2011115394 A3 WO2011115394 A3 WO 2011115394A3 KR 2011001754 W KR2011001754 W KR 2011001754W WO 2011115394 A3 WO2011115394 A3 WO 2011115394A3
Authority
WO
WIPO (PCT)
Prior art keywords
ketones
biomass
base oil
lubricating base
hydrodeoxygenation
Prior art date
Application number
PCT/KR2011/001754
Other languages
English (en)
French (fr)
Other versions
WO2011115394A2 (ko
Inventor
정영민
김옥윤
전희중
윤영식
이성호
김희수
오승훈
임윤재
Original Assignee
에스케이이노베이션 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020100024794A external-priority patent/KR101871496B1/ko
Priority claimed from KR1020100069983A external-priority patent/KR101670515B1/ko
Application filed by 에스케이이노베이션 주식회사 filed Critical 에스케이이노베이션 주식회사
Priority to BR112012023605A priority Critical patent/BR112012023605A2/pt
Priority to CN201180024203.9A priority patent/CN102906229B/zh
Priority to US13/635,584 priority patent/US8679805B2/en
Publication of WO2011115394A2 publication Critical patent/WO2011115394A2/ko
Publication of WO2011115394A3 publication Critical patent/WO2011115394A3/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C10G3/52—Hydrogen in a special composition or from a special source
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02—Well-defined hydrocarbons
    • C10M105/04—Well-defined hydrocarbons aliphatic
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6409—Fatty acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02—Well-defined aliphatic compounds
    • C10M2203/022—Well-defined aliphatic compounds saturated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)

Abstract

본 발명은 바이오 매스 유래의 휘발성 지방산(VFA)을 이용하여 가솔린 연료 또는 윤활기유에 해당하는 파라핀 화합물을 경제적으로 제조하는 방법에 관한 것이다. 본 발명에 따른 방법은 바이오 매스의 발효과정을 통하여 산출된 C2 ~ C4의 휘발성 지방산을 준비하는 단계; 상기 휘발성 지방산을 케톤화 반응시켜 C3 ~ C7의 케톤 혼합물을 산출시키는 단계; 상기 산출된 케톤을 알돌 축합 반응을 통해 C6 ~ C60의 케톤을 제조하는 단계; 및 수첨탈산소 반응을 통해 C6 ~ C60의 파라핀으로 전환시키는 단계를 포함한다. 알돌 축합 반응 및 수첨탈산소 반응은 순차적 또는 하나의 단계에서 동시에 진행될 수 있으며, 저온 조건에서 반응이 진행될 수 있는 것이 특징이고, 축합, 수첨, 수첨탈산소화 기능 등을 하나 이상 가지고 있는 물질을 물리적으로 혼합 또는 바인더 물질을 이용하여 성형하는 형태로 촉매를 구성하거나, 또는 이중 층으로 구성하는 방식으로 촉매계를 사용할 경우, 고품질의 가솔린 연료 또는 윤활기유를 경제적인 방법으로 직접 제조할 수 있다.
PCT/KR2011/001754 2010-03-19 2011-03-14 바이오 매스를 이용한 수송용 연료 또는 윤활기유의 제조방법 WO2011115394A2 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR112012023605A BR112012023605A2 (pt) 2010-03-19 2011-03-14 método de preparo de combustível ou óleo base lubrificante para transporte utilizando biomassa
CN201180024203.9A CN102906229B (zh) 2010-03-19 2011-03-14 使用生物质制备运输燃料或润滑油基础油的方法
US13/635,584 US8679805B2 (en) 2010-03-19 2011-03-14 Preparation method of transportation fuel or lubricating base oil using biomass

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2010-0024794 2010-03-19
KR1020100024794A KR101871496B1 (ko) 2010-03-19 2010-03-19 바이오 매스를 이용한 수송용 연료 및 윤활기유의 제조방법
KR10-2010-0069983 2010-07-20
KR1020100069983A KR101670515B1 (ko) 2010-07-20 2010-07-20 케톤으로부터 파라핀 제조 방법

Publications (2)

Publication Number Publication Date
WO2011115394A2 WO2011115394A2 (ko) 2011-09-22
WO2011115394A3 true WO2011115394A3 (ko) 2012-01-12

Family

ID=44649703

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2011/001754 WO2011115394A2 (ko) 2010-03-19 2011-03-14 바이오 매스를 이용한 수송용 연료 또는 윤활기유의 제조방법

Country Status (5)

Country Link
US (1) US8679805B2 (ko)
CN (1) CN102906229B (ko)
BR (1) BR112012023605A2 (ko)
MY (1) MY162616A (ko)
WO (1) WO2011115394A2 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101748442B1 (ko) * 2010-10-21 2017-06-19 에스케이이노베이션 주식회사 바이오매스 혹은 유기성 폐기물로부터 탄화수소를 제조하는 방법
US8546635B1 (en) 2012-04-04 2013-10-01 Uop Llc Methods and apparatuses for preparing upgraded pyrolysis oil
US9221725B2 (en) 2012-07-18 2015-12-29 Exxonmobil Research And Engineering Company Production of lubricant base oils from biomass
US9103042B2 (en) 2013-03-07 2015-08-11 Exxonmobil Research And Engineering Company Electrochemical synthesis to produce lube stock from renewable feeds
KR102063945B1 (ko) 2013-06-05 2020-01-09 에스케이이노베이션 주식회사 바이오매스 유래 아세트산으로부터 방향족 화합물을 제조하는 방법
ES2842199T3 (es) * 2016-09-29 2021-07-13 Neste Oyj Mejoramiento de 5-nonanona
CN107629810A (zh) * 2017-03-07 2018-01-26 华东理工大学 一种由生物质制备润滑油组分的方法
CA3064982C (en) 2017-06-19 2023-08-08 Neste Oyj Process for the production of renewable base oil, diesel and naphtha
CN107723054A (zh) * 2017-09-06 2018-02-23 吴江华威特种油有限公司 一种环保生物基润滑油制备方法
US11111509B2 (en) 2018-03-15 2021-09-07 Indian Oil Corporation Limited Bio-assisted process for conversion of mixed volatile fatty acids to selective drop-in fuels
CN108587702B (zh) * 2018-04-19 2020-06-26 徐州鑫辉生物能源科技有限公司 一种催化放氧清洁燃料的制备方法
CN111215073B (zh) * 2018-11-23 2024-03-12 中国石油化工股份有限公司 镍硅复合氧化物、其制备方法、包含该氧化物的催化剂及其应用
GB201900553D0 (en) 2019-01-15 2019-03-06 Norwegian Univ Sci & Tech Ntnu Preparation of biofuel from biomass
US11420912B2 (en) * 2019-12-13 2022-08-23 Alliance For Sustainable Energy, Llc Fuels and methods of making the same
CN112844387B (zh) * 2020-12-30 2022-07-19 山西大学 一种双功能镍铁类水滑石催化剂及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007068800A2 (en) * 2005-12-12 2007-06-21 Neste Oil Oyj Process for producing a saturated hydrocarbon component
WO2007068795A1 (en) * 2005-12-12 2007-06-21 Neste Oil Oyj Process for producing a hydrocarbon component
US20070244343A1 (en) * 2006-03-20 2007-10-18 Eelko Brevoord Process for the decarboxylation of fatty acids
KR20080079310A (ko) * 2005-12-12 2008-08-29 네스테 오일 오와이제이 분지형 탄화수소 성분의 제조방법
WO2008152200A1 (en) * 2007-06-11 2008-12-18 Neste Oil Oyj Process for producing branched hydrocarbons

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5874263A (en) 1996-07-31 1999-02-23 The Texas A&M University System Method and apparatus for producing organic acids
US5969189A (en) 1997-06-30 1999-10-19 The Texas A&M University System Thermal conversion of volatile fatty acid salts to ketones
US6043392A (en) 1997-06-30 2000-03-28 Texas A&M University System Method for conversion of biomass to chemicals and fuels
BR0010379A (pt) 1999-03-11 2001-12-26 Dan Verser Processo para a produção de etanol
US7998339B2 (en) * 2005-12-12 2011-08-16 Neste Oil Oyj Process for producing a hydrocarbon component
FI20055665L (fi) * 2005-12-12 2007-06-13 Neste Oil Oyj Prosessi haarautuneen hiilivetykomponentin valmistamiseksi
US7850841B2 (en) * 2005-12-12 2010-12-14 Neste Oil Oyj Process for producing a branched hydrocarbon base oil from a feedstock containing aldehyde and/or ketone
US20080280338A1 (en) 2007-05-11 2008-11-13 Hall Kenneth R Biofuel Processing System
US8153850B2 (en) 2007-05-11 2012-04-10 The Texas A&M University System Integrated biofuel production system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007068800A2 (en) * 2005-12-12 2007-06-21 Neste Oil Oyj Process for producing a saturated hydrocarbon component
WO2007068795A1 (en) * 2005-12-12 2007-06-21 Neste Oil Oyj Process for producing a hydrocarbon component
KR20080079310A (ko) * 2005-12-12 2008-08-29 네스테 오일 오와이제이 분지형 탄화수소 성분의 제조방법
US20070244343A1 (en) * 2006-03-20 2007-10-18 Eelko Brevoord Process for the decarboxylation of fatty acids
WO2008152200A1 (en) * 2007-06-11 2008-12-18 Neste Oil Oyj Process for producing branched hydrocarbons

Also Published As

Publication number Publication date
BR112012023605A2 (pt) 2016-08-02
US8679805B2 (en) 2014-03-25
US20130017590A1 (en) 2013-01-17
CN102906229A (zh) 2013-01-30
MY162616A (en) 2017-06-30
CN102906229B (zh) 2015-01-07
WO2011115394A2 (ko) 2011-09-22

Similar Documents

Publication Publication Date Title
WO2011115394A3 (ko) 바이오 매스를 이용한 수송용 연료 또는 윤활기유의 제조방법
CA2631879C (en) Process for the manufacture of hydrocarbons
Vonortas et al. Comparative analysis of biodiesel versus green diesel
CA2688449C (en) Process for producing branched hydrocarbons
Sotelo-Boyás et al. Hydroconversion of triglycerides into green liquid fuels
Santillan‐Jimenez et al. Catalytic deoxygenation of fatty acids and their derivatives to hydrocarbon fuels via decarboxylation/decarbonylation
Yigezu et al. Catalytic cracking of vegetable oil with metal oxides for biofuel production
JP5171946B2 (ja) バイオ燃料組成物、その製造方法、及びその燃料供給方法
US8143469B2 (en) Process for producing branched hydrocarbons
CA2812976C (en) Process for the hydrotreatment of vegetal materials
WO2008105798A3 (en) Method for cold stable biojet fuel
MY156853A (en) Method for producing aviation fuel oil base and aviation fuel oil composition
WO2011060116A3 (en) Process for producing renewable gasoline, and fuel compositions produced therefrom
SG194210A1 (en) Low pour point renewable fuel blend
Kaushik et al. Biodiesel a substitution for conventional diesel fuel: a comprehensive review
KR101607868B1 (ko) 비식용 유지를 이용한 고품질 바이오항공유 제조방법 및 이에 의해 제조된 바이오항공유
Pattanaik et al. Experimental studies on production of deoxygenated vegetable oils and their performance evaluation in a compression ignition engine
Cremonez et al. Potential of green diesel to complement the Brazilian energy production: a review
da Silva et al. Catalytic upgrading of fats and vegetable oils for the production of fuels
KR102355673B1 (ko) 올레핀계 화합물 및 탄화수소 연료 또는 이의 분획의 제조 공정
WO2012087505A3 (en) Biofuel production by co-feeding fischer-tropsch wax and biomass derived oil into upgrader
WO2009089456A3 (en) Ethanol as a feedstock for a bctl facility
KR101871496B1 (ko) 바이오 매스를 이용한 수송용 연료 및 윤활기유의 제조방법
Babcock et al. Yield characteristics of biodiesel produced from chicken fat-tall oil blended feedstocks
Ganesan et al. Synthesis and characterization of core-shell modeled AlMCM-48/HZSM-5 composite catalyst and studies on its catalytic activity in cracking of pongamia oil into bio liquid products

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201180024203.9

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11756525

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 13635584

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 8715/CHENP/2012

Country of ref document: IN

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112012023605

Country of ref document: BR

122 Ep: pct application non-entry in european phase

Ref document number: 11756525

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 112012023605

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20120919