WO2011040766A3 - Preparation method of 1,4-disubstituted cyclohexane derivatives - Google Patents

Preparation method of 1,4-disubstituted cyclohexane derivatives Download PDF

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Publication number
WO2011040766A3
WO2011040766A3 PCT/KR2010/006656 KR2010006656W WO2011040766A3 WO 2011040766 A3 WO2011040766 A3 WO 2011040766A3 KR 2010006656 W KR2010006656 W KR 2010006656W WO 2011040766 A3 WO2011040766 A3 WO 2011040766A3
Authority
WO
WIPO (PCT)
Prior art keywords
preparation
hydroxymethyl
cyclohexane
cyclohexane derivatives
cyclohexanecarboxylic acid
Prior art date
Application number
PCT/KR2010/006656
Other languages
French (fr)
Korean (ko)
Other versions
WO2011040766A2 (en
Inventor
조양래
정선이
김병환
Original Assignee
(주)위즈켐
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)위즈켐 filed Critical (주)위즈켐
Priority to JP2012532011A priority Critical patent/JP5372258B2/en
Publication of WO2011040766A2 publication Critical patent/WO2011040766A2/en
Publication of WO2011040766A3 publication Critical patent/WO2011040766A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C62/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C62/02—Saturated compounds containing hydroxy or O-metal groups
    • C07C62/04—Saturated compounds containing hydroxy or O-metal groups with a six-membered ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention relates to a preparation method of 1,4-disubstituted cyclohexane derivatives, and more specifically, to a preparation of 4-(hydroxymethyl)cyclohexanecarboxylic acid useful as a main raw material in fine chemistry such as medicine, a special polymer and the like from by-products generated in the preparation of 1,4-di(hydroxymethyl)cyclohexane through hydrolysis and extraction and purification processes by steps. The present invention relates to a preparation method of 4-(hydroxymethyl)cyclohexanecarboxylic acid characterized by comprising the process being capable of separating and recovering 1,4-di(hydroxymethyl)cyclohexane bimolecular dehydration polymerization ether and 1,4-di(hydroxymethyl)cyclohexane as by-products in a preparation and separation process thereof.
PCT/KR2010/006656 2009-09-30 2010-09-30 Preparation method of 1,4-disubstituted cyclohexane derivatives WO2011040766A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012532011A JP5372258B2 (en) 2009-09-30 2010-09-30 Process for producing 1,4-disubstituted cyclohexane derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090093521A KR101102574B1 (en) 2009-09-30 2009-09-30 A preparative method for 1,4-disubstituted cyclohexane derivatives
KR10-2009-0093521 2009-09-30

Publications (2)

Publication Number Publication Date
WO2011040766A2 WO2011040766A2 (en) 2011-04-07
WO2011040766A3 true WO2011040766A3 (en) 2011-09-01

Family

ID=43826791

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/006656 WO2011040766A2 (en) 2009-09-30 2010-09-30 Preparation method of 1,4-disubstituted cyclohexane derivatives

Country Status (3)

Country Link
JP (1) JP5372258B2 (en)
KR (1) KR101102574B1 (en)
WO (1) WO2011040766A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102082304B1 (en) 2013-05-02 2020-02-27 에스케이케미칼 주식회사 Copolymer polyester resin and molded product using same
KR101545392B1 (en) * 2013-08-29 2015-08-19 주식회사 제넨칩 Method of producing ether diol compound
JP6602301B2 (en) * 2014-07-30 2019-11-06 昭和電工株式会社 Method for separating and recovering alkylene glycol monoalkyl ether, method for recycling resist composition processing waste liquid, and method for recycling resist composition processing liquid
KR101491419B1 (en) * 2014-08-06 2015-02-09 주식회사 제넨칩 Photocurable monomer and method for producing thereof
US20160075858A1 (en) * 2014-09-16 2016-03-17 Eastman Chemical Company Polymeric compositions with improved noise suppression
KR102162857B1 (en) * 2014-10-01 2020-10-07 에스케이케미칼 주식회사 Method for processing by-products of 1,4-cyclohexanedimethanol
KR102413118B1 (en) * 2015-11-02 2022-06-24 에스케이케미칼 주식회사 Method for processing by-products generated on the preparation of 1,4-cyclohexanedimethanol
KR102092457B1 (en) * 2018-06-15 2020-05-22 (주)휴이노베이션 Cyclohexanedimethanol Pitch-based Plasticizer and Resin Composition Comprising the Same
JPWO2021107047A1 (en) * 2019-11-29 2021-06-03
CN112321433B (en) * 2020-11-03 2021-04-27 凯美克(上海)医药科技有限公司 Synthesis method of tert-butyl 3- (hydroxymethyl) cyclohexanecarboxylate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0517393A (en) * 1991-07-04 1993-01-26 Nikko Kyodo Co Ltd Production of omega-hydroxyfatty acid
EP0922690A1 (en) * 1996-06-28 1999-06-16 New Japan Chemical Co.,Ltd. Process for the preparation of cyclohexanedimethanol
JP2001253847A (en) * 2000-03-10 2001-09-18 Nippon Shokubai Co Ltd Method for producing (hydroxyalkyl)cycloaliphatic carboxylic acids
JP2003292590A (en) * 2002-03-29 2003-10-15 Nippon Shokubai Co Ltd Copolyester produced from hydroxymethylcyclohexanecarboxylic acids as raw material

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57131738A (en) * 1981-02-09 1982-08-14 Hisamitsu Pharmaceut Co Inc Novel cyclohexanecarboxylic acid derivative
JPS57181033A (en) * 1981-03-05 1982-11-08 Hisamitsu Pharmaceut Co Inc Novel cyclohexanecarboxylic acid derivative
JPH08157402A (en) * 1994-12-03 1996-06-18 Toyota Central Res & Dev Lab Inc Method for decomposing polyester
JP2001181223A (en) * 1999-12-27 2001-07-03 Mitsui Chemicals Inc Method for producing 1, 4-cyclohexanedimethanol
JP3993427B2 (en) * 2001-12-03 2007-10-17 本州化学工業株式会社 Method for producing alicyclic hydroxycarboxylic acid
JP2005097158A (en) * 2003-09-24 2005-04-14 Asahi Glass Co Ltd Method for producing fluorine-containing organic compound
JP2008133223A (en) * 2006-11-29 2008-06-12 Honshu Chem Ind Co Ltd Exo type hydroxytetracyclododecane carboxylic acid and preparation process thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0517393A (en) * 1991-07-04 1993-01-26 Nikko Kyodo Co Ltd Production of omega-hydroxyfatty acid
EP0922690A1 (en) * 1996-06-28 1999-06-16 New Japan Chemical Co.,Ltd. Process for the preparation of cyclohexanedimethanol
JP2001253847A (en) * 2000-03-10 2001-09-18 Nippon Shokubai Co Ltd Method for producing (hydroxyalkyl)cycloaliphatic carboxylic acids
JP2003292590A (en) * 2002-03-29 2003-10-15 Nippon Shokubai Co Ltd Copolyester produced from hydroxymethylcyclohexanecarboxylic acids as raw material

Also Published As

Publication number Publication date
KR101102574B1 (en) 2012-01-03
KR20110035705A (en) 2011-04-06
WO2011040766A2 (en) 2011-04-07
JP5372258B2 (en) 2013-12-18
JP2013506658A (en) 2013-02-28

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