WO2011066142A1 - Stabilized blends containing friction modifiers - Google Patents
Stabilized blends containing friction modifiers Download PDFInfo
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- WO2011066142A1 WO2011066142A1 PCT/US2010/056918 US2010056918W WO2011066142A1 WO 2011066142 A1 WO2011066142 A1 WO 2011066142A1 US 2010056918 W US2010056918 W US 2010056918W WO 2011066142 A1 WO2011066142 A1 WO 2011066142A1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/06—Particles of special shape or size
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
- C10M2215/28—Amides; Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbased sulfonic acid salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/70—Soluble oils
Definitions
- Functional fluid compositions have been discovered that may contain high amounts of friction modifiers, and particularly friction modifiers with limited solubility in and/or compatibility with the functional fluid compositions in which they are used, allowing for the use of higher amounts of such friction modifiers in these functional fluid compositions, while maintaining the stability, clarity, and/or compatibility of the overall composition.
- the present invention provides a composition that includes: (a) a medium, which may include a solvent, a functional fluid, or combinations thereof; and (b) a friction modifier component that is not fully soluble in the medium; and (c) a stabilizing component that is soluble in (a) and that interacts with (b) such that (b)'s solubility in (a) is improved, or perhaps more accurately, (b)'s solubility in the combination of (a) and (b) is improved over (b)'s colubili- ty in (a).
- Components (b) and (c) may be present in component (a) in the form of dispersed particles having an average diameter of less than 10 microns.
- the types of functional fluids in and with which the compositions and methods of the present invention may be used can include: gear oils, transmission oils, hydraulic fluids, engine oils, two cycle oils, metalworking fluids, fuels and the like.
- the functional fluid is engine oil.
- the functional fluid is gear oil.
- the functional fluid is a transmission fluid.
- the functional fluid is a hydraulic fluid.
- the functional fluid is a fuel.
- Suitable solvents include aliphatic hydrocarbons, aromatic hydrocarbons, oxygen containing compositions, or mixtures thereof.
- the oxygen containing composition can include an alcohol, a ketone, an ester of a carboxylic acid, a glycol and/or a polyglycol, or a mixture thereof.
- Suitable solvents also include oils of lubricating viscosity, naphtha, toluene, xylene, or combinations thereof.
- the oil of lubricating viscosity can comprise natural oils, synthetic oils, or mixtures thereof.
- the oil of lubricating viscosity can be an API (American Petroleum Institute) Group II, III, IV, V base oil or mixture thereof.
- PilotTM 140 and PilotTM 299 and PilotTM 900 available from Petrochem Carless, Petro -CanadaTM 100N, NexbaseTM, YubaseTM, and 4 to 6 cSt poly(alpha-olefms).
- the friction modifier can be represented by a compound of Formula (III)
- the fatty acid monoester of glycerol is useful.
- Mixtures of mono and diesters may be used.
- Mixtures of mono- and diester can contain at least about 40% of the monoester.
- Mixtures of mono- and diesters of glycerol containing from about 40% to about 60% by weight of the monoester can be used.
- commercial glycerol monooleate containing a mixture of from 45% to 55% by weight monoester and from 55% to 45% diester can be used.
- Suitable polyamines also include ethylenepolyamines, as described under the heading Ethylene Amines in Kirk Othmer's "Encyclopedia of Chemical Technology", 2d Edition, Vol. 7, pages 22-37, Interscience Publishers, New York (1965). These materials are a complex mixture of polyalkylenepolyamines including cyclic condensation products such as the aforedescribed piperazines.
- any reference to acids such as carboxylic or sulfonic acids, is intended to include the acid-producing derivatives thereof such as anhydrides, lower alkyl esters, acyl halides, lactones and mixtures thereof, unless otherwise specifically stated.
- Suitable overbased detergents also include those derived from phenol and alkylated phenols, which may be referred to as phenates, for example calcium phenate sulfides.
- the phenate may be a sulphur-containing phenate, a methyl ene-bridged phenate, or mixtures thereof.
- the phenate is sulphur-containing/coupled phenate.
- Such materials are described in US Pat. No. 6,551,965 and EP Publications EP 1903093 A, EP 0601721 A, EP 0271262B2 and EP 0273588 B2.
- Component (ii) may be any of the earth metal based described above and in some embodiments is calcium hydroxide.
- compositions of the present invention improve the stability and/or compatibility of the friction modifier component in the overall composition due to the friction modifier component being solubilized in a complex with the solubilizer.
- components (b) and (c), or (b) alone may be present in component (a) in the form of dispersed particles having an average diameter of less than 10 microns.
- the particles have an average diameter of less than 10, 5 or 3 microns.
- the particles have an average diameter of from 0.01 , 0.02, 0.03 or 0.09 to 10, 6, 5 or 3 microns.
- 80% of the particles meet one or more of the size limitations described above.
- 90%, 95%, 99% or even 100% of the particles meet the size limits. That is, in some embodiments no more than 10% by weight of the particles have a diameter of more than 10, 5, 3, 1 or even 0.5 microns.
- the means by which the particles are formed is not overly limited, and may include the mixing of components (a), (b) and (c) using conventional equipment and/or techniques.
- hydrocarbyl groups include: hydrocarbon substituents, that is, aliphatic (e.g., alkyl or alkenyl), alicyclic (e.g., cycloalkyl, cycloalkenyl) substituents, and aromatic-, aliphatic-, and alicyclic-substituted aromatic substi- tuents, as well as cyclic substituents wherein the ring is completed through another portion of the molecule (e.g., two substituents together form a ring); substituted hydrocarbon substituents, that is, substituents containing non- hydrocarbon groups which, in the context of this invention, do not alter the predominantly hydrocarbon nature of the substituent (e.g., halo (especially chloro and fluoro), hydroxy, alkoxy, mercapto, alkylmercapto, nitro, nitroso, and sulfoxy); hetero substituents, that is, substituents which, while having a predominantly hydrocarbon character, in the
- the lubricating composition used in this sample set is a fully formulated 0W20 GF-5 engine oil composition.
- the composition is clear when 0 wt% of the friction modifier component is present.
- the friction modifier component used in these samples is a hydroxy-carboxylic acid derived additive formed by the condensation reaction of tartaric acid and a fatty amine.
- polyisobutenyl means a polymeric alkenyl group derived from polyisobutylene, which may be a saturated or unsaturated group.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2782216A CA2782216A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| US13/512,651 US9163196B2 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| CN201080061938.4A CN102712866B (zh) | 2009-11-30 | 2010-11-17 | 含有摩擦改进剂的稳定混合物 |
| EP10781562.3A EP2507350B1 (en) | 2009-11-30 | 2010-11-17 | Use of stabilized blends containing friction modifiers |
| BR112012012891A BR112012012891A2 (pt) | 2009-11-30 | 2010-11-17 | misturas estabilizadas que contêm modificadores de fricção. |
| US14/886,206 US10190071B2 (en) | 2009-11-30 | 2015-10-19 | Stabilized blends containing friction modifiers |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26487109P | 2009-11-30 | 2009-11-30 | |
| US61/264,871 | 2009-11-30 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/512,651 A-371-Of-International US9163196B2 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| US14/886,206 Continuation US10190071B2 (en) | 2009-11-30 | 2015-10-19 | Stabilized blends containing friction modifiers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011066142A1 true WO2011066142A1 (en) | 2011-06-03 |
Family
ID=43480595
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2010/056918 Ceased WO2011066142A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| PCT/US2010/056922 Ceased WO2011066144A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| PCT/US2010/056923 Ceased WO2011066145A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2010/056922 Ceased WO2011066144A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
| PCT/US2010/056923 Ceased WO2011066145A1 (en) | 2009-11-30 | 2010-11-17 | Stabilized blends containing friction modifiers |
Country Status (7)
| Country | Link |
|---|---|
| US (4) | US9175241B2 (enExample) |
| EP (3) | EP2507350B1 (enExample) |
| CN (3) | CN102712864B (enExample) |
| BR (3) | BR112012012890A2 (enExample) |
| CA (3) | CA2782216A1 (enExample) |
| IN (2) | IN2012DN05120A (enExample) |
| WO (3) | WO2011066142A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012162219A1 (en) * | 2011-05-26 | 2012-11-29 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
| WO2013013026A1 (en) * | 2011-07-21 | 2013-01-24 | The Lubrizol Corporation | Carboxylic pyrrolidinones and methods of use thereof |
| EP2714858A1 (en) * | 2011-05-26 | 2014-04-09 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
| EP3153568A1 (en) * | 2015-10-05 | 2017-04-12 | Infineum International Limited | Additive concentrates for the formulation of lubricating oil compositions |
| US9771540B2 (en) | 2009-01-20 | 2017-09-26 | Exxonmobil Research And Engineering Company | Hydraulic oil compositions with improved hydraulic motor efficiency |
| EP3222698A1 (en) * | 2016-03-22 | 2017-09-27 | Infineum International Limited | Additive concentrates |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013028292A2 (pt) * | 2011-05-04 | 2019-09-24 | Lubrizol Corp | lubrificante para motor de motocicleta |
| US20160122683A1 (en) * | 2013-05-30 | 2016-05-05 | The Lubrizol Corporation | Synergistic additive combination for industrial gear oils |
| US20170175027A1 (en) * | 2014-03-11 | 2017-06-22 | The Lubrizol Corporation | Method of lubricating an internal combustion engine |
| KR20150141839A (ko) | 2014-06-10 | 2015-12-21 | 연세대학교 원주산학협력단 | 물을 분산매로 사용한 폴리이미드의 제조방법 |
| EP3222699B1 (en) * | 2016-03-22 | 2022-06-22 | Infineum International Limited | Additive concentrates |
| WO2019018790A1 (en) * | 2017-07-21 | 2019-01-24 | Exxonmobil Research And Engineering Company | LUBRICANT COMPOSITION FOR EXTENDED FUEL SAVING |
| WO2019018794A1 (en) * | 2017-07-21 | 2019-01-24 | Exxonmobil Research And Engineering Company | LUBRICATING COMPOSITION WITH IMPROVED FILTRABILITY |
| WO2022010606A1 (en) * | 2020-07-09 | 2022-01-13 | Exxonmobil Research And Engineering Company | Engine oil lubricant compositions and methods for making same with superior engine wear protection and corrosion protection |
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| US2777874A (en) | 1952-11-03 | 1957-01-15 | Lubrizol Corp | Metal complexes and methods of making same |
| US3000916A (en) | 1958-06-03 | 1961-09-19 | Standard Oil Co | Composition of matter prepared by reacting polymerized linoleic acid with an amine and subsequently reacting the mixture with boric acid |
| US3087936A (en) | 1961-08-18 | 1963-04-30 | Lubrizol Corp | Reaction product of an aliphatic olefinpolymer-succinic acid producing compound with an amine and reacting the resulting product with a boron compound |
| US3282955A (en) | 1963-04-29 | 1966-11-01 | Lubrizol Corp | Reaction products of acylated nitrogen intermediates and a boron compound |
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| US3819521A (en) | 1971-06-07 | 1974-06-25 | Chevron Res | Lubricant containing dispersed borate and a polyol |
| US3853772A (en) | 1971-06-01 | 1974-12-10 | Chevron Res | Lubricant containing alkali metal borate dispersed with a mixture of dispersants |
| US3907601A (en) | 1970-02-17 | 1975-09-23 | Union Carbide Corp | Vinyl battery separators |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9771540B2 (en) | 2009-01-20 | 2017-09-26 | Exxonmobil Research And Engineering Company | Hydraulic oil compositions with improved hydraulic motor efficiency |
| US9631160B2 (en) | 2011-05-26 | 2017-04-25 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
| EP2714858A1 (en) * | 2011-05-26 | 2014-04-09 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
| WO2012162219A1 (en) * | 2011-05-26 | 2012-11-29 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
| WO2013013026A1 (en) * | 2011-07-21 | 2013-01-24 | The Lubrizol Corporation | Carboxylic pyrrolidinones and methods of use thereof |
| JP2014520891A (ja) * | 2011-07-21 | 2014-08-25 | ザ ルブリゾル コーポレイション | カルボン酸ピロリジノンおよびその使用方法 |
| US9481848B2 (en) | 2011-07-21 | 2016-11-01 | The Lubrizol Corporation | Carboxylic pyrrolidinones and methods of use thereof |
| KR20170040754A (ko) * | 2015-10-05 | 2017-04-13 | 인피늄 인터내셔날 리미티드 | 윤활유 조성물의 제형화를 위한 첨가제 농축물 |
| EP3153568A1 (en) * | 2015-10-05 | 2017-04-12 | Infineum International Limited | Additive concentrates for the formulation of lubricating oil compositions |
| US11168280B2 (en) | 2015-10-05 | 2021-11-09 | Infineum International Limited | Additive concentrates for the formulation of lubricating oil compositions |
| KR102691227B1 (ko) | 2015-10-05 | 2024-08-07 | 인피늄 인터내셔날 리미티드 | 윤활유 조성물의 제형화를 위한 첨가제 농축물 |
| EP3222698A1 (en) * | 2016-03-22 | 2017-09-27 | Infineum International Limited | Additive concentrates |
| US11292980B2 (en) | 2016-03-22 | 2022-04-05 | Infineum International Ltd | Additive concentrates |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130005621A1 (en) | 2013-01-03 |
| US9163196B2 (en) | 2015-10-20 |
| CA2782217A1 (en) | 2011-06-03 |
| US20160040091A1 (en) | 2016-02-11 |
| CN102712864A (zh) | 2012-10-03 |
| CN102712864B (zh) | 2016-01-06 |
| CA2782152A1 (en) | 2011-06-03 |
| CN102712866B (zh) | 2015-03-25 |
| EP2507350B1 (en) | 2018-06-13 |
| EP2507352B1 (en) | 2018-05-30 |
| BR112012012892A2 (pt) | 2017-06-20 |
| WO2011066145A1 (en) | 2011-06-03 |
| CN102712865A (zh) | 2012-10-03 |
| WO2011066144A1 (en) | 2011-06-03 |
| IN2012DN05120A (enExample) | 2015-10-23 |
| EP2507351B1 (en) | 2018-05-16 |
| CN102712866A (zh) | 2012-10-03 |
| EP2507350A1 (en) | 2012-10-10 |
| US10190071B2 (en) | 2019-01-29 |
| US20130005627A1 (en) | 2013-01-03 |
| US9175241B2 (en) | 2015-11-03 |
| BR112012012891A2 (pt) | 2017-06-20 |
| CN102712865B (zh) | 2016-06-08 |
| CA2782216A1 (en) | 2011-06-03 |
| US20120329691A1 (en) | 2012-12-27 |
| EP2507351A1 (en) | 2012-10-10 |
| EP2507352A1 (en) | 2012-10-10 |
| US9193934B2 (en) | 2015-11-24 |
| BR112012012890A2 (pt) | 2017-06-20 |
| IN2012DN05127A (enExample) | 2015-10-23 |
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