WO2011034015A1 - Retention structure of honeycomb structure in exhaust gas purification device - Google Patents

Retention structure of honeycomb structure in exhaust gas purification device Download PDF

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Publication number
WO2011034015A1
WO2011034015A1 PCT/JP2010/065695 JP2010065695W WO2011034015A1 WO 2011034015 A1 WO2011034015 A1 WO 2011034015A1 JP 2010065695 W JP2010065695 W JP 2010065695W WO 2011034015 A1 WO2011034015 A1 WO 2011034015A1
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Prior art keywords
honeycomb structure
convex portion
metal case
holding member
coat layer
Prior art date
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PCT/JP2010/065695
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French (fr)
Japanese (ja)
Inventor
由章 畠山
土佐 真一
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本田技研工業株式会社
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Publication of WO2011034015A1 publication Critical patent/WO2011034015A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/0211Arrangements for mounting filtering elements in housing, e.g. with means for compensating thermal expansion or vibration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/9454Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
    • B01J35/56
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/18Construction facilitating manufacture, assembly, or disassembly
    • F01N13/1872Construction facilitating manufacture, assembly, or disassembly the assembly using stamp-formed parts or otherwise deformed sheet-metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1021Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1023Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1025Rhodium
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2350/00Arrangements for fitting catalyst support or particle filter element in the housing
    • F01N2350/02Fitting ceramic monoliths in a metallic housing
    • F01N2350/04Fitting ceramic monoliths in a metallic housing with means compensating thermal expansion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/02Fitting monolithic blocks into the housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/20Methods or apparatus for fitting, inserting or repairing different elements by mechanical joints, e.g. by deforming housing, tube, baffle plate or parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to a honeycomb structure holding structure in an exhaust gas purification apparatus.
  • a DPF Diesel particulate filter
  • PM particulate matter
  • honeycomb structure As another exhaust gas purification device, a DPF (Diesel particulate filter) is known which collects particulate matter (PM) such as soot contained in exhaust gas by allowing the exhaust gas to permeate through a honeycomb structure as a filter.
  • Some DPFs have a continuous regeneration function by further supporting a catalyst such as platinum or rhodium on the honeycomb structure.
  • the honeycomb structure is made of, for example, ceramics, and a support member and a buffer member are provided between the honeycomb structure and the case in order to prevent breakage.
  • a side surface holding member (support member) for restricting the radial movement of the honeycomb structure is provided between the outer peripheral surface of the cylindrical honeycomb structure and the inner peripheral surface of the case.
  • An end holding member (buffer member) that restricts the movement of the honeycomb structure in the axial direction is attached between the peripheral edges of the upstream and downstream ends of the honeycomb structure and the holding frame provided on the inner peripheral surface of the case. ing.
  • the case expands in the axial direction of the honeycomb structure due to heat during operation of the internal combustion engine, so that a clearance is generated between the case and the honeycomb structure, and the honeycomb structure is axially moved by vibration of the internal combustion engine.
  • the end face of the honeycomb structure or the end face of the end portion holding member will be stepped and worn.
  • Patent Document 1 in order to suppress step wear, an annular groove is formed along the circumferential direction on the outer periphery of the catalyst carrier (honeycomb structure), and the catalyst container containing the catalyst carrier is provided with this An annular recess projecting into the annular groove is formed, and a buffer member is disposed between the side surface of the annular groove and the side surface of the annular recess, thereby restricting the movement of the catalyst carrier in the axial direction (manifold) Converter).
  • the honeycomb structure is a ceramic member composed of a plurality of cells such as a honeycomb shape or a monolith shape, there is a high possibility that a crack or the like is generated when the annular groove is formed. Further, when installing the buffer member in the annular groove, the buffer member has to be once widened, which makes it difficult to manufacture and damages the buffer member and the honeycomb structure.
  • the present invention has been made in view of these points.
  • the main structure is the holding by the side surface holding member wound around the outer peripheral surface of the honeycomb structure, and the exhaust efficiency is not reduced. It is an object of the present invention to provide a honeycomb structure holding structure in an exhaust gas purification apparatus that can suppress cracking and the like and can be easily manufactured.
  • the present invention is a honeycomb structure holding structure in an exhaust gas purification apparatus disposed in an exhaust passage, and has a plurality of cells and an outer peripheral surface covered with a coating layer, and the honeycomb structure.
  • a metal case held inside, and a side surface holding member interposed between the honeycomb structure and the metal case, the honeycomb structure having a plurality of cells and an outer peripheral surface of the honeycomb structure The side surface holding member disposed on the outside of the convex portion, wherein the coat layer has a convex portion formed at least partially along a circumferential direction. It is characterized by being fixed to the metal case via
  • the coat layer covering the outer peripheral surface of the honeycomb structure has the convex portions formed along the circumferential direction, and the honeycomb structure is made of metal via the side surface holding member disposed outside the convex portions. Since the position is fixed to the case, the cross-sectional area of the honeycomb structure does not decrease as in the case of forming the annular groove, and the reduction in exhaust efficiency can be suppressed. In addition, since the convex portions are formed in the coat layer, the member strength is not lowered as in the case of forming the annular groove, and cracking of the honeycomb structure can be prevented.
  • the thickness of the side surface holding member is reduced to increase the surface pressure, and the honeycomb structure is held in the axial direction and the radial direction by the side surface holding member. be able to. Therefore, conventionally, it is possible to omit the end holding member that has been installed on the peripheral edge of the upstream and downstream ends of the honeycomb structure, and it is possible to reduce the thickness of the side holding member. Mounting of the holding member is facilitated.
  • the convex portion is configured by making the coat layer thicker than other portions, and the coat layer is mainly composed of ceramics, alumina, mullite, lithium aluminum silicate, silicon carbide, silicon nitride, It is preferably made of a material containing at least one selected from the group consisting of alumina titanate and cordierite.
  • the convex portion is formed by thickly coating the coat layer, it can be handled in the coating layer manufacturing process, and the convex portion can be easily formed without complicating the manufacturing work. Can be formed.
  • the metal case is reduced in diameter by a diameter reduction process in accordance with the surface shape of the convex portion, and the side surface holding member is fixedly held at a predetermined pressure.
  • the metal case is configured so that the honeycomb structure can be held in the metal case with a predetermined surface pressure while suppressing the displacement of the side surface holding member. Can be easily processed.
  • the axial length dimension of the convex portion of the honeycomb structure is 0.3 to 1.0 times the axial length dimension of the honeycomb structure itself, and the outer diameter of the convex portion. Is preferably 1.01 to 1.2 times the outer diameter of the portion of the honeycomb structure not including the convex portion.
  • the contact area is sufficient to hold the honeycomb structure sufficiently while reducing the area of the side surface holding member, and the cell structure of the honeycomb structure is affected while holding the honeycomb structure on the side surface. Sufficient strength can be obtained.
  • the side surface holding member is formed on an outer peripheral surface of the convex portion of the honeycomb structure including the concave portion by further forming a concave portion by recessing a part of the convex portion formed by the coat layer.
  • the diameter of the metal case is reduced in accordance with the surface shape of the convex portion including the recess.
  • the metal case formed so as to enter the recess also thermally expands in the axial direction even when the metal case thermally expands in the radial direction.
  • the honeycomb structure can be reliably held by the metal case.
  • a plurality of protrusions are further formed on the surface of the protrusions formed of the coating layer at intervals in the axial direction, and the protrusions of the honeycomb structure including the plurality of protrusions are formed. It is preferable that the side surface holding member is attached to the outer peripheral surface of the portion, and the diameter of the metal case is reduced in accordance with the surface shape of the convex portion including the protruding portion.
  • the metal case fitted between the protrusions is also heated in the axial direction.
  • the metal case strongly meshes with the side surface holding member disposed on the outer peripheral surface of the protruding portion, so that vibration applied to the honeycomb structure can be suppressed and stably held.
  • the present invention provides an end holding member that restricts the movement of the honeycomb structure in the axial direction at a position facing the upstream end and the downstream end of the convex portion formed of the coat layer.
  • the metal case is reduced in diameter by spinning so as to apply a predetermined pressure in the axial direction to the upstream end and the downstream end of the end holding member.
  • the end holding member is mounted in addition to the side holding member, and these are directly fixed by the metal case, the side and end of the honeycomb structure can be held only by spinning. This makes it possible to improve workability.
  • a plurality of grooves are formed on the outer peripheral surface of the convex portion.
  • the holding by the side surface holding member wound around the outer peripheral surface of the honeycomb structure is set as the main holding, and the cracking of the honeycomb structure can be suppressed without lowering the exhaust efficiency, and the manufacturing work can be suppressed.
  • An easy carrier support structure for a catalytic converter can be provided.
  • a catalytic converter 1 to which the honeycomb structure holding structure according to the first embodiment is applied is a purification device that is installed on, for example, an exhaust path of an automobile and purifies harmful substances contained in exhaust gas. is there.
  • the catalytic converter 1 includes a catalyst carrier 2 that supports a catalyst, a metal case 3 that houses the catalyst carrier 2, and a side surface holding member 4 that is installed between the catalyst carrier 2 and the metal case 3. .
  • the catalyst carrier 2 is formed by coating alumina on the surface of a ceramic honeycomb structure formed in a cylindrical shape, for example.
  • the alumina coating layer contains a three-way catalyst such as platinum, palladium, or rhodium.
  • the catalyst carrier 2 has a plurality of cells 21 through which exhaust gas flows.
  • the cell 21 is a hollow passage and is formed, for example, in a quadrangular shape in a cross-sectional view.
  • the surface of the cell 21 is coated with the above-described three-way catalyst.
  • the cell 21 is sealed at either the inflow side or the outflow side end, and the cells 21 with the inflow side sealed and the cells 21 with the outflow side sealed are alternately arranged.
  • the catalyst carrier 2 is made of ceramics, although nitrogen oxides (NOx), hydrocarbons (HC), and carbon monoxide (CO) in the exhaust gas come into contact with the three-way catalyst to cause a redox reaction and become high temperature. Therefore, the heat resistance is high, and since the honeycomb structure is used, the contact area with the exhaust gas is wide and the purification ability is high.
  • the catalyst carrier 2 is installed on the exhaust path with the axial direction of the honeycomb structure oriented in the flow direction of the exhaust gas.
  • the cross-sectional shape of the catalyst carrier 2 is not limited to a circular shape, and may be formed in an elliptical shape or a polygonal shape.
  • a coat layer 5 is formed on the outer peripheral surface of the catalyst carrier 2.
  • the coat layer 5 is composed mainly of ceramics, and is selected from the group consisting of alumina, mullite, lithium aluminum silicate, silicon carbide (SiC), silicon nitride, alumina titanate (AT), cordierite, and the like. It is comprised with the material containing 1 type or 2 types.
  • the thickness dimension of the flat portions 5a and 5b described later of the coat layer 5 is preferably about 5 mm.
  • the coat layer 5 is formed in an annular shape along the circumferential direction of the catalyst carrier 2 at the flat portions 5 a and 5 b on the upstream side and the downstream side that are formed flat and in the center portion in the axial direction.
  • a convex portion 51 is formed by making the thickness of the coat layer 5 larger than the flat parts 5a and 5b. A method for forming the convex portion 51 will be described in detail later.
  • the convex portion 51 is formed in a mountain shape in which the central portion in the axial direction is the highest apex 52.
  • taper portions 53 and 53 that are reduced in diameter as they are separated from the top portion 52 are formed. It is preferable that a plurality of grooves 53a, 53a... Are formed on the surfaces of the tapered portions 53, 53, for example, along the circumferential direction.
  • the length L1 of the convex portion 51 in the axial direction of the catalyst carrier 2 is 0.3 to 1.0 times (30% or more and 100% or less) of the length L2 of the catalyst carrier 2 in the axial direction. preferable. If it is smaller than 0.3 times, a sufficient holding area cannot be obtained, and if it is larger than 1.0 times, the weight of the catalyst carrier 2 becomes too large, and side surface holding becomes difficult.
  • the maximum outer diameter D1 of the convex portion 51 is preferably 1.01 to 1.2 times (101% to 120%) of the outer diameter D2 of the portion not including the convex portion 51 of the catalyst carrier 2. . This is because the mass of the honeycomb structure becomes too large and is difficult to hold, and the exhaust gas purification device becomes too large, making it difficult to mount and layout the engine.
  • the metal case 3 is a metal member that houses the catalyst carrier 2 and is formed in a substantially cylindrical shape.
  • An upstream end portion 3a of the metal case 3 is connected to, for example, an exhaust manifold EX of an internal combustion engine branched into four.
  • the downstream end 3b of the metal case 3 is narrowed to a small diameter, and is connected to, for example, a silencer (not shown).
  • the metal case 3 is processed into a shape along the surface shape of the coat layer 5 by, for example, spinning.
  • the holding portion 3 c that is a portion corresponding to the convex portion 51 of the coat layer 5 swells in the annular shape along the circumferential direction and radially outwardly in a mountain shape in a cross-sectional view.
  • the upstream portion 3 d on the upstream side of the catalyst carrier 2 is narrowed to substantially the same diameter as the catalyst carrier 2. Thereby, it is possible to suppress the exhaust gas from the exhaust manifold EX from directly entering the gap between the catalyst carrier 2 and the metal case 3.
  • the side surface holding member 4 is a member that prevents the catalyst carrier 2 from moving in the axial direction and the radial direction with respect to the metal case 3, and is formed on the convex portion 51 on the outer peripheral surface of the catalyst carrier 2. Installed in the corresponding range.
  • the side surface holding member 4 also has a function of making it difficult for the heat of the catalyst carrier 2 to be transferred to the metal case 3.
  • the side surface holding member 4 is a wire mesh ring formed by forming metal fibers such as stainless steel into a cylindrical shape, and has elasticity (stretchability).
  • the inner diameter of the side surface holding member 4 is formed to be substantially the same as the outer diameter of the convex portion 51 of the catalyst carrier 2. Further, the thickness dimension of the side surface holding member 4 is preferably about 3 mm to 25 mm.
  • the material of the side surface holding member 4 is not limited to the metal fiber, and for example, one or more kinds of glass fiber, alumina fiber, carbon fiber, polyamide fiber, etc. are appropriately selected and used. Also good.
  • the side surface holding member 4 is formed in a cylindrical shape, but the present invention is not limited to this, and the side surface holding member 4 may be formed in a belt shape and wound around the convex portion 51. Further, by using a stretchable material, the side surface holding member 4 is formed in a cylindrical shape so that the inner diameter is smaller than the outer diameter of the convex portion 51 of the catalyst carrier 2, and the side surface holding member 4 is expanded to expand the catalyst carrier. 2, and the side surface holding member 4 may be fitted to the convex portion 51 exactly.
  • FIG. 3 is an explanatory diagram of a method for forming a convex portion.
  • the material M of the coat layer 5 is sprayed from the spray S while rotating the catalyst carrier 2, so that the coat layer 5 is uniformly formed on the outer peripheral surface of the catalyst carrier 2.
  • the pair of shielding plates W, W are installed in accordance with the width forming the convex portion 51, and the material M of the convex portion 51 that is the same as the coat layer 5 is sprayed between the pair of shielding plates W, W.
  • the convex part 51 will be formed in the center part of the axial direction of the coat layer 5.
  • the position of the top part 52 of the convex part 51 and the gradient of the taper part 53 can be changed by changing the interval between the shielding plates W and W and the position of the spray S.
  • the convex portions 51 formed separately from the same material are bonded and fixed with an adhesive B. May be.
  • attach the convex part 51 after dividing what was formed in the cylindrical shape by the separate part into 2 in an axial direction.
  • an extra coat layer is formed with the bit T. 5 'may be cut and the convex part 51 may be formed. Further, instead of forming the coat layer 5 thick, an unnecessary material may be adhered and cut.
  • the formation method of the convex part 51 is not restricted to these, For example, although illustration is abbreviate
  • the convex portion 51 may be integrally formed.
  • FIG. 4 is an explanatory view of a method for assembling the catalytic converter.
  • the side surface holding member 4 is fitted into the outer peripheral surface of the catalyst carrier 2, and the side surface holding member 4 is disposed at a portion corresponding to the convex portion 51 of the catalyst carrier 2.
  • the side surface holding member 4 has elasticity, the side surface holding member 4 is deformed so as to conform to the surface shape of the convex portion 51.
  • the catalyst carrier 2 and the side surface holding member 4 are inserted into the cylindrical metal case 3.
  • the metal case 3 is rotated with the catalyst carrier 2 and the side surface holding member 4 disposed therein, and the rollers R and R of the spinning machine are moved to the surface of the metal case 3.
  • the roller R is moved in the axial direction while pressing the metal case 3.
  • the diameter of the metal case 3 is reduced in accordance with the surface shape of the coat layer 5 by adjusting the distance between the rollers R and R according to the surface shape of the coat layer 5 (that is, the surface shape of the convex portion 51).
  • the holding part 3c corresponding to the convex part 51 of the coat layer 5 in the metal case 3 is in a state of bulging toward the outer side in the radial direction in a ring shape and in a cross-sectional view along the circumferential direction. Become. Therefore, the convex portion 51 of the catalyst carrier 2 is held immovably in the axial direction and the radial direction by the holding portion 3 c corresponding to the convex portion 51 of the metal case 3 via the side surface holding member 4.
  • rollers R, R of the spinning machine are applied to the upstream portion 3d of the metal case 3 on the upstream side of the catalyst carrier 2, and the metal case 3 is reduced in diameter to approximately the same diameter as the catalyst carrier 2. In this way, the spinning of the metal case 3 completes the assembly of the catalytic converter 1.
  • a convex portion 51 is formed along the circumferential direction on the coat layer 5 covering the outer peripheral surface of the catalyst carrier 2, and the catalyst carrier is interposed via the side surface holding member 4 disposed outside the convex portion 51. Since the position 2 is fixed to the metal case 3, the cross-sectional area of the catalyst carrier 2 does not decrease as in the prior art, and a decrease in exhaust efficiency can be suppressed. Moreover, since the convex part 51 is formed in the coat layer 5, a member intensity
  • the thickness of the side surface holding member 4 can be reduced to increase the surface pressure and increase the holding force. .
  • the catalyst carrier 2 can be held in the axial direction and the radial direction by the side surface holding member 4. Therefore, it is possible to omit an end holding member (not shown) that has been conventionally installed at the upstream and downstream end peripheral edges of the catalyst carrier 2 as necessary, and the thickness of the side holding member 4 can be reduced. Since the number of parts can be reduced, the number of parts can be reduced and the weight can be reduced, and the side surface holding member 4 can be easily attached.
  • the convex part 51 can be formed by thickly coating the coat layer 5, it can respond in the production process of the coat layer 5, and the convex part 51 can be easily formed without complicating the manufacturing work. be able to.
  • the catalyst carrier 2 is placed in the metal case 3 with a predetermined surface pressure while suppressing the displacement of the side surface holding member 4.
  • the metal case 3 can be easily processed so that it can be held.
  • the length L1 of the convex portion 51 in the axial direction of the catalyst carrier 2 is 0.3 to 1.0 times the axial length L2 of the catalyst carrier 2 itself. If D1 is configured to be 1.01 to 1.2 times the outer diameter D2 of the portion not including the convex portion 51 of the catalyst carrier 2, the catalyst carrier 2 is reduced while reducing the area of the side surface holding member 4. It is possible to obtain a sufficient strength that does not affect the cell 21 of the catalyst carrier 2 while having a contact area that can be sufficiently retained and holding the catalyst carrier 2 on the side surface.
  • the plurality of grooves 53a are formed in the circumferential direction on the outer peripheral surface of the convex portion 51, the contact area between the side surface holding member 4 and the convex portion 51 increases, and the frictional force increases. Therefore, the holding force of the catalyst carrier 2 by the side surface holding member 4 can be improved.
  • FIG. 5 is a cross-sectional view of a main part of the catalytic converter according to the second embodiment. Note that the arrow f in FIG. 5 indicates the flow direction of the exhaust gas.
  • the carrier holding structure of the catalytic converter 1 according to the second embodiment is different from the first embodiment described above in that an annular recess 62 is provided on the outer peripheral surface of the protrusion 61 formed in the coat layer 5. ing. That is, in the second embodiment, the holding portion 3c and the side surface holding member 4 which are portions corresponding to the convex portion 61 of the metal case 3 enter the recess 62, thereby holding the catalyst carrier 2 in the axial direction and the radial direction. is doing.
  • the recess 62 is formed in a substantially V shape in cross-sectional view, and the upstream side and the downstream side of the recess 62 relatively constitute projecting portions 63 and 63.
  • the diameter of the metal case 3 is reduced according to the surface shape of the recess 62 and the protrusions 63 and 63 by spinning. Further, the side surface holding member 4 is also deformed so as to conform to the surface shape of the recess 62 and the protrusions 63 and 63 due to the reduced diameter of the metal case 3.
  • the upstream portion 3 d on the upstream side of the catalyst carrier 2 and the downstream portion 3 e on the downstream side are reduced in diameter to approximately the same diameter as the outer diameter of the catalyst carrier 2.
  • the outer peripheral edge on the upstream side and the outer peripheral edge on the downstream side of the catalyst carrier 2 are not in contact with the metal case 3.
  • the metal case 3 and the side surface holding member 4 enter the recess 62 formed in the convex portion 61, the metal case 3 is axially aligned even when the metal case 3 is thermally expanded in the radial direction. And the inclined surface of the recess 62 (or the projecting portions 63 and 63) is pressed radially inward via the side surface holding member 4, so that the holding force of the catalyst carrier 2 by the metal case 3 is increased. The decrease can be suppressed.
  • FIG. 6 is a cross-sectional view of a main part of the catalytic converter according to the third embodiment.
  • the arrow f of FIG. 6 has shown the flow direction of waste gas.
  • the carrier holding structure of the catalytic converter 1 according to the third embodiment includes end holding members 8 and 9 that come into contact with the upstream end 72 and the downstream end 73 of the convex portion 71 formed in the coat layer 5. This is different from the first and second embodiments described above.
  • the outer peripheral surface of the convex part 71 is formed flat, and the side surface holding member 4 is installed in the circumference
  • the length dimension of the convex portion 71 in the axial direction is about 0.3 to 0.9 times the length dimension of the catalyst carrier 2 in the axial direction.
  • end holding members 8 and 9 which are wire mesh rings formed in an annular shape using a metal fiber or the like are installed facing the upstream end 72 and the downstream end 73 of the convex portion 71. .
  • the holding portion 3 c which is a portion corresponding to the convex portion 71 is reduced in diameter by spinning processing in accordance with the surface shape of the convex portion 71.
  • the catalyst carrier 2 is held by the metal case 3 so as not to move in the radial direction via the side surface holding member 4.
  • the upstream portion 3 d on the upstream side of the catalyst carrier 2 and the downstream portion 3 e on the downstream side are reduced in diameter to approximately the same diameter as the outer diameter of the catalyst carrier 2.
  • the outer peripheral edge on the upstream side and the outer peripheral edge on the downstream side of the catalyst carrier 2 are not in contact with the metal case 3.
  • maintenance part 3c and the upstream part 3d among the metal cases 3 is formed so that it may become a small diameter, so that it goes upstream.
  • the inner peripheral surface of the taper portion 3f is in contact with the upstream end of the upstream end holding member 8, and restricts the end holding member 8 and the catalyst carrier 2 from moving upstream.
  • maintenance part 3c and the downstream part 3e among the metal cases 3 is formed so that it may become a small diameter, so that it goes downstream.
  • the inner peripheral surface of the taper portion 3g is in contact with the downstream end of the downstream end holding member 9, and restricts the end holding member 9 and the catalyst carrier 2 from moving downstream.
  • the end holding members 8 and 9 are mounted in addition to the side holding member 4 and are directly fixed by the metal case 3.
  • the side and end portions of the catalyst carrier 2 can be held only by spinning, and workability is improved. Further, since the upstream end and the downstream end of the catalyst carrier 2 are not in contact with the metal case 3 and the end holding members 8 and 9, no load is applied when the catalytic converter 1 vibrates. Therefore, cracking of the catalyst carrier 2 can be prevented.
  • convex portion 51, 61, 71 is formed in a ring shape at the central portion in the axial direction of the coat layer 5 of the catalyst carrier 2, but the present invention is not limited to this.
  • the convex part 51 does not need to be annular.
  • the diameter of the metal case 3 is reduced by spinning, but the present invention is not limited to this.
  • the cylindrical metal case 3 is divided in half in the axial direction to form two halved members, which are pressed according to the surface shape of the coat layer 5 of the catalyst carrier 2.
  • the two half-shaped members may be welded to form the cylindrical metal case 3.
  • the diameter of the metal case 3 may be reduced using a split mold or an integrated mold.
  • the plurality of grooves 53a are formed along the circumferential direction on the surface of the convex portion 51.
  • the present invention is not limited to this, and for example, a granular material is applied to the surface of the tapered portion 53. It is only necessary to roughen the surface of the convex portion 51 and increase the friction with the side surface holding member 4 by a method such as spraying.
  • the catalyst carrier 2 of the catalytic converter 1 has been described as an example of the honeycomb structure in the exhaust gas purifying apparatus.
  • the present invention is not limited to this, for example, a honeycomb as a filter in a DPF. It may be a structure.
  • Catalytic converter exhaust gas purification device
  • Catalyst carrier honeycomb structure
  • Metal Case Side Surface Holding Member 5 Coat Layer 51 Projection

Abstract

Provided is a retention structure of a honeycomb structure in an exhaust gas purification device, wherein the exhaust efficiency is not reduced while a honeycomb structure is mainly retained by a side surface retention member wound around the outer peripheral surface of the honeycomb structure, the honeycomb structure can be prevented from cracking, and the retention structure can be easily produced. The retention structure of a honeycomb structure is provided with a catalyst carrier (2) composed of a honeycomb structure, a metal case (3) within which the catalyst carrier (2) is retained, and a side surface retention member (4) provided between the catalyst carrier (2) and the metal case (3). The catalyst carrier (2) has a plurality of cells (21) and a coat layer (5) which covers the outer peripheral surface of the catalyst carrier (2). A projected portion (51) is formed on at least a part of the coat layer (5) in the circumferential direction, and the catalyst carrier (2) is positioned and secured to the metal case (3) via the side surface retention member (4) disposed on the outside of the projected portion (51).

Description

排ガス浄化装置におけるハニカム構造体の保持構造Holding structure of honeycomb structure in exhaust gas purification device
 本発明は、排ガス浄化装置におけるハニカム構造体の保持構造に関する。 The present invention relates to a honeycomb structure holding structure in an exhaust gas purification apparatus.
 耐熱性を有するハニカム構造体に白金やロジウムなどの触媒を担持させた触媒担体を金属製の筒状ケース内に収容して、流体を浄化するフィルタとした排ガス浄化装置が知られている。例えば、自動車の排気系においては、いわゆる触媒コンバータ(キャタライザ)を排気系路上に設置して、排ガスに含まれる窒素酸化物(NOx)や炭化水素(HC)や一酸化炭素(CO)の浄化を行っている。
 また、他の排ガス浄化装置としては、フィルタとしてのハニカム構造体に排ガスを透過させることで、排ガスに含まれる煤などの粒子状物質(PM)を捕集するDPF(Diesel particulate filter)が知られている。なお、DPFには、ハニカム構造体にさらに白金やロジウムなどの触媒を担持させ、連続再生機能を持たせたものもある。
 ハニカム構造体は、例えばセラミックスで構成されており、破損を防止するために、ハニカム構造体とケースとの間にサポート部材や緩衝部材を設けることが行われている。
2. Description of the Related Art There is known an exhaust gas purifying apparatus in which a catalyst carrier in which a catalyst such as platinum or rhodium is supported on a heat-resistant honeycomb structure is housed in a metal cylindrical case and used as a filter for purifying fluid. For example, in an automobile exhaust system, a so-called catalytic converter (catalyzer) is installed on the exhaust system path to purify nitrogen oxides (NOx), hydrocarbons (HC) and carbon monoxide (CO) contained in the exhaust gas. Is going.
In addition, as another exhaust gas purification device, a DPF (Diesel particulate filter) is known which collects particulate matter (PM) such as soot contained in exhaust gas by allowing the exhaust gas to permeate through a honeycomb structure as a filter. ing. Some DPFs have a continuous regeneration function by further supporting a catalyst such as platinum or rhodium on the honeycomb structure.
The honeycomb structure is made of, for example, ceramics, and a support member and a buffer member are provided between the honeycomb structure and the case in order to prevent breakage.
 従来の排ガス浄化装置は、円筒状のハニカム構造体の外周面とケースの内周面との間に、ハニカム構造体の径方向の移動を規制する側面保持部材(サポート部材)が設けられており、ハニカム構造体の上下流の端部周縁とケースの内周面に設けられた保持枠との間に、ハニカム構造体の軸方向の移動を規制する端部保持部材(緩衝部材)が取り付けられている。 In the conventional exhaust gas purifying apparatus, a side surface holding member (support member) for restricting the radial movement of the honeycomb structure is provided between the outer peripheral surface of the cylindrical honeycomb structure and the inner peripheral surface of the case. An end holding member (buffer member) that restricts the movement of the honeycomb structure in the axial direction is attached between the peripheral edges of the upstream and downstream ends of the honeycomb structure and the holding frame provided on the inner peripheral surface of the case. ing.
 排ガス浄化装置は、内燃機関の運転時の熱によってハニカム構造体の軸方向にケースが膨張するため、ケースとハニカム構造体との間にクリアランスが生じ、内燃機関の振動によってハニカム構造体が軸方向に振動すると、ハニカム構造体の端面あるいは端部保持部材の端面が段付磨耗してしまう。 In the exhaust gas purification device, the case expands in the axial direction of the honeycomb structure due to heat during operation of the internal combustion engine, so that a clearance is generated between the case and the honeycomb structure, and the honeycomb structure is axially moved by vibration of the internal combustion engine. When it vibrates, the end face of the honeycomb structure or the end face of the end portion holding member will be stepped and worn.
 そこで、例えば特許文献1には、段付磨耗を抑制するために、触媒担体(ハニカム構造体)の外周に、周方向に沿って環状溝を形成し、触媒担体を収容する触媒容器に、この環状溝内に突出する環状の凹部を形成し、環状溝の側面と環状の凹部の側面との間に緩衝部材を配置することにより、触媒担体の軸方向への移動を規制した触媒コンバータ(マニホールドコンバータ)が記載されている。 Therefore, for example, in Patent Document 1, in order to suppress step wear, an annular groove is formed along the circumferential direction on the outer periphery of the catalyst carrier (honeycomb structure), and the catalyst container containing the catalyst carrier is provided with this An annular recess projecting into the annular groove is formed, and a buffer member is disposed between the side surface of the annular groove and the side surface of the annular recess, thereby restricting the movement of the catalyst carrier in the axial direction (manifold) Converter).
実開平5-38318号公報(図3)Japanese Utility Model Publication No. 5-38318 (Fig. 3)
 しかし、特許文献1に記載の構造では、ハニカム構造体の外周に周方向に沿って環状溝を形成しているので、環状溝によってハニカム構造体の断面積が減少することで排ガスの流路が絞られ、排気圧が上がって排気効率が低下してしまうという問題がある。
 また、ハニカム構造体は、ハニカム形状又はモノリス形状等の複数のセルからなるセラミックス部材であるため、環状溝を形成する際に割れ等が生じる可能性が高い。
 また、環状溝に緩衝部材を設置する際に、緩衝部材を一旦広げなければならず、製造作業が困難であるとともに、緩衝部材やハニカム構造体が破損するおそれがあった。
However, in the structure described in Patent Document 1, since the annular groove is formed along the circumferential direction on the outer periphery of the honeycomb structure, the cross-sectional area of the honeycomb structure is reduced by the annular groove, so that the flow path of the exhaust gas is reduced. There is a problem that the exhaust efficiency is lowered due to the throttle being reduced.
Further, since the honeycomb structure is a ceramic member composed of a plurality of cells such as a honeycomb shape or a monolith shape, there is a high possibility that a crack or the like is generated when the annular groove is formed.
Further, when installing the buffer member in the annular groove, the buffer member has to be once widened, which makes it difficult to manufacture and damages the buffer member and the honeycomb structure.
 本発明は、これらの点に鑑みて成されたものであり、ハニカム構造体の外周面に巻いた側面保持部材による保持をメイン保持としつつ、排気効率を低下させることがなく、ハニカム構造体の割れ等を抑制可能であり、製造作業の容易な排ガス浄化装置におけるハニカム構造体の保持構造を提供することを課題とする。 The present invention has been made in view of these points. The main structure is the holding by the side surface holding member wound around the outer peripheral surface of the honeycomb structure, and the exhaust efficiency is not reduced. It is an object of the present invention to provide a honeycomb structure holding structure in an exhaust gas purification apparatus that can suppress cracking and the like and can be easily manufactured.
 本発明は、排気通路に配置される排ガス浄化装置におけるハニカム構造体の保持構造であって、複数のセルを有するとともに、外周面をコート層で覆われたハニカム構造体と、前記ハニカム構造体を内部に保持する金属ケースと、前記ハニカム構造体と前記金属ケースとの間に介在する側面保持部材と、を備え、前記ハニカム構造体は、複数のセルを有するとともに、前記ハニカム構造体の外周面を覆うコート層を有し、前記コート層には、周方向に沿って少なくとも一部に凸部が形成されており、前記ハニカム構造体は、前記凸部の外側に配置された前記側面保持部材を介して、前記金属ケースに位置固定されることを特徴とする。 The present invention is a honeycomb structure holding structure in an exhaust gas purification apparatus disposed in an exhaust passage, and has a plurality of cells and an outer peripheral surface covered with a coating layer, and the honeycomb structure. A metal case held inside, and a side surface holding member interposed between the honeycomb structure and the metal case, the honeycomb structure having a plurality of cells and an outer peripheral surface of the honeycomb structure The side surface holding member disposed on the outside of the convex portion, wherein the coat layer has a convex portion formed at least partially along a circumferential direction. It is characterized by being fixed to the metal case via
 かかる構成によれば、ハニカム構造体の外周面を覆うコート層に、周方向に沿って凸部が形成されており、凸部の外側に配置された側面保持部材を介してハニカム構造体が金属ケースに位置固定されているので、環状溝を形成する場合のようにハニカム構造体の断面積が減少することがなく、排気効率の低下を抑制することができる。また、コート層に凸部が形成されるので、環状溝を形成する場合のように部材強度が低下することがなく、ハニカム構造体の割れ等を防止することができる。
 また、凸部を有するコート層により十分な強度を得ることができるため、側面保持部材の厚さを減少させて面圧を高め、側面保持部材によってハニカム構造体を軸方向及び径方向に保持することができる。そのため、従来、ハニカム構造体の上下流の端部周縁に設置されていた端部保持部材を省略することが可能となり、かつ、側面保持部材の厚さを減少させることが可能となるので、側面保持部材の取り付けが容易になる。
According to this configuration, the coat layer covering the outer peripheral surface of the honeycomb structure has the convex portions formed along the circumferential direction, and the honeycomb structure is made of metal via the side surface holding member disposed outside the convex portions. Since the position is fixed to the case, the cross-sectional area of the honeycomb structure does not decrease as in the case of forming the annular groove, and the reduction in exhaust efficiency can be suppressed. In addition, since the convex portions are formed in the coat layer, the member strength is not lowered as in the case of forming the annular groove, and cracking of the honeycomb structure can be prevented.
In addition, since a sufficient strength can be obtained by the coat layer having the convex portion, the thickness of the side surface holding member is reduced to increase the surface pressure, and the honeycomb structure is held in the axial direction and the radial direction by the side surface holding member. be able to. Therefore, conventionally, it is possible to omit the end holding member that has been installed on the peripheral edge of the upstream and downstream ends of the honeycomb structure, and it is possible to reduce the thickness of the side holding member. Mounting of the holding member is facilitated.
 また、前記凸部は、前記コート層を他の部分よりも厚くして構成したものであり、前記コート層は、セラミックスを主成分として、アルミナ、ムライト、リチウムアルミニウムシリケート、炭化ケイ素、窒化ケイ素、アルミナチタネート、コーディエライト、からなる群から選択される少なくとも1種を含む材料から成るのが好ましい。 Further, the convex portion is configured by making the coat layer thicker than other portions, and the coat layer is mainly composed of ceramics, alumina, mullite, lithium aluminum silicate, silicon carbide, silicon nitride, It is preferably made of a material containing at least one selected from the group consisting of alumina titanate and cordierite.
 かかる構成によれば、コート層を厚塗りすることで凸部を形成しているので、コート層の作製工程で対応することができ、製造作業が複雑化することがなく、凸部を容易に形成することができる。 According to such a configuration, since the convex portion is formed by thickly coating the coat layer, it can be handled in the coating layer manufacturing process, and the convex portion can be easily formed without complicating the manufacturing work. Can be formed.
 また、前記金属ケースは、前記凸部の表面形状に合わせて縮径加工により縮径され、前記側面保持部材を所定圧力で固定保持しているのが好ましい。 Further, it is preferable that the metal case is reduced in diameter by a diameter reduction process in accordance with the surface shape of the convex portion, and the side surface holding member is fixedly held at a predetermined pressure.
 かかる構成によれば、例えばスピニング加工などの縮径加工により縮径するので、側面保持部材の位置ずれを抑制しつつハニカム構造体を所定の面圧で金属ケース内に保持できるように、金属ケースを容易に加工することができる。 According to such a configuration, since the diameter is reduced by, for example, a diameter reduction process such as spinning, the metal case is configured so that the honeycomb structure can be held in the metal case with a predetermined surface pressure while suppressing the displacement of the side surface holding member. Can be easily processed.
 また、前記凸部の前記ハニカム構造体の軸方向の長さ寸法は、前記ハニカム構造体自体の軸方向の長さ寸法の0.3倍乃至1.0倍であり、前記凸部の外径は、前記ハニカム構造体の前記凸部を含まない部分の外径の1.01倍乃至1.2倍であるのが好ましい。 Further, the axial length dimension of the convex portion of the honeycomb structure is 0.3 to 1.0 times the axial length dimension of the honeycomb structure itself, and the outer diameter of the convex portion. Is preferably 1.01 to 1.2 times the outer diameter of the portion of the honeycomb structure not including the convex portion.
 かかる構成によれば、側面保持部材の面積を削減しつつハニカム構造体を十分に保持できるだけの接触面積を有し、かつ、側面でハニカム構造体を保持しつつもハニカム構造体のセル構造に影響を及ぼさない十分な強度を得ることができる。 According to such a configuration, the contact area is sufficient to hold the honeycomb structure sufficiently while reducing the area of the side surface holding member, and the cell structure of the honeycomb structure is affected while holding the honeycomb structure on the side surface. Sufficient strength can be obtained.
 また、本発明は、前記コート層で形成された前記凸部の一部を窪ませて窪部をさらに形成し、前記窪部を含む前記ハニカム構造体の凸部の外周面に前記側面保持部材を取り付け、さらに、前記窪部を含む前記凸部の表面形状に合わせて前記金属ケースを縮径させた構成とするのが好ましい。 Further, in the present invention, the side surface holding member is formed on an outer peripheral surface of the convex portion of the honeycomb structure including the concave portion by further forming a concave portion by recessing a part of the convex portion formed by the coat layer. In addition, it is preferable that the diameter of the metal case is reduced in accordance with the surface shape of the convex portion including the recess.
 かかる構成によれば、凸部にさらに窪部を形成することで、金属ケースが径方向に熱膨張した際にも、窪部内に入り込むように形成された金属ケースが軸方向にも熱膨張することで、凸部を押圧するため、確実にハニカム構造体を金属ケースで保持することができる。 According to this configuration, by forming a recess in the convex portion, the metal case formed so as to enter the recess also thermally expands in the axial direction even when the metal case thermally expands in the radial direction. Thus, since the convex portion is pressed, the honeycomb structure can be reliably held by the metal case.
 また、本発明は、前記コート層で形成された前記凸部の表面に、軸方向に互いに間隔を隔てて複数の突出部をさらに形成し、前記複数の突出部を含む前記ハニカム構造体の凸部の外周面に前記側面保持部材を取り付け、さらに前記突出部を含む前記凸部の表面形状に合わせて前記金属ケースを縮径させた構成とするのが好ましい。 In the present invention, a plurality of protrusions are further formed on the surface of the protrusions formed of the coating layer at intervals in the axial direction, and the protrusions of the honeycomb structure including the plurality of protrusions are formed. It is preferable that the side surface holding member is attached to the outer peripheral surface of the portion, and the diameter of the metal case is reduced in accordance with the surface shape of the convex portion including the protruding portion.
 かかる構成によれば、凸部の表面にさらに複数の突出部を形成することで、金属ケースが径方向に熱膨張した際にも、突出部の間に嵌入した金属ケースが軸方向にも熱膨張することで、突出部の外周面に配置されている側面保持部材に金属ケースが強く噛み合うため、ハニカム構造体に加わる振動を抑制し、安定して保持することができる。 According to this configuration, by forming a plurality of protrusions on the surface of the protrusion, even when the metal case is thermally expanded in the radial direction, the metal case fitted between the protrusions is also heated in the axial direction. By expanding, the metal case strongly meshes with the side surface holding member disposed on the outer peripheral surface of the protruding portion, so that vibration applied to the honeycomb structure can be suppressed and stably held.
 また、本発明は、前記コート層で形成された前記凸部の上流側端部及び下流側端部に面する位置に、前記ハニカム構造体の軸方向への移動を規制する端部保持部材を配設し、前記端部保持部材の上流側端部及び下流側端部に軸方向に所定圧力を付与するようにスピニング加工によって前記金属ケースを縮径した構成とするのが好ましい。 Further, the present invention provides an end holding member that restricts the movement of the honeycomb structure in the axial direction at a position facing the upstream end and the downstream end of the convex portion formed of the coat layer. Preferably, the metal case is reduced in diameter by spinning so as to apply a predetermined pressure in the axial direction to the upstream end and the downstream end of the end holding member.
 かかる構成によれば、側面保持部材に加えて端部保持部材を装着し、かつ、これらを金属ケースで直接固定するようにしたので、スピニング加工のみでハニカム構造体の側面及び端部の保持が可能となり、作業性が向上する。 According to such a configuration, since the end holding member is mounted in addition to the side holding member, and these are directly fixed by the metal case, the side and end of the honeycomb structure can be held only by spinning. This makes it possible to improve workability.
 また、本発明は、前記凸部の外周面に、複数の溝が形成されているのが好ましい。 In the present invention, it is preferable that a plurality of grooves are formed on the outer peripheral surface of the convex portion.
 かかる構成によれば、凸部の外周面に、複数の溝が形成されているので、側面保持部材と凸部との接触面積が多くなり、摩擦力が上昇する。そのため、側面保持部材によるハニカム構造体の保持力を向上させることができる。 According to such a configuration, since a plurality of grooves are formed on the outer peripheral surface of the convex portion, the contact area between the side surface holding member and the convex portion increases, and the frictional force increases. Therefore, the retention strength of the honeycomb structure by the side surface holding member can be improved.
 本発明によれば、ハニカム構造体の外周面に巻いた側面保持部材による保持をメイン保持としつつ、排気効率を低下させることがなく、ハニカム構造体の割れ等を抑制可能であり、製造作業の容易な触媒コンバータの担体保持構造を提供することができる。 According to the present invention, the holding by the side surface holding member wound around the outer peripheral surface of the honeycomb structure is set as the main holding, and the cracking of the honeycomb structure can be suppressed without lowering the exhaust efficiency, and the manufacturing work can be suppressed. An easy carrier support structure for a catalytic converter can be provided.
第1実施形態に係る触媒コンバータの断面図である。It is sectional drawing of the catalytic converter which concerns on 1st Embodiment. 触媒担体の斜視図である。It is a perspective view of a catalyst carrier. 凸部の形成方法の説明図である。It is explanatory drawing of the formation method of a convex part. 触媒コンバータの組立方法の説明図である。It is explanatory drawing of the assembly method of a catalytic converter. 第2実施形態に係る触媒コンバータの要部断面図である。It is principal part sectional drawing of the catalytic converter which concerns on 2nd Embodiment. 第3実施形態に係る触媒コンバータの要部断面図である。It is principal part sectional drawing of the catalytic converter which concerns on 3rd Embodiment.
 本発明の第1実施形態について、図面を参照して詳細に説明する。説明において、同一の要素には同一の番号を付し、重複する説明は省略する。なお、本実施形態において方向を説明する場合は、図1、図2に矢印で示す径方向rと軸方向aに基づいて説明する。 The first embodiment of the present invention will be described in detail with reference to the drawings. In the description, the same elements are denoted by the same reference numerals, and redundant description is omitted. In addition, when describing a direction in this embodiment, it demonstrates based on the radial direction r and the axial direction a which are shown by the arrow in FIG. 1, FIG.
 図1に示すように、第1実施形態に係るハニカム構造体の保持構造が適用される触媒コンバータ1は、例えば自動車の排気経路上に設置され、排ガスに含まれる有害物質を浄化する浄化装置である。触媒コンバータ1は、触媒を担持する触媒担体2と、この触媒担体2を収容する金属ケース3と、触媒担体2と金属ケース3との間に設置される側面保持部材4と、を備えている。 As shown in FIG. 1, a catalytic converter 1 to which the honeycomb structure holding structure according to the first embodiment is applied is a purification device that is installed on, for example, an exhaust path of an automobile and purifies harmful substances contained in exhaust gas. is there. The catalytic converter 1 includes a catalyst carrier 2 that supports a catalyst, a metal case 3 that houses the catalyst carrier 2, and a side surface holding member 4 that is installed between the catalyst carrier 2 and the metal case 3. .
 図1、図2に示すように、触媒担体2は、例えば円筒形状に形成されたセラミックス製のハニカム構造体の表面にアルミナをコーティングして形成されている。アルミナのコーティング層には、白金、パラジウム、ロジウム等の三元触媒が含有されている。
 触媒担体2は、排ガスが通流するための複数のセル21を有している。セル21は、中空の通路であり、例えば断面視で四角形状に形成されている。このセル21の表面に前記した三元触媒がコーティングされている。セル21は、流入側及び流出側の端部のいずれかが目封じされており、流入側が目封じされたセル21と流出側が目封じされたセル21とが交互に配置されている。
 触媒担体2は、排ガス中の窒素酸化物(NOx)や炭化水素(HC)や一酸化炭素(CO)が三元触媒に接触することで酸化還元反応が生じ高温になるが、セラミックスで構成されているため耐熱性が高く、また、ハニカム構造であるため排ガスとの接触面積が広く、浄化能力が高い。
 触媒担体2は、ハニカム構造体の軸方向を排ガスの流通方向に向けて、排気経路上に設置されている。
 なお、触媒担体2の断面形状は、円形状に限定されるものではなく、楕円状や多角形状に形成してもよい。
As shown in FIGS. 1 and 2, the catalyst carrier 2 is formed by coating alumina on the surface of a ceramic honeycomb structure formed in a cylindrical shape, for example. The alumina coating layer contains a three-way catalyst such as platinum, palladium, or rhodium.
The catalyst carrier 2 has a plurality of cells 21 through which exhaust gas flows. The cell 21 is a hollow passage and is formed, for example, in a quadrangular shape in a cross-sectional view. The surface of the cell 21 is coated with the above-described three-way catalyst. The cell 21 is sealed at either the inflow side or the outflow side end, and the cells 21 with the inflow side sealed and the cells 21 with the outflow side sealed are alternately arranged.
The catalyst carrier 2 is made of ceramics, although nitrogen oxides (NOx), hydrocarbons (HC), and carbon monoxide (CO) in the exhaust gas come into contact with the three-way catalyst to cause a redox reaction and become high temperature. Therefore, the heat resistance is high, and since the honeycomb structure is used, the contact area with the exhaust gas is wide and the purification ability is high.
The catalyst carrier 2 is installed on the exhaust path with the axial direction of the honeycomb structure oriented in the flow direction of the exhaust gas.
The cross-sectional shape of the catalyst carrier 2 is not limited to a circular shape, and may be formed in an elliptical shape or a polygonal shape.
 触媒担体2の外周面には、コート層5が形成されている。コート層5は、セラミックスを主成分として構成されており、例えばアルミナ、ムライト、リチウムアルミニウムシリケート、炭化ケイ素(SiC)、窒化ケイ素、アルミナチタネート(AT)、コーディエライト等からなる群から選択される1種あるいは2種を含む材料で構成されている。コート層5の後記する平坦部5a,5bの厚さ寸法は、5mm程度とするのが好ましい。 A coat layer 5 is formed on the outer peripheral surface of the catalyst carrier 2. The coat layer 5 is composed mainly of ceramics, and is selected from the group consisting of alumina, mullite, lithium aluminum silicate, silicon carbide (SiC), silicon nitride, alumina titanate (AT), cordierite, and the like. It is comprised with the material containing 1 type or 2 types. The thickness dimension of the flat portions 5a and 5b described later of the coat layer 5 is preferably about 5 mm.
 図2に示すように、コート層5は、平坦に形成された上流側及び下流側の平坦部5a、5bと、軸方向の中央部に触媒担体2の周方向に沿って環状に形成された凸部51と、を有している。凸部51は、平坦部5a、5bよりもコート層5の厚さを大きくすることで形成されている。凸部51を形成する方法については、後に詳しく説明する。 As shown in FIG. 2, the coat layer 5 is formed in an annular shape along the circumferential direction of the catalyst carrier 2 at the flat portions 5 a and 5 b on the upstream side and the downstream side that are formed flat and in the center portion in the axial direction. And a convex portion 51. The convex part 51 is formed by making the thickness of the coat layer 5 larger than the flat parts 5a and 5b. A method for forming the convex portion 51 will be described in detail later.
 凸部51は、軸方向の中央部が最も高い頂部52となる山形状に形成されている。頂部52の上流側及び下流側には、頂部52から離れるほど縮径するテーパ部53,53が形成されている。
 テーパ部53,53の表面には、例えば周方向に沿って複数の溝53a,53a…が形成されているのが好ましい。
The convex portion 51 is formed in a mountain shape in which the central portion in the axial direction is the highest apex 52. On the upstream side and the downstream side of the top portion 52, taper portions 53 and 53 that are reduced in diameter as they are separated from the top portion 52 are formed.
It is preferable that a plurality of grooves 53a, 53a... Are formed on the surfaces of the tapered portions 53, 53, for example, along the circumferential direction.
 凸部51の触媒担体2の軸方向の長さ寸法L1は、触媒担体2の軸方向の長さ寸法L2の0.3倍乃至1.0倍(30%以上100%以下)とするのが好ましい。0.3倍よりも小さくすると、十分な保持面積が得られなくなり、1.0倍よりも大きくすると、触媒担体2の重量が大きくなりすぎ、側面保持が困難となるからである。
 また、凸部51の最大外径D1は、触媒担体2の凸部51を含まない部分の外径D2の1.01倍乃至1.2倍(101%以上120%以下)とするのが好ましい。ハニカム構造体の質量が大きくなり過ぎ保持が困難になること、及び、排ガス浄化装置が大きくなり過ぎ、機関の搭載性やレイアウトが困難になるからである。
The length L1 of the convex portion 51 in the axial direction of the catalyst carrier 2 is 0.3 to 1.0 times (30% or more and 100% or less) of the length L2 of the catalyst carrier 2 in the axial direction. preferable. If it is smaller than 0.3 times, a sufficient holding area cannot be obtained, and if it is larger than 1.0 times, the weight of the catalyst carrier 2 becomes too large, and side surface holding becomes difficult.
The maximum outer diameter D1 of the convex portion 51 is preferably 1.01 to 1.2 times (101% to 120%) of the outer diameter D2 of the portion not including the convex portion 51 of the catalyst carrier 2. . This is because the mass of the honeycomb structure becomes too large and is difficult to hold, and the exhaust gas purification device becomes too large, making it difficult to mount and layout the engine.
 金属ケース3は、触媒担体2を内部に収容する金属製部材であり、略円筒形状に形成されている。金属ケース3の上流側の端部3aは、例えば4つに分岐された内燃機関のエキゾーストマニホールドEXに接続されている。また、金属ケース3の下流側の端部3bは、細径に絞られており、例えばサイレンサー(図示省略)等に接続されている。 The metal case 3 is a metal member that houses the catalyst carrier 2 and is formed in a substantially cylindrical shape. An upstream end portion 3a of the metal case 3 is connected to, for example, an exhaust manifold EX of an internal combustion engine branched into four. Moreover, the downstream end 3b of the metal case 3 is narrowed to a small diameter, and is connected to, for example, a silencer (not shown).
 図1に示すように、金属ケース3は、例えばスピニング加工によって、コート層5の表面形状に沿う形状に加工されている。例えば、金属ケース3のうち、コート層5の凸部51に対応する部分である保持部3cは、周方向に沿って環状に、且つ、断面視で山形状に径方向外側に向かって膨らんでいる。また、金属ケース3のうち、触媒担体2よりも上流側の上流部3dは、触媒担体2と略同径に絞られている。これにより、エキゾーストマニホールドEXからの排ガスが、触媒担体2と金属ケース3との間の隙間に直接入ることを抑制することができる。 As shown in FIG. 1, the metal case 3 is processed into a shape along the surface shape of the coat layer 5 by, for example, spinning. For example, in the metal case 3, the holding portion 3 c that is a portion corresponding to the convex portion 51 of the coat layer 5 swells in the annular shape along the circumferential direction and radially outwardly in a mountain shape in a cross-sectional view. Yes. In the metal case 3, the upstream portion 3 d on the upstream side of the catalyst carrier 2 is narrowed to substantially the same diameter as the catalyst carrier 2. Thereby, it is possible to suppress the exhaust gas from the exhaust manifold EX from directly entering the gap between the catalyst carrier 2 and the metal case 3.
 図1に示すように、側面保持部材4は、触媒担体2が金属ケース3に対して軸方向及び径方向に移動するのを防止する部材であり、触媒担体2の外周面の凸部51に対応する範囲に取り付けられている。また、側面保持部材4は、触媒担体2の熱を金属ケース3に伝わり難くする機能も有している。
 側面保持部材4は、例えばステンレス材などの金属繊維を円筒状に成形してなるワイヤメッシュリングであり、弾性(伸縮性)を有している。
 側面保持部材4の内径は、触媒担体2の凸部51の外径と略同径に形成されている。また、側面保持部材4の厚さ寸法は、3mm乃至25mm程度とするのが好ましい。
As shown in FIG. 1, the side surface holding member 4 is a member that prevents the catalyst carrier 2 from moving in the axial direction and the radial direction with respect to the metal case 3, and is formed on the convex portion 51 on the outer peripheral surface of the catalyst carrier 2. Installed in the corresponding range. The side surface holding member 4 also has a function of making it difficult for the heat of the catalyst carrier 2 to be transferred to the metal case 3.
The side surface holding member 4 is a wire mesh ring formed by forming metal fibers such as stainless steel into a cylindrical shape, and has elasticity (stretchability).
The inner diameter of the side surface holding member 4 is formed to be substantially the same as the outer diameter of the convex portion 51 of the catalyst carrier 2. Further, the thickness dimension of the side surface holding member 4 is preferably about 3 mm to 25 mm.
 なお、側面保持部材4の材料は、金属繊維に限定されるものではなく、例えば、ガラス繊維、アルミナ繊維、カーボン繊維、ポリアミド繊維などの中から1種あるいは複数種を適宜選択して使用してもよい。
 また、本実施形態では、側面保持部材4を円筒状に形成したが、これに限定されるものではなく、側面保持部材4を帯状に形成して凸部51に巻き付けるようにしてもよい。また、伸縮性のある材料を用いて、触媒担体2の凸部51の外径よりも内径が小さくなるように側面保持部材4を円筒状に形成し、側面保持部材4を押し広げて触媒担体2に嵌め込み、側面保持部材4を凸部51にぴったりとフィットさせるようにしてもよい。
The material of the side surface holding member 4 is not limited to the metal fiber, and for example, one or more kinds of glass fiber, alumina fiber, carbon fiber, polyamide fiber, etc. are appropriately selected and used. Also good.
In the present embodiment, the side surface holding member 4 is formed in a cylindrical shape, but the present invention is not limited to this, and the side surface holding member 4 may be formed in a belt shape and wound around the convex portion 51. Further, by using a stretchable material, the side surface holding member 4 is formed in a cylindrical shape so that the inner diameter is smaller than the outer diameter of the convex portion 51 of the catalyst carrier 2, and the side surface holding member 4 is expanded to expand the catalyst carrier. 2, and the side surface holding member 4 may be fitted to the convex portion 51 exactly.
 次に、図3を参照して凸部51の形成方法について説明する。図3は、凸部の形成方法の説明図である。
 図3(a)に示すように、触媒担体2を回転させながらスプレーSからコート層5の材料Mを噴射して、触媒担体2の外周面にコート層5を均一に形成する。
 その後、一対の遮蔽板W,Wを、凸部51を形成する幅に合わせて設置し、一対の遮蔽板W,Wの間にコート層5と同じ凸部51の材料Mを噴射する。これにより、コート層5の軸方向の中央部に凸部51が形成されることとなる。なお、遮蔽板W,Wの間隔や、スプレーSの位置を変化させることで、凸部51の頂部52の位置やテーパ部53の勾配を変化させることができる。
Next, a method for forming the convex portion 51 will be described with reference to FIG. FIG. 3 is an explanatory diagram of a method for forming a convex portion.
As shown in FIG. 3A, the material M of the coat layer 5 is sprayed from the spray S while rotating the catalyst carrier 2, so that the coat layer 5 is uniformly formed on the outer peripheral surface of the catalyst carrier 2.
Thereafter, the pair of shielding plates W, W are installed in accordance with the width forming the convex portion 51, and the material M of the convex portion 51 that is the same as the coat layer 5 is sprayed between the pair of shielding plates W, W. Thereby, the convex part 51 will be formed in the center part of the axial direction of the coat layer 5. FIG. In addition, the position of the top part 52 of the convex part 51 and the gradient of the taper part 53 can be changed by changing the interval between the shielding plates W and W and the position of the spray S.
 また、図3(b)に示すように、触媒担体2の外周面に均一な厚さでコート層5を形成した後に、同一材料で別体に形成した凸部51を接着剤Bで接着固定してもよい。なお、凸部51は、別体で円筒状に形成したものを軸方向に2分割してから接着するようにすればよい。
 また、図3(c)に示すように、触媒担体2の外周面に均一な厚さでコート層5を凸部51の厚さに等しくなるように形成した後に、ビットTで余分なコート層5’を切削し、凸部51を形成してもよい。また、コート層5を厚く形成する代わりに、不要材料を接着しておいてそれを切削加工するようにしてもよい。
Further, as shown in FIG. 3 (b), after the coat layer 5 is formed with a uniform thickness on the outer peripheral surface of the catalyst carrier 2, the convex portions 51 formed separately from the same material are bonded and fixed with an adhesive B. May be. In addition, what is necessary is just to adhere | attach the convex part 51, after dividing what was formed in the cylindrical shape by the separate part into 2 in an axial direction.
Further, as shown in FIG. 3C, after the coat layer 5 is formed on the outer peripheral surface of the catalyst carrier 2 with a uniform thickness so as to be equal to the thickness of the convex portion 51, an extra coat layer is formed with the bit T. 5 'may be cut and the convex part 51 may be formed. Further, instead of forming the coat layer 5 thick, an unnecessary material may be adhered and cut.
 なお、凸部51の形成方法は、これらに限られるものではなく、例えば、図示は省略するが、図3(a)の遮蔽板W,Wに替えて、平坦部5a,5b(図2参照)にテープ等でマスキングを施し、凸部51を形成した後にテープに付着した不要なコート層をマスキングごと剥がすようにしてもよい。また、凸部51を含むコート層5の表面形状をかたどった型枠を作製し、型枠内に設置した触媒担体2と型枠との間にコート層5の材料を充填してコート層5と凸部51を一体成形してもよい。 In addition, the formation method of the convex part 51 is not restricted to these, For example, although illustration is abbreviate | omitted, it replaces with the shielding plates W and W of Fig.3 (a), flat part 5a, 5b (refer FIG. 2). ) May be masked with a tape or the like, and after forming the convex portion 51, an unnecessary coating layer attached to the tape may be peeled off together with the masking. Further, a mold having a surface shape of the coat layer 5 including the convex portion 51 is produced, and the material of the coat layer 5 is filled between the catalyst carrier 2 and the mold placed in the mold, and the coat layer 5 is formed. The convex portion 51 may be integrally formed.
 つづいて、図4を参照して触媒コンバータ1の組立方法について説明する。図4は、触媒コンバータの組立方法の説明図である。
 図4(a)に示すように、まず、触媒担体2の外周面に側面保持部材4を嵌め入れ、触媒担体2の凸部51に対応する部分に側面保持部材4を配置する。このとき、側面保持部材4は、弾性を有しているので、凸部51の表面形状に馴染むように変形する。
 そして、円筒状の金属ケース3の内部に、触媒担体2と側面保持部材4とを挿入する。
Next, an assembly method of the catalytic converter 1 will be described with reference to FIG. FIG. 4 is an explanatory view of a method for assembling the catalytic converter.
As shown in FIG. 4A, first, the side surface holding member 4 is fitted into the outer peripheral surface of the catalyst carrier 2, and the side surface holding member 4 is disposed at a portion corresponding to the convex portion 51 of the catalyst carrier 2. At this time, since the side surface holding member 4 has elasticity, the side surface holding member 4 is deformed so as to conform to the surface shape of the convex portion 51.
Then, the catalyst carrier 2 and the side surface holding member 4 are inserted into the cylindrical metal case 3.
 次に、図4(b)に示すように、触媒担体2と側面保持部材4とを内部に配置した状態で金属ケース3を回転させ、スピニング加工機のローラR,Rを金属ケース3の表面にあてがい、金属ケース3を押圧しながらローラR,Rを軸方向に移動させる。そして、コート層5の表面形状(すなわち凸部51の表面形状)に合わせて、ローラR,Rの間隔を調節することにより、コート層5の表面形状に合わせて金属ケース3を縮径させる。
 これにより、金属ケース3のうち、コート層5の凸部51に対応する保持部3cが、周方向に沿って環状に、且つ、断面視で山形状に径方向外側に向かって膨らんだ状態となる。そのため、触媒担体2の凸部51が、側面保持部材4を介して、金属ケース3の凸部51に対応する保持部3cに、軸方向及び径方向に移動不能に保持されることとなる。
Next, as shown in FIG. 4B, the metal case 3 is rotated with the catalyst carrier 2 and the side surface holding member 4 disposed therein, and the rollers R and R of the spinning machine are moved to the surface of the metal case 3. The roller R is moved in the axial direction while pressing the metal case 3. Then, the diameter of the metal case 3 is reduced in accordance with the surface shape of the coat layer 5 by adjusting the distance between the rollers R and R according to the surface shape of the coat layer 5 (that is, the surface shape of the convex portion 51).
Thereby, the holding part 3c corresponding to the convex part 51 of the coat layer 5 in the metal case 3 is in a state of bulging toward the outer side in the radial direction in a ring shape and in a cross-sectional view along the circumferential direction. Become. Therefore, the convex portion 51 of the catalyst carrier 2 is held immovably in the axial direction and the radial direction by the holding portion 3 c corresponding to the convex portion 51 of the metal case 3 via the side surface holding member 4.
 次に、スピニング加工機のローラR,Rを、金属ケース3のうち触媒担体2よりも上流側にある上流部3dにあてがい、金属ケース3を触媒担体2と略同径に縮径させる。このようにして、金属ケース3にスピニング加工を施すことにより、触媒コンバータ1の組立が完成する。 Next, the rollers R, R of the spinning machine are applied to the upstream portion 3d of the metal case 3 on the upstream side of the catalyst carrier 2, and the metal case 3 is reduced in diameter to approximately the same diameter as the catalyst carrier 2. In this way, the spinning of the metal case 3 completes the assembly of the catalytic converter 1.
 以上のように構成された触媒コンバータ1の担体保持構造によれば、次のような作用効果を奏する。
 触媒コンバータ1は、触媒担体2の外周面を覆うコート層5に、周方向に沿って凸部51が形成されており、凸部51の外側に配置された側面保持部材4を介して触媒担体2が金属ケース3に位置固定されているので、従来のように触媒担体2の断面積が減少することがなく、排気効率の低下を抑制することができる。また、コート層5に凸部51が形成されるので、従来のように部材強度が低下することがなく、触媒担体2の割れ等を防止することができる。
According to the carrier holding structure of the catalytic converter 1 configured as described above, the following operational effects can be obtained.
In the catalytic converter 1, a convex portion 51 is formed along the circumferential direction on the coat layer 5 covering the outer peripheral surface of the catalyst carrier 2, and the catalyst carrier is interposed via the side surface holding member 4 disposed outside the convex portion 51. Since the position 2 is fixed to the metal case 3, the cross-sectional area of the catalyst carrier 2 does not decrease as in the prior art, and a decrease in exhaust efficiency can be suppressed. Moreover, since the convex part 51 is formed in the coat layer 5, a member intensity | strength does not fall like the past, and the crack of the catalyst carrier 2, etc. can be prevented.
 また、凸部51を形成することでコート層5が厚くなり、触媒担体2の強度が向上するため、側面保持部材4の厚さを減少させて面圧を高め保持力を大きくすることができる。これにより、側面保持部材4によって触媒担体2を軸方向及び径方向に保持することができる。そのため、従来、触媒担体2の上下流の端部周縁に設置されていた端部保持部材(図示せず)を必要に応じて省略することが可能となり、かつ、側面保持部材4の厚さを減少させることが可能となるので、部品点数の削減及び軽量化が図られ、また、側面保持部材4の取り付けが容易になる。 Moreover, since the coat layer 5 is thickened by forming the convex portions 51 and the strength of the catalyst carrier 2 is improved, the thickness of the side surface holding member 4 can be reduced to increase the surface pressure and increase the holding force. . Thereby, the catalyst carrier 2 can be held in the axial direction and the radial direction by the side surface holding member 4. Therefore, it is possible to omit an end holding member (not shown) that has been conventionally installed at the upstream and downstream end peripheral edges of the catalyst carrier 2 as necessary, and the thickness of the side holding member 4 can be reduced. Since the number of parts can be reduced, the number of parts can be reduced and the weight can be reduced, and the side surface holding member 4 can be easily attached.
 また、コート層5を厚塗りすることで凸部51を形成できるので、コート層5の作製工程で対応することができ、製造作業が複雑化することがなく、凸部51を容易に形成することができる。 Moreover, since the convex part 51 can be formed by thickly coating the coat layer 5, it can respond in the production process of the coat layer 5, and the convex part 51 can be easily formed without complicating the manufacturing work. be able to.
 また、金属ケース3は、凸部51の表面形状に合わせてスピニング加工により縮径されているので、側面保持部材4の位置ずれを抑制しつつ触媒担体2を所定の面圧で金属ケース3内に保持できるように、金属ケース3を容易に加工することができる。 Further, since the diameter of the metal case 3 is reduced by spinning processing in accordance with the surface shape of the convex portion 51, the catalyst carrier 2 is placed in the metal case 3 with a predetermined surface pressure while suppressing the displacement of the side surface holding member 4. The metal case 3 can be easily processed so that it can be held.
 また、凸部51の触媒担体2の軸方向の長さ寸法L1は、触媒担体2自体の軸方向の長さ寸法L2の0.3倍乃至1.0倍であり、凸部51の外径D1は、触媒担体2の凸部51を含まない部分の外径D2の1.01倍乃至1.2倍となるように構成すれば、側面保持部材4の面積を削減しつつ触媒担体2を十分に保持できるだけの接触面積を有し、かつ、側面で触媒担体2を保持しつつも触媒担体2のセル21に影響を及ぼさない十分な強度を得ることができる。 Further, the length L1 of the convex portion 51 in the axial direction of the catalyst carrier 2 is 0.3 to 1.0 times the axial length L2 of the catalyst carrier 2 itself. If D1 is configured to be 1.01 to 1.2 times the outer diameter D2 of the portion not including the convex portion 51 of the catalyst carrier 2, the catalyst carrier 2 is reduced while reducing the area of the side surface holding member 4. It is possible to obtain a sufficient strength that does not affect the cell 21 of the catalyst carrier 2 while having a contact area that can be sufficiently retained and holding the catalyst carrier 2 on the side surface.
 また、凸部51の外周面に、複数の溝53aが周方向に形成されているので、側面保持部材4と凸部51との接触面積が多くなり、摩擦力が上昇する。そのため、側面保持部材4による触媒担体2の保持力を向上させることができる。 Further, since the plurality of grooves 53a are formed in the circumferential direction on the outer peripheral surface of the convex portion 51, the contact area between the side surface holding member 4 and the convex portion 51 increases, and the frictional force increases. Therefore, the holding force of the catalyst carrier 2 by the side surface holding member 4 can be improved.
 次に、第2実施形態に係る触媒コンバータ1の担体保持構造について、図5を参照して説明する。説明において、第1実施形態と同一の要素については同一の符号を付し、重複する説明は省略する。 Next, the carrier holding structure of the catalytic converter 1 according to the second embodiment will be described with reference to FIG. In the description, the same elements as those of the first embodiment are denoted by the same reference numerals, and redundant description is omitted.
 図5は、第2実施形態に係る触媒コンバータの要部断面図である。なお、図5の矢印fは、排ガスの流れ方向を示している。
 第2実施形態に係る触媒コンバータ1の担体保持構造は、コート層5に形成された凸部61の外周面に環状の窪部62を有している点が、前記した第1実施形態と異なっている。つまり、第2実施形態では、金属ケース3の凸部61に対応する部分である保持部3c及び側面保持部材4が、窪部62に入り込むことで、触媒担体2を軸方向及び径方向に保持している。
FIG. 5 is a cross-sectional view of a main part of the catalytic converter according to the second embodiment. Note that the arrow f in FIG. 5 indicates the flow direction of the exhaust gas.
The carrier holding structure of the catalytic converter 1 according to the second embodiment is different from the first embodiment described above in that an annular recess 62 is provided on the outer peripheral surface of the protrusion 61 formed in the coat layer 5. ing. That is, in the second embodiment, the holding portion 3c and the side surface holding member 4 which are portions corresponding to the convex portion 61 of the metal case 3 enter the recess 62, thereby holding the catalyst carrier 2 in the axial direction and the radial direction. is doing.
 窪部62は、断面視で略V字形状に形成されており、窪部62の上流側及び下流側は、相対的に突出部63,63を構成している。
 金属ケース3は、スピニング加工によって、窪部62及び突出部63,63の表面形状に合わせて縮径されている。また、側面保持部材4も、金属ケース3の縮径によって、窪部62及び突出部63,63の表面形状に馴染むように変形している。
 また、金属ケース3のうち、触媒担体2よりも上流側にある上流部3d及び下流側にある下流部3eは、触媒担体2の外径と略同径に縮径されている。
 なお、触媒担体2の上流側の外周縁及び下流側の外周縁は、金属ケース3に接触していない。
The recess 62 is formed in a substantially V shape in cross-sectional view, and the upstream side and the downstream side of the recess 62 relatively constitute projecting portions 63 and 63.
The diameter of the metal case 3 is reduced according to the surface shape of the recess 62 and the protrusions 63 and 63 by spinning. Further, the side surface holding member 4 is also deformed so as to conform to the surface shape of the recess 62 and the protrusions 63 and 63 due to the reduced diameter of the metal case 3.
In addition, in the metal case 3, the upstream portion 3 d on the upstream side of the catalyst carrier 2 and the downstream portion 3 e on the downstream side are reduced in diameter to approximately the same diameter as the outer diameter of the catalyst carrier 2.
The outer peripheral edge on the upstream side and the outer peripheral edge on the downstream side of the catalyst carrier 2 are not in contact with the metal case 3.
 かかる構成によれば、金属ケース3及び側面保持部材4が、凸部61に形成した窪部62に入り込んでいるので、金属ケース3が径方向に熱膨張した場合でも、金属ケース3が軸方向にも膨張して、側面保持部材4を介して、窪部62(あるいは突出部63,63)の傾斜面を径方向内側に向かって押圧するので、金属ケース3による触媒担体2の保持力の低下を抑制することができる。 According to such a configuration, since the metal case 3 and the side surface holding member 4 enter the recess 62 formed in the convex portion 61, the metal case 3 is axially aligned even when the metal case 3 is thermally expanded in the radial direction. And the inclined surface of the recess 62 (or the projecting portions 63 and 63) is pressed radially inward via the side surface holding member 4, so that the holding force of the catalyst carrier 2 by the metal case 3 is increased. The decrease can be suppressed.
 次に、第3実施形態に係る触媒コンバータ1の担体保持構造について、図6を参照して説明する。説明において、第1実施形態と同一の要素については同一の符号を付し、重複する説明は省略する。 Next, the carrier holding structure of the catalytic converter 1 according to the third embodiment will be described with reference to FIG. In the description, the same elements as those of the first embodiment are denoted by the same reference numerals, and redundant description is omitted.
 図6は、第3実施形態に係る触媒コンバータの要部断面図である。なお、図6の矢印fは、排ガスの流れ方向を示している。
 第3実施形態に係る触媒コンバータ1の担体保持構造は、コート層5に形成した凸部71の上流側端部72及び下流側端部73に当接する端部保持部材8,9を有している点が、前記した第1、第2実施形態と異なっている。
FIG. 6 is a cross-sectional view of a main part of the catalytic converter according to the third embodiment. In addition, the arrow f of FIG. 6 has shown the flow direction of waste gas.
The carrier holding structure of the catalytic converter 1 according to the third embodiment includes end holding members 8 and 9 that come into contact with the upstream end 72 and the downstream end 73 of the convex portion 71 formed in the coat layer 5. This is different from the first and second embodiments described above.
 第3実施形態においては、凸部71の外周面は平坦に形成されており、その周囲には側面保持部材4が設置されている。なお、第3実施形態においては、凸部71の軸方向の長さ寸法は、触媒担体2の軸方向の長さ寸法の0.3倍乃至0.9倍程度になっている。
 また、金属繊維等を用いて環状に形成されたワイヤメッシュリングである端部保持部材8,9が、凸部71の上流側端部72及び下流側端部73に面して設置されている。
 金属ケース3のうち、凸部71に対応する部分である保持部3cは、凸部71の表面形状に合わせてスピニング加工によって縮径されている。これにより、触媒担体2は、側面保持部材4を介して、金属ケース3に径方向に移動不能に保持されている。
 また、金属ケース3のうち、触媒担体2よりも上流側にある上流部3d及び下流側にある下流部3eは、触媒担体2の外径と略同径に縮径されている。
 なお、触媒担体2の上流側の外周縁及び下流側の外周縁は、金属ケース3に接触していない。
In 3rd Embodiment, the outer peripheral surface of the convex part 71 is formed flat, and the side surface holding member 4 is installed in the circumference | surroundings. In the third embodiment, the length dimension of the convex portion 71 in the axial direction is about 0.3 to 0.9 times the length dimension of the catalyst carrier 2 in the axial direction.
Further, end holding members 8 and 9 which are wire mesh rings formed in an annular shape using a metal fiber or the like are installed facing the upstream end 72 and the downstream end 73 of the convex portion 71. .
Of the metal case 3, the holding portion 3 c which is a portion corresponding to the convex portion 71 is reduced in diameter by spinning processing in accordance with the surface shape of the convex portion 71. Thereby, the catalyst carrier 2 is held by the metal case 3 so as not to move in the radial direction via the side surface holding member 4.
In addition, in the metal case 3, the upstream portion 3 d on the upstream side of the catalyst carrier 2 and the downstream portion 3 e on the downstream side are reduced in diameter to approximately the same diameter as the outer diameter of the catalyst carrier 2.
The outer peripheral edge on the upstream side and the outer peripheral edge on the downstream side of the catalyst carrier 2 are not in contact with the metal case 3.
 そして、金属ケース3のうち、保持部3cと上流部3dとを繋ぐテーパ部3fは、上流側に向かうほど小径となるように形成されている。テーパ部3fの内周面は、上流側の端部保持部材8の上流側端部に当接しており、端部保持部材8及び触媒担体2が上流側に移動することを規制している。
 また、金属ケース3のうち、保持部3cと下流部3eとを繋ぐテーパ部3gは、下流側に向かうほど小径となるように形成されている。テーパ部3gの内周面は、下流側の端部保持部材9の下流側端部に当接しており、端部保持部材9及び触媒担体2が下流側に移動することを規制している。
And the taper part 3f which connects the holding | maintenance part 3c and the upstream part 3d among the metal cases 3 is formed so that it may become a small diameter, so that it goes upstream. The inner peripheral surface of the taper portion 3f is in contact with the upstream end of the upstream end holding member 8, and restricts the end holding member 8 and the catalyst carrier 2 from moving upstream.
Moreover, the taper part 3g which connects the holding | maintenance part 3c and the downstream part 3e among the metal cases 3 is formed so that it may become a small diameter, so that it goes downstream. The inner peripheral surface of the taper portion 3g is in contact with the downstream end of the downstream end holding member 9, and restricts the end holding member 9 and the catalyst carrier 2 from moving downstream.
 第3実施形態に係る触媒コンバータ1の担体保持構造によれば、側面保持部材4に加えて端部保持部材8,9を装着し、かつ、これらを金属ケース3で直接固定するようにしたので、スピニング加工のみで触媒担体2の側面及び端部の保持が可能となり、作業性が向上する。
 また、触媒担体2の上流側端部及び下流側端部は、金属ケース3や端部保持部材8,9に接触していないので、触媒コンバータ1が振動した場合に荷重が加わることがない。そのため、触媒担体2の割れ等を防止することができる。
According to the carrier holding structure of the catalytic converter 1 according to the third embodiment, the end holding members 8 and 9 are mounted in addition to the side holding member 4 and are directly fixed by the metal case 3. The side and end portions of the catalyst carrier 2 can be held only by spinning, and workability is improved.
Further, since the upstream end and the downstream end of the catalyst carrier 2 are not in contact with the metal case 3 and the end holding members 8 and 9, no load is applied when the catalytic converter 1 vibrates. Therefore, cracking of the catalyst carrier 2 can be prevented.
 以上、本発明の実施形態について図面を参照して詳細に説明したが、本発明はこれに限定されるものではなく、発明の主旨を逸脱しない範囲で適宜変更可能である。 As mentioned above, although embodiment of this invention was described in detail with reference to drawings, this invention is not limited to this, In the range which does not deviate from the main point of invention, it can change suitably.
 例えば、本実施形態では、触媒担体2のコート層5の軸方向の中央部に、凸部51,61,71を一つだけ環状に形成したが、本発明は、これに限定されるものではなく、例えば複数の凸部を軸方向に間隔を隔てて形成してもよい。また、凸部51は環状でなくてもよい。 For example, in the present embodiment, only one convex portion 51, 61, 71 is formed in a ring shape at the central portion in the axial direction of the coat layer 5 of the catalyst carrier 2, but the present invention is not limited to this. For example, you may form a some convex part at intervals in the axial direction. Moreover, the convex part 51 does not need to be annular.
 また、本実施形態では、スピニング加工によって金属ケース3を縮径させたが、本発明はこれに限定されるものではない。例えば、図示は省略するが、円筒状の金属ケース3を軸方向に半割りにして2つの半割り状の部材を形成し、触媒担体2のコート層5の表面形状に合わせてプレス加工して、触媒担体2と側面保持部材4とを内部に配置したあとに、2つの半割り状の部材を溶接して円筒状の金属ケース3を形成するようにしてもよい。
 また、割り型や一体型を用いて金属ケース3を縮径してもよい。
In the present embodiment, the diameter of the metal case 3 is reduced by spinning, but the present invention is not limited to this. For example, although not shown, the cylindrical metal case 3 is divided in half in the axial direction to form two halved members, which are pressed according to the surface shape of the coat layer 5 of the catalyst carrier 2. Alternatively, after the catalyst carrier 2 and the side surface holding member 4 are disposed inside, the two half-shaped members may be welded to form the cylindrical metal case 3.
Further, the diameter of the metal case 3 may be reduced using a split mold or an integrated mold.
 また、本実施形態では、凸部51の表面に複数の溝53aを周方向に沿って形成したが、本発明はこれに限定されるものではなく、例えば、テーパ部53の表面に粒状物質を吹きつける等の方法により、凸部51の表面を目荒らして側面保持部材4との摩擦を増加することができればよい。 In the present embodiment, the plurality of grooves 53a are formed along the circumferential direction on the surface of the convex portion 51. However, the present invention is not limited to this, and for example, a granular material is applied to the surface of the tapered portion 53. It is only necessary to roughen the surface of the convex portion 51 and increase the friction with the side surface holding member 4 by a method such as spraying.
 また、本実施形態では、排ガス浄化装置におけるハニカム構造体として、触媒コンバータ1の触媒担体2を例にとって説明したが、本発明はこれに限定されるものではなく、例えば、DPFにおけるフィルタとしてのハニカム構造体であってもよい。 In the present embodiment, the catalyst carrier 2 of the catalytic converter 1 has been described as an example of the honeycomb structure in the exhaust gas purifying apparatus. However, the present invention is not limited to this, for example, a honeycomb as a filter in a DPF. It may be a structure.
 1   触媒コンバータ(排ガス浄化装置)
 2   触媒担体(ハニカム構造体)
 3   金属ケース
 4   側面保持部材
 5   コート層
 51  凸部
1 Catalytic converter (exhaust gas purification device)
2 Catalyst carrier (honeycomb structure)
3 Metal Case 4 Side Surface Holding Member 5 Coat Layer 51 Projection

Claims (8)

  1.  排気通路に配置される排ガス浄化装置におけるハニカム構造体の保持構造であって、
     複数のセルを有するとともに、外周面をコート層で覆われたハニカム構造体と、
     前記ハニカム構造体を内部に保持する金属ケースと、
     前記ハニカム構造体と前記金属ケースとの間に介在する側面保持部材と、を備え、
     前記コート層には、周方向に沿って少なくとも一部に凸部が形成されており、
     前記ハニカム構造体は、前記凸部の外側に配置された前記側面保持部材を介して、前記金属ケースに位置固定されることを特徴とする排ガス浄化装置におけるハニカム構造体の保持構造。
    A honeycomb structure holding structure in an exhaust gas purification device disposed in an exhaust passage,
    A honeycomb structure having a plurality of cells and having an outer peripheral surface covered with a coat layer;
    A metal case for holding the honeycomb structure inside;
    A side surface holding member interposed between the honeycomb structure and the metal case,
    The coat layer has a convex portion at least partially along the circumferential direction,
    The honeycomb structure holding structure in an exhaust gas purifying apparatus, wherein the honeycomb structure is fixed to the metal case via the side surface holding member disposed outside the convex portion.
  2.  前記凸部は、前記コート層を他の部分よりも厚くして構成したものであり、
     前記コート層は、セラミックスを主成分として、アルミナ、ムライト、リチウムアルミニウムシリケート、炭化ケイ素、窒化ケイ素、アルミナチタネート、コーディエライト、からなる群から選択される少なくとも1種を含む材料から成ることを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。
    The convex portion is configured by making the coat layer thicker than other portions,
    The coat layer is made of a material containing at least one selected from the group consisting of ceramics, alumina, mullite, lithium aluminum silicate, silicon carbide, silicon nitride, alumina titanate, and cordierite. A holding structure for a honeycomb structure in the exhaust gas purifying apparatus according to claim 1.
  3.  前記金属ケースは、前記凸部の表面形状に合わせて縮径加工により縮径され、前記側面保持部材を所定圧力で固定保持していることを特徴とする請求の範囲第1項に記載の触媒コンバータの担体保持構造。 2. The catalyst according to claim 1, wherein the metal case is reduced in diameter by a diameter reduction process in accordance with a surface shape of the convex portion, and the side surface holding member is fixedly held at a predetermined pressure. Converter carrier holding structure.
  4.  前記凸部の前記ハニカム構造体の軸方向の長さ寸法は、前記ハニカム構造体自体の軸方向の長さ寸法の0.3倍乃至1.0倍であり、前記凸部の外径は、前記ハニカム構造体の前記凸部を含まない部分の外径の1.01倍乃至1.2倍であることを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。 The length of the convex portion in the axial direction of the honeycomb structure is 0.3 to 1.0 times the length of the honeycomb structure itself in the axial direction, and the outer diameter of the convex portion is The retention of the honeycomb structure in the exhaust gas purifying apparatus according to claim 1, wherein the honeycomb structure has an outer diameter of 1.01 to 1.2 times an outer diameter of a portion not including the convex portion. Construction.
  5.  前記コート層で形成された前記凸部の一部を窪ませて窪部をさらに形成し、前記窪部を含む前記ハニカム構造体の凸部の外周面に前記側面保持部材を取り付け、さらに、前記窪部を含む前記凸部の表面形状に合わせて前記金属ケースを縮径させたことを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。 A part of the convex part formed by the coat layer is depressed to further form a concave part, the side surface holding member is attached to the outer peripheral surface of the convex part of the honeycomb structure including the concave part, The honeycomb structure holding structure in the exhaust gas purifying apparatus according to claim 1, wherein the diameter of the metal case is reduced in accordance with a surface shape of the convex portion including a recess.
  6.  前記コート層で形成された前記凸部の表面に、軸方向に互いに間隔を隔てて複数の突出部をさらに形成し、前記複数の突出部を含む前記ハニカム構造体の凸部の外周面に前記側面保持部材を取り付け、さらに前記突出部を含む前記凸部の表面形状に合わせて前記金属ケースを縮径させたことを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。 A plurality of protrusions are further formed on the surface of the protrusions formed by the coat layer at intervals in the axial direction, and the outer peripheral surface of the protrusions of the honeycomb structure including the plurality of protrusions is The honeycomb structure according to claim 1, wherein a side surface holding member is attached and the diameter of the metal case is reduced in accordance with a surface shape of the convex portion including the protruding portion. Holding structure.
  7.  前記コート層で形成された前記凸部の上流側端部及び下流側端部に面する位置に、前記ハニカム構造体の軸方向への移動を規制する端部保持部材を配設し、前記端部保持部材の上流側端部及び下流側端部に軸方向に所定圧力を付与するように前記金属ケースを縮径したことを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。 An end holding member that restricts movement of the honeycomb structure in the axial direction is disposed at a position facing the upstream end and the downstream end of the convex portion formed of the coat layer, and the end The honeycomb in the exhaust gas purification apparatus according to claim 1, wherein the diameter of the metal case is reduced so as to apply a predetermined pressure in an axial direction to an upstream end and a downstream end of the portion holding member. Structure holding structure.
  8.  前記凸部の外周面に、複数の溝が形成されていることを特徴とする請求の範囲第1項に記載の排ガス浄化装置におけるハニカム構造体の保持構造。 The honeycomb structure holding structure in an exhaust gas purification apparatus according to claim 1, wherein a plurality of grooves are formed on the outer peripheral surface of the convex portion.
PCT/JP2010/065695 2009-09-15 2010-09-13 Retention structure of honeycomb structure in exhaust gas purification device WO2011034015A1 (en)

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JP2015148171A (en) * 2014-02-05 2015-08-20 日本碍子株式会社 Honeycomb structure, and exhaust emission control device
CN112135962A (en) * 2018-05-18 2020-12-25 马瑞利株式会社 Exhaust gas purification device
FR3106853A1 (en) * 2020-02-04 2021-08-06 Psa Automobiles Sa EXHAUST SYSTEM INCLUDING BOSSES TO MAINTAIN A DEPOLLUTION BOX
WO2021181758A1 (en) * 2020-03-09 2021-09-16 日本碍子株式会社 Electrically heated carrier and exhaust gas purification device
US11149613B2 (en) 2016-07-13 2021-10-19 Corning Incorporated Exhaust gas treatment article and methods of manufacturing same
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JP2015148171A (en) * 2014-02-05 2015-08-20 日本碍子株式会社 Honeycomb structure, and exhaust emission control device
US11149613B2 (en) 2016-07-13 2021-10-19 Corning Incorporated Exhaust gas treatment article and methods of manufacturing same
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US20230067514A1 (en) * 2019-12-11 2023-03-02 Focus Universal Inc. Activated carbon air filter
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FR3106853A1 (en) * 2020-02-04 2021-08-06 Psa Automobiles Sa EXHAUST SYSTEM INCLUDING BOSSES TO MAINTAIN A DEPOLLUTION BOX
WO2021181758A1 (en) * 2020-03-09 2021-09-16 日本碍子株式会社 Electrically heated carrier and exhaust gas purification device
JP7313540B2 (en) 2020-03-09 2023-07-24 日本碍子株式会社 Electrically heated carrier and exhaust gas purification device

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