WO2011048567A1

WO2011048567A1 - Integrated circuit

Info

Publication number: WO2011048567A1
Application number: PCT/IB2010/054770
Authority: WO
Inventors: Georgios Vellianitis; Gilberto Curatola; Kyriaki Fotopoulou; Nader Akil
Original assignee: NXP BV
Current assignee: NXP BV
Priority date: 2009-10-22
Filing date: 2010-10-21
Publication date: 2011-04-28
Anticipated expiration: 2012-04-22
Also published as: US20120199937A1; EP2315246B1; EP2315246A1; US9287414B2

Abstract

An integrated circuit including a Schottky diode, and a method of making the same. The diode includes an active region bordered by an isolation region in a semiconductor substrate of the integrated circuits, a first electrode having a metal contact provided on a surface of the active region,and a second electrode having a silicide contact also provided on the surface of the active region.

Description

DESCRIPTION

INTEGRATED CIRCUIT BACKGROUND OF THE INVENTION

This invention relates to an integrated circuit and to a method of making an integrated circuit. Diodes are well known the art for their rectifying properties, whereby current is allowed to pass only in a single direction through the device. With reference to Figures 1 A and IB, the properties of the ideal diode and a typical real-world diode are briefly compared. As shown in Figure 1 A, for V > 0 (forward bias), the current in the ideal electrode is essentially an exponential function of V, while for V < 0 (reverse bias), no current is allowed to flow through the device.

As is well known, the behaviour of a typical real-world diode deviates from the ideal shown in Figure 1A in three main ways. These deviations are illustrated in Figure IB.

In particular, Figure IB shows that below a characteristic forward bias switch- on voltage V_f, the current flowing through the diode for V > 0 remains substantially at zero. The current in the device rises exponentially above V_f. An alternative way of viewing the behaviour of the ideal diode shown in Figure 1A is to treat V_f as essentially equal to zero.

Also, as shown in Figure IB, for V < 0, a small reverse current (reverse bias leakage current I_RB) flows through the diode, such that the diode does not act as a perfect rectifier (current may pass through the diode in either direction, but is limited to I_RB in the reverse direction). Further, as shown in Figure IB, and as is also well known, typical real- world diodes exhibit large reverse breakdown currents below a certain reverse bias voltage

The values of V_f, IRB, and VBR depend on the design of the diode, and can be tailored according to design requirements by altering parameters such as the doping levels and work functions of the materials used within the device.

For certain applications, such as in rectifiers for low amplitude AC signals and/or in charge pump circuits, it is desirable to use diodes that have a low value of V_f.

For example, to rectify an AC signal with a small amplitude, a small V_f is necessary in order to have any output signal (V_f should be smaller than the AC signal amplitude).

A more specific example is the charge pump circuit, which can be used for rectification and amplification purposes in an RFID tag (an example of this can be found at www.eecg.utoronto.ca/~kphang/ecel371/chargepumps.pdf). Such a circuit receives a small AC signal with amplitude Vi_n and rectifies/amplifies it to a value of:

V_0Ut = 2 - n - (V_in - V_f ) (1) where n is the number of charge pump circuits (stages) in series. From equation (1) it can be seen that in order to have an output voltage, V_f should be lower than Vi_n. Taking into account that Vi_n depends on the distance between RF signal emitter and receiver (the longer the distance between them, the smaller the Vi_n), having a low V_f implies that the RFID can operate at even greater distances. Furthermore, even at a fixed distance between RFID tag and RF signal emitter, a low V_f implies higher power efficiency (how much of the input signal will pass through the diode). For applications such as those mentioned above, Schottky diodes, which typically do have low values of V_f, are therefore particularly suitable. As is well known, Schottky diodes typically include a metal-semiconductor junction, which forms the basis for the rectifying action of the diode.

To reduce costs and allow easy integration with other devices, it is desirable to be able to fabricate Schottky diodes using existing CMOS processing steps.

However, it is difficult to integrate the provision of a metal-semiconductor contact into existing CMOS process flows. For example, with some exceptions (in highly advanced, more expensive process flows), metal is excluded from use in Front End Of Line (FEOL) wafer processing.

Accordingly, the provision of a Schottky diode into integrated circuit chips or dies manufactured by CMOS processing (e.g. for incorporation into the die of an RFID tag) is difficult to achieve.

SUMMARY OF THE INVENTION

Aspects of the invention are set out in the accompanying independent and dependent claims. Combinations of features from the dependent claims may be combined with features of the independent claims as appropriate and not merely as explicitly set out in the claims.

According to an aspect of the invention, there is provided an integrated circuit including a Schottky diode. The diode comprises an active region bordered by an isolation region in a semiconductor substrate of the integrated circuit. The diode also comprises a first electrode comprising a metal contact provided on a surface of the active region. The diode further comprises a second electrode comprising a silicide contact also provided on said surface of said active region. According to another aspect of the invention, there is provided a method of making an integrated circuit including a Schottky diode. The method comprises providing a semiconductor substrate. The method also comprises providing an isolation region in the substrate, wherein the isolation borders an active region of the substrate. The method further comprises forming a metal contact on a surface of the active region to provide a first electrode of the diode. The method also comprises forming a silicide contact on said surface of said active region to provide a second electrode of the diode.

The invention allows the provision of a Schottky diode in an integrated circuit, using a novel combination of standard CMOS processing techniques. Accordingly, manufacture of the diode can be integrated into middle or back end of line process flows.

In one embodiment, the isolation region comprises shallow trench isolation.

In one embodiment, the active region can include a doped well. The first and second electrodes in this example can be provided on the surface of the active region above the doped well. The doped well can be formed by ion implantation. In one embodiment, a portion of the surface of the active region is covered by a protection layer comprising, for example, a nitride layer. In this example, the metal contact can extend through an opening (formed by, for example, an etching process) in the protection layer, to meet the surface of the active region. The silicide contact can be provided on an exposed portion of the surface of the active region that is not covered by the protection layer. The protection layer serves to protect the non- exposed portions of the surface from the silicidation process.

In one example, the diode can include a portion of semiconductor material located in the active region, adjacent the edges of the metal contact of the first electrode. This can reduce leakage current at the edges of the metal contact. In this example, the portion of semiconductor material can be more highly doped than the remainder of the active region. The portion of semiconductor material can also have a conductivity type opposite to that of the remainder of the active region. The portion of semiconductor material adjacent can form a closed ring around the metal contact, again minimising leakage currents.

The metal contact of the first electrode can comprise a portion of an interconnect level of the substrate. In this way, the output characteristics of the Schottky diode can be tailored by selecting the metal composition used for interconnects. The metal composition of the interconnect determines the work function of the first electrode, thus influencing factors such as the switch on voltage V_f of the diode. The interconnect level can be a local interconnect level of the substrate, or a lowest metal interconnect level (Ml) of the substrate. This conveniently allows the manufacture of the diode to be integrated in middle end or back end of line process flows.

According to a further aspect of the invention, there is provided an RFID tag including an integrated circuit of the kind described above.

According to another aspect of the invention, there is provided a method of making an RFID tag. The method includes the method described above for making an integrated circuit of the RFID tag. BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the present invention will be described hereinafter, by way of example only, with reference to the accompanying drawings in which like reference signs relate to like elements and in which:

Figure 1 A schematically illustrates the behaviour of an ideal diode;

Figure IB schematically illustrates the behaviour of a typical real- world diode, for comparison with the ideal diode behaviour shown in Figure 1 A;

Figures 2A-2E schematically illustrate the various stages in a process flow for making an integrated circuit in accordance with an embodiment of the invention;

Figures 3A-3F schematically illustrate the various stages in a process flow for making an integrated circuit in accordance with another embodiment of the invention; and

Figures 4A-4E schematically illustrate the various stages in a process flow for making an integrated circuit in accordance with a further embodiment of the invention.

DETAILED DESCRIPTION

Embodiments of the present invention are described in the following with reference to the accompanying drawings.

This invention can provide an integrated circuit comprising a diode, such as a Schottky diode, which can be manufactured using standard CMOS processing techniques. In particular, a diode in accordance with this invention can be manufactured as part of a middle or back end of line process flow.

A first embodiment of a method for making an integrated circuit comprising a Schottky diode is described below in relation to Figure 2.

In a first stage of the method, there is provided a semiconductor substrate 2. The substrate 2 may comprise any suitable material, for example silicon. Trenches 4 are formed in a major surface of the substrate 2 using, for example, one or more conventional masking and etching steps. The trenches 4 may be filled with an insulating material. The trenches 4 may, for example, be shallow trench isolation (STI) trenches.

In this example, the trenches 4 define an active region 6 of the substrate 2. The active region 6 is bordered by the trenches 4, which can constitute an isolation region in the substrate 2, isolating the active region 6 from other parts of the substrate 2. In plan view, the active region 6 bordered by the trenches 4 may have a substantially oblong shape, although other shapes may also be used (for example, hexagonal, square, circle etc.).

Turning to Figure 2, following formation of the trenches 4 to define the active region 6 a well implantation step Ii is performed, to dope the active region 6. Either n-type or p-type doping may be used, according to design requirements for the diode.

As shown in Figure 2c, a further implantation step I₂ is then performed, to form doped contact implants 8. Typically, the contact implants 8 will have a conductivity type that is the same as that of the doped active region 6. However, the contact implant 8 can be doped to a higher level than the remainder of the active region 6, thereby to enable silicidation to ensure the provision of ohmic contacts.

A protection layer 14 is then formed on the surface of the active region 6. This layer 14 protects the surface of the active region 6 during the subsequent silicidation step. In this example, the protection layer 14 is formed in a gap in between the contact implants 8. The protection layer 14 may, for example, comprise a nitride layer. Thereafter, the contact implants 8 are silicidated to form the silicide contacts 12.

In a further step shown in Figure 2e, metal contacts 16 and 18 are formed. The contacts 18 connect to the silicide contacts 12, while the contact 16 makes direct contact with the surface of the doped active region 6. The contact 16 passes through an opening provided in the protection layer 14. The opening can be formed using, for example, an etching step.

All of the method steps described above can be incorporated into standard CMOS process flows in the middle or back end of line. Accordingly, a diode according to an embodiment of the invention can comprise a semiconductor substrate 2 having an active region 6 that is bordered by an isolation region (such as the trenches 4). A first electrode 16 of the diode comprises a metal contact that is provided on a surface of the active region 6. A second electrode of the diode comprises a silicide contact 12 that is also provided on the surface of the active region 6.

A second embodiment of a method according to this invention is described below in relation to Figure 3. As shown in Figures 3 a, 3b and 3 c, the initial stages of the second embodiment are substantially the same as those described above in relation to Figures 2a, 2b and 2c. However, in this second embodiment, a third implantation step I₃ is performed to form a semiconductor portion 20, which has a conductivity type which is opposite to the conductivity type of the doped active portion 6. The semiconductor portion 20 in this example is located in between the contact implants 8. The semiconductor portion 20 may also have a higher doping level than the remainder of the active region 6. Subsequently, and as described above in relation to Figure 2d, a protection layer 14 is formed, and silicide contacts 12 are provided. The result of this stage is shown in Figure 3e.

Turning to Figure 3f, it is shown that metal contacts 18, 16 are then provided as described above in relation to Figure 2e. In this example, the portion of semiconductor material 20 is provided adjacent the edges of the metal contact 16. The provision of the portion of semiconductor material 20 having a conductivity type opposite to that of the remainder of the active region 6 aids in reducing leakage currents. In particular the junction between the active region 6 (which has a first conductivity type) and the portion 20 (which has a conductivity type opposite to the first conductivity type) blocks such leakage currents. The portion of semiconductor material 20 can substantially surround the metal contact 16 in the region at which the metal contact 16 meets the surface of the active region 6, forming a closed ring. Moreover, the portion of semiconductor material 20 can overlap the edges of the metal contact 16. This enhances the ability of the portion of semiconductor material 20 to inhibit leakage currents, since extra leakage currents normally arise from the Schottky contact edges.

The metal contact 16 can, in accordance with an embodiment of the invention, be provided as part of an interconnect level of the integrated circuit. The interconnect level can, for example, comprise a local interconnect level (LIL) of the integrated circuit. The local interconnect level is typically provided as part of standard of back end of line processing. Since the use of metal is normally prohibited during front end of line of processing, this invention conveniently allows the formation of a metal Schottky contact, using standard CMOS processing, in which the standard local interconnect level metallisation process can be employed to provide the necessary metal contacts of the diode. A third embodiment of the invention is described below in relation to Figure 4. In this third embodiment, the initial stages are substantially the same as those described above in relation to Figures 2a to 2d. Some back end of line process flows do not include the provision of a local interconnect level. In such examples, instead of using the local interconnect level to provide the necessary metal for the diode, a lower (for example, lowest) metal level (Ml) can be used instead. This is shown in Figure 40, where the metal contacts 16 form part of the lowest metal level Ml . As is shown, multiple contacts 16 may be provided, and the number of contacts is limited primarily by the amount of space that is provided on the surface of the active region 6 in between the silicide contacts 12.

In embodiments in which an interconnect level (for example, either a local interconnect level or a lower metal level) of the integrated circuit is used the switch output characteristics of the Schottky diode can be tailored by selecting the metal composition used for the interconnects. The metal composition of the interconnect determines the work function of the first electrode, thus influencing factors such as the switch on voltage V_f of the diode. Examples of materials that can be used for the interconnect level include Ti and Co. These can be used to form TiSi, TiSi₂, and CoSi₂ contacts.

Accordingly, there has been described a diode and a method of making the same. The diode includes a semiconductor substrate having an active region bordered by an isolation region, a first electrode having a metal contact provided on a surface of the active region, and a second electrode having a silicide contact also provided on the surface of the active region.

Although particular embodiments of the invention have been described, it will be appreciated that many modifications/additions and/or substitutions may be made within the scope of the claimed invention.

Claims

1. An integrated circuit including a Schottky diode, the diode comprising:

an active region bordered by an isolation region in a semiconductor substrate of the integrated circuit;

a first electrode comprising a metal contact provided on a surface of the active region; and

a second electrode comprising a silicide contact also provided on said surface of said active region.

2. The integrated circuit of claim 1, wherein the isolation region comprises shallow trench isolation.

3. The integrated circuit of claim 1 or claim 2, wherein the active region comprises a doped well, and wherein the first and second electrodes are provided on the surface of the active region above the doped well.

4. The integrated circuit of any preceding claim, wherein:

a portion of the surface of the active region is covered by a protection layer;

the metal contact extends through the protection layer to meet the surface of the active region; and

the silicide contact is provided on an exposed portion of the surface of the active region not covered by the protection layer.

5. The integrated circuit of any preceding claim, comprising a portion of semiconductor material located in the active region and adjacent the edges of the metal contact of the first electrode, for reducing leakage current at said edges, wherein the portion of semiconductor material is doped to have a conductivity type opposite to that of the remainder of the active region.

6. The integrated circuit of claim 5, wherein portion of semiconductor material adjacent the edges of the metal contact of the first electrode forms a closed ring around the metal contact.

7. The integrated circuit of any preceding claim, wherein the metal contact of the first electrode comprises a portion of an interconnect level of the substrate.

8. The integrated circuit of claim 7, wherein the interconnect level is a local interconnect level of the substrate.

9. The integrated circuit of claim 7, wherein the interconnect level is a lowest metal interconnect level (Ml) of the substrate.

10. An RFID tag including the integrated circuit of any preceding claim.

11. A method of making an integrated circuit including a Schottky diode, the method comprising:

providing a semiconductor substrate;

providing an isolation region in the substrate, wherein the isolation borders an active region of the substrate;

forming a metal contact on a surface of the active region to provide a first electrode of the diode; and

forming a silicide contact on said surface of said active region to provide a second electrode of the diode.

12. The method of claim 11, comprising:

covering a portion of the surface of the active region with a protection layer;

forming the metal contact of the first electrode such that it extends through the protection layer to meet the surface of the active region; and

forming the silicide contact on an exposed portion of the surface of the active region not covered by the protective layer of semiconductor material.

13. The method of claim 11 or claim 12, comprising:

forming a portion of semiconductor material in the active region corresponding to an intended configuration of the metal contact of the first electrode, wherein the portion of semiconductor material is has a conductivity type opposite to that of the remainder of the active region; and

forming said metal contact such that the portion of semiconductor material is positioned adjacent the edges of the metal contact, for reducing leakage current at said edges.

The method of any of claims 11 to 13, comprising forming an interconnect level of the substrate, wherein the metal contact of the first electrode is formed is the same processing step as the formation of the interconnect level.

The method of claim 14, wherein the interconnect level is a local interconnect level of the substrate.

The method of claim 14, wherein the interconnect level is a lowest metal interconnect level (Ml) of the substrate.

A method of making an RFID tag, the method including the method of any of claims 11 to 16 for making an integrated circuit of the RFID tag.