WO2011085199A3 - Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials - Google Patents

Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials Download PDF

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Publication number
WO2011085199A3
WO2011085199A3 PCT/US2011/020517 US2011020517W WO2011085199A3 WO 2011085199 A3 WO2011085199 A3 WO 2011085199A3 US 2011020517 W US2011020517 W US 2011020517W WO 2011085199 A3 WO2011085199 A3 WO 2011085199A3
Authority
WO
WIPO (PCT)
Prior art keywords
silica
styrene butadiene
butadiene polymer
compatibilized silica
compatibilized
Prior art date
Application number
PCT/US2011/020517
Other languages
French (fr)
Other versions
WO2011085199A2 (en
Inventor
Lawrence Douglas Harris
Harold William Young
Deepak Rasiklal Parikh
Daniel Courtney Patton
Vernon Vincent Vanis
Robert Stephen Rikhoff
Gregory Neville Nelson
Original Assignee
Lion Copolymer, Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/984,295 external-priority patent/US8329810B2/en
Priority claimed from US12/984,280 external-priority patent/US8329794B2/en
Priority claimed from US12/984,267 external-priority patent/US20110166262A1/en
Priority to EP11732204.0A priority Critical patent/EP2521751A4/en
Priority to CN2011800119301A priority patent/CN102782035A/en
Priority to JP2012548150A priority patent/JP2013516540A/en
Application filed by Lion Copolymer, Llc filed Critical Lion Copolymer, Llc
Priority to CA2786602A priority patent/CA2786602A1/en
Priority to RU2012133281/05A priority patent/RU2012133281A/en
Priority to MX2012007953A priority patent/MX2012007953A/en
Priority to BR112012016722A priority patent/BR112012016722A2/en
Publication of WO2011085199A2 publication Critical patent/WO2011085199A2/en
Publication of WO2011085199A3 publication Critical patent/WO2011085199A3/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/205Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
    • C08J3/21Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
    • C08J3/215Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/06Copolymers with styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A process for forming a compatibilized silica and nitrile polymer blend in latex form is described herein. The process can include treating a silica with a coupling agent to form a compatibilized silica slurry. The process can include blending the compatibilized silica slurry into a styrene butadiene polymer latex and an acrylonitrile butadiene polymer latex. The process can include blending silica styrene butadiene polymer latex with silica acrylonitrile butadiene polymer latex. A polymer composition of a compatibilized silica in blends of acrylonitrile butadiene polymer and styrene butadiene polymer and a recycled elastomeric composition are described herein. The recycled elastomeric composition can also include a compatibilized silica with a coupling agent, a crumb rubber, a carbon black, a filler, and an extender oil. Articles comprising the recycled elastomeric composition are disclosed herein.
PCT/US2011/020517 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials WO2011085199A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BR112012016722A BR112012016722A2 (en) 2010-01-07 2011-01-07 "mixture of compatible silica and latex-shaped nitrile polymer formed by a process, mixture of acrylonitrile styrene butadiene terpolymer latex with compatibilized silica, latex mixture"
MX2012007953A MX2012007953A (en) 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials.
RU2012133281/05A RU2012133281A (en) 2010-01-07 2011-01-07 COMPOSITIONS CONTAINING COMPATIBILIZED SILICON DIOXIDE, NITRIL RUBBER, BUTADIENE-STYROL RUBBER, ELASTOMER COMPOUNDS AND / OR SECONDLY USED MATERIALS
CN2011800119301A CN102782035A (en) 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials
JP2012548150A JP2013516540A (en) 2010-01-07 2011-01-07 Composition comprising compatible silica, nitrile rubber, styrene butadiene rubber, elastomer compound, and / or recycled material
EP11732204.0A EP2521751A4 (en) 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials
CA2786602A CA2786602A1 (en) 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US29291010P 2010-01-07 2010-01-07
US29291710P 2010-01-07 2010-01-07
US29292310P 2010-01-07 2010-01-07
US61/292,917 2010-01-07
US61/292,923 2010-01-07
US61/292,910 2010-01-07
US12/984,295 US8329810B2 (en) 2010-01-07 2011-01-04 Elastomeric compounds containing recycled materials and silica
US12/984,267 US20110166262A1 (en) 2010-01-07 2011-01-04 Process for making compatibilized silica and nitrile polymer compositions
US12/984,280 2011-01-04
US12/984,280 US8329794B2 (en) 2010-01-07 2011-01-04 Compatibilized silica in nitrile rubber and blends of nitrile rubber and styrene butadiene rubber compositions
US12/984,295 2011-01-04
US12/984,267 2011-01-04

Publications (2)

Publication Number Publication Date
WO2011085199A2 WO2011085199A2 (en) 2011-07-14
WO2011085199A3 true WO2011085199A3 (en) 2012-01-19

Family

ID=44306167

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/020517 WO2011085199A2 (en) 2010-01-07 2011-01-07 Compositions with compatibilized silica, nitrile rubber, styrene butadiene rubber, elastomeric compounds, and/or recycled materials

Country Status (8)

Country Link
EP (1) EP2521751A4 (en)
KR (1) KR20120115355A (en)
CN (1) CN102782035A (en)
BR (1) BR112012016722A2 (en)
CA (1) CA2786602A1 (en)
MX (1) MX2012007953A (en)
RU (1) RU2012133281A (en)
WO (1) WO2011085199A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2495889C2 (en) * 2011-12-28 2013-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" Heat-resistant rubber mixture
BR112015019260B1 (en) * 2013-02-12 2021-12-28 Cooper Tire & Rubber Company FUNCTIONALIZED SILICA PRODUCT, ITS MANUFACTURING METHODS AND RUBBER FORMULATION
US10557024B2 (en) 2013-07-31 2020-02-11 Kimberly-Clark Worldwide, Inc. Sustainable injection molded articles
CN104650414B (en) * 2013-11-19 2016-09-07 中国石油天然气股份有限公司 A kind of preparation method of rice hull ash modified powder butadiene-acrylonitrile polymer
KR101389517B1 (en) * 2013-12-19 2014-04-25 주식회사 유한인터텍 Mat composition and method of manufacturing mat using the composition thereof
SG11201605111YA (en) * 2013-12-23 2016-07-28 Arlanxeo Singapore Pte Ltd Rubbers with tunable levels of metal containing anti-agglomerants
CN104910475A (en) * 2015-06-17 2015-09-16 周彩球 Regenerated rubber material
IT201600108121A1 (en) 2016-10-26 2018-04-26 Pirelli New reinforcing materials, elastomeric compositions and tires for vehicle wheels that include them
JP6785196B2 (en) * 2017-06-16 2020-11-18 株式会社ブリヂストン Resin metal composite members for tires and tires
CN107502010A (en) * 2017-09-30 2017-12-22 浙江瀚镪自动化设备股份有限公司 A kind of manipulator face coat
CN107502009B (en) * 2017-09-30 2019-06-25 浙江瀚镪自动化设备股份有限公司 A kind of preparation method of manipulator surface covering
CN107502008A (en) * 2017-09-30 2017-12-22 浙江瀚镪自动化设备股份有限公司 A kind of preparation method of belt conveyor belt covercoat paste
FR3085167B1 (en) * 2018-08-23 2020-07-31 Michelin & Cie PNEUMATICS PROVIDED WITH A COMPOSITION CONSISTING OF AN ELASTOMER RICH IN ETHYLENE, A PEROXIDE AND A SPECIFIC ACRYLATE DERIVATIVE
CN109206679A (en) * 2018-08-24 2019-01-15 中国工程物理研究院材料研究所 It is a kind of that high-density packing is realized to uniform highly filled method in latex
CN113174111B (en) * 2021-05-26 2022-09-02 广州华邦电器工业有限公司 Modified ABS resin with good heat resistance and flame retardance and preparation method thereof
CN115304835A (en) * 2022-07-21 2022-11-08 太仓精艺弹簧有限公司 Anti-aging sealing ring for heat exchange pipeline of compressor
CN115850714B (en) * 2022-12-13 2024-03-22 东华大学 POSS modified nitrile rubber compound and preparation method and application thereof

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US5985953A (en) * 1996-12-18 1999-11-16 Dsm Copolymer, Inc. Compatibilized silica and polymer silica-reinforced masterbatch containing same
US6579929B1 (en) * 2000-01-19 2003-06-17 Bridgestone Corporation Stabilized silica and method of making and using the same
JP2005330319A (en) * 2004-05-18 2005-12-02 Yokohama Rubber Co Ltd:The Rubber composition and method for producing the same
US20060100320A1 (en) * 2004-02-13 2006-05-11 Dalphond Jake A Synthetic rubber that exhibits low hysteresis

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CA2224609A1 (en) * 1996-12-18 1998-06-18 David J. Kneiling Process for producing improved silica-reinforced masterbatch of polymers in latex form
WO2001010946A2 (en) 1999-08-10 2001-02-15 Bayer Inc. Process for preparation of rubber silica masterbatches based on the use of polymer latices
US7312271B2 (en) * 2005-12-29 2007-12-25 Bridgestone Corporation Solution masterbatch process using fine particle silica for low hysteresis rubber

Patent Citations (4)

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US5985953A (en) * 1996-12-18 1999-11-16 Dsm Copolymer, Inc. Compatibilized silica and polymer silica-reinforced masterbatch containing same
US6579929B1 (en) * 2000-01-19 2003-06-17 Bridgestone Corporation Stabilized silica and method of making and using the same
US20060100320A1 (en) * 2004-02-13 2006-05-11 Dalphond Jake A Synthetic rubber that exhibits low hysteresis
JP2005330319A (en) * 2004-05-18 2005-12-02 Yokohama Rubber Co Ltd:The Rubber composition and method for producing the same

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Title
PEREZ ET AL.: "Effect of the Filler Characteristics on the Miscibility of Styrene-Butadiene Rubber and Nitrile-Butadiene Rubber Blends.", POLYMER ENGINEERING AND SCIENCE, vol. 48, no. 1, 25 August 2008 (2008-08-25), pages 1986 - 1993, Retrieved from the Internet <URL:http://onlinelibrary.wiley.com> [retrieved on 20010601] *
See also references of EP2521751A4 *

Also Published As

Publication number Publication date
EP2521751A2 (en) 2012-11-14
EP2521751A4 (en) 2013-07-17
WO2011085199A2 (en) 2011-07-14
KR20120115355A (en) 2012-10-17
MX2012007953A (en) 2013-02-21
RU2012133281A (en) 2014-02-20
BR112012016722A2 (en) 2017-06-13
CN102782035A (en) 2012-11-14
CA2786602A1 (en) 2011-07-14

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