WO2011095540A3 - Mousses polymères ignifugées contenant du phosphore et exemptes d'halogène - Google Patents

Mousses polymères ignifugées contenant du phosphore et exemptes d'halogène Download PDF

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Publication number
WO2011095540A3
WO2011095540A3 PCT/EP2011/051550 EP2011051550W WO2011095540A3 WO 2011095540 A3 WO2011095540 A3 WO 2011095540A3 EP 2011051550 W EP2011051550 W EP 2011051550W WO 2011095540 A3 WO2011095540 A3 WO 2011095540A3
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WO
WIPO (PCT)
Prior art keywords
aryl
alkyl
alkoxy
identically
cycloalkyl
Prior art date
Application number
PCT/EP2011/051550
Other languages
German (de)
English (en)
Other versions
WO2011095540A2 (fr
Inventor
Klaus Hahn
Olaf Kriha
Ingo Bellin
Patrick Spies
Sabine Fuchs
Peter Deglmann
Klemens Massonne
Hartmut Denecke
Christoph Fleckenstein
Geert Janssens
Maximilian Hofmann
Manfred DÖRING
Ciesielski Michael
Jochen Wagner
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN2011800083795A priority Critical patent/CN102741332A/zh
Priority to EP11703640A priority patent/EP2531552A2/fr
Priority to JP2012551617A priority patent/JP2013518956A/ja
Priority to RU2012137856/05A priority patent/RU2012137856A/ru
Priority to KR1020127020471A priority patent/KR20120120282A/ko
Priority to MX2012008974A priority patent/MX2012008974A/es
Publication of WO2011095540A2 publication Critical patent/WO2011095540A2/fr
Publication of WO2011095540A3 publication Critical patent/WO2011095540A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0038—Use of organic additives containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/5398—Phosphorus bound to sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

La présente invention concerne une mousse polymère présentant une densité située entre 5 et 120 kg/m3, contenant a) un composant polymère qui comporte au moins un polymère styrène, b) 0,1 à 5 parties en poids (par rapport aux 100 parties en poids du composant a)) d'un mélange d'agent ignifugeant qui comprend b1) au moins un composé phosphore de formule (I) avec une teneur en phosphore située entre 5 et 80% en poids par rapport au composé phosphore, (X1)s =PR1R2R3 (I), les symboles et les indices dans la formule (I) ayant les significations suivantes : R1 représente alkyle C1-C16, hydroxyalkyle C1-C10, alcényle C2-C16, alcoxy C1-C16, alcénoxy C2-C16,cycloalkyle C3-C10, cycloalcoxy C3-C10, aryle C6-C10, aryloxy C6-C10, aryle C6-C10-alkyle C1-C16, aryle C6-C10-alcoxy C1-C16, SR9, COR10, COOR11, CONR12R13; R2 représente alkyle C1-C16, hydroxyalkyle C1-C10, alcényle C2-C16, alcoxy C1-C16, alcénoxy C2-C16,cycloalkyle C3-C10, cycloalcoxy C3-C10, aryle C6-C10, aryle C6-C10-alkyle C1-C16, aryle C6-C10-alcoxy C1-C16, SR9, COR10, COOR11, CONR12R13; R3 représente H, SH, SR4, OH, OR5 ou un groupe -(Y1)n-[P(= X2)uR6 -(Y2)n]m-P(= X3)tR7R8; ou deux groupes R1, R2, R3 forment ensemble un système cyclique avec l'atome de phosphore auquel ils sont liés; X1, X2 et X3 sont identiques ou différents et représentent indépendamment les uns des autres O ou S; Y1, Y2 sont identiques ou différents et représentent O ou S; R4, R5, R9, R10, R11, R12,R13 sont identiques ou différents et représentent alkyle C1-C12, cycloalkyle C3-C8, non substitué ou substitué par un ou plusieurs groupes alkyle C1-C4, alcényle C2-C12, alcynyle C2-C12, aryle C6-C10, aryle C6-C10-alkyle C1-C4; R6, R7, R8 sont identiques ou différents et représentent indépendamment les uns des autres alkyle C1-C16, alcényle C1-C16, alcoxy C1-C16, alcénoxy C1-C16,cycloalkyle C3-C10, cycloalcoxy C3-C10, aryle C6-C10, aryloxy C6-C10, aryle C6-C10-alkyle C1-C16,aryle C6-C10-alcoxy C1-C16, SR9, COR10, COOR11, CONR12R13; n vaut 1 si Y1 ou Y2 représente O, et 1, 2, 3, 4, 5, 6, 7 ou 8 si Y1 ou Y2 représente S; m est un entier de 0 à 100; s, t et u représentent indépendamment les uns des autres 0 ou 1; et b2) du soufre élémentaire.
PCT/EP2011/051550 2010-02-05 2011-02-03 Mousses polymères ignifugées contenant du phosphore et exemptes d'halogène WO2011095540A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2011800083795A CN102741332A (zh) 2010-02-05 2011-02-03 无卤含磷阻燃聚合物泡沫
EP11703640A EP2531552A2 (fr) 2010-02-05 2011-02-03 Mousses polymères ignifugées contenant du phosphore et exemptes d'halogène
JP2012551617A JP2013518956A (ja) 2010-02-05 2011-02-03 ハロゲンを有しない、リン含有の難燃性ポリマーフォーム
RU2012137856/05A RU2012137856A (ru) 2010-02-05 2011-02-03 Свободные от галогена фосфорсодержащие огнестойкие полимерные пены
KR1020127020471A KR20120120282A (ko) 2010-02-05 2011-02-03 할로겐-부재 인-함유 방염 중합체 발포체
MX2012008974A MX2012008974A (es) 2010-02-05 2011-02-03 Espumas polimericas retardadoras de llama que contienen fosoro, libres de halogeno.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10152842 2010-02-05
EP10152842.0 2010-02-05

Publications (2)

Publication Number Publication Date
WO2011095540A2 WO2011095540A2 (fr) 2011-08-11
WO2011095540A3 true WO2011095540A3 (fr) 2011-11-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/051550 WO2011095540A2 (fr) 2010-02-05 2011-02-03 Mousses polymères ignifugées contenant du phosphore et exemptes d'halogène

Country Status (7)

Country Link
EP (1) EP2531552A2 (fr)
JP (1) JP2013518956A (fr)
KR (1) KR20120120282A (fr)
CN (1) CN102741332A (fr)
MX (1) MX2012008974A (fr)
RU (1) RU2012137856A (fr)
WO (1) WO2011095540A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2733165A1 (fr) 2012-11-20 2014-05-21 Basf Se Procédé pour la préparation de mousses de polystyrène retardateurs de flamme et libre d'halogène
EP2733166A1 (fr) 2012-11-20 2014-05-21 Basf Se Procédé de fabrication de granulés de polymère de styrène expansibles et de mousses de polymère de styrène à teneur réduite en monomères résiduels
KR101539663B1 (ko) * 2014-11-10 2015-07-27 손민일 폐기물을 이용한 난연성 폴리스티렌계 발포 입자 및 그 제조방법
CN104804213A (zh) * 2015-05-08 2015-07-29 北京理工大学 原位无卤阻燃可发性聚苯乙烯的制备
DE102019135325A1 (de) 2019-12-19 2021-06-24 Hochschule Hamm-Lippstadt, Körperschaft des öffentlichen Rechts Flammgeschützte Copolymere und Formmassen
DE112021006475A5 (de) 2020-12-17 2023-12-07 Hochschule Hamm-Lippstadt, Körperschaft des öffentlichen Rechts Brandhindernde copolymere und formmassen

Citations (2)

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WO1999010429A1 (fr) * 1997-08-27 1999-03-04 Albemarle Corporation Compositions ignifugeantes pour polymeres styreniques
WO2011035357A1 (fr) * 2009-09-24 2011-03-31 Sunpor Kunststoff Ges.M.B.H. Polymères expansés à l'épreuve du feu

Family Cites Families (6)

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GB1107237A (en) 1966-11-29 1968-03-27 Shell Int Research Process for the manufacture of cellular structures of synthetic macromolecular substances with decreased inflammability
IT1134333B (it) 1980-11-19 1986-08-13 F F A Spa Sa Processo per stabilizzare mediante incapsulamento il fosforo rosso per impiego come ritardante di fiamma dei materiali polimerici e prodotto cosi' ottenuto
IT1200424B (it) 1985-03-19 1989-01-18 Saffa Spa Fosforo rosso stabilizzato per uso come ritardante di fiamma,particolarmente per composizioni a base di polimeri
CA2203306A1 (fr) 1996-05-06 1997-11-06 Albemarle Corporation Compositions ignifugeantes utilisees dans les polymeres styrenique
US7851558B2 (en) 2005-11-12 2010-12-14 Dow Global Technologies Inc. Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer and polymeric foams formed from such blends
CN101611085B (zh) * 2006-12-21 2012-08-08 陶氏环球技术公司 磷-硫fr添加剂及含有它的聚合物体系

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999010429A1 (fr) * 1997-08-27 1999-03-04 Albemarle Corporation Compositions ignifugeantes pour polymeres styreniques
WO2011035357A1 (fr) * 2009-09-24 2011-03-31 Sunpor Kunststoff Ges.M.B.H. Polymères expansés à l'épreuve du feu

Also Published As

Publication number Publication date
WO2011095540A2 (fr) 2011-08-11
KR20120120282A (ko) 2012-11-01
JP2013518956A (ja) 2013-05-23
CN102741332A (zh) 2012-10-17
MX2012008974A (es) 2012-08-23
RU2012137856A (ru) 2014-03-10
EP2531552A2 (fr) 2012-12-12

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