WO2011065794A2 - Appareil d'électrolyse à flux continu et dispositif d'injection comprenant ce dernier - Google Patents

Appareil d'électrolyse à flux continu et dispositif d'injection comprenant ce dernier Download PDF

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Publication number
WO2011065794A2
WO2011065794A2 PCT/KR2010/008494 KR2010008494W WO2011065794A2 WO 2011065794 A2 WO2011065794 A2 WO 2011065794A2 KR 2010008494 W KR2010008494 W KR 2010008494W WO 2011065794 A2 WO2011065794 A2 WO 2011065794A2
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WIPO (PCT)
Prior art keywords
electrode
fluid
retainer
positive
rod
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PCT/KR2010/008494
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English (en)
Korean (ko)
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WO2011065794A3 (fr
Inventor
이혁
최장수
김말순
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(주)경우이앤씨
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Publication of WO2011065794A2 publication Critical patent/WO2011065794A2/fr
Publication of WO2011065794A3 publication Critical patent/WO2011065794A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46152—Electrodes characterised by the shape or form
    • C02F2001/46157—Perforated or foraminous electrodes
    • C02F2001/46161—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4611—Fluid flow

Definitions

  • the present invention relates to a flow-type electrolytic device and an injection device using the same, and more particularly, it is produced by electrical and chemical action during electrolysis and discharge of a liquid passing between positive and negative electrodes of a porous structure.
  • the present invention relates to a flow type electrolytic device for applying oxidants and radicals to application areas such as sterilization, disinfection and cleaning, and an injection device using the same.
  • oxidents O, O 2 , O 3 , H 2 O 2 , OH, Cl 2 , ClO 3 ⁇
  • Liquid discharge and plasma techniques are used to provide strong chemical and electrical interactions between the plated electrodes.
  • the general electrolysis method makes it difficult to generate and use radicals, which are very short-lived oxidant components, and also contacts only a small amount of liquid in the electrolyzer, which is present only at the surface of the electrode. Therefore, this electrolysis method does not work effectively on viruses, bacteria and organic compounds that require the action of sterilization, removal and decomposition in the liquid of the entire electrolyzer.
  • oxygen is produced at the positive electrode and hydrogen at the negative electrode, which reacts with radicals that significantly lower the oxidant product of the positive electrode, thus reducing the ability of the radicals because hydrogen produces water in contact with the oxidant.
  • the contact between the hydrogen and the positive electrode reduces the conductivity of the liquid.
  • Electrolytes having positive and negative electrodes composed of a porous or conductive material composed of a cloth or expanded metal or carbon felt, carbon woven cloth, or meshed glassy carbon and metal foam comprising a metal or carbon comprising a precious metal have.
  • the electrode structure includes an open solution area in which liquid flows between the spacer, the positive electrode, and the negative electrode to the open area.
  • the positive electrode and the negative electrode are separated into unipolar or bipolar by spacers and are not shorted to each other.
  • the electrolyzer is selected from perforated plates, screens, wool, felt, stainless steel, aluminum, copper, platinum-plated titanium, mixtures of metal oxides, weaves of gold, and gold-plated steel, and is made of a liquid-permeable conductive material. It includes a positive electrode and a negative electrode. This electrode structure prevents a short circuit between the positive electrode and the negative electrode by using a spacer even if the positive electrode and the negative electrode elements are short.
  • the conductive frame includes a means for connecting to a current source through a plurality of liquid passage openings.
  • One or both sides of the conductive frame is covered with a conductive perforated thin film or wire mesh.
  • the wire mesh has a spacer formed to cover the surface structure of the frame. Both sides of the frame are covered with a conductive perforated thin film or wire mesh.
  • the spacer has a planar section corresponding to the plane of the frame to block electrical contact between the electrodes in use without blocking the through-holes of the frame arranged on a thin film, wire mesh or net.
  • the spacer has a thickness of 1 mm or less.
  • the electrode module forms a fixed shape in a water tank or a water channel, and its structure is large and complicated. Therefore, in applications other than the water tank, there is little freedom of design application, it takes a long time for the whole liquid in the water tank to generate an electrolysis reaction, and it is difficult to utilize simultaneously with radical generation, and the effect of radicals falls.
  • the gap between the positive electrode and the negative electrode is large, and non-conductive spacers that prevent short-circuit between the electrodes reduce flow capacity during electrolysis, thereby increasing current consumption and reducing electrolysis efficiency.
  • a substance that precipitates in the electrolyzed liquid adheres to the electrode, reducing the efficiency and life of the electrode, and the generated precipitate contaminates the electrolytic cell.
  • One embodiment of the present invention relates to a flow-type electrolytic apparatus and an injection apparatus using the same, which minimizes the electrode gap and increases energy efficiency between the positive electrode and the negative electrode regardless of whether a spacer or a separator for preventing short circuits between electrodes is used.
  • One embodiment of the present invention relates to a flow-type electrolytic device and an injection device using the same to increase the electrolysis efficiency at low energy while circulating a large amount of fluid in a simple electrode structure.
  • the body inflow of the fluid flows out of the oxidant and radicals generated fluid, installed in the body orthogonal to the flow direction of the fluid and installed in a spaced state from each other It is provided on at least one side of each of the first electrode retainer and the second electrode retainer, the first electrode retainer and the second electrode retainer to be spaced apart from each other in the flow direction of the fluid, and has a pore through which the fluid flows A positive electrode and a negative electrode, and a positive electrode rod and a negative electrode rod electrically connected to each of the positive electrode and the negative electrode and drawn out of the body.
  • the body has a cylinder, a first sealing cap coupled to one side of the cylinder to form an inlet for the fluid, a second sealing cap coupled to the cylinder at an opposite side of the first sealing cap to form an outlet of the fluid, And first and second fastening caps respectively supporting the first sealing cap and the second sealing cap and coupled to both ends of the cylinder.
  • the inlet may be formed to penetrate in the flow direction of the fluid in the first sealing cap, and the outlet may be formed to penetrate in the flow direction of the fluid in the second sealing cap.
  • the inlet is formed through the first sealing cap and the cylinder in a direction perpendicular to the flow direction of the fluid
  • the outlet is the second sealing cap and the cylinder in a direction perpendicular to the flow direction of the fluid. It can be formed through.
  • the flow type electrolytic apparatus is disposed on the outermost sides of the first electrode retainer and the second electrode retainer, respectively, and includes a first electrode support member supporting the neighboring positive and negative electrodes, respectively. And a second electrode support member.
  • the first sealing cap forms a first fluid chamber connected to the inlet port with the first electrode support member facing each other, and the second sealing cap is between the second electrode support member facing each other.
  • the second fluid chamber may be formed at the outlet.
  • the first electrode retainer and the second electrode retainer may be formed in an annular ring which is in close contact with the inner circumferential surface of the body.
  • the first electrode retainer may form an eleventh groove electrically connected to the positive electrode rod, and a twelfth groove electrically separated from the negative electrode rod.
  • the second electrode retainer may form a twenty-first groove electrically connected to the negative electrode rod, and a twenty-second groove electrically separated from the positive electrode rod.
  • the first electrode retainer and the second electrode retainer may form upper and lower steps on both surfaces.
  • the outermost line of the upper step and the lower step may be arranged in the same line in the flow direction of the fluid.
  • the outermost line of the upper step is located outside the outermost line of the lower step, the positive electrode is electrically connected to the positive electrode rod, on the negative electrode rod side, the lower step
  • the outermost line of the is located outside the outermost line of the upper step, the negative electrode is electrically connected to the negative electrode rod, the first electrode retainer and the second electrode retainer is formed of an electrical insulating material Can be.
  • the first electrode retainer and the second electrode retainer may include an annular portion and ribs extending from the inner circumferential surface of the annular portion to the center of the annular portion and connected to each other.
  • the annular portion may be formed to have a first thickness T1, and the rib may be formed to have a second thickness T2 smaller than the first thickness T1.
  • the first electrode retainer and the second electrode retainer may include an annular portion, a hub forming a through hole at the center of the annular portion, and a rib connecting the annular portion and the hub to each other.
  • the annular portion and the hub may be formed to have a first thickness T1, and the rib may be formed to have a second thickness T2 smaller than the first thickness T1.
  • the positive electrode and the negative electrode among a mesh structure woven from a metal wire, a metal lath structure, a honeycomb structure, a structure in which holes are formed in a plate, and a structure in which holes of a single size or a plurality of sizes are formed in a plate It may have one porous structure.
  • the positive electrode and the negative electrode may be formed of platinum, rhodium, palladium, tantalum, niobium, hafnium, zirconium, iridium, ruthenium, alloys thereof, stainless steel and titanium in one of platinum plating.
  • the gap between the positive electrode and the negative electrode may be formed to 100 to 1000 ⁇ m.
  • the flow type electrolytic device may further include a spacer installed between the first electrode retainer and the second electrode retainer to electrically insulate the positive electrode and the negative electrode.
  • the spacer may have a thickness of 0.1 to 1 mm.
  • the spacer may be formed in an annular contact with the inner circumferential surface of the body.
  • the spacer may form a thirty-first hole and a thirty-second hole passing through the positive electrode rod and the negative electrode rod.
  • the spacer may include an annular portion and a rib extending from the inner circumferential surface of the annular portion to the center of the annular portion and connected to each other.
  • the spacer may include an annular portion, a hub forming a through hole at the center of the annular portion, and a rib connecting the annular portion and the hub to each other.
  • the first electrode retainer, the spacer, and the second electrode retainer are fastened in an electrically insulating structure to set a distance between the first electrode retainer and the second electrode retainer. It may further comprise a fastening rod.
  • the fastening rod is disposed between the positive electrode rod and the negative electrode rod in the circumferential direction of the body, and connects the first fastening rod and the second fastening rod to be fastened through the first electrode retainer, the spacer, and the second electrode retainer. It may include.
  • the first electrode retainer and the second electrode retainer may form a forty-first hole and a forty-second hole into which the first fastening rod and the second fastening rod are inserted, and the spacer may include the first fastening rod and the second fastening rod.
  • a 51 th hole and a 52 th hole corresponding to the 41 th hole and the 42 th hole may be formed to be inserted.
  • a second set adjacent to the first set consisting of the first electrode retainer, the spacer and the second electrode retainer is between the first set of electrode retainers and the second set of first electrode retainers.
  • a gap can be formed.
  • the first electrode retainer may include an eleventh hole electrically connected to the positive electrode rod, and a twelfth groove electrically separated from the negative electrode rod, and the second electrode retainer may be electrically connected to the negative electrode rod.
  • a twenty-first hole and a twenty-second groove electrically connected to the positive electrode rod may be formed.
  • the first electrode retainer and the second electrode retainer may form a forty-first hole and a forty-second hole into which the first and second fastening rods are inserted.
  • a flow type electrolytic device includes a first fluid connector interposed between the first sealing cap of the first fluid chamber and the first electrode support member, and the first fluid connector of the second fluid chamber. It may further include a second fluid connector interposed between the second sealing cap and the second electrode support member.
  • the first fluid connector may include one eleventh inlet connected to the inlet to introduce the fluid, and a plurality of eleventh branches branched from the eleventh inlet and laterally open to supply the fluid to the first fluid chamber. It may include outlets.
  • the second fluid connector is a plurality of twenty-first inlets for opening the fluid from the second fluid chamber and laterally open, one connected to the twenty-first inlets and to the outlet to outflow the fluid It may include the twenty-first outlet of.
  • the first electrode retainer and the second electrode retainer are installed in the body in a state orthogonal to the flow direction of the first fluid spaced apart, the first electrode retainer and the second electrode
  • a positive electrode and a negative electrode are provided on at least one side of each of the electrode retainers to form a gap therebetween in a flow direction of the first fluid, and have a porous hole through which the first fluid flows, and a positive electrode rod and a negative electrode on each of the positive electrode and the negative electrode.
  • An electrolysis device that electrically connects a rod and draws it to the outside of the body to generate an oxidant and a radical by applying an electrolysis and a liquid discharge action to the first fluid, and supplying a first fluid including the oxidant and the radical part; And injecting the first fluid including the oxidant and the radical supplied from the electrolytic device to the electrolytic device, or at least one of a second fluid and a third fluid introduced separately from the first fluid and the first fluid. It includes an injection unit for atomizing and spraying together.
  • the electrolytic device may be built in one side of the body of the injection unit.
  • the body of the electrolytic device the cylinder is inserted into the body of the injection portion, the first sealing cap is coupled to one side of the cylinder to form the inlet of the first fluid embedded in the body of the injection portion, the first sealing cap A second sealing cap coupled to the cylinder on the opposite side to form an outlet of the first fluid and embedded in the body of the injection portion, and a first fastening cap supporting the first sealing cap and coupled to the body of the injection portion; can do.
  • the body of the injector may include a first passage connected to the outlet and receiving the electrolytic device, and a second passage connected to the second inlet for supplying the second fluid.
  • the ejection unit, the ejection body is mounted to the front end of the second passage is disposed inside the body end of the ejection portion, and connected to the electrolytic device portion to the first passage and having a discharge port connected to the first passage, the discharge It is coupled to the outside of the sieve, and discharges the second fluid supplied to the second passage toward the discharge surface and the discharge port formed on the outer side of the discharge body through the incision groove, the rotational shear force is applied to the discharged second fluid A vortex to be provided, and a vortex to receive the vortex, which is coupled to the injector body to connect the vortex to the second passage, and forms a vortex induction portion that narrows while going forward of the discharge body, and the vortex induction portion and the discharge
  • the second fluid is concentrated and spread at a center point formed in front of the discharge port.
  • a first negative pressure in the discharge port forming a second negative pressure on the side of the center point, and arranging micro holes on the side of the center point where the second negative pressure is formed, thereby connecting the micro holes to a third fluid.
  • It may include an annular chamber.
  • the electrolytic device may be formed of a cartridge and connected to the rear of the injection unit.
  • the second sealing cap of the electrolytic device unit may include a protrusion corresponding to the rear of the injection unit, and the protrusion may be screwed to the body of the injection unit.
  • the protrusion may form a hydraulic chamber that connects the outlet and the first passage to each other.
  • the electrolytic device portion is formed of a cartridge may be connected to the side of the injection portion by a connecting member.
  • connection member may be connected to the outlet of the second sealing cap of the electrolytic device part on one side thereof and to the second passage of the injection part on the other side thereof.
  • the positive and negative electrodes of the porous structure are installed in the first and second electrode retainers so as to be perpendicular to the flow direction of the fluid, and the positive and negative electrodes are set by the interval setting of the first and second electrode retainers.
  • Oxidants and radicals are produced by the electrical and chemical action of the electrolysis and discharge action. By supplying oxidants and radicals directly to the liquid, or by spraying using an injector, it can be applied to application areas such as sterilization, disinfection and cleaning.
  • the positive electrode and the negative electrode are formed in a porous structure and installed in a state perpendicular to the flow direction of the fluid, a high current density can be obtained because the surface area of the electrode is wide and the electrode intervals are shortened. Thus, when handling a large amount of fluid, the cost of electrolysis is saved. Most flowing fluids contact the positive electrode in the region adjacent to the positive electrode where radicals are generated, thus maximizing the short-lived radical effect.
  • the positive electrode and the negative electrode are provided in plural, a high current density of a large area can be obtained without reducing the flow volume of the fluid, so that the effect of electrolysis can be realized while flowing a large amount of fluid.
  • the positive electrode and the negative electrode are formed in a porous structure to form a flow-through structure installed in a state perpendicular to the flow direction of the fluid, it is possible to prevent the oxidation and scale adhesion of the positive electrode and the negative electrode by adjusting the flow rate of the fluid.
  • the positive electrode and the negative electrode are provided in the first and second electrode retainers in a symmetrical structure, the positive electrode and the negative electrode may be made of the same material, and the polarities may be exchanged for each set period.
  • FIG. 1 is an exploded perspective view of a flow-through electrolytic apparatus according to a first embodiment of the present invention.
  • FIG. 2 is a cross-sectional view of the flow type electrolytic apparatus of FIG.
  • FIG 3 is a sectional view (a) and a plan view (b) of the first embodiment of the first and second electrode retainers.
  • FIG. 4 is a plan view of a first embodiment of a positive and negative electrode
  • FIG 5 is a plan view of a first embodiment of a spacer.
  • FIG. 6 is a sectional view (a) and a plan view (b) of a second embodiment of the first and second electrode retainers.
  • FIG 7 is a sectional view (a) and a plan view (b) of a third embodiment of the first and second electrode retainers.
  • FIG. 8 is a plan view of a second embodiment of a positive and negative electrode
  • FIG. 9 is a plan view of a third embodiment of a positive and negative electrode.
  • Fig. 10 is a plan view of a fourth embodiment of a positive and negative electrode.
  • Fig. 11 is a plan view of a fifth embodiment of a positive and negative electrode.
  • Fig. 12 is a plan view of a sixth embodiment of a positive and negative electrode.
  • Fig. 13 is a plan view of a seventh embodiment of a positive and negative electrode.
  • Fig. 14 is a plan view of an eighth embodiment of a positive and negative electrode.
  • Fig. 15 is a sectional view (a) and a plan view (b) in which the positive and negative electrodes of the second embodiment are assembled into the first and second electrode retainers of the first embodiment.
  • Fig. 16 is a sectional view (b) and a plan view (c) in which the positive and negative electrodes of the sixth embodiment are assembled to the first and second electrode retainers of the third embodiment.
  • Fig. 17 is a layout view of the structure of the bi-electrode structure of the positive and negative electrodes and the first and second electrode retainers.
  • Fig. 18 is a diagram showing the arrangement of the single electrode structures of the positive and negative electrodes and the first and second electrode retainers.
  • Figure 19 is a plan view of a second embodiment of a spacer.
  • 20 is a plan view of a third embodiment of a spacer.
  • FIG. 21 is a cross-sectional view of the connection structure of the first and second electrode retainers and the positive and negative electrode rods in FIG.
  • FIG. 22 is a cross-sectional view of the first embodiment of the fastening structure of the first and second electrode retainers and the spacer and the fastening rod in FIG. 21; FIG.
  • FIG. 23 is a cross-sectional view of the second embodiment of the fastening structure of the first and second electrode retainers and the spacer and the fastening rod in FIG.
  • FIG. 24 is a cross-sectional view of the connection structure of the first and second electrode retainers and the positive and negative electrode rods in the flow-through electrolytic apparatus according to the second embodiment of the present invention.
  • FIG. 25 is a cross-sectional view of a fastening structure between the first and second electrode retainers and the fastening bar in FIG. 24.
  • FIG. 26 is a plan view of the first and second electrode retainers a and b used in FIGS. 24 and 25.
  • FIG. 26 is a plan view of the first and second electrode retainers a and b used in FIGS. 24 and 25.
  • FIG. 27 is a sectional view of a flow-through electrolytic apparatus according to a third embodiment of the present invention.
  • FIG. 28 is an exploded perspective view of the first chamber and the second chamber in the flow-through electrolytic apparatus according to the fourth embodiment of the present invention.
  • FIG. 29 is a longitudinal cross-sectional view of FIG. 28;
  • FIG. 30 is a cross-sectional view of the injector according to the first embodiment of the present invention.
  • Fig. 31 is a sectional view of an injector according to a second embodiment of the present invention.
  • FIG. 32 is a sectional view of an injector according to a third embodiment of the present invention.
  • FIG. 1 is an exploded perspective view of a flow type electrolytic apparatus according to a first embodiment of the present invention
  • FIG. 2 is a cross-sectional view of the flow type electrolytic apparatus of FIG. 1 and 2
  • the flow type electrolytic apparatus 100 according to an embodiment electrolytically dissolves a fluid, ie, a liquid circulating through the pores of the positive and negative electrodes 11 and 12, And oxidants and radicals produced by chemical action in a liquid, or a liquid containing oxidants and radicals is supplied to the outside, so as to be used for various applications such as sterilization, disinfection and cleaning.
  • the flow type electrolytic apparatus 100 forms a gap between the positive and negative electrodes 11 and 12 in the direction in which the liquid flows, distributes the liquid through the pores of the positive and negative electrodes 11 and 12, and distributes the liquid to the liquid to be distributed. Electrolysis and liquid discharge action. At this time, the positive and negative electrodes 11 and 12 form a short circuit prevention structure while maintaining a fine interval regardless of whether the spacer 15 or the separator is used.
  • the surface areas of the positive and negative electrodes 11 and 12 are wide and the intervals are minute, the current density is high and the throughput of the liquid is increased. Since most of the liquid circulating through the pores of the positive and negative electrodes 11 and 12 flows through the positive electrode 11 and contacts the positive electrode 11, the effect of radicals having a short lifespan is maximized.
  • the distributor type electrolytic apparatus 100 of the embodiment includes a body 30, a first electrode retainer 10, a second electrode retainer 20, a positive electrode 11, a negative electrode 12, and a positive electrode rod 51. ) And the negative electrode rod 52.
  • the body 30 is formed to inject liquid to generate oxidants and radicals in the positive and negative electrodes 11 and 12 and to drain the liquid containing them.
  • the body 30 includes a cylinder 33, first and second sealing caps 311 and 312 for sealing both ends of the cylinder 33, and first and second fastening caps 321 and 322. do.
  • the cylinder 33 forms a space for receiving the positive and negative electrodes 11 and 12 and the components supporting them.
  • the first sealing cap 311 is coupled to one side of the cylinder 33 to form the inlet 60 of the liquid.
  • the inlet 60 is formed penetrating through the first sealing cap 311 in the flow direction of the liquid (the longitudinal direction of the cylinder).
  • the second sealing cap 312 is coupled to one side of the cylinder 33 on the opposite side of the first sealing cap 311 to form the outlet 70 of the liquid.
  • Outlet 70 is formed through the second sealing cap 312 in the flow direction of the liquid (the longitudinal direction of the cylinder).
  • the first fastening cap 321 supports the first sealing cap 311 and is screwed to one end of the cylinder 33.
  • the second fastening cap 322 supports the second sealing cap 312 and is screwed to the other end of the cylinder 33.
  • the first and second electrode retainers 10 and 20 are installed while maintaining the interval set in the cylinder 33 in a state orthogonal to the liquid flow direction (the longitudinal direction of the cylinder) (the state corresponding to the cross section of the cylinder).
  • the first and second electrode retainers 10 and 20 are spaced apart from each other to set the interval between the positive and negative electrodes 11 and 12 provided thereon.
  • the positive electrode 11 is provided on one side or both sides of the first electrode retainer 10 and has pores for circulating liquid.
  • the negative electrode 12 is installed on one side or both sides of the second electrode retainer 20 and has pores for circulating the liquid.
  • the positive and negative electrodes 11 and 12 form a gap G therebetween.
  • the positive and negative electrodes 11 and 12 may be provided in plural, as shown in FIGS. 1 and 2, and in this case, the first and second electrode retainers 10 for installing the positive and negative electrodes 11 and 12 may be provided. , 20) is also provided in plurality.
  • the positive electrode rod 51 is electrically connected to the positive electrode 11 and the positive electrodes 11 and electrically separated from the negative electrode 12.
  • the negative electrode rod 51 is electrically connected to the negative electrode 12 and the negative electrodes 12, and is electrically separated from the positive electrode 11.
  • the positive electrode rod 51 is electrically connected to the positive electrodes 11 and is drawn out of the first sealing cap 311.
  • the negative electrode rod 52 is drawn out of the first sealing cap 311 by electrically connecting the negative electrodes 12.
  • the positive and negative electrode rods 51 and 52 connect external power to the positive and negative electrodes 11 and 12, respectively, and the polarities of the positive and negative electrodes 11 and 12 are switched when the external power is connected by switching the polarity.
  • the flow type electrolytic apparatus 100 includes a first electrode support member 81 supporting the outermost positive electrode 11 and the outermost structure in the arrangement structure of the plurality of positive and negative electrodes 11 and 12. It may further include a second electrode support member 82 for supporting the negative electrode 12.
  • the first electrode support member 81 supports the first electrode retainer 10 and the positive electrode 11 at the side of the first electrode retainer 10.
  • the second electrode support member 82 supports the second electrode retainer 20 and the negative electrode 12 on the second electrode retainer 20 side.
  • the first sealing cap 311 forms a first fluid chamber C81 between the first electrode support member 81 facing each other and is connected to the inlet 60.
  • the pressurized liquid flowing into the inlet 60 is rectified and supplied uniformly in the first fluid chamber C81 corresponding to the total area of the positive electrode 11.
  • the second sealing cap 312 forms a second fluid chamber C82 between the second electrode support member 82 facing each other and is connected to the outlet 70.
  • the positive and negative electrodes 11 and 12 are circulated, and the liquid containing the oxidant and the radical is uniformly rectified and flowed out in the second fluid chamber C82 corresponding to the total area of the negative electrode 12.
  • first and second electrode retainers 10 and 20 are a sectional view (a) and a plan view (b) of the first embodiment of the first and second electrode retainers. Since the first and second electrode retainers 10 and 20 may be formed in the same manner, the same will be described with reference to one drawing.
  • the first and second electrode retainers 10 and 20 are formed in an annular shape that is in close contact with the inner circumferential surface of the cylinder 33 to support the positive and negative electrodes 11 and 12, and the upper step 13 on both sides. 23 and lower steps 14 and 24 are formed. Therefore, the first and second electrode retainers 10 and 20 can maximize the flow area of the liquid in the positive and negative electrodes 11 and 12.
  • the first and second electrode retainers 10 and 20 are the eleventh and twenty-first grooves G11 and G21 and the twelfth and twenty-second grooves so as to be electrically connected to or electrically separated from the positive and negative electrode rods 51 and 52, respectively. (G12, G22) are formed.
  • Fig. 17 is a layout view of the structure of the bi-electrode structure of the positive and negative electrodes and the first and second electrode retainers.
  • the upper step 13 and the lower step 14 of the first electrode retainer 10 support the positive electrode 11 provided at both sides.
  • the positive electrode 11 is provided at both sides of one first electrode retainer 10 to form a double electrode structure.
  • the upper step 23 and the lower step 24 of the second electrode retainer 20 support the negative electrode 12 provided on both sides.
  • the negative electrode 12 is provided on both sides of one second electrode retainer 20 to form a double electrode structure.
  • the outermost lines of the upper steps 13 and 23 and the lower steps 14 and 24 are arranged in the same line with respect to the flow direction of the fluid, so that the positive electrode ( 11) and the negative electrode 12 face each other as a whole, it is possible to electrolyze and discharge in the liquid to the entire liquid flowing through the positive and negative electrodes (11, 12).
  • the eleventh groove G11 is in close contact with the positive electrode rod 51 and electrically connected to the positive electrode rod 51, and the twelfth groove G12 is separated from the negative electrode rod 52.
  • the negative electrode rod 52 is electrically blocked (S1).
  • the first electrode retainer 10 is formed of a conductor.
  • An electrical insulating material (not shown) is interposed between the twelfth groove G12 and the negative electrode rod 52 to improve electrical insulation reliability of the negative electrode rod 52 and the first electrode retainer 10.
  • the twenty-first groove G21 is in close contact with the negative electrode rod 52 and electrically connected to the negative electrode rod 52, and the twenty-second groove G22 is separated from the positive electrode rod 51.
  • the positive electrode rod 51 is electrically blocked (S2).
  • the second electrode retainer 20 is formed of a conductor.
  • An electrical insulating material (not shown) is interposed between the twenty-second grooves G22 and the positive electrode rod 51 to improve electrical insulation reliability of the positive electrode rod 51 and the second electrode retainer 20.
  • the positive and negative electrodes facing each other between the first and second electrode retainers 10 and 20 by adjusting the distance between the first and second electrode retainers 10 and 20 on the positive and negative electrode rods 51 and 52. It is possible to finely set the interval G between 11 and 12).
  • the distance G between the positive and negative electrodes 11 and 12 may be set to 100 to 1000 ⁇ m with or without spacers or separators. Due to the porous structure, the surface area of the positive and negative electrodes 11 and 12 is wide and the spacing G is minute, so that the current density is high.
  • Fig. 18 is a diagram showing the arrangement of the single electrode structures of the positive and negative electrodes and the first and second electrode retainers. While FIG. 17 illustrates the positive and negative electrodes 11 and 12 of the bipolar structure, FIG. 18 illustrates the positive and negative electrodes 11 'and 12' of the single electrode structure.
  • the first and second electrode retainers 10 'and 20' form left and right upper steps 13, 23; 13 'and 23' differently, and the left and right lower steps 14, 24; 14 ', 24') are formed differently.
  • the positive electrode 11 ' is provided in the upper step 13, 13'; 23, 23 ', and the negative electrode 12' is provided in the lower step 14, 14 '; 24, 24'. That is, the positive electrode 11 'is further extended to the upper steps 13' and 23 ', and the negative electrode 12' is further extended to the lower steps 14 'and 24'.
  • portions of the positive and negative electrodes 11 'and 12' which do not face each other are generated.
  • the first and second electrode retainers 10 'and 20' are formed in the same structure.
  • the outermost line of the upper steps 13 ', 23' is more than the outermost line of the lower steps 14, 24. It is located outside. Therefore, the positive electrode 11 ′ provided at the upper steps 13 ′ and 23 ′ is in close contact with the positive electrode rod 51 and electrically connected thereto.
  • the negative electrode 12 'installed on the lower steps 14' and 24 ' is closely connected to the negative electrode rod 52 and electrically connected thereto.
  • the first and second electrode retainers 10 'and 20' are formed of an electrical insulating material.
  • the first and second electrode retainers 10 'and 20' are opposed to each other by adjusting the distance between the first and second electrode retainers 10 'and 20' on the positive and negative electrode rods 51 and 52.
  • the gap G between the negative electrodes 11 'and 12' can be finely set.
  • the flow type electrolytic apparatus 100 of one embodiment has a bielectrode structure for supporting the positive and negative electrodes 11 and 12 with the first and second electrode retainers 10 and 20.
  • a single electrode structure supporting the positive and negative electrodes 11 'and 12' may be applied to the first and second electrode retainers 10 'and 20'.
  • FIG. 4 is a plan view of a first embodiment of a positive and negative electrode; Referring to FIG. 4, the positive and negative electrodes 11 and 12 may be formed in a mesh structure woven from metal wires.
  • FIGS. 13 and 14 are plan views of the second to eighth embodiments of the positive and negative electrodes.
  • the positive and negative electrodes 11 and 12 have a porous structure (see FIG. 8) in which holes are formed in a plate by drilling, punching, laser processing, etc., and punching expanded metal lath. ) Structure (see FIG. 9), punching structure (see FIG. 10) and honeycomb structure (see FIG. 11).
  • the positive and negative electrodes 11 and 12 may be formed in a porous structure in which a single size of holes is formed in a plate (see FIG. 12) or a porous structure in which a plurality of sizes of holes are formed (see FIGS. 13 and 14). .
  • the positive and negative electrodes 11 and 12 can increase the surface area to increase the flow volume of the liquid due to the porous structure.
  • the positive and negative electrodes 11 and 12 may be formed by platinum plating platinum, rhodium, palladium, tantalum, niobium, hafnium, zirconium, iridium, ruthenium, alloys thereof, stainless steel or titanium.
  • the positive and negative electrodes 11 and 12 formed by platinum plating on titanium are harmless to the human body and have high electrode life and electrolysis and liquid discharge efficiency.
  • the flow type electrolytic apparatus 100 of FIGS. 1 and 2 discloses a spacer 15, but as described above, even when the spacer 15 is not provided, the electrolysis and liquid as described above. Discharge action can be implemented.
  • the flow type electrolytic apparatus 100 has a configuration capable of maintaining the first and second electrode retainers 10 and 20 on the positive and negative electrode rods 51 and 52 at set intervals. in need.
  • the positive electrode rod 51 and the eleventh groove G11 of the first electrode retainer 10 in close contact therewith are screwed together to form the first electrode retainer on the positive electrode rod 51.
  • the position of 10 can be fixed.
  • the negative electrode rod 52 and the twenty-first groove G21 of the second electrode retainer 20 closely contacted thereto may be screwed to fix the position of the second electrode retainer 20 on the negative electrode rod 52.
  • the positive and negative electrodes 11 and 12 are bi-electrode structures provided in pairs in the first and second electrode retainers 10 and 20, respectively, and include spacers 15.
  • the gap G between the positive and negative electrodes 11 and 12 is defined by the thickness of the spacer 15.
  • the spacer 15 is provided between the first and second electrode retainers 10 and 20 to electrically connect the positive and negative electrodes 11 and 12 provided in the first and second electrode retainers 10 and 20, respectively. Insulate. The spacer 15 may improve the reliability of the electrical insulation of the positive and negative electrodes 11 and 12.
  • the spacer 15 may be formed to a thickness of 0.1 to 1mm. In this case, the gap G between the positive and negative electrodes 11 and 12 is limited to 0.1 to 1 mm, which is the thickness of the spacer 15.
  • the spacer 15 may be formed in an annular ring whose outer circumferential surface is in close contact with the inner circumferential surface of the cylinder 33 in order to minimize the disturbance of the liquid flow flowing through the pores of the positive and negative electrodes 11 and 12.
  • the spacer 15 has an outer circumferential surface corresponding to the outer circumferential surfaces of the first and second electrode retainers 10 and 20 to support the annular portion so that the 31st hole H31 penetrates the positive and negative electrode rods 51 and 52.
  • the thirty-second hole H32 is formed. That is, the thirty-first hole H31 faces the eleventh and twenty-second grooves G11 and G22 of the first and second electrode retainers 10 and 20, and the thirty-second hole H32 is the first and second electrode retainer. It faces the 12th, 21st groove
  • FIG. 21 is a cross-sectional view of the connecting structure of the first and second electrode retainers and the positive and negative electrode rods in FIG. 1
  • FIG. 22 is a first view of the fastening structure of the first and second electrode retainers and the spacer and the fastening rods in FIG. It is sectional drawing of an Example.
  • the first electrode retainer 10, the spacer 15, and the second electrode retainer 20 may be connected to the positive and negative electrode rods 51 and 52.
  • the flow-through electrolytic apparatus 100 according to an embodiment fastens the first electrode retainer 10, the spacer 15, and the second electrode retainer 20 by an electrically insulating structure to form first and second electrodes. It may further include a fastening rod 90 for setting the interval (G) of the retainers (10, 20).
  • the fastening rods 90 may be formed as one (not shown), but may be formed of first and second fastening rods 91 and 92 as shown in FIG. 22.
  • the first and second fastening rods 91 and 92 are disposed between the positive and negative electrode rods 51 and 52 in the circumferential direction of the cylinder 33, so that the first and second electrode retainers 10 and 20 and the spacer ( 15 through the nut (91a, 92a) to form a more stable fastening structure.
  • the first and second electrode retainers 10 and 20 form a forty-first hole H41 and a forty-second hole H42 into which the first and second fastening rods 91 and 92 are inserted, respectively (Fig. 3 and Fig. 3). 22).
  • the spacer 15 forms the 51st hole H51 and the 52nd hole H52 corresponding to the 41st and 42nd holes H41 and H42 so that the first and second fastening rods 91 and 92 are inserted, respectively. do.
  • the first and second fastening rods 91 and 92 are interposed between the spacers 15 between the first and second electrode retainers 10 and 20 which are repeatedly arranged.
  • FIG. 23 is a cross-sectional view of the second embodiment of the fastening structure of the first and second electrode retainers and the spacer and the fastening rod in FIG.
  • the first and second fastening rods 91 and 92 form a pair of first and second electrode retainers 10 and 20 via a spacer 15 in one set and neighbor each other.
  • the gap G between the first and second electrode retainers 10 and 20 is set without providing the spacer 15 between the first and second sets ST1 and ST2.
  • the distance G between the first and second electrode retainers 10 and 20 in each of the first and second sets ST1 and ST2 is defined by the thickness of the spacer 15.
  • the interval SG of the first and second electrode retainers 10 and 20 may be variously set between the two sets ST1 and ST2. That is, FIG. 23 illustrates various combinations of the first and second electrode retainers 10 and 20 and the spacer 15.
  • FIG. 6 is a sectional view (a) and a plan view (b) of a second embodiment of the first and second electrode retainers.
  • the second embodiment of the first and second electrode retainers 210 and 220 of FIG. 6 further includes ribs. .
  • the first and second electrode retainers 210 and 220 include an annular portion 211 and ribs 212 extending from the inner circumferential surface of the annular portion 211 to the center of the annular portion 211 and connected to each other.
  • the torus 211 is formed to have a first thickness T1
  • the rib 212 is formed to have a second thickness T2 smaller than the first thickness T1.
  • the annular portion 211 and the rib 212 form a step to support the positive and negative electrodes 11 and 12.
  • the first and second electrode retainers 210 and 220 may prevent sagging of the positive and negative electrodes 11 and 12 at the center while minimizing the reduction of the area in which the liquid flows in the positive and negative electrodes 11 and 12. have.
  • the thicknesses of the positive and negative electrodes 11 and 12 applied to the first and second electrode retainers 210 and 220 are positive and negative electrodes applied to the first and second electrode retainers 10 and 20 of the first embodiment. 11, 12) may be thinner.
  • the third embodiment of the first and second electrode retainers 310 and 320 of FIG. 7 further includes a hub. .
  • the first and second electrode retainers 310 and 320 may include a torus 311a, a hub 314 forming a through hole 313a at the center of the torus 311a, and a torus 311a and the hub ( 314 includes ribs 312a that connect to each other.
  • the annular portion 311a and the hub 314 are formed to have a first thickness T1
  • the rib 312a is formed to have a second thickness T2 smaller than the first thickness T1. Therefore, the first and second electrode retainers 310 and 320 may prevent the sag of the positive and negative electrodes 11 and 12, and may increase the flow amount of the liquid through the central through hole 313a.
  • the first and second electrode retainers 310 and 320 of the third embodiment may compensate for the circulation area of the positive and negative electrodes 11 and 12 reduced by the ribs 312a and the hub 314.
  • Fig. 15 is a sectional view (a) and a plan view (b) in which the positive and negative electrodes of the second embodiment are assembled into the first and second electrode retainers of the first embodiment.
  • first electrode retainer 10 and the positive electrode 11 will be described as an example.
  • the positive electrode 11 of the second embodiment of FIG. 8 is assembled to the first electrode retainer 10 in a double electrode structure.
  • Fig. 16 is a sectional view (b) and a plan view (c) in which the positive and negative electrodes of the sixth embodiment are assembled to the first and second electrode retainers of the third embodiment.
  • the second electrode retainer 320 and the negative electrode 12 ' will be described as an example.
  • the negative electrode 12 'of the sixth embodiment of Fig. 12 is assembled to the second electrode retainer 320 of the third embodiment of Fig. 7 in a double electrode structure.
  • 15 and 16 illustrate that various positive and negative electrodes 11 and 12 'can be assembled to various first and second electrode retainers 10 and 320, and may be assembled in more combinations (not shown). .
  • Figure 19 is a plan view of a second embodiment of a spacer. Compared with the first embodiment of the spacer 15 of FIG. 5, the second embodiment of the spacer 215 of FIG. 19 further includes ribs.
  • the spacer 215 includes an annular portion 151 and ribs 152 extending from the inner circumferential surface of the annular portion 151 to the center of the annular portion 151 and connected to each other. 11, 12 and the positive and negative electrodes 11, 12 and the first and second electrode retainers 10, at the center, while minimizing the reduction of the area through which liquid flows in the first and second electrode retainers 10, 20. It is possible to prevent the sag of 20. Also, when the spacer 215 is applied, the thicknesses of the positive and negative electrodes 11 and 12 and the first and second electrode retainers 10 and 20 are equal to those of the spacer 15 of the first embodiment.
  • the spacer 15 of the first embodiment is connected to the spacer 215 of the second embodiment. In comparison, it can have higher planar precision.
  • FIG. 20 is a plan view of a third embodiment of a spacer. Compared with the second embodiment of the spacer 215 of FIG. 19, the third embodiment of the spacer 315 of FIG. 20 further includes a hub.
  • the spacer 315 may include a torus 151, a hub 154 having a through hole 153 formed at the center of the torus 151, and a rib connecting the torus 151 and the hub 154 to each other. 152). Therefore, the spacer 315 may increase the flow amount of the liquid through the central through hole 153 while preventing the sag of the positive and negative electrodes 11 and 12 and the first and second electrode retainers 10 and 20. have.
  • the spacer 315 of the third embodiment may compensate for the positive and negative flow rates of the negative electrodes 11 and 12 reduced by the ribs 152 and the hub 154.
  • the spacer 315 of the third embodiment may compensate for the positive and negative flow rates of the negative electrodes 11 and 12 reduced by the ribs 152 and the hub 154.
  • FIG. 24 is a cross-sectional view of the connection structure of the first and second electrode retainers and the positive and negative electrode rods in the flow type electrolytic apparatus according to the second embodiment of the present invention
  • FIG. 25 is the first and second electrode retainers in FIG.
  • Fig. 26 is a plan view of the first and second electrode retainers (a, b) used in Figs. 24 and 25. Figs.
  • the flow-through electrolytic apparatus 100 of the first embodiment may or may not apply the spacers 15, and the eleventh, twelfth, twenty-first, and twenty-second operations of the first and second electrode retainers 10 and 20 may be performed. Grooves G11, G12, G21, and G22 are formed.
  • the flow type electrolytic apparatus 200 of the second embodiment does not apply the spacer 15. 24 and 26 (a), the first electrode retainer 410 is formed of an eleventh hole H11 electrically connected to the positive electrode rod 51 and a first electrode electrically separated from the negative electrode rod 52. Twelve grooves G12 are formed.
  • the positive electrode rod 51 and the eleventh hole H11 of the first electrode retainer 410 may be screwed to set an interval G between the second electrode retainer 420.
  • the second electrode retainer 420 is the twenty-first hole H21 electrically connected to the negative electrode rod 52, and the twenty-second electrically separated from the positive electrode rod 51.
  • the groove G22 is formed.
  • the twenty-first hole H21 of the negative electrode rod 52 and the second electrode retainer 420 may be screwed to set a distance G from the first electrode retainer 410.
  • the first and second electrode retainers 410 and 420 form the forty-first and forty-second holes H41 and H42 into which the first fastening rod 91 and the second fastening rod 92 are inserted. do.
  • the first and second fastening rods 91 and 92 may include the 41st and 42nd holes H41 and H42 of the first and second electrode retainers 410 and 420. The screws are coupled to each other and fastened to the nuts 91a and 92a to form a more stable fastening structure while setting and maintaining a gap G between the first and second electrode retainers 410 and 420.
  • FIG. 27 is a sectional view of a flow-through electrolytic apparatus according to a third embodiment of the present invention.
  • the flow type electrolytic apparatus 100 of the first embodiment forms an inlet 60 in the first sealing cap 311 and an outlet 70 in the second sealing cap 312. Inlet 60 and outlet 70 are set in the same direction as the flow direction of the liquid.
  • the flow type electrolytic apparatus 300 of the third embodiment forms the inlet port 360 through the first sealing cap 311 and the cylinder 33 in a direction perpendicular to the flow direction of the liquid, and the outlet port 370. ) Is formed through the second sealing cap 312 and the cylinder 33 in a direction perpendicular to the flow direction of the liquid.
  • the flow type electrolytic device 300 of the third embodiment can be applied to various degrees of freedom of design and various applications.
  • FIG. 28 is an exploded perspective view of the first chamber and the second chamber in the flow-through electrolytic apparatus according to the fourth embodiment of the present invention
  • FIG. 29 is a longitudinal sectional view of FIG.
  • first and second fluid chambers C81 and C82 are formed on the first and second sealing caps 311 and 312, respectively. Uniformly rectify the incoming and outgoing liquids.
  • the flow-through electrolytic apparatus 400 of the fourth embodiment includes first and second fluid connectors 61 and 62 in the first and second fluid chambers C81 and C82, respectively.
  • the first fluid connector 61 rectifies the liquid flowing in between the first sealing cap 311 and the first electrode support member 81 of the first fluid chamber C81.
  • the first fluid connector 61 is one eleventh inlet 611 connected to the inlet 60 to introduce liquid, and branched at the eleventh inlet 611 and laterally opened to open the first fluid.
  • the second fluid connector 62 rectifies the liquid flowing out between the second sealing cap 312 and the second electrode support member 82 of the second fluid chamber C82, for example, the second fluid.
  • the connector 62 is opened in a lateral direction and is provided with a plurality of twenty-first inlets 621 for introducing liquid from the second fluid chamber C82, and an outlet 70 connected to the twenty-first inlets 621 and for discharging liquid. It includes one twenty-first outlet 622 connected to.
  • the liquid flows into the twenty-first inlets 621 from the entire distribution area of the negative electrode 12 and flows out through the twenty-second outlets 622 to uniformly rectify the liquid.
  • fluid ie liquid
  • the positive and negative electrodes are supplied to the negative electrode rods 51, 52.
  • a voltage or negative or positive voltage
  • electrolysis and liquid phase discharge occur between the positive and negative electrodes 11 and 12, and oxidants and radicals are generated by electrical and chemical actions.
  • the oxidant and radical-containing liquid is discharged through the outlet 70 and can be applied to sterilization, disinfection and cleaning of the liquid.
  • the injection apparatuses 1000, 2000, and 3000 to which the flow type electrolytic apparatuses 100, 200, 300, and 400 of the first to fourth embodiments will be described.
  • the flow type electrolytic apparatus 100 of the first embodiment will be described as an example.
  • the injector 1000 of the first embodiment includes an electrolytic device 1001 that generates oxidants and radicals by applying electrolysis and liquid discharge to a liquid, and an oxidant generated by the electrolytic device 1001. And an injection part 1002 that atomizes and injects a liquid (or first fluid) containing radicals according to the use, thereby enabling application in various fields such as sterilization, disinfection and cleaning.
  • the electrolyzer unit 1001 supplies the generated oxidant and radical-containing liquid (for convenience, referred to as "first fluid") to the injection unit 1002.
  • the injection unit 1002 is connected to the electrolytic device unit 1001 and injects the pressurized or self-injected first fluid as it is, or at least one of the second and third fluids introduced separately from the pressurized or self-injected first fluid. Configured to atomize together and spray.
  • the injection unit 1002 for atomizing and injecting the first, second, and third fluids together will be described.
  • the electrolytic device 1001 and the injection unit 1002 can be connected in various structures, and the injection device 1000 according to the first embodiment has an electrolytic device unit (one side of the body 71 of the injection unit 1002). 1001) is applied.
  • the injector 1000 of the electrolytic apparatus 100 shown in FIGS. 2 fastening cap 322 is not provided.
  • the electrolytic apparatus 1001 has the same configuration as the electrolytic apparatus 100 of Figs. 1 and 2 as a whole, but deletes some components and is configured to connect to the injection unit 1002. Therefore, hereinafter, the overall description of the electrolytic device unit 1001 will be omitted, and different portions from the electrolytic device 100 of FIGS. 1 and 2 will be described. That is, the electrolytic device 1001 includes a cylinder 33 embedded in the body 71 extending from the injection unit 1002, a first sealing cap 311 forming a inlet 60 for introducing a first fluid, and a first sealing cap 311.
  • a first fastening cap 321 is coupled. Since the first fastening cap 321 is fastened, the electrolytic device part 1001 is mounted to the injection part 1002.
  • the body 71 of the injection unit 1002 receives the electrolytic unit 1001 and is connected to the first passage 41 connected to the outlet 70 and the second inlet 260 for supplying the second fluid.
  • a second passage 42 is provided.
  • the first passage 41 is connected to the first fluid containing oxidant and radicals through the outlet 70 and the inlet 60, and the second passage 42 is connected to the second fluid through the second inlet 260. Connected.
  • the injection part 1002 includes a discharge body 72, a vortex 73, and an annular chamber 74 mounted to the body 71.
  • the discharge body 72 is mounted at the front end of the second passage 42 to be disposed inside one end of the body 71 and connected to the electrolytic apparatus 1001 by the first passage 41 and to the first passage 41.
  • the discharge port 721 is connected.
  • Vortex 73 is coupled to the outside of the discharge body 72, the discharge surface (2) is formed on the outside of the discharge body 72 through the cutting groove 731 for the second fluid supplied to the second passage (42) 722 and discharge to the discharge port 721 to impart a rotational shear force to the second fluid.
  • the annular chamber 74 is coupled to the body 71 while receiving the vortex 73 to connect the vortex 73 to the second passage 42.
  • the annular chamber 74 forms a vortex induction part 741 that gradually narrows in an inclined state while moving forward of the ejection body 72, and forms a gap C between the vortex induction part 741 and the discharge surface 722. do.
  • the interval C flows through the incision groove 731 and discharges the second fluid having the rotational shear force at high speed.
  • the second fluid is concentrated at the center point CP formed in front of the discharge port 721 and then again. To spread. Accordingly, the first negative pressure P1 acting backward is formed in the discharge port 721, and the second negative pressure P2 acting as the center point CP is formed on the side of the center point CP.
  • the annular chamber 74 is mounted to the outside of the body 71 (for example, screwed), and the micro holes 742 are disposed on the side of the center point CP at which the second negative pressure P2 is formed, and thus, the third chamber 3 is disposed on the third side. It is formed to connect to the fluid. That is, the annular chamber 74 forms a space while narrowing in the forward direction with respect to the discharge direction of the fluid corresponding to the vortex induction part 741, and forms the final jet port 744 at the end. The final jet port 744 finally ejects the particles generated in the discharge body 72, the vortex 73 and the vortex induction part 741, and forms a fine hole 742 on the inner peripheral surface.
  • the annular chamber 74 enables the self suction of the first fluid through the discharge port 721 and the inlet port 60 of the electrolytic apparatus part 1001 by the first negative pressure P1, and the second negative pressure P2 is By arranging the micro holes 742 on the side of the center point CP to be formed, the micro holes 742 are connected to the third fluid through the third inlet 745 to enable self-suction of the third fluid.
  • the annular chamber 74 enhances the degree of atomization of the fluid or enables the role of various kinds of fluid mixing injections.
  • Fig. 31 is a sectional view of an injector according to a second embodiment of the present invention. While the injector 1000 of the first embodiment of FIG. 31 incorporates the electrolytic apparatus 1001 into the injector 1002, the injector 2000 of the second embodiment forms the electrolytic apparatus 2001 as a cartridge. To be connected to the rear of the injection unit 1002.
  • the second sealing cap 312 of the electrolytic device portion 2001 has a protrusion 313 corresponding to the rear of the injection portion 1002, and the protrusion 313 is screwed into the body 71 of the injection portion 1002. Combined.
  • the protrusion 313 forms a fluid chamber C83 connecting the outlet 70 and the first passage 41 to each other.
  • the fluid chamber C83 rectifies and supplies a liquid containing oxidant and radicals flowing out through the outlet 70 to the first passage 41.
  • the second inlet 260 may be formed in plural to supply a plurality of second fluids.
  • the injector 3000 of the third embodiment is different from the injector 2000 of the second embodiment in which the electrolytic apparatus 3001 is formed as a cartridge to connect the connecting member 93 to the side of the injector 1002. It is formed by connecting.
  • the connecting member 93 is connected to the outlet 70 of the electrolytic apparatus 3001 to one side and to the second passage 42 through the second inlet 260 of the injection unit 1002 to the other side.
  • the injector 3000 of the third embodiment shows the possibility of attaching and detaching the electrolytic apparatus 3001 at various positions of the injector 1002.

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Abstract

Un mode de réalisation de la présente invention concerne un appareil d'électrolyse à flux continu qui accroît l'efficacité énergétique entre une anode et une cathode par une réduction de l'intervalle entre les électrodes, indépendamment de l'utilisation d'un espaceur ou d'un séparateur servant à empêcher une insuffisance entre les électrodes. L'appareil d'électrolyse à flux continu selon un mode de réalisation de la présente invention comprend: un corps servant à recevoir un fluide pour rejeter un fluide dans lequel sont générés des oxydants et des radicaux; un premier élément de retenue d'électrode et un second élément de retenue d'électrode espacés l'un de l'autre, qui sont placés à l'intérieur du corps de manière perpendiculaire au sens d'écoulement du fluide; une anode et une cathode qui comportent des pores à travers lesquels le fluide s'écoule, et qui se trouvent sur au moins un côté du premier élément de retenue d'électrode et du second élément de retenue d'électrode, respectivement et entre lesquels un intervalle est formé dans le sens d'écoulement du fluide; et une tige d'anode et une tige de cathode reliées électriquement à l'anode et à la cathode, respectivement, pour être tirées à l'extérieur du corps.
PCT/KR2010/008494 2009-11-30 2010-11-29 Appareil d'électrolyse à flux continu et dispositif d'injection comprenant ce dernier WO2011065794A2 (fr)

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US11692516B1 (en) * 2022-05-11 2023-07-04 McKane B. Lee Quantum kinetic injector

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KR200279796Y1 (ko) 2002-03-16 2002-06-26 이천열 전기분해를 이용한 오폐수처리장치
KR100603536B1 (ko) * 2003-11-19 2006-07-26 박상길 메쉬형 전극판을 갖는 전기분해장치
KR100802364B1 (ko) 2006-05-17 2008-02-13 (주) 테크로스 조립식 전극세트
KR100997011B1 (ko) * 2006-08-28 2010-11-25 김칠영 살균된 식염수의 분무 방법
KR100927445B1 (ko) 2009-03-04 2009-11-19 조금일 살균수 생성 유닛, 이를 포함하는 살균수 생성 카트리지 및살균 세탁기

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CN102424456A (zh) * 2011-10-21 2012-04-25 陈枫 高频水处理用电极装置
CN102424456B (zh) * 2011-10-21 2013-07-10 深圳市水力清节能环保有限公司 高频水处理用电极装置
CN111573917A (zh) * 2017-12-30 2020-08-25 骆秀芳 一种基于绿色环保的生活污水处理方法
CN111573917B (zh) * 2017-12-30 2022-03-25 湖南惟创环境科技有限公司 一种生活污水处理方法
CN108928893A (zh) * 2018-09-14 2018-12-04 上海济俭工业设备有限公司 一种杆壳结构电解电催化氧化电絮凝反应装置

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