WO2011010495A1 - エンジニアリングウッド製造用防腐組成物及びエンジニアリングウッド - Google Patents
エンジニアリングウッド製造用防腐組成物及びエンジニアリングウッド Download PDFInfo
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- WO2011010495A1 WO2011010495A1 PCT/JP2010/056737 JP2010056737W WO2011010495A1 WO 2011010495 A1 WO2011010495 A1 WO 2011010495A1 JP 2010056737 W JP2010056737 W JP 2010056737W WO 2011010495 A1 WO2011010495 A1 WO 2011010495A1
- Authority
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- WIPO (PCT)
- Prior art keywords
- wood
- engineering wood
- antiseptic
- engineering
- resin
- Prior art date
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- 239000011120 plywood Substances 0.000 claims abstract description 23
- ZMYFCFLJBGAQRS-IAGOWNOFSA-N (2S,3R)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@]1(CN2N=CN=C2)[C@@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IAGOWNOFSA-N 0.000 claims abstract description 19
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- 229960003536 phenothrin Drugs 0.000 description 1
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- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
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- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- QHGVXILFMXYDRS-UHFFFAOYSA-N pyraclofos Chemical compound C1=C(OP(=O)(OCC)SCCC)C=NN1C1=CC=C(Cl)C=C1 QHGVXILFMXYDRS-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- CXJSOEPQXUCJSA-UHFFFAOYSA-N pyridaphenthion Chemical compound N1=C(OP(=S)(OCC)OCC)C=CC(=O)N1C1=CC=CC=C1 CXJSOEPQXUCJSA-UHFFFAOYSA-N 0.000 description 1
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- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
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- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
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- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- USPTVMVRNZEXCP-UHFFFAOYSA-N sulfamoyl fluoride Chemical class NS(F)(=O)=O USPTVMVRNZEXCP-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- UAWDZAKIFJNTHX-UHFFFAOYSA-N tert-butyl(oxo)tin Chemical compound CC(C)(C)[Sn]=O UAWDZAKIFJNTHX-UHFFFAOYSA-N 0.000 description 1
- LEZAYTDLNNEFJT-UHFFFAOYSA-N tetracosasodium octaborate tetrahydrate Chemical class O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] LEZAYTDLNNEFJT-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
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- 235000010296 thiabendazole Nutrition 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
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- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08L61/12—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols with polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic and acyclic or carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08L61/04, C08L61/18 and C08L61/20
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Definitions
- the present invention relates to a wood preservative composition. More specifically, an antiseptic composition for producing engineering wood, which is obtained by blending a specific preservative with an adhesive used in the production of so-called processed wood (engineering wood) such as veneer laminate (LVL) and plywood,
- processed wood engineering wood
- veneer laminate veneer laminate
- the present invention relates to an engineering wood produced using an antiseptic composition.
- So-called processed wood such as plywood and veneer laminate (LVL) is an excellent material that improves the defects of solid wood, and future production expansion is expected.
- a raw material of engineering wood a low quality material such as a southern ocean material is used, and therefore, there is a drawback that it is susceptible to biological deterioration (rotation, insect damage).
- the adhesive treatment it is necessary to select a chemical (preservative) in consideration of processing conditions different from those for pressure injection and surface treatment.
- the adhesive used in the manufacture of engineering wood is generally based on a thermosetting resin in an alkaline region such as a phenol resin
- the antiseptic compounded in this adhesive has basic antiseptic activity. Besides that, (1) Compatibility with base resin, (2) No alteration in the alkaline region of pH 9-13 (Alkaline resistance), and (3) Thermosetting conditions (130- The performance of not changing in quality at 150 ° C. (having heat resistance) is required.
- Epoxyconazole used in the antiseptic composition for producing engineering wood according to the present invention (hereinafter sometimes abbreviated as “wood preservative composition”) is a known compound, and there are many references from old times.
- Patent Document 1 discloses that epoxiconazole can be used for controlling wood-degrading fungi.
- Patent No. 3541975 discloses that epoxiconazole can be used for controlling wood-degrading fungi.
- Patent Document 2 discloses that Japanese Patent Laid-Open No. 2000-95621 (International Publication No. 00/004776 pamphlet) (Patent Document 3), Japanese Patent Laid-Open No. 2003-73211 (Patent Document 4), JP-A 2003-81714 (Patent Document 5), JP-A 2003-252705 (Patent Document 6), JP-A 2005-47056 (Patent Document 7), JP-A 2007-118261.
- Patent Document 3 discloses that Japanese Patent Laid-Open No. 2003-73211
- Patent Document 5 discloses Japanese Patent Laid-Open No. 2003-73211
- Patent Document 5 JP-A 2003-81714
- Patent Document 6 JP-A 2003-252705
- Patent Document 7 JP-A
- Patent Document 8 Japanese Patent Application Laid-Open No. 2007-254321 (Patent Document 9), and Japanese Patent Application Laid-Open No. 2009-96751 (Patent Document 10), which list many bactericides and preservatives, respectively.
- compositions containing epoxiconazole can also be used for adhesive treatment.
- these documents do not describe any examples of actually using epoxiconazole for adhesive treatment.
- WO98 / 018328 pamphlet Patent Document 11 discloses a binder for producing a timber material containing a specific insecticidal compound and an azole compound as a bactericide, but describes epoxyconazole. Not.
- Japanese Patent Publication No. 4-74355 U.S. Pat. No. 4,464,381
- Japanese Patent No. 3541975 Australian Patent No. 698343
- JP 2000-95621 A International Publication No. 00/004776 pamphlet
- an object of the present invention is to provide an antiseptic composition for producing engineering wood, which can be used for producing engineering wood such as plywood and single-plate laminated material (LVL), and can efficiently produce engineering wood having a high antiseptic effect, and the antiseptic composition thereof. It is to provide an engineering wood obtained by using the composition.
- engineering wood such as plywood and single-plate laminated material (LVL)
- the inventors have conducted a very comprehensive and extensive experiment using actual adhesives used in the manufacture of engineering wood and a number of agents having antiseptic activity. As a result, among these many chemicals, only epoxiconazole was found to be compatible with the manufacturing conditions of engineering wood such as plywood and veneer laminate (LVL), and exhibit an antiseptic effect at an extremely low concentration. Was completed.
- this invention provides the following antiseptic composition for engineering wood manufacture, and engineering wood.
- An antiseptic composition for producing engineering wood comprising epoxyconazole and a thermosetting resin.
- the thermosetting resin is selected from the group consisting of a phenol resin, a phenol / resorcinol copolymer resin, a urea resin, a urea / melamine resin, and a melamine / phenol resin.
- 3. The preservative composition for engineering wood production according to 1 or 2 above, wherein the engineering wood is a plywood, a single board laminate (LVL), a particle board or a fiber board. 4). An engineering wood produced using the preservative composition for producing engineering wood according to any one of 1 to 3 above. 5. 5.
- the engineering wood as described in 4 above which is a plywood, a single plate laminate (LVL), a particle board or a fiber board.
- the present invention provides a wood preservative composition in which a specific preservative (epoxyconazole) that does not deteriorate under manufacturing conditions is blended with an adhesive used in the manufacture of engineering wood.
- a specific preservative epoxyconazole
- an engineering wood exhibiting an excellent antiseptic effect can be efficiently produced by blending a small amount of active ingredients.
- Epoxyconazole is used as an active ingredient of an antiseptic composition for producing engineering wood.
- Epoxyconazole used as an active ingredient in the present invention can be produced by a known method, for example, a method described in Japanese Patent Publication No. 4-74355 (US Pat. No. 4,464,381).
- the active ingredient may be added to the resin as it is, but usually the active ingredient is mixed with a solid carrier, liquid carrier or gas carrier in advance. If necessary, add surfactants and other formulation aids, formulate oils, emulsions, solubilizers, wettable powders, suspensions, flowables, powders, etc., and add them to the resin. To do.
- aromatic organic solvents such as toluene, xylene, and methylnaphthalene solvents
- halogenated hydrocarbons such as dichloromethane and trichloroethane
- alcohols such as isopropyl alcohol and benzyl alcohol
- glycol solvents such as polyethylene glycol and polypropylene glycol
- kerosene N-methylpyrrolidone phosphate esters
- benzoate esters benzoate est
- An anionic, nonionic, or zwitterionic surfactant can be used as a surfactant used for formulation.
- the active ingredient is usually contained in an amount of 0.01 to 90% by mass, preferably 0.1 to 50% by mass.
- the active ingredient of the wood preservative composition of the present invention can be used in combination with other antibiotic compounds to further enhance the antibiotic effect of the drug or expand the action spectrum.
- Wood treatment with these antibiotic compounds can also be carried out as a pretreatment (treatment of single veneer before bonding) or posttreatment (treatment of engineering wood after production) of the wood preservative composition (adhesive) treatment according to the present invention.
- the wood treatment can be performed simultaneously with the addition of the wood preservative composition of the present invention.
- a copper compound can be mentioned.
- copper compounds include copper sulfate, copper chloride, copper phosphate, copper hydroxide, copper carbonate, basic copper carbonate, basic copper acetate, basic copper phosphate, basic copper chloride, copper oxide, suboxide Copper, copper acetate, copper naphthenate, copper oleate, copper stearate, copper octoate, copper benzoate, copper citrate, copper lactate, copper tartrate, copper 2-ethylhexanoate, and these copper compounds Examples include complexes stabilized in a water-soluble state, and hydrates of these compounds.
- ammonium-based compounds and amine-based compounds can be used to make the copper compound a stable solution.
- various carbonate compounds, carboxylic acid compounds, or mineral acids can be further added for pH adjustment, and specifically, boric acid, naphthenic acid, formic acid, acetic acid, propionic acid, hexane can be used.
- antibiotic compounds used in combination include azaconazole, viteltanol, bromconazole, Cyproconazole, diniconazole, fenbuconazole, fuchkinconazole, flusilazole, flutriazole, hexaconazole, imibenconazole, ipconazole, metconazole, microbutanyl, paclobutrazole, penconazole, propiconazole, tebuconazole, tetra Conazole, triadimephone, triadimenol, triticonazole, uniconazole, hexaconazole, 2- (2,4-difluorophenyl) -1- (1H-1,2,4-triazol-1-yl)- 3- (Trimethyl Ril) propan-2-ol and other triazoles; azoxystrobin, picoxystrobin
- Wood decay fungi that the wood preservative composition of the present invention works effectively include the following bacterial species. Coniophora souna, Trametes versicolor, Postia placenta, Postia vaporaria, Poria vaillantii, Gloeophyria sepialium sepialium , Gloeophylium adoratum, Gloeophylium abietinum, Gloeophylium trabeum, Gloeophylium protactum, Lentinus enti lepidus L Eddes (Lentinus edodes), Lentinus cyathiformes (Lentinus cyathiformes), Lentinus squarrolosus (Lentinus squarrolosus), Paxillas Panuides (Pa xillus panuoides, Fomitopsis palustris, Pleurotus ostreatus, Donkiop
- Wood discoloration bacteria to which the preservative for preservation of wood of the present invention works effectively include the following bacterial species. Aureobasidium pullulans, Scleroph pithyophila, Scopular phycomyces, Aspergillus niger, Penicillium varie , Incomplete fungi including Trichoderma rignorum and Dactyleum fusarioides. Ascomycetes, including Caratocystis minor. A zygomycete containing Mucor spinosus.
- the wood preservative composition of the present invention can be used for the production of various engineering woods, that is, plywood, veneer laminate (LVL), particle board and fiber board, and imparts a very high antiseptic effect to these engineering woods. can do.
- Plywood refers to a board made of thinly stripped wood, that is, a single board, which is bonded together by odd-numbered sheets by crossing the fiber directions of adjacent single boards.
- LVL is a product obtained by laminating and bonding several sheets to several tens of layers, with the fiber direction being almost parallel to each other, with a thickness of about 2 to 4 mm cut by a rotary lace or slicer. It is also called a material (Laminated Veneer Lumber; LVL) or a parallel single plate laminate (parallel plywood).
- the particle board is a wooden board obtained by mixing a small piece of wood with an adhesive and hot-pressing it.
- the fiber board is a wood board that has been cooked by mixing the digested wood fibers with an adhesive and hot-pressed. From the lowest density, insulation board (density less than 0.35 g / cm 3 ), medium density fiber board (Mid Density Fiber Board; MDF) (density 0.35 g / cm 3 to 0.80 g / cm 3 ) and hard board (density 0.85 g / cm 3 or more).
- phenol resin alkaline resole resin
- phenol-resorcinol copolymer resin urea resin
- urea-melamine resin melamine-phenol resin
- phenolic resin alkaline resole resin
- phenol / resorcinol copolymer resin phenol / resorcinol copolymer resin
- melamine / phenolic resin which are alkaline base resins
- phenolic resin (alkaline resole resin) can be used more suitably is there.
- these adhesives use wheat flour, wood flour, walnut flour, palm flour, and inorganic salts as hardeners to prevent excessive penetration into wood, promote curing, control viscosity, and prevent aging of the adhesive layer. It is done.
- the concentration of active ingredients (absorption amount for wood) in engineering wood (plywood, LVL, etc.) produced using the wood preservation composition of the present invention is usually 0.1 to 500 g / m 3 , preferably 1 to 150 g / m 3 .
- the wood preservative composition of the present invention which is an adhesive containing an active ingredient, is added to the surface of a veneer by a glue spreader, a roll spreader or an extruder coater.
- the standard coating amount is 50 to 500 g / m 2 .
- the adhesive is cured by cold pressure and heating to obtain a final product.
- the hot pressing temperature varies somewhat depending on the adhesive and is usually 50 to 200 ° C., but preferably 100 to 150 ° C ..
- the hot pressing time varies somewhat depending on the adhesive and is usually 5 to 300 seconds / mm, but 10 to 60 seconds / mm is preferable.
- the pressing pressure varies depending on the wood species and specific gravity of the veneer used, and is usually 5 to 20 kgf / cm 2 , but 7 to 15 kgf / cm 2 is preferable.
- Preparation Example 1 The following compounds known to have wood preservative activity were dissolved in methylethylene triglycol at a concentration of 10% (W / W) to obtain solutions of the respective compounds.
- Epoxyconazole manufactured by Wako Pure Chemical Industries, the same applies hereinafter
- Example 1 hexaconazole (Comparative Example 1), 2- (2,4-difluorophenyl) -1- (1H-1,2,4- Triazol-1-yl) -3- (trimethylsilyl) propan-2-ol (prepared according to the method of JP-B-7-68251) (Comparative Example 2), benzalkonium chloride (Comparative Example 3), didecyldimethylammonium chloride ( Comparative Example 4), Cyproconazole (Comparative Example 5), Tebuconazole (Comparative Example 6), Azaconazole (Comparative Example 7), Cimeconazole (Comparative Example 8), Fenbuconazole (Comparative Example 1
- Test Example 1 Miscibility test with phenol resin adhesive 1000 g of phenol resin adhesive Dianol D-117 (manufactured by Oshika), 70 g of wheat flour and 100 g of calcium carbonate were mixed and kneaded well. The solutions of Example 1 and Comparative Examples 1 to 25 were added to 17 g of this kneaded product, mixed well, and the viscosity change of the adhesive was visually observed for 60 minutes. The results are shown in Table 1. From Table 1, it was revealed that the compounds of Comparative Examples 3 and 4 cured the adhesive and had practical problems. Although many documents listed in the prior art documents describe that quaternary ammonium compounds can also be applied to the adhesive mixing method, it is clear that there are practical problems (Comparative Example 3 and 4). On the other hand, it was clarified that other compounds including Example compounds have no problem in terms of compatibility.
- Preparation Example 2 Preparation of antiseptic plywood with urea-melamine resin 1000 g of urea-melamine resin (PWP-60, manufactured by Oshika) was added to 180 g of wheat flour and kneaded sufficiently to obtain a kneaded product. To this kneaded product, 8 g of ammonium chloride was added as a curing agent, and the solutions of the compounds of Example 1 and Comparative Examples 1, 2, and 5 to 25 were adjusted to 150, 100, 50, and 25 g / m 3 in the finished wood. Each was added and kneaded.
- PWP-60 urea-melamine resin
- Preparation Example 3 Preparation of Preservative LVL with Phenol Resin 1000 g of phenol resin adhesive Dianol D-117 (manufactured by Oshika), 70 g of flour and 100 g of calcium carbonate were mixed and kneaded well. To this kneaded product, the solutions of the compounds of Example 1 and Comparative Examples 1, 2, 5 to 25 were added at concentrations of 150, 100, 50, and 25 g / m 3 in the finished wood, and further kneaded.
- Test Example 2 Preservation test of antiseptic plywood and LVL
- the plywood and LVL sample prepared in Preparation Examples 2 and 3 were evaluated by an antiseptic performance test for JIS K 1571: 2004 injection treatment.
- the weathering operation and the antiseptic test method were carried out according to the test method.
- the results are shown in Tables 2 and 3.
- the compound of Comparative Example 1 showed an antiseptic effect at 50 g / m 3 or more for Prunus and Kawatake
- the compound of Comparative Example 2 was 50 g / m 3 or more for Prunus, and 100 g / m for Kawatake.
- the epoxyconazole as an example compound showed a sufficient antiseptic effect even at 25 to 50 g / m 3 , as compared with almost no effect except that the antiseptic effect was exhibited at 3 or more.
- Preparation Example 4 Preparation of antiseptic plywood with urea-melamine resin An antiseptic plywood was prepared in the same manner as in Preparation Example 2. Each prepared plywood was processed into a size of 8.9 ⁇ 8.9 ⁇ 100 mm to obtain a test sample.
- Preparation Example 5 Preparation of preservative LVL with phenol resin
- Preservative LVL was prepared in the same manner as Preparation Example 3. Each of the prepared LVLs was processed into a size of 9 ⁇ 9 ⁇ 100 mm and used as a test sample.
- Test example 3 Preservation test of antiseptic plywood and LVL (fungus cellar decay tank test)
- the plywood and LVL samples prepared in Preparation Examples 4 and 5 were evaluated by the JISK1571: 2004 fan gas cellar decay tank test.
- the weathering operation and the antiseptic test method were carried out according to the test method.
- the test temperature was 25 ° C. and the test period was 6 months (because the average damage degree of the untreated specimen exceeded 2.5 in 6 months).
- the results are shown in Tables 4 and 5.
- the compounds of Comparative Examples 1 and 2 that showed the effect in Test Example 2 were not effective in the adhesive mixing method. Nazole showed a sufficient antiseptic effect even at 25-50 g / m 3 .
- Japanese Patent No. 4223558 discloses a composition containing an insecticidal component (imidacloprid) for use in an adhesive mixing method, and IPBC and azoles such as tebuconazole, propiconazole, and cyproconazole can be added together with the insecticidal component.
- IPBC and azoles such as tebuconazole, propiconazole, and cyproconazole can be added together with the insecticidal component.
- the active ingredient used in the wood preservative composition of the present invention showed an outstanding effect as compared with the compounds described in the patent. Therefore, it is clear that the wood preservative composition of the present invention cannot be easily achieved by those skilled in the art based on the techniques described in the prior art documents.
- the present invention provides a wood preservative composition in which a specific preservative (epoxyconazole) that does not deteriorate under manufacturing conditions is blended with an adhesive used in the manufacture of engineering wood.
- a specific preservative epoxyconazole
- an engineering wood exhibiting an excellent antiseptic effect can be efficiently produced with a small amount of an active ingredient.
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Abstract
Description
1.エポキシコナゾールと熱硬化性樹脂を含むことを特徴とするエンジニアリングウッド製造用防腐組成物。
2.熱硬化性樹脂が、フェノール樹脂、フェノール・レゾルシノール共重合体樹脂、ユリア樹脂、ユリア・メラミン樹脂、及びメラミン・フェノール樹脂からなる群から選ばれる前記1記載のエンジニアリングウッド製造用防腐組成物。
3.エンジニアリングウッドが、合板、単板積層材(LVL)、パーティクルボードまたはファイバーボードである前記1または2記載のエンジニアリングウッド製造用防腐組成物。
4.前記1~3のいずれかに記載のエンジニアリングウッド製造用防腐組成物を用いて製造されるエンジニアリングウッド。
5.合板、単板積層材(LVL)、パーティクルボードまたはファイバーボードである前記4記載のエンジニアリングウッド。
本発明で有効成分として使用するエポキシコナゾールは、公知の方法、例えば特公平4-74355号公報(米国特許第4464381号明細書)に記載の方法によって製造することができる。
本発明の木材防腐組成物が有効に作用する木材腐朽菌には以下の菌種が含まれる。
コニオフォラ・プテアナ(Coniophora puteana)、トラメテス・ベルシコラー(Trametes versicolor )、ポスティア・プラセンタ(Postia placenta )、ポスティア・バポラリア(Poria vaporaria )、ポリア・バイランティー(Poria vaillantii)、グロエオフィリウム・セピアリウム(Gloeophylium sepiarium)、グロエオフィリウム・アドラタム(Gloeophylium adoratum )、グロエオフィリウム・アビエティナム(Gloeophylium abietinum)、グロエオフィリウム・トラベウム(Gloeophylium trabeum)、グロエオフィリウム・プロタクタム(Gloeophylium protactum)、レンティナス・レピドウス(Lentinus lepideus )、レンティナス・エドデス(Lentinus edodes )、レンティナス・シアチフォルメス(Lentinus cyathiformes )、レンティナス・スクアロロサス(Lentinus squarrolosus )、パキシラス・パヌオイデス(Paxillus panuoides)、ホミトプシス・パルストリス(Fomitopsis palustris)、プレウロタス・オストレアタス(Pleurotus ostreatus )、ドンキオポリア・エクスパンサ(Donkioporia expansa )、セルプウラ・ラクリマンス(Serpula lacrymans )、セルプウラ・ヒマントイデス(Serpula himantoides )、グレノスポラ・グラフィー(Glenospora graphii)、ホミトプシス・リラシノギルバ(Fomitopsis lilacino-gilva )、ペレニポリア・テフロポラ(Perenniporia tephropora )、アントロディア・キサンタ(Antrodia xantha )、アントロディア・バイランティー(Antrodia vaillantii )を含む担子菌類、クラドスポリウム・ヘルバラム(Cladosporium herbarum )を含む不完全菌類、ケトミウム・グロブサム(Chaetomiumu globsum )、ケトミウム・アルバアレナラム(Chaetomium alba-arenulum)、ペトリエラ・セティフェラ(Petriella setifera)、トリチュラス・スピラリス(Trichurus spiralis)、フミコウラ・グリセラ(Humicola grisera)を含む子嚢菌類。
オーレオバシディウム・プルランス(Aureobasidium pullulans )、スクレロフ・ピティオフィラ(Scleroph pithyophila)、スコプウラ・フィコミセス(Scopular phycomyces )、アスペルギルス・ニガー(Aspergillus niger )、ペニシリウム・バリアビル(Penicillium variabile )、トリコデルマ・ビリデ(Trichoderma viride)、トリコデルマ・リグノラム(Trichoderma rignorum)、ダクティレウム・フサリオイデス(Dactyleum fusarioides )を含む不完全菌類。カラトシステス・ミナー(Caratocystis minor)を含む子嚢菌類。ムコール・スピノサス(Mucor spinosus)を含む接合菌類。
本発明の木材防腐組成物は、様々なエンジニアリングウッド、すなわち合板、単板積層材(LVL)、パーティクルボード及びファイバーボードの製造に利用可能であり、これらのエンジニアリングウッドに非常に高い防腐効果を付与することができる。
ファイバーボードは蒸解した木材繊維を接着剤と混合し熱圧成形した木質ボードであり、密度が小さい方からインシュレーションボード(密度0.35g/cm3未満)、中密度ファイバーボード(Mid Density Fiber Board ;MDF)(密度0.35g/cm3~0.80g/cm3)、ハードボード(密度0.85g/cm3以上)に区分される。
本発明ではこれらの添加剤を接着剤へ配合する際に、有効成分(防腐剤)を添加することが望ましい。
木材防腐活性を有することが知られている以下の化合物をメチルエチレントリグリコールに10%(W/W)の濃度に溶解させ、各化合物の溶液を得た。
エポキシコナゾール(和光純薬社製、以下同じ)(実施例1)、ヘキサコナゾール(比較例1)、2-(2,4-ジフルオロフェニル)-1-(1H-1,2,4-トリアゾール-1-イル)-3-(トリメチルシリル)プロパン-2-オール(特公平7-68251の方法に従って調製)(比較例2)、塩化ベンザルコニウム(比較例3)、ジデシルジメチルアンモニウムクロライド(比較例4)、シプロコナゾール(比較例5)、テブコナゾール(比較例6)、アザコナゾール(比較例7)、シメコナゾール(比較例8)、フェンブコナゾール(比較例9)、フルシラゾール(比較例10)、フルトリアホール(比較例11)、イミベンコナゾール(比較例12)、イプコナゾール(比較例13)、メトコナゾール(比較例14)、ミクロブタニル(比較例15)、ペンコナゾール(比較例16)、プロピコナゾール(比較例17)、テトラコナゾール(比較例18)、トリアジメフォン(比較例19)、トリチコナゾール(比較例20)、アゾキシストロビン(比較例21)、ピラクロストロビン(比較例22)、3-ヨード-2-プロピニル-n-ブチルカルバメート(IPBC)(ナガセケムテックス社製)(比較例23)、N-オクチルイソチアゾリン-3-オン(ナガセケムテックス社製)(比較例24)、クロロタロニル(エスディーエスバイオテック製)(比較例25)。
フェノール樹脂系接着剤ディアノールD-117(オーシカ社製)1000g、小麦粉70g、炭酸カルシウム100gを混合し、よく混練した。この混練物17gに実施例1及び比較例1~25の溶液をそれぞれ添加し、さらに良く混合し、目視で接着剤の粘度変化を60分間観察した。結果を表1に示す。表1から比較例3及び4の化合物は接着剤を硬化させ、実用上問題があることが明らかとなった。先行技術文献等に挙げた多くの文献に4級アンモニウム系化合物が接着剤混入法にも適用できることが記載されているが、実際には実用上問題があることは明白である(比較例3及び4)。一方、実施例化合物を含む他の化合物は相溶性の点では問題ないことが明らかとなった。
小麦粉180gにユリア・メラミン樹脂(PWP-60、オーシカ社製)1000gを加え、十分混練し、混練物を得た。この混練物に硬化剤として塩化アンモニウム8gを加え、さらに、実施例1及び比較例1、2、5~25化合物の溶液を出来上がった木材中の濃度として150、100、50、25g/m3になるようにそれぞれ添加し混練した。広さが30×30cmで、厚さが0.85mm/2.4mm/0.85mmの赤ラワン単板3枚に対し、上記混練物を接着面に各18g塗布し、張り合わせた後、室温で20分冷圧後、120℃の熱圧(10kgf/cm2)を2分加えて目的の合板を作成した。調製したそれぞれの合板は、20×20×4.1mmのサイズに加工し、試験サンプルとした。
フェノール樹脂系接着剤ディアノールD-117(オーシカ社製)1000g、小麦粉70g、炭酸カルシウム100gを混合し、良く混練した。この混練物に実施例1及び比較例1、2、5~25化合物の溶液を出来上がった木材中の濃度として150、100、50、25g/m3になるようにそれぞれ添加し、更に混練した。広さが30×30cmで、厚さが3mmのラジアタパイン単板3枚に対し、上記混練物を接着面に各18g塗布し、張り合わせた後、室温で20分冷圧後、140℃の熱圧(10kgf/cm2)を2分加えて目的のLVLを作成した。調製したそれぞれのLVLは、20×20×9mmのサイズに加工し、試験サンプルとした。
調製例2及び3で調製した合板及びLVLサンプルを、JISK1571:2004注入処理用防腐性能試験により評価した。耐候操作及び防腐試験方法は、同試験方法に準じて実施した。結果を表2及び3に示す。比較例化合物は接着剤混入法では比較例1の化合物がオオウズラタケ及びカワラタケで50g/m3以上で防腐効果を示し、比較例2の化合物がオオウズラタケでは50g/m3以上で、カワラタケでは100g/m3以上で防腐効果を示した以外は殆ど効果を示さないのに比べ、実施例化合物であるエポキシコナゾールは25~50g/m3でも十分な防腐効果を示した。
調整例2と同様にして防腐合板を調整した。調製したそれぞれの合板は、8.9×8.9×100mmのサイズに加工し、試験サンプルとした。
調整例3と同様にして防腐LVLを調整した。調製したそれぞれのLVLは、9×9×100mmのサイズに加工し、試験サンプルとした。
調製例4及び5で調製した合板及びLVLサンプルを、JISK1571:2004ファンガスセラー腐朽槽試験により評価した。耐候操作及び防腐試験方法は、同試験方法に準じて実施した。試験温度を25℃、試験期間は6ヶ月とした(無処理試験体の平均被害度が6ヶ月で2.5を超えたため)。結果を表4及び5に示す。比較例化合物は、試験例2で効果を示した比較例1及び2の化合物を含む全てが接着剤混入法では殆ど効果を示さないのに比べ、驚くべきことに、実施例化合物であるエポキシコナゾールは25~50g/m3でも十分な防腐効果を示した。多くの既存の防腐剤について、実際に接着剤処理法における効果を検討し、エポキシコナゾールのみが低濃度で接着剤処理法に適合することが確認された。すなわち、エポキシコナゾールのみが接着剤混入法の過酷な条件を経ても十分な防腐活性を有していることを示した。特許第4223558号公報は、接着剤混入法に用いる殺虫成分(イミダクロプリド)を含有する組成物を開示し、殺虫成分と共に殺菌剤としてIPBC及びテブコナゾール、プロピコナゾール、シプロコナゾール等のアゾールを添加できることをも開示しているが、本発明の木材防腐組成物で使用する有効成分は、前記特許に記載の化合物に比べてずば抜けた効果を示した。従って本発明の木材防腐組成物は、先行技術文献の記載の技術等に基づいて当業者が容易に成し遂げることができるものではないことは明らかである。
Claims (5)
- エポキシコナゾールと熱硬化性樹脂を含むことを特徴とするエンジニアリングウッド製造用防腐組成物。
- 熱硬化性樹脂が、フェノール樹脂、フェノール・レゾルシノール共重合体樹脂、ユリア樹脂、ユリア・メラミン樹脂、及びメラミン・フェノール樹脂からなる群から選ばれる請求項1記載のエンジニアリングウッド製造用防腐組成物。
- エンジニアリングウッドが、合板、単板積層材(LVL)、パーティクルボードまたはファイバーボードである請求項1または2記載のエンジニアリングウッド製造用防腐組成物。
- 請求項1~3のいずれかに記載のエンジニアリングウッド製造用防腐組成物を用いて製造されるエンジニアリングウッド。
- 合板、単板積層材(LVL)、パーティクルボードまたはファイバーボードである請求項4記載のエンジニアリングウッド。
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US13/380,781 US20120100361A1 (en) | 2009-07-23 | 2010-04-15 | Antiseptic composition for engineering wood production, and engineering wood |
JP2011523582A JP4798811B2 (ja) | 2009-07-23 | 2010-04-15 | エンジニアリングウッド製造用防腐組成物及びエンジニアリングウッド |
CA 2766495 CA2766495A1 (en) | 2009-07-23 | 2010-04-15 | Antiseptic composition for engineering wood production, and engineering wood |
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US20210400976A1 (en) | 2020-06-26 | 2021-12-30 | Lonza Solutions Ag | Methods and Compositions for Use in Glued-Wood Products |
US20210400975A1 (en) | 2020-06-26 | 2021-12-30 | Lonza Solutions Ag | Methods and Compositions for Use in Glued-Wood Products |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08238608A (ja) * | 1995-03-04 | 1996-09-17 | Dantani Plywood Co Ltd | パーティクルボード |
JP2003073211A (ja) * | 2001-08-30 | 2003-03-12 | Shinto Fine Co Ltd | 木材防腐組成物及び木材防腐方法 |
JP2006510501A (ja) * | 2002-12-18 | 2006-03-30 | ランクセス ドイチュラント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 木材ベースの製品のための防腐剤における改善 |
JP2007118261A (ja) * | 2005-10-26 | 2007-05-17 | Sumika Enviro-Science Co Ltd | 防虫・防蟻木質繊維板 |
Family Cites Families (4)
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US7439280B2 (en) * | 2004-04-06 | 2008-10-21 | Basf Corporation | Lignocellulosic composite material and method for preparing the same |
WO2006010192A1 (en) * | 2004-07-27 | 2006-02-02 | Orica Australia Pty. Ltd. | System for providing powder coated reconstituted cellulosic substrate |
AU2006282789B2 (en) * | 2005-08-25 | 2011-02-10 | Koppers Performance Chemicals Inc. | Layered wood composites |
US20080057134A1 (en) * | 2006-08-31 | 2008-03-06 | Agion Technologies, Inc. | Antifungal compositions and method |
-
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- 2010-04-15 CA CA 2766495 patent/CA2766495A1/en not_active Abandoned
- 2010-04-15 US US13/380,781 patent/US20120100361A1/en not_active Abandoned
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08238608A (ja) * | 1995-03-04 | 1996-09-17 | Dantani Plywood Co Ltd | パーティクルボード |
JP2003073211A (ja) * | 2001-08-30 | 2003-03-12 | Shinto Fine Co Ltd | 木材防腐組成物及び木材防腐方法 |
JP2006510501A (ja) * | 2002-12-18 | 2006-03-30 | ランクセス ドイチュラント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 木材ベースの製品のための防腐剤における改善 |
JP2007118261A (ja) * | 2005-10-26 | 2007-05-17 | Sumika Enviro-Science Co Ltd | 防虫・防蟻木質繊維板 |
Cited By (1)
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WO2015045942A1 (ja) * | 2013-09-30 | 2015-04-02 | 株式会社Lixil | 繊維板 |
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