WO2011069520A1 - Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse - Google Patents
Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse Download PDFInfo
- Publication number
- WO2011069520A1 WO2011069520A1 PCT/EP2009/008766 EP2009008766W WO2011069520A1 WO 2011069520 A1 WO2011069520 A1 WO 2011069520A1 EP 2009008766 W EP2009008766 W EP 2009008766W WO 2011069520 A1 WO2011069520 A1 WO 2011069520A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compound
- compound according
- polymer
- oxygen
- polyethylene
- Prior art date
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 62
- 239000002245 particle Substances 0.000 title claims description 10
- 238000007789 sealing Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 title description 12
- 239000002516 radical scavenger Substances 0.000 title description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 238000007906 compression Methods 0.000 claims abstract description 11
- 230000006835 compression Effects 0.000 claims abstract description 11
- 238000012360 testing method Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulphite Substances [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 21
- -1 compound sodium sulfite Chemical class 0.000 claims description 15
- 239000004698 Polyethylene Substances 0.000 claims description 13
- 229920000573 polyethylene Polymers 0.000 claims description 13
- 239000007799 cork Substances 0.000 claims description 12
- 235000010265 sodium sulphite Nutrition 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 7
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 7
- 229920001684 low density polyethylene Polymers 0.000 claims description 7
- 239000004702 low-density polyethylene Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 238000009928 pasteurization Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims 2
- 238000013023 gasketing Methods 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 230000002792 vascular Effects 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 17
- 239000001301 oxygen Substances 0.000 description 17
- 230000004888 barrier function Effects 0.000 description 7
- 235000013405 beer Nutrition 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000012536 packaging technology Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/08—Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
Definitions
- the invention relates to PVC-free polymer compounds for the production of scavenger-containing seals for screw caps, in particular
- barrier technologies such as described in EP-0503124A1 are preferred.
- oxygen-depleting compounds as described in EP-0328337 Bl, find use. Both technologies are used for sealing compounds of crown corks, but are so far for use in so-called "pry-off
- Twist crowns are an advantage over regular crown corks, as they can be opened without tools, and are usually manufactured in the industry with PVC-containing compounds, as this is the only way to meet stringent requirements Tightness on the one hand, the opening forces on the other hand can be ensured.
- the tightness must avoid the leakage of the filling contents and contamination of the filling contents.
- the filling container can be opened without too much effort by a rotational movement of the rotary crown cork, but does not open undesirable.
- As an additional requirement for the seal must be ensured that the opening and closing of any can be repeated without having to accept a loss of tightness and / or the opening forces. It is advantageous to use such compounds for seals of turning crown corks, which are not PVC components, whether in the form of PVC in the
- the seals must also meet the aforementioned requirements for the eventual migration of chemical constituents.
- Packaging components as well as the guidelines for a foreign taste test.
- the formulation according to the invention makes it possible to produce rotary crown corks which, on the one hand, satisfy the requirements for tightness and opening forces and, on the other hand, contain an oxygen-consuming component, without, however, being made of PVC.
- Rotary crown corks can be used and thus the oxygen-consuming functionality can be optimized.
- sulfites but especially metal sulfites, but especially sodium sulfite, is a suitable additive for creating the above-mentioned oxygen barrier for rotary crown corks.
- the oxygen-consuming component must also be added to the appropriate standards, e.g. regarding a foreign taste test according to DIN 10950, as also described in the "Leitver Ver rempli" of the Working Group Packaging Technology in the TWA of the VLB Berlin (Berlin, March 2009).
- Component in particular of the sulfite
- Component can be controlled by means of the average particle size. Due to the increased inner surface area associated with the reduced particle size, the availability of active agent (e.g.
- Scavenger particles present sodium sulfate is a diffusion barrier for further oxygen and thus increases the barrier effect. Thus, the necessary amounts of additive can be minimized.
- Scavengen particles can be modified by various additives, as described in the patent EP-1050556 Bl.
- the polymer compounds for the rotary crown cork seals according to the invention also achieve the reduction of the oxygen input compared to a scavenger-free reference material.
- the oxygen input into the product was determined using the "total package oxygen” method (Orbisphere technology), in which bottles are filled in a glove box with a beer simulant (in terms of pH and C0 2 content) and the total oxygen content is measured Even after 150 days, entries of less than 0.4 ppm of oxygen can be achieved, and beer is usually referred to as having an oxygen-related taste influence at concentrations of 1 ppm compared to the scavenger-free reference material the factor 3 can be achieved.
- the sealing member is similarly formed as an insert on the inner surface of the vessel closure, as is the case with the known PVC-containing rotary crown corks.
- the formulation according to the invention enables the production of PVC-free
- Sealants for rotary crown corks which with at least one
- oxygen-depleting component is equipped.
- the recipe according to the invention enables the production of a
- Rotary crown cork sealant which can be foamed by means of chemical or physical blowing agents.
- the compound contains between 2% to 20% copolymer consisting of polypropylene (PP) and polyethylene (PE), preferably the material contains between 5% to 15% copolymer.
- the compound contains between 5% to 25% polyethylene (low density polyethylene, LDPE), preferably the material contains between 10% to 20% LDPE.
- polyethylene low density polyethylene, LDPE
- the compound does not contain more than 10%, preferably not more than 7%, more preferably not more than 4% and most preferably not more than 1% of lubricants.
- the compound contains between 10% to 40% of thermoplastic elastomers based on styrene-ethylene-butylene-styrene (SEBS), more preferably the material contains between 20% to 30% of TPE based on SEBS.
- SEBS styrene-ethylene-butylene-styrene
- the compound contains between 20% to 45% medicinal white oil, more preferably the material contains between 30% to 40% medicinal white oil.
- the compound contains between 10% to 30% polyethylene (linear low density polyethylene, LLDPE), preferably the material contains between 15% to 25% LLDPE.
- LLDPE linear low density polyethylene
- the compound contains between 1% to 10% sodium sulfite, preferably the material contains from 4% to 8% sodium sulfite. In other preferred embodiments, the compound contains between 20% and 100% of at least one block copolymer, the block copolymer preferably being an interpolymer of ethylene with at least one C 3 -C 2 o-alpha-olefin or a copolymer of ethylene with a C 3 -C 2 0 -alpha-olefin or an ethylene with a C 3 -C 2 o-alpha-olefin optionally in combination with other unsaturated monomers.
- said material has a Shore A hardness of 50-90, preferably 60-80 and more preferably 65-76. It is also preferable that the polymer compounds in the compression deformation test according to ASTM D395-97 method B after 22 hours of storage at 70 ° C and a
- a compression set between 20% and 90%, preferably from 30% and 60%, and particularly preferably from 40% to 50%.
- the mean particle size of the sodium sulfite is less than 20 ⁇ m, preferably less than 12 ⁇ m and particularly preferably less than 7 ⁇ m. According to the invention, the adjustment of the polymer compounds for the
- the polymer compounds according to the invention for Drekronenkorkendichtungen can show a pressure maintenance of more than 8 bar, after pasteurization, (determined on Secure Seal Tester from Fa. Secure Pak). It should be noted that the parameters of the opening forces, as well as pressure maintenance and oxygen input, are dependent on the width of the bottle mouth and the optionally provided sealing profile.
- pigments can be added to the formulation of the compound.
- An example recipe includes:
- LLDPE polyethylene 16.3%
- the oxygen input was determined by the "totally oxgenic" method (Orbisphere
- bottles are filled in a glove box with a beer simulant (in terms of pH and C0 2 content) and the
- Total package oxygen (ppm) means the total concentration of oxygen in the filling container (bottle).
- Svelon TC VP 642394 white contains no sodium sulphite / Svelon TC VP 849189 T / A contains sodium sulphite, otherwise the material composition is identical
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Closures For Containers (AREA)
- Sealing Material Composition (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/514,899 US9663643B2 (en) | 2009-12-08 | 2009-12-08 | Sealing compounds with scavenger materials of small particle size |
| PL09768504T PL2509883T3 (pl) | 2009-12-08 | 2009-12-08 | Mieszanki uszczelniające z materiałami typu scavenger o małym rozmiarze cząstek |
| MX2012006618A MX347184B (es) | 2009-12-08 | 2009-12-08 | Componentes sellantes con materiales absorbentes de oxigeno con particulas de tamaño pequeño. |
| CA2782488A CA2782488C (en) | 2009-12-08 | 2009-12-08 | Sealing compounds with scavenger materials of small particle size |
| PT97685044T PT2509883T (pt) | 2009-12-08 | 2009-12-08 | Compósitos de vedação com materiais sequestradores de pequena dimensão de partículas |
| NZ600296A NZ600296A (en) | 2009-12-08 | 2009-12-08 | Sealing compounds with scavenger materials of small particle size |
| PCT/EP2009/008766 WO2011069520A1 (de) | 2009-12-08 | 2009-12-08 | Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse |
| CN200980162806.8A CN102648134B (zh) | 2009-12-08 | 2009-12-08 | 具有小粒度的清除剂材料的密封化合物 |
| AU2009356489A AU2009356489B2 (en) | 2009-12-08 | 2009-12-08 | Sealing compounds with scavenger materials of small particle size |
| ES09768504.4T ES2627044T3 (es) | 2009-12-08 | 2009-12-08 | Composiciones de estanqueidad con materiales depuradores de pequeño tamaño de partículas |
| EP09768504.4A EP2509883B1 (de) | 2009-12-08 | 2009-12-08 | Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse |
| ZA2012/03598A ZA201203598B (en) | 2009-12-08 | 2012-05-17 | Sealing compounds with scavenger materials of small particle size |
| US15/496,697 US10450448B2 (en) | 2009-12-08 | 2017-04-25 | Sealing compounds with scavenger materials of small particle size |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2009/008766 WO2011069520A1 (de) | 2009-12-08 | 2009-12-08 | Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/514,899 A-371-Of-International US9663643B2 (en) | 2009-12-08 | 2009-12-08 | Sealing compounds with scavenger materials of small particle size |
| US15/496,697 Continuation US10450448B2 (en) | 2009-12-08 | 2017-04-25 | Sealing compounds with scavenger materials of small particle size |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011069520A1 true WO2011069520A1 (de) | 2011-06-16 |
Family
ID=41716201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2009/008766 WO2011069520A1 (de) | 2009-12-08 | 2009-12-08 | Dichtungscompounds mit scavengermaterialien kleiner teilchengrösse |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US9663643B2 (es) |
| EP (1) | EP2509883B1 (es) |
| CN (1) | CN102648134B (es) |
| AU (1) | AU2009356489B2 (es) |
| CA (1) | CA2782488C (es) |
| ES (1) | ES2627044T3 (es) |
| MX (1) | MX347184B (es) |
| NZ (1) | NZ600296A (es) |
| PL (1) | PL2509883T3 (es) |
| PT (1) | PT2509883T (es) |
| WO (1) | WO2011069520A1 (es) |
| ZA (1) | ZA201203598B (es) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015010718A1 (de) | 2013-07-22 | 2015-01-29 | Actega Ds Gmbh | Dichtungscompounds mit barriereeigenschaften |
| US20150118366A1 (en) * | 2012-03-01 | 2015-04-30 | W.R. Grase S.A. | Closure Liner Composition With Improved Oxygen Reduction |
| US9248943B2 (en) | 2012-02-18 | 2016-02-02 | Anheuser-Busch, Llc | Container closure |
| US11208314B2 (en) | 2015-01-30 | 2021-12-28 | Anheuser-Busch Inbev S.A. | Pressurized beverage concentrates and appliances and methods for producing beverages therefrom |
| WO2022174887A1 (en) | 2021-02-16 | 2022-08-25 | Actega Ds Gmbh | Transparent liner compounds |
| WO2023194589A1 (de) | 2022-04-08 | 2023-10-12 | Actega Ds Gmbh | Laser-markierbare dichtungsmassen mit sauerstoffabsorbern |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102648134B (zh) | 2009-12-08 | 2015-11-25 | 阿克泰加Ds有限公司 | 具有小粒度的清除剂材料的密封化合物 |
| RU2552554C2 (ru) * | 2013-10-16 | 2015-06-10 | Открытое акционерное общество "Пластполимер" (ОАО "Пластполимер") | Способ получения полиолефиновой кислородопоглощающей композиции для уплотнительных прокладок |
| CN103788560A (zh) * | 2013-12-06 | 2014-05-14 | 成都闿阳科技有限公司 | 一种环保型热塑性阻燃汽车门窗密封条 |
| CN107787346B (zh) * | 2015-05-27 | 2021-05-07 | 安海斯-布希英博股份有限公司 | 氧清除聚合物组合物 |
| US20180346205A1 (en) * | 2017-06-05 | 2018-12-06 | Silgan White Cap LLC | Closure with gasket |
| BE1027489B1 (nl) | 2019-08-09 | 2021-03-10 | Anheuser Busch Inbev Sa | Tpe-gebaseerde bekledingen |
| BE1027490B1 (nl) | 2019-08-09 | 2021-03-10 | Anheuser Busch Inbev Sa | Tpe-gebaseerde bekledingen voor houders onder druk |
| KR102307435B1 (ko) * | 2021-02-15 | 2021-09-30 | 삼화화학공업주식회사 | 변형방지 특성을 가지는 산소흡수수지 조성물 |
| WO2024081539A1 (en) | 2022-10-11 | 2024-04-18 | Eastman Chemical Company | Pvc-free vessel caps and methods of making thereof |
| WO2024081533A1 (en) | 2022-10-11 | 2024-04-18 | Eastman Chemical Company | Methods of manufacturing pvc-free vessel caps |
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2009
- 2009-12-08 CN CN200980162806.8A patent/CN102648134B/zh active Active
- 2009-12-08 US US13/514,899 patent/US9663643B2/en active Active
- 2009-12-08 PT PT97685044T patent/PT2509883T/pt unknown
- 2009-12-08 AU AU2009356489A patent/AU2009356489B2/en active Active
- 2009-12-08 EP EP09768504.4A patent/EP2509883B1/de active Active
- 2009-12-08 CA CA2782488A patent/CA2782488C/en active Active
- 2009-12-08 ES ES09768504.4T patent/ES2627044T3/es active Active
- 2009-12-08 PL PL09768504T patent/PL2509883T3/pl unknown
- 2009-12-08 WO PCT/EP2009/008766 patent/WO2011069520A1/de active Application Filing
- 2009-12-08 NZ NZ600296A patent/NZ600296A/xx unknown
- 2009-12-08 MX MX2012006618A patent/MX347184B/es active IP Right Grant
-
2012
- 2012-05-17 ZA ZA2012/03598A patent/ZA201203598B/en unknown
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2017
- 2017-04-25 US US15/496,697 patent/US10450448B2/en active Active
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| EP0250057A2 (de) * | 1986-06-20 | 1987-12-23 | DS-Chemie GmbH | Formteil |
| US5060818A (en) * | 1988-08-08 | 1991-10-29 | Japan Crown Cork Co., Ltd. | Heat-resistant liner-provided vessel closure and process for preparation thereof |
| EP1116747A1 (en) * | 2000-01-14 | 2001-07-18 | Sumitomo Rubber Industries, Ltd. | Low-modulus polymer composition and sealant using the same |
| EP1816086A1 (en) * | 2004-11-10 | 2007-08-08 | Kaneka Corporation | Composition for cap liner |
| EP1894974A1 (en) * | 2006-08-28 | 2008-03-05 | Kraton Polymers Research B.V. | Block copolymer compositions for moulded articles |
| EP2058379A1 (de) * | 2007-11-09 | 2009-05-13 | ACTEGA DS GmbH | Verfahren zur Herstellung eines Gefässverschlusses |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9248943B2 (en) | 2012-02-18 | 2016-02-02 | Anheuser-Busch, Llc | Container closure |
| US10112750B2 (en) | 2012-02-18 | 2018-10-30 | Anheuser-Busch, Llc | Beverage container sealing system |
| US20150118366A1 (en) * | 2012-03-01 | 2015-04-30 | W.R. Grase S.A. | Closure Liner Composition With Improved Oxygen Reduction |
| WO2015010718A1 (de) | 2013-07-22 | 2015-01-29 | Actega Ds Gmbh | Dichtungscompounds mit barriereeigenschaften |
| US20160152808A1 (en) * | 2013-07-22 | 2016-06-02 | Actega Ds Gmbh | Sealing compounds with barrier properties |
| AU2013395216B2 (en) * | 2013-07-22 | 2017-06-15 | Actega Ds Gmbh | Sealing compounds with barrier properties |
| US9708478B2 (en) | 2013-07-22 | 2017-07-18 | Actega Ds Gmbh | Sealing compounds with barrier properties |
| US11208314B2 (en) | 2015-01-30 | 2021-12-28 | Anheuser-Busch Inbev S.A. | Pressurized beverage concentrates and appliances and methods for producing beverages therefrom |
| WO2022174887A1 (en) | 2021-02-16 | 2022-08-25 | Actega Ds Gmbh | Transparent liner compounds |
| WO2023194589A1 (de) | 2022-04-08 | 2023-10-12 | Actega Ds Gmbh | Laser-markierbare dichtungsmassen mit sauerstoffabsorbern |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ600296A (en) | 2013-07-26 |
| US10450448B2 (en) | 2019-10-22 |
| CN102648134A (zh) | 2012-08-22 |
| CA2782488C (en) | 2017-09-05 |
| ZA201203598B (en) | 2013-01-30 |
| US20170327673A1 (en) | 2017-11-16 |
| AU2009356489B2 (en) | 2014-02-20 |
| EP2509883B1 (de) | 2017-03-22 |
| MX347184B (es) | 2017-04-19 |
| CA2782488A1 (en) | 2011-06-16 |
| CN102648134B (zh) | 2015-11-25 |
| PT2509883T (pt) | 2017-06-14 |
| US9663643B2 (en) | 2017-05-30 |
| MX2012006618A (es) | 2012-07-10 |
| AU2009356489A1 (en) | 2012-06-21 |
| PL2509883T3 (pl) | 2017-09-29 |
| EP2509883A1 (de) | 2012-10-17 |
| US20130041087A1 (en) | 2013-02-14 |
| ES2627044T3 (es) | 2017-07-26 |
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