WO2011087877A3 - Réacteur à compression et procédé d'hydrotraitement - Google Patents

Réacteur à compression et procédé d'hydrotraitement Download PDF

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Publication number
WO2011087877A3
WO2011087877A3 PCT/US2010/062153 US2010062153W WO2011087877A3 WO 2011087877 A3 WO2011087877 A3 WO 2011087877A3 US 2010062153 W US2010062153 W US 2010062153W WO 2011087877 A3 WO2011087877 A3 WO 2011087877A3
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
hydrocarbon feedstock
hydroprocessing
temperature
pressure
Prior art date
Application number
PCT/US2010/062153
Other languages
English (en)
Other versions
WO2011087877A2 (fr
Inventor
Larry L. Iaccino
Original Assignee
Exxonmobil Chemical Patents Inc.,
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/689,154 external-priority patent/US8691079B2/en
Application filed by Exxonmobil Chemical Patents Inc., filed Critical Exxonmobil Chemical Patents Inc.,
Publication of WO2011087877A2 publication Critical patent/WO2011087877A2/fr
Publication of WO2011087877A3 publication Critical patent/WO2011087877A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/185—Stationary reactors having moving elements inside of the pulsating type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/40—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed subjected to vibrations or pulsations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00283—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B01J2208/00557—Flow controlling the residence time inside the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B01J2208/00566—Pulsated flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé d'hydrotraitement d'une matière première hydrocarbonée liquide, comprenant : (a) le mélange d'une matière première hydrocarbonée liquide, partiellement vaporisée et/ou vaporisée avec de l'hydrogène moléculaire ; (b) l'introduction dudit mélange dans un réacteur à compression ; (c) la compression dudit mélange à une pression, à une température et pendant un temps de séjour suffisants pour : i) craquer thermiquement au moins une partie des molécules d'hydrocarbures dans ladite matière première hydrocarbonée, et ii) mettre en réaction l'hydrogène en présence d'un catalyseur d'hydrogénation avec des parties instables des molécules craquées, formant ainsi un produit hydrotraité ; et (d) l'expansion dudit mélange pour réduire la pression et la température, réduisant ainsi les réactions indésirables ultérieures.
PCT/US2010/062153 2010-01-18 2010-12-27 Réacteur à compression et procédé d'hydrotraitement WO2011087877A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US12/689,154 US8691079B2 (en) 2010-01-18 2010-01-18 Compression reactor and process for hydroprocessing
US12/689,154 2010-01-18
EP10156019.1 2010-03-10
EP10156019 2010-03-10

Publications (2)

Publication Number Publication Date
WO2011087877A2 WO2011087877A2 (fr) 2011-07-21
WO2011087877A3 true WO2011087877A3 (fr) 2012-05-10

Family

ID=44304912

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/062153 WO2011087877A2 (fr) 2010-01-18 2010-12-27 Réacteur à compression et procédé d'hydrotraitement

Country Status (1)

Country Link
WO (1) WO2011087877A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9725657B2 (en) 2012-09-27 2017-08-08 Exxonmobil Chemical Patents Inc. Process for enhancing feed flexibility in feedstock for a steam cracker
US10329493B2 (en) 2014-06-18 2019-06-25 The Trustees Of The Stevens Institute Of Technology Reciprocating biomass conversion scheme
DE102019135741A1 (de) * 2019-12-23 2021-06-24 Andreas Döring Verfahren und Vorrichtung zur Speicherung von Energie
GB2602313A (en) * 2020-12-22 2022-06-29 Andreas Doering Method and apparatus for controlling a reactor

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1422038A (en) * 1919-06-17 1922-07-04 David T Day Treatment of hydrocarbon oils
US1586508A (en) * 1919-08-04 1926-05-25 Brutzkus Marcus Apparatus for chemical production and research
GB252787A (en) * 1925-03-05 1926-06-07 Markus Brutzkus Production of light oil, suitable for use as fuel for internal combustion engines, from liquid and solid organic bodies
DE2830824A1 (de) * 1978-07-13 1980-01-24 Linde Ag Verfahren zum spalten von kohlenwasserstoffen
US20040166055A1 (en) * 2003-02-24 2004-08-26 Stickney Michael J. Process for the conversion of feedstocks and apparatus for performing the same
US20090166255A1 (en) * 2008-01-02 2009-07-02 Halsey Richard B Olefin production utilizing whole crude oil/condensate feedstock with a partitioned vaporization unit

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2814551A (en) 1949-10-07 1957-11-26 Shell Dev Method and reciprocating compressionreactor for short period, high temperature and high pressure chemical reactions
US2814552A (en) 1950-01-13 1957-11-26 Shell Dev Reciprocating compression-reactor for short period, high temperature and high pressure chemical reactions
US4066530A (en) 1976-07-02 1978-01-03 Exxon Research & Engineering Co. Hydroconversion of heavy hydrocarbons
US4226742A (en) 1978-07-14 1980-10-07 Exxon Research & Engineering Co. Catalyst for the hydroconversion of heavy hydrocarbons
US4244839A (en) 1978-10-30 1981-01-13 Exxon Research & Engineering Co. High surface area catalysts
US4740489A (en) 1986-04-21 1988-04-26 Exxon Research And Engineering Company Method of preparing a hydroconversion sulfided molybdenum catalyst concentrate
US5039392A (en) 1990-06-04 1991-08-13 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1422038A (en) * 1919-06-17 1922-07-04 David T Day Treatment of hydrocarbon oils
US1586508A (en) * 1919-08-04 1926-05-25 Brutzkus Marcus Apparatus for chemical production and research
GB252787A (en) * 1925-03-05 1926-06-07 Markus Brutzkus Production of light oil, suitable for use as fuel for internal combustion engines, from liquid and solid organic bodies
DE2830824A1 (de) * 1978-07-13 1980-01-24 Linde Ag Verfahren zum spalten von kohlenwasserstoffen
US20040166055A1 (en) * 2003-02-24 2004-08-26 Stickney Michael J. Process for the conversion of feedstocks and apparatus for performing the same
US20090166255A1 (en) * 2008-01-02 2009-07-02 Halsey Richard B Olefin production utilizing whole crude oil/condensate feedstock with a partitioned vaporization unit

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Publication number Publication date
WO2011087877A2 (fr) 2011-07-21

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