WO2010113271A1 - 二次電池および電池システム - Google Patents
二次電池および電池システム Download PDFInfo
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- WO2010113271A1 WO2010113271A1 PCT/JP2009/056681 JP2009056681W WO2010113271A1 WO 2010113271 A1 WO2010113271 A1 WO 2010113271A1 JP 2009056681 W JP2009056681 W JP 2009056681W WO 2010113271 A1 WO2010113271 A1 WO 2010113271A1
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- WIPO (PCT)
- Prior art keywords
- battery
- electrode group
- sheet
- electrode terminal
- secondary battery
- Prior art date
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/049—Processes for forming or storing electrodes in the battery container
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L50/00—Electric propulsion with power supplied within the vehicle
- B60L50/50—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
- B60L50/60—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells using power supplied by batteries
- B60L50/64—Constructional details of batteries specially adapted for electric vehicles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0468—Compression means for stacks of electrodes and separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/102—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
- H01M50/103—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L53/00—Methods of charging batteries, specially adapted for electric vehicles; Charging stations or on-board charging equipment therefor; Exchange of energy storage elements in electric vehicles
- B60L53/50—Charging stations characterised by energy-storage or power-generation means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Definitions
- the present invention relates to a secondary battery in which a positive electrode and a negative electrode are laminated via a separator, and a power supply / storage system using the battery.
- lithium ion secondary batteries As is well known, among secondary batteries as rechargeable batteries, lithium ion secondary batteries, in particular, have high energy density and high capacity, and are therefore used as power sources for home appliances. Further, in recent years, it has been attracting attention as a storage battery for storing surplus power such as a power source for electric vehicles, a power source for houses, and a power plant.
- a wound lithium ion secondary battery in which a pair of belt-like sheet-like positive electrode and sheet-like negative electrode are spirally wound via a separator, and a plurality of sheet-like
- a stacked lithium ion secondary battery in which a positive electrode and a sheet-like negative electrode are stacked via a plurality of separators.
- the electrode group composed of the plurality of sheet-like positive electrodes and sheet-like negative electrodes is usually enclosed in a rectangular battery can having a substantially rectangular cross section.
- a wound lithium ion secondary battery it may be enclosed in a cylindrical battery can having a substantially circular cross section, or may be enclosed in a square battery can.
- an insulating auxiliary sheet is provided on the sheet-like electrode surface at the end of the electrode group, and fixed with tape together with the electrode group (See Patent Document 1 below).
- FIG. 7A shows a cross section of the surface of the rectangular battery can 1 that intersects the surface direction (first direction) where a positive electrode terminal and a negative electrode terminal (not shown) are formed.
- the electrode group G in which the sheet-like positive electrode 2 and the negative electrode 3 are laminated via a separator (not shown) is inserted into the rectangular battery can 1.
- insulating auxiliary sheets 4 and 6 are provided on the four sides of the electrode group on the long side of the surface on which the positive electrode terminal and the negative electrode terminal are formed. Are arranged in the direction and the short side direction as shown in the figure.
- the electrode surface width a is the same dimension as the inner side (inner) b in the long side direction, since the square battery can corner 1c is rounded, the electrode near the corner 1c is pressed and deformed, As a result, the separator is broken, and as a result, there is a high risk of causing a failure such as a short circuit.
- the electrode surface width a is slightly smaller than the inner method b in the long side direction and is designed to have a size that is not affected by the roundness of the battery can corner 1c.
- the insulating auxiliary sheet 6 is made of an insulating material having a thickness that can withstand at least the insulation, in other words, an extremely thin insulator.
- the present invention can prevent electrode deformation at the corners of a rectangular battery can as much as possible even when continuous vibration is applied, and maximize performance as designed. It is an object of the present invention to provide a secondary battery and a power feeding or power storage system using the battery.
- the secondary battery of the present invention employs the following configuration. That is, a rectangular battery can having a positive electrode terminal and a negative electrode terminal, and a sheet-like positive electrode disposed in the rectangular battery can and electrically connected to the positive electrode terminal and electrically connected to the negative electrode terminal An electrode group in which a sheet-like negative electrode is laminated via a separator, and a position facing each other across the electrode group from the long side of the surface where the positive electrode terminal and the negative electrode terminal of the rectangular battery can are formed
- the first and second insulating auxiliary sheets, and the width of the rectangular battery can in the short side direction of the surface is substantially the same size as that in the rectangular battery can in the short side direction of the surface, the short side side
- the first and second cages are arranged at positions facing each other across the electrode group and support the electrode group in contact with the rectangular battery can at a plurality of locations.
- An electric vehicle as a power supply system includes a rectangular battery can having a positive electrode terminal and a negative electrode terminal, and a sheet-like positive electrode disposed in the square battery can and electrically connected to the positive electrode terminal. And an electrode group in which a sheet-like negative electrode electrically connected to the negative electrode terminal is laminated via a separator, and from the long side of the surface on which the positive electrode terminal and the negative electrode terminal of the rectangular battery can are formed,
- the first and second insulating auxiliary sheets respectively disposed at positions facing each other across the electrode group, and the width of the surface substantially the same as the method in the rectangular battery can in the short side direction of the surface 1st and 2nd holding
- the electric vehicle may be any vehicle that can be driven by electricity, and may be
- the power storage system includes a rectangular battery can having a positive electrode terminal and a negative electrode terminal, a sheet-like positive electrode disposed in the square battery can and electrically connected to the positive electrode terminal, and the negative electrode terminal.
- An electrode group in which sheet-like negative electrodes electrically connected to each other are stacked via a separator, and the electrode group is sandwiched from the long side of the surface on which the positive electrode terminal and the negative electrode terminal of the rectangular battery can are formed
- the first and second insulating auxiliary sheets respectively disposed at positions opposed to each other, and the width of the surface of the rectangular battery can in the short side direction of the surface is substantially the same dimension as the short side direction of the surface
- a first cage and a second cage that are arranged at positions facing each other across the electrode group from the short side and that support the electrode group in contact with the rectangular battery can at a plurality of locations.
- the power storage receives power from the power generation equipment.
- the power generation equipment any power generation equipment such as a solar battery, a fuel cell, a windmill, a thermal power generation equipment, a hydroelectric power generation equipment, and a nuclear power generation equipment may be used. Good. Even if it is not a power plant, the power generation equipment installed in a general household may be sufficient.
- the end of the sheet-like electrode Since the end of the sheet-like electrode has a physically weak structure such as being easily bent, care must be taken not to touch the end to the prismatic battery can when inserting the electrode group into the prismatic battery can. is there.
- the cage By inserting the electrode group together with the cage into the square battery can, the cage performs the function of an insertion guide, so that the electrode group can be easily inserted into the square battery can without requiring the above-mentioned attention. For this reason, manufacture can be made fast and easy.
- the cage is preferably made of a plastic material because it has insulating properties and is easy to form. Since it is necessary to provide a space for storing a sufficient amount of electrolyte between the square battery can 1 and the cage, the cage is provided at the corner of the square battery can 1 by the surface portion that supports the electrodes of the electrode group. It is desirable that the support portion supporting the surface portion in contact with the rectangular battery can be in contact with a point. Moreover, in order to fully infiltrate electrolyte solution to an electrode group, what has the function to permeate electrolyte solution to the holder itself is desirable. A through hole may be provided in the cage to provide the permeation function.
- the support portion may be formed by bending an end portion of an insulating sheet having a beam, or may be molded from a mold having the surface portion and the plurality of support portions from the beginning.
- the support portion may be hemispherical.
- the formation of the hemispherical shape may be a structure in which a plurality of hemispherical shapes are formed by hot press molding in which a mold having a plurality of convex portions is heated and pressed against a sheet-like plastic material having a beam.
- a structure in which a plurality of the hemispherical shapes are formed by vacuum molding may be used.
- the above-mentioned insulating auxiliary sheet is used only for electrical insulation between the electrode group and the rectangular battery can, and therefore may or may not have a beam.
- the assembled battery may be configured by connecting a plurality of the secondary batteries in series or in parallel.
- the end of the electrode group Can prevent deformation of each electrode along the roundness of the corner of the rectangular battery can, resulting in a secondary battery that exhibits less failure and performs as designed, and power supply and storage using the same battery You can get a system.
- This effect can be obtained in any of a laminated type and a wound type secondary battery, for example, a laminated type lithium ion secondary battery or a wound type lithium ion secondary battery.
- FIG. 1 is a schematic configuration diagram of a stacked secondary battery 101 according to a first embodiment of the present invention, in which FIG. 1A is a sectional view of a rectangular battery can, and FIG. It is.
- FIG. 3 is a schematic cross-sectional view of a multilayer secondary battery 102 according to a second embodiment of the present invention.
- FIG. 6 is a schematic cross-sectional view of a multilayer secondary battery 103 according to a third embodiment of the present invention.
- FIG. 4 is a schematic configuration diagram of a cage 13 of a stacked secondary battery 104 according to a fourth embodiment of the present invention, where FIG. 4 (a) is a top view and FIG. 4 (b) is a cross-sectional view taken along line II-II.
- FIG. 4 (a) is a top view
- FIG. 4 (b) is a cross-sectional view taken along line II-II.
- FIG. 4 (a) is a top view
- FIG. 4 (b) is a cross
- FIG. 7A is a cross-sectional view at a normal time
- FIG. 7 (c) is an enlarged cross-sectional view of the main part I of FIG. 7 (b).
- (First embodiment) 1 (a) and 1 (b) are plane directions in which the positive electrode terminal 8 and the negative electrode terminal 9 of the prismatic battery can 1 are formed in the laminated secondary battery 101 according to the first embodiment of the present invention, respectively.
- 2 is a cross-sectional view (hereinafter referred to as “first direction”) and an internal perspective view of the battery can.
- first direction a cross-sectional view
- FIG.1 (b) the position of each electrode terminal 8 and 9 is also shown.
- the stacked secondary battery 101 includes a square battery can 1, an electrode group G, and a first insulation provided between the square battery can 1 and the electrode group G.
- FIG. 1A the stacked secondary battery 101 includes a square battery can 1, an electrode group G, and a first insulation provided between the square battery can 1 and the electrode group G.
- the battery can 1 is a rectangular shape in which the can wall 1a forms a box-like body, and the electrode terminals 8 and 9 are provided on the can wall 1a on one side in the first direction. Is provided. As shown in FIG. 1A, the battery can 1 extends in directions intersecting each other (a laminating direction and a second direction described later) in a closed cross section orthogonal to the first direction, and is adjacent to each other. Two can flat wall portions 1b are configured to be continuous via a corner portion 1c having a curvature.
- a substantially rectangular sheet-like positive electrode 2 electrically connected to the positive electrode terminal 8 and a substantially rectangular sheet-like negative electrode electrically connected to the negative electrode terminal 9 are provided inside the rectangular battery can 1 formed of aluminum or the like.
- 3 is housed in a plurality of stacked electrode groups G via a separator (not shown).
- the two insulating properties are arranged so as to sandwich the electrode group from the long-side cross-sectional direction (hereinafter referred to as “second direction”) in which the electrode terminals 8 and 9 of the rectangular battery can 1 are formed.
- the auxiliary sheet 4 and two cages 5 arranged so as to sandwich the electrode group from the short side direction (hereinafter referred to as “stacking direction”) of the cross section are inserted.
- the two laminated end faces 23 in which the end of each sheet-like positive electrode 2 and the end of each sheet-like negative electrode 3 are continuous are sandwiched by the two cages 5 from the direction along the second direction. Yes. These two laminated end faces 23 are opposed to the can wall flat portion 1b via the gap 7 in the second direction.
- the gap 7 stores the above-described electrolyte solution (not shown).
- the cage 5 has a surface portion (support surface portion 5a) in contact with and supporting the end portion of each sheet-like electrode of the electrode group G, that is, the laminated end surface 23. Moreover, it has two support parts (support leg part 5b) which contact
- the support leg portion 5b extends from both ends of the support surface portion 5a in the stacking direction to the can flat wall portion 1b and is in contact with the can flat wall portion 1b.
- the support portion having a substantially U-shape is formed by bending both ends of the insulating sheet having one beam.
- the surface portion is formed integrally with the surface portion, and the shape in the short side direction of the cross section that supports the surface in contact with the rectangular battery can at the short side of the cross section is a substantially square shape. You may mold so that it may have two support parts. It is desirable that the cage 5 is made of a plastic resin from the viewpoint of insulation and easy formation.
- the dimension of the support surface portion 5a of the cage 5 in the stacking direction is preferably substantially the same as the square battery can inner method (inner) f in the stacking direction.
- the vertical distance c from the portion of the cage 5 in contact with the rectangular battery can 1 to the support surface portion 5a is the electrode surface width in the long side direction (second direction) of the cross section, and the cross section long side direction internal method. Is b, and the thickness of the support surface portion 5a of the cage 5 is e.
- the electrode surface width a is the width of the flat surface (can flat wall portion 1b) excluding the rounded corner portion (corner portion 1c) in the long side direction of the square battery can 1 described above. Designed to be approximately the same size.
- the thickness e of the support surface portion 5a is designed to have a sufficient beam to support each electrode of the electrode group G. It may be a plate-like thickness that is difficult to deform, such as bending and bending.
- the gap 7 formed by the stacked end face 23 of the electrode group and the rectangular battery can 1 with the cage 5 interposed therebetween needs to have a dimension that can sufficiently store the electrolytic solution.
- the support surface portion 5a sandwiching the electrode group G of the cage 5 supports the electrode group G, and the substantially leg-shaped support leg portion 5b supports the support surface portion 5a, thereby generating vibration.
- the sheet-like electrodes 2 and 3 at the end of the electrode group are prevented from entering the rounded corners of the rectangular battery can 1, and as a result, battery failure can be prevented.
- the cage 5 serves as an insertion guide when the electrode group G is inserted into the prismatic battery can 1, the electrode group can be inserted into the prismatic battery can 1 at high speed and safely. Therefore, the manufacturing speed can be improved.
- the insulating auxiliary sheet 4 is only for electrical insulation between the rectangular battery can 1 and the electrode group G, it may be a non-beam, for example, an insulating plastic film.
- the cage 5 needs to be at least a material with a beam and a thickness. You may use the material which does not generate
- the case where the stacked secondary battery electrode group is enclosed in the rectangular battery can is shown, but the case where the wound type secondary battery electrode group is enclosed in the rectangular battery can is also shown. Needless to say, similar effects can be obtained.
- the secondary battery for example, a lithium ion secondary battery can be targeted.
- a stacked secondary battery 102 according to a second embodiment of the present invention will be described with reference to FIG.
- the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within a range not changing the gist of the present invention.
- symbol is attached
- the stacked secondary battery 102 has a cage 10 different from the cage 5 of FIG. 1.
- the cage 10 is supported by a support surface portion 5a that supports each sheet-like electrode of the electrode group G, and the support surface portion 5a is integral with the corner portion 1c of the rectangular battery can 1 so as to fill a rounded portion (inner corner).
- the second embodiment is the same as the first embodiment.
- the cage 10 includes two supporting leg portions 10b that fill the rounded portion of the corner portion 1c of the rectangular battery can 1 and come into contact with the rectangular battery can 1, and each of the supporting leg portions 10b has two points. Since the support surface portion 5a is supported, unlike the cage 5 of FIG. 1, the sheet-like electrodes 2 and 3 of the electrode group G are more firmly prevented from entering the rounded portion of the corner portion 1c of the prismatic battery can 1. can do.
- a stacked secondary battery 103 according to a third embodiment of the present invention will be described with reference to FIG.
- the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within a range not changing the gist of the present invention.
- symbol is attached
- the stacked secondary battery 103 is positioned between the two support legs 10b of the cage 10 of FIG. 2, and extends from the support surface 5a to the can flat wall 1b so that the can flat wall 1b. It is set as the structure which provided the holder
- FIGS. 4 (a) and 4 (b) A laminated secondary battery 104 according to a fourth embodiment of the present invention will be described with reference to FIGS. 4 (a) and 4 (b).
- the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within a range not changing the gist of the present invention.
- symbol is attached
- FIG. 4A is a plan view of the cage 13 arranged in the prismatic battery can 1 similarly to the cages 5, 10, and 11.
- FIG. 4B is a cross-sectional view taken along the plane of the hemispherical portion 14 of the cage 13 parallel to the surface of the prismatic battery can provided with the electrode terminals, that is, a cross-sectional view taken along the line II-II.
- the upper part of the illustrated cage 13 is arranged on the surface side where the electrode terminals 8 and 9 of the square battery can 1 are formed, and the lower part thereof is arranged on the bottom side of the square battery can 1.
- the cage 13 includes a plurality of hemispherical portions 14.
- the hemispherical portion 14 serves as a support leg that contacts the prismatic battery can 1.
- Each of the plurality of hemispherical portions 14 is formed by a method of heating and pressing a mold in which a plurality of convex portions are formed in alignment with a sheet-like plastic material having a beam, that is, a hot press molding method. You may shape
- the process of bending the insulating sheet to be the cage 5 and the shape of the cage 10 and the cage 11 This eliminates the need for a complicated process such as a mold making process when molding a mold with plastic.
- the cage 13 is formed simply by pressing the mold from one side of the sheet-like plastic material. Therefore, the manufacturing process is simplified and the manufacturing cost can be reduced.
- a laminated secondary battery 105 according to a fifth embodiment of the present invention will be described with reference to FIG.
- the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within a range not changing the gist of the present invention.
- symbol is attached
- FIG. 5 is a plan view of the cage 15 arranged in the prismatic battery can 1 similarly to the cages 5, 10, 11, and 13.
- the upper portion of the cage 15 is disposed on the surface side where the electrode terminals of the rectangular battery can 1 are formed, and the lower portion thereof is disposed on the bottom surface side of the rectangular battery can 1.
- the cage 15 is different from the cage 13 in that a plurality of hemispherical portions 14 are arranged in a staggered manner. Except for this point, the second embodiment is the same as the fourth embodiment.
- the sheet-like electrodes 2 and 3 are supported by the retainer 15 in contact with the support surface portion 5a in the vertical direction of FIG.
- the hemispherical portions 14 are arranged so that the number of the hemispherical portions 14 in the vertical direction is uniform. It is formed in a staggered pattern. Since the hemispherical portion 14 is formed, a recess is formed in the support surface portion 5a in which the cage 15 supports the electrode group G on the surface, but the surface portion excluding the recess portion of each sheet-like electrode. By making each of the areas corresponding to the two substantially the same, the pressure difference between each sheet-like electrode and the cage 15 can be alleviated substantially uniformly. Therefore, the effect of reducing the failure occurrence rate can be expected more than the cage 13 in the fourth embodiment.
- the secondary battery 122 mounted on the electric vehicle 121 and the standby secondary battery 117 disposed outside the house 115 are the secondary batteries according to the present invention described in the first to fifth embodiments.
- Electric power generated from power generation facilities 120 such as wind power generation, thermal power generation, hydroelectric power generation, nuclear power generation, solar cells, and fuel cells is supplied to a control box 118 used by a user via a supply power system 119.
- the power transmitted from the power generation facility 120 is supplied to any one of the secondary battery 122, the standby secondary battery 117, and the switchboard 116, which are power sources for driving the electric vehicle 121.
- the standby secondary battery 117 or the secondary battery 122 of the electric vehicle 121 is charged and stored when electric power is supplied.
- the control box may be programmed to supply power to the switchboard 116 during the daytime and to the secondary battery 117 or the secondary battery 122 of the electric vehicle 121 during the nighttime.
- the standby secondary battery 117 charged by the power storage system is electrically connected to the switchboard 116 in the house 115 via the control box 118.
- the switchboard 116 is electrically connected to electrical appliances such as air conditioners and televisions connected to plugs in the house 115.
- the user can select whether to drive the electrical appliance in the house 115 by receiving power from the power feeding system 119 or to drive the electrical appliance using the power of the standby secondary battery 117 stored by the power storage system, This selection / switching is performed by the control box 118.
- the backup secondary battery 117 is electrically connected to the switchboard 116 by switching in the control box 118, power is supplied from the backup secondary battery 117 to the switchboard 116, and the appliance can be driven.
- the electric vehicle 121 can run by supplying power to the motor that drives the wheels from the secondary battery 122 stored by the power storage system.
- the electric vehicle 21 may be a vehicle capable of driving wheels with an electric motor, and may be a hybrid vehicle.
- the power storage / power supply system using the secondary battery according to the present invention it is possible to prevent as much as possible the stacking deviation and the electrode bending at the corner of the rectangular battery can due to the vibration that is a cause of failure in the secondary battery.
- a power supply system in a car with a lot of vibrations and a power supply / storage system in an earthquake-prone country stable operation with few failures is possible.
Abstract
Description
このリチウムイオン二次電池の形態としては、一対の帯状のシート状正極電極とシート状負極電極とをセパレータを介して渦巻状に巻回した巻回型リチウムイオン二次電池と、複数のシート状正極とシート状負極とを複数のセパレータを介して積層した積層型リチウムイオン二次電池がある。
積層型リチウムイオン二次電池では、上記複数のシート状正極とシート状負極とからなる電極群は、断面が略長方形の角型の電池缶に封入されるのが通常である。一方、巻回型リチウムイオン二次電池では、断面が略円形の円筒型の電池缶に封入される場合もあれば、角型電池缶に封入される場合もある。
そこで、角型電池缶に積層型リチウムイオン二次電池の電極群を封入する場合に、絶縁性の補助シートを電極群の最端部にあるシート状電極面上に設け、電極群とともにテープ固定する提案がなされている(下記特許文献1参照)。
また、角型電池缶1には電解液を蓄える必要があるため、電極群Gと角型電池缶1との間には一定の空間を設けなければならない。このため絶縁性補助シート6は絶縁に最低限耐えられる程度の厚み、言い換えれば極めて薄くはりのない絶縁体が用いられている。
すなわち、正極端子および負極端子を備えた角型電池缶と、前記角型電池缶内に配置され、前記正極端子に電気的に接続されたシート状正極及び前記負極端子に電気的に接続されたシート状負極がセパレータを介して積層された電極群と、前記角型電池缶の前記正極端子および前記負極端子が形成された面の長辺側から前記電極群を挟んで対向する位置にそれぞれ配置された第1および第2の絶縁性補助シートと、前記面の短辺方向の前記角型電池缶内法と実質的に同一寸法の幅を前記面の短辺方向に備え、前記短辺側から前記電極群を挟んで対向する位置にそれぞれ配置され、且つ複数箇所で前記角型電池缶と接して前記電極群を支える第1および第2の保持器とを有することを特徴とする。
電気自動車としては、電気で駆動可能な自動車であればよく、ハイブリッド自動車でもよい。
発電設備としては、太陽電池、燃料電池、風車、火力発電設備、水力発電設備、原子力発電設備など、発電を行う設備であればいずれのものでもよく、自動車、自転車などに備えられる単なる発電機でもよい。発電所でなくとも、一般家庭に設置される発電設備でもよい。
また、電極群へ十分に電解液を浸透させるために、保持器それ自体に電解液を浸透させる機能があるものが望ましい。保持器に貫通穴を設けて当該浸透機能をもたせてもよい。
上記支持部分は、はりのある絶縁性シートの端部を折り曲げて形成してもよいし、当初から上記面部分と複数の上記支持部分とを有するような型により成型してもよい。
上記支持部分は半球形状としてもよい。半球形状の形成については、はりのあるシート状のプラスチック材に複数の凸部のある型を熱して押し当てる熱プレス成型により半球形状を複数形成した構造でもよい。または真空成型して上記半球形状を複数形成した構造でもよい。
1a…缶壁
1b…缶平壁部
1c…角部
2…シート状正極
3…シート状負極
4…絶縁性補助シート
5,10,11,13,15…保持器
5a…支持面部
5b,10b…支持脚部
7…間隙
8…正極端子
9…負極端子
12…補助支持脚部
14…半球状部分
101,102,103,104,105…積層型二次電池
115…家屋
116…配電盤
117…予備二次電池
118…制御ボックス
119…給電電力系統
120…発電設備
121…電気自動車
122…二次電池
G…電極群
図1(a)、図1(b)は、それぞれ本発明の第1の実施形態に係る積層型二次電池101における角型電池缶1の正極端子8、負極端子9が形成された面方向(以下、「第一の方向」という)での断面図および同電池缶の内部斜視図である。なお、図1(b)では、各電極端子8、9の位置も示している。
図1(a)に示すように、積層型二次電池101は、角型電池缶1と、電極群Gと、これら角型電池缶1と電極群Gとの間に設けられた第1絶縁性補助シート(第1絶縁性補助部材)4及び保持器5と、図示しない電解液とから概略構成される。
電池缶1は、図1(b)に示すように、缶壁1aが箱状体を構成する角型のものであり、第一の方向の一方側における缶壁1aに電極端子8、9が設けられている。
この電池缶1は、図1(a)に示すように、第一の方向に直交する閉断面において、互いに交差する方向(後述の積層方向及び第二の方向)に伸びると共に、互いに隣接する二つの缶平壁部1bが曲率を持った角部1cを介して連続する構成とされている。
そして、角型電池缶1の各電極端子8、9が形成された面方向の断面長辺方向(以下、「第二の方向」という)から電極群を挟み込むように配置された2つの絶縁性補助シート4と、上記断面の短辺方向(以下、「積層方向」という)から電極群を挟み込むように配置された2つの保持器5が挿入される。
言い換えれば、各シート状正極2の端部と各シート状負極3の端部とが連続してなる二つの積層端面23が、2つの保持器5によって第二の方向に沿う方向から挟まれている。
これら二つの積層端面23は、第二の方向において、それぞれ缶壁平部1bと間隙7を介して対向している。そして、この間隙7には、上述した図示しない電解液が蓄えられる。
保持器5は、電極群Gの各シート状電極の端部、すなわち積層端面23に接してこれらを支える面部分(支持面部5a)を有する。また、角型電池缶1に点で接する支持部分(支持脚部5b)を2つ有する。支持脚部5bは、支持面部5aの積層方向両端部から缶平壁部1bまで延出して、この缶平壁部1bと接している。
この形状の保持器5では、1つのはりのある絶縁シートの両端を折り曲げることで、上記面部分と略くの字の上記支持部分が形成される。もちろん、当初より、上記面部分と、上記面部分と一体に形成され且つ上記断面の短辺で角型電池缶と接して上記面を支える上記断面短辺方向の形状が略くの字の上記支持部分を2つ有するように型成型してもよい。絶縁性を有しかつ形成容易の点で、保持器5はプラスチック樹脂で形成されることが望ましい。
保持器5の角型電池缶1と接する箇所から上記支持面部5aまでの垂直距離cは、上記断面の長辺方向(第二の方向)の電極面幅をa、上記断面長辺方向内法をb、保持器5の上記支持面部5aの厚みをeとすると、
c ≒ (b-2e-a)÷2
となるよう設計される。電極面幅aは電気容量を極力大きくするために、角型電池缶1の上記断面長辺方向の角の丸み部分(角部1c)を除いた平らな面(缶平壁部1b)の幅寸法とほぼ同一となるよう設計される。
また、上記支持面部5aの厚みeは電極群Gの各電極を支えるに十分なはりを有するように設計される。曲がり、たわみ等の変形困難な板状の厚みとしてもよい。
(f-g)÷2 ≒ d
と設計するのが望ましい。
さらに、保持器5が電極群Gを角型電池缶1へ挿入する際に挿入ガイドの役割を果たすため、電極群を角型電池缶1に高速かつ安全に挿入することができる。よって、製造速度の改善を図ることができる。
絶縁性補助シート4は、角型電池缶1と電極群Gとの電気的絶縁をするためだけのものであるので、はりのないもの、例えば絶縁性のプラスチック膜でもよい。
保持器5ははりのある材料、厚みであることが少なくとも必要である。たわみや折れ曲がりの発生し難い変形困難な材料を用いてもよい。
本発明の第2の実施形態に係る積層型二次電池102について、図2を参照して説明する。本発明は以下の実施形態に限定されるものでなく、本発明の要旨を変更しない範囲内で適宜変更して実施できる。なお、図1と同様の構成要素については、同一の符号を付し、その説明を省略する。
本発明の第3の実施形態に係る積層型二次電池103について、図3を参照して説明する。本発明は以下の実施形態に限定されるものでなく、本発明の要旨を変更しない範囲内で適宜変更して実施できる。なお、図1、図2と同様の構成要素については、同一の符号を付し、その説明を省略する。
本構成では、上記板状の補助支持脚部12により、第2の実施形態よりも、電極群Gを支える保持器11の支持面部5aをさらにしっかりと支えることができる。
図3では、上記板状の補助支持脚部12を角型電池缶1の断面短辺方向のほぼ中間の位置に1つだけ示しているが、電解液を十分に蓄えられる場合には、上記板状の補助支持脚部12を複数形成して、よりしっかりと保持器11の支持面部5aを支える構成としてもよい。
本発明の第4の実施形態に係る積層型二次電池104について、図4(a)、図4(b)を参照して説明する。本発明は以下の実施形態に限定されるものでなく、本発明の要旨を変更しない範囲内で適宜変更して実施できる。なお、図1、図2および図3と同様の構成要素については、同一の符号を付し、その説明を省略する。
図示された保持器13の上部が角型電池缶1の電極端子8、9が形成された面側に、その下部が角型電池缶1の底面側に配置される。
保持器13は、複数の半球状部分14を備えている。半球状部分14が角型電池缶1に接する支持脚部となる。その点以外は、上記第1の実施形態と同様である。
複数の半球状部分14のそれぞれは、はりのあるシート状のプラスチック材料に複数の凸部が整列して形成された金型を熱して押し当てる方法、すなわち熱プレス成型法により形成される。真空成型法を用いて同様に成型してもよい。
本発明の第5の実施形態に係る積層型二次電池105について、図5を参照して説明する。本発明は以下の実施形態に限定されるものでなく、本発明の要旨を変更しない範囲内で適宜変更して実施できる。なお、図1、図2、図3および図4と同様の構成要素については、同一の符号を付し、その説明を省略する。
保持器15は、複数の半球状部分14が千鳥状に配置された点で、保持器13と相違している。その点以外は、上記第4の実施形態と同様である。
シート状電極2、3は図5の上下方向で支持面部5aに当接して保持器15により支えられることとなるが、この上下方向の半球状部分14の数をそろえるように半球状部分14が千鳥状に形成されている。半球状部分14が形成されることで、保持器15が電極群Gを面で支える支持面部5aには凹みが形成されることになるが、各シート状電極の上記凹み部分を除く上記面部分に当たる面積をそれぞれ略同一とできることで、各シート状電極と保持器15間の圧力差をほぼ均一に緩和できる。よって、第4の実施形態における保持器13よりも故障発生率低減の効果が期待できる。
本発明の第6の実施形態に係る二次電池を利用した蓄電・給電システムについて、図6を参照して説明する。本発明は以下の実施形態に限定されるものでなく、本発明の要旨を変更しない範囲内で適宜変更して実施できる。
昼間は配電盤116、夜間は予備二次電池117または電気自動車121の二次電池122へ電力供給するように制御ボックスをプログラム制御してもよい。
制御ボックス118における切り替えにより、予備二次電池117が配電盤116に電気的に接続された場合には、予備二次電池117から配電盤116へ給電され、上記電化製品の駆動が可能となる。
Claims (5)
- 正極端子および負極端子を備えた角型電池缶と、
前記角型電池缶内に配置され、前記正極端子に電気的に接続されたシート状正極及び前記負極端子に電気的に接続されたシート状負極がセパレータを介して積層された電極群と、
前記角型電池缶の前記正極端子および前記負極端子が形成された面の長辺側から前記電極群を挟んで対向する位置にそれぞれ配置された第1および第2の絶縁性補助シートと、
前記面の短辺方向の前記角型電池缶内法と実質的に同一寸法の幅を前記面の短辺方向に備え、前記短辺側から前記電極群を挟んで対向する位置にそれぞれ配置され、且つ複数箇所で前記角型電池缶と接して前記電極群を支える第1および第2の保持器とを有することを特徴とする二次電池。 - 前記第1および第2の保持器の前記複数箇所で接する部位は、それぞれ半球状であることを特徴とする請求項1に記載の二次電池。
- 前記保持器はプラスチック材料の熱プレス成型により形成されることを特徴とする請求項2に記載の二次電池。
- 正極端子および負極端子を備えた角型電池缶と、
前記角型電池缶内に配置され、前記正極端子に電気的に接続されたシート状正極及び前記負極端子に電気的に接続されたシート状負極がセパレータを介して積層された電極群と、
前記角型電池缶の前記正極端子および前記負極端子が形成された面の長辺側から前記電極群を挟んで対向する位置にそれぞれ配置された第1および第2の絶縁性補助シートと、
前記面の短辺方向の前記角型電池缶内法と実質的に同一寸法の幅を前記面の短辺方向に備え、前記短辺側から前記電極群を挟んで対向する位置にそれぞれ配置され、且つ複数箇所で前記角型電池缶と接して前記電極群を支える第1および第2の保持器とを備えた二次電池と、
車輪を駆動するモーターとを有し、
前記モーターは前記二次電池から給電を受けて駆動することを特徴とする電気自動車。 - 正極端子および負極端子を備えた角型電池缶と、
前記角型電池缶内に配置され、前記正極端子に電気的に接続されたシート状正極及び前記負極端子に電気的に接続されたシート状負極がセパレータを介して積層された電極群と、
前記角型電池缶の前記正極端子および前記負極端子が形成された面の長辺側から前記電極群を挟んで対向する位置にそれぞれ配置された第1および第2の絶縁性補助シートと、
前記面の短辺方向の前記角型電池缶内法と実質的に同一寸法の幅を前記面の短辺方向に備え、前記短辺側から前記電極群を挟んで対向する位置にそれぞれ配置され、且つ複数箇所で前記角型電池缶と接して前記電極群を支える第1および第2の保持器とを備えた二次電池と、
発電設備とを有し、
前記二次電池は前記発電設備から給電を受けて蓄電することを特徴とする蓄電システム。
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2009
- 2009-03-31 KR KR1020107026400A patent/KR101269265B1/ko active IP Right Grant
- 2009-03-31 US US13/123,139 patent/US20110200872A1/en not_active Abandoned
- 2009-03-31 EP EP09842625A patent/EP2416398A1/en not_active Withdrawn
- 2009-03-31 JP JP2010541604A patent/JP5244919B2/ja active Active
- 2009-03-31 CN CN200980118048XA patent/CN102037598B/zh active Active
- 2009-03-31 WO PCT/JP2009/056681 patent/WO2010113271A1/ja active Application Filing
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US20160133885A1 (en) * | 2010-11-02 | 2016-05-12 | Sharp Kabushiki Kaisha | Secondary battery |
WO2013154155A1 (ja) * | 2012-04-13 | 2013-10-17 | 株式会社 豊田自動織機 | 蓄電装置及び二次電池 |
JP2013235818A (ja) * | 2012-04-13 | 2013-11-21 | Toyota Industries Corp | 蓄電装置及び二次電池 |
US9905826B2 (en) | 2012-04-13 | 2018-02-27 | Kabushiki Kaisha Toyota Jidoshokki | Electric storage device and rechargeable battery |
JP2014078389A (ja) * | 2012-10-10 | 2014-05-01 | Toyota Industries Corp | 蓄電装置 |
Also Published As
Publication number | Publication date |
---|---|
JP5244919B2 (ja) | 2013-07-24 |
EP2416398A1 (en) | 2012-02-08 |
KR101269265B1 (ko) | 2013-05-29 |
US20110200872A1 (en) | 2011-08-18 |
CN102037598B (zh) | 2013-08-28 |
KR20110005892A (ko) | 2011-01-19 |
CN102037598A (zh) | 2011-04-27 |
JPWO2010113271A1 (ja) | 2012-10-04 |
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