WO2011108019A1 - Refrigeration cycle device - Google Patents
Refrigeration cycle device Download PDFInfo
- Publication number
- WO2011108019A1 WO2011108019A1 PCT/JP2010/001359 JP2010001359W WO2011108019A1 WO 2011108019 A1 WO2011108019 A1 WO 2011108019A1 JP 2010001359 W JP2010001359 W JP 2010001359W WO 2011108019 A1 WO2011108019 A1 WO 2011108019A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heating operation
- heat storage
- temperature
- compressor
- heat exchanger
- Prior art date
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B47/00—Arrangements for preventing or removing deposits or corrosion, not provided for in another subclass
- F25B47/02—Defrosting cycles
- F25B47/022—Defrosting cycles hot gas defrosting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B49/00—Arrangement or mounting of control or safety devices
- F25B49/02—Arrangement or mounting of control or safety devices for compression type machines, plants or systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B31/00—Compressor arrangements
- F25B31/006—Cooling of compressor or motor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B47/00—Arrangements for preventing or removing deposits or corrosion, not provided for in another subclass
- F25B47/02—Defrosting cycles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/05—Compression system with heat exchange between particular parts of the system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/24—Storage receiver heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2600/00—Control issues
- F25B2600/01—Timing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2700/00—Sensing or detecting of parameters; Sensors therefor
- F25B2700/15—Power, e.g. by voltage or current
- F25B2700/151—Power, e.g. by voltage or current of the compressor motor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2700/00—Sensing or detecting of parameters; Sensors therefor
- F25B2700/21—Temperatures
- F25B2700/2111—Temperatures of a heat storage receiver
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2700/00—Sensing or detecting of parameters; Sensors therefor
- F25B2700/21—Temperatures
- F25B2700/2115—Temperatures of a compressor or the drive means therefor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2700/00—Sensing or detecting of parameters; Sensors therefor
- F25B2700/21—Temperatures
- F25B2700/2115—Temperatures of a compressor or the drive means therefor
- F25B2700/21152—Temperatures of a compressor or the drive means therefor at the discharge side of the compressor
Definitions
- the present invention relates to a refrigeration cycle apparatus including a heat storage tank that stores a heat storage material that stores heat generated by a compressor, and a heat storage heat exchanger that performs heat exchange using heat stored in the heat storage material.
- FIG. 7 shows an example of a refrigeration cycle apparatus that employs such a defrosting method.
- the compressor 100, the four-way valve 102, the outdoor heat exchanger 104, the capillary tube 106, the indoor unit provided in the outdoor unit are shown. Is connected to the indoor heat exchanger 108 provided by the refrigerant pipe, the first bypass circuit 110 for bypassing the capillary tube 106, and the discharge side of the compressor 100 to the indoor heat exchanger 108 via the four-way valve 102.
- a second bypass circuit 112 is provided in which one end is connected to the connecting pipe and the other end is connected to the pipe extending from the capillary tube 106 to the outdoor heat exchanger 104.
- the first bypass circuit 110 is provided with a two-way valve 114, a check valve 116, and a heat storage heat exchanger 118, and the second bypass circuit 112 is provided with a two-way valve 120 and a check valve 122. Yes.
- a heat storage tank 124 is provided around the compressor 100, and the heat storage tank 124 is filled with a heat storage material 126 for exchanging heat with the heat storage heat exchanger 118.
- the two two-way valves 114 and 120 are opened, a part of the refrigerant discharged from the compressor 100 flows to the second bypass circuit 112, and the remaining refrigerant is the four-way valve 102. And flows to the indoor heat exchanger 108.
- a small amount of refrigerant flows to the outdoor heat exchanger 104 through the capillary tube 106, while the remaining most of the refrigerant passes through the first bypass circuit.
- the heat storage heat exchanger 118 flows into the heat storage heat exchanger 118 through the two-way valve 114, takes heat from the heat storage material 126, passes through the check valve 116, and then merges with the refrigerant that has passed through the capillary tube 106 to the outdoor. It flows to the heat exchanger 104. After that, it merges with the refrigerant flowing through the second bypass circuit 112 at the inlet of the outdoor heat exchanger 104, performs defrosting using the heat of the refrigerant, passes through the four-way valve 102, and then enters the compressor 100. Inhaled.
- the hot gas discharged from the compressor 100 during defrosting is guided to the outdoor heat exchanger 104 and the pressure of the refrigerant flowing into the outdoor heat exchanger 104 Therefore, the defrosting ability can be increased, and the defrosting can be completed in a very short time.
- the heat storage material 126 itself may be altered (for example, oxidized) or the water boiling of the heat storage material 126 may occur, causing the heat storage material 126 to deteriorate.
- the present invention has been made in view of such problems of the prior art, and provides a refrigeration cycle apparatus capable of preventing deterioration of a heat storage material that accumulates heat generated by a compressor. It is aimed.
- the present invention accommodates a compressor, an indoor heat exchanger, an expansion valve and an outdoor heat exchanger connected via a refrigerant pipe, and a heat storage material that accumulates heat generated by the compressor.
- a refrigeration cycle apparatus comprising a heat storage tank and a heat storage device having a heat storage heat exchanger that performs heat exchange with heat storage of the heat storage material, and discharged from the compressor when the temperature of the heat storage material is equal to or lower than a predetermined temperature.
- the refrigerant discharged from the compressor when the temperature of the heat storage material exceeds a predetermined temperature is exchanged with the indoor heat exchanger.
- a controller for switching to the second heating operation for passing the heat storage heat exchanger.
- a compressor, an indoor heat exchanger, an expansion valve, and an outdoor heat exchanger are used during the first heating operation.
- heat generated by the compressor is generated in the heat storage material of the heat storage device. Accumulated.
- the controller switches to the second heating operation using the heat storage heat exchanger, and during the second heating operation, the heat storage heat exchanger performs heat exchange by heat storage of the heat storage material. As a result, the temperature of the heat storage material decreases.
- coolant of the air conditioner of FIG. The schematic diagram which shows the operation
- the present invention relates to a compressor, an indoor heat exchanger, an expansion valve, and an outdoor heat exchanger connected via a refrigerant pipe, a heat storage tank that stores a heat storage material that stores heat generated by the compressor, and a heat storage material.
- a predetermined temperature When the temperature of the heat storage material is equal to or lower than a predetermined temperature, the refrigerant discharged from the compressor is expanded with the indoor heat exchanger. From the first heating operation in which the valve and the outdoor heat exchanger are passed, the refrigerant discharged from the compressor when the temperature of the heat storage material exceeds a predetermined temperature is passed through the indoor heat exchanger and the heat storage heat exchanger. And a controller for switching to the second heating operation.
- switching from the first heating operation to the second heating operation is performed.
- the heat generated by the compressor is accumulated in the heat storage material
- the heat storage heat exchanger performs heat exchange by storing heat in the heat storage material.
- the temperature of the material decreases.
- the refrigerant pipe that branches from the refrigerant pipe connecting the indoor heat exchanger and the expansion valve to the heat storage heat exchanger further includes an electromagnetic valve that is opened and closed based on a control signal from the controller, Switches from the first heating operation to the second heating operation by opening the solenoid valve.
- the controller controls the opening and closing of the solenoid valve so that the solenoid valve is opened for a first predetermined time and then the solenoid valve is closed for a second predetermined time.
- the second predetermined time is typically longer than the first predetermined time.
- the opening / closing control of the solenoid valve is repeated for a predetermined cycle, with the open state of the solenoid valve for the first predetermined time and the closed state for the second predetermined time as one cycle.
- the temperature of a thermal storage material can be reduced to the temperature which does not cause deterioration of a thermal storage material.
- the refrigeration cycle apparatus further includes, for example, a heat storage material temperature sensor that detects a temperature of the heat storage material, and the controller performs the first heating operation from the first heating operation based on the temperature detected by the heat storage material temperature sensor. Switch to 2 heating operation.
- the refrigeration cycle apparatus further includes a compressor temperature sensor that detects a temperature of the compressor, and the controller performs the first heating operation based on the temperature detected by the compressor temperature sensor. Switch to the second heating operation.
- the refrigeration cycle apparatus further includes a discharge refrigerant temperature sensor that detects a temperature of refrigerant discharged from the compressor, and the controller is configured to detect the first temperature based on the temperature detected by the discharge refrigerant temperature sensor. The heating operation is switched from the first heating operation to the second heating operation.
- the refrigeration cycle apparatus further includes a heat storage tank temperature sensor that detects the temperature of the heat storage tank itself, and the controller performs the first heating operation based on the temperature detected by the heat storage tank temperature sensor. To the second heating operation.
- the refrigeration cycle apparatus further includes an operating current sensor that detects an operating current of the compressor, and the controller is configured to perform the first operation based on the operating current of the compressor detected by the operating current sensor. The heating operation is switched to the second heating operation.
- the operating frequency of the compressor is lowered as compared with that during the first heating operation.
- the controller has a temperature of the heat storage material that is lower than a second predetermined temperature lower than the first predetermined temperature during the second heating operation. It is preferable to switch to the first heating operation. Thus, by making a difference between the first predetermined temperature and the second predetermined temperature, it is possible to prevent the first heating operation and the second heating operation from being frequently switched with each other.
- the refrigeration cycle apparatus further includes a timer capable of timing at least an elapsed time since switching to the second heating operation, and the controller is an elapsed time measured by the timer during the second heating operation. Can be switched to the first heating operation at a predetermined time.
- FIG. 1 shows a configuration of an air conditioner that is a refrigeration cycle apparatus according to the present invention, and the air conditioner includes an outdoor unit 2 and an indoor unit 4 that are connected to each other through a refrigerant pipe.
- a compressor 6, a four-way valve 8, a strainer 10, an expansion valve 12, and an outdoor heat exchanger 14 are provided inside the outdoor unit 2.
- a heat exchanger 16 is provided, and these are connected to each other via a refrigerant pipe to constitute a refrigeration cycle.
- the compressor 6 and the indoor heat exchanger 16 are connected via a first pipe 18 provided with a four-way valve 8, and the indoor heat exchanger 16 and the expansion valve 12 are provided with a strainer 10.
- the second pipe 20 is connected.
- the expansion valve 12 and the outdoor heat exchanger 14 are connected via a third pipe 22, and the outdoor heat exchanger 14 and the compressor 6 are connected via a fourth pipe 24.
- the four-way valve 8 is disposed in the middle of the fourth pipe 24, and an accumulator 26 for separating the liquid-phase refrigerant and the gas-phase refrigerant is provided in the fourth pipe 24 on the refrigerant suction side of the compressor 6. ing.
- the compressor 6 and the third pipe 22 are connected via a fifth pipe 28, and the first solenoid valve 30 is provided in the fifth pipe 28.
- a heat storage tank 32 is provided around the compressor 6, and a heat storage heat exchanger 34 is provided inside the heat storage tank 32, and a heat storage material for exchanging heat with the heat storage heat exchanger 34 (for example, An ethylene glycol aqueous solution) 36 is filled, and the heat storage tank 32, the heat storage heat exchanger 34, and the heat storage material 36 constitute a heat storage device.
- a heat storage material for exchanging heat with the heat storage heat exchanger 34 for example, An ethylene glycol aqueous solution
- the second pipe 20 and the heat storage heat exchanger 34 are connected via a sixth pipe 38, the heat storage heat exchanger 34 and the fourth pipe 24 are connected via a seventh pipe 40, and the sixth pipe 38. Is provided with a second electromagnetic valve 42.
- an air blower fan (not shown), upper and lower blades (not shown), and left and right blades (not shown) are provided inside the indoor unit 4, and indoor heat exchange is performed.
- the unit 16 exchanges heat between the indoor air sucked into the interior of the indoor unit 4 by the blower fan and the refrigerant flowing through the interior of the indoor heat exchanger 16, and blows out the air heated by heat exchange into the room during heating.
- air cooled by heat exchange is blown into the room during cooling.
- the upper and lower blades change the direction of air blown from the indoor unit 4 up and down as necessary, and the left and right blades change the direction of air blown from the indoor unit 4 to right and left as needed.
- the compressor 6, the blower fan, the upper and lower blades, the left and right blades, the four-way valve 8, the expansion valve 12, the electromagnetic valves 30 and 42, etc. are electrically connected to a controller 48 (see FIG. 4, for example, a microcomputer).
- the operation or operation of the blower fan, the upper and lower blades, the left and right blades, the four-way valve 8 and the expansion valve 12 is controlled based on a control signal from the controller 48, and the two solenoid valves 30 and 42 are controlled by the controller 48. Opened and closed based on the signal.
- the refrigerant discharged from the discharge port of the compressor 6 passes from the four-way valve 8 to the indoor heat exchanger 16 through the first pipe 18.
- the refrigerant condensed by exchanging heat with the indoor air in the indoor heat exchanger 16 passes through the second pipe 20 through the indoor heat exchanger 16, expands through the strainer 10 that prevents foreign matter from entering the expansion valve 12.
- To valve 12. The refrigerant decompressed by the expansion valve 12 reaches the outdoor heat exchanger 14 through the third pipe 22, and the refrigerant evaporated by exchanging heat with the outdoor air in the outdoor heat exchanger 14 is the fourth pipe 24 and the four-way valve 8. And returns to the suction port of the compressor 6 through the accumulator 26.
- the fifth pipe 28 branched from the compressor 6 discharge port of the first pipe 18 and the four-way valve 8 is connected to the expansion valve 12 of the third pipe 22 and the outdoor heat exchanger 14 via the first electromagnetic valve 30. I am joining in between.
- the heat storage tank 32 in which the heat storage material 36 and the heat storage heat exchanger 34 are housed is disposed so as to be in contact with and surround the compressor 6, and the heat generated in the compressor 6 is accumulated in the heat storage material 36, and the second The sixth pipe 38 branched from the pipe 20 between the indoor heat exchanger 16 and the strainer 10 reaches the inlet of the heat storage heat exchanger 34 via the second electromagnetic valve 42 and exits from the outlet of the heat storage heat exchanger 34.
- the seventh pipe 40 joins between the four-way valve 8 and the accumulator 26 in the fourth pipe 24.
- FIG. 2 schematically showing the operation during normal heating and the flow of the refrigerant of the air conditioner shown in FIG.
- the first solenoid valve 30 and the second solenoid valve 42 are closed, and the refrigerant discharged from the discharge port of the compressor 6 as described above passes through the first pipe 18 and the four-way valve 8. It reaches the indoor heat exchanger 16.
- the refrigerant evaporated by exchanging heat with outdoor air in the outdoor heat exchanger 14 returns from the four-way valve 8 to the suction port of the compressor 6 through the fourth pipe 24.
- the heat generated in the compressor 6 is accumulated in the heat storage material 36 housed in the heat storage tank 32 from the outer wall of the compressor 6 through the outer wall of the heat storage tank 32.
- FIG. 3 schematically showing the operation of the air conditioner shown in FIG. 1 during defrosting / heating and the flow of refrigerant.
- the solid line arrows indicate the flow of the refrigerant used for heating
- the broken line arrows indicate the flow of the refrigerant used for defrosting.
- the air conditioner that is a refrigeration cycle apparatus according to the present invention is provided with a pipe temperature sensor 44 that detects the pipe temperature of the outdoor heat exchanger 14.
- the controller 48 outputs an instruction from the normal heating operation to the defrosting / heating operation.
- the first electromagnetic valve 30 and the second electromagnetic valve 42 are controlled to open, and in addition to the refrigerant flow during the normal heating operation described above, the first solenoid valve 30 and the second electromagnetic valve 42 are discharged from the discharge port of the compressor 6. After a part of the vapor-phase refrigerant passes through the fifth pipe 28 and the first electromagnetic valve 30 and merges with the refrigerant passing through the third pipe 22, the outdoor heat exchanger 14 is heated, condensed, and converted into a liquid phase. Through the fourth pipe 24, the four-way valve 8 and the accumulator 26 are returned to the suction port of the compressor 6.
- a part of the liquid-phase refrigerant that is divided between the indoor heat exchanger 16 and the strainer 10 in the second pipe 20 passes through the sixth pipe 38 and the second electromagnetic valve 42, and then is stored in the heat storage material 36 in the heat storage heat exchanger 34. From the accumulator 26 and returns to the suction port of the compressor 6 through the seventh pipe 40 and the refrigerant that passes through the fourth pipe 24.
- the refrigerant returning to the accumulator 26 includes the liquid phase refrigerant returning from the outdoor heat exchanger 14. By mixing this with the high-temperature gas phase refrigerant returning from the heat storage heat exchanger 34, The evaporation of the phase refrigerant is promoted, and the liquid phase refrigerant does not return to the compressor 6 through the accumulator 26, so that the reliability of the compressor 6 can be improved.
- the temperature of the outdoor heat exchanger 14 that has become below freezing due to the attachment of frost at the start of defrosting and heating is heated by the gas-phase refrigerant discharged from the discharge port of the compressor 6, and the frost is melted near zero, When melting is finished, the temperature of the outdoor heat exchanger 14 begins to rise again. When the temperature rise of the outdoor heat exchanger 14 is detected by the pipe temperature sensor 44, it is determined that the defrosting is completed, and the controller 48 outputs an instruction from the defrosting / heating operation to the normal heating operation.
- the heat storage material 36 itself may be altered (for example, oxidation) or water boiling of the heat storage material 36 may occur, and the heat storage material 36 may be deteriorated. Is preventing the deterioration of the heat storage material 36 by the controller 48 performing switching control between the first heating operation and the second heating operation described below.
- the first heating operation is the normal heating operation shown in FIG. 2. Since the first electromagnetic valve 30 and the second electromagnetic valve 42 are closed during the normal heating operation, the compressor 6 The refrigerant discharged from the refrigerant passes through the indoor heat exchanger 16, the expansion valve 12, and the outdoor heat exchanger 14 and returns to the compressor 6. At this time, since the second electromagnetic valve 42 is closed, the refrigerant does not flow through the heat storage heat exchanger 34, and the temperature of the heat storage material 36 accommodated in the heat storage tank 32 depends on the heat generated in the compressor 6. Rise gradually.
- the second heating operation is the heating operation shown in FIG. 4.
- the first electromagnetic valve 30 is closed, while the second electromagnetic valve 42 is opened. Therefore, the refrigerant discharged from the compressor 6 passes through the indoor heat exchanger 16 and the heat storage heat exchanger 34 and returns to the compressor 6. At this time, the refrigerant flowing through the heat storage heat exchanger 34 is subjected to heat exchange in the indoor heat exchanger 16 for heating and its temperature is lowered, so that the heat accumulated in the heat storage material 36 is recovered. The temperature of the heat storage material 36 accommodated in the heat storage tank 32 gradually decreases.
- the heat storage material temperature sensor 46 for detecting the temperature of the heat storage material 36 is provided, and the second electromagnetic valve 42 is controlled by the controller 48 based on the detected temperature of the heat storage material temperature sensor 46 to perform the first heating operation.
- the second heating operation is appropriately selected. Specifically, while the temperature detected by the heat storage material temperature sensor 46 is a predetermined temperature (for example, 90 ° C.) or less, the first heating operation is performed to store heat in the heat storage material 36, while the temperature detected by the heat storage material temperature sensor 46. When the temperature exceeds the predetermined temperature, the first heating operation is switched to the second heating operation, thereby reducing the temperature of the heat storage material 36.
- the predetermined temperature is set to 90 ° C., which is a temperature selected in consideration of the boiling point of the moisture of the heat storage material 36.
- the compressor 6, the indoor heat exchanger 16, the expansion valve 12, and the outdoor heat exchanger 14 are used during the first heating operation, and during this time, the heat storage of the heat storage device is performed.
- the material 36 accumulates heat generated by the compressor 6.
- the controller 48 switches to the second heating operation using the heat storage heat exchanger 34, and the heat storage heat exchanger 34 passes through the inside during the second heating operation.
- the temperature of the heat storage material 36 is lowered.
- Such control by the controller 48 can prevent the heat storage material 36 from becoming excessively high in temperature, and can further prevent moisture evaporation. Thereby, deterioration of the heat storage material 36 can be prevented.
- FIG. 5 shows a modification of the switching control described above.
- the controller 48 shifts to the second heating operation. Reduces the operating frequency of the compressor 6 and gives a control signal to first open the second electromagnetic valve 42 for a first predetermined time (about 1 second). Furthermore, after the first predetermined time has elapsed, the controller 48 provides a control signal to close the second electromagnetic valve 42 for a second predetermined time (about 20 seconds).
- the second electromagnetic valve 42 is opened and closed for 10 cycles, for example.
- the second heating operation is performed during these 10 cycles.
- how many cycles the opening and closing of the second electromagnetic valve 42 is repeated is appropriately selected.
- the first and second predetermined times mainly depend on the size of the second electromagnetic valve 42, it is usually preferable that the second predetermined time is longer than the first predetermined time, for example, the first predetermined time. Is set to 1 second, and the second predetermined time is set to 20 seconds. In this case, assuming that the second heating operation and the first heating operation are repeated 10 cycles, the switching control to the first heating operation is performed after the second heating operation and the first heating operation are switched for 210 seconds. Is done. In this case, the controller 48 counts the number of ON times in the control signal, and switches to the first heating operation when the number of ON times becomes 10.
- the controller 48 has a built-in timer 481 that counts time, and may switch to the first heating operation after counting 210 seconds after switching to the second heating operation. .
- the first heating operation may be switched to the continuous operation.
- the temperature detected by the heat storage material temperature sensor 46 for opening and closing the second electromagnetic valve 42 is set to different temperatures when the temperature of the heat storage material 36 rises and falls. Frequent repetition of opening and closing of the second electromagnetic valve 42 can be prevented.
- a first predetermined temperature for example, 90 ° C.
- a second predetermined temperature for example, 85 ° C.
- the temperature of the heat storage material 36 is the first temperature. If the temperature of the heat storage material 36 exceeds the first predetermined temperature, the second electromagnetic valve 42 is controlled to open while the temperature of the heat storage material 36 is maintained. When the temperature falls below the second predetermined temperature, the second electromagnetic valve 42 is controlled to be closed.
- a compressor temperature sensor for detecting the temperature of the compressor 6 or the compressor 6 discharged from the compressor 6.
- a discharge refrigerant temperature sensor that detects the temperature of the refrigerant, a heat storage tank temperature sensor that detects the temperature of the heat storage tank 32 itself, an operating current sensor that detects the operating current of the compressor 6, and the like can also be used.
- -Compressor temperature sensor The temperature of the compressor 6 closely correlates with the temperature of the heat storage material 36. If the temperature of the compressor 6 increases, the temperature of the heat storage material 36 also increases.
- coolant temperature sensor The temperature of the refrigerant
- -Thermal storage tank temperature sensor The temperature of the thermal storage tank 32 is also basically correlated with the temperature of the thermal storage material 36, and if the temperature of the thermal storage tank 32 increases, the temperature of the thermal storage material 36 also increases.
- -Operating current sensor If the operating current of the compressor 6 increases, the temperature of the heat storage material 36 also increases.
- the first heating operation is performed to store the heat. While heat is stored in the material 36, when the detected current of the operating current sensor exceeds a predetermined current, the heat storage material 36 is cooled by switching from the first heating operation to the second heating operation.
- the second electromagnetic valve 42 is controlled to open. Then, the second heating operation is started, the second heating operation is continued for a first predetermined time, and after the first predetermined time has elapsed, the second electromagnetic valve 42 is controlled to be closed and the second heating operation is started.
- the operation proceeds to the first heating operation (however, the operation frequency of the compressor 6 is maintained in a reduced state), the first heating operation is continued for a second predetermined time, and this is repeated a predetermined number of times (for example, 10 cycles). You may do it.
- the switching control between the first heating operation and the second heating operation is performed based on the detection results of various sensors.
- the switching control from the second heating operation to the first heating operation may be based on the time measurement result by the timer 481.
- Switching by the timer 481 timing result may be based on the following concept.
- the time from when the temperature of the heat storage material 36 becomes equal to or higher than a predetermined temperature until it falls below the predetermined temperature can be estimated to some extent.
- the accuracy is not critical.
- the composition and amount of the heat storage material 36 do not change, the time for the heat storage material 36 to reach a predetermined temperature after operation of the compressor 6 and the time until the heat storage material 36 reliably reaches the predetermined temperature after reaching the predetermined temperature. Is obtained in advance through experiments or the like.
- the controller 48 can set this calculated
- the first predetermined temperature for example, 90 ° C.
- the second predetermined temperature for example, 85 ° C.
- the refrigeration cycle apparatus can prevent deterioration of a heat storage material that accumulates heat generated by a compressor, it is useful for an air conditioner, a refrigerator, a water heater, a heat pump washing machine, and the like.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
Abstract
Description
図1は、本発明に係る冷凍サイクル装置である空気調和機の構成を示しており、空気調和機は、冷媒配管で互いに接続された室外機2と室内機4とで構成されている。 Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 shows a configuration of an air conditioner that is a refrigeration cycle apparatus according to the present invention, and the air conditioner includes an
ここで、図2に示される通常暖房運転に注目すると、除霜運転を行わない通常の暖房運転の場合、二つの電磁弁30,42は閉じられた状態で圧縮機6は運転され、圧縮機6で発生した熱は蓄熱材36に蓄積されるので、その温度は徐々に上昇する。 <Switching control between first heating operation and second heating operation>
Here, paying attention to the normal heating operation shown in FIG. 2, in the normal heating operation without the defrosting operation, the
図5は上述した切替制御の変形例を示しており、蓄熱材温度センサ46の検出温度が所定温度以下の場合、前述同様の第1の暖房運転を行う一方、蓄熱材温度センサ46の検出温度が所定温度を超えると、第2電磁弁42の開閉を伴う第2の暖房運転を行うようにしている。 <Modification of switching control>
FIG. 5 shows a modification of the switching control described above. When the temperature detected by the heat storage
・圧縮機温度センサ: 圧縮機6の温度は蓄熱材36の温度と密接に相関し、圧縮機6の温度が高くなれば、蓄熱材36の温度も高くなる。
・吐出冷媒温度センサ: 圧縮機6から吐出された冷媒の温度は蓄熱材36の温度と密接に相関し、吐出冷媒の温度が高くなれば、蓄熱材36の温度も高くなる。
・蓄熱槽温度センサ: 蓄熱槽32の温度も基本的には蓄熱材36の温度と相関し、蓄熱槽32の温度が高くなれば、蓄熱材36の温度も高くなる。
・運転電流センサ: 圧縮機6の運転電流が大きくなれば、蓄熱材36の温度も高くなる。 This is due to the following reason.
-Compressor temperature sensor: The temperature of the
-Discharge refrigerant | coolant temperature sensor: The temperature of the refrigerant | coolant discharged from the
-Thermal storage tank temperature sensor: The temperature of the
-Operating current sensor: If the operating current of the
10 ストレーナ、 12 膨張弁、 14 室外熱交換器、
16 室内熱交換器、 18 第1配管、 20 第2配管、
22 第3配管、 24 第4配管、 26 アキュームレータ、
28 第5配管、 30 第1電磁弁、 32 蓄熱槽、
34 蓄熱熱交換器、 36 蓄熱材、 38 第6配管、
40 第7配管、 42 第2電磁弁、 44 配管温度センサ、
46 蓄熱材温度センサ、 48 コントローラ、 481 タイマー。 2 outdoor units, 4 indoor units, 6 compressors, 8 four-way valves,
10 strainer, 12 expansion valve, 14 outdoor heat exchanger,
16 indoor heat exchanger, 18 first piping, 20 second piping,
22 3rd piping, 24 4th piping, 26 accumulator,
28 5th piping, 30 1st solenoid valve, 32 heat storage tank,
34 heat storage heat exchanger, 36 heat storage material, 38 sixth pipe,
40 seventh piping, 42 second solenoid valve, 44 piping temperature sensor,
46 thermal storage material temperature sensor, 48 controller, 481 timer.
Claims (13)
- 冷媒配管を介して接続された圧縮機、室内熱交換器、膨張弁及び室外熱交換器と、前記圧縮機で発生した熱を蓄積する蓄熱材を収容する蓄熱槽及び前記蓄熱材の蓄熱で熱交換を行う蓄熱熱交換器を有する蓄熱装置とを備える冷凍サイクル装置であって、
前記蓄熱材の温度が所定温度以下の場合に前記圧縮機から吐出された冷媒を前記室内熱交換器と前記膨張弁と前記室外熱交換器とを通過させる第1の暖房運転から、前記蓄熱材の温度が前記所定温度を超えた場合に前記圧縮機から吐出された冷媒を前記室内熱交換器と前記蓄熱熱交換器を通過させる第2の暖房運転へと切り替えるコントローラとをさらに備えることを特徴とする冷凍サイクル装置。 Compressor, indoor heat exchanger, expansion valve and outdoor heat exchanger connected via refrigerant piping, heat storage tank for storing heat storage material for storing heat generated by the compressor, and heat storage by heat storage of the heat storage material A refrigeration cycle apparatus comprising a heat storage device having a heat storage heat exchanger for performing exchange,
From the first heating operation in which the refrigerant discharged from the compressor passes through the indoor heat exchanger, the expansion valve, and the outdoor heat exchanger when the temperature of the heat storage material is equal to or lower than a predetermined temperature, the heat storage material And a controller that switches the refrigerant discharged from the compressor to a second heating operation that passes the indoor heat exchanger and the heat storage heat exchanger when the temperature of the refrigerant exceeds the predetermined temperature. Refrigeration cycle equipment. - 前記室内熱交換器と前記膨張弁とを接続する冷媒配管から分岐して前記蓄熱熱交換器に至る冷媒配管に、前記コントローラからの制御信号に基づいて開閉される電磁弁をさらに備え、
前記コントローラは、前記電磁弁を開くことにより前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 A refrigerant pipe branched from a refrigerant pipe connecting the indoor heat exchanger and the expansion valve to the heat storage heat exchanger is further provided with an electromagnetic valve that is opened and closed based on a control signal from the controller,
The refrigeration cycle apparatus according to claim 1, wherein the controller switches from the first heating operation to the second heating operation by opening the electromagnetic valve. - 前記コントローラは、前記第2の暖房運転において、前記電磁弁を第1の所定時間だけ開いた状態にし、その後前記電磁弁を第2の所定時間だけ閉じた状態にするよう前記電磁弁を開閉制御することを特徴とする請求項2に記載の冷凍サイクル装置。 In the second heating operation, the controller controls the opening and closing of the solenoid valve so that the solenoid valve is opened for a first predetermined time, and then the solenoid valve is closed for a second predetermined time. The refrigeration cycle apparatus according to claim 2, wherein:
- 前記第2の所定時間は、前記第1の所定時間よりも長いことを特徴とする請求項3に記載の冷凍サイクル装置。 The refrigeration cycle apparatus according to claim 3, wherein the second predetermined time is longer than the first predetermined time.
- 前記電磁弁の前記第1の所定時間の開状態と前記第2の所定時間の閉状態を1周期として、前記電磁弁の開閉制御を所定周期繰り返すことを特徴とする請求項3に記載の冷凍サイクル装置。 The refrigeration according to claim 3, wherein opening and closing control of the electromagnetic valve is repeated for a predetermined period, with the open state of the electromagnetic valve for the first predetermined time and the closed state for the second predetermined time as one period. Cycle equipment.
- 前記蓄熱材の温度を検出する蓄熱材温度センサをさらに備え、前記コントローラは、前記蓄熱材温度センサが検出した温度に基づいて前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 It further includes a heat storage material temperature sensor that detects the temperature of the heat storage material, and the controller switches from the first heating operation to the second heating operation based on the temperature detected by the heat storage material temperature sensor. The refrigeration cycle apparatus according to claim 1, wherein:
- 前記圧縮機の温度を検出する圧縮機温度センサをさらに備え、前記コントローラは、前記圧縮機温度センサが検出した温度に基づいて前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 A compressor temperature sensor for detecting the temperature of the compressor; and the controller switches from the first heating operation to the second heating operation based on the temperature detected by the compressor temperature sensor. The refrigeration cycle apparatus according to claim 1, wherein:
- 前記圧縮機から吐出された冷媒の温度を検出する吐出冷媒温度センサをさらに備え、前記コントローラは、前記吐出冷媒温度センサが検出した温度に基づいて前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 The apparatus further includes a discharge refrigerant temperature sensor that detects a temperature of the refrigerant discharged from the compressor, and the controller performs the second heating operation from the first heating operation based on the temperature detected by the discharge refrigerant temperature sensor. The refrigeration cycle apparatus according to claim 1, wherein the refrigeration cycle apparatus is switched to.
- 前記蓄熱槽自体の温度を検出する蓄熱槽温度センサをさらに備え、前記コントローラは、前記蓄熱槽温度センサが検出した温度に基づいて前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 A heat storage tank temperature sensor for detecting the temperature of the heat storage tank itself is further provided, and the controller switches from the first heating operation to the second heating operation based on the temperature detected by the heat storage tank temperature sensor. The refrigeration cycle apparatus according to claim 1.
- 前記圧縮機の運転電流を検出する運転電流センサをさらに備え、前記コントローラは、前記運転電流センサが検出した前記圧縮機の運転電流に基づいて前記第1の暖房運転から前記第2の暖房運転へと切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 An operation current sensor for detecting an operation current of the compressor is further provided, and the controller changes from the first heating operation to the second heating operation based on the operation current of the compressor detected by the operation current sensor. The refrigeration cycle apparatus according to claim 1, wherein the refrigeration cycle apparatus is switched.
- 前記第2の暖房運転中、前記圧縮機の運転周波数は、前記第1の暖房運転中と比較して下げられることを特徴とする請求項1に記載の冷凍サイクル装置。 2. The refrigeration cycle apparatus according to claim 1, wherein an operating frequency of the compressor is lowered during the second heating operation as compared with that during the first heating operation.
- 前記所定温度を第1の所定温度とする場合において、前記コントローラは、前記第2の暖房運転中に前記蓄熱材の温度が前記第1の所定温度よりも低い第2の所定温度を下回ると、前記第1の暖房運転に切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 In the case where the predetermined temperature is set as the first predetermined temperature, the controller, when the temperature of the heat storage material falls below a second predetermined temperature lower than the first predetermined temperature during the second heating operation, The refrigeration cycle apparatus according to claim 1, wherein the refrigeration cycle apparatus is switched to the first heating operation.
- 前記第2の暖房運転に切り替わってからの経過時間を少なくとも計時可能なタイマーをさらに備え、前記コントローラは、前記第2の暖房運転中、前記タイマーにより計時される経過時間が予め定められた時間になると、前記第1の暖房運転に切り替えることを特徴とする請求項1に記載の冷凍サイクル装置。 A timer capable of timing at least an elapsed time since switching to the second heating operation; and the controller sets an elapsed time measured by the timer during the second heating operation to a predetermined time. Then, the refrigeration cycle apparatus according to claim 1, wherein the refrigeration cycle apparatus is switched to the first heating operation.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020127022754A KR20130027460A (en) | 2010-03-01 | 2010-03-01 | Refrigeration cycle device |
PCT/JP2010/001359 WO2011108019A1 (en) | 2010-03-01 | 2010-03-01 | Refrigeration cycle device |
CN201080065064.XA CN102782423B (en) | 2010-03-01 | 2010-03-01 | Refrigeration cycle device |
BR112012021194A BR112012021194A2 (en) | 2010-03-01 | 2010-03-01 | refrigeration cycle equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2010/001359 WO2011108019A1 (en) | 2010-03-01 | 2010-03-01 | Refrigeration cycle device |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011108019A1 true WO2011108019A1 (en) | 2011-09-09 |
Family
ID=44541712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2010/001359 WO2011108019A1 (en) | 2010-03-01 | 2010-03-01 | Refrigeration cycle device |
Country Status (4)
Country | Link |
---|---|
KR (1) | KR20130027460A (en) |
CN (1) | CN102782423B (en) |
BR (1) | BR112012021194A2 (en) |
WO (1) | WO2011108019A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105102249B (en) * | 2013-03-29 | 2017-02-15 | 日本空调系统股份有限公司 | Vehicle air conditioner |
JP2015001326A (en) * | 2013-06-14 | 2015-01-05 | パナソニックIpマネジメント株式会社 | Hot-water generation device |
EP3169950A4 (en) * | 2014-07-17 | 2018-07-11 | Electrolux (Hangzhou) Home Appliances CO., LTD. | Heat pump system |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6219652A (en) * | 1985-07-19 | 1987-01-28 | 株式会社東芝 | Heat pump |
JPS6321449A (en) * | 1986-07-11 | 1988-01-29 | 株式会社東芝 | Refrigeration cycle |
JPS63143473A (en) * | 1986-12-08 | 1988-06-15 | 松下電器産業株式会社 | Defrostation controller for heat pump type air conditioner |
JPS63148063A (en) * | 1986-12-08 | 1988-06-20 | 松下電器産業株式会社 | Defrostation controller for heat pump type air conditioner |
JPS63156980A (en) * | 1986-12-19 | 1988-06-30 | 松下電器産業株式会社 | Heat pump type air conditioner |
JPH02251052A (en) * | 1989-03-22 | 1990-10-08 | Daikin Ind Ltd | Compressor for refrigerator |
JP2004020097A (en) * | 2002-06-18 | 2004-01-22 | Fuji Electric Holdings Co Ltd | Heat storage system integrating refrigeration with air-conditioning |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2526716B2 (en) * | 1990-06-19 | 1996-08-21 | ダイキン工業株式会社 | Air conditioner |
JP3010934B2 (en) * | 1992-08-28 | 2000-02-21 | ダイキン工業株式会社 | Air conditioner |
-
2010
- 2010-03-01 BR BR112012021194A patent/BR112012021194A2/en not_active Application Discontinuation
- 2010-03-01 WO PCT/JP2010/001359 patent/WO2011108019A1/en active Application Filing
- 2010-03-01 CN CN201080065064.XA patent/CN102782423B/en not_active Expired - Fee Related
- 2010-03-01 KR KR1020127022754A patent/KR20130027460A/en active IP Right Grant
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6219652A (en) * | 1985-07-19 | 1987-01-28 | 株式会社東芝 | Heat pump |
JPS6321449A (en) * | 1986-07-11 | 1988-01-29 | 株式会社東芝 | Refrigeration cycle |
JPS63143473A (en) * | 1986-12-08 | 1988-06-15 | 松下電器産業株式会社 | Defrostation controller for heat pump type air conditioner |
JPS63148063A (en) * | 1986-12-08 | 1988-06-20 | 松下電器産業株式会社 | Defrostation controller for heat pump type air conditioner |
JPS63156980A (en) * | 1986-12-19 | 1988-06-30 | 松下電器産業株式会社 | Heat pump type air conditioner |
JPH02251052A (en) * | 1989-03-22 | 1990-10-08 | Daikin Ind Ltd | Compressor for refrigerator |
JP2004020097A (en) * | 2002-06-18 | 2004-01-22 | Fuji Electric Holdings Co Ltd | Heat storage system integrating refrigeration with air-conditioning |
Also Published As
Publication number | Publication date |
---|---|
BR112012021194A2 (en) | 2016-05-17 |
KR20130027460A (en) | 2013-03-15 |
CN102782423A (en) | 2012-11-14 |
CN102782423B (en) | 2015-03-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5204189B2 (en) | Refrigeration cycle equipment | |
JP5238001B2 (en) | Refrigeration cycle equipment | |
JP5265010B2 (en) | Heat pump equipment | |
JP5108923B2 (en) | Air conditioner | |
JP5615561B2 (en) | Refrigeration cycle equipment | |
JP2012057869A (en) | Air conditioner | |
JP5144728B2 (en) | Air conditioner | |
JP5210364B2 (en) | Air conditioner | |
WO2012042692A1 (en) | Refrigeration cycle device | |
JP2013104623A (en) | Refrigeration cycle device and air conditioner with the same | |
WO2013065233A1 (en) | Refrigeration cycle apparatus and air conditioner provided with same | |
JP4666111B1 (en) | Refrigeration cycle equipment | |
WO2011108019A1 (en) | Refrigeration cycle device | |
JP5440466B2 (en) | Air conditioner | |
JP5287820B2 (en) | Air conditioner | |
JP5287821B2 (en) | Air conditioner | |
JP5927500B2 (en) | Refrigeration cycle apparatus and air conditioner equipped with the same | |
JP2012037130A (en) | Refrigeration cycle device | |
JP5927502B2 (en) | Refrigeration cycle apparatus and air conditioner equipped with the same | |
JP6031673B2 (en) | Refrigeration cycle apparatus and air conditioner equipped with the same | |
JP5310696B2 (en) | Air conditioner | |
JP2012077938A (en) | Refrigerating cycle device | |
JP5307096B2 (en) | Air conditioner | |
JP2013104586A (en) | Refrigerating cycle device and air conditioner with the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201080065064.X Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10846931 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 20127022754 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 7500/CHENP/2012 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1201004452 Country of ref document: TH |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 10846931 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112012021194 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112012021194 Country of ref document: BR Kind code of ref document: A2 Effective date: 20120823 |