WO2010135947A1 - Electrolytic system for producing hypochlorous acidic water - Google Patents

Electrolytic system for producing hypochlorous acidic water Download PDF

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Publication number
WO2010135947A1
WO2010135947A1 PCT/CN2010/072490 CN2010072490W WO2010135947A1 WO 2010135947 A1 WO2010135947 A1 WO 2010135947A1 CN 2010072490 W CN2010072490 W CN 2010072490W WO 2010135947 A1 WO2010135947 A1 WO 2010135947A1
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Prior art keywords
water
hypochlorous acid
zone
electrolyte
hydrochloric acid
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PCT/CN2010/072490
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French (fr)
Chinese (zh)
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官有文
蔡子棋
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百事通有限公司
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine

Definitions

  • the present invention relates to an electrolysis system, and more particularly to an electrolysis system for preparing hypochlorous acid water, which electrolyzes hydrochloric acid to generate chlorine gas, and mixes the generated chlorine gas with water to form a hypochlorite-containing sub-acid. Chlorochloric acid.
  • Hypochlorous acid water is acidic electrolyzed water containing hypochlorous acid molecules (HClO), which is a water with a pH of 5.0 to 6.5 and an effective chlorine concentration of 10-30 mg/L.
  • This hypochlorous acid water has strong oxidation. Ability and the role of rapid killing of microorganisms.
  • the existing electrolysis system for preparing hypochlorous acid water comprises an electrolysis tank, a tap water supply line and a hypochlorous acid water discharge line, and the tap water supply line supplies tap water to which sodium salt is added to the electrolysis tank, and the cathode is provided in the electrolyzer.
  • the anode electrode plate of the anode is provided with an ion membrane, and the anode side and the cathode side of the electrolytic cell are separated by an ion membrane.
  • the preparation principle is: tap water added with salt NaCl is electrolyzed by the electrolytic cell with ion separator Since the ion separator separates the anode side and the cathode side of the electrolytic cell, the anode generates chlorine gas from chloride ions, and then further reacts with H 2 O to form hydrochloric acid and hypochlorous acid HClO, so that the water obtained from the anode tank contains 10-50 mg/L. The available chlorine is then discharged into the hypochlorous acid water tank through the hypochlorous acid water discharge line.
  • the existing electrolysis system for preparing hypochlorous acid water mainly has the following problems: 1) using tap water supplemented with salt NaCl as a raw material, it is necessary to generate hypochlorous acid water by using an electrolytic cell with an ion membrane, but the ion membrane is The price is expensive, it is easy to block during the electrolysis process, affecting the electrolysis efficiency; and the existing double-slot diaphragm type electrolysis method obtains hypochlorous acid water in the anode tank in the production process, and the cathode tank obtains the same amount of alkaline water, and the alkali The use value of water is low; 2) During the electrolysis process, high current will generate heat through the electrolyte sheet, and the heat will increase the impedance of the electrolyte sheet, so that the current flow is reduced, which affects the amount of chlorine gas generated, thereby affecting the formation of hypochlorous acid water.
  • hypochlorous acid water does not meet the pH requirements, and it is therefore necessary to improve the existing electrolysis system for preparing hypochlorous acid water.
  • the technical problem to be solved by the present invention is to provide a method for preparing an electrolysis system for preparing hypochlorous acid water by using tap water supplemented with salt NaCl as a raw material and having a low production rate of hypochlorous acid water.
  • the electrolysis system for preparing hypochlorous acid water can effectively increase the production rate of hypochlorous acid water by using hydrochloric acid and tap water as raw materials.
  • the technical solution adopted by the present invention to solve the technical problem thereof is to provide an electrolysis system for preparing hypochlorous acid water, comprising: an electrolysis tank, a tap water supply pipeline, a hypochlorous acid water discharge pipeline, a hydrochloric acid supply pipeline, and Electrically connecting the intelligent controller with the electrolytic cell;
  • An inner tank for accommodating hydrochloric acid electrolyte and an outer tank for circulating tap water are formed in the electrolytic tank, and the inner tank is provided with an anode and a cathode electrode plate, and the lower end is provided with an electrolysis for introducing a hydrochloric acid electrolyte.
  • the lower side of the outer groove is provided with a water inlet hole for flowing in tap water, and the upper side is provided with a water outlet hole for discharging hypochlorous acid water;
  • One end of the tap water supply pipe is provided with a water inlet for connecting the water inlet pipe, and the other end is connected to the water inlet hole;
  • hydrochloric acid supply line is connected to a hydrochloric acid container for storing hydrochloric acid, and the other end is connected to the electrolyte inflow hole;
  • hypochlorous acid water discharge line is connected to the water outlet hole, and the other end is provided with a water outlet for connecting the hypochlorous acid water container or directly used.
  • the tap water supply pipe is sequentially provided with a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve, a flow restrictor, and a flow rate along the water flow direction.
  • the check valve, the intelligent controller is electrically connected with the two-way valve and the flow meter to monitor the flow of water in real time.
  • the hydrochloric acid supply line is provided with a liquid pump, and the intelligent controller is electrically connected with the liquid pump to monitor the electrolyte flow rate in real time.
  • the hypochlorous acid water discharge line is provided with an acid-base sensor, and the intelligent controller is electrically connected with the acid-base sensor to The pH of hypochlorous acid water is monitored in real time.
  • the hypochlorous acid water discharge line is further provided with a mixer, and the mixer is disposed in the water outlet hole of the electrolysis tank and the acid-base sensor.
  • the mixer includes an inner tube and a sleeve on the inner tube.
  • the inner tube is provided with a comb plate, and the comb plate is provided with a plurality of guide holes.
  • the chlorine gas discharge port is provided near the water outlet hole at the upper end of the inner tank.
  • the arrangement height of the chlorine gas discharge port is higher than the set height of the water discharge hole.
  • the inner tank is placed at an inclination of 20° to 40°, and a central electrolytic sheet is disposed in a middle portion thereof, and the central electrolytic sheet separates the inner tank into the A region.
  • Zone B and Zone C Zone A is the electrolyte buffer zone
  • Zone B and Zone C are the electrolysis zones
  • the electrolyte inflow holes are located in Zone A
  • the cathode and anode electrode plates are located in Zone C and Zone B, respectively.
  • a flow hole of 2 to 4 mm is opened under the central electrolytic sheet.
  • the electrolysis system without diaphragm is made of tap water and hydrochloric acid with wide source and low price. Because there is no diaphragm, it is easy to operate, high in production efficiency, and no alkaline water is produced during the production process, which can save a lot of raw materials;
  • the electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank.
  • the inner tank is disposed inside the outer tank and is sealed from the outer tank.
  • the inner tank contains hydrochloric acid electrolyte, the outer tank circulates tap water, and the hydrochloric acid electrolyte is electrolyzed to generate chlorine gas.
  • the chlorine gas discharge port is combined with the tap water of the outer tank to form hypochlorous acid (HClO), and the tap water flowing through the outer tank can also cool the electrolytic sheet of the inner tank, thereby reducing the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoiding the influence.
  • the amount of chlorine produced is produced.
  • the electrolysis cell is tilted by 20° ⁇ Place at 40° to avoid poor electrolyte flow.
  • the chlorine gas discharge port is arranged close to the water outlet hole. The setting height of the chlorine gas discharge port is higher than the set height of the water outlet hole.
  • the chlorine gas is mixed with the tap water to form hypochlorous acid in the mixing zone, which avoids the hydrochloric acid electrolyte being diluted by the tap water and can stabilize the chlorine gas. Discharge amount.
  • the electrolysis force, electrolyte flow rate and water flow rate are used as the control loop parameters of the intelligent controller to control the chlorine production of the electrolytic cell, and the most effective hypochlorous acid water is obtained.
  • the pressure and water flow of the water flow can be controlled by installing a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line; the flow meter is set to measure the water flow and feed back to the intelligent controller.
  • a check valve is provided to prevent the generated hypochlorous acid water from flowing back. 8)
  • the mixing amount of chlorine gas and water can be increased, the production efficiency of hypochlorous acid water can be provided, and the pH value of hypochlorous acid water can be determined by setting an acid-base sensor. And feedback to the intelligent controller.
  • the electrolysis system for preparing hypochlorous acid water of the present invention has a simple structure and can effectively increase the production rate of hypochlorous acid water, and the produced hypochlorous acid water has the environmental protection effect of sterilization and disinfection.
  • Figure 1 is a schematic illustration of an electrolysis system for preparing hypochlorous acid water of the present invention
  • Figure 2 is a schematic structural view of the electrolytic cell of Figure 1;
  • FIG. 3 is a schematic view showing the cooling structure of the electrolytic cell shown in Figure 2;
  • Figure 4 is a schematic view showing the structure of the electrolytic cell shown in Figure 2;
  • Figure 5 is a schematic view showing another structure of the electrolytic cell shown in Figure 2;
  • Figure 6 is a schematic structural view of a preferred embodiment of the inner groove shown in Figure 2;
  • Figure 7 is a schematic structural view of the mixer of Figure 1;
  • Figure 8 is a control schematic diagram of an electrolysis system for preparing hypochlorous acid water of the present invention.
  • FIG. 1 is a schematic structural view of an electrolysis system for preparing hypochlorous acid water according to a preferred embodiment of the present invention
  • FIG. 2 is a schematic structural view of the electrolysis cell of FIG. 1.
  • the present invention is used for preparing hypochlorous acid.
  • the electrolysis system of water comprises: an electrolysis tank 1, a tap water supply line 2, a hypochlorous acid water discharge line 3, a hydrochloric acid supply line 4, and an intelligent controller 5.
  • FIG. 2 is a schematic structural view of the electrolytic cell of FIG. 1.
  • the electrolytic cell 1 is formed with an inner tank 11 for accommodating hydrochloric acid electrolyte and an outer tank 12 for circulating tap water.
  • 11 is provided with an anode and a cathode electrode plate 18, 19, an electrolyte inflow hole 111 for introducing a hydrochloric acid electrolyte is disposed at a lower end thereof, and a chlorine gas discharge port 112 communicating with the outer groove 12 is opened at an upper end; the outer groove 12
  • the lower side is provided with a water inlet hole 121 for flowing in tap water, and the upper side is provided with a water outlet hole 122 for discharging hypochlorous acid water.
  • One end of the tap water supply line 2 is provided with a water inlet 21 for connecting a water inlet pipe (not shown), and the other end is connected to a water inlet hole 121 of the outer tank 12 for introducing tap water into the outer tank 12 of the electrolytic cell 1.
  • One end of the hydrochloric acid supply line 4 is connected to the hydrochloric acid container 41 for storing the hydrochloric acid electrolyte, and the other end is connected to the electrolyte inflow hole 111 of the inner tank 11 for introducing hydrochloric acid into the inner tank 11 of the electrolytic cell 1.
  • the intelligent controller 5 is provided with a power module and a control module.
  • the power module is electrically connected to the anode and cathode electrode plates 18 and 19, and provides DC voltages of the anode and cathode electrodes 18 and 19.
  • the principle of the hypochlorous acid water of the present invention is: using hydrochloric acid electrolyte (HCl) and tap water (H 2 O) as raw materials, the inner tank 11 of the electrolytic cell 1 is introduced into the hydrochloric acid electrolyte (HCl) through the hydrochloric acid supply line 4, The anode and cathode electrolysis sheets 18 and 19 are connected to a direct current voltage, and the hydrochloric acid electrolyte (HCl) is electrolyzed to generate hydrogen gas (H 2 ) and chlorine gas (Cl 2 ). The outer tank 12 of the electrolytic cell 1 is introduced into the tap water through the tap water supply line 2.
  • hypochlorous acid water with bactericidal and environmental protection effects can be obtained, which can be used as a food additive or as a food additive. disinfectant.
  • the tap water supply line 2 is provided with a pressure regulating valve 22, a water pressure gauge 23, a filter valve 24, a two-way valve 25, a flow restrictor 26, a flow meter 27, and a check valve 28 in the order of the flow direction.
  • the pressure regulating valve 22 and the water pressure gauge 23 are for regulating the pressure of the water flow;
  • the filter valve 24 is for filtering impurities in the tap water, and
  • the two-way valve 25, the flow restrictor 26 and the flow meter 27 are used for controlling the water.
  • the flow rate wherein the two-way valve 25 and the flow meter 27 are electrically connected to the intelligent controller 5, the two-way valve 25 is a solenoid valve, and the flow of the water is controlled by opening or closing, the flow meter 27 is used for measuring the water flow. And feeding back to the intelligent controller 5; the check valve 28 is for preventing the generated hypochlorous acid water from flowing back from the water inlet hole 121 back to the tap water supply line 2, which can be realized by the prior art.
  • a liquid pump 42 is disposed on the hydrochloric acid supply line 4, and the liquid pump 42 is electrically connected to the intelligent controller 5 for pumping hydrochloric acid into the inner tank 12 of the electrolytic cell 1.
  • the hypochlorous acid water discharge line 3 is provided with an acid-base sensor 32, and the acid-base sensor 32 is electrically connected to the intelligent controller 5 for measuring the pH value of the hypochlorous acid water and feeding back to the intelligent controller; It is noted that, as shown in FIG. 7, it is a schematic structural view of the mixer of FIG. 1.
  • the hypochlorous acid water discharge line 3 is provided with a mixer 31.
  • the mixer 31 is disposed in the water outlet 122 of the electrolytic cell 1 and the acid and alkali. Between the inductors 32, the mixer 31 includes an inner tube 311 and a sleeve 312 on the inner tube 311.
  • the inner tube 311 is internally provided with a thin tube 315, and a comb plate 313 is disposed thereon.
  • the plate 313 is provided with a plurality of guide holes 314.
  • the chlorine gas electrolyzed through the inner groove 11 of the electrolytic cell 1 is combined with the water in the outer tank 12 to produce hypochlorous acid water.
  • a small amount of chlorine gas is not mixed in the water.
  • the mixer 31 By adding the mixer 31, the chlorine gas 32 and water can be further mixed in the thin tube 315 and flow out from the pilot holes 314, and the production efficiency of hypochlorous acid water can be improved.
  • FIG. 8 is a schematic diagram showing the control of the electrolysis device for preparing hypochlorous acid water according to the present invention.
  • the intelligent controller 5 is electrically connected to the electrolytic cell 1 to the electrolytic cell 1 .
  • the electrolysis force is controlled in real time, and the intelligent controller 5 is electrically connected with the two-way valve 25 and the flow meter 27 to monitor the flow rate of the water in real time, and the intelligent controller 5 is electrically connected with the liquid pump 42 to perform real-time operation on the electrolyte flow.
  • the intelligent controller 5 is electrically connected with the acid-base sensor 32 to monitor the pH of the hypochlorous acid water in real time, and the electrolysis force, the electrolyte flow rate and the water flow rate are used as control loop parameters of the intelligent controller, for example: when entering When the water fluctuates under water, the intelligent controller increases or decreases the electrolysis force correspondingly to ensure the effective amount of hypochlorous acid molecules (HClO) in hypochlorous acid water. For example, the softness of tap water will affect the formation of hypochlorous acid water.
  • hypochlorous acid molecules HLO
  • the softness of tap water will affect the formation of hypochlorous acid water.
  • the pH of the intelligent controller corresponding to the increase or decrease of the electrolyte flow or the electrolysis force to control the amount of chlorine gas to be electrolyzed to balance the pH value of the finally produced hypochlorous acid water, and thus can be controlled by the intelligent controller 5
  • the electrolysis cell produces hypochlorous acid water of the desired pH to produce the most efficient hypochlorous acid water, which can be achieved by prior art techniques.
  • the improvement of the present invention also lies in how to stabilize the specific structural improvement of the electrolytic cell involved in the formation of hypochlorous acid water:
  • FIG. 3 is a schematic diagram of a cooling structure of an electrolysis system for preparing hypochlorous acid water according to the present invention
  • an inner space for accommodating a hydrochloric acid electrolyte is formed in a middle portion of the inner tank 11.
  • the cathode and anode electrode plates 18, 19 are located on both sides of the inner tank 11.
  • the outer tank 12 is disposed at the outer periphery of the inner tank 11, and an outer space for accommodating tap water is formed in the outer tank 12, and a water inlet hole 121 for flowing tap water (H 2 O) is opened on the lower side thereof, and the upper side is opened.
  • the water inlet hole 121 and the water outlet hole 122 communicate with the external space in the outlet hole 122 of the hypochlorous acid water (HClO).
  • the formation structure of the electrolytic cell is used to stably generate hypochlorous acid water.
  • FIG. 4 is a schematic diagram showing the generation structure of the electrolysis system for preparing hypochlorous acid water of the present invention; the electrolyte inflow hole 111, the chlorine gas discharge port 112 and the inner portion of the inner tank 11 The space is connected, and the water outlet hole 122 for discharging the hypochlorous acid water is close to the chlorine gas discharge port 112, thereby avoiding the change of the chlorine gas discharge amount due to the unstable pressure in the electrolytic cell 1, affecting the mixing ratio of the tap water and the chlorine gas, in this embodiment.
  • the chlorine gas discharge port 112 is disposed at the upper end of the inner tank 11 near the water outlet hole 122, and is a mixed zone 115 of chlorine gas (Cl 2 ) and tap water (H 2 O) at the chlorine gas discharge port 112, chlorine gas (Cl 2 ).
  • Hydrochloric acid (HCl) and hypochlorous acid (HClO) are mixed with tap water in the mixing zone 115 to obtain hypochlorous acid water, which flows out from the water outlet hole 122.
  • FIG. 5 is a schematic diagram of another generation structure of the electrolysis system for preparing hypochlorous acid water of the present invention.
  • the set height of the discharge port 112 is higher than the set height of the water outlet hole 122.
  • the figure shows that after the tap water supply is stopped, the water level of the outer tank 12 is lowered below the plane height of the chlorine gas discharge port 112, so that tap water is prevented from entering.
  • the inner tank 11 dilutes the electrolyte.
  • the inner groove 11 of the present invention adopts a multi-groove inner groove, and the central portion of the inner groove 11 is provided with a central electrolytic sheet 23, and the central electrolytic sheet 23 divides the inner groove 11 into the A region 13 , zone B 14 and zone C, zone A is the electrolyte buffer zone, zone B 14 and zone C are the electrolysis zone, electrolyte inflow port 111 is located in zone A, and the anode and cathode electrodes 18, 19 are respectively Located in Zone C and Zone B.
  • the central electrolyte sheet 23 is arranged to buffer the hydrochloric acid electrolyte (HCl) to optimize the electrolysis effect.
  • the electrolytic cell 1 is placed at an inclination of 20 to 40° so that the inner groove 11 is also inclined by 20 to 40 degrees, or the inner groove 11 is directly inclined by 20 to 40 degrees.
  • a flow hole 231 of 2 to 4 mm is opened below the central electrolytic sheet 23.
  • the electrolyte When it is blocked, the electrolyte will enter the C zone 15 from the A zone 13 and then convect to the B zone 14 through the flow hole 231.
  • the flow control of the electrolyte is more convenient, and the electrolyte in the inner tank is prevented from being more than the budget. To make hypochlorous acid water more stable.
  • the electrolysis system of the present invention for preparing hypochlorous acid water has the following characteristics: 1) The electrolysis system without diaphragm is made of tap water and hydrochloric acid with wide source and low price. Because there is no diaphragm, it is easy to operate, high in production efficiency, and no alkaline water is produced during the production process, which can save a lot of raw materials;
  • the electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank.
  • the inner tank is disposed inside the outer tank and is sealed from the outer tank.
  • the inner tank contains hydrochloric acid electrolyte, the outer tank circulates tap water, and the hydrochloric acid electrolyte is electrolyzed to generate chlorine gas.
  • the chlorine gas discharge port is combined with the tap water of the outer tank to form hypochlorous acid (HClO), and the tap water flowing through the outer tank can also cool the electrolytic sheet of the inner tank, thereby reducing the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoiding the influence.
  • the amount of chlorine produced is produced.
  • the electrolysis cell is tilted by 20° ⁇ Place at 40° to avoid poor electrolyte flow.
  • the chlorine gas discharge port is arranged close to the water outlet hole. The setting height of the chlorine gas discharge port is higher than the set height of the water outlet hole.
  • the chlorine gas is mixed with the tap water to form hypochlorous acid in the mixing zone, which avoids the hydrochloric acid electrolyte being diluted by the tap water and can stabilize the chlorine gas. Discharge amount.
  • the electrolysis force, electrolyte flow rate and water flow rate are used as the control loop parameters of the intelligent controller to control the chlorine production of the electrolytic cell, and the most effective hypochlorous acid water is obtained.
  • the pressure and water flow of the water flow can be controlled by installing a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line; the flow meter is set to measure the water flow and feed back to the intelligent controller.
  • a check valve is provided to prevent the generated hypochlorous acid water from flowing back. 8)
  • the mixing amount of chlorine gas and water can be increased, the production efficiency of hypochlorous acid water can be provided, and the pH value of hypochlorous acid water can be determined by setting an acid-base sensor. And feedback to the intelligent controller.
  • the electrolysis system for preparing hypochlorous acid water of the present invention has a simple structure and can effectively increase the production rate of hypochlorous acid water, and the produced hypochlorous acid water has the environmental protection effect of sterilization and disinfection.

Abstract

An electrolytic system for producing hypochlorous acidic water includes an electrolytic cell, a pipeline for supplying tap water, a pipeline for discharging hypochlorous acidic water, and a pipeline for supplying hydrochloric acid. An inner chamber for holding a hydrochloric acid containing electrolyte and an outer chamber for circulating the tap water are separately arranged in the electrolytic cell. Electrode plates are arranged in the inner chamber, in which an inlet from which the electrolyte flows into the chamber is provided at its lower end while an outlet connected with the outer chamber for discharging chlorine gas is provided at its upper end. An inlet from which the tap water flows into the chamber is provided at the lower end of the outer chamber while an outlet for discharging hypochlorous acidic water is provided at its upper end. One end of the pipeline for supplying tap water is connected with a water flow pipe, and the other end of it is connected with the inlet for flowing into the tap water. One end of the pipeline for supplying hydrochloric acid is connected with a container for hydrochloric acid, and the other end of it is connected with the inlet for flowing into the electrolyte. One end of the pipeline for discharging hypochlorous acidic water is connected with a outlet for discharging water, and the other end of it is connected with a container for hypochlorous acidic water or for field-work use. The present system has simple structure and can improve the efficiency of producing hypochlorous acidic water, and the obtained hypochlorous acidic water has the environment-friendly functions of sterilization and disinfection.

Description

用于制备次氯酸水的电解系统  Electrolysis system for preparing hypochlorous acid water 技术领域Technical field
本发明涉及一种电解系统,更具体地说,涉及一种用于制备次氯酸水的电解系统,将盐酸予以电解生成氯气,用水来混合所生成的氯气,以生成含有次氯酸的次氯酸水。The present invention relates to an electrolysis system, and more particularly to an electrolysis system for preparing hypochlorous acid water, which electrolyzes hydrochloric acid to generate chlorine gas, and mixes the generated chlorine gas with water to form a hypochlorite-containing sub-acid. Chlorochloric acid.
背景技术 Background technique
次氯酸水为酸性电解水,含有次氯酸分子(HClO),是一种PH为5.0~6.5、有效氯浓度为10-30mg/L的水,这种次氯酸水具有较强的氧化能力和快速杀灭微生物的作用。现有制备次氯酸水的电解系统包括电解槽、自来水供应管路以及次氯酸水排出管路,自来水供应管路向电解槽内供应添加了食盐Nacl的自来水,电解槽内设有的阴、阳两极电解片,并设有离子隔膜,由离子隔膜将电解槽的阳极侧和阴极侧分开,其制备原理是:将添加了食盐Nacl的自来水,通过该带有离子隔膜的电解槽电解而成,由于离子隔膜将电解槽的阳极侧和阴极侧分开,阳极由氯离子生成氯气,然后进一步与H2O反应生成盐酸和次氯酸HClO,使从阳极槽得到的水含10-50mg/L有效氯,然后再通过次氯酸水排出管路排入次氯酸水容器。Hypochlorous acid water is acidic electrolyzed water containing hypochlorous acid molecules (HClO), which is a water with a pH of 5.0 to 6.5 and an effective chlorine concentration of 10-30 mg/L. This hypochlorous acid water has strong oxidation. Ability and the role of rapid killing of microorganisms. The existing electrolysis system for preparing hypochlorous acid water comprises an electrolysis tank, a tap water supply line and a hypochlorous acid water discharge line, and the tap water supply line supplies tap water to which sodium salt is added to the electrolysis tank, and the cathode is provided in the electrolyzer. The anode electrode plate of the anode is provided with an ion membrane, and the anode side and the cathode side of the electrolytic cell are separated by an ion membrane. The preparation principle is: tap water added with salt NaCl is electrolyzed by the electrolytic cell with ion separator Since the ion separator separates the anode side and the cathode side of the electrolytic cell, the anode generates chlorine gas from chloride ions, and then further reacts with H 2 O to form hydrochloric acid and hypochlorous acid HClO, so that the water obtained from the anode tank contains 10-50 mg/L. The available chlorine is then discharged into the hypochlorous acid water tank through the hypochlorous acid water discharge line.
然而,现有用于制备次氯酸水的电解系统主要存在下述问题:1)采用添加了食盐Nacl的自来水为原料,需要利用带有离子隔膜的电解槽生成次氯酸水,然而离子隔膜的价格昂贵,电解过程中容易堵塞,影响电解效率;并且,现有的双槽隔膜式电解方式在生产过程中,阳极槽得到次氯酸水,阴极槽就得到等量的碱性水,而碱性水的利用价值低;2)电解过程中,高电流会通过电解片而产生热量,热量会增加电解片的阻抗,使得电流流量减低,影响氯气的产生量,进而影响次氯酸水的生成效率;3)氯气与水在电解槽中混合,但会存在少量的氯气没有与水混合,影响次氯酸水的生成效率;4)水流量、电解液流量及次氯酸水的酸碱值没有得到有效控制,使得所生成次氯酸水不符合PH值的要求,因而有必要对现有的用于制备次氯酸水的电解系统进行改进。However, the existing electrolysis system for preparing hypochlorous acid water mainly has the following problems: 1) using tap water supplemented with salt NaCl as a raw material, it is necessary to generate hypochlorous acid water by using an electrolytic cell with an ion membrane, but the ion membrane is The price is expensive, it is easy to block during the electrolysis process, affecting the electrolysis efficiency; and the existing double-slot diaphragm type electrolysis method obtains hypochlorous acid water in the anode tank in the production process, and the cathode tank obtains the same amount of alkaline water, and the alkali The use value of water is low; 2) During the electrolysis process, high current will generate heat through the electrolyte sheet, and the heat will increase the impedance of the electrolyte sheet, so that the current flow is reduced, which affects the amount of chlorine gas generated, thereby affecting the formation of hypochlorous acid water. Efficiency; 3) chlorine and water are mixed in the electrolysis tank, but a small amount of chlorine gas is not mixed with water, which affects the production efficiency of hypochlorous acid water; 4) water flow rate, electrolyte flow rate and pH value of hypochlorous acid water Without effective control, the resulting hypochlorous acid water does not meet the pH requirements, and it is therefore necessary to improve the existing electrolysis system for preparing hypochlorous acid water.
发明内容Summary of the invention
本发明要解决的技术问题在于,针对上述现有用于制备次氯酸水的电解系统,采用添加了食盐Nacl的自来水为原料,次氯酸水的生成率不高的缺点,提供一种用于制备次氯酸水的电解系统,采用盐酸与自来水为原料,能够有效提高次氯酸水的生成率。The technical problem to be solved by the present invention is to provide a method for preparing an electrolysis system for preparing hypochlorous acid water by using tap water supplemented with salt NaCl as a raw material and having a low production rate of hypochlorous acid water. The electrolysis system for preparing hypochlorous acid water can effectively increase the production rate of hypochlorous acid water by using hydrochloric acid and tap water as raw materials.
本发明解决其技术问题所采用的技术方案是:提供一种用于制备次氯酸水的电解系统,包括:电解槽、自来水供应管路、次氯酸水排出管路、盐酸供应管路以及与电解槽电性连接智能控制器;The technical solution adopted by the present invention to solve the technical problem thereof is to provide an electrolysis system for preparing hypochlorous acid water, comprising: an electrolysis tank, a tap water supply pipeline, a hypochlorous acid water discharge pipeline, a hydrochloric acid supply pipeline, and Electrically connecting the intelligent controller with the electrolytic cell;
所述电解槽内分隔形成有用于容纳盐酸电解液的内槽及用于流通自来水的外槽,所述内槽内设有阴、阳两极电解片,其下端开设有用于引入盐酸电解液的电解液流入孔,上端开设有与外槽相连通的氯气排出口;所述外槽的下侧开设有用于流入自来水的进水孔,其上侧开设有用于流出次氯酸水的出水孔; An inner tank for accommodating hydrochloric acid electrolyte and an outer tank for circulating tap water are formed in the electrolytic tank, and the inner tank is provided with an anode and a cathode electrode plate, and the lower end is provided with an electrolysis for introducing a hydrochloric acid electrolyte. a liquid inflow hole, the upper end is provided with a chlorine gas discharge port communicating with the outer groove; the lower side of the outer groove is provided with a water inlet hole for flowing in tap water, and the upper side is provided with a water outlet hole for discharging hypochlorous acid water;
所述自来水供应管路的一端设有入水口用于连接入水管,另一端连接所述进水孔;One end of the tap water supply pipe is provided with a water inlet for connecting the water inlet pipe, and the other end is connected to the water inlet hole;
所述盐酸供应管路的一端连接用于储存盐酸的盐酸容器,另一端连接所述电解液流入孔;One end of the hydrochloric acid supply line is connected to a hydrochloric acid container for storing hydrochloric acid, and the other end is connected to the electrolyte inflow hole;
所述次氯酸水排出管路的一端连接所述出水孔,另一端设有出水口用于连接次氯酸水容器或直接使用。One end of the hypochlorous acid water discharge line is connected to the water outlet hole, and the other end is provided with a water outlet for connecting the hypochlorous acid water container or directly used.
在本发明所述的用于制备次氯酸水的电解系统中,所述自来水供应管路沿水流方向顺序设有调压阀、水压表、过滤阀、两通阀、限流器、流量计以及单向阀,所述智能控制器与两通阀及流量计电性连接,以对水流流量进行实时监控。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the tap water supply pipe is sequentially provided with a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve, a flow restrictor, and a flow rate along the water flow direction. And the check valve, the intelligent controller is electrically connected with the two-way valve and the flow meter to monitor the flow of water in real time.
在本发明所述的用于制备次氯酸水的电解系统中,所述盐酸供应管路上设有液体泵,所述智能控制器与液体泵电性连接,以对电解液流量进行实时监控。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the hydrochloric acid supply line is provided with a liquid pump, and the intelligent controller is electrically connected with the liquid pump to monitor the electrolyte flow rate in real time.
在本发明所述的用于制备次氯酸水的电解系统中,所述次氯酸水排出管路上设有酸碱感应器,所述智能控制器与酸碱感应器电性连接,以对次氯酸水的酸碱度进行实时监控。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the hypochlorous acid water discharge line is provided with an acid-base sensor, and the intelligent controller is electrically connected with the acid-base sensor to The pH of hypochlorous acid water is monitored in real time.
在本发明所述的用于制备次氯酸水的电解系统中,所述次氯酸水排出管路上进一步设有混合器,所述混合器设于电解槽的出水孔和酸碱感应器之间,混合器包括内管及套设内管上的套管,所述内管的上方设有梳板,所述梳板上开设有数个导孔。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the hypochlorous acid water discharge line is further provided with a mixer, and the mixer is disposed in the water outlet hole of the electrolysis tank and the acid-base sensor. The mixer includes an inner tube and a sleeve on the inner tube. The inner tube is provided with a comb plate, and the comb plate is provided with a plurality of guide holes.
在本发明所述的用于制备次氯酸水的电解系统中,所述氯气排出口靠近出水孔设于内槽的上端。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the chlorine gas discharge port is provided near the water outlet hole at the upper end of the inner tank.
在本发明所述的用于制备次氯酸水的电解系统中,所述氯气排出口的设置高度高于所述出水孔的设置高度。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the arrangement height of the chlorine gas discharge port is higher than the set height of the water discharge hole.
在本发明所述的用于制备次氯酸水的电解系统中,所述内槽倾斜20°~40°放置,其中部设有中央电解片,所述中央电解片将内槽分隔为A区、B区及C区,A区为电解液缓冲区,B区和C区为电解区,所述电解液流入孔设于A区,所述阴、阳两极电解片分别位于C区和B区。In the electrolysis system for preparing hypochlorous acid water according to the present invention, the inner tank is placed at an inclination of 20° to 40°, and a central electrolytic sheet is disposed in a middle portion thereof, and the central electrolytic sheet separates the inner tank into the A region. , Zone B and Zone C, Zone A is the electrolyte buffer zone, Zone B and Zone C are the electrolysis zones, the electrolyte inflow holes are located in Zone A, and the cathode and anode electrode plates are located in Zone C and Zone B, respectively. .
在本发明所述的用于制备次氯酸水的电解系统中,所述中央电解片的下方开设有2~4mm的流通孔。 In the electrolysis system for preparing hypochlorous acid water according to the present invention, a flow hole of 2 to 4 mm is opened under the central electrolytic sheet.
本发明的用于制备次氯酸水的电解系统的有益效果: 1)采用无隔膜的电解系统,以来源广泛、价格低廉的自来水和盐酸为原料,由于没有隔膜,操作简便、生产效率高,且生产过程中,不产生碱性水,可以大量节约原料;2)电解系统的电解槽分隔为内槽、外槽,内槽设于外槽的内部并与外槽密封隔离,内槽容纳盐酸电解液,外槽流通自来水,盐酸电解液被电解后生成氯气从氯气排出口排出与外槽的自来水相结合生成次氯酸(HClO),且外槽流通的自来水还能够冷却内槽的电解片,能够降低电解片的热量,从而减低电解片的阻抗,避免影响氯气的生成量。3)电解过程中,电解槽倾斜20°~ 40°放置,避免电解液的流通不畅。4)氯气排出口靠近出水孔设置,氯气排出口的设置高度高于出水孔的设置高度,氯气在混合区与自来水混合生成次氯酸,避免了盐酸电解液被自来水稀释,且能稳定氯气的排出量。 5)采用智能控制器,以电解力、电解液流量和水流流量作为智能控制器的控制回路参数,来控制电解槽的氯气生产量,制得最有效的次氯酸水。7)通过在自来水供应管路上设置调压阀、水压表、过滤阀、两通阀及限流器可以控制水流的压力和水流量;设置流量计用于量度水流量并向智能控制器反馈;设置单向阀用于防止生成的次氯酸水回流。8)通过在次氯酸水排出管路上设置混合器,能够增加氯气与水的混合量,提供次氯酸水的生成效率,通过设置酸碱感应器,用于测定次氯酸水的PH值并向智能控制器反馈。综上所述,本发明的用于制备次氯酸水的电解系统的结构简单,且能够有效提高次氯酸水的生成率,所制得的次氯酸水具有杀菌和消毒的环保功效。Advantageous effects of the electrolysis system of the present invention for preparing hypochlorous acid water: 1) The electrolysis system without diaphragm is made of tap water and hydrochloric acid with wide source and low price. Because there is no diaphragm, it is easy to operate, high in production efficiency, and no alkaline water is produced during the production process, which can save a lot of raw materials; The electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank. The inner tank is disposed inside the outer tank and is sealed from the outer tank. The inner tank contains hydrochloric acid electrolyte, the outer tank circulates tap water, and the hydrochloric acid electrolyte is electrolyzed to generate chlorine gas. The chlorine gas discharge port is combined with the tap water of the outer tank to form hypochlorous acid (HClO), and the tap water flowing through the outer tank can also cool the electrolytic sheet of the inner tank, thereby reducing the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoiding the influence. The amount of chlorine produced. 3) During the electrolysis process, the electrolysis cell is tilted by 20°~ Place at 40° to avoid poor electrolyte flow. 4) The chlorine gas discharge port is arranged close to the water outlet hole. The setting height of the chlorine gas discharge port is higher than the set height of the water outlet hole. The chlorine gas is mixed with the tap water to form hypochlorous acid in the mixing zone, which avoids the hydrochloric acid electrolyte being diluted by the tap water and can stabilize the chlorine gas. Discharge amount. 5) Using intelligent controller, the electrolysis force, electrolyte flow rate and water flow rate are used as the control loop parameters of the intelligent controller to control the chlorine production of the electrolytic cell, and the most effective hypochlorous acid water is obtained. 7) The pressure and water flow of the water flow can be controlled by installing a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line; the flow meter is set to measure the water flow and feed back to the intelligent controller. A check valve is provided to prevent the generated hypochlorous acid water from flowing back. 8) By setting a mixer on the hypochlorous acid water discharge line, the mixing amount of chlorine gas and water can be increased, the production efficiency of hypochlorous acid water can be provided, and the pH value of hypochlorous acid water can be determined by setting an acid-base sensor. And feedback to the intelligent controller. In summary, the electrolysis system for preparing hypochlorous acid water of the present invention has a simple structure and can effectively increase the production rate of hypochlorous acid water, and the produced hypochlorous acid water has the environmental protection effect of sterilization and disinfection.
附图说明DRAWINGS
下面将结合附图及实施例对本发明作进一步说明,附图中:The present invention will be further described below in conjunction with the accompanying drawings and embodiments, in which:
图1是本发明的用于制备次氯酸水的电解系统的示意图;Figure 1 is a schematic illustration of an electrolysis system for preparing hypochlorous acid water of the present invention;
图2是图1中电解槽的结构示意图;Figure 2 is a schematic structural view of the electrolytic cell of Figure 1;
图3是图2所示的电解槽的冷却结构原理图;Figure 3 is a schematic view showing the cooling structure of the electrolytic cell shown in Figure 2;
图4是图2所示的电解槽的生成结构原理图;Figure 4 is a schematic view showing the structure of the electrolytic cell shown in Figure 2;
图5是图2所示的电解槽的另一生成结构原理图;Figure 5 is a schematic view showing another structure of the electrolytic cell shown in Figure 2;
图6是图2所示的内槽的优选实施例的结构示意图;Figure 6 is a schematic structural view of a preferred embodiment of the inner groove shown in Figure 2;
图7是图1中混合器的结构示意图;及Figure 7 is a schematic structural view of the mixer of Figure 1;
图8是本发明的用于制备次氯酸水的电解系统的控制原理图。Figure 8 is a control schematic diagram of an electrolysis system for preparing hypochlorous acid water of the present invention.
具体实施方式detailed description
如图1所示,图1是本发明优选实施例的用于制备次氯酸水的电解系统的结构示意图,图2是图1中电解槽的结构示意图;本发明的用于制备次氯酸水的电解系统,包括:电解槽1、自来水供应管路2、次氯酸水排出管路3、盐酸供应管路4以及智能控制器5。1 is a schematic structural view of an electrolysis system for preparing hypochlorous acid water according to a preferred embodiment of the present invention, and FIG. 2 is a schematic structural view of the electrolysis cell of FIG. 1. The present invention is used for preparing hypochlorous acid. The electrolysis system of water comprises: an electrolysis tank 1, a tap water supply line 2, a hypochlorous acid water discharge line 3, a hydrochloric acid supply line 4, and an intelligent controller 5.
参阅图2,图2所示是图1中电解槽的结构示意图;所述电解槽1内分隔形成有用于容纳盐酸电解液的内槽11及用于流通自来水的外槽12,所述内槽11内设有阴、阳两极电解片18、19,其下端开设有用于引入盐酸电解液的电解液流入孔111,上端开设有与外槽12相连通的氯气排出口112;所述外槽12的下侧开设有用于流入自来水的进水孔121,其上侧开设有用于流出次氯酸水的出水孔122。Referring to FIG. 2, FIG. 2 is a schematic structural view of the electrolytic cell of FIG. 1. The electrolytic cell 1 is formed with an inner tank 11 for accommodating hydrochloric acid electrolyte and an outer tank 12 for circulating tap water. 11 is provided with an anode and a cathode electrode plate 18, 19, an electrolyte inflow hole 111 for introducing a hydrochloric acid electrolyte is disposed at a lower end thereof, and a chlorine gas discharge port 112 communicating with the outer groove 12 is opened at an upper end; the outer groove 12 The lower side is provided with a water inlet hole 121 for flowing in tap water, and the upper side is provided with a water outlet hole 122 for discharging hypochlorous acid water.
自来水供应管路2的一端设有入水口21,用于连接入水管(未图示),另一端连接外槽12的进水孔121,用于向电解槽1的外槽12通入自来水。盐酸供应管路4的一端连接用于储存盐酸电解液的盐酸容器41,另一端连接内槽11的电解液流入孔111,用于向电解槽1的内槽11通入盐酸。次氯酸水排出管路3的一端连接外槽12的出水孔122,另一端设有出水口33连接收纳次氯酸水容器(未图示),用于向次氯酸水容器中排放次氯酸水。智能控制器5内设有电源模块及控制模块,所述电源模块与阴、阳两极电解片18、19电性连接,提供阴、阳两极电解片18、19直流电压。One end of the tap water supply line 2 is provided with a water inlet 21 for connecting a water inlet pipe (not shown), and the other end is connected to a water inlet hole 121 of the outer tank 12 for introducing tap water into the outer tank 12 of the electrolytic cell 1. One end of the hydrochloric acid supply line 4 is connected to the hydrochloric acid container 41 for storing the hydrochloric acid electrolyte, and the other end is connected to the electrolyte inflow hole 111 of the inner tank 11 for introducing hydrochloric acid into the inner tank 11 of the electrolytic cell 1. One end of the hypochlorous acid water discharge line 3 is connected to the water outlet hole 122 of the outer tank 12, and the other end is provided with a water outlet 33 connected to the hypochlorous acid water container (not shown) for discharging to the hypochlorous acid water container. Chlorochloric acid. The intelligent controller 5 is provided with a power module and a control module. The power module is electrically connected to the anode and cathode electrode plates 18 and 19, and provides DC voltages of the anode and cathode electrodes 18 and 19.
本发明的次氯酸水的生成原理是:以盐酸电解液(HCl)及自来水(H2O)为原料,电解槽1的内槽11通过盐酸供应管路4引入盐酸电解液(HCl),阴、阳两极电解片18、19接通直流电压,将盐酸电解液(HCl)电解生成氢气(H2)和氯气(Cl2),电解槽1的外槽12通过自来水供应管路2引入自来水(H2O)与氯气(Cl2)结合生成盐酸(HCl)和次氯酸(HClO),通过该电解系统能够制得具有杀菌、环保效果的次氯酸水,可以作为食物添加剂,或作成消毒液。The principle of the hypochlorous acid water of the present invention is: using hydrochloric acid electrolyte (HCl) and tap water (H 2 O) as raw materials, the inner tank 11 of the electrolytic cell 1 is introduced into the hydrochloric acid electrolyte (HCl) through the hydrochloric acid supply line 4, The anode and cathode electrolysis sheets 18 and 19 are connected to a direct current voltage, and the hydrochloric acid electrolyte (HCl) is electrolyzed to generate hydrogen gas (H 2 ) and chlorine gas (Cl 2 ). The outer tank 12 of the electrolytic cell 1 is introduced into the tap water through the tap water supply line 2. (H 2 O) combines with chlorine (Cl 2 ) to form hydrochloric acid (HCl) and hypochlorous acid (HClO). Through the electrolysis system, hypochlorous acid water with bactericidal and environmental protection effects can be obtained, which can be used as a food additive or as a food additive. disinfectant.
参阅图1-8,以下就电解系统的各部分结构进行详述: Referring to Figure 1-8, the following is a detailed description of the structure of each part of the electrolysis system:
参阅图1,自来水供应管路2沿水流方向顺序设有调压阀22、水压表23、过滤阀24、两通阀25、限流器26、流量计27以及单向阀28。所述调压阀22、水压表23用于调节水流的压力;所述过滤阀24用于过滤自来水中的杂质,所述两通阀25、限流器26及流量计27用于控制水流量,其中,两通阀25及流量计27与智能控制器5电性连接,所述两通阀25为电磁阀,通过开启或关闭控制水流的流通,所述流量计27用于量度水流量并向智能控制器5反馈;所述单向阀28用于防止生成的次氯酸水从进水孔121处倒流回自来水供应管路2,上述元件可通过现有技术实现。Referring to Fig. 1, the tap water supply line 2 is provided with a pressure regulating valve 22, a water pressure gauge 23, a filter valve 24, a two-way valve 25, a flow restrictor 26, a flow meter 27, and a check valve 28 in the order of the flow direction. The pressure regulating valve 22 and the water pressure gauge 23 are for regulating the pressure of the water flow; the filter valve 24 is for filtering impurities in the tap water, and the two-way valve 25, the flow restrictor 26 and the flow meter 27 are used for controlling the water. The flow rate, wherein the two-way valve 25 and the flow meter 27 are electrically connected to the intelligent controller 5, the two-way valve 25 is a solenoid valve, and the flow of the water is controlled by opening or closing, the flow meter 27 is used for measuring the water flow. And feeding back to the intelligent controller 5; the check valve 28 is for preventing the generated hypochlorous acid water from flowing back from the water inlet hole 121 back to the tap water supply line 2, which can be realized by the prior art.
盐酸供应管路4上设有液体泵42,液体泵42与智能控制器5电性连接,用于向电解槽1的内槽12内泵入盐酸。A liquid pump 42 is disposed on the hydrochloric acid supply line 4, and the liquid pump 42 is electrically connected to the intelligent controller 5 for pumping hydrochloric acid into the inner tank 12 of the electrolytic cell 1.
次氯酸水排出管路3上设有酸碱感应器32,酸碱感应器32与智能控制器5电性连接,用于测定次氯酸水的PH值并向智能控制器反馈;值得一提的是,如图7所示,是图1中混合器的结构示意图,次氯酸水排出管路3上设有混合器31,混合器31设于电解槽1的出水孔122和酸碱感应器32之间,所述混合器31包括内管311及套设内管311上的套管312,所述内管311内部设有细管315,其上方设有梳板313,所述梳板313上开设有数个导孔314,经过电解槽1的内槽11电解出的氯气在与外槽12中的水结合后生产次氯酸水,然而,其中少量的氯气并没有混合在水中,通过增加混合器31,氯气32和水可以在细管315中进一步的混合,并从导孔314中流出,能够提高次氯酸水的生成效率。The hypochlorous acid water discharge line 3 is provided with an acid-base sensor 32, and the acid-base sensor 32 is electrically connected to the intelligent controller 5 for measuring the pH value of the hypochlorous acid water and feeding back to the intelligent controller; It is noted that, as shown in FIG. 7, it is a schematic structural view of the mixer of FIG. 1. The hypochlorous acid water discharge line 3 is provided with a mixer 31. The mixer 31 is disposed in the water outlet 122 of the electrolytic cell 1 and the acid and alkali. Between the inductors 32, the mixer 31 includes an inner tube 311 and a sleeve 312 on the inner tube 311. The inner tube 311 is internally provided with a thin tube 315, and a comb plate 313 is disposed thereon. The plate 313 is provided with a plurality of guide holes 314. The chlorine gas electrolyzed through the inner groove 11 of the electrolytic cell 1 is combined with the water in the outer tank 12 to produce hypochlorous acid water. However, a small amount of chlorine gas is not mixed in the water. By adding the mixer 31, the chlorine gas 32 and water can be further mixed in the thin tube 315 and flow out from the pilot holes 314, and the production efficiency of hypochlorous acid water can be improved.
参阅图1及图8,图8所示是本发明的用于制备次氯酸水的电解装置的控制原理图,所述智能控制器5与电解槽1电性连接,以对电解槽1的电解力进行实时控制,智能控制器5与两通阀25及流量计27电性连接,以对水流流量进行实时监控,智能控制器5与液体泵42电性连接,以对电解液流量进行实时监控;智能控制器5与酸碱感应器32电性连接,以对次氯酸水的酸碱度进行实时监控,电解力、电解液流量和水流流量作为智能控制器的控制回路参数,例如:当入水上、下波动时,智能控制器就对应地增加或减少电解力,来保证次氯酸水中次氯酸分子(HClO)的有效量,又如,自来水的软硬度会影响次氯酸水生成的酸碱度,智能控制器对应的增加或减少电解液流量或电解力,来控制电解出的氯气的量来平衡最终生成的次氯酸水的酸碱值,因而通过智能控制器5可以控制电解槽生成所需PH值的次氯酸水,制得最有效的次氯酸水,该智能控制器可通过现有技术实现。Referring to FIG. 1 and FIG. 8 , FIG. 8 is a schematic diagram showing the control of the electrolysis device for preparing hypochlorous acid water according to the present invention. The intelligent controller 5 is electrically connected to the electrolytic cell 1 to the electrolytic cell 1 . The electrolysis force is controlled in real time, and the intelligent controller 5 is electrically connected with the two-way valve 25 and the flow meter 27 to monitor the flow rate of the water in real time, and the intelligent controller 5 is electrically connected with the liquid pump 42 to perform real-time operation on the electrolyte flow. Monitoring; the intelligent controller 5 is electrically connected with the acid-base sensor 32 to monitor the pH of the hypochlorous acid water in real time, and the electrolysis force, the electrolyte flow rate and the water flow rate are used as control loop parameters of the intelligent controller, for example: when entering When the water fluctuates under water, the intelligent controller increases or decreases the electrolysis force correspondingly to ensure the effective amount of hypochlorous acid molecules (HClO) in hypochlorous acid water. For example, the softness of tap water will affect the formation of hypochlorous acid water. The pH of the intelligent controller corresponding to the increase or decrease of the electrolyte flow or the electrolysis force to control the amount of chlorine gas to be electrolyzed to balance the pH value of the finally produced hypochlorous acid water, and thus can be controlled by the intelligent controller 5 The electrolysis cell produces hypochlorous acid water of the desired pH to produce the most efficient hypochlorous acid water, which can be achieved by prior art techniques.
本发明的改进之处还在于如何稳定次氯酸水的生成所涉及的电解槽的具体结构上的改进:The improvement of the present invention also lies in how to stabilize the specific structural improvement of the electrolytic cell involved in the formation of hypochlorous acid water:
一、电解槽的冷却结构,用于冷却电解片。1. The cooling structure of the electrolytic cell for cooling the electrolytic sheet.
参阅图2及图3,如图3所示是本发明的用于制备次氯酸水的电解系统的冷却结构原理图;所述内槽11的中部形成有用于容纳盐酸电解液的内部空间,所述阴、阳两极电解片18、19位于内槽11的两侧。所述外槽12设于内槽11的外围,外槽12内形成用于容纳自来水的外部空间,其下侧开设有用于流入自来水(H2O)的进水孔121,其上侧开设有用于流出次氯酸水(HClO)的出水孔122,所述进水孔121、出水孔122与外部空间相连通。Referring to FIG. 2 and FIG. 3, FIG. 3 is a schematic diagram of a cooling structure of an electrolysis system for preparing hypochlorous acid water according to the present invention; an inner space for accommodating a hydrochloric acid electrolyte is formed in a middle portion of the inner tank 11. The cathode and anode electrode plates 18, 19 are located on both sides of the inner tank 11. The outer tank 12 is disposed at the outer periphery of the inner tank 11, and an outer space for accommodating tap water is formed in the outer tank 12, and a water inlet hole 121 for flowing tap water (H 2 O) is opened on the lower side thereof, and the upper side is opened. The water inlet hole 121 and the water outlet hole 122 communicate with the external space in the outlet hole 122 of the hypochlorous acid water (HClO).
电解过程中,高电流通过电解片而产生热量,使得电解片的温度上升,阻抗增加,电流流量减低,影响氯气的产生量,采用上述结构,将自来水从外槽12的进水孔121引入外部空间,由于自来水引入到内槽11的外围,因而能够有效冷却内槽11中的电解片,降低电解片的阻抗,避免影响到氯气的生成量。In the electrolysis process, a high current generates heat through the electrolytic sheet, so that the temperature of the electrolytic sheet rises, the impedance increases, the current flow rate decreases, and the amount of chlorine gas is generated. With the above structure, tap water is introduced from the water inlet hole 121 of the outer tank 12 to the outside. In the space, since the tap water is introduced to the outer periphery of the inner tank 11, the electrolytic sheet in the inner tank 11 can be effectively cooled, the impedance of the electrolytic sheet can be lowered, and the amount of chlorine gas generated can be prevented from being affected.
二、电解槽的生成结构,用于稳定生成次氯酸水。Second, the formation structure of the electrolytic cell is used to stably generate hypochlorous acid water.
参阅图2、图4及图5,图4是本发明的用于制备次氯酸水的电解系统的生成结构原理图;所述电解液流入孔111、氯气排出口112与内槽11的内部空间相连通,用于排出次氯酸水的出水孔122要接近氯气排出口112,避免因电解槽1内压力不稳定,而改变氯气的排出量,影响自来水和氯气的混合比例,在本实施例中,所述氯气排出口112靠近出水孔122设于内槽11的上端,在氯气排出口112处为氯气(Cl2)和自来水(H2O)的混合区115,氯气(Cl2)在混合区115与自来水混合生成盐酸(HCl)和次氯酸(HClO),得到次氯酸水,从出水孔122流出。Referring to FIG. 2, FIG. 4 and FIG. 5, FIG. 4 is a schematic diagram showing the generation structure of the electrolysis system for preparing hypochlorous acid water of the present invention; the electrolyte inflow hole 111, the chlorine gas discharge port 112 and the inner portion of the inner tank 11 The space is connected, and the water outlet hole 122 for discharging the hypochlorous acid water is close to the chlorine gas discharge port 112, thereby avoiding the change of the chlorine gas discharge amount due to the unstable pressure in the electrolytic cell 1, affecting the mixing ratio of the tap water and the chlorine gas, in this embodiment. In the example, the chlorine gas discharge port 112 is disposed at the upper end of the inner tank 11 near the water outlet hole 122, and is a mixed zone 115 of chlorine gas (Cl 2 ) and tap water (H 2 O) at the chlorine gas discharge port 112, chlorine gas (Cl 2 ). Hydrochloric acid (HCl) and hypochlorous acid (HClO) are mixed with tap water in the mixing zone 115 to obtain hypochlorous acid water, which flows out from the water outlet hole 122.
另外,值得一提的是,在正常运作时,盐酸电解液不会被自来水稀释,参阅图5是本发明的用于制备次氯酸水的电解系统的另一生成结构原理图;所述氯气排出口112的设置高度高于所述出水孔122的设置高度,图示中示出了停止自来水供应后,外槽12的水位会降至氯气排出口112的平面高度以下,这样就避免自来水进入内槽11,稀释电解液。因而,采用上述结构避免了盐酸电解液被自来水稀释。In addition, it is worth mentioning that, in normal operation, the hydrochloric acid electrolyte is not diluted by tap water, and FIG. 5 is a schematic diagram of another generation structure of the electrolysis system for preparing hypochlorous acid water of the present invention; The set height of the discharge port 112 is higher than the set height of the water outlet hole 122. The figure shows that after the tap water supply is stopped, the water level of the outer tank 12 is lowered below the plane height of the chlorine gas discharge port 112, so that tap water is prevented from entering. The inner tank 11 dilutes the electrolyte. Thus, the use of the above structure avoids dilution of the hydrochloric acid electrolyte by tap water.
三、电解槽的结构及放置形式,用于稳定供应盐酸电解液。Third, the structure and placement of the electrolytic cell for the stable supply of hydrochloric acid electrolyte.
参阅图6,图6示出了优选实施例的电解槽的内槽的结构示意图。在上述结构的基础上,本实用新型的内槽11采用多槽式内槽,所述内槽11的中部设有中央电解片23,所述中央电解片23将内槽11分隔为A区13、B区14及C区15,A区13为电解液缓冲区,B区14和C区15为电解区,电解液流入孔111设于A区13,阴、阳两极电解片18、19分别设于C区和B区。中央电解片23的设置可以缓冲盐酸电解液(HCl),优化电解效果。在本实施例中,电解槽1倾斜20°~40°放置,以使内槽11也倾斜20°~40°,或者内槽11直接倾斜20°~40°设置。所述中央电解片23的下方开设有2~4mm的流通孔231。在电解过程中,电解液的泵入速度不能太快,电解液会从A区13进入B区14,然后由B区14对流到C区15,如果电解液进入B区14的容量不足或孔道被堵塞,这时,电解液就会从A区13进入C区15,再通过流通孔231对流到B区14,电解液的流通控制更为方便,避免内槽中的电解液多于预算量,使得次氯酸水较为稳定。Referring to Figure 6, there is shown a schematic view of the structure of the inner tank of the electrolytic cell of the preferred embodiment. On the basis of the above structure, the inner groove 11 of the present invention adopts a multi-groove inner groove, and the central portion of the inner groove 11 is provided with a central electrolytic sheet 23, and the central electrolytic sheet 23 divides the inner groove 11 into the A region 13 , zone B 14 and zone C, zone A is the electrolyte buffer zone, zone B 14 and zone C are the electrolysis zone, electrolyte inflow port 111 is located in zone A, and the anode and cathode electrodes 18, 19 are respectively Located in Zone C and Zone B. The central electrolyte sheet 23 is arranged to buffer the hydrochloric acid electrolyte (HCl) to optimize the electrolysis effect. In the present embodiment, the electrolytic cell 1 is placed at an inclination of 20 to 40° so that the inner groove 11 is also inclined by 20 to 40 degrees, or the inner groove 11 is directly inclined by 20 to 40 degrees. A flow hole 231 of 2 to 4 mm is opened below the central electrolytic sheet 23. During the electrolysis process, the pumping speed of the electrolyte should not be too fast, and the electrolyte will enter the B zone 14 from the A zone 13 and then convect the B zone 14 to the C zone 15 if the electrolyte enters the B zone 14 with insufficient capacity or pores. When it is blocked, the electrolyte will enter the C zone 15 from the A zone 13 and then convect to the B zone 14 through the flow hole 231. The flow control of the electrolyte is more convenient, and the electrolyte in the inner tank is prevented from being more than the budget. To make hypochlorous acid water more stable.
本发明的用于制备次氯酸水的电解系统具有下述特点: 1)采用无隔膜的电解系统,以来源广泛、价格低廉的自来水和盐酸为原料,由于没有隔膜,操作简便、生产效率高,且生产过程中,不产生碱性水,可以大量节约原料;2)电解系统的电解槽分隔为内槽、外槽,内槽设于外槽的内部并与外槽密封隔离,内槽容纳盐酸电解液,外槽流通自来水,盐酸电解液被电解后生成氯气从氯气排出口排出与外槽的自来水相结合生成次氯酸(HClO),且外槽流通的自来水还能够冷却内槽的电解片,能够降低电解片的热量,从而减低电解片的阻抗,避免影响氯气的生成量。3)电解过程中,电解槽倾斜20°~ 40°放置,避免电解液的流通不畅。4)氯气排出口靠近出水孔设置,氯气排出口的设置高度高于出水孔的设置高度,氯气在混合区与自来水混合生成次氯酸,避免了盐酸电解液被自来水稀释,且能稳定氯气的排出量。 5)采用智能控制器,以电解力、电解液流量和水流流量作为智能控制器的控制回路参数,来控制电解槽的氯气生产量,制得最有效的次氯酸水。7)通过在自来水供应管路上设置调压阀、水压表、过滤阀、两通阀及限流器可以控制水流的压力和水流量;设置流量计用于量度水流量并向智能控制器反馈;设置单向阀用于防止生成的次氯酸水回流。8)通过在次氯酸水排出管路上设置混合器,能够增加氯气与水的混合量,提供次氯酸水的生成效率,通过设置酸碱感应器,用于测定次氯酸水的PH值并向智能控制器反馈。综上所述,本发明的用于制备次氯酸水的电解系统的结构简单,且能够有效提高次氯酸水的生成率,所制得的次氯酸水具有杀菌和消毒的环保功效。The electrolysis system of the present invention for preparing hypochlorous acid water has the following characteristics: 1) The electrolysis system without diaphragm is made of tap water and hydrochloric acid with wide source and low price. Because there is no diaphragm, it is easy to operate, high in production efficiency, and no alkaline water is produced during the production process, which can save a lot of raw materials; The electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank. The inner tank is disposed inside the outer tank and is sealed from the outer tank. The inner tank contains hydrochloric acid electrolyte, the outer tank circulates tap water, and the hydrochloric acid electrolyte is electrolyzed to generate chlorine gas. The chlorine gas discharge port is combined with the tap water of the outer tank to form hypochlorous acid (HClO), and the tap water flowing through the outer tank can also cool the electrolytic sheet of the inner tank, thereby reducing the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoiding the influence. The amount of chlorine produced. 3) During the electrolysis process, the electrolysis cell is tilted by 20°~ Place at 40° to avoid poor electrolyte flow. 4) The chlorine gas discharge port is arranged close to the water outlet hole. The setting height of the chlorine gas discharge port is higher than the set height of the water outlet hole. The chlorine gas is mixed with the tap water to form hypochlorous acid in the mixing zone, which avoids the hydrochloric acid electrolyte being diluted by the tap water and can stabilize the chlorine gas. Discharge amount. 5) Using intelligent controller, the electrolysis force, electrolyte flow rate and water flow rate are used as the control loop parameters of the intelligent controller to control the chlorine production of the electrolytic cell, and the most effective hypochlorous acid water is obtained. 7) The pressure and water flow of the water flow can be controlled by installing a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line; the flow meter is set to measure the water flow and feed back to the intelligent controller. A check valve is provided to prevent the generated hypochlorous acid water from flowing back. 8) By setting a mixer on the hypochlorous acid water discharge line, the mixing amount of chlorine gas and water can be increased, the production efficiency of hypochlorous acid water can be provided, and the pH value of hypochlorous acid water can be determined by setting an acid-base sensor. And feedback to the intelligent controller. In summary, the electrolysis system for preparing hypochlorous acid water of the present invention has a simple structure and can effectively increase the production rate of hypochlorous acid water, and the produced hypochlorous acid water has the environmental protection effect of sterilization and disinfection.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。 The above is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily think of changes or within the technical scope disclosed by the present invention. Alternatives are intended to be covered by the scope of the present invention. Therefore, the scope of protection of the present invention should be determined by the scope of the claims.

Claims (9)

1、一种用于制备次氯酸水的电解系统,其特征在于,包括:电解槽(1)、自来水供应管路(2)、次氯酸水排出管路(3)、盐酸供应管路(4)以及与电解槽(1)电性连接智能控制器(5);An electrolysis system for preparing hypochlorous acid water, comprising: an electrolysis tank (1), a tap water supply line (2), a hypochlorous acid water discharge line (3), a hydrochloric acid supply line (4) and electrically connected to the electrolytic cell (1) intelligent controller (5);
所述电解槽(1)内分隔形成有用于容纳盐酸电解液的内槽(11)及用于流通自来水的外槽(12),所述内槽(11)内设有阴、阳两极电解片,其下端开设有用于引入盐酸电解液的电解液流入孔(111),上端开设有与外槽(12)相连通的氯气排出口(112);所述外槽(12)的下侧开设有用于流入自来水的进水孔(121),其上侧开设有用于流出次氯酸水的出水孔(122); An inner tank (11) for accommodating hydrochloric acid electrolyte and an outer tank (12) for circulating tap water are formed in the electrolytic tank (1), and the inner tank (11) is provided with an anode and a cathode electrode plate. The lower end is provided with an electrolyte inflow hole (111) for introducing a hydrochloric acid electrolyte, and the upper end is provided with a chlorine gas discharge port (112) communicating with the outer groove (12); the lower side of the outer groove (12) is opened a water inlet hole (121) flowing into the tap water, and a water outlet hole (122) for discharging hypochlorous acid water on the upper side thereof;
所述自来水供应管路(2)的一端设有入水口(21)用于连接入水管,另一端连接所述进水孔(121);One end of the tap water supply line (2) is provided with a water inlet (21) for connecting the water inlet pipe, and the other end is connected to the water inlet hole (121);
所述盐酸供应管路(4)的一端连接用于储存盐酸的盐酸容器(41),另一端连接所述电解液流入孔(111);One end of the hydrochloric acid supply line (4) is connected to a hydrochloric acid container (41) for storing hydrochloric acid, and the other end is connected to the electrolyte inflow hole (111);
所述次氯酸水排出管路(3)的一端连接所述出水孔(122),另一端设有出水口(33)。One end of the hypochlorous acid water discharge line (3) is connected to the water outlet hole (122), and the other end is provided with a water outlet (33).
2、根据权利要求1所述的用于制备次氯酸水的电解系统,其特征在于,所述自来水供应管路(2)沿水流方向顺序设有调压阀(22)、水压表(23)、过滤阀(24)、两通阀(25)、限流器(26)、流量计(27)以及单向阀(28),所述智能控制器(5)与两通阀(25)及流量计(27)电性连接,以对水流流量进行实时监控。2. The electrolysis system for preparing hypochlorous acid water according to claim 1, wherein the tap water supply line (2) is provided with a pressure regulating valve (22) and a water pressure gauge in the order of the water flow direction. 23), a filter valve (24), a two-way valve (25), a flow restrictor (26), a flow meter (27), and a check valve (28), the intelligent controller (5) and the two-way valve (25) And the flow meter (27) is electrically connected to monitor the flow of water in real time.
3、根据权利要求1所述的用于制备次氯酸水的电解系统,其特征在于,所述盐酸供应管路(4)上设有液体泵(42),所述智能控制器(5)与液体泵(42)电性连接,以对电解液流量进行实时监控。The electrolysis system for preparing hypochlorous acid water according to claim 1, characterized in that the hydrochloric acid supply line (4) is provided with a liquid pump (42), and the intelligent controller (5) It is electrically connected to the liquid pump (42) to monitor the electrolyte flow in real time.
4、根据权利要求1所述的用于制备次氯酸水的电解系统,其特征在于,所述次氯酸水排出管路(3)上设有酸碱感应器(32),所述智能控制器(5)与酸碱感应器(32)电性连接,以对次氯酸水的酸碱度进行实时监控。The electrolysis system for preparing hypochlorous acid water according to claim 1, characterized in that the hypochlorous acid water discharge line (3) is provided with an acid-base sensor (32), the smart The controller (5) is electrically connected to the acid-base sensor (32) to monitor the pH of the hypochlorous acid water in real time.
5、根据权利要求4所述的用于制备次氯酸水的电解系统,其特征在于,所述次氯酸水排出管路(3)上进一步设有混合器(31),所述混合器(31)设于电解槽(1)的出水孔(122)和酸碱感应器(32)之间,包括内管(311)及套设内管(311)上的套管(312),所述内管(311)内部设有细管(315),其上方设有梳板(313),所述梳板(313)上开设有数个导孔(314)。The electrolysis system for preparing hypochlorous acid water according to claim 4, characterized in that the hypochlorous acid water discharge line (3) is further provided with a mixer (31), the mixer (31) disposed between the water outlet hole (122) of the electrolytic cell (1) and the acid-base sensor (32), including an inner tube (311) and a sleeve (312) on the inner tube (311). A thin tube (315) is disposed inside the inner tube (311), and a comb plate (313) is disposed thereon, and the guide plate (313) is provided with a plurality of guide holes (314).
6、根据权利要求1所述的用于制备次氯酸水的电解系统,其特征在于,所述氯气排出口(112)靠近出水孔(122)设于内槽(11)的上端。The electrolysis system for preparing hypochlorous acid water according to claim 1, characterized in that the chlorine gas discharge port (112) is provided at an upper end of the inner tank (11) near the water outlet hole (122).
7、根据权利要求1或6所述的用于制备次氯酸水的电解系统,其特征在于,所述氯气排出口(112)的设置高度高于所述出水孔(122)的设置高度。The electrolysis system for preparing hypochlorous acid water according to claim 1 or 6, wherein the chlorine gas discharge port (112) is disposed at a height higher than a set height of the water outlet hole (122).
8、根据权利要求1所述的用于制备次氯酸水的电解系统,其特征在于,所述内槽(11)倾斜20°~40°放置,其中部设有中央电解片(32),所述中央电解片(32)将内槽(11)分隔为A区、B区及C区,A区为电解液缓冲区,B区和C区为电解区,所述电解液流入孔(111)设于A区,所述阴、阳两极电解片分别位于C区和B区。The electrolysis system for preparing hypochlorous acid water according to claim 1, wherein the inner tank (11) is placed at an inclination of 20 to 40, and a central electrolytic sheet (32) is disposed at a middle portion thereof. The central electrolytic sheet (32) divides the inner tank (11) into the A zone, the B zone and the C zone, the zone A is the electrolyte buffer zone, the zone B and the zone C are the electrolysis zone, and the electrolyte inflow hole (111) ) is disposed in the A zone, and the anode and cathode electrode plates are located in the C zone and the B zone, respectively.
9、根据权利要求8所述的用于制备次氯酸水的电解系统,其特征在于,所述中央电解片(32)的下方开设有2~4mm的流通孔。The electrolysis system for preparing hypochlorous acid water according to claim 8, wherein a flow hole of 2 to 4 mm is opened under the central electrolytic sheet (32).
PCT/CN2010/072490 2009-05-25 2010-05-06 Electrolytic system for producing hypochlorous acidic water WO2010135947A1 (en)

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